Propellane ⇑ Robynne Kirkpatrick A, Tony Masiello B, Matthew Martin A, Joseph W
Journal of Molecular Spectroscopy 281 (2012) 51–62 Contents lists available at SciVerse ScienceDirect Journal of Molecular Spectroscopy journal homepage: www.elsevier.com/locate/jms High-resolution infrared studies of the m10, m11, m14, and m18 levels of [1.1.1]propellane ⇑ Robynne Kirkpatrick a, Tony Masiello b, Matthew Martin a, Joseph W. Nibler a, , Arthur Maki c, Alfons Weber d, Thomas A. Blake e a Department of Chemistry, Oregon State University, Corvallis, OR 97332-4003, USA b Department of Chemistry and Biochemistry, California State University, East Bay, Hayward, CA 94542, USA c 15012 24th Ave., Mill Creek, WA 98012, USA d Sensor Science Division, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA e Pacific Northwest National Laboratory, P.O. Box 999, Mail Stop K8-88, Richland, WA 99352, USA article info abstract Article history: This paper is a continuation of earlier work in which the high resolution infrared spectrum of [1.1.1]pro- Received 27 July 2012 pellane was measured and its k and l structure resolved for the first time. Here we present results from an In revised form 3 September 2012 0 0 0 0 analysis of more than 16000 transitions involving three fundamental bands m10 ðE À A1Þ; m11ðE À A1Þ, m14 Available online 15 September 2012 00 0 0 00 0 00 ðA2 À A1Þ and two difference bands (m10–m18)(E ÀE ) and (m11 À m18)(E À E ). Additional information 0 00 about m18 was also obtained from the difference band (m15 + m18) À m18 (E À E ) and the binary combina- Keywords: 0 0 tion band (m15 + m18) ðE À A Þ.
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