ANNEXURES Sr. Content No. 1 List of products with production capacity and raw materials 2 Plant layout 3 Brief manufacturing process, chemical reaction and mass balance 4 Details of water consumption and waste water generation 5 Details of effluent treatment plant 6 Details of hazardous/solid waste generation, management and disposal mode 7 Details of air pollution sources and control measures 8 Details hazardous chemical storage facility 9 Socio - Economic impacts 10 Proposed Terms of References 11 GIDC Plot Allotment Letter 12 GIDC Water Supply Letter 13 Toposheet ANNEXURE-I LIST OF PRODUCTS WITH THEIR PRODUCTION CAPACITY Sr. Name of Product CAS. No. Production LD50 /LC50 No. (MT/Month) (mg/kg ) (A) Chlorinated Products 1. 3-Chloromethylbenzoic (Toluic) 31719-77-4 - acid 2. 4-Chloromethylbenzoic (Toluic) 1642-81-5 - acid 3. Benzotrichloride 98-07-7 6000 4. o-Chlorobenzotrichloride 2136-89-2 - 5. P-Chlorobenzotrichloride 5216-25-1 250 820 6. m-Chlorobenzotrichloride 2136-81-4 500 7. 2,3-Dichlorobenzotrichloride 84613-97-8 - 8. 2,4-Dichlorobenzotrichloride 13014-18-1 3160 9. 2-Chloro-4- 88578-92-1 - Fluorobenzotrichloride 10. o-Fluorobenzotrichloride 488-98-2 - 11. p-Fluorobenzotrichloride 5216-25-1 - 12. Trichloromethoxy benzene 456-55-3 - 13. o-Chlorobenzyl chloride 611-19-8 50 14. 2,4-Dichlorobenzyl chloride 94-99-5 - 15. 3-Chloro pivaloyl chloride 4300-97-4 - (B) Acid Chlorides 16. Benzoyl chloride 98-88-4 1900 17. Chloroacetyl chloride 79-04-9 200 18. 2-Ethylhexanoyl chloride 760-67-8 1260 mg/m3 19. Octanoyl chloride 111-64-8 - 20. o-Chlorobenzoyl chloride 609-65-4 3250 21. P-Chlorobenzoyl chloride 122-01-0 - 22. m-Chlorobenzoyl chloride 618-46-2 - 23. 2,3-Dichlorobenzoyl chloride 2905-60-4 - 24. 2,4-Dichlorobenzoyl chloride 89-75-8 4640 25. 2-Chloro-4-Fluorobenzoyl 21900-54-9 - chloride 26. o-Fluorobenzoyl chloride 393-52-2 - 27. p-Fluorobenzoyl chloride 403-43-0 - 28. 2-Ethoxybenzoyl chloride 256-003-4 - 29. 3-Chloromethylbenzoyl (Toluoy) 63024-77-1 - 200 chloride 30. 4-Chloromethylbenzoyl (Toluoy) 876-08-4 - chloride 31. 2-Methylbenzoyl chloride 933-88-0 - 32. 4-Methylbenzoyl chloride 874-60-2 - 33. 4-Methoxybenzoyl chloride 100-07-2 - 34. n-Butyryl chloride 141-75-3 1470 35. Isobutyryl chloride 79-30-1 1000 36. 4-Chlorobutyryl chloride 4635-59-0 1350 37. Propionyl chloride 79-03-8 823 38. 2-Chloropropionyl chloride 7623-09-8 642 39. 3-chloropropionyl chloride 625-36-5 - 40. n-Valeryl chloride 638-29-9 2.07 mg/L 41. 5-Chlorovaleryl chloride 1575-61-7 <2000 42. Isovaleryl chloride 108-12-3 - 43. Heptanoyl chloride 2528-61-2 - 44. Hexanoyl chloride 142-61-0 - 45. Isophthaloyl chloride 99-63-8 2200 46. Cyclopropane carbonyl chloride 4023-34-1 - 47. Cyclobutane carbonyl chloride 5006-22-4 - 48. Cyclohexane carbonyl chloride 2719-27-9 - 49. 2-Furoyl chloride 527-69-5 - 50. 2-Thiophenecarbonyl chloride 5271-67-0 - 51. Trimethylacetyl chloride 3282-30-2 638 (C) Alkyl chlorides 52. n-Propyl chloride 540-54-5 >2000 53. n-Butyl chloride 109-69-3 2670 54. Isobutyl chloride 513-36-0 - 55. n-Pentyl chloride 543-59-9 - 56. n-Hexyl chloride 544-10-5 40 - 57. n-Heptyl Chloride 629-06-1 - 58. n-Octyl Chloride 111-85-3 >20,000 59. 