DAR-1 Guidelines for the Evaluation and Control of Ambient Air
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List of Lists
United States Office of Solid Waste EPA 550-B-10-001 Environmental Protection and Emergency Response May 2010 Agency www.epa.gov/emergencies LIST OF LISTS Consolidated List of Chemicals Subject to the Emergency Planning and Community Right- To-Know Act (EPCRA), Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and Section 112(r) of the Clean Air Act • EPCRA Section 302 Extremely Hazardous Substances • CERCLA Hazardous Substances • EPCRA Section 313 Toxic Chemicals • CAA 112(r) Regulated Chemicals For Accidental Release Prevention Office of Emergency Management This page intentionally left blank. TABLE OF CONTENTS Page Introduction................................................................................................................................................ i List of Lists – Conslidated List of Chemicals (by CAS #) Subject to the Emergency Planning and Community Right-to-Know Act (EPCRA), Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and Section 112(r) of the Clean Air Act ................................................. 1 Appendix A: Alphabetical Listing of Consolidated List ..................................................................... A-1 Appendix B: Radionuclides Listed Under CERCLA .......................................................................... B-1 Appendix C: RCRA Waste Streams and Unlisted Hazardous Wastes................................................ C-1 This page intentionally left blank. LIST OF LISTS Consolidated List of Chemicals -
Calculations 273 Absolute Asymmetric Synthesis 634, 635 Absolute
1317 Index A activation enthalpy 23, 39, 188, 195–196, 204, 205, 206, aaptosine 358, 359 217, 339, 341, 345, 370, 393, 398, 411, 412, 443, 444, ab initio Hartree–Fock (HF) calculations 273 452, 453, 462, 465, 500, 697, 728 absolute asymmetric synthesis 634, 635 activation entropy 39, 188, 190, 192–196, 198, 369, 500, absolute electronegativity 37 689, 695, 872 absolute hardness 37–39, 839 activation entropy and reaction mechanism absolute softness 37 – Cope rearrangement 195 absorbance 616 – gas phase – – homolysis and radical combination 192–193 absorption complex 624, 667 – – isomerizations 193–194 absorption on crystalline quartz 44 – neighboring group directing effects 197 acetaldehyde 15, 18, 60, 66, 70, 80, 82, 86, 145, 146, 147, – retro-carbonyl-ene reaction 195–197 195, 197, 223, 514, 551, 619, 683, 686, 697, 732, 797, activation parameters 819, 855, 920, 921, 1168 – Curtin–Hammett principle 190–192 acetamide 62, 66, 82, 89, 619 – temperature effect, two parallel reactions 190 acetic acid 12, 13, 49, 60, 87, 89, 151, 373, 503, 619, 650, acyclic ,-and,-enones 60, 642 699, 800, 808, 900, 1030, 1032–1034, 1050 acyclic alkylaminocarbene 439 acetic anhydride 12, 61, 216, 619, 802, 1033 acyclic diene 55, 468, 633, 1126 acetone 15, 25, 35, 36, 60, 70, 80, 85, 86, 88, 90, 122, acyclic 1,3-dienes 55, 697, 698 143, 146–148, 153, 203, 210, 213, 224, 226, 229–232, acyclic dithiosilylene 448 373, 374, 382, 383, 412, 413, 435, 619, 622, 623, 628, acyclic peroxides 729 633, 637, 638, 641, 656, 662, 669, 671, 682, 685, 686, (1,2)-acyloxy shifts -
Development and Application of a Sensitive Method to Determine Concentrations of Acrolein and Other Carbonyls in Ambient Air Thomas M
