New Mineral Names*
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An Application of Near-Infrared and Mid-Infrared Spectroscopy to the Study of 3 Selected Tellurite Minerals: Xocomecatlite, Tlapallite and Rodalquilarite 4 5 Ray L
QUT Digital Repository: http://eprints.qut.edu.au/ Frost, Ray L. and Keeffe, Eloise C. and Reddy, B. Jagannadha (2009) An application of near-infrared and mid- infrared spectroscopy to the study of selected tellurite minerals: xocomecatlite, tlapallite and rodalquilarite. Transition Metal Chemistry, 34(1). pp. 23-32. © Copyright 2009 Springer 1 2 An application of near-infrared and mid-infrared spectroscopy to the study of 3 selected tellurite minerals: xocomecatlite, tlapallite and rodalquilarite 4 5 Ray L. Frost, • B. Jagannadha Reddy, Eloise C. Keeffe 6 7 Inorganic Materials Research Program, School of Physical and Chemical Sciences, 8 Queensland University of Technology, GPO Box 2434, Brisbane Queensland 4001, 9 Australia. 10 11 Abstract 12 Near-infrared and mid-infrared spectra of three tellurite minerals have been 13 investigated. The structure and spectral properties of two copper bearing 14 xocomecatlite and tlapallite are compared with an iron bearing rodalquilarite mineral. 15 Two prominent bands observed at 9855 and 9015 cm-1 are 16 2 2 2 2 2+ 17 assigned to B1g → B2g and B1g → A1g transitions of Cu ion in xocomecatlite. 18 19 The cause of spectral distortion is the result of many cations of Ca, Pb, Cu and Zn the 20 in tlapallite mineral structure. Rodalquilarite is characterised by ferric ion absorption 21 in the range 12300-8800 cm-1. 22 Three water vibrational overtones are observed in xocomecatlite at 7140, 7075 23 and 6935 cm-1 where as in tlapallite bands are shifted to low wavenumbers at 7135, 24 7080 and 6830 cm-1. The complexity of rodalquilarite spectrum increases with more 25 number of overlapping bands in the near-infrared. -
Podiform Chromite Deposits—Database and Grade and Tonnage Models
Podiform Chromite Deposits—Database and Grade and Tonnage Models Scientific Investigations Report 2012–5157 U.S. Department of the Interior U.S. Geological Survey COVER View of the abandoned Chrome Concentrating Company mill, opened in 1917, near the No. 5 chromite mine in Del Puerto Canyon, Stanislaus County, California (USGS photograph by Dan Mosier, 1972). Insets show (upper right) specimen of massive chromite ore from the Pillikin mine, El Dorado County, California, and (lower left) specimen showing disseminated layers of chromite in dunite from the No. 5 mine, Stanislaus County, California (USGS photographs by Dan Mosier, 2012). Podiform Chromite Deposits—Database and Grade and Tonnage Models By Dan L. Mosier, Donald A. Singer, Barry C. Moring, and John P. Galloway Scientific Investigations Report 2012-5157 U.S. Department of the Interior U.S. Geological Survey U.S. Department of the Interior KEN SALAZAR, Secretary U.S. Geological Survey Marcia K. McNutt, Director U.S. Geological Survey, Reston, Virginia: 2012 This report and any updates to it are available online at: http://pubs.usgs.gov/sir/2012/5157/ For more information on the USGS—the Federal source for science about the Earth, its natural and living resources, natural hazards, and the environment—visit http://www.usgs.gov or call 1–888–ASK–USGS For an overview of USGS information products, including maps, imagery, and publications, visit http://www.usgs.gov/pubprod To order this and other USGS information products, visit http://store.usgs.gov Suggested citation: Mosier, D.L., Singer, D.A., Moring, B.C., and Galloway, J.P., 2012, Podiform chromite deposits—database and grade and tonnage models: U.S. -
Empressite, Agte, from the Empress-Josephine Mine, Colorado, U.S.A.: Composition, Physical Properties, and Determination of the Crystal Structure
