SAFETY DATA SHEET Creation Date 22-Sep-2009 Revision Date 10-Dec-2020 Revision Number 5 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Description: Allyl chloride, stabilized Cat No. : 102910000; 102910010; 102911000; 102910025 Synonyms 3-Chloropropene CAS-No 107-05-1 EC-No. 203-457-6 Molecular Formula C3 H5 Cl 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company UK entity/business name Fisher Scientific UK Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom EU entity/business name Acros Organics BVBA Janssen Pharmaceuticalaan 3a 2440 Geel, Belgium E-mail address [email protected] 1.4. Emergency telephone number For information US call: 001-800-ACROS-01 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No.US:001-800-424-9300 / Europe:001-703-527-3887 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Flammable liquids Category 2 (H225) Health hazards ______________________________________________________________________________________________ ACR10291 Page 1 / 12 SAFETY DATA SHEET Allyl chloride, stabilized Revision Date 10-Dec-2020 ______________________________________________________________________________________________ Acute oral toxicity Category 4 (H302) Acute dermal toxicity Category 4 (H312) Acute Inhalation Toxicity - Vapors Category 4 (H332) Skin Corrosion/Irritation Category 2 (H315) Serious Eye Damage/Eye Irritation Category 2 (H319) Germ Cell Mutagenicity Category 2 (H341) Carcinogenicity Category 2 (H351) Specific target organ toxicity - (single exposure) Category 3 (H335) Specific target organ toxicity - (repeated exposure) Category 2 (H373) Environmental hazards Acute aquatic toxicity Category 1 (H400) Full text of Hazard Statements: see section 16 2.2. Label elements Signal Word Danger Hazard Statements H225 - Highly flammable liquid and vapor H319 - Causes serious eye irritation H351 - Suspected of causing cancer H341 - Suspected of causing genetic defects H373 - May cause damage to organs through prolonged or repeated exposure H315 - Causes skin irritation H335 - May cause respiratory irritation H400 - Very toxic to aquatic life H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled Precautionary Statements P280 - Wear protective gloves/protective clothing/eye protection/face protection P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P332 + P313 - If skin irritation occurs: Get medical advice/attention P337 + P313 - If eye irritation persists: Get medical advice/attention P240 - Ground and bond container and receiving equipment P243 - Take action to prevent static discharges P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P260 - Do not breathe dust/fume/gas/mist/vapors/spray P273 - Avoid release to the environment P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P403 + P235 - Store in a well-ventilated place. Keep cool ______________________________________________________________________________________________ ACR10291 Page 2 / 12 SAFETY DATA SHEET Allyl chloride, stabilized Revision Date 10-Dec-2020 ______________________________________________________________________________________________ 2.3. Other hazards Lachrymator (substance which increases the flow of tears) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Component CAS-No EC-No. Weight % CLP Classification - Regulation (EC) No 1272/2008 Allyl chloride 107-05-1 EEC No. 203-457-6 >95 Acute Tox. 4 (H302) Acute Tox. 4 (H312) Acute Tox. 4 (H332) Skin Irrit. 2 (H315) Eye Irrit. 2 (H319) Muta. 2 (H341) Carc. 2 (H351) STOT SE 3 (H335) STOT RE 2 (H373) Aquatic Acute 1 (H400) Flam. Liq. 2 (H225) Propylene oxide 75-56-9 EEC No. 200-879-2 0.05-0.09 Flam. Liq. 1 (H224) Acute Tox. 4 (H302) Acute Tox. 3 (H311) Acute Tox. 3 (H331) Eye Irrit. 2 (H319) STOT SE 3 (H335) Muta. 1B (H340) Carc. 1B (H350) Component Specific concentration limits M-Factor Component notes (SCL's) Allyl chloride - 1 - Full text of Hazard Statements: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Eye Contact Immediate medical attention is required. Get medical attention. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required. Ingestion Do NOT induce vomiting. Get medical attention. Inhalation Remove to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required. If not breathing, give artificial respiration. Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. 4.2. Most important symptoms and effects, both acute and delayed Difficulty in breathing. Inhalation of high vapor concentrations may cause symptoms like ______________________________________________________________________________________________ ACR10291 Page 3 / 12 SAFETY DATA SHEET Allyl chloride, stabilized Revision Date 10-Dec-2020 ______________________________________________________________________________________________ headache, dizziness, tiredness, nausea and vomiting 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Symptoms may be delayed. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Carbon dioxide (CO 2). Dry chemical. Water mist may be used to cool closed containers. Chemical foam. Water mist may be used to cool closed containers. Extinguishing media which must not be used for safety reasons No information available. 5.2. Special hazards arising from the substance or mixture Flammable. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated. Vapors may form explosive mixtures with air. Do not allow run-off from fire-fighting to enter drains or water courses. Hazardous Combustion Products Carbon monoxide (CO), Carbon dioxide (CO2), Phosgene, Hydrogen chloride gas. 5.3. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Wear protective gloves/clothing and eye/face protection. Remove all sources of ignition. Take precautionary measures against static discharges. Avoid contact with skin, eyes or clothing. 6.2. Environmental precautions Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. 6.3. Methods and material for containment and cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Provide adequate ventilation. 6.4. Reference to other sections Refer to protective measures listed in Sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling ______________________________________________________________________________________________ ACR10291 Page 4 / 12 SAFETY DATA SHEET Allyl chloride, stabilized Revision Date 10-Dec-2020 ______________________________________________________________________________________________ Ensure adequate ventilation. Wear personal protective equipment/face protection. Do not breathe mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Handle product only in closed system or provide appropriate exhaust ventilation. Use spark-proof tools and explosion-proof equipment. Use only non-sparking tools. Remove all sources of ignition. Take precautionary measures against static discharges. Keep away from open flames, hot surfaces and sources of ignition. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work. 7.2. Conditions for safe storage, including any incompatibilities Flammables area. Keep away from heat, sparks and flame. Keep container tightly closed in a dry and