SDS060 SNOOP® Leak Detector SAFETY DATA SHEET Identification LABEL IDENTIFIER: SNOOP® Leak Detector PRODUCT IDENTIFIER: P/N 600920 Liquid Leak Detector, SNOOP® COMPANY IDENTIFICATION: MSA Safety Incorporated 1000 Cranberry Woods Drive Cranberry Township, PA 16066 CUSTOMER SERVICE: 1-800-MSA-2222 (8:00 a.m. – 5:00 p.m., USA local time) EMERGENCY: 1-800-255-3924 (CHEM-TEL, INC.) Supplier Information A Material Safety Data Sheet as furnished by Swagelok Manufacturing Company is attached (22 Pages). Swagelok SDS REVISION DATE: 02/12/2015 Other Information WARNING: This is a hazardous chemical product. By following the directions and warnings provided with this product, the hazards associated with the use of this product can be greatly reduced but never entirely eliminated. MSA Safety makes no warranties, expressed or implied, with respect to this product and EXPRESSLY DISCLAIMS THE WARRANTY OF MERCHANTABILITY AND ANY WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE. Users assume all risks in handling, using or storing this product. Revision 3: 05-04-2015 Page 1 of 1 Snoop® liquid leak detector Safety Data Sheet Section 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product identifier Product Name l Snoop® liquid leak detector 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified use(s) l Liquid leak detector 1.3 Details of the supplier of the safety data sheet Manufacturer l Swagelok Manufacturing Company 29495 F.A. Lennon Dr. Solon, OH 44139 United States Telephone (General) l 440­349­5600 1.4 Emergency telephone number Manufacturer l (800)­424­9300 ­ Chemtrec Section 2: Hazards Identification EU/EEC According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to: EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD) 2.1 Classification of the substance or mixture CLP l Not classified DSD/DPD l Not classified 2.2 Label Elements CLP Hazard statements l No label element(s) required DSD/DPD Risk phrases l No label element(s) required 2.3 Other Hazards CLP l According to Regulation (EC) No. 1272/2008 (CLP) this material is not considered hazardous. DSD/DPD l This product is not considered dangerous under the European Directive 1999/45/EC. UN GHS According to: UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS) Preparation Date: 27/February/2012 Format: EU CLP/REACH Language: English (US) Revision Date: 12/February/2015 WHMIS, UN GHS, EU CLP, EU DSD/DPD, OSHA HCS Page 1 of 22 2012 Snoop® liquid leak detector 2.1 Classification of the substance or mixture UN GHS l Not classified 2.2 Label elements UN GHS Hazard statements l No label element(s) required 2.3 Other hazards UN GHS l According to the Globally Harmonized System for Classification and Labeling (GHS) this product is not considered hazardous. United States (US) According to: OSHA 29 CFR 1910.1200 HCS 2.1 Classification of the substance or mixture OSHA HCS 2012 l Not classified 2.2 Label elements OSHA HCS 2012 Hazard statements l No label element(s) required 2.3 Other hazards OSHA HCS 2012 l This product is not considered hazardous under the U.S. OSHA 29 CFR 1910.1200 Hazard Communication Standard. Canada According to: WHMIS 2.1 Classification of the substance or mixture WHMIS l Not classified 2.2 Label elements WHMIS l No label element(s) required. 2.3 Other hazards WHMIS l In Canada, the product mentioned above is not considered hazardous under the Workplace Hazardous Materials Information System (WHMIS). Section 3 ­ Composition/Information on Ingredients 3.1 Substances l Material does not meet the criteria of a substance. 3.2 Mixtures Composition Classifications According to Chemical Name Identifiers % LD50/LC50 Comments Regulation/Directive Preparation Date: 27/February/2012 Format: EU CLP/REACH Language: English (US) Revision Date: 12/February/2015 WHMIS, UN GHS, EU CLP, EU DSD/DPD, OSHA HCS Page 2 of 22 2012 Snoop® liquid leak detector CAS:7732­18­5 EU DSD/DPD: Not Hazardous EC Ingestion/Oral­Rat Water > 99% EU CLP: Not Hazardous NDA Number:231­ LD50 • >90 mL/kg OSHA HCS 2012: Not Hazardous 791­2 CAS:68649­00­3 UN GHS: Not Classified Isopropylamine alkyl (C9­17BR) < EU DSD/DPD: Not Classified NDA NDA benzenesulfonate EINECS:272­018­ 0.255% EU CLP: Not Classified 9 OSHA HCS 2012: Not Classified UN GHS: Skin Irrit. 2; Eye Irrit. 