Infrared Astronomy Break: Sara and Rebeka
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Electronic Spectroscopy of Free Base Porphyrins and Metalloporphyrins
Absorption and Fluorescence Spectroscopy of Tetraphenylporphyrin§ and Metallo-Tetraphenylporphyrin Introduction The word porphyrin is derived from the Greek porphura meaning purple, and all porphyrins are intensely coloured1. Porphyrins comprise an important class of molecules that serve nature in a variety of ways. The Metalloporphyrin ring is found in a variety of important biological system where it is the active component of the system or in some ways intimately connected with the activity of the system. Many of these porphyrins synthesized are the basic structure of biological porphyrins which are the active sites of numerous proteins, whose functions range from oxygen transfer and storage (hemoglobin and myoglobin) to electron transfer (cytochrome c, cytochrome oxidase) to energy conversion (chlorophyll). They also have been proven to be efficient sensitizers and catalyst in a number of chemical and photochemical processes especially photodynamic therapy (PDT). The diversity of their functions is due in part to the variety of metals that bind in the “pocket” of the porphyrin ring system (Fig. 1). Figure 1. Metallated Tetraphenylporphyrin Upon metalation the porphyrin ring system deprotonates, forming a dianionic ligand (Fig. 2). The metal ions behave as Lewis acids, accepting lone pairs of electrons ________________________________ § We all need to thank Jay Stephens for synthesizing the H2TPP 2 from the dianionic porphyrin ligand. Unlike most transition metal complexes, their color is due to absorption(s) within the porphyrin ligand involving the excitation of electrons from π to π* porphyrin ring orbitals. Figure 2. Synthesis of Zn(TPP) The electronic absorption spectrum of a typical porphyrin consists of a strong transition to the second excited state (S0 S2) at about 400 nm (the Soret or B band) and a weak transition to the first excited state (S0 S1) at about 550 nm (the Q band). -
A Candidate Analog for Carbonaceous Interstellar Dust: Formation by Reactive Plasma Polymerization E
The Astrophysical Journal, 623:242–251, 2005 April 10 # 2005. The American Astronomical Society. All rights reserved. Printed in U.S.A. A CANDIDATE ANALOG FOR CARBONACEOUS INTERSTELLAR DUST: FORMATION BY REACTIVE PLASMA POLYMERIZATION E. Kovacˇevic´,1 I. Stefanovic´,1,2 J. Berndt,1 Y. J. Pendleton,3 and J. Winter1 Received 2004 June 1; accepted 2004 December 19 ABSTRACT Carbonaceous compounds are a significant component of interstellar dust, and the composition and structure of such materials is therefore of key importance. We present 1.5–15 m spectra of a plasma-polymerized carbona- ceous material produced in radio-frequency discharge under low pressure, using C2H2 as a precursor component. The infrared spectra of the resulting spheroidal carbonaceous nanoparticles reveal a strong aliphatic band (3.4 m feature), weak OH and carbonyl bands, and traces of aromatic compounds, all characteristics identified with dust in the diffuse interstellar medium of our Galaxy. The plasma polymerization process described here provides a convenient way to make carbonaceous interstellar dust analogs under controlled conditions and to compare their characteristics with astronomical observations. Here we focus on a comparison with the IR spectra of interstellar dust. The IR spectrum of carbonaceous dust in the diffuse interstellar medium is characterized by a strong 3.4 m CÀH stretching band and weak 6.8 and 7.2 mCÀH bending bands, with little evidence for the presence of oxygen in the form of carbonyl (C = O) or hydroxide (OH) groups. The plasma polymerization products produced under oxygen-poor conditions compare well with the peak position and profiles of the observed IR spectrum of diffuse dust. -
Spectrum and the Technological Transformation of the Satellite Industry Prepared by Strand Consulting on Behalf of the Satellite Industry Association1
