GC/MS BATCH NUMBER: S50106 ESSENTIAL OIL: SPRUCE HEMLOCK BOTANICAL NAME: TSUGA CANADENSIS ORIGIN: CANADA KEY CONSTITUENTS PRESENT IN THIS BATCH OF % SPRUCE HEMLOCK OIL ISOBORNYL ACETATE 37.2 α-PINENE 17.0 β-PINENE 13.2 CAMPHENE 7.0 LIMONENE 5.5 CAMPHOR 3.9 Δ3-CARENE 3.3 MYRCENE 2.9 β-PHELLANDRENE 1.2 Comments from Robert Tisserand: Fresh, green, coniferous odor quality. Constituents are in expected amounts. 510 2nd St S. Twin Falls, ID 83301 * 800-917-6577 * planttherapy.com facebook.com/PlantTherapy * planttherapy.com/blog Date : August 23, 2017 SAMPLE IDENTIFICATION Internal code : 17H18-PTH2-1-DM Customer identification : Spruce - Canada - S5010669R Type : Essential oil Source : Tsuga canadensis Customer : Plant Therapy ANALYSIS Method : PC-PA-001-15E06, "Analysis of the composition of a liquid essential oil by GC-FID" (in French). Identifications double-checked by GC-MS Analyst : Sylvain Mercier, M. Sc., chimiste Analysis date : 2017-08-23 Checked and approved by : Alexis St-Gelais, M. Sc., chimiste 2013-174 Note: This report may not be published, including online, without the written consent from Laboratoire PhytoChemia. This report is digitally signed, it is only considered valid if the digital signature is intact. Page 1 of 2 Essential oil, Tsuga canadensis Customer Identification: Report prepared for Internal Code: 17H18-PTH2-1-DM Spruce - Canada - S5010669R Plant Therapy IDENTIFIED COMPOUNDS Column: BP5 Column: WAX Identification Molecular Class R.T. R.I. % % R.I. R.T. cis -Hex-3-en-1-ol 2.49 864 0.09 0.09 1326 5.67 Aliphatic alcohol Santene 2.63 875 0.86 0.83 887 0.98 Normonoterpene Hexanol 2.72 882 0.04 0.04 1301 5.28 Aliphatic alcohol Tricyclene 3.23 916 0.67 0.65 921 1.12 Monoterpene α-Thujene 3.32 921 0.08 16.75 951 1.24* Monoterpene α-Pinene 3.46 929 16.99 [16.75] 951 1.24* Monoterpene Camphene 3.73* 945 7.12 6.97 996 1.54 Monoterpene α-Fenchene 3.73* 945 [7.12] 0.06 987 1.47 Monoterpene Thuja-2,4(10)-diene 3.81 950 0.02 0.34 1058 2.06* Monoterpene Sabinene 4.15 970 0.13 [0.34] 1058 2.06* Monoterpene β-Pinene 4.24 975 13.19 12.65 1044 1.93 Monoterpene Myrcene 4.50 990 2.89 2.99 1116 2.69* Monoterpene Δ3-Carene 4.78* 1006 3.58 3.30 1094 2.41 Monoterpene α-Phellandrene 4.78* 1006 [3.58] 0.16 1109 2.59 Monoterpene α-Terpinene 4.95 1015 0.10 [2.99] 1116 2.69* Monoterpene para-Cymene 5.16 1027 0.16 0.23 1212 3.94* Monoterpene Limonene 5.20 1029 5.46 5.17 1143 3.03 Monoterpene β-Phellandrene 5.22 1030 1.24 1.71 1147 3.09* Monoterpene 1,8-Cineole 5.25 1031 0.34 [1.71] 1147 3.09* Monoterp. ether cis -β-Ocimene 5.36 1038 0.01 0.14 1194 3.66* Monoterpene trans -β-Ocimene 5.54 1047 0.01 [0.23] 1212 3.94* Monoterpene γ-Terpinene 5.73 1058 0.14 [0.14] 1194 3.66* Monoterpene Isoterpinolene 6.13 1079 0.01 [0.23] 1212 3.94* Monoterpene Terpinolene 6.21 1084 0.51 0.48 1227 4.17 Monoterpene Fenchone 6.36 1092 0.07 0.05 1322 5.61 Monoterp. ketone para-Cymenene 6.42 1096 0.07 0.11 1370 6.36 Monoterpene γ-Campholenal 6.47 1098 0.03 Monoterp. aldehyde Linalool 6.70 