PUBLICATIONS Journal of Geophysical Research: Planets RESEARCH ARTICLE Can perchlorates be transformed to hydrogen peroxide (H2O2) 10.1002/2017JE005329 products by cosmic rays on the Martian surface? Key Points: Parker B. Crandall1,2 , Sándor Góbi1,2, Jeffrey Gillis-Davis3, and Ralf I. Kaiser1,2 • Magnesium perchlorate samples were irradiated with deuterium ions and 1Department of Chemistry, University of Hawai’iatMānoa, Honolulu, Hawaii, USA, 2W.M. Keck Laboratory in Astrochemistry, electrons to model galactic cosmic ray ’ ā 3 ’ (GCR) exposure University of Hawai iatM noa, Honolulu, Hawaii, USA, Hawai i Institute of Geophysics and Planetology, University of • GCRs supplanted in the regolith can Hawai’iatMānoa, Honolulu, Hawaii, USA participate in the formation of hydrogen peroxide via the destruction À of perchlorates Abstract Due to their oxidizing properties, perchlorates (ClO4 ) are suggested by the planetary science • Volatile oxidizing agents formed likely community to play a vital role in the scarcity of organics on the Martian surface. However, alternative contribute to the lack of organic material beneath the Martian surface oxidation agents such as hydrogen peroxide (H2O2) have received surprisingly little attention. In this study, samples of magnesium perchlorate hexahydrate (Mg(ClO4)2 ·6H2O) were exposed to monoenergetic + electrons and D2 ions separately, sequentially, and simultaneously to probe the effects of galactic cosmic ray Correspondence to: exposure of perchlorates and the potential incorporation of hydrogen (deuterium) into these minerals. The R. I. Kaiser, experiments were carried out under ultrahigh-vacuum conditions at 50 K, after which the samples were
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