Appendix: List of investigated metabolites and respective limits of detection Analyte LOD (µg/kg sample) 15-Acetyldeoxynivalenol 53 15-Hydroxyculmorin 18 15-Hydroxyculmoron 110 15-Methyl_epi_Fumiquinazolin A N/A 15-Monoacetoxyscirpenol 7 16-Ketoaspergillimide 2 2-Chlorunguinol 0,3 3-Acetyldeoxynivalenol 5 3-Nitropropionic acid 4 3-O-Methylvirdicatin 1 4-Hydroxyalternariol 9 4-Monoacetoxyscirpenol N/A 5-Hydroxyculmorin 180 5-Methylmellein 26 7-Hydroxypestalotin 2 A 23187 N/A AAL TA Toxin 21 Abscisic acid 7 Acetyldeoxypentahydroxyscirpenol N/A Acetylpentahydroxyscirpenol N/A Aflatoxicol 9 Aflatoxin B1 1 Aflatoxin B2 2 Aflatoxin G1 1 Aflatoxin G2 4 Aflatoxin M1 2 Aflatoxin M2 N/A Aflatoxin P1 11 Aflatrem N/A Aflavarin N/A Agistatin B 35 Agistatin D 25 Agistatin E 12 Agroclavine 1 Aigualomycin D 9 Alamethicin F30 4 alpha-Zearalenol 4 alpha-ZOL-Glucosid 11 Alteichin N/A Altenuene 2 Altenusin 280 Alternarian acid 350 Alternariol 2 Alternariol-3-glucoside 4 Alternariol-9-glucoside 4 Alternariolmethylether 0,1 Alternariolmethylether-glucoside 35 Altersetin 2 Altersolanol 110 Altertoxin-I 4 Altertoxin II N/A Amidepsin B 5 Aminooctadecyldecan-3-ol 21 Amoxycillin N/A Amphotericin N/A Anacin 28 Andrastin A 1 Andrastin B 2 Andrastin C N/A Andrastin D N/A Anisomycin 1 Anomalin A N/A Antibiotic F 1849 A 4 Antibiotic L 696474 71 Antibiotic PF 1052 7 Apicidin 1 Ascochlorin 1 Ascomycin 11 Asparason A N/A Aspercolorin 4 Asperfuran 71 Aspergamide A 9 Aspergillicin Derivat 4 Aspergillin PZ N/A Aspergillimide 1 Asperglauccide 0,4 Asperlactone 0,1 Asperloxin A 4 Asperphenamate 0,2 Asperthecin N/A Aspinolid B 3 Aspinonene N/A Aspochalasin C 7 Aspochalasin D 7 Aspochalasin I 18 Aspochalasin J 18 Aspterric acid 35 Aspyrone 140 Asterric acid 14 Asteltoxin 9 Atpenin A5 0,2 Atroventinmethylether 5 Aurantiamin A 3 Auranticin A 18 Aurasperon B N/A Aurasperon C N/A Aurasperon G N/A Aureobasidin A 14 Aurofusarin 11 Austalide A 4 Austalide B 4 Austalide D 9 Austalide F 9 Austamide 3 Austdiol N/A Austocystin A 7 Austocystin D 9 Austocystin I 14 Avenacein Y 180 Averantin 0,2 Averantinmethylether 0,3 Averufanin 0,3 Averufin 0,3 Averufin-Derivat 2 Bacitracin N/A Bafilomycin A1 1 Barceloneic acid A 28 Bassianolide 2 Beauvericin 0,04 Benzomalvin A 35 Benzomalvin C 9 Berkedrimane B 2 Berkeleyacetal B 530 beta-Zearalenol 5 beta-ZOL-Glucosid 11 Bikaverin 35 Bis(dethio)methylthiogliotoxin 4 Bismethylgliotoxin 18 Botryan-Derivat N/A Brasiliamide A 11 Brefeldin A 71 Brevianamid F 1 Brevicompanine B 4 Butenolid 25 Butyrolacton I 35 Butyrolacton II 18 Butyrolacton III 9 Calonectrin 25 Calphostin C 18 Calyxanthone 35 Cephalochromin N/A Cephalosporin C N/A Cercosporamide 1 Cercosporin 53 Cereulide 2 Cerulenin 350 Chaetocin 53 Chaetoglobosin A 350 Chaetoglobosin D 350 Chaetomin 71 Chaetoviridin A 4 Chanoclavine 0,4 Chetoseminudin N/A Chevalone C 1 Chlamydospordiol 1 Chlamydosporol 4 Chloramphenicol 1 Chlorocitreorosein 9 Chloronectrin 1 Chlortetracyclin N/A Chrodrimanin 35 Chromomycin A3 N/A Chrysogine 2 Chrysophanol 35 Citreorosein 3 Citreoviridin A 18 Citreoviridin C N/A Citreoviridinol N/A Citrinin 1 Citromycetin 88 CJ 21058 1 Cladosporin 7 Clonostachydiol 4 CNM 115443 4 Cochliodinol N/A