Spectrum & the Technological Transformation of the Satellite Industry Spectrum and the Technological Transformation of the Satellite Industry Prepared by Strand Consulting on behalf of the Satellite Industry Association1 1 AT&T, a member of SIA, does not necessarily endorse all conclusions of this study. Page 1 of 75 Spectrum & the Technological Transformation of the Satellite Industry 1. Table of Contents 1. Table of Contents ................................................................................................ 1 2. Executive Summary ............................................................................................. 4 2.1. What the satellite industry does for the U.S. today ............................................... 4 2.2. What the satellite industry offers going forward ................................................... 4 2.3. Innovation in the satellite industry ........................................................................ 5 3. Introduction ......................................................................................................... 7 3.1. Overview .................................................................................................................. 7 3.2. Spectrum Basics ...................................................................................................... 8 3.3. Satellite Industry Segments .................................................................................... 9 3.3.1. Satellite Communications .............................................................................. -
N600 Wireless Dual Band Gigabit Router Wndr3700v3 Setup Manual
N600 Wireless Dual Band Gigabit Router WNDR3700v3 Setup Manual NETGEAR, Inc. 350 E. Plumeria Drive San Jose, CA 95134 USA May 2011 208-10774-02 v1.0 ©2011 by NETGEAR, Inc. All rights reserved. Trademarks NETGEAR, the NETGEAR logo, and Connect with Innovation are trademarks and/or registered trademarks of NETGEAR. Inc. ad/or its subsidiaries in the United States and/or other countries. Information is subject to change without notice. Other brand and product names are registered trademarks or trademarks of their respective holders. Statement of Conditions In the interest of improving internal design, operational function, and/or reliability, NETGEAR reserves the right to make changes to the products described in this document without notice. NETGEAR does not assume any liability that may occur due to the use or application of the product(s) or circuit layout(s) described herein. 2 Contents N600 Wireless Dual Band Gigabit Router WNDR3700v3 Setup Manual Getting to Know Your Wireless Router................................................................................1 Unpacking Your New Wireless Router ..............................................................................1 Hardware Features ............................................................................................................2 Front Panel ..................................................................................................................3 Back Panel ..................................................................................................................5 -
A Multi-Wavelength Interferometric Study of the Massive Young Stellar Object IRAS 13481-6124
A&A 586, A78 (2016) Astronomy DOI: 10.1051/0004-6361/201527502 & c ESO 2016 Astrophysics A multi-wavelength interferometric study of the massive young stellar object IRAS 13481-6124 Paul A. Boley1,2, Stefan Kraus3, Willem-Jan de Wit4, Hendrik Linz5, Roy van Boekel5, Thomas Henning5, Sylvestre Lacour6,7, John D. Monnier8, Bringfried Stecklum9, and Peter G. Tuthill7 1 Ural Federal University, Kourovka Astronomical Observatory, 51 Lenin Ave., 620075 Ekaterinburg, Russia e-mail: [email protected] 2 Max Planck Institute for Radio Astronomy, Auf dem Hügel 69, 53121 Bonn, Germany 3 University of Exeter, Astrophysics Group, Stocker Road, Exeter, EX4 4QL, UK 4 European Southern Observatory, Casilla 19001, Santiago 19, Chile 5 Max Planck Institute for Astronomy, Königstuhl 17, 69117 Heidelberg, Germany 6 LESIA/Observatoire de Paris, CNRS, UPMC, Université Paris Diderot, 5 place Jules Janssen, 92195 Meudon, France 7 Sydney Institute of Astronomy, School of Physics, University of Sydney, NSW 2006, Australia 8 Department of Astronomy, University of Michigan, 830 Dennison Building, 500 Church St., Ann Arbor, MI 48109, USA 9 Thüringer Landessternwarte Tautenburg, Sternwarte 5, 07778 Tautenburg, Germany Received 5 October 2015 / Accepted 30 October 2015 ABSTRACT We present new mid-infrared interferometric observations of the massive young stellar object IRAS 13481-6124, using VLTI/MIDI for spectrally-resolved, long-baseline measurements (projected baselines up to ∼120 m) and GSO/T-ReCS for aperture-masking interferometry in five narrow-band filters (projected baselines of ∼1.8−6.4 m) in the wavelength range of 7.5−13 μm. We combine these measurements with previously-published interferometric observations in the K and N bands in order to assemble the largest collection of infrared interferometric observations for a massive YSO to date. -
