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Israelisrael ר .-. -,.;.-., . ' .... ' .. ~~,,. נ N [L. 8'i; C/j04cD ~ JO({j I -rA : INIS-mf'--9072 "... .;:.ז'ז" 'יין ~\~ . .rb 'ד נr I"L'-' ~ "':F Q ••' ~ C.. \ ,_ המחקי הכומו בושראל CHEMICALCHEMICAL RESEARCHRESEARCH IINN ISRAELISRAEL -. הכנס ה - 49 של החברה הישראלית לכימיה אוניברסטית תל - אביב , רמת - אביב 10-11 באוקטובר 1882 י כ"ג - כיין בתשרי י תשמ"ג Ii\ * ,פי."..".' __1 I """"""""""".;'.היי.ק.'''. l' ~ -_-__________________' ~"F המחקר הכימי בישראל CHEMICALCHEMICAL RESEARCRESEARCHH ININ ISRAELISRAEL הכנס ה - 49 של החברה הישראלית לכימיה אוניברסיטת תל - אביב , רמת - אביב 10-11 באוקטובר 1982 , כ"ג -כ"ד בתשרי , תשמ"ג (~ ,~I * J_. ... ~ ד . i?t , 1 "י t ! .... _ .. 11'1? ~ ~_ d"'_". _", " '"' ~ .... ק.' ....." .............................. f __.. t .................... ·'·'.r -- 1I -- ר ע דתה כנם ===== ==== ==== =:== == יר"ר ישראל גרלדברג .. חברים שמחה אברהמי יעקב פנצינר קדמה בר-אלי סטפו צירקז שמשרו גרטטפלד אררי צישנרבסקי ררה מנדלר אדרארר קרסרבר עילה מררנר שמערי שצפילר גיל נברי דפנה שרף טל דע נרכר; תערוכה: טל( זלץ רעדת הכנט יהחנרה הישראלית לכימיה מביעים את הערכתם לחרג לכימיה רלפקרלטה למדעים מדרייקים בארניברסיטת תל-אביב על שיתרף פערלה רהענקת עזרה בארגרו הכנס. .. איגךי הכנט הרא בשתרף עם האגררה הישראלית להנדטה כימית ראגרד • האינגינרים לכימיה תעשייתית. , 1 __--. _____ _._י·1w... pr_י_._ .... .,..,.,....,-. ._-_ _________ ~ SM.ייייי-י- I r _________ - IIזז - תררת המארגנים נתרנה גם למרסדרת רחבררת הרשרמים מטה על תמיכתם ותררמרתיהם לכנס זה: בנק ריסקרנט לישראל בע"מ ררנר מיכשרר רפראי רמדעי בע"מ בנק לארמי לישראל בע"מ אפא - טכנרלרגירת מתקדמרת בע"מ בנק איגור לישראל בע"מ אי . אס. אי ,. מכשרר מדעי לישראל בע"מ אלדו צירד אלקטררני כע"מ "מדע" סייאנטיפיק אינסטרימנטס בע"מ חברת ישראמקס בע"מ קרגטררל דאטה (ישראל) בע"מ קרמירה בע"מ אל-חמה שיררק ( 1972 ) בע"מ לנרסיס (ישראל) ב~זמ שילרב - פירסרם, שיררק, קידרם מכיררת אסטרגל בע"מ מ. קרכו רשרתי ( 1977 ) בע"מ מרטכניקה בע"מ מרקררי גציגריות כימיקלים בע"מ חמררד בע"מ לרמיטריו מכשרר מדעי בע"מ פריד אלקטריק בע"מ לחמו צירד תהליכי בע"מ אנקור צירד מדעי בע"מ ש.א.ק. חברה לצירד מדעי בע"מ l' , -______ 1 .., f . n. I - 111Ill -- מ ידע כ ל ל י=================== אריעי הכנס מתקיימים בבניני שנקר ראירנשטייך notnpaaבפקרלטה למדעים מדרייקים; ראה on>sפיררט bt\b\".להלך. piרק aunnמרשב nrpnanהפתיחה A>ann<החגיגי Tonנערר di'iio'Titoבארדיטררירם בר-שירה. אררחרת קלרת. jכריכים. ni>iyערגרת niNpaoiרמשקארת ci'bpקלים oניתךr\-\}pb irrלקנרת במזנרנים השרנים בשטח oianpn.