American Mineralogist, Volume 89, pages 1043–1047, 2004 Empressite, AgTe, from the Empress-Josephine mine, Colorado, U.S.A.: Composition, physical properties, and determination of the crystal structure LUCA BINDI,1,* PAUL G. SPRY,2 AND CURZIO CIPRIANI1 1 Museo di Storia Naturale, Sezione di Mineralogia, Università degli Studi di Firenze, Via La Pira, 4 I-50121 Firenze, Italy 2 Department of Geological and Atmospheric Sciences, 253 Science I, Iowa State University, Ames, Iowa 50011-3210, U.S.A. ABSTRACT The chemistry and composition of empressite, AgTe, a rare silver telluride mineral, has been mistaken in the mineralogical literature for the silver telluride stützite (Ag5–xTe3). Empressite from the type locality, the Empress-Josephine deposit (Colorado), occurs as euhedral prismatic grains up to 400 μm in length and contains no inclusions or intergrowths with other minerals. It is pale bronze in color and shows a grey-black to black streak. No cleavage is observed in empressite but it shows an uneven to subconchoidal 2 fracture and Vickers hardness (VHN25) of 142 kg/mm . Empressite is greyish white in color, with strong bireflectance and pleochroism. Reflectance percentages forR min and Rmax are 40.1, 45.8 (471.1 nm), 39.6, 44.1 (548.3 nm), 39.4, 43.2 (586.6 nm), and 38.9, 41.8 (652.3 nm), respectively. Empressite is orthorhombic and belongs to space group Pmnb (Pnma as standard), with the fol- lowing unit-cell parameters: a = 8.882(1), b = 20.100(5), c = 4.614(1) Å, V = 823.7(3) Å3, and Z = 16. -
New Mineral Names*
American Mineralogist, Volume 68, pages 280-2E3, 1983 NEW MINERAL NAMES* MrcnnBr- FrelscHen AND ADoLF Pnnsr Arsendescloizite* The mineral occurs at Uchucchacua,Peru, in acicular crystals up to 2fi) x 20 microns, associatedwith galena, manganoan (1982) Paul Keller and P. J. Dunn Arsendescloizite, a new sphalerite, pyrite, pyrrhotite, and alabandite, with gangue of mineral from Tsumeb. Mineralog. Record, 13, 155-157. quartz, bustamite, rhodonite, and calcite. Also found at Stitra, pyrite-pyrrhotite in rhyo- Microprobe analysis (HzO by TGA) gave AszOs 26.5, PbO Sweden,in a metamorphosed deposit 52.3,ZnO1E.5, FeO 0.3, Il2O2.9, sum 100.5%,corresponding to litic and dacitic rocks; in roundedgrains up to 50 fl.min diameter, associated with galena, freibergite, gudmundite, manganoan Pb1.s6(Zn1.63Fe6.oJ(AsOaXOH)1a or PbZn(AsO+XOH), the ar- senateanalogue ofdescloizite. The mineral is slightly soluble in sphalerite,bismuth, and spessartine. hot HNO3. The name is for A. Benavides, for his contribution to the Weissenbergand precessionmeasurements show the mineral development of mining in Peru. Type material is at the Ecole (Uchucchacua)and at the Free to be orthorhombic, space group F212121,a : 6.075, b = 9.358, Natl. Superieuredes Mines, Paris (SAtra). c = 7.$44, Z = 4, D. calc. 6.57. The strongestX-ray lines University, Amsterdam, Netherlands M.F. (31 eiven) are 4.23(6)(lll); 3.23(lOXl02);2.88(10)(210,031); 2.60 Kolfanite* (E)(13 I ) ; 2.W6)Q3r) ; I .65(6X33I, 143,233); r.559 (EX3I 3,060,25I ). Crystalsare tabular up to 1.0 x 0.4 x 0.5 mm in size, on {001}, A. -
New Mineral Names*,†
