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AMMONIUM BIFLUORIDE 98% CRY GSO SDSUS 672691 Version*: 01 Issue Date: 05-21-2015 1 II Product #: 872691 From: BRENNTAG PACIFIC INC

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AMMONIUM BIFLUORIDE 98% CRY GSO SDSUS 672691 Version*: 01 Issue Date: 05-21-2015 1 II Product #: 872691 From: BRENNTAG PACIFIC INC Product#: 872691 From: BRENNTAG PACIFIC INC. To: HILL BROTHERS CHEMICAL CO Monday June 08, 2015 BRENNTAG SAFETY DATA SHEET 1. Identification Product identifier AMMONIUM BIFLUOR1DE 98% CRY GSO Other means of identification None. Recommended use ALL PROPER AND LEGAL PURPOSES Recommended restrictions None known. Manufacturer/lmporter/Supplier/Distributor information Manufacturer Company name Brenntag Pacific Inc. Address 10747 Patterson Place Santa Fe Springs, CA 90670 Telephone 562-903-9626 E-mail Not available. Emergency phone number 800-424-9300 CHEMTREC 2. Hazard(s) identification Physical hazards Not classified. Health hazards Acute toxicity, oral Category 3 Acute toxicity, inhalation Category 4 Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Environmental hazards Not classified. OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement Toxic if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if inhaled. Precautionary statement Prevention Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear eye protection/face protection. Wear protective gloves/protective clothing/eye protection/face protection. Response If swallowed: Immediately call a poison center/doctor. If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Wash contaminated clothing before reuse. Storage Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information 2% of the mixture consists of component(s) of unknown acute oral toxicity. 2% of the mixture consists of component(s) of unknown acute inhalation toxicity. 3. Composition/information on ingredients Mixtures Material name: AMMONIUM BIFLUORIDE 98% CRY GSO SDSUS 672691 Version*: 01 Issue date: 05-21-2015 1 II Product #: 872691 From: BRENNTAG PACIFIC INC. To: HILL BROTHERS CHEMICAL CO Monday, June 08, 2015 Chemical name Common name and synonyms CAS number AMMONIUM FLUORIDE 1341 -49-7 98 ((NH4)(HF2)) Other components below reportable levels ^Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4, First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing, Oxygen or artificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or poison control center immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse, Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Most important Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may symptoms/effects, acute and include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including delayed blindness could result. Indication of immediate Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water medical attention and special immediately, While flushing, remove clothes which do not adhere to affected area, Call an treatment needed ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed, General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance, 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire, media Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire fighting Move containers from fire area if you can do so without risk. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away, Keep people away from and upwind of spill/leak, Wear protective equipment and appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do emergency procedures not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained, For personal protection, see section 8 of the SDS. Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is containment and cleaning up possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece), Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Do not taste or swallow. When using, do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices, Material name: AMMONIUM BIFLUORIDE 98% CRY GSO SDS us 872691 Version #: 01 Issue date: 05-21-2015 2/7 Product#: 872691 From: BREMNTAG PACIFIC INC. To: HILL BROTHERS CHEMICAL CO Monday June 08, 2015 Conditions for safe storage, Store locked up, Store in original tightly closed container. Store in a well-ventilated place. Store including any incompatibilities away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Skin protection Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Other Wear appropriate chemical resistant clothing. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazards Wear appropriate thermal protective clothing, when necessary, General hygiene Keep away from food and drink. Always observe good personal hygiene measures, such as considerations washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color Not available. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point 258.08 "F (125.6 °C) estimated Initial boiling point and boiling 464 °F (240 °C) estimated range Flash point Not available. Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Not available. Flammability limit - upper Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 0.00001 hPa estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient
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