VI NBS SPECIAL PUBLICATION 392 J U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards National Bureau of Standards Bldg. Library, _ E-01 Admin. OCT 1 1981 191023 / oO Vibrationally Excited Hydrogen Halides: A Bibliography on Chemical Kinetics of Chemiexcitation and Energy Transfer Processes (1958 through 1973) QC 100 • 1X57 no. 2te c l !14 c '- — | NATIONAL BUREAU OF STANDARDS The National Bureau of Standards' was established by an act of Congress March 3, 1901. The Bureau's overall goal is to strengthen and advance the Nation's science and technology and facilitate their effective application for public benefit. To this end, the Bureau conducts research and provides: (1) a basis for the Nation's physical measurement system, (2) scientific and technological services for industry and government, (3) a technical basis for equity in trade, and (4) technical services to promote public safety. The Bureau consists of the Institute for Basic Standards, the Institute for Materials Research, the Institute for Applied Technology, the Institute for Computer Sciences and Technology, and the Office for Information Programs. THE INSTITUTE FOR BASIC STANDARDS provides the central basis within the United States of a complete and consistent system of physical measurement; coordinates that system with measurement systems of other nations; and furnishes essential services leading to accurate and uniform physical measurements throughout the Nation's scientific community, industry, and commerce. The Institute consists of a Center for Radiation Research, an Office of Meas- urement Services and the following divisions: Applied Mathematics — Electricity — Mechanics — Heat — Optical Physics — Nuclear Sciences" — Applied Radiation 2 — Quantum Electronics 1 — Electromagnetics 3 — Time 3 1 1 and Frequency — Laboratory Astrophysics — Cryogenics . 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THE INSTITUTE FOR COMPUTER SCIENCES AND TECHNOLOGY conducts research and provides technical services designed to aid Government agencies in improving cost effec- tiveness in the conduct of their programs through the selection, acquisition, and effective utilization of automatic data processing equipment; and serves as the principal focus within the executive branch for the development of Federal standards for automatic data processing equipment, techniques, and computer languages. The Institute consists of the following divisions: Computer Services — Systems and Software — Computer Systems Engineering — Informa- tion Technology. THE OFFICE FOR INFORMATION PROGRAMS promotes optimum dissemination and accessibility of scientific information generated within NBS and other agencies of the Federal Government; promotes the development of the National Standard Reference Data System and a system of information analysis centers dealing with the broader aspects of the National Measurement System; provides appropriate services to ensure that the NBS staff has optimum accessibility to the scientific information of the world. The Office consists of the following organizational units: Office of Standard Reference Data — Office of Information Activities — Office of Technical Publications — Library — Office of International Relations. 'Headquarters and Laboratories at Gaithersburg, Maryland, unless otherwise noted; mailing address Washington, D.C. 20234. 3 Part of the Center for Radiation Research. 3 Located at Boulder, Colorado 80302. « Part of the Center for Building Technology. Vibrational^ Excited Hydrogen Halides: A Bibliography on Chemical Kinetics of Chemiexcitation and Energy Transfer Processes (1958 through 1973) Natlprial Bureau of Standards MAY 6 1974 Francis Westley Chemical Kinetics Information Center Institute for Materials Research National Bureau of Standards Washington, D.C. 20234 This work was supported by the NBS Office of Standard Reference Data and the Air Force Office of Scientific Research 1400 Wilson Blvd., Arlington, Va. 22209 U.S. DEPARTMENT OF COMMERCE, Frederick B. Dent, Secretary NATIONAL BUREAU OF STANDARDS, Richard W. Roberts, Director Issued April 1974 Supt. of Docs. No. C13.10:392 1. Chemical reaction, Kate of— Bibliography. 2. Hydrogen halides— Bibliography. 