2-Ethylhexyl (Isooctyl) Chloride 123-04-6 - 60. Propoxyethyl chloride 42149-74-6 - 61. 2-Chloroethylacetoacetate 609-15-4 2000 62. Methyl-2-chloropropionate 17639-93-9 - (D) Alkyl Bromides 63. Isopropyl bromide 75-26-3 >2000 64. Butyl bromide 109-65-9 2761 65. Pentyl bromide 110-53-2 1300 66. Hexyl bromide 111-25-1 3300 67. 1,4-Dibromobutane 110-52-1 20 - 68. Cyclopropyl bromide 4333-56-6 - 69. Cyclobutyl bromide 4399-47-7 - 70. Cyclohexyl bromide 108-85-0 4100 (E) Others 71. Chloromethyl Naphthalene 86-52-2 890 72. Chloroacetic Anhydride 541-88-8 - 73. Trimethyl acetic acid 75-98-9 40 900 74. HCl in Isopropanol (IPA.HCl) 7647-01-0/67-63-0 5840/277 75. HCl in Methanol (MeOH.HCl) 132228-87-6 4701 76. 4-Methylbenzoic acid tert-butyl 13756-42-8 - ester 77. 4-Chloromethylbenzoic acid 121579-86-0 - tert-butyl ester TOTAL 550 LIST OF RAW MATERIAL Sr Product Raw material Quantity Cas No. No. (MT/Month) 1 3-CHLOROMETHYL M-Toluic acid 200 99-04-7 BENZOIC ACID Chlorine 102.94 7782-50-5 EDC 588.24 107-06-2 2 4-CHLOROMETHYL P-Toluic acid 200 99-94-5 BENZOIC ACID Chlorine 102.94 7782-50-5 EDC 588.24 107-06-2 3 Benzotrichloride Toluene 118.56 108-88-3 Chlorine gas 270.62 7782-50-5 4 O-Chlorobenzotri chloride o-chlorotoluene 138.16 95-49-8 Chlorine gas 230.26 7782-50-5 5 p-Chlorobenzotri chloride p-chlorotoluene 138.16 106-43-4 Chlorine gas 230.26 7782-50-5 6 m-Chlorobenzotri chloride m-chlorotoluene 138.16 108-41-8 Chlorine gas 230.26 7782-50-5 7 2,3-Dichlorobenzotri m-chlorotoluene 153.04 108-41-8 chloride Chlorine gas 199.62 7782-50-5 8 2,4-Dichlorobenzotri 2,4-Dichlorotoluene 153.04 95-73-8 chloride Chlorine gas 199.62 7782-50-5 9 2-Chloro-4-Fluorobenzotri 2-Chloro-4- 146.34 452-73-3 chloride Fluorotoluene Chlorine gas 213.41 7782-50-5 10 O-Fluorobenzotri o-Fluorotoluene 129.72 95-52-3 chloride Chlorine gas 247.64 7782-50-5 11 p-Fluorobenzotri chloride p-Fluorotoluene 129.72 352-32-9 Chlorine gas 247.64 7782-50-5 12 Trichloromethoxy Anisole 130.43 100-66-3 benzene Chlorine 253.62 7782-50-5 13 O-CHLOROBENZYL o-Chlorotoluene 196.88 95-49-8 CHLORIDE Chlorine 109.38 7782-50-5 14 2,4-CHLOROBENZYL 2,4-Dichlorotoluene 206.41 95-73-8 CHLORIDE Chlorine 89.74 7782-50-5 15 3-CHLOROPIVALOYL Pivaloyl chloride 196.08 3282-30-2 CHLORIDE Chlorine 114.38 7782-50-5 16 Benzoyl Chloride Benzotrichloride 141.30 98-07-7 Benzoicic acid 88.41 65-85-0 17 Chloroacetyl Chloride benzotrichloride 348.21 98-07-7 Monochloroacetic 167.86 79-11-8 acid 18 2-Ethylhexanoyl Chloride 2-Ethylhexanoic acid 177.78 149-57-5 Thionyl Chloride 146.91 7719-09-7 NaOH 15% solution 333.33 1310-73-2 19 Octanoyl Chloride Octanoic acid 177.78 124-07-2 Thionyl Chloride 146.91 7719-09-7 NaOH 15% solution 333.33 1310-73-2 20 2-CHLOROBENZOYL 2-chlorobenzoic acid 179.31 118-91-2. CHLORIDE Thionyl Chloride 136.78 7719-09-7 15% NaOH Solution 310.34 1310-73-2 21 4-CHLOROBENZOYL 4-chlorobenzoic acid 179.31 74-11-3 CHLORIDE Thionyl Chloride 136.78 7719-09-7 15% NaOH Solution 310.34 1310-73-2 22 3-CHLOROBENZOYL 3-chlorobenzoic acid 179.31 535-80-8 CHLORIDE Thionyl Chloride 136.78 7719-09-7 15% NaOH Solution 310.34 1310-73-2 23 2,3-DICHLOROBENZOYL 2,3-dichlorobenzoic 182.78 50-45-3 CHLORIDE acid Thionyl Chloride 113.88 7719-09-7 15% NaOH