STANAG 4545, Edition 1 (For Promulgation Use Only) NATO STANDARDIZATION AGREEMENT (STANAG)
Downloaded from http://www.everyspec.com NATO UNCLASSIFIED (Releasable for Internet Posting) STANAG No. 4545 (Edition 1) Amendment 1 NORTH ATLANTIC TREATY ORGANISATION (NATO) MILITARY AGENCY FOR STANDARDIZATION (MAS) STANDARDIZATION AGREEMENT (STANAG) SUBJECT: NATO Secondary Imagery Format (NSIF) Promulgated on 27 November 1998 Original Signed A. GRØNHEIM Major General, NOAF Chairman, MAS NATO UNCLASSIFIED Amendment 1 (Releasable for Internet Posting) Downloaded from http://www.everyspec.com NATO UNCLASSIFIED (Releasable for Internet Posting) RECORD OF AMENDMENTS Reference/date of No. Date Entered Signature amendment 1 (administravie 14 April 2000 14 April 2000 /signed/ change) (custodian) EXPLANATORY NOTES AGREEMENT 1. This NATO Standardization Agreement (STANAG) is promulgated by the Chairman MAS under the authority vested in him by the NATO Military Committee. 2. No departure may be made from the agreement without consultation with the Custodian. Nations may propose changes at any time to the Custodian where they will be processed in the same manner as the original agreement. 3. Ratifying nations have agreed that national orders, manuals and instructions implementing this STANAG will include a reference to the STANAG number for purposes of identification. DEFINITIONS 4. Ratification is “In NATO Standardization, the fulfilment by which a member nation formally accepts, with or without reservation, the content of a Standardization Agreement” (AAP-6). 5. Implementation is “In NATO Standardization, the fulfilment by a member nation of its obligations as specified in a Standardization Agreement” (AAP-6). 6. Reservation is “In NATO Standardization, the stated qualification by a member nation that describes the part of a Standardization Agreement that it will not implement or will implement only with limitations” (AAP-6). -
Guidelines for the Review of Spectrum Pricing Methodologies and the Preparation of Spectrum Fee Schedules
INFRASTRUCTURE International Telecommunication Union Telecommunication Development Bureau Place des Nations Guidelines for the Review CH-1211 Geneva 20 OF SPECTRUM PRICING METHO- Switzerland www.itu.int DOLOGIES AND THE PREPARATION OF SPECTRUM FEES SCHEDULES Report Printed in Switzerland Geneva, 2016 FEES SCHEDULES OF SPECTRUM THE PREPARATION AND PRICING METHODOLOGIES THE REVIEW OF SPECTRUM GUIDELINES FOR Telecommunication Development Sector Guidelines for the review of spectrum pricing methodologies and the preparation of spectrum fee schedules These guidelines focus on the review of spectrum pricing methodologies and the preparation of spectrum fee schedules. In addition, a brief overview of market-based and administrative methodologies is provided. These guidelines also address the need for spectrum revenue and pricing policies and an understanding of the future demand for spectrum. This report was prepared by ITU expert Adrian Foster, under the supervision of the ITU Telecommunication Development Bureau (BDT) Spectrum Management and Broadcasting Division and with the co-operation of the ITU Radiocommunication Bureau (BR). ISBN: 978-92-61-19651-6 (paper version) 978-92-61-19661-5 (electronic version) Please consider the environment before printing this report. © ITU 2016 All rights reserved. No part of this publication may be reproduced, by any means whatsoever, without the prior written permission of ITU. Table of Contents 1 Introduction 1 2 Spectrum price principles and objectives 2 3 Determining spectrum prices: Administrative and -
Assessment of Spatial and Temporal Properties of Ka/Q Band Earth-Space Radio Channel Across Europe Using Alphasat Aldo Paraboni
