Right to Know Hazardous Substance Fact Sheet Common Name: AMMONIUM PERSULFATE Synonyms: Ammonium Peroxydisulfuric Acid; Diammonium Persulfate CAS Number: 7727-54-0 Chemical Name: Peroxydisulfuric Acid, Diammonium Salt RTK Substance Number: 0111 Date: June 2009 Revision: September 2016 DOT Number: UN 1444 Description and Use EMERGENCY RESPONDERS >>>> SEE LAST PAGE Ammonium Persulfate is a colorless, white or straw-colored, Hazard Summary crystalline (sand-like) powder with a mild, unpleasant odor. It Hazard Rating NJDHSS NFPA is used as a bleaching agent, food preservative, and HEALTH 2 - polymerization inhibitor. FLAMMABILITY 0 - REACTIVITY 1 - OXIDIZER POISONOUS GASES ARE PRODUCED IN FIRE CONTAINERS MAY EXPLODE IN FIRE Reasons for Citation Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious; Ammonium Persulfate is on the Right to Know Hazardous 4=severe Substance List because it is cited by ACGIH and DOT. Ammonium Persulfate can affect you when inhaled. Contact can irritate the skin and eyes. Exposure can irritate the nose and throat. Inhaling Ammonium Persulfate can irritate the lungs. Higher exposures may cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency. Ammonium Persulfate may cause a skin allergy. SEE GLOSSARY ON PAGE 5. Ammonium Persulfate is not combustible, but it is a STRONG OXIDIZER that enhances the combustion of other FIRST AID substances. Eye Contact Immediately flush with large amounts of water for at least 15 minutes, lifting upper and lower lids. Remove contact lenses, if worn, while rinsing. Workplace Exposure Limits ACGIH: The threshold limit value (TLV) is 0.1 mg/m3 (as Skin Contact Persulfate) averaged over an 8-hour workshift. Quickly remove contaminated clothing. Immediately wash contaminated skin with large amounts of water. Inhalation Remove the person from exposure. Begin rescue breathing (using universal precautions) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. Medical observation is recommended for 24 to 48 hours after overexposure, as pulmonary edema may be delayed. EMERGENCY NUMBERS Poison Control: 1-800-222-1222 CHEMTREC: 1-800-424-9300 NJDEP Hotline: 1-877-927-6337 National Response Center: 1-800-424-8802 AMMONIUM PERSULFATE Page 2 of 6 Determining Your Exposure Reproductive Hazard According to the information presently available to the New Read the product manufacturer’s Material Safety Data Jersey Department of Health and Senior Services, Sheet (MSDS) and the label to determine product Ammonium Persulfate has not been tested for its ability to ingredients and important safety and health information affect reproduction. about the product mixture. Other Effects For each individual hazardous ingredient, read the New Ammonium Persulfate can irritate the lungs. Repeated Jersey Department of Health and Senior Services exposure may cause bronchitis to develop with coughing, Hazardous Substance Fact Sheet, available on the RTK phlegm, and/or shortness of breath. Program website Ammonium Persulfate may cause a skin allergy. If allergy (http://www.state.nj.us/health/workplacehealthandsafety/ri develops, very low future exposure can cause itching and a ght-to-know/) or in your facility’s RTK Central File or skin rash. Hazard Communication Standard file. You have a right to this information under the New Jersey Worker and Community Right to Know Act, the Public Medical Employees Occupational Safety and Health (PEOSH) Act Medical Testing if you are a public worker in New Jersey, and under the If symptoms develop or overexposure is suspected, the federal Occupational Safety and Health Act (OSHA) if you following are recommended: are a private worker. Consider chest x-ray after acute overexposure The New Jersey Right to Know Act requires most Evaluation by a qualified allergist can help diagnose skin employers to label chemicals in the workplace and allergy. requires public employers to provide their employees with information concerning chemical hazards and controls. Any evaluation should include a careful history of past and present symptoms with an exam. Medical tests that look for The federal OSHA Hazard Communication Standard (29 damage already done are not a substitute for controlling CFR 1910.1200) and the PEOSH Hazard Communication exposure. Standard (N.J.A.C. 12:100-7) require employers to provide similar information and training to their employees. Request copies of your medical testing. You have a legal right to this information under the OSHA Access to Employee This Fact Sheet is a summary of available information Exposure and Medical Records Standard (29 CFR 1910.1020). regarding the health hazards that may result from exposure. Duration of exposure, concentration of the substance and other