Cochlioquinone A N/A Communsein B 2 Cordycepin 9 Culmorin 35 Curvularin 4 Curvulin 1 Cycloaspeptide A 0,4 Cycloechinulin 1 Cycloheximide 9 Cyclo (L-Leu-L-Pro) 3 Cyclo (L-Pro-L-Tyr) 4 Cyclo (L-Pro-L-Val) 3 Cyclopenin 1 Cyclopenol 7 Cyclopeptine 2 Cyclopiazonic acid 53 Cyclosporin A 18 Cyclosporin B 18 Cyclosporin C 18 Cyclosporin D 2 Cyclosporin H 4 Cylindrol B 0 Cylindrocarpon A 0 Cytochalasin D 4 Cytochalasin E 11 Cytochalasin H 71 Cytochalasin J 4 Daunorubicin 53 Deacetylneosolaniol 53 Decalonectrin 25 Decarestrictin 71 Dechlorogriseofulvin 5 Dechloroisochromophilon IV 5 Deepoxy-deoxynivalenol 9 Dehydroaustinol 9 Dehydrocurvularin 7 Dehydrocyclopeptine 7 Dehydrogriseofulvin 2 Demethylasteltoxin 28 Demethylsulochrin 3 Deoxyaltersolaniol A N/A Deoxybrevianamid E 35 Deoxyfusapyrone 4 Deoxynivalenol 5 Deoxynivalenol-3-Glucoside 4 DON-Glutathion N/A Deoxynivalenol-3-Sulfate N/A Deoxynivalenol-15-Sulfate N/A Deoxypentahydroxyscirpenol N/A Deoxytryptoquialanine N/A Deoxytryptoquivaline A 9 Desoxypaxillin N/A Desoxyverrucosidin N/A Destruxin A 2 Destruxin B 4 Destruxin CHL 28 Destruxin D 4 Destruxin Ed 35 Dethiosecoemestrin N/A Diacetoxyscirpenol 2 Dichlormethylasterric acid 4 Dechloronornidulin 0,3 Dihydrobotrydial N/A Dihydrochlamydocin 2 Dihydrocitrinone 9 Dihydroergosine 1 Dihydroergotamine 3 Dihydrogriseofulvin N/A Dihydroinfectopyron 14 Dihydrolysergol 2 Dihydrosterigmatocystin N/A Dihydrotrichotetronine 35 Dihydroxycalonectrin N/A Dihydroxymellein 9 Dimethoxymethylgrisantrion N/A Dihydroxy-ZON-Mrethylether N/A Dinactin N/A Diplodiatoxin 35 Doxorubicin 18 Doxycyclin N/A Drimane 6 110 Drimane 8 7 Elymoclavine 2 Elymoclavine-Fructoside 5 Emindole SA N/A Emodin 0,2 Enniatin A 0,1 Enniatin A1 0,1 Enniatin B 0,1 Enniatin B1 0,2 Enniatin B2 0,2 Enniatin B3 0,01 epi-Equisetin 1 Epoxyagroclavin N/A Epoxycytochalasin C 4 Epoxycytochalasin D 4 Equisetin 1 Eremofortine A 18 Eremofortine B 180 Ergine 0,4 Ergocornine 3 Ergocorninine 1 Ergocristam N/A Ergocristinam N/A Ergocristine 5 Ergocristinine 1 Ergocryptine 3 Ergocryptinine 2 Ergometrine 5 Ergometrinine 0,4 Ergosinine 1 Ergosine 4 Ergotaminine 1 Ergotamine 3 Ergovaline N/A Erythromycin N/A F01 1358-A 4 Fallacinol 1 Fellutannine A 3 Fellutannine B 14 Festuclavine 4 FK 506 9 FK 9775 A N/A FK 9775 B N/A Flavipucin 2 Flavoglaucin 1 Fonsecin N/A FS4 N/A Fulvic acid 26 Fumagillin 71 Fumifungin 140 Fumigaclavine C 11 Fumigaclavine A 1 Fumiquinazolin A 7 Fumiquinazolin D 7 Fumiquinazolin E N/A Fumiquinazolin F 71 Fumiquinazolin I N/A Fumiquinazolin Derivat 71 Fumitremorgin A 9 Fumitremorgin B N/A Fumitremorgin C 9 Fumonisin A1 N/A Fumonisin A1 precursor 9 Fumonisin A2 N/A Fumonisin B1 14 Fumonisin B2 11 Fumonisin B3 11 Fumonisin B4 N/A Fumonisin B6 N/A Fusaproliferin 180 Fusarenon-X 14 Fusapyrone 4 Fusaric acid 71 Fusarin C 21 Fusarinolic acid N/A Fusarielin A 180 Fusidic acid 0 Geldanamycin 1 Geodin 18 Geodin hydrate 35 Gibberellic acid 71 Gibepyron D 53 Gliocladic acid 28 Gliotoxin 35 Glyantrypine 3 Gregatin B N/A Griseofulvin 5 Griseophenone B 9 Griseophenone C 1 Harzianopyridone 2 Harzianum A 18 HC-Toxin 4 Helvolic acid 28 Helvolinic acid N/A Heptaibin 88 Heptelidic acid 11 Herquline A 1 HT-2 Glucoside 7 