Received: 28 February 2018 Revised: 19 April 2019 Accepted: 27 April 2019 DOI: 10.1002/sat.1313 SPECIAL ISSUE PAPER Assessment of spatial and temporal properties of Ka/Q band earth‐space radio channel across Europe using Alphasat Aldo Paraboni payload Spiros Ventouras1 | Antonio Martellucci11 | Richard Reeves1 | Emal Rumi1 | Fernando P. Fontan2 | Fernando Machado2 | Vicente Pastoriza2 | Armando Rocha3 | Susana Mota3 | Flavio Jorge3 | Athanasios D. Panagopoulos4 | Apostolos Z. Papafragkakis4 | Charilaos I. Kourogiorgas4 | Ondrej Fiser5 | Viktor Pek5 | Petr Pesice5 | Martin Grabner6 | Andrej Vilhar7 | Arsim Kelmendi7 | Andrej Hrovat7 | Danielle Vanhoenacker‐Janvier8 | Laurent Quibus8 | George Goussetis9 | Alexios Costouri9 | James Nessel10 1 STFC Rutherford Appleton Laboratory, RAL Space, Oxford, UK Summary 2 Escola de Enxeñaría de Telecomunicación, The upcoming migration of satellite services to higher bands, namely, the Ka‐ and University of Vigo, Vigo, Spain Q/V‐bands, offers many advantages in terms of bandwidth and system capacity. 3 Dep. Elect. Telec. e Informática, Instituto de However, it poses challenges as propagation effects introduced by the various atmo- Telecomunicações, Aveiro, Portugal 4 School of Electrical and Computer spheric phenomena are particularly pronounced in these bands and can become a Engineering, National Technical University of serious constraint in terms of system reliability and performance. This paper presents Athens, Athens, Greece the goals, organisation, and preliminary results of an ongoing large‐scale European 5 Meteorological Department, Institute of Atmospheric Physics ASCR, Prague, Czech coordinated propagation campaign using the Alphasat Aldo Paraboni Ka/Q band sig- Republic nal payload on satellite, performed by a wide scientific consortium in the framework 6 TESTCOM, Czech Metrology Institute, Prague, Czech Republic of a European Space Agency (ESA) project. -
MATISSE User Manual
European Organisation for Astronomical Research in the Southern Hemisphere Programme: PIP Project/WP: MATISSE MATISSE User Manual Document Number: ESO-289268 Document Version: 5 Document Type: Manual (MAN) Released On: 2020-08-07 Document Classification: Public Prepared by: Paladini, Claudia Validated by: Mieske, Steffen Approved by: Kaufer, Andreas Name European Southern Observatory Karl-Schwarzschild-Straße 2 www.eso.org Headquarters Garching 85748 Garching bei München Doc. Number: ESO-289268 Doc. Version: 5 MATISSE User Manual Released on: 2020-08-07 Page: 2 of 2 Authors Name Affiliation Claudia Paladini DOO Thomas Rivinius DOO Document Classification: Public MATISSE User Manual VLT-MAN-ESO-289268 ii This page was intentionally left blank MATISSE User Manual VLT-MAN-ESO-289268 iii Change Record Issue/Rev. Date Section/Parag. affected Reason/Initiation/Documents/Remarks 103 2018-08-15 All First published version 105 2020-01-15 Updated Sect. 2.5.2, 3.1, and 4. Release for P105-Phase2 106 2020-03-26 Updated Sect.4, added Sect. 2.5.3 Release of P106 and GRA4MAT SV 106 2020-04-20 Updated Sect. 2, 3 and 4 Updates for P106 MATISSE User Manual VLT-MAN-ESO-289268 iv This page was intentionally left blank MATISSE User Manual VLT-MAN-ESO-289268 v Contents 1 Introduction1 1.1 Scope........................................1 1.2 Definitions, Acronyms and Abbreviations.....................1 2 Instrument description3 2.1 Scientific drivers of the instrument development.................3 2.2 Optical principle, detector and signal.......................3 -
Design of Terahertz Reconfigurable Devices by Locally Controlling Topological Phases of Square Gyro-Electric Rod Arrays
Downloaded from orbit.dtu.dk on: Mar 30, 2019 Design of terahertz reconfigurable devices by locally controlling topological phases of square gyro-electric rod arrays Zhang, L.; Xiao, Sanshui Published in: Optical Materials Express Link to article, DOI: 10.1364/OME.9.000544 Publication date: 2019 Document Version Publisher's PDF, also known as Version of record Link back to DTU Orbit Citation (APA): Zhang, L., & Xiao, S. (2019). Design of terahertz reconfigurable devices by locally controlling topological phases of square gyro-electric rod arrays. Optical Materials Express, 9(2), 544-554. DOI: 10.1364/OME.9.000544 General rights Copyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights. Users may download and print one copy of any publication from the public portal for the purpose of private study or research. You may not further distribute the material or use it for any profit-making activity or commercial gain You may freely distribute the URL identifying the publication in the public portal If you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim. Vol. 9, No. 2 | 1 Feb 2019 | OPTICAL MATERIALS EXPRESS 544 Design of terahertz reconfigurable devices by locally controlling topological phases of square gyro-electric -
