CHEMISTRY RELATED TO POSSIBLE OUTGASSING SOURCES ON MARS. A. S. Wong, S. K. Atreya and N. O. Renno, Department of Atmospheric, Oceanic and Space Sciences, University of Michigan, Ann Arbor, MI 48109-2143 (
[email protected]). Introduction: An earlier paper, “Chemical mark- which the surface mixing ratio of each outgassed spe- ers of possible hot spots on Mars” by A. S. Wong, S. cies is set to 100 ppm (Figure 2). The resulting mixing K. Atreya and Th. Encrenaz [1], explored the modifi- ratios and column abundances of SO2, H2S, and SO are cation of the atmosphere of Mars following an influx summarized in Table 1. All sulfur species scale more of methane, sulfur dioxide and hydrogen sulfide (CH4, or less proportionally with the amount of outgassing SO2, H2S) from any outgassing sources which are re- species. ferred to as hot spots. The feasibility of detection of the new species by Planetary Fourier Spectrometer on O2 Mars Express is reported in a subsequent paper, “At- HSO SO2 mospheric photochemistry above possible martian hot O ,HO hν O ,OH,O spots” by A. S. Wong, S. K. Atreya, V. Formisano, Th. 3 2 2 Encrenaz and N. Ignatiev [2]. This abstract is a fol- HS SO SO3 low-up on the previous two papers. Here we treat the O O3 effect of any outgassed halogens rigorously. We also hν hν O H2O make estimates of dilution factors relative to the source 2 location following convection and meridional trans- H S S H SO port. 2 2 4 The typical terrestrial outgassing species include H2O, CO2, SO2, H2S, CH4, and small amounts of halo- gens.