Controlling the Surfaces of Atomically Thin Materials to Create New Electronic Phases Michael S
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Controlling the surfaces of atomically thin materials to create new electronic phases Michael S. Fuhrer School of Physics, New Horizons Centre Monash University Center for Nanophysics and Advanced Materials Michael S. Fuhrer University of Maryland Monash University Michael S. Fuhrer Monash University Michael S. Fuhrer Monash University Michael S. Fuhrer Monash University Michael S. Fuhrer Monash University Michael S. Fuhrer Monash University Michael S. Fuhrer Monash University Monash University • One of “Group of Eight” in Australia • Largest University in Australia: • 60,000 students total on 7 campuses (incl. South Africa and Malaysia) • 30,000 students at Clayton campus • Ranked 91st in the world (Times Higher Education); 69th in the world (QS); and top 150 (ARWU) Michael S. Fuhrer Monash University New Horizons Centre 23,000 m2 building, opened July 2013 Foster new interdisciplinary collaborative efforts: Brings together Monash researchers in Advanced Materials Physics, Chemistry, Engineering (Materials, Mechanical, Medical etc.) with Advanced Manufacturing CSIRO researchers Physics laboratories built to NIST-A vibration standards. Michael S. Fuhrer Monash University Research Facilities in Monash precinct Monash Centre for Electron Microscopy Melbourne Centre for Nanofabrication Electron Microscopy including double-aberration- Cleanroom for device fabrication, including 100 corrected TEM , SEM, FIB, atom probe keV electron beam lithography Australian Synchrotron Currently 8 beamlines Michael S. Fuhrer Monash University Monash Centre for Atomically Thin Materials Director: Michael Fuhrer (School of Physics, Faculty of Science) Co-Director: Dan Li (Dept. of Materials Engineering, Faculty of Engineering) Goal: Establish Monash as the hub for 2D material research in Australia Strategy: Seed-fund new collaborative research at Monash Form strong links with international partners Coordinate major bids for external funding Michael S. Fuhrer Monash University Monash Centre for Atomically Thin Materials: Personnel Prof Udo Bach (Materials Engineering) – Dye-sensitized photovoltaic cells. Dr. Qiaoliang Bao (Materials Engineering) – Optoelectronics with atomically thin materials. Dr. Toby Bell (Chemistry) – Spectroscopy of atomically thin materials. AProf Wenlong Cheng (Chemical Engineering) – Plasmonic nanoparticle assemblies. Prof Yi-Bing Cheng (Materials Engineering) – Dye-sensitized photovoltaic cells. Dr. Wenhui Duan (Structures Engineering) – Composites with atomically thin materials as fillers for smart materials and structures. AProf John Forsythe (Materials Engineering) – Graphene-based biomaterials. Prof Michael S. Fuhrer (Director, Physics) – Electronic properties of atomically thin materials. Dr. Alison Funston (Chemistry) – Plasmonic nanoparticle assemblies. Prof Victor Galitski (Physics) – Condensed matter theory, topological phases. Prof Dan Li (Associate Director, Materials Engineering) – Soft materials science of graphene and graphene oxide; hierarchical assembly of graphene-based materials. Dr. Zhe Liu (Mechanical Engineering) – Modelling of moelcualr interactions with atomically thin materials. Dr. Mainak Majumder (Mechanical Engineering) – Membranes constructed from atomically thin materials. Dr. Nikhil Medhekar (Materials Engineering) – First-principles theory of atomically thin materials. Dr. Meera Parish (Physics) – Theory of electronic conduction in disordered two-dimensional materials. Dr. Agustin Schiffrin (Physics) – Electronic and optical properties of 2D molecular assemblies on surfaces. Prof George Simon (Materials Engineering) – Polymer/graphene interactions. Prof Raman Singh (Mechanical Engineering) – Graphene as a corrosion-resistant coating. Michael S. Fuhrer Monash University Part I Atomically thin materials: New opportunities Michael S. Fuhrer Monash University Why is condensed matter interesting? 1 cm3 block of material: ~1024 electrons Impossibly complex many-body problem! Yet can understand in terms of single-(quasi)particle problem, plus: Interactions → collective phenomena that can be understood magnetism, superconductivity, charge density waves… Disorder → weak and strong localization, Kondo effect, … 1 cm Interactions Disorder see e.g. “More Is Different,” P. W. Anderson, Science 177, 393 (1972) Michael S. Fuhrer Monash University Even when it’s simple, it’s different… The periodic potential in a solid can give rise to an effective single-particle Hamiltonian which is qualitatively different than Schrodinger equation for a free electron. free electron graphene 3D strong topological insulator E py E px p2 H py 2me px HvF ()σp Michael S. Fuhrer Monash University Graphene