Count Basie and His Bands
NEW YORKJAZZ MUSEUM , . (:OU~T 13A,I~ and 171,13A~u, _.......-- · ' - . -~•,.,. - (:OU~T 13Ail~ and I-iii 13A~l)i Edited by Dan Morgenstern and Jack Bradley Biographies by Bill Esposito Dan Morgenstern Arnold J. Smith © Copyright 1975 by New York Jazz Museum Cover photo/Phil Stern Cover design/ Fran Greenberg WILLIAM "COUNT" BASIE A PROFILE OF HIS LI FE & MUSIC 1904 Born , August 21, at Red Bank, N.J. 1917 Starts as a drummer, switches to piano. 1919-20 Plays in local bands and stage shows in N. Y. and N.J. Takes lessons from Fats Waller. 1925-27 Tours theaters accompanying variety acts: Kate Crippen and Her Kids, Sonny Thompson Band, Gonzelle White. Vaudevillians ; first hears Kansas City style music in Tulsa, Walter Page Blue Devils; Gonzelle White Show folds in Kansas City; Accompanies Whitman Sisters in Kansas City . 1928 Join s Blue Devils in Dallas, Texas in July. 1929 Plays briefly with Elmer Payne and his Ten Royal Americans (summer). 1930 Basie and members of the Blue Devils join Benny Mote.n's band. 1934 Leaves Moten early in year to lead own band (under Mote.n's auspices) in Little Rock, Arkansas, then rejoins Moten. 1935 Death of Moten breaks up the famous Kansas City unit, after working a short time under Mote.n's brother Buster's leadership; returning to Kansas City, · works as a single, then with own trio before jointly leading "Barons of Rhythm" with altoist, Buster Smith. 1936 Broadcasts over Station WIXBY and is heard by John Hammond, famed jazz buff and sponsor, who initiates the band's first national tour; plays at Grand Terrace in Chicago - not a rousing success - then the Vendome Hotel in Buffalo, N.Y. -
Full Waveguide Q-Band Low Noise Amplifier AFB-Q20LN-0X
www.ducommun.com Full Waveguide Q-Band Low Noise Amplifier AFB-Q20LN-0X The AFB series low noise amplifiers are constructed with MMICWT-A-7 PHEMT devices and provide state-of-the-art broadbandWT -A-8 performances. 0.096 DIA x THRU WR-28 W/UG599/U FLANGE 4PLS OR WR-42 W/UG595/U FLANGE 1 PLS Application • Telecommunication D M S D/ M S / /C / N N: / / N: C: N: : : X X X X X X X X X X X XX X / X XX • Test instrumentation X / X X X X X X X X X X • Transceiver subassemblies Specifications SIZE L W LM 0.096 DIA x THRU WR-28 W/UG599/U FLANGE SMALL 1.73 1.20 1.63 OUTPUT CONNECTOR CAN BE VARIED ON CUSTOMER'S REQUEST • Frequency: 33.0 -4 PL45.0S GHz OR WR-42 W/UG595/U FLANGE LARGE 2.53 1.30 2.43 K BAND ONLY APPLY TO SMALL SIZE SIZE L WLM • Gain:SMAL L 201.73 dB nominal1.20 1.63 LARGE 2.53 1.30 2.43 Dimensions are in inches Dimensions are in inches • Gain flatness: +/- 2.0 dB WT-A-9 WT-A-10 • Noise figure: 3.5 dB (typ) / 5.0 dB (max) WR-28 W/UG599/U FLANGE • I/O VSWR: 2.0:1 (typ) 2 PLS Features • DC bias: 8-12 V / 100 mA nominal • Broadband performance across entire Q-band • I/O connectors: 2.4mm(F) or WR-22 with UG383/U flange • Ultra-low noise with gain choice • Operating temperature: -40˚C to +50˚C M/N: XXXXX S/N: XXXXX • Single DC power supply/internal regulated D/C: XX/XX sequential biasing • Compact size and light weight WR-15 W/UG385/U FLANGE 4-40 x 0.20 DP OR WR-10 W/UG387/U MOD FLANGE 2 PLS 2 PLS • Variable I/O interface options 0.096 DIA x THRU 8 PLS Outline Drawings Dimensions are in inches Dimensions are in inches WT-A-1 WT-A-2 WT-A-11 WT-A-12 0.089 DIA X THRU 4 PLS M/N: XXXXX 4-40 x 0.20 DP S/N: XXXXX WR-10 W/UG 387/U-MOD FLANGE M/N: XXXXX D/C: XX/XX S/N: XXXXX 4 PLS OR WR-15 W/UG 385/U FLANGE D/C: XX/XX 4-40 x 0.20 DP 2 PLS 4 PLS M/N: XXXXX S/N: XXXXX D/C: XX/XX BAND L HW V,E, & W 1.50 1.00 0.75 M/N: XXXXX Q & U 1.80 1.13 1.13 S/N: XXXXX D/C: XX/XX Dimensions are in inches Dimensions areDimensions in inches are in inches Dimensions are in inches AllWT specifications-A-3 are subject to change without notice.