הקמפרס. d^jurnnהמזנרנים tPDioonהסמרכים למקרם הכנס נמצאים בבניך שנקר-פיסיקה (מזנרך לב). בניך גילמו. בניך משפטים רבמרזיארך בית התפרצרת. ninnxאריחרת rmieaבשרירת nie/Aiaמרגשרת IKאן pmררק במנזה המרכזית בכית הסטרדנט. בתקרפת פגרת הלימרדים anרב המזנרנים רהמנזה פתרחים עד שעה 4 אחה"צ. מזניך גילמך פתרח גם בשערת מארחררת ירתר. מגרשי חניה לרכב d>nniynהערמדים nioibלרשרת ^K'באי oj^nהכנס a'NSOiנמצאים in?!מיל «nyvשערי no'osnהכניםה on'מסי 4 ר - 5 לקמפרס, ליד מכרך התקנים רבניך הפקרלטה להנדסה. לצערנר • לא ניתך אישרר nunbלחנרת no©aבשטח n'^an'הפנימי bwשל oiaapnה~מפיס. תיקים אישיים עם חרברת התקצירים, תכנית הכנס, דפי כתיבה, תגירת רחרמר אחר מחרלקים ליד שרלחך ההרשמה.. d>annu»nnהמשתתפים מתבקשים לרשרם את שמם על גבי התגירת רלעברד iniN;ארתן; n!?Nאלה nuynaaמשמשרת O>DIDכרטיס no^jaכניסה bobלכל אררעי הכנס. המרצים רירשבי Iראשn OKהישיברתd>BTTJ nirpcpנדרשים ?!mapnלהקפדה <*ninיתרה ^על nibלרח fiהזמנים שנקבע מראש oiiaaiרמפררט lbnb .להלן. mapnהקפדה uזר naie/nחשרבה na''כדי D^B^שלכל nx'mמרצה *inw1יישמר intnהזמך המרקצב להרצאתר, רכדי לאפשר למשתתפים לתכנך שמיעת הרצארת הניתנרת בישיברת מקבילרת. 1< I _~J ך """"""",,"".כ.?". ~ .: , " .. ....."'-'-,_,, . • I I ____________________ - IVIV -- תכנית כללית של אריעי הכנס=========================== יימ אי~ 10 באיקטיבר 1982 08:30 - 09:45 הרשמה (בר שירה), הכנת תציגת הפיסטרימ (שנקר). 09:45 - 11:30 מישב פתיחה חגיגי (בר שירה) ברכית: ד"ר ר. הבר נשלא החברה הישראלית לכימיה פריפ' י.דינשטייך רקסיר איניברסיטת תל-אביב פריפ' א. לביא מדעך ראשל של משרד התעשיה יהמסחר ד"ר ש. אברהמי נשיא האגידה הישראלית להנדסה כימית מר י. שלדיב נשיא איגיד האינגינרים לכימיה תעשייתית הרצאת מליאה מרכזית: פריפ' יהישע יירטנר (חתך פרס ישראל תשמ"ב) - "כייינים ימגמית במחקר הבסיסי" 11:30 - 14:00 תציגת פיסטרימ בתחימי הכימיה השינימ (שנקר יאירנשטייך) , הרצאית מימחים על מיכשיר אנליטי מתקדם, הפסקת צהריים. 14:00 - 17:00 ישיבית הרצאית בתחימי הכימיה השינלם יבהיראת הכימיה. 16:00 - 18:00 רב-שיח על הנישא !וצרכימ יבעיית בהיראת הכימיה בישראל" (אילם לב) מנחה הדייך: פריפי ד. סמיאל '. במסגרת מישב זה ייענקי פרסים לתלמידי תיכיך על עבידית גמר מצטיינית בכימיה. ~ 17:00 - 18:00 תציגת פיסטרים (המשך). 18:00 - 19:00 קבלת פנים לא פירמלית מטעם פריפי א. גלעדי, דיקאך הפקילטה למדעים מדיייקים יפריפי א. בך-ראיבך, יי"ר החיג לכימיה (כיביד קל). (------ '-' .,~ - ___ >י__ ,.~,_, _ ..... ~_,_ ...... ~ ........ -...'oח .•_--. ~ ך ;1 ר "-'' .. ,-. f - vV -- יימ בו. 11 באיקטיבר 1982 08:30 - 09:30 מישב מליאה (אילם לב) דברי פתיחה : פריפו ייבל נאמי - שר המדע יהפתיח הרצאה מרכזית ד··ר אירי אייזנר - "מחקר יפתיח נחנרית כימיקלימ לישראלי· . 