SAFETY DATA SHEET Creation Date 20-Sep-2010 Revision Date 07-Sep-2021 Revision Number 3 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Description: Lithium perchlorate, anhydrous Cat No. : 44225 Synonyms Perchloric acid lithium salt CAS No 7791-03-9 EC No 232-237-2 Molecular Formula Cl Li O4 REACH registration number - 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Alfa Aesar . Avocado Research Chemicals, Ltd. Shore Road Port of Heysham Industrial Park Heysham, Lancashire LA3 2XY United Kingdom Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608 E-mail address [email protected] www.alfa.com Product Safety Department 1.4. Emergency telephone number Call Carechem 24 at +44 (0) 1865 407333 (English only); +44 (0) 1235 239670 (Multi-language) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Oxidizing solids (H271) Category 1 ______________________________________________________________________________________________ ALFAA44225 Page 1 / 11 SAFETY DATA SHEET Lithium perchlorate, anhydrous Revision Date 07-Sep-2021 ______________________________________________________________________________________________ Health hazards Acute oral toxicity Category 4 (H302) Skin Corrosion/Irritation Category 1 C (H314) Serious Eye Damage/Eye Irritation Category 1 (H318) Environmental hazards Based on available data, the classification criteria are not met Full text of Hazard Statements: see section 16 2.2. Label elements Signal Word Danger Hazard Statements H271 - May cause fire or explosion; strong oxidizer H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage Precautionary Statements P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P220 - Keep away from clothing and other combustible materials P280 - Wear protective gloves/protective clothing/eye protection/face protection P371 + P380 + P375 - In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician 2.3. Other hazards No information available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Component CAS No EC No Weight % CLP Classification - Regulation (EC) No 1272/2008 Perchloric acid, lithium salt 7791-03-9 EEC No. 232-237-2 >95 Ox. Sol. 1 (H271) Acute Tox. 4 (H302) Skin Corr. 1C (H314) ______________________________________________________________________________________________ ALFAA44225 Page 2 / 11 SAFETY DATA SHEET Lithium perchlorate, anhydrous Revision Date 07-Sep-2021 ______________________________________________________________________________________________ REACH registration number - Full text of Hazard Statements: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General Advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is required. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required. Keep eye wide open while rinsing. Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Call a physician immediately. Ingestion Immediate medical attention is required. Do NOT induce vomiting. Drink plenty of water. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If not breathing, give artificial respiration. Call a physician or poison control center immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. 4.2. Most important symptoms and effects, both acute and delayed Causes burns by all exposure routes. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Flooding quantities of water. CO 2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing media which must not be used for safety reasons No information available. 5.2. Special hazards arising from the substance or mixture The product causes burns of eyes, skin and mucous membranes. Oxidizer: Contact with combustible/organic material may cause fire. May ignite combustibles (wood paper, oil, clothing, etc.). Hazardous Combustion Products Lithium oxide, Hydrogen chloride. ______________________________________________________________________________________________ ALFAA44225 Page 3 / 11 SAFETY DATA SHEET Lithium perchlorate, anhydrous Revision Date 07-Sep-2021 ______________________________________________________________________________________________ 5.3. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective equipment as required. Evacuate personnel to safe areas. Avoid contact with skin, eyes or clothing. 6.2. Environmental precautions Should not be released into the environment. Do not allow material to contaminate ground water system. Do not flush into surface water or sanitary sewer system. 6.3. Methods and material for containment and cleaning up Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Sweep up and shovel into suitable containers for disposal. 6.4. Reference to other sections Refer to protective measures listed in Sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not breathe dust. Do not ingest. If swallowed then seek immediate medical assistance. Keep away from clothing and other combustible materials. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work. 7.2. Conditions for safe storage, including any incompatibilities Keep containers tightly closed in a dry, cool and well-ventilated place. Do not store near combustible materials. Corrosives area. Store under an inert atmosphere. Protect from moisture. Technical Rules for Hazardous Substances (TRGS) 510 Storage Class (LGK) Class 5.1A (Germany) 7.3. Specific end use(s) Use in laboratories SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Exposure limits List source(s): ______________________________________________________________________________________________ ALFAA44225 Page 4 / 11 SAFETY DATA SHEET Lithium perchlorate, anhydrous Revision Date 07-Sep-2021 ______________________________________________________________________________________________ Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies Derived No Effect Level (DNEL) / Derived Minimum Effect Level (DMEL) No information available Predicted No Effect Concentration (PNEC) No information available. 8.2. Exposure controls Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source Personal protective equipment Eye Protection Goggles (European standard - EN 166) Hand Protection Protective gloves Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Skin and body protection Wear appropriate protective