Right to Know Hazardous Substance Fact Sheet Common Name: METHYLENE CHLORIDE Synonyms: Dichloromethane; Methylene Dichloride CAS Number: 75-09-2 Chemical Name: Methane, Dichloro- RTK Substance Number: 1255 Date: October 2008 Revision: September 2016 DOT Number: UN 1593 Description and Use EMERGENCY RESPONDERS >>>> SEE BACK PAGE Methylene Chloride is a colorless, volatile, liquid with a sweet Hazard Summary odor. It is used as a paint and varnish remover, solvent for Hazard Rating NJDHSS NFPA plastics, degreasing agent, propellant, and blowing agent. HEALTH - 2 FLAMMABILITY - 1 ODOR THRESHOLD=25 to 150 ppm REACTIVITY - 0 Odor thresholds vary greatly. Do not rely on odor alone to determine potentially hazardous exposures. CARCINOGEN POISONOUS GASES ARE PRODUCED IN FIRE Reasons for Citation Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious; Methylene Chloride is on the Right to Know Hazardous 4=severe Substance List because it is cited by OSHA, ACGIH, DOT, NIOSH, NTP, DEP, IARC, NFPA and EPA. Methylene Chloride can affect you when inhaled and by This chemical is on the Special Health Hazard Substance passing through the skin List. Methylene Chloride should be handled as a CARCINOGEN and MUTAGEN--WITH EXTREME CAUTION. Contact can severely irritate and burn the skin and eyes with possible eye damage. Inhaling Methylene Chloride can irritate the nose, throat SEE GLOSSARY ON PAGE 5. and lungs. Higher exposure can cause headache, nausea, dizziness, FIRST AID weakness and unconsciousness. Eye Contact Methylene Chloride may damage the liver and affect the Immediately flush with large amounts of water for at least 30 kidneys and brain. minutes, lifting upper and lower lids. Remove contact lenses, if worn, while flushing. Seek medical attention. Skin Contact Workplace Exposure Limits Quickly remove contaminated clothing. Immediately wash OSHA: The legal airborne permissible exposure limit (PEL) is contaminated skin with large amounts of soap and water. 25 ppm averaged over an 8-hour workshift and 125 ppm, not to be exceeded during any 15-minute Inhalation work period. Remove the person from exposure Begin rescue breathing (using universal precautions) if breathing has stopped and CPR if heart action has stopped. NIOSH: Recommends that exposure to occupational Transfer promptly to a medical facility. carcinogens be limited to the lowest feasible concentration. EMERGENCY NUMBERS Poison Control: 1-800-222-1222 ACGIH: The threshold limit value (TLV) is 50 ppm averaged CHEMTREC: 1-800-424-9300 over an 8-hour workshift. NJDEP Hotline: 1-877-927-6337 National Response Center: 1-800-424-8802 Methylene Chloride may be a CARCINOGEN in humans. There may be no safe level of exposure to a carcinogen, so all contact should be reduced to the lowest possible level. The above exposure limits are for air levels only. When skin contact also occurs, you may be overexposed, even though air levels are less than the limits listed above. METHYLENE CHLORIDE Page 2 of 6 Determining Your Exposure Reproductive Hazard Read the product manufacturer’s Material Safety Data There is limited evidence that Methylene Chloride causes Sheet (MSDS) and the label to determine product spontaneous abortions. ingredients and important safety and health information about the product mixture. Other Effects Methylene Chloride can irritate the lungs. Repeated For each individual hazardous ingredient, read the New exposure may cause bronchitis to develop with coughing, Jersey Department of Health and Senior Services phlegm, and/or shortness of breath. Hazardous Substance Fact Sheet, available on the RTK Methylene Chloride may damage the liver and affect the Program website kidneys. (http://www.state.nj.us/health/workplacehealthandsafety/ri Long-term exposure may affect the brain causing memory loss, poor coordination, and reduced thinking ability ght-to-know/) or in your facility’s RTK Central File or . Hazard Communication Standard file. You have a right to this information under the New Jersey Worker and Community Right to Know Act, the Public Medical Employees Occupational Safety and Health (PEOSH) Act Medical Testing if you are a public worker in New Jersey, and under the Before first exposure and every 12 months thereafter, OSHA federal Occupational Safety and Health Act (OSHA) if you requires your employer to provide (for persons exposed to greater than 12.5 ppm of Methylene Chloride): are a private worker. The New Jersey Right to Know Act requires most Complete work and medical history employers to label chemicals in the workplace and Thorough physical examination requires public employers to provide their employees with Liver and kidney function tests information concerning chemical hazards and controls. If symptoms develop or