HT-2 Toxin 14 hydrolysed Fumonisin B1 7 hydrolysed Nidulin N/A Hydroxycarnequinazoline A 5 Hydroxycurvularin 5 Hydroxyroquefortine C N/A Hydroxysydonic acid 7 Hypothemycin 18 Ilicicolin A 1 Ilicicolin B 1 Ilicicolin C 3 Ilicicolin E 1 Infectopyron 35 Infectopyron-Derivat 71 Integracin A 0,4 Integracin B 0,4 Ionomycin 14 Irgasan 350 Isochromophilon III 88 Isochromophilon IV 3 Isochromophilon VI 5 Isochromophilon IX 5 Isofusidienol 9 Isokotanin B 7 Isorhodoptilometrin 0,3 Josamycin N/A K252a 14 K252b 71 K-76 Derivative 4 3 Kipuksain B 9 Kipuksain D 28 KO 143 71 Kojic acid 71 Koninginin D 110 Koninginin E 9 Linamarin 11 Lincomycin N/A LL-Z 1272e 0,3 Lolitrem B N/A Lolitrem N N/A Lotaustralin 1 Luteoskyrin N/A Luteusin A 9 Lysergol 4 Macrosphaelide A 1 Macrosporin 0,2 Malformin A 4 Malformin A2 4 Malformin C 1 Marcfortine A 1 Marcfortine B N/A Marcfortine C N/A Meleagrin 26 Meleagrin Derivat 11 Methoxycurvularin 9 Methoxysterigmatocystin 0,2 Methylasterric acid 1 Methylsulochrin 1 Methysergid 2 Mevastatin 11 Mevinolin 4 Mithramycin C N/A Mitomycin N/A Monactin 1 Moniliformin 7 Monocerin 2 Monomethylcurvulin 11 Mycophenolic acid 1 Mycophenolic acid IV 4 Myriocin 14 N-Benzoyl-Phenylalanin 4 Neoechinulin A 3 Neosolaniol 7 Neoxaline 2 NG 012 5 Nidulin 1 Nidurufin 1 Nigericin 1 NIgragillin N/A Nivalenol 5 Nivalenol-Glucosid 14 Nonactin 0,1 Norlichexanthone 1 Nornidulin 0,4 Norsolorinic acid 4 Nortryptoquialanine N/A Notoamide E 4 Notoamide Derivat 4 NP 19199 28 NP 12318 4 NT-2 Toxin 28 NX-1 N/A NX-2 N/A NX-3 N/A Ochratoxin A 2 Ochratoxin alpha 35 Ochratoxin B 7 Ochratoxin C 1 Ochrephilone 2 Okaramine D 3 Oligomycin A 35 Oligomycin B 21 O-Methylsterigmatocystin 0,3 Oosporin N/A Ophiobolin A 7 Ophiobolin B 30 Orsellinic acid 180 oxidized Elymoclavin 9 oxidized Luol 35 Oxalicine 26 Oxaline 0 Oxaspirodion 350 Oxytetracyclin N/A Papyracillic acid 25 Paracelsin A N/A Paracelsin B N/A Paraherquamide A 4 Paraherquamide E 2 Paspalic acid 1800 Paspalin N/A Paspalinin N/A Paspalitrem A N/A Paspalitrem B N/A Patulin 21 Paxillin 35 Penicillazaphilone B 3 Penicillic acid 18 Penicillide 4 Penicillin G 2 Penicillin V N/A Penigequinolone A 1 Penitrem A 4 Pennigritrem A 180 Pentahydroxyscirpenol 35 Pentoxyfylline 1 Pestalotin 2 Phenopyrrozin 11 Phomalactone 4 Phomalone 1 Phomopsin A 4 Phomopsin B N/A Phomopsolide B 4 Physcion 28 Piscarinin A 9 Porritoxinol 28 Prehelminthosporol N/A Prehelminthosporollacton N/A Prelaptin 1 PR Toxin N/A Pseurotin A 35 Pseurotin D N/A Puromycin 4 Purpactin A 4 Purpuride 1 Pyranonigrin 250 Pyrenophorol 11 Pyrenocin A 11 Pyripyropene A 25 Pyripyropene B N/A Pyripyropene D 4 Pyrophen 4 Quadrone 18 Questiomycin A 7 Quinadoline A 9 Quinadoline B 35 Quinolactacin A 0,04 Quinocitrinine A 0,4 Radicicol 5 Radiclonic acid 9 Rapamycin 110 Rasfonin 28 Roquefortine C 9 Roquefortine D 4 Roquefortine E 2 Roridin A 5 Roridin L-2 N/A Rubellin D 2 Rubratoxin A N/A Rubrofusarin 18 Rugulosin 2 Rugulosuvine 1 Rugulotrosin 110 Rugulovasine A 2 Sambucinol 71 Satratoxin F N/A Satratoxin G N/A Satratoxin H N/A Scalusamid A 5 Sclerotioramin 11 Sclerotiorin 9 Sch 725680 N/A Secalonic acid D 35 Secoemestrin C Derivat 88 Seco-Sterigmatocystin 1 semi Vioxanthin 7 semi