Mixed Exposures factors will affect your susceptibility to any of the potential Smoking can cause heart disease, lung cancer, effects described below. emphysema, and other respiratory problems. It may worsen respiratory conditions caused by chemical exposure. Even if you have smoked for a long time, stopping now will reduce Health Hazard Information your risk of developing health problems. Acute Health Effects The following acute (short-term) health effects may occur immediately or shortly after exposure to Ammonium Persulfate: Contact can irritate the skin and eyes. Exposure can irritate the nose and throat. Inhaling Ammonium Persulfate can irritate the lungs causing coughing and/or shortness of breath. Higher exposures may cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency, with severe shortness of breath. Chronic Health Effects The following chronic (long-term) health effects can occur at some time after exposure to Ammonium Persulfate and can last for months or years: Cancer Hazard According to the information presently available to the New Jersey Department of Health and Senior Services, Ammonium Persulfate has not been tested for its ability to cause cancer in animals. AMMONIUM PERSULFATE Page 3 of 6 Workplace Controls and Practices Eye Protection Very toxic chemicals, or those that are reproductive hazards or Wear eye protection with side shields or goggles. sensitizers, require expert advice on control measures if a less If additional protection is needed for the entire face, use in toxic chemical cannot be substituted. Control measures combination with a face shield. A face shield should not be include: (1) enclosing chemical processes for severely used without another type of eye protection. irritating and corrosive chemicals, (2) using local exhaust ventilation for chemicals that may be harmful with a single Respiratory Protection exposure, and (3) using general ventilation to control Improper use of respirators is dangerous. Respirators exposures to skin and eye irritants. For further information on should only be used if the employer has implemented a written workplace controls, consult the NIOSH document on Control program that takes into account workplace conditions, Banding at www.cdc.gov/niosh/topics/ctrlbanding/. requirements for worker training, respirator fit testing, and The following work practices are also recommended: medical exams, as described in the OSHA Respiratory Protection Standard (29 CFR 1910.134). Label process containers. Provide employees with hazard information and training. Where the potential exists for exposure over 0.1 mg/m3 (as Monitor airborne chemical concentrations. Persulfate), use a NIOSH approved negative pressure, air- Use engineering controls if concentrations exceed purifying, particulate filter respirator with an N, R or P95 recommended exposure levels. filter. More protection is provided by a full facepiece Provide eye wash fountains and emergency showers. respirator than by a half-mask respirator, and even greater Wash or shower if skin comes in contact with a hazardous protection is provided by a powered-air purifying respirator. material. Leave the area immediately if (1) while wearing a filter or Always wash at the end of the workshift. cartridge respirator you can smell, taste, or otherwise detect Change into clean clothing if clothing becomes Ammonium Persulfate, (2) while wearing particulate filters contaminated. abnormal resistance to breathing is experienced, or (3) eye Do not take contaminated clothing home. irritation occurs while wearing a full facepiece respirator. Get special training to wash contaminated clothing. Check to make sure the respirator-to-face seal is still good. Do not eat, smoke, or drink in areas where chemicals are If it is, replace the filter or cartridge. If the seal is no longer being handled, processed or stored. good, you may need a new respirator. Wash hands carefully before eating, smoking, drinking, Consider all potential sources of exposure in your workplace. applying cosmetics or using the toilet. You may need a combination of filters, prefilters or cartridges to protect against different forms of a chemical (such as In addition, the following may be useful or required: vapor and mist) or against a mixture of chemicals. 3 Where the potential exists for exposure over 1 mg/m (as Use a vacuum to reduce dust during clean-up. DO NOT Persulfate), use a NIOSH approved supplied-air respirator DRY SWEEP. with a full facepiece operated in a pressure-demand or other positive-pressure mode. For increased protection use in combination with an auxiliary self-contained breathing apparatus or an emergency escape air cylinder. Personal Protective Equipment The