SAFETY DATA SHEET Revision Date 29-Jun-2018 Revision Number 1 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identification Product Description: Cadmium arsenide Cat No. : 22773 CAS-No 12006-15-4 Molecular Formula As2 Cd3 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Alfa Aesar . Avocado Research Chemicals, Ltd. Shore Road Port of Heysham Industrial Park Heysham, Lancashire LA3 2XY United Kingdom Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608 E-mail address [email protected] www.alfa.com Product Safety Department 1.4. Emergency telephone number Call Carechem 24 at +44 (0) 1865 407333 (English only); +44 (0) 1235 239670 (Multi-language) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Based on available data, the classification criteria are not met Health hazards Acute oral toxicity Category 3 (H301) Acute Inhalation Toxicity - Dusts and Mists Category 2 (H330) Environmental hazards ______________________________________________________________________________________________ ALFAA22773 Page 1 / 10 SAFETY DATA SHEET Cadmium arsenide Revision Date 29-Jun-2018 ______________________________________________________________________________________________ Acute aquatic toxicity Category 1 (H400) Chronic aquatic toxicity Category 1 (H410) 2.2. Label elements Signal Word Danger Hazard Statements H301 - Toxic if swallowed H330 - Fatal if inhaled H350i - May cause cancer by inhalation H410 - Very toxic to aquatic life with long lasting effects Precautionary Statements P264 - Wash face, hands and any exposed skin thoroughly after handling P304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing P310 - Immediately call a POISON CENTER or doctor/ physician P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection 2.3. Other hazards No information available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Component CAS-No EC-No. Weight % CLP Classification - Regulation (EC) No 1272/2008 Cadmium arsenide (Cd3As2) 12006-15-4 EEC No. 234-484-1 <=100 Acute Tox. 3 (H301) Acute Tox. 2 (H330) Carc. 1B (H350i) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) Full text of Hazard Statements: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures ______________________________________________________________________________________________ ALFAA22773 Page 2 / 10 SAFETY DATA SHEET Cadmium arsenide Revision Date 29-Jun-2018 ______________________________________________________________________________________________ General Advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is required. Eye Contact In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required. Ingestion Do not induce vomiting. Call a physician or Poison Control Center immediately. Inhalation Move to fresh air. If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required. Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. 4.2. Most important symptoms and effects, both acute and delayed None reasonably foreseeable. 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Not combustible. Extinguishing media which must not be used for safety reasons No information available. 5.2. Special hazards arising from the substance or mixture Do not allow run-off from fire fighting to enter drains or water courses. Hazardous Combustion Products arsenic oxides, Cadmium oxide. 5.3. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Use personal protective equipment. Avoid dust formation. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas. 6.2. Environmental precautions ______________________________________________________________________________________________ ALFAA22773 Page 3 / 10 SAFETY DATA SHEET Cadmium arsenide Revision Date 29-Jun-2018 ______________________________________________________________________________________________ Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. Should not be released into the environment. 6.3. Methods and material for containment and cleaning up Sweep up or vacuum up spillage and collect in suitable container for disposal. Avoid dust formation. 6.4. Reference to other sections Refer to protective measures listed in Sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Avoid dust formation. Use only under a chemical fume hood. Do not breathe vapors/dust. Do not ingest. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. Wash hands before breaks and at the end of workday. 7.2. Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. 7.3. Specific end use(s) Use in laboratories SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Exposure limits List source(s): UK - EH40/2005 Containing the workplace exposure limits (WELs) for use with the Control of Substances Hazardous to Health Regulations (COSHH) 2002 (as amended). Updated by September 2006 official press release and October 2007 Supplement. Component The United Kingdom European Union Ireland Cadmium arsenide (Cd3As2) STEL: 0.075 mg/m3 15 min STEL: 0.3 mg/m3 15 min TWA: 0.025 mg/m3 8 hr TWA: 0.1 mg/m3 8 hr Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust MDHS10/2 Cadmium and inorganic compounds of cadmium in air Laboratory method using flame atomic absorption spectrometry ______________________________________________________________________________________________ ALFAA22773 Page 4 / 10 SAFETY DATA SHEET Cadmium arsenide Revision Date 29-Jun-2018 ______________________________________________________________________________________________ or electrothermal atomic absorption spectrometry MDHS41/2 Arsenic and inorganic compounds of arsenic (except arsine) in air Laboratory method using continuous flow or flow injection analysis hydride generation atomic absorption spectrometry Derived No Effect Level (DNEL) No information available Route of exposure Acute effects (local) Acute effects Chronic effects Chronic effects (systemic) (local) (systemic) Oral Dermal Inhalation Predicted No Effect Concentration No information available. (PNEC) 8.2. Exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source Personal protective equipment Eye Protection Safety glasses with side-shields (European standard - EN 166) Hand Protection Protective gloves Glove material Breakthrough time Glove thickness EU standard Glove comments Butyl rubber See manufacturers - EN 374 (minimum requirement) recommendations Skin and body protection Long sleeved clothing Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific