Corex® Efficient and Environmentally Friendly Smelting Reduction
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COREX® EFFICIENT AND ENVIRONMENTALLY FRIENDLY SMELTING REDUCTION primetals.com ECONOMICALLY AND ECOLOGICALLY HOT ADVANTAGES OF COREX METAL PRODUCTION • Product quality – hot metal quality suitable for all steel applications • Economic benefit – low investment and operational costs due to the elimination of coking and sinter plants • Ecologic benefit – lowest process-related emission rates YOUR CHALLENGE OUR SOLUTION • Resource preserving – use of The conventional blast furnace route Corex is besides FINEX® the only a wide variety of iron ores and is too costly and energy-intensive reliable alternative to the conventional especially non-coking coals to keep pace with dynamic market blast furnace route. It frees from changes, where even short- and the need to invest in the erection, • Beneficial by-products – medium-term fluctuations show their operation and maintenance of generation of a highly valuable dramatic impact on iron production. coking and sinter plants because export gas for various purposes The need to use coke and sinter makes these additional facilities are not (electric power generation, it much more difficult to fulfill ever needed at all. Because it combines DRI production, or natural gas stricter environmental regulations and two decisive advantages, adaptable substitution) achieve economical competitiveness energy management/production and based on long-term sustainable outstanding ecological compatibility, growth. Rising energy demand, Corex provides you with the key continuous price increases for natural technology for producing hot metal gas and raw materials, and steadily in an economically and ecologically decreasing quality of iron ore due sustainable manner. The ability to use to the global resource depletion are a wider spectrum of raw materials with formidable challenges today. Radical Corex will make you less dependent on changes are inevitable and are forcing price trends for raw materials. As an operators to revamp their production industrially and commercially proven routes and explore promising solutions solution, it already provides a number to continue developing their iron of plant operators worldwide with all making business successfully and the advantages to fulfill prospective responsibly. requirements for the iron and steel industry. And how well prepared are you? COKING PLANT SINTER PLANT COREX BLAST FURNACE The Corex process combines coking plant, sinter plant and blast furnace into a single iron making unit. 2 3 COREX THE ALTERNATIVE TO THE CONVENTIONAL BLAST FURNACE ROUTE Conventional BF route Corex route NOVEMBER 1989 NOVEMBER 1995 JANUARY 1999 NOVEMBER 2007 Commissioning of the Commissioning Introduction of the Corex C-3000 The BAOSTEEL group started Fine ore Coking coal Non-coking coal Lump ore/pellets C-1000 plant at ISCOR of the first Corex module on the market. up the first Corex C-3000 Pretoria Works (South C-2000 plant at JUNE 1999 plant at its Luojing Works in Africa). POSCO‘s Pohang Commissioning of the MIDREXTM Shanghai (China). Works (Korea). DR plant based on Corex gas for Export ArcelorMittal South Africa - Saldanha MARCH 2014 Commissioning of a Corex gas Works. gas based MIDREXTM DR AUGUST 1999 plant at JSW (India) Sinter plant Coking plant Commissioning of Corex C-2000 plant No. 1 at JSW (India). Reduction zone Top gas Melting, gasification zone MARCH 2011 The BAOSTEEL group started up the DECEMBER 1998 second Corex C-3000 plant at its Commissioning of the APRIL 2000 Luojing Works in Shanghai (China). Corex C-2000 plant Commissioning of 2011 at ArcelorMittal South the Corex C-2000 Commissioning of the two Corex Hot Hot Hot Oxygen Africa - Saldanha plant No. 2 at JSW C-2000 plants at ESSAR STEEL Ltd. in metal metal blast Works. (India). Hazira (India) and slag and slag The reduction process of Corex Milestones of Corex MAIN DIFFERENCES FROM THE BLAST FURNACE ROUTE HIGH FRACTION OF LUMP ORE The main differences between Corex and a conventional The typical iron oxide mix for Corex is 30% lump ore and blast furnace route are: 70% pellets. Operational results proved stable operations • Non-coking coal can be used directly as a reducing agent with a lump ore fraction up to 80%. In addition, no sinter and energy source – and therefore no sinter plant – is necessary for optimal operation. • Up to 80% of the iron oxide fraction can be lump ore; no sintering is required USE OF PURE OXYGEN • Pure oxygen instead of nitrogen-rich hot blast While blast furnace operators aim to enrich the hot blast with oxygen, Corex already uses high-purity oxygen, DIRECT USE OF NON-COKING COAL resulting in nearly nitrogen-free top gas. Due to its high As the coal is chared inside the melter gasifier, even calorific value, this gas can be recycled for reduction work non-coking coal can be used, making a coking plant or used for heat or energy generation. Depending on the unnecessary. The high dome temperature exceeds steelworks demand, additional value can be created with 1,000°C, resulting in entire cracking of the coal‘s