American Mineralogist, Volume 104, pages 625–629, 2019 New Mineral Names*,† DMITRIY I. BELAKOVSKIY1 AND FERNANDO CÁMARA2 1Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18 korp. 2, Moscow 119071, Russia 2Dipartimento di Scienze della Terra “Ardito Desio”, Universitá di degli Studi di Milano, Via Mangiagalli, 34, 20133 Milano, Italy IN THIS ISSUE This New Mineral Names has entries for 8 new minerals, including fengchengite, ferriperbøeite-(Ce), genplesite, heyerdahlite, millsite, saranchinaite, siudaite, vymazalováite and new data on lavinskyite-1M. FENGCHENGITE* X-ray diffraction pattern [d Å (I%; hkl)] are: 7.186 (55; 110), 5.761 (44; 113), 4.187 (53; 123), 3.201 (47; 028), 2.978 (61; 135). 2.857 (100; 044), G. Shen, J. Xu, P. Yao, and G. Li (2017) Fengchengite: A new species with 2.146 (30; 336), 1.771 (36; 24.11). Single-crystal X-ray diffraction data the Na-poor but vacancy-dominante N(5) site in the eudialyte group. shows the mineral is trigonal, space group R3m, a = 14.2467 (6), c = Acta Mineralogica Sinica, 37 (1/2), 140–151. 30.033(2) Å, V = 5279.08 Å3, Z = 3. The structure was solved by direct methods and refined to R = 0.043 for all unique I > 2σ(I) reflections. Fengchengite (IMA 2007-018a), Na Ca (Fe3+,) Zr Si (Si O ) 12 3 6 3 3 25 73 Fenchengite is the Fe3+ analog of eudialyte with a structural difference (H O) (OH) , trigonal, is a new eudialyte-group mineral discovered in 2 3 2 in vacancy dominant N5 site and splitting its Na site N1 into N1a and the agpaitic nepheline syenites and its pegmatite facies near the Saima N1b sites. -
Ajoite: New Data
American Mineralogist, Volume 66, pages 201-203, 1981 Ajoite: new data GEORGE Y. CHAO Department of Geology, Carleton University Ottawa, Ontario Kl S 5B6, Canada Abstract New data show that ajoite is triclinic, PI or pI, a ==13.637, b ==14.507, c ==13.620A, a == 107.16, f3 = 105.45, y = 110.57°; Z ==3. The mineral is biaxial positive, 2V ==80°, a ==1.550, f3 = 1.583, y = 1.641 (in Na light); pleochroic: X = very light bluish green, Y -- Z ==brilliant bluish green. {010} cleavage is perfect. The orientation of the principal vibration directions is defined by the spherical coordinates X(26.5°, 80°), Y(118°, 79°), Z(-104.5°, 15°). The ex- tinction angle c: Z' on (0 I0) is 150. Electron microprobe and chemical analyses gave Si02 41.2, Al203 3.81, CuO 42.2, MnO 0.02, FeO 0.11, CaO 0.04, Na20 0.84, K20 2.50, H20 (TGA to 1000°C) 8.35, sum 99.07 wt.%. The analysis corresponds to (Ko.70NaO.36Cao.Ol)(CUt,.97 Feo.o2)Alo.98Si9.oo024(OH)6'3.09H20 or ideally, (K,Na)Cu7AISi9024(OH)6' 3H20. TGA showed a two-stage dehydration; 50% of the total water was released between 70° and 425°C and the rest between 4250 and 800°C. Half of the water is zeolitic in nature. Introduction are always present. The termination on c may be ei- Ajoite, first described by Schaller and Vlisidis ther {001} or {203} or both. (1958) from Ajo, Pima County, Arizona, was thought to be monoclinic on the basis of optical studies. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Chromite Crystal Structure and Chemistry Applied As an Exploration Tool
Western University Scholarship@Western Electronic Thesis and Dissertation Repository February 2015 Chromite Crystal Structure and Chemistry applied as an Exploration Tool Patrick H.M. Shepherd The University of Western Ontario Supervisor Dr. Roberta L. Flemming The University of Western Ontario Graduate Program in Geology A thesis submitted in partial fulfillment of the equirr ements for the degree in Master of Science © Patrick H.M. Shepherd 2015 Follow this and additional works at: https://ir.lib.uwo.ca/etd Part of the Geology Commons Recommended Citation Shepherd, Patrick H.M., "Chromite Crystal Structure and Chemistry applied as an Exploration Tool" (2015). Electronic Thesis and Dissertation Repository. 