DGP-WG/06-IP/3 18/10/06 DANGEROUS GOODS PANEL (DGP) MEETING OF THE WORKING GROUP OF THE WHOLE Beijing, China, 25 October to 3 November 2006 Agenda Item 6: Discussion of miscellaneous dangerous goods issues EXCEPTED QUANTITY PROVISIONS ADOPTED BY UNITED NATIONS (Presented by the Secretary) 1. To assist members reviewing DGP-WG/06-WP/4, two listings (one in UN number and the other in alphabetical order) of the proposed excepted quantities sorted by class or division/packing group/liquid or solid are presented in the appendices. Appendix A contains the listing in UN number order and Appendix B contains the listing in alphabetical order. — — — — — — — — (79 pages) IP.3.en.doc DGP-WG/06-IP/3 NUMBERICAL LISTING Appendix A Excepted Quantities Division 2.2 Air, compressed 1002 2.2 Argon, compressed 1006 2.2 Bromotrifluoromethane 1009 2.2 Refrigerant gas R 13B1 1009 2.2 Carbon dioxide 1013 2.2 Carbon dioxide and nitrous oxide mixture 1015 2.2 Chlorodifluoromethane 1018 2.2 Refrigerant gas R 22 1018 2.2 Chloropentafluoroethane 1020 2.2 Refrigerant gas R 115 1020 2.2 1-Chloro-1,2,2,2-tetrafluoroethane 1021 2.2 Refrigerant gas R 124 1021 2.2 Chlorotrifluoromethane 1022 2.2 Refrigerant gas R 13 1022 2.2 Dichlorodifluoromethane 1028 2.2 Refrigerant gas R 12 1028 2.2 Dichlorofluoromethane 1029 2.2 Refrigerant gas R 21 1029 2.2 Helium, compressed 1046 2.2 Krypton, compressed 1056 2.2 Liquefied gases, non-flammable, charged with nitrogen, carbon dioxide or air 1058 2.2 Neon, compressed 1065 2.2 Nitrogen, compressed 1066 2.2 Refrigerant gas, n.o.s.* 1078 2.2 Sulphur hexafluoride 1080 2.2 Hexafluoropropylene 1858 2.2 Refrigerant gas R 1216 1858 2.2 Neon, refrigerated liquid 1913 2.2 Argon, refrigerated liquid 1951 2.2 Ethylene oxide and carbon dioxide mixture, with not more than 9% ethylene oxide 1952 2.2 Compressed gas, n.o.s.* 1956 2.2 1,2-Dichloro-1,1,2,2-tetrafluoroethane 1958 2.2 Refrigerant gas R 114 1958 2.2 Helium, refrigerated liquid 1963 2.2 Insecticide gas, n.o.s.* 1968 2.2 Krypton, refrigerated liquid 1970 2.2 Chlorodifluoromethane and chloropentafluoroethane mixture with fixed boiling point, with approximately 49% chlorodifluoromethane 1973 2.2 Refrigerant gas R 502 1973 2.2 Chlorodifluorobromomethane 1974 2.2 Refrigerant gas R 12B1 1974 2.2 Octafluorocyclobutane 1976 2.2 Refrigerant gas R C318 1976 2.2 Nitrogen, refrigerated liquid 1977 2.2 Rare gases mixture, compressed 1979 2.2 Rare gases and oxygen mixture, compressed 1980 2.2 Rare gases and nitrogen mixture, compressed 1981 2.2 Refrigerant gas R 14 1982 2.2 Tetrafluoromethane 1982 2.2 1-Chloro-2,2,2-trifluoroethane 1983 2.2 DGP-WG/06-IP/3 Appendix A A-2 Excepted Quantities Refrigerant gas R 133a 1983 2.2 Refrigerant gas R 23 1984 2.2 Trifluoromethane 1984 2.2 Xenon 2036 2.2 Carbon dioxide, refrigerated liquid 2187 2.2 Hexafluoroethane 2193 2.2 Refrigerant gas R 116 2193 2.2 Octafluorobut-2-ene 2422 2.2 Refrigerant gas R 1318 2422 2.2 Octafluoropropane 2424 2.2 Refrigerant gas R 218 2424 2.2 Xenon, refrigerated liquid 2591 2.2 Chlorotrifluoromethane and trifluoromethane azeotropic mixture with approximately 60% chlorotrifluoromethane 2599 2.2 Refrigerant gas R 503 2599 2.2 Dichlorodifluoromethane and difluoroethane azeotropic mixture with approximately 74% dichlorodifluoromethane 2602 2.2 Refrigerant gas R 500 2602 2.2 Ethylene oxide and dichlorodifluoromethane mixture, with not more than 12.5% ethylene oxide 3070 2.2 Trifluoromethane, refrigerated liquid 3136 2.2 Gas, refrigerated liquid, n.o.s.