relieved the produced gas. hydrocarbons and avoiding the formation of tar. Corex ArcelorMittal South Africa, Saldanha Works – profitable and environmental friendly iron making 4 5 A LOOK INSIDE EFFICIENCY AT WORK Lump ore/pellets/ additives Export gas Coal, coal briquettes Ø 5.5m Ø 7.3m Ø 7.8m Ø 9.4m Ø 9.6m Ø 11.5m C-1000 C-2000 C-3000 C-0.5M C-0.8M C-1.0M C-1.3M C-1.5MC-1.5M C-2.0M 40 - 60 t/h 80 - 100 t/h 100 - 125 t/h 125 - 160 t/h 160 - 180 t/h 210 - 240 t/h Hot metal Oxygen and slag 600,000 - 800,000 - 1,000,000 - 1,300,000 - 1,700,000 - PCI 800,000 t/a 1,000,000 t/a 1,300,000 t/a 1,500,000 t/a 2,000,000 t/a The Corex process Available Corex modules PROCESS DESCRIPTION ECOLOGICAL AND PROFITABLE RECYCLING SAVES RESOURCES EXTENDED RAW MATERIAL SPECTRUM With Corex, all metallurgical work is carried out in two The reduction gas exiting the melter gasifier mainly Due to an increased gas utilization which is based on In terms of raw materials, the main advantage of Corex separate process reactors – the reduction shaft and the consists of CO and H2 laden with fine coal, ash, and iron gas recycling, gas production in the melter gasifier can technology compared to the blast furnace route is the melter gasifier. Iron ore (lump ore, pellets, or a mixture dust. This dust is largely removed from the gas stream be significantly lowered, which is directly reflected in direct use of non-coking coal as the fuel/reducing agent thereof) is charged into the reduction shaft, where it is in a hot gas cyclone and is then recycled to the process. lower fuel and oxygen consumption. Slag production is and lump ore as the iron oxide feed. While the use of reduced to direct reduced iron (DRI) by the reduction gas Oxygen is injected into the melter gasifier when the coal subsequently reduced by more than 20%. fine coal via pulverized coal injection is available for both in counterflow. Discharge screws convey the DRI into the is combusted, resulting in the generation of a highly technologies, coal briquetting is applicable to the Corex melter gasifier, where final reduction and melting take efficient reduction gas. The top gas is subsequently cooled TYPICAL CONSUMPTION FIGURES only. By coal briquetting it is possible to mix low-quality, place in addition to all other metallurgical reactions. Hot and cleaned in a scrubber, after which it is available as low-cost coal fines with coals of higher grades. This results Standard Recycle metal and slag are tapped as in conventional blast furnace a highly valuable export gas with a net calorific value of in lower coal cost and a substantially wider spectrum of option practice. approximately 8000 kJ/m³ (STP) suitable for a wide range coals to be utilized in Corex. This important economic of applications (e.g., power generation, DRI production, advantage will counter limited raw material availability and Fueldry 940 770 [kg/tHM] DIRECT AND EFFICIENT natural gas substitution, and heating within the steel prospective price increases in the future. Additives 265 185 [kg/t ] From the coal route perspective, coal is directly charged works). HM into the melter gasifier. It is gasified by injecting oxygen CUSTOMIZED PLANT OPERATION Oxygen 520 455 [m³/tHM] into the melter gasifier, resulting in the generation of a INCREASED GAS UTILIZATION The implemented recycling circuit allows the operator highly efficient reduction gas. This gas exits the melter A recycling system consisting of a compressor station and to adjust the system according to on-site requirements gasifier and is cleaned, cooled, and then blown into CO2 removal makes it possible to utilize more export gas TYPICAL CONSUMPTION FIGURES – to minimize coal consumption or to maximize export the reduction shaft, reducing the iron ore to DRI in for metallurgical work. This raises gas utilization to a higher gas generation – in order to respond to the steelworks Standard Recycle countercurrent flow as described above. level and makes the overall process even more economic demand. The reduced volume of export gas lowers the option and environmentally friendly. investment required for Corex export gas application, e.g., Due to the high temperatures prevailing in the dome of a downstream power plant. Slag 340 265 [kg/tHM] the melter gasifier (in excess of 1,000 °C), the higher Export gas 1,650 1,410 [m3/t ] hydrocarbons released from the coal during devolatilization HM 8,000 7,500 [kJ/m3] are immediately dissociated to carbon monoxide and hydrogen. Undesirable by-products such as tars and phenols are destroyed and therefore cannot be released to the atmosphere. 6 7 A LOOK INSIDE EFFICIENCY AT WORK Alternative Electrical energy for export: 1 x Corex plant 1 x Corex gas based 134 MW TM Conventional power plant el C-1.0M MIDREX DR plant 1,070,000 MWh/a Corex export gas 451 MW th Combined cycle power plant 178 MWel (CCPP) 1,424,000 MWh/a Heater Electrical energy 10 MWel Coal Corex export gas DR export gas 3 973 MW CO2 33,000 m (STP)/h th removal Oxygen 66,000 m3(STP)/h Oxygen plant 28 MWel Corex Hot metal DRI 1,000,000 t/a 860,000 t/a Hot metal 125 t/h 108 t/h 1,000,000 t/a 125 t/h Production of electricity (Basis: e.g.