Effect of Glass Transition: Density and Thermal Conductivity Measurements of B2O3
High Temperatures-High Pressures, Vol. 49, pp. 125–142 ©2020 Old City Publishing, Inc. Reprints available directly from the publisher Published by license under the OCP Science imprint, Photocopying permitted by license only a member of the Old City Publishing Group DOI: 10.32908/hthp.v49.801 Effect of glass transition: density and thermal conductivity measurements of B2O3 DMITRY CHEBYKIN1*, HANS-PETER HELLER1, IVAN SAENKO2, GERT BARTZSCH1, RIE ENDO3 AND OLENA VOLKOVA1 1Institute of Iron and Steel Technology, TU Bergakademie Freiberg, Leipziger Straße 34, 09599 Freiberg, Germany 2Institute of Materials Science, TU Bergakademie Freiberg, Gustav-Zeuner-Straße 5, 09599 Freiberg, Germany 3Department of Materials Science and Engineering, Tokyo Institute of Technology, 152–8552 Tokyo, Japan Received: May 28, 2019; Accepted: October 11, 2019. The role of B2O3 as a fluxing agent for developing fluoride free fluxes has been accentuated in the recent years. Therefore, knowledge about thermo- physical properties of the oxide are essential to find the optimal chemical composition of the mold fluxes. In the present study, the density and ther- mal conductivity of B2O3 were measured by means of the buoyancy method, the maximal bubble pressure (MBP) method and the hot-wire method in the temperature range of 295–1573 K. The results are discussed in the context of the chemical stability of the B2O3 as well as the effect of glass transition on the thermal conductivity. The density of the B2O3 decreases non-linearly with increasing temperature in the temperature range of 973–1573 K. The MBP method was successfully applied for the density measurements with a viscosity up to 91 Pa.s.
[Show full text]