* 3158 2.2 Refrigerant gas R 134a 3159 2.2 1,1,1,2-Tetrafluoroethane 3159 2.2 Liquefied gas, n.o.s.* 3163 2.2 Pentafluoroethane 3220 2.2 Refrigerant gas R 125 3220 2.2 Heptafluoropropane 3296 2.2 Refrigerant gas R 227 3296 2.2 Ethylene oxide and chlorotetrafluoroethane mixture, with not more than 8.8% ethylene oxide 3297 2.2 Ethylene oxide and pentafluoroethane mixture, with not more than 7.9% ethylene oxide 3298 2.2 Ethylene oxide and tetrafluoroethane mixture, with not more than 5.6% ethylene oxide 3299 2.2 Refrigerant gas R 404A 3337 2.2 Refrigerant gas R 407A 3338 2.2 Refrigerant gas R 407B 3339 2.2 Refrigerant gas R 407C 3340 2.2 Class 3 Packing Group I n-Amylene 1108 3 I 1-Pentene 1108 3 I Adhesives containing flammable liquid 1133 3 I Coating solution, 1139 3 I Crotonylene 1144 3 I Diethyl ether 1155 3 I Ethyl ether 1155 3 I Divinyl ether, stabilized 1167 3 I Printing ink, flammable 1210 3 I Printing ink related material, 1210 3 I Isoprene, stabilized 1218 3 I Isopropylamine 1221 3 8 I Methyl formate 1243 3 I Paint 1263 3 I Paint related material 1263 3 I DGP-WG/06-IP/3 A-3 Appendix A Excepted Quantities Pentanes 1265 3 I Petroleum crude oil 1267 3 I Petroleum distillates, n.o.s. 1268 3 I Petroleum products, n.o.s. 1268 3 I Propylene oxide 1280 3 I Trimethylamine, aqueous solution, not more than 50% trimethylamin 1297 3 8 I Vinyl ethyl ether, stabilized 1302 3 I Vinylidene chloride, stabilized 1303 3 I Fuel, aviation, turbine engine 1863 3 I Resin solution, flammable 1866 3 I Propyleneimine, stabilized 1921 3 6.1 I Aldehydes, n.o.s.* 1989 3 I Flammable liquid, n.o.s.* 1993 3 I Nitrocellulose solution, flammable with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose 2059 3 I 2-Chloropropane 2356 3 I Isopentenes 2371 3 I Furan 2389 3 I 2-Chloropropene 2456 3 I 2-Methyl-1-butene 2459 3 I 3-Methyl-1-butene 2561 3 I Amines, flammable, corrosive, n.o.s.* 2733 3 8 I Polyamines, flammable, corrosive, n.o.s.* 2733 3 8 I Flammable liquid, corrosive, n.o.s. 2924 3 8 I Hydrocarbons, liquid, n.o.s. 3295 3 I Mercaptan mixture, liquid, flammable, n.o.s.* 3336 3 I Mercaptans, liquid, flammable, n.o.s.* 3336 3 I Paint, flammable, corrosive 3469 3 8 I Paint related material, flammable, corrosive 3469 3 8 I Class 3 Packing Group II Acetal 1088 3 II Acetone 1090 3 II Acetone oils 1091 3 II Pentanols 1105 3 II Amylamine 1106 3 8 II Amyl chloride 1107 3 II Amyl mercaptan 1111 3 II Amyl nitrite 1113 3 II Benzene 1114 3 II Butanols 1120 3 II Butyl acetates 1123 3 II n-Butylamine 1125 3 8 II 1-Bromobutane 1126 3 II Chlorobutanes 1127 3 II n-Butyl formate 1128 3 II Butyraldehyde 1129 3 II Adhesives containing flammable liquid 1133 3 II Coal tar distillates, flammable 1136 3 II Coating solution, 1139 3 II Cyclohexane 1145 3 II Cyclopentane 1146 3 II DGP-WG/06-IP/3 Appendix A A-4 Excepted Quantities Diacetone alcohol 1148 3 II 1,2-Dichloroethylene 