Supramolecular Studies on the Behaviour of Different Chiral

Supramolecular Studies on the Behaviour of Different Chiral

ADVERTIMENT. Lʼaccés als continguts dʼaquesta tesi queda condicionat a lʼacceptació de les condicions dʼús establertes per la següent llicència Creative Commons: http://cat.creativecommons.org/?page_id=184 ADVERTENCIA. El acceso a los contenidos de esta tesis queda condicionado a la aceptación de las condiciones de uso establecidas por la siguiente licencia Creative Commons: http://es.creativecommons.org/blog/licencias/ WARNING. The access to the contents of this doctoral thesis it is limited to the acceptance of the use conditions set by the following Creative Commons license: https://creativecommons.org/licenses/?lang=en ,IDF5AC@97I@5FGHI8=9G CBH<9 69<5J=CIF C:8=::9F9BH7<=F5@ 7M7@C5@?5B9 65G987CADCIB8G5G F979DHCFG ;9@5HCFG5B8GIF:57H5BHG 9FB5H)= =C@985 -9G=C7HCF5@ GHI8= 89C7HCF5H9B*IVA=75 ,ID9FJ=G986M )FC: /=79BSF5B7<589@@ 5@@C )FC: +CG5&ª (FHIYC&=B;5FFC 9D5FH5A9BH89*IVA=75 57I@H5H89=TB7=9G -BJzOF>MOBPBKQ>A> MBO>PMFO>O>IDO>RAB$L@QLOMBO 9FB5H)= = C@985 4EFPQEBPFPFPMOBPBKQBACLODO>AR>QFLK>P$L@QLO?V 9FB5H)= = C@985 6FPQFMI>R 2B>A>KA>MMOLSBA 0OLC 6F@BKq"O>K@E>ABII'>IIL 0OLC 2LP>-X/OQRx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β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ª /OQRxL>KA 0OLC 6F@BKq"O>K@E>ABII )OB>IIVQE>KHQEBJCLODFSFKDJBQEB@E>K@BQLTLOHFKQEBFO DOLRM CLOQEBFO P@FBKQFCF@ >KA CFK>K@F>IPRMMLOQ >KA QEB@LKCFABK@BMI>@BAFKJB )TLRIAIFHBQLQE>KHQL5KFSBOPFQ>Q!RQz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t> !I?BOQ >KA LQEBOP !IPL QE>KHP QL QEB SFPFQFKD JBJ?BOP PR@E >P 9>OLPI>S 4ELJ>P>KA#EOFPQF>K -LOBLSBO QE>KHPQL /OFLI +tOF>K "LELOBP>KA!ICLKPCLO PE>OFKD QEBFOHKLTIBADBFK LRO FKQBOBPQFKDP@FBKQFCF@AFP@RPPFLKP )TLRIAQL>@HKLTIBADB QEBTLOHLC>IIQELPBTELOBJLSB ?>OOFBOPFKQEBT>VLC P@FBK@B>KABPMB@F>IIVQL>II QEB0E$PQRABKQPCOLJ>OLRKAQEBTLOIA )TLRIAIFHBQLQE>KHQEBQB@EKF@F>KPCOLJQEBAFCCBOBKQPBOSF@BPQE>QTBRPBAFKQEFP QEBPFP (2 .-2$O 0>R.LIFP 3BOSBFAB2BPPLKkK@F>->DKrQF@>ABI> 5!" 8 2>VAFCCO>@QFLK$O aKDBIaIS>OBW 3BOSBFAB$FCO>@@F{AB2>GLP8ABI> 5!" #OVL4%-$O 0>?IL#>PQOL 3BOSBFAB-F@OLP@LMF>ABI> 5!" 3!83$O 2>JLK0LKP $O *LOAF-LOOLP *LOAF#>BIIBP>KA)JJ>#>OOBO>P )1!# #3)# -B>PROBJBKQPTBOB@>OOFBALRQ FK!,"!3VK@EOLQOLK 3%- $O !KK>%PQEBO#>OOFIIL >KA $O *RAFQE/O{ 3BOSBFAB-F@OLP@LMF>%IB@QOzKF@> ABI)KPQFQRQAB#FrK@F>ABIP->QBOF>IPAB">O@BILK>)#-!" #3)# !&-$O 'GBOQORA->ROPQ>A .4.5 $,3!KK 3FPPBI4BF>IBOBQ5IPBQ .4.5 "FLILDF@>I>PP>VP$O .BOB>'>WQBIRJBKAF>KA$O #>OJB.LDRs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• ,MBH<9G=G ,9@97H=J=HM 5B8 ,HFI7HIF5@ ,HI8M C: '9K ,MAA9HF=7 -F=DC85@ A=89G 5G B=CB+979DHCFG BLD9F=A9BH5@5B8-<9CF9H=75@DDFC57< 3BODF#BIFP "BOK>Q0F "LIBA> 0>R.LIFP /K>)II> 6F@BKq"O>K@E>ABII>KA2LP>- /OQRxL 1.52;<:A$.4.,< • ,HI8=9G CB 7M7@C5@?5B9 65G98 6=G5A=89 CF;5BC;9@5HCFG G=B;I@5F 75G9 C: 7<=F5@ 5;;F9;5H9G:FCA AC@97I@9G "BOK>Q0F "LIBA> ->OQ>3>KP ->Ot>#>JMLP 0>R.LIFP /K>)II> *R>K#>OILKP%PQsSBW 6F@BKq"O>K@E>ABII >KA2LP>- /OQRx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γ !JFKL?RQVOF@>@FA '&0 'OBBK&IRLOBP@BKQ0OLQBFK (2-3 (FDE2BPLIRQFLK->PP3MB@QOLP@LMV (2 .-2 (FDE2BPLIRQFLK.R@IB>O->DKBQF@ 2BPLK>K@B (30P (>KPBK3LIR?FIFQV0>O>JBQBOP )2 )KCO>OBA H?M HFIL?>PB M>FO , #0, ,BCQ E>KABA #FO@RI>OIV0LI>OFPBA,FDEQ ,-7' ,LT-LIB@RI>O7BFDEQ'BI>QLO ,-7/' ,LT-LIB@RI>O7BFDEQ/OD>KLDBI>QLO 50, JFKFJRJDBI>QFLK@LK@BKQO>QFLK -2) ->DKBQF@2BPLK>K@B)J>DFKD ."/ .>QRO>I"LKA/O?FQ>I .-2 .R@IB>O->DKBQF@2BPLK>K@B .4! .FQOFILQOF>@BQF@>@FA 0#2 0LIVJBO>PB#E>FK2B>@QFLK 0$) 0LIVAFPMBOPBC>@QLO

View Full Text

Details

  • File Type
    pdf
  • Upload Time
    -
  • Content Languages
    English
  • Upload User
    Anonymous/Not logged-in
  • File Pages
    318 Page
  • File Size
    -

Download

Channel Download Status
Express Download Enable

Copyright

We respect the copyrights and intellectual property rights of all users. All uploaded documents are either original works of the uploader or authorized works of the rightful owners.

  • Not to be reproduced or distributed without explicit permission.
  • Not used for commercial purposes outside of approved use cases.
  • Not used to infringe on the rights of the original creators.
  • If you believe any content infringes your copyright, please contact us immediately.

Support

For help with questions, suggestions, or problems, please contact us