RESEA R C H R E P O R T HE A L TH HE A L TH Development and Application of a EFF E CTS EFF E CTS Sensitive Method to Determine INSTITUTE INSTITUTE Concentrations of Acrolein and 101 Federal Street, Suite 500 Other Carbonyls in Ambient Air Boston, MA 02110, USA Number 149 May 2010 +1-617-488-2300 Thomas M. Cahill, M. Judith Charles, and www.healtheffects.org Vincent Y. Seaman RESEA R CH REPO R T Number 149 May 2010 Development and Application of a Sensitive Method to Determine Concentrations of Acrolein and Other Carbonyls in Ambient Air Thomas M. Cahill, M. Judith Charles, and Vincent Y. Seaman with a Critique by the HEI Health Review Committee Research Report 149 Health Effects Institute Boston, Massachusetts Trusted Science · Cleaner Air · Better Health Publishing history: The Web version of this document was posted at www.healtheffects.org in May 2010. Citation for document: Cahill TM, Charles MJ, Seaman VY. 2010. Development and Application of a Sensitive Method to Determine Concentrations of Acrolein and Other Carbonyls in Ambient Air. HEI Research Report 149. Health Effects Institute, Boston, MA. © 2010 Health Effects Institute, Boston, Mass., U.S.A. Cameographics, Belfast, Me., Compositor. Printed by Recycled Paper Printing, Boston, Mass. Library of Congress Number for the HEI Report Series: WA 754 R432. Cover paper: made with at least 55% recycled content, of which at least 30% is post-consumer waste; free of acid and elemental chlorine. Text paper: made with 100% post-consumer waste recycled content; acid free; no chlorine used in processing. -
Acrolein, Crotonaldehyde, and Arecoline Volume 128
ACROLEIN, CROTONALDEHYDE, AND ARECOLINE VOLUME 128 This publication represents the views and expert opinions of an IARC Working Group on the Identification of Carcinogenic Hazards to Humans, which met remotely, 29 October–13 November 2020 LYON, FRANCE - 2021 IARC MONOGRAPHS ON THE IDENTIFICATION OF CARCINOGENIC HAZARDS TO HUMANS ACROLEIN 1. Exposure Characterization 1.1.3 Chemical and physical properties 1.1 Identification of the agent Description: colourless to yellowish liquid with extremely acrid, pungent, and irritating 1.1.1 Nomenclature odour, causing lachrymation (Verschueren, 1983; IARC, 1985; O’Neil, 2013) Chem. Abstr. Serv. Reg. No.: 107-02-8 Boiling point: 52.5–53.5 °C (Lide, 1993) Deleted Chem. Abstr. Serv. Reg. No.: 25314-61-8 Melting-point: –86.9 °C (Lide, 1993) EC/List No.: 203-453-4 Relative density: 0.8410 at 20 °C/4 °C (Lide, Chem. Abstr. Serv. name: 2-propenal 1993) IUPAC systematic name: prop-2-enal Solubility: soluble in water (206 g/L at 20 °C), Synonyms: acraldehyde; acrylaldehyde; acryl - ethanol, diethyl ether, and acetone (IPCS, ic aldehyde; allyl aldehyde; ethylene aldehyde; 1992; Lide, 1993) propenal; 2-propenal; prop-2-en-l-al Volatility: vapour pressure 29.3 kPa (IARC, 1995; O’Neil, 2013; ECHA, 2020). (220 mm Hg) at 20 °C (IPCS, 1992) Flash-point: −26 °C (IPCS, 1992) 1.1.2 Structural and molecular formulae, and Stability: unstable in the absence of an inhib- itor (IPCS, 1992); polymerizes, especially relative molecular mass under light or in the presence of alkali or strong acid, to form disacryl, a plastic solid Structural formula: (O’Neil, 2013). -
Arxiv:2006.16299V2 [Physics.Chem-Ph] 11 Sep 2020
Spatial Separation of the Conformers of Methyl Vinyl Ketone Jia Wang,1, a) Ardita Kilaj,2 Lanhai He,1, b) Karol Długołęcki,1 Stefan Willitsch,2, c) and Jochen Küpper1, 3, 4, d) 1)Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestrasse 85, 22607 Hamburg, Germany 2)Department of Chemistry, University of Basel, Klingelbergstrasse 80, 4056 Basel, Switzerland 3)Department of Physics, Universität Hamburg, Luruper Chaussee 149, 22761 Hamburg, Germany 4)Center for Ultrafast Imaging, Universität Hamburg, Luruper Chaussee 149, 22761 Hamburg, Germany Methyl vinyl ketone (C4H6O) is a volatile, labile organic compound of importance in atmospheric chemistry. We prepared a molecular beam of methyl vinyl ketone with a rotational temperature of 1.2(2) K and demonstrated the spatial separation of the s-cis and s-trans conformers of methyl vinyl ketone using the electrostatic 8 3 deflector. The resulting sample density was 1.5(2) 10 cm− for the direct beam in the laser ionization × region. These conformer-selected methyl vinyl ketone samples are well suited for conformer-specific chemical reactivity studies such as in Diels-Alder cycloaddition reactions. I. INTRODUCTION The reactivity of different conformers may vary sig- nificantly27,28. Neutral molecules can be manipulated Methyl vinyl ketone (MVK, 3-butene-2-one, C4H6O) is in the gas-phase using the electrostatic deflection tech- 29 the simplest α, β-unsaturated ketone and an important nique , which was demonstrated for the separation of 30–32 33–37 oxygenated volatile organic compound. MVK results from individual quantum states , conformers , or molec- 37–39 many sources such as vehicle exhaust1,2, biomass burning3 ular clusters . -