2685. https://ir.lib.uwo.ca/etd/2685 This Dissertation/Thesis is brought to you for free and open access by Scholarship@Western. It has been accepted for inclusion in Electronic Thesis and Dissertation Repository by an authorized administrator of Scholarship@Western. For more information, please contact [email protected]. Western University Scholarship@Western University of Western Ontario - Electronic Thesis and Dissertation Repository Chromite Crystal Structure and Chemistry Applied as an Exploration Tool Patrick H.M. Shepherd Supervisor Roberta Flemming The University of Western Ontario Follow this and additional works at: http://ir.lib.uwo.ca/etd Part of the Geology Commons This Thesis is brought to you for free and open access by Scholarship@Western. It has been accepted for inclusion in University of Western Ontario - Electronic Thesis and Dissertation Repository by an authorized administrator of Scholarship@Western. For more information, please contact [email protected]. Chromite Crystal Structure and Chemistry Applied as an Exploration Tool (Thesis format: Integrated Article) by Patrick H.M. -
NEW MINEI{AL NAMES Mrcuanr, Frbrscnun Fersilicite, Ferdisilicite L
TFIE AMI'RICAN MINERALOGIST, VOL 54, NOVEMBER DECEMBER, 1969 NEW MINEI{AL NAMES Mrcuanr, FrBrscnun Fersilicite,Ferdisilicite V. Kn. Gnvoar'ven (1969) The occurrence of natural ferrosilicon in the northern Azov region. Dokl. Ahad. Nauh.S.S.SR,185, 4lG+18 (in Russian). V. Ku. Grvonx'veN, A. L. Lrrvrw, .qNo A. S. Povannnny<u (1969) Occurrence of the new minerals fersilicite and ferdisilicate. Geol.Zh. (Lrkraine) 29 No.2,62-71 (in Russian). In placers and in drill-core samples of sandstones of the Poltava series near Zachativsk station, Donets region, fragments 0.1 to 3 mm in size were found of material with strong steely luster, although many of the grains are covered by a dark gray opaque film. Chemical 'I'ananaev analysesby N V. of fractions of size )1 mm and 0.25-0.5 mm gave, resp.; Fe 52.09,50.51; Si 43 25, 41.45;TiOz 0.05,0.55; AI2OB1.30, 2.70; MnO 0.65,2.56; MgO 0.18, O.32;CaO 092,0.42; Na2Onot detd., 0.15; K:O not detd.,0.01;NiO 0.30,not detd., sum 98.74 (given as99.74),98.67 (given as 10O.67a/).Spectrographic analyses by E. S. Nazare- vich showed also Co 0.06, 0 06; V 0.003, 0.003, Cr 0.2, 0 03; Zr 0.O03(?), 0.0a; Cu 0.6, 0.3; 2nO.01,0.02; Sn 0.02,0.027a.The analysescorrespond approximately to I'e2SL. Optical and X-ray data showed that the material consists of two distinct phases, a cubic phase with o 4.48*0.012 A corresponding to synthetic FeSi, and a tetragonal phase with a 2 69+0.012, c 5.08+ 0.02 A, correspondingto synthetic FeSi2 The cubic phase, named {ersilicate, has strongest lines 3.143 (5)(110), 2.566 (5)(111), l.ee1(10)(210), r.8r7 (9)(211), 1.347 (s)(311), 1.196 (10)(321), r.lre (s)(400),1.028 (e) (331), 0.978 (9)(421). -
Wickenburgite Pb3caal2si10o27² 3H2O
Wickenburgite Pb3CaAl2Si10O27 ² 3H2O c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Hexagonal. Point Group: 6=m 2=m 2=m: Tabular holohedral crystals, dominated by 0001 and 1011 , to 1.5 mm. As spongy aggregates of small, highly perfect f g f g individuals; as subparallel aggregates or rosettes; granular. Physical Properties: Cleavage: 0001 , indistinct. Tenacity: Brittle but tough. Hardness = 5 D(meas.) = 3.85 D(cfalc.) g= 3.88 Fluoresces dull orange under SW UV. Optical Properties: Transparent to translucent. Color: Colorless to white; rarely salmon-pink. Luster: Vitreous. Optical Class: Uniaxial ({). Dispersion: r < v; moderate. ! = 1.692 ² = 1.648 Cell Data: Space Group: P 63=mmc: a = 8.53 c = 20.16 Z = 2 X-ray Powder Pattern: Near Wickenburg, Arizona, USA. 10.1 (100), 3.26 (80), 3.93 (60), 3.36 (40), 2.639 (40), 5.96 (30), 5.04 (30) Chemistry: (1) (2) SiO2 42.1 40.53 Al2O3 7.6 6.88 PbO 44.0 45.17 CaO 3.80 3.78 H2O 3.77 3.64 Total 101.27 100.00 (1) Near Wickenburg, Arizona, USA. (2) Pb3CaAl2Si10O24(OH)6: [needsnew??formula] Occurrence: In oxidized hydrothermal veins, carrying galena and sphalerite, in quartz and °uorite gangue (near Wickenburg, Arizona, USA). Association: Phoenicochroite, mimetite, cerussite, willemite, crocoite, duftite, hemihedrite, alamosite, melanotekite, luddenite, ajoite, shattuckite, vauquelinite, descloizite, laumontite. Distribution: In the USA, in Arizona, at several localities south of Wickenburg, Maricopa Co., including the Potter-Cramer property, Belmont Mountains, and the Moon Anchor mine; on dumps at a Pb-Ag-Cu prospect in the Artillery Peaks area, Mohave Co.; and in the Dives (Padre Kino) mine, Silver district, La Paz Co. -