1150 3 II Ethylene glycol diethyl ether 1153 3 II Diethylamine 1154 3 8 II Diethyl ketone 1156 3 II Diisopropylamine 1158 3 8 II Diisopropyl ether 1159 3 II Dimethylamine, aqueous solution 1160 3 8 II Dimethyl carbonate 1161 3 II Dimethyldichlorosilane 1162 3 8 II Dimethyl sulphide 1164 3 II Dioxane 1165 3 II Dioxolane 1166 3 II Extracts, aromatic, liquid † 1169 3 II Ethanol 1170 3 II Ethanol solution 1170 3 II Ethyl alcohol 1170 3 II Ethyl alcohol solution 1170 3 II Ethyl acetate 1173 3 II Ethylbenzene 1175 3 II Ethyl borate 1176 3 II 2-Ethylbutyraldehyde 1178 3 II Ethyl butyl ether 1179 3 II Ethylene dichloride 1184 3 6.1 II Ethyl formate 1190 3 II Ethyl methyl ketone 1193 3 II Methyl ethyl ketone 1193 3 II Ethyl propionate 1195 3 II Ethyltrichlorosilane 1196 3 8 II Extracts, flavouring, liquid † 1197 3 II Fusel oil 1201 3 II Gasoline 1203 3 II Motor spirit 1203 3 II Petrol 1203 3 II Nitroglycerin solution in alcohol with not more than 1% nitroglycerin 1204 3 II Heptanes 1206 3 II Hexanes 1208 3 II Printing ink, flammable 1210 3 II Printing ink related material, flammable 1210 3 II Isobutyl acetate 1213 3 II Isobutylamine 1214 3 8 II Isooctene 1216 3 II Isopropanol 1219 3 II Isopropyl alcohol 1219 3 II Isopropyl acetate 1220 3 II Isopropyl nitrate 1222 3 II Ketones, liquid, n.o.s.* 1224 3 II Methanol 1230 3 6.1 II Methyl acetate 1231 3 II Methylal 1234 3 II Methylamine, aqueous solution 1235 3 8 II DGP-WG/06-IP/3 A-5 Appendix A Excepted Quantities Methyl butyrate 1237 3 II Methyl isobutyl ketone 1245 3 II Methyl isopropenyl ketone, stabilized 1246 3 II Methyl methacrylate monomer, stabilized 1247 3 II Methyl propionate 1248 3 II Methyl propyl ketone 1249 3 II Octanes 1262 3 II Paint 1263 3 II Paint related material 1263 3 II Pentanes 1265 3 II Perfumery products with flammable solvents 1266 3 II Petroleum crude oil 1267 3 II Petroleum distillates, n.o.s. 1268 3 II Petroleum products, n.o.s. 1268 3 II n-Propanol 1274 3 II Propyl alcohol, normal 1274 3 II Propionaldehyde 1275 3 II n-Propyl acetate 1276 3 II Propylamine 1277 3 8 II 1,2-Dichloropropane 1279 3 II Propyl formates 1281 3 II Pyridine 1282 3 II Rosin oil 1286 3 II Rubber solution 1287 3 II Shale oil 1288 3 II Sodium methylate solution in alcohol 1289 3 8 II Tinctures, medicinal 1293 3 II Toluene 1294 3 II Triethylamine 1296 3 8 II Trimethylamine, aqueous solution, not more than 50% trimethylamin 1297 3 8 II Trimethylchlorosilane 1298 3 8 II Turpentine substitute † 1300 3 II Vinyl acetate, stabilized 1301 3 II Vinyl isobutyl ether, stabilized 1304 3 II Wood preservatives, liquid 1306 3 II Xylenes 1307 3 II Zirconium suspended in a flammable liquid † 1308 3 II Acetonitrile 1648 3 II Acetyl chloride 1717 3 8 II Allyl iodide 1723 3 8 II Propionyl chloride 1815 3 8 II Ethyl crotonate 1862 3 II Fuel, aviation, turbine engine 1863 3 II n-Propyl nitrate 1865 3 II Resin solution, flammable 1866 3 II Ethyl acrylate, stabilized 1917 3 II Methyl acrylate, stabilized 1919 3 II Pyrrolidine 1922 3 8 II Alcohols, flammable, toxic, n.o.s.* 1986 3 6.1 II Alcohols, n.o.s.* 1987 3 II Aldehydes, flammable, toxic, n.o.s.* 1988 3 6.1 II DGP-WG/06-IP/3 Appendix A A-6 Excepted Quantities Aldehydes,