Solution 258.37 1310-73-2 24 2,4-DICHLOROBENZOYL 2,4-dichlorobenzoic 182.78 50-84-0 CHLORIDE acid Thionyl Chloride 113.88 7719-09-7 15% NaOH Solution 258.37 1310-73-2 25 2-Chloro-4-Fluorobenzoyl 2-Chloro-4- 233.96 21900-54-9 chloride Fluorobenzoyl chloride 26 2-Fluorobenzoyl Chloride 2-Fluorobenzoic acid 177.22 445-29-4 Thionyl Chloride 150.63 7719-09-7 15% NaOH Solution 341.77 1310-73-2 27 4-Fluorobenzoyl 4-Fluorobenzoic acid 177.22 122-01-0 chloride Thionyl Chloride 150.63 7719-09-7 15% NaOH Solution 341.77 1310-73-2 28 2-Ethoxybenzoyl Chloride 2-Ethoxybenzoic acid 180.43 134-11-2 Thionyl Chloride 129.35 7719-09-7 15% NaOH Solution 293.48 1310-73-2 29 3-Chloromethylbenzoyl 4- 180.85 1642-81-5 (Toluoy) Chloride Chloromethylbenzoic acid Thionyl Chloride 126.60 7719-09-7 15% NaOH Solution 287.23 1310-73-2 30 4-Chloromethylbenzoyl 4- 180.85 1642-81-5 (Toluoy) Chloride Chloromethylbenzoic acid Thionyl Chloride 126.60 7719-09-7 15% NaOH Solution 287.23 1310-73-2 31 2-Methylbenzoyl chloride 2-methylbenzoic acid 176.62 118-90-1 Thionyl Chloride 154.55 7719-09-7 15% NaOH Solution 350.65 1310-73-2 32 4-Methylbenzoyl Chloride 4-methylbenzoic acid 176.62 99-94-5 Thionyl Chloride 154.55 7719-09-7 15% NaOH Solution 350.65 1310-73-2 33 4-Methoxybenzoyl 4-methoxybenzoic 178.82 99-94-5 chloride acid Thionyl Chloride 140 7719-09-7 15% NaOH Solution 317.65 1310-73-2 34 (A) n-BUTYRYL CHLORIDE benzotrichloride 367.92 98-07-7 butyric acid 166.04 107-92-6 (B) n-Butyryl chloride Butyric acid 164.49 107-92-6 Thionyl chloride 222.43 7719-09-7 NaOH 15% solution 504.67 1310-73-2 35 Isobutyryl Chloride Isobutyric acid 164.49 79-31-2 Thionyl chloride 222.43 7719-09-7 NaOH 15% solution 504.67 1310-73-2 36 4-Chlorobutyryl Chloride gamma- 122.86 96-48-0 butyrolactone thionyl chloride 170 7719-09-7 15% NaOH solution 385.71 1310-73-2 37 (A)PROPIONYL CHLORIDE Pripionic Acid 160.87 79-09-4 benzotrichloride 423.91 98-07-7 (B)PROPIONYL CHLORIDE Pripionic Acid 159.14 79-09-4 thionyl chloride 255.91 7719-09-7 15% NaOH solution 580.65 1310-73-2 38 2-CHLOROPROPIONYL 2-chloropropionic 171.65 29617-66-1 CHLORIDE acid benzotrichloride 307.09 98-07-7 39 3-CHLOROPROPIONYL HCL g 66.67 7647-01-0 CHLORIDE Acrylic acid 133.33 79-10-7 3-chloropropionic 171.43 107-94-8 acid Thionyl Chloride 188.89 7719-09-7 15% NaOH solution 428.57 1310-73-2 40 VALERYL CHLORIDE Valeric acid 168.60 109-52-4 Thionyl Chloride 196.69 7719-09-7 15% NaOH solution 446.28 1310-73-2 41 5-Chlorovaleryl Chloride Delta-valerolactone 129.87 542-28-9 thionyl chloride 154.55 7719-09-7 15% NaOH solution 350.65 1310-73-2 42 Isovaleryl chloride Isovaleric acid 168.60 503-74-2 Thionyl Chloride 196.69 7719-09-7 15% NaOH solution 446.28 1310-73-2 43 Heptanoyl chloride Heptanoic acid 174.50 111-14-8 Thionyl Chloride 159.73 7719-09-7 15% NaOH solution 362.42 1310-73-2 44 Hexanoyl chloride Hexanoic acid 171.85 142-62-1 Thionyl Chloride 176.30 7719-09-7 15% NaOH solution 400 1310-73-2 45 Isophthaloyl Chloride Isophthalic acid 162.75 121-91-5 Thionyl Chloride 233.33 7719-09-7 15% NaOH solution 529.41 1310-73-2 46 Cyclopropane carbonyl Cyclopropane 163.81 1759-53-1 chloride carboxylic Thionyl Chloride 226.67 7719-09-7 15% NaOH solution