Liniment Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 09/03/2019 Version: 1.1 SECTION 1: Identification 1.1. Identification Product form : Mixture Product name : Liniment 1.2. Recommended use and restrictions on use Use of the substance/mixture : Topical treatment for livestock 1.3. Supplier Sanco Industries, Inc. 1819 S. Calhoun Street Fort Wayne, IN 46802 Phone: 260-426-6281 Toll Free: 888-697-2626 1.4. Emergency telephone number Emergency number : 24 Hour Contact - CHEMTREC 1-800-424-9300 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Flammable liquids Category 2 H225 Highly flammable liquid and vapor Acute toxicity (oral) Category 3 H301 Toxic if swallowed Acute toxicity (dermal) Category 3 H311 Toxic in contact with skin Acute toxicity (inhalation:dust,mist) Category 4 H332 Harmful if inhaled Skin corrosion/irritation Category 2 H315 Causes skin irritation Serious eye damage/eye irritation Category 1 H318 Causes serious eye damage Specific target organ toxicity (single exposure) Category 1 H370 Causes damage to organs Full text of H statements : see section 16 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapor H301+H311 - Toxic if swallowed or in contact with skin H315 - Causes skin irritation H318 - Causes serious eye damage H332 - Harmful if inhaled H370 - Causes damage to organs Precautionary statements (GHS-US) : P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P233 - Keep container tightly closed P240 - Ground/Bond container and receiving equipment P241 - Use explosion-proof electrical/ventilating/lighting equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P260 - Do not breathe vapors P264 - Wash hands thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - If swallowed: Immediately call a poison center/doctor. P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing 09/03/2019 EN (English US) Page 1 Liniment Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations P307+P311 - If exposed: Call a poison center/doctor P330 - Rinse mouth if ingested P332+P313 - If skin irritation occurs: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse P370+P378 - In case of fire: Use an appropriate extinguisher to extinguish P403+P235 - Store in a well-ventilated place. Keep cool P501 - Dispose of contents/container in accordance with local, state, and federal regulations 2.3. Other hazards which do not result in classification No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS-US classification Methyl alcohol (CAS No) 67-56-1 37.81 Flam. Liq. 2, H225 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 1, H370 Acetone (CAS No) 67-64-1 18.9 Flam. Liq. 2, H225 Eye Irrit. 2A, H319 STOT SE 3, H336 Ethyl alcohol (CAS No) 64-17-5 1.4 Flam. Liq. 2, H225 Skin Irrit. 2, H315 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Call a poison center or doctor/physician. First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell. First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Immediately call a poison center or doctor/physician. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Immediately call a poison center or doctor/physician. 4.2. Most important symptoms and effects (acute and delayed) Potential Adverse human health effects and : Harmful if inhaled. Toxic if swallowed. Toxic in contact with skin. symptoms Symptoms/injuries : Causes damage to organs. Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms/injuries after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. 4.3. Immediate medical attention and special treatment, if necessary No additional information available SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 09/03/2019 EN (English US) 2/9 Liniment Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 5.2. Specific hazards arising from the chemical Fire hazard : Highly flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No smoking. 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Avoid breathing dust/fume/gas/mist/vapors/spray. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No smoking. Use only non-sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing vapors. Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place. Keep in fireproof place. Keep container tightly closed. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Acetone (67-64-1) ACGIH ACGIH TWA (ppm) 500 ppm ACGIH ACGIH STEL (ppm) 750 ppm OSHA OSHA PEL (TWA) (mg/m³) 2400 mg/m³ OSHA OSHA PEL (TWA) (ppm) 1000 ppm IDLH US IDLH (ppm) 2500 ppm (10% LEL) NIOSH NIOSH REL (TWA) (mg/m³) 590 mg/m³ NIOSH NIOSH REL (TWA) (ppm) 250 ppm 09/03/2019 EN (English US) 3/9 Liniment Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Ethyl alcohol (64-17-5) ACGIH ACGIH STEL (ppm) 1000 ppm OSHA OSHA PEL (TWA) (mg/m³) 1900 mg/m³ OSHA OSHA PEL (TWA) (ppm) 1000 ppm IDLH US IDLH (ppm) 3300 ppm (10% LEL) NIOSH NIOSH REL (TWA) (mg/m³) 1900 mg/m³ NIOSH NIOSH REL (TWA) (ppm) 1000 ppm Methyl alcohol (67-56-1) ACGIH ACGIH TWA (ppm) 200 ppm ACGIH ACGIH STEL (ppm) 250 ppm OSHA OSHA PEL (TWA) (mg/m³) 260 mg/m³ OSHA OSHA PEL (TWA) (ppm) 200 ppm IDLH US IDLH (ppm) 6000 ppm NIOSH NIOSH REL (TWA) (mg/m³) 260 mg/m³ NIOSH NIOSH REL (TWA) (ppm) 200 ppm NIOSH NIOSH REL (STEL) (mg/m³) 325 mg/m³ NIOSH NIOSH REL (STEL) (ppm) 250 ppm NIOSH US-NIOSH chemical category Potential for dermal absorption 8.2.