overexposure is suspected, the The federal OSHA Hazard Communication Standard (29 following are recommended: CFR 1910.1200) and the PEOSH Hazard Communication Standard (N.J.A.C. 12:100-7) require employers to provide Lung function tests similar information and training to their employees. Exam of the nervous system Evaluate for brain effects such as changes in memory, This Fact Sheet is a summary of available information concentration, sleeping patterns and mood (especially regarding the health hazards that may result from exposure. irritability and social withdrawal), as well as for headaches Duration of exposure, concentration of the substance and other and fatigue. Consider evaluations of the cerebellar, factors will affect your susceptibility to any of the potential autonomic and peripheral nervous systems. Positive and effects described below. borderline individuals should be referred for neuropsychological testing. OSHA requires your employer to provide you and your doctor Health Hazard Information with a copy of the OSHA Methylene Chloride Standard (29 Acute Health Effects CFR 1910.1052). The following acute (short-term) health effects may occur immediately or shortly after exposure to Methylene Chloride: Any evaluation should include a careful history of past and present symptoms with an exam. Medical tests that look for Contact can severely irritate and burn the skin and eyes with damage already done are not a substitute for controlling possible eye damage. exposure. Inhaling Methylene Chloride can irritate the nose, throat and lungs causing coughing, wheezing and/or shortness of Request copies of your medical testing. You have a legal right breath. to this information under the OSHA Access to Employee Higher exposure can cause headache, nausea, fatigue, Exposure and Medical Records Standard (29 CFR 1910.1020). dizziness, lightheadedness, weakness and unconsciousness. Mixed Exposures More than light alcohol consumption can cause liver Chronic Health Effects damage. Drinking alcohol may increase the liver damage The following chronic (long-term) health effects can occur at caused by Methylene Chloride. some time after exposure to Methylene Chloride and can last for months or years: Cancer Hazard Methylene Chloride may be a CARCINOGEN in humans since it has been shown to cause liver and lung cancer in animals. Many scientists believe there is no safe level of exposure to a carcinogen. METHYLENE CHLORIDE Page 3 of 6 All protective clothing (suits, gloves, footwear, headgear) Workplace Controls and Practices should be clean, available each day, and put on before work. Do not wear leather shoes. Methylene Chloride is Very toxic chemicals, or those that are reproductive hazards or absorbed into the leather and can not be removed by sensitizers, require expert advice on control measures if a less cleaning. toxic chemical cannot be substituted. Control measures include: (1) enclosing chemical processes for severely irritating and corrosive chemicals, (2) using local exhaust Eye Protection ventilation for chemicals that may be harmful with a single Wear non-vented, impact resistant goggles when working exposure, and (3) using general ventilation to control with fumes, gases, or vapors. exposures to skin and eye irritants. For further information on Wear indirect-vent, impact and splash resistant goggles workplace controls, consult the NIOSH document on Control when working with liquids. Banding at www.cdc.gov/niosh/topics/ctrlbanding/. Wear a face shield along with goggles when working with corrosive, highly irritating or toxic substances. The following work practices are also recommended: Respiratory Protection Label process containers. Improper use of respirators is dangerous. Respirators Provide employees with hazard information and training. should only be used if the employer has implemented a written Monitor airborne chemical concentrations. program that takes into account workplace conditions, Use engineering controls if concentrations exceed requirements for worker training, respirator fit testing, and recommended exposure levels. medical exams, as described in the OSHA Respiratory Provide eye wash fountains and emergency showers. Wash or shower if skin comes in contact with a hazardous Protection Standard (29 CFR 1910.134). material. Always wash at the end of the workshift. Where the potential exists for exposure over 25 ppm, use a Change into clean clothing if clothing becomes NIOSH approved supplied-air respirator with a full facepiece contaminated. operated in a pressure-demand or other positive-pressure Do not take contaminated clothing home. mode. For increased protection use in combination with an Get special training to wash contaminated clothing. auxiliary self-contained