STUDIES in CONDENSATION REACTIONS Thesis Presented To
STUDIES IN CONDENSATION REACTIONS Thesis presented to The University of Glasgow by Elspeth Mary Austin 1969. ProQuest Number: 11011871 All rights reserved INFORMATION TO ALL USERS The quality of this reproduction is dependent upon the quality of the copy submitted. In the unlikely event that the author did not send a com plete manuscript and there are missing pages, these will be noted. Also, if material had to be removed, a note will indicate the deletion. uest ProQuest 11011871 Published by ProQuest LLC(2018). Copyright of the Dissertation is held by the Author. All rights reserved. This work is protected against unauthorized copying under Title 17, United States C ode Microform Edition © ProQuest LLC. ProQuest LLC. 789 East Eisenhower Parkway P.O. Box 1346 Ann Arbor, Ml 48106- 1346 ACKNOWLEDGEMENTS I should like to express ray sincere thanks to Dr. G.L. Buchanan for the constant encouragement and assistance he has given me throughout this period of research, and to Professor R.A. Raphael, F.R.S., for the opportunity to carry out this work. I also wish to thank the members of staff of the various departments responsible for recording high- resolution infra-red spectra, n.m.r, spectra, micro analyses and mass-spectra, and those who performed combined g.c.m.s. analyses and preparative g.l.c. work. The work described in this thesis was performed during the tenure of a Maintenance Award from the Scientific Research Council (Oct., 1967 - Feb., 1969). SUMMARY The mechanism of the Thermal Michael reaction, i.e., the condensation of a Mannich base with a compound containing an activated methylene group, has been studied and evidence has been obtained which corroborates the postulated reaction steps. -
Rev. 23 Table 2: Pacs by Chemical Name (Pdf)
Table 2: Protective Action Criteria (PAC) Rev 23 based on applicable AEGLs, ERPGs, or TEELs (chemicals listed in alphabetical order) PAC Rev 23 – August 2007 Table 2 presents an alphabetical listing of the chemicals in the PAC data set and provides Chemical Abstracts Service Registry Numbers (CAS RNs)1, PAC data, and technical comments focusing on changes in the PACs since the previous version of the PAC/TEEL data set (Rev 21). PACs are provided for TEEL-0 (i.e., PAC-0), PAC-1, PAC-2, and PAC-3. Values are usually given in parts per million (ppm) for gases and volatile liquids and in milligrams per cubic meter (mg/m3) for particulate materials (aerosols) and nonvolatile liquids. The columns presented in Table 2 provide the following information: Heading Definition No. The ordered numbering of the chemicals as they appear in this alphabetical listing. Chemical The common name of the chemical compound. Compound CAS RN The Chemical Abstracts Service Registry Number for this chemical. TEEL-0 This is the threshold concentration below which most people will experience no appreciable risk of health effects. This PAC is always based on TEEL-0 because AEGL-0 or ERPG-0 values do not exist. PAC-1 Based on the applicable AEGL-1, ERPG-1, or TEEL-1 value. PAC-2 Based on the applicable AEGL-2, ERPG-2, or TEEL-3 value. PAC-3 Based on the applicable AEGL-3, ERPG-3, or TEEL-3 value. Units The units for the PAC values (ppm or mg/m3). Comments Technical comments by the developers of the PAC data set.