09:45 - 16:00 תציגה רציפה של פיסטרימ 09:45 - 12:15 ישיבית הרצאית בתחימי הכימיה השינים 12:15 - 13:30 הפסקת צהריים 13:30 - 16:00 ישיבית הרצאית נתחימי הכימיה השינימ 16:00 - 18:00 רב-שיח על הנישא ·יכיייני התפתחית של המחקר יהתעשיה הכימית בישראל נשנית ה - 80." מנחה הדיין: פריפ' א. גלעדי נעילת הכנס, תציגת צייד מדעי תתקיימ במשך שני ימי הכנס באילם הכניסה לבנין שנקר-פיסיקה. מפגש תעסיקה ייערך ביים א' ה - 10.10.82 בבנין אירנשטיין. להלן מיכא ליח זמנים מפורט של ההרצאית, רשימת העבידית המוצגיח בתציגת הפיסטרים יאיסף התקצירים שהיגשי לכנס. תיכו הפרסימים של החברית המסחריות אשר כלילים נחיברת זי היא באחריותם הבלעדית של המפרסמים. '-~--'''''''' -------~ - .... _-_ .. ~_.~ ___ f - vi - .5 O^IN ,14:00 - 17:00 'K 01 .00 14.00 1 E. ZADOK and Y. MAZUR (Invited Lecture) Oxygen Atoms: Formation, Properties and Utilization in Organic Synthesis 14:45 4 S. HIRSH and D. BEN-ISHAI Amidoalkylations of Dienes with Adducts of Glyoxylic Acid. 15:05 5 S. BITTNER and Y. ASSAF Synthesis of Phospha(V)azenes by Redox Condensation Reactions. 15:25 6 S. BRAVERMAN and Y. DUAR Stereochemistry of the Electrophilic Fragmentation-Cyclization of Allenic Sulfones and Sulfinates: Stereoselective Synthesis of Chiral <x,3-Unsaturated y-Sulfines. 15:45 Discussion (Coffee) 16:00 7 Y. ITTAH Stereochemical and Electronic Factors in Hydrocarbon Carcinogenesis. 16:20 8 E.M. KOSOWER Single Group Rotation. An Early Step in the Transduction of Chemical Stimuli: Neurotransmitters. A Structural and Mechanistic Model for Ionic Channels in Biomembranes. 16:40 A. TABAK. N. LOTAN, S. SIDEMAN and U. TAITELMAN Composite Sorbents - Applications in Biomedical Engineering. ObiK ,09:45 - 12:10 O1> 09:45 2 Z. RAPPOPORT (Invited Lecture) Some Mechanistic Aspects of Nucleophilic Vinylic Substitution. 10:30 10 D. HUPPERT, H. KANETY and E.M. KOSOWER Kinetics and Mechanism of Intramolecular Electron Transfer in Solution. 10:50 11 A. MINSKY and M. RABINOVITZ Singlet-Triplet Equilibrium in Doubly Charged Benzenoid Polycyclic Systems. 11:10 12 B. WEITMAN and E.A. HALEVI The Mechanism of Thermal Decomposition of Diazofluorene in Solution. 11:30 13 S. HOZ and D. AURBACH Nucleophilic "Vinylic-like" Substitution in Bicyclobutane System. 11:50 14 B.A. FEIT and U. MELAMED Configurational Stability of Vinyl Carbanions Derived from Mono-substituted Activated Ethylenes. I f - VII - .3!? D!HN ,13:30 - 15:45 'a DP 13:30 3 Z. GOLDSCHMIDT (Invited Lecture) Pentacoordinate Irontricarbonyl Complexes. Model Compounds for the Study of Organometallic Pericyclic Reactions. 