3. Energy transfer— Bibliography. I. United States. National Bureau of Standards. Institute for Materials Research. Chemical Kinetics Information Center. II. Title. III. Series: United States. National Bureau of Standards. Special Publication 392. QC100.U57 No. 392 [Z5524.R5] 389\08s 74-5358 [016.54U39] National Bureau of Standards Special Publication 392 Nat. Bur. Stand. (U.S.), Spec. Publ. 392, 81 pages (Apr. 1974) CODEN: XNBSAV U.S. GOVERNMENT PRINTING OFFICE WASHINGTON: 1974 For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402 (Order by SD Catalog No. C13.10:392). Price $1.30 Foreword The National Standard Reference Data System was established in 1963 for the purpose of pro- moting the critical evaluation and dissemination of numerical data of the physical sciences. The pro- gram is coordinated by the Office of Standard Reference Data of the National Bureau of Standards but involves the efforts of many groups in universities, government laboratories, and private indus- try. The primary aim of the program is to provide compilations of critically evaluated physical and chemical property data. These tables are published in the Journal of Physical and Chemical Ref- erence Data, in the NSRDS-NBS series of the National Bureau of Standards, and through other appropriate channels. The task of critical evaluation is carried out in various data centers, each with a well-defined technical scope. A necessary preliminary step to the critical evaluation process is the retrieval from the world scientific literature of all papers falling within the scope of the center. Each center, therefore, builds up a comprehensive well-indexed bibliographical file which forms the base for the evaluation task. Bibliographies derived from these files are published when they appear to be of value to research workers and others interested in the particular technical area. Further information on NSRDS and the publications which form the primary output of the program may be obtained by writing to the Office of Standard Reference Data, National Bureau of Standards, Washington, DC 20234. David R. Lide, Jr., Chief Office of Standard Reference Data TABLE OP CONTENTS Introduction 1 Guidelines for the user 7 Journal and report codes 11 Part I. Hydrogen fluoride (HP, DF ) 15 A. Formation of HF* (DF*) 15 1. Bimolecular reactions (Abstraction lasers) 15 a. Abstraction of H (D) atom by F atom 15 i. F + H + HF + H 2 15 > ii. F + HX HF* + X . 16 iii. F + RH * HF* + R . 17 b. Abstraction of F atom by H (D) atom 17 i. H + Fp HF* + F 17 ii. H + FX > HF* + X . 18 iii. H + RF -> HF* + R 18 2. Unimolecular reactions (Elimination lasers) 18 a. R- + R * Cr R ] ^ HF + M (Chemical activation ) .18 2 i 2 -» b. M., + hv HF + M 9 (Photochemical elimination) . .19 B. HF (DF ) Energy transfer and quenching 19 1. HF (DF ) Energy transfer 19 a. HF(v. = 0) + M* -* HF*(v. > 0) + M (M ^ HF) (Energy transferred to HF from M ) 19 b. HF*(v. = m) + M -» HF^(v. < m) + M* (v > 0) 1 J J. J (Energy transferred from HF to M) 19 -* c . HF(v. ) + HF(v . ) HF(v, ) + HF(v. ) = (i + j k + I ) (HF - HF Energy transfer) ... ^0 2. HF* (DF*) Quenching .21 + r ±\ -> a. HF (v. = m ) + M HF ( v . < m ) + M (v. > 0) (Collisional quenching) .21 b. HF*(v. = m) + HF -> HF^^v. < m) + HF (v. & 0) (HF - HF self-quenching) .22 £ c. HF (v = m) + M -> prod. quenching .22 1 (Dissociative ) i. HF*(v = m) + M HF(v^ = 0) + M + M. 22 1 2 ii. HF*(v = m) + M > H + F + M 23 1 C. HF* (DF*) Theoretical papers 23 v Part II. Hydrogen chloride (HC1, DC1) 24 A. Formation of hCl* (DCl*) 24 1. Bimolecular reactions (Abstraction lasers) 24 a. Abstraction of H (D) atom by CI atom 24 i. CI + H * HC1* + H . 24 2 -> 24 ii. CI +• HX HC1* + X . iii. CI + RH -> FC1* + R 25 b. Abstraction of CI atom by H (D) atom 25 i. H + Cl -> HCl* + CI 25 2 ii. H + C1X * HCl* + X 26 iii. H + RC1 HCl* + R 26 iv. H + HC1 -> HCl* + H 27 2. Unimolecular reactions (Elimination lasers) 27 a. R + R -* [R^Rp] * HC1* + M(Chemical activation) . 27 1 2 b. + hv -* HC1 + (Photochemical elimination). .27 ± i B. HC1 (DC1 ) Energy transfer and quenching 27 1. HCl* (DCl*) Energy transfer 27 a. HC1 (v. = 0) + M* -> HCl^v. > 0) + M (M ? HC1) (Energy transferred to HC1 from M ) 27 b. HCl*(v. = m) + M -> HCl^(v. < m) + M* (v. > 0) (Energy transferred from HC1 to M) 27 c. HCl(v.) + hCl(v.) > HCl(v, ) + HCl(v ) 1 J K I 28 (i + j = k + i ) (HC1 - HC1 Energy transfer) . + 28 2. HCl* (DC1 ) Quenching a. HCl*(v. = m) + M -> HC1- (v. <m)+M (v. > 0) i J J (Collisional quenching) 28 (4:) b. HCl^Cv. = m) + HC1 + HCl (v. < m) + HC1 i i (v. a 0) (HC1 - HC1 self-quenching) 29 c.