safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Chlorobenzene ≥99,5 %, for synthesis article number: KK01 date of compilation: 2016-08-18 Version: 1.0 en SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Identification of the substance Chlorobenzene Article number KK01 Registration number (REACH) This information is not available. Index No 602-033-00-1 EC number 203-628-5 CAS number 108-90-7 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: laboratory chemical 1.3 Details of the supplier of the safety data sheet Carl Roth GmbH + Co KG Schoemperlenstr. 3-5 D-76185 Karlsruhe Germany Telephone: +49 (0) 721 - 56 06 0 Telefax: +49 (0) 721 - 56 06 149 e-mail: [email protected] Website: www.carlroth.de Competent person responsible for the safety data : Department Health, Safety and Environment sheet e-mail (competent person) : [email protected] 1.4 Emergency telephone number Emergency information service Poison Centre Munich: +49/(0)89 19240 SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 (CLP) Classification acc. to GHS Section Hazard class Hazard class and cat- Hazard egory state- ment 2.6 flammable liquid (Flam. Liq. 3) H226 3.1I acute toxicity (inhal.) (Acute Tox. 4) H332 3.2 skin corrosion/irritation (Skin Irrit. 2) H315 4.1C hazardous to the aquatic environment - chronic hazard (Aquatic Chronic 2) H411 United Kingdom (en) Page 1 / 15 safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Chlorobenzene ≥99,5 %, for synthesis article number: KK01 Remarks For full text of Hazard- and EU Hazard-statements: see SECTION 16. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 (CLP) Signal word Warning Pictograms Hazard statements H226 Flammable liquid and vapour. H315 Causes skin irritation. H332 Harmful if inhaled. H411 Toxic to aquatic life with long lasting effects. Precautionary statements Precautionary statements - prevention P210 Keep away from heat. No smoking. P280 Wear protective gloves/eye protection. Precautionary statements - response P303+P361+P353 IF ON SKIN (or hair): take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/doctor if you feel unwell. P332+P313 If skin irritation occurs: Get medical advice/attention. Labelling of packages where the contents do not exceed 125 ml Signal word: Warning Symbol(s) 2.3 Other hazards There is no additional information. United Kingdom (en) Page 2 / 15 safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Chlorobenzene ≥99,5 %, for synthesis article number: KK01 SECTION 3: Composition/information on ingredients 3.1 Substances Name of substance Chlorobenzene Index No 602-033-00-1 EC number 203-628-5 CAS number 108-90-7 Molecular formula C6H5Cl g Molar mass 112,6 /mol SECTION 4: First aid measures 4.1 Description of first aid measures General notes Take off contaminated clothing. Following inhalation Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice. Following skin contact Rinse skin with water/shower. In case of skin irritation, consult a physician. Following eye contact Rinse cautiously with water for several minutes. In all cases of doubt, or when symptoms persist, seek medical advice. Following ingestion Observe aspiration hazard if vomiting occurs. 4.2 Most important symptoms and effects, both acute and delayed Irritation, Localised redness, oedema, pruritis and/or pain, Malaise, Gastrointestinal complaints, Vomiting, Narcotic effects, Headaches and dizziness may occur, proceeding to fainting or uncon- sciousness 4.3 Indication of any immediate medical attention and special treatment needed none United Kingdom (en) Page 3 / 15 safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Chlorobenzene ≥99,5 %, for synthesis article number: KK01 SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings water spray, foam, dry extinguishing powder, carbon dioxide (CO2) Unsuitable extinguishing media water jet 5.2 Special hazards arising from the substance or mixture Combustible. Vapours are heavier than air, spread along floors and form explosive mixtures with air. Vapours can form explosive mixtures with air. Hazardous combustion products In case of fire may be liberated: carbon monoxide (CO), carbon dioxide (CO2), hydrogen chloride (HCl), phosgene 5.3 Advice for firefighters Do not allow firefighting water to enter drains or water courses. Fight fire with normal precautions from a reasonable distance. Wear self-contained breathing apparatus. Special protective equipment for firefighters Protective clothing against liquid and gaseous chemicals, including liquid aerosols and solid particles. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Wearing of suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. Avoid contact with skin, eyes and clothes. Do not breathe vapour/spray. Avoidance of ignition sources. 6.2 Environmental precautions Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it. Explosive properties. 6.3 Methods and material for containment and cleaning up Advices on how to contain a spill Covering of drains. Advices on how to clean up a spill Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Other information relating to spills and releases Place in appropriate containers for disposal. Ventilate affected area. Reference to other sections Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materials: see section 10. Disposal considerations: see section 13. United Kingdom (en) Page 4 / 15 safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Chlorobenzene ≥99,5 %, for synthesis article number: KK01 SECTION 7: Handling and storage 7.1 Precautions for safe handling Provision of sufficient ventilation. • Measures to prevent fire as well as aerosol and dust generation Keep away from sources of ignition - No smoking. Take precautionary measures against static discharge. Advice on general occupational hygiene Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs. When using do not smoke. 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed. Incompatible substances or mixtures Observe hints for combined storage. Consideration of other advice Ground/bond container and receiving equipment. • Ventilation requirements Use local and general ventilation. • Specific designs for storage rooms or vessels Recommended storage temperature: 15 - 25 °C. 7.3 Specific end use(s) No information available. SECTION 8: Exposure controls/personal protection 8.1 Control parameters National limit values Occupational exposure limit values (Workplace Exposure Limits) Cou Name of agent CAS No Nota- Identifi- TWA TWA STEL STEL Source ntry tion er [pp [mg/m [pp [mg/m m] ³] m] ³] EU chlorobenzene 108-90-7 IOELV 5 23 15 70 2006/15/EC GB chlorobenzene 108-90-7 WEL 1 4,7 3 14 EH40/2005 Notation STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15- minute period unless otherwise specified TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-weighted average Relevant DNELs/DMELs/PNECs and other threshold levels United Kingdom (en) Page 5 / 15 safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Chlorobenzene ≥99,5 %, for synthesis article number: KK01 • human health values Endpoint Threshold Protection goal, Used in Exposure time level route of exposure DNEL 23 mg/m³ human, inhalatory worker (industry) chronic - systemic effects DNEL 70 mg/m³ human, inhalatory worker (industry) acute - systemic effects DNEL 5 mg/kg bw/day human, dermal worker (industry) chronic - systemic effects DNEL 15 mg/kg human, dermal worker (industry) acute - systemic effects bw/day • environmental values Endpoint Threshold level Environmental compartment Exposure time PNEC 0,032 mg/l freshwater short-term (single instance) PNEC 0,003 mg/l marine water short-term (single instance) PNEC 1,4 mg/l sewage treatment plant (STP) short-term (single instance) PNEC 0,922 mg/kg freshwater sediment short-term (single instance) PNEC 0,092 mg/kg marine sediment short-term (single instance) PNEC 0,166 mg/kg soil short-term (single instance) 8.2 Exposure controls Individual protection measures (personal protective equipment) Eye/face protection Use safety goggle with side protection. Skin protection • hand protection Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of