Chemistry of Formation of Lanarkite, Pb2oso 4
SHORT COMMUNICATIONS MINERALOGICAL MAGAZINE, DECEMBER 1982, VOL. 46, PP. 499-501 Chemistry of formation of lanarkite, Pb2OSO 4 W E have recently reported (Humphreys et al., 1980; sion which is at odds with the widespread occur- Abdul-Samad et al., 1982) the free energies of rence of the simple sulphate and the extreme rarity formation of a variety of chloride-bearing minerals of the basic salt, and with aqueous synthetic of Pb(II) and Cu(II) together with carbonate procedures for the preparation of the compound and sulphate species of the same metals includ- (Bode and Voss, 1959), which involve reaction of ing leadhillite, Pb,SO4(COa)2(OH)2, caledonite, angtesite in basic solution. PbsCu2CO3(SO4)3(OH)6, and linarite, (Pb,Cu)2 Kellog and Basu (1960) also determined AG~ for SO4(OH)2. By using suitable phase diagrams it has Pb2OSOa(s) at 298.16 K using the method of proved possible to reconstruct, in part, the chemical univariant equilibria in the system Pb-S-O. They history of the development of some complex obtained a value of -1016.4 kJ mol-1 based on secondary mineral assemblages such as those at literature values for PbO(s), PbS(s), PbSO4(s), and the Mammoth-St. Anthony mine, Tiger, Arizona, SO2(g) and another of - 1019.8 kJ mol- 1 based on and the halide and carbonate suite of the Mendip adjusted values for the above compounds. These Hills, Somerset. two results, for which the error was estimated to A celebrated locality for the three sulphate- be about 4.5 kJ mol-1, seem to be considerably bearing minerals above is the Leadhills-Wanlock- more compatible with observed associations than head district of Scotland (Wilson, 1921; Heddle, the earlier values. -
About Our Mineral World
About Our Mineral World Compiled from series of Articles titled "TRIVIAL PURSUITS" from News Nuggets by Paul F. Hlava "The study of the natural sciences ought to expand the mind and enlarge the ability to grasp intellectual problems." Source?? "Mineral collecting can lead the interested and inquisitive person into the broader fields of geology and chemistry. This progression should be the proper outcome. Collecting for its own sake adds nothing to a person's understanding of the world about him. Learning to recognize minerals is only a beginning. The real satisfaction in mineralogy is in gaining knowledge of the ways in which minerals are formed in the earth, of the chemistry of the minerals and of the ways atoms are packed together to form crystals. Only by grouping minerals into definite categories is is possible to study, describe, and discuss them in a systematic and intelligent manner." Rock and Minerals, 1869, p. 260. Table of Contents: AGATE, JASPER, CHERT AND .............................................................................................................................2 GARNETS..................................................................................................................................................................2 GOLD.........................................................................................................................................................................3 "The Mystery of the Magnetic Dinosaur Bones" .......................................................................................................4