14:15 15 S. AVRAMOVICI-GRISARU and S. SAREL Novel Macrocyclic Iron(II) Complexes. 14:35 16 G. SAGIV and L. NETZER Synthesis of Bifunctional Surfactants and Investigation of their Ability to Form Multilayer Molecular Systems. 14:55 17 U. ZOLER Quaternary Imidazolium Salts: Electrophilic Substitutions and their Onium-anion as an Intermediate (?) 15:15 18 I. WILNER and Y. DEGANI Photosensitized Electron Transfer Reactions in Organized Environments as Photosynthetic Models. .111 1"DW311K ,09:45 - 12:15 '3 Dl' 09:45 60 R. REISFELD (Invited Lecture) Luminescent Solar Concentrators for Energy Conversion. 10:30 62 D. MEYERSTEIN (Invited Lecture) Chemical Reactions of Unstable Compounds with Metal-Carbon Bonds in Aqueous Solutions. 11:15 63 Y. SOREK. H. COHEN and D. MEYERSTEIN Reactions of Iron(II) Protoporphyrin with Free Radicals. A Pulse Radiolytic Study. 11:35 64 M. COJOCARU andJ.M.E. GOLDSCHMIDT A Study of the Mechanism of Formation of Polymeric Species in the Mass Spectra of Pentacarbonyltrimethylsilyl-iso-cyano- Complexes of Group VI Metals. 11:55 65 H. COHEN, E.S. GOULD, D. MEYERSTEIN, M. NUTKOVICH and C.E. RADLOWSKI Intermolecular Vs. Intramolecular-Electron Transfer Reactions in Cobalt(III) Pentaamine Coordinated to Pyridinyl Radicals. 1 - VIII - i"i* ,in-p .b 'ana - 111 p»oer:niN ,13:30 - 15:55 !3 01 •,•"./. 13:30 61 (v'Z. DORI (Invited Lecture) Macrocyclic Complexes of Iron and Cobalt 14:15 66 F. FROLOW, A. EFRATY and A. EISENSTADT 2 5 2 5 A Novel [Ru4CC0) (y-CO)2(n ,n ,n -indenyl)(n -dihydroindenyl)] Cluster. 14:35 67 A. EISENSTADT and A. EFRATY Preparation of Some Unusual u-Carbene Complexes of Ruthenium. 14:55 68 U. OLSHER. E.R. BLOUT, G. SHOHAM and W.N. LIPSCOMB Complexes of Lithium Salts with the Macrocyclic Polyether Dibenzo-14-crown-4. 15:15 69 F.H. HERBSTEIN and W. SCHWOTZER Extended Donor-Acceptor Molecular Compounds Between Thiones and Chains of Bis (iodine) Molecules. A. GIVAN, I. MAYER and L. BEN-DOR Uranium in Apatites. .205 •p'uemiN ,13:30 - 15:55 '3 01* 13:30 74 J. BLUM (Invited Lecture) Catalytic Hydrogenation and Transfer Hydrogenation Reactions in Multi-phase Systems. 14:15 75 M. ROTEM and Y. SHVO Formation and Reactivity of Ruthenium Carboxylate Complexes. 14:35 76 I. PRI-BAR and J.K. STILLE Formation of New C-C and C-0 Bonds in Homogeneous Catalyzed Organotin Coupling Reaction.
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