Tight-binding model: (Wallace, 1947) 3k a k a k a E(k) E 1 4cos x cos y 4cos2 y F 0 (nearest neighbor overlap = γ0) 2 2 2 k∙p approximation: Hamiltonian: E 0 p ip F (r) F (r) v x y A A F p ip 0 x y FB (r) FB (r) H v (σ p) σ || k F K’ k σ K|| -k x Massless Dirac equation in 2D ky K Zero bandgap at K,K’ K’ points (two irreducible points) Gapless semiconductor Tunable metal Optical transitions at all energies High Fermi velocity – high conductivity Mechanically strong (E > 1 TPa) High thermal conductivity (κ > 5,000 W/m-K) Michael S. Fuhrer Monash University Topological Phases (full) energy band ψ k can be characterized by a topological number: 1 υ d 2k u k u k integer k k 2πi band Chern topological invariant (Thouless et al., 1982) Integer Quantum Hall Effect xy ρ , von Klitzing, 1980 xx ρ B e2 integer xy h Michael S. Fuhrer Monash University Quantum Hall effect: a 2D Topological Insulator xy ρ , xx ρ B Fermi energy lies in gap – bulk insulator Identify Chern number with number of conducting 1D edge modes e2 integer 1D edge modes are chiral, carryxy currenth in one direction Dissipationless conductance e2/h per edge mode Michael S. Fuhrer Monash University Room-Temperature Quantum Hall Effect Quantum Hall effect: Novoselov et al., Science 315, 1379 (2007) • Quantum-coherent orbits of electrons in high magnetic fields – requires ωcτ >> 1 (high field, low disorder) • Zero longitudinal resistance – current is carried without dissipation over macroscopic distances! Can be realized at room temperature (but large magnetic field = 29 Tesla) in graphene zero resistance Michael S. Fuhrer Monash University 2D Topological Insulators – QHE vs. QSHE k k -kF kF -kF kF The Quantum Hall effect (QHE) state The Quantum spin Hall effect spatially separates the two (QSHE) state spatially separates the chiral states of a spinless 1D liquid four chiral states of a spinful 1D liquid x x Benervig and Zhang, Kane and Mele (2005) Time reversal symmetry is broken (B ≠ 0) Time reversal symmetric (B = 0 possible!) Michael S. Fuhrer Monash University 2D TI – quantum spin Hall effect - experiment x x “perfect” (dissipationless) 1D conducting channel Konig et al., Science 318, 766 (2007) Michael S. Fuhrer Monash University Generalize TI to 3D 2D - QSHE 3D – Strong Topological Insulator top edge 2D surface state k with Dirac dispersion -kF kF spin-momentum coupling x Γ x bottom edge k -kF kF Michael S. Fuhrer Monash University 3D Topological Insulators 3D “Strong Topological Insulator” Bi2(Se,Te)3 Due to inverted band structure, spin-orbit coupling, metallic 2D surface state on every surface Easily exfoliated to atomically-flat thin crystals 2D surface state has Dirac dispersion, spin-momentum locking amenable to van der Waals Γ epitaxy of thin films Michael S. Fuhrer Monash University Transition-metal Dichalcogenides (Mo,W)(S,Se)2 are 2D semiconductors; single-layer has direct gap 1.5-1.9 eV graphene E C C k K K’ MoS2 E “symmetry-broken graphene” • Bandgap at K points • Spin-orbit coupling • Spin-valley coupling Mo S2 k • Optical excitation of spin/valley possible • Strong excitonic effects K K’ Michael S. Fuhrer Monash University Atomically Thin Materials graphite Transition-metal dichalcogenides: “topological insulators” 2D semiconductors materials which have a and metals metallic 2D surface and insulating bulk MoS graphene 2 Bi2Se3 Michael S. Fuhrer Monash University Atomically Thin Materials - Opportunities (1) New Materials silicene, germanene QSHE systems with Eg >> room temperature: • 1T’ phase of (Mo,W)(S,Se,Te)2 Qian et al., Science Express 20 November 2014 • Bilayer bismuth S. Murakami, PRL 97, 236805 (2006) • Few-layer Bi2Se3 PRB 80, 205401 (2009); PRB 81, 041307 (2010); PRB 81, 115407 (2010) • Silicene, germanene APL 102, 162412 (2013) Michael S. Fuhrer Monash University Atomically Thin Materials - Opportunities (2) Every atom is a surface atom Control of surface → control of properties Adsorbates on surface can change properties: - Doping - Time-reversal symmetry breaking → local moments, magnetism, quantum anomalous Hall effect - Spin-orbit coupling → spin currents, quantum spin Hall effect - Inversion symmetry breaking → +/- bangap, gapless edge modes, valley currents, valleytronics Michael S. Fuhrer Monash University Atomically Thin Materials - Opportunities (3) Strong Coulomb interaction Coulomb interaction is poorly screened in 2D material - Enormous exciton binding energies, exciton-free charge (trion) binding → Exciton trapping, polariton condensates - Enormous electron-impurity binding energies → Atom- and molecule-like impurities, new types of defect engineering, strongly confined quantum dots and wires - Strongly-interacting electrons → Excitonic superfluidity in heterostructures → Superconductivity via repulsive interactions in nested bands Michael S. Fuhrer Monash