1106 0.10 0.12 1499 9.35 Monoterp. alcohol Nonanal 6.75 1108 0.14 0.12 1347 6.00 Aliphatic aldehyde endo-Fenchol 7.16 1123 0.05 0.05 1517 9.97 Monoterp. alcohol α-Campholenal 7.27 1127 0.02 Monoterp. aldehyde trans -Pinocarveol 7.63 1140 0.11 0.14 1569 11.95 Monoterp. alcohol Camphor 7.79 1146 3.87 3.93 1425 7.48* Monoterp. ketone Camphene hydrate 8.04 1155 0.23 0.43 1520 10.10* Monoterp. alcohol Borneol 8.64 1177 0.93 1.07 1618 14.10* Monoterp. alcohol Terpinen-4-ol 8.81 1183 0.23 0.31 1527 10.37* Monoterp. alcohol Myrtenal 9.34 1200 0.04 [0.31] 1527 10.37* Monoterp. aldehyde α-Terpineol 9.49 1204 0.62 0.66 1621 14.26* Monoterp. alcohol Verbenone 9.88* 1212 0.12 0.02 1605 13.38 Monoterp. ketone endo-Fenchyl acetate 9.88* 1212 [0.12] 0.10 1405 7.02 Monoterp. ester Thymol methyl ether 10.63 1229 0.03 [0.31] 1527 10.37* Monoterp. ether Page 2 of 2 Essential oil, Tsuga canadensis Customer Identification: Report prepared for Internal Code: 17H18-PTH2-1-DM Spruce - Canada - S5010669R Plant Therapy Citronellol 10.93 1235 0.11 0.17 1707 18.93* Monoterp. alcohol Piperitone 11.82 1255 0.18 [1.07] 1618 14.10* Monoterp. ketone Isobornyl acetate 13.17 1285 37.16 38.75 1513 9.84 Monoterp. ester trans -Pinocarvyl acetate 13.57 1293 0.03 0.02 1537 10.73 Monoterp. ester α-Ylangene 17.26 1351 0.05 [3.93] 1425 7.48* Sesquiterpene α-Copaene 17.72 1357 0.01 [3.93] 1425 7.48* Sesquiterpene β-Elemene 18.95 1376 0.05 [0.43] 1520 10.10* Sesquiterpene Geranyl acetate 19.36 1382 0.05 0.10 1693 18.05 Monoterp. ester Longifolene 19.69 1387 0.15 0.16 1493 9.14 Sesquiterpene β-Caryophyllene 20.61 1400 0.14 [0.43] 1520 10.10* Sesquiterpene α-Humulene 23.42 1434 0.09 0.09 1583 12.47 Sesquiterpene γ-Muurolene 25.49 1459 0.05 0.07 1610 13.69 Sesquiterpene Germacrene D 25.63 1460 0.02 [1.07] 1618 14.10* Sesquiterpene β-Selinene 26.26 1468 0.04 [0.66] 1621 14.26* Sesquiterpene α-Muurolene 27.68 1485 0.11 0.11 1644 15.49 Sesquiterpene γ-Cadinene 28.72 1497 0.15 0.13 1668 16.74 Sesquiterpene δ-Cadinene 29.38 1506 0.40 0.41 1674 17.10 Sesquiterpene α-Cadinene 30.87 1527 0.03 [0.17] 1707 18.93* Sesquiterpene τ-Cadinol 37.54 1638 0.03 0.04 2069 39.33 Sesquiterp. alcohol τ-Muurolol 37.65 1641 0.03 0.03 2083 39.79 Sesquiterp. alcohol α-Cadinol 38.09 1651 0.06 0.05 2122 40.93 Sesquiterp. alcohol Total identified 99.24% 99.80% *: Two or more compounds are coeluting on this column [xx]: Duplicate percentage due to coelutions, not taken account in the identified total Note: no correction factor was applied OTHER DATA Physical aspect : Clear liquid Refractive index : 1.4680 ± 0.0003 (20 °C) CONCLUSION No adulterant, contaminant or diluent were detected using this method. Page 3 of 3 Essential oil, Tsuga canadensis Customer Identification: Report prepared for Internal Code: 17H18-PTH2-1-DM Spruce - Canada - S5010669R Plant Therapy Page 4 of 4 Essential oil, Tsuga canadensis Customer Identification: Report prepared for Internal Code: 17H18-PTH2-1-DM Spruce - Canada - S5010669R Plant Therapy Page 5 of 5 .