2; Acute Tox. 4 (orl) CAS:26264­05­1 EU DSD/DPD: Xi; R36/38; Xn; R22 Benzenesulfonic acid, dodecyl­, < EINECS:247­556­ NDA EU CLP: Acute Tox. 4, H302; Eye NDA compd. with 2­propanamine (1:1) 0.205% 2 Irrit. 2, H319; Skin Irrit. 2, H315 OSHA HCS 2012: Skin Irrit. 2; Eye Irrit. 2; Acute Tox. 4 (orl) CAS:68512­02­7 EU CLP: Community workplace < Benzene, (tetrapropenyl) derivs. EINECS:270­954­ NDA exposure limit NDA 0.015% 2 OSHA HCS 2012: Exposure limits CAS:75­31­0 EC EU CLP: Community workplace Number:200­ < Isopropylamine NDA exposure limit NDA 860­9 0.001% OSHA HCS 2012: Exposure limits EU Index:612­ 007­00­1 See Section 16 for full text of H­statements and R­phrases. Section 4 ­ First Aid Measures 4.1 Description of first aid measures Inhalation l First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. Get medical attention if symptoms occur. Skin l First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. IF ON SKIN: Wash with plenty of soap and water. Get medical attention if symptoms occur. Eye l First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if symptoms occur. Ingestion l First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. Get medical attention if symptoms occur. 4.2 Most important symptoms and effects, both acute and delayed l Refer to Section 11 ­ Toxicological Information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to Physician l All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Section 5 ­ Firefighting Measures 5.1 Extinguishing media Suitable Extinguishing Media l Material is non­combustible. In case of fire use media as appropriate for surrounding fire. Unsuitable Extinguishing l No data available. Preparation Date: 27/February/2012 Format: EU CLP/REACH Language: English (US) Revision Date: 12/February/2015 WHMIS, UN GHS, EU CLP, EU DSD/DPD, OSHA HCS Page 3 of 22 2012 Snoop® liquid leak detector Media 5.2 Special hazards arising from the substance or mixture Unusual Fire and Explosion l No unusual fire or explosion hazards anticipated. Hazards Hazardous Combustion l None known. Products 5.3 Advice for firefighters l Structural firefighters' protective clothing will only provide limited protection. Wear positive pressure self­contained breathing apparatus (SCBA). Keep unauthorized personnel away. Stay upwind. Section 6 ­ Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Personal Precautions l Do not touch or walk through spilled material. Stay upwind. Emergency Procedures l As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. 6.2 Environmental precautions l No special precautions required. 6.3 Methods and material for containment and cleaning up Containment/Clean­up l Stop leak if you can do it without risk. Measures SMALL SPILLS: Take up with sand or other non­combustible absorbent material and place into containers for later disposal. LARGE SPILLS: Dike far ahead of liquid spill for later disposal. 6.4 Reference to other sections l Refer to Section 8 ­ Exposure Controls/Personal Protection and Section 13 ­ Disposal Considerations. Section 7 ­ Handling and Storage 7.1 Precautions for safe handling Handling l Use good safety and industrial hygiene practices. 7.2 Conditions for safe storage, including any incompatibilities Storage l Store in a cool/low­temperature, well­ventilated, dry place. 7.3 Specific end use(s) l Refer to Section 1.2 ­ Relevant identified uses. Section 8 ­ Exposure Controls/Personal Protection 8.1 Control parameters Exposure Limits/Guidelines Result ACGIH Canada Ontario Canada Quebec China Germany DFG 10 ppm STEV; 24 STELs 10 ppm STEL 10 ppm STEL 24 mg/m3 STEL Not established mg/m3 STEV 5 ppm TWAEV; 12 TWAs 5 ppm TWA 5 ppm TWA 12 mg/m3 TWA Not established Isopropylamine mg/m3 TWAEV Preparation Date: 27/February/2012 Format: EU CLP/REACH Language: English (US) Revision Date: 12/February/2015 WHMIS, UN GHS, EU CLP, EU DSD/DPD, OSHA HCS Page 4 of 22 2012 Snoop® liquid leak detector (75­31­0) 10 ppm Peak; 24 Ceilings Not established Not established Not established Not established mg/m3 Peak 5 ppm TWA MAK; 12 MAKs Not established Not established Not established Not established mg/m3 TWA MAK Exposure Limits/Guidelines (Con't.) Result Germany TRGS Korea OSHA 10 ppm STEL (Serial STELs Not established No. 454); 24 mg/m3 Not established STEL (Serial No. 454) 5 ppm TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW Isopropylamine and BGW values are observed, ceiling (75­31­0) 5 ppm TWA (Serial No.