Relativistic Quantum Mechanics

Total Page:16

File Type:pdf, Size:1020Kb

Relativistic Quantum Mechanics Relativistic Quantum Mechanics Contents Review of Quantum Mechanics and Relativity Klein Gordon Equation Feynman Stueckelburg Interpretation Dirac Equation An tiparticles Fermion spin variant notation Co Massless fermions Learning Outcomes Be able to derive KG equation and explain physical meaning of ve E solutions i Be able to derive Dirac eqn and algebra for Be able to solve the free Dirac equation and interpret the solutions in terms of energy and spin Be able to use the covariant notation Reference Bo oks Halzen and Martin many other QM b o oks cover this material In this section of the course we will study relativistic quantum mechanics In a for example the interactions of highly ener particle accelerator we are interested in getic electrons so the need to combine relativity and quantum mechanics is pressing Some remarkable results will come out of this synthesis In particular we will theo retically predict the existence of antiparticles and also fermion spin Sit back and enjo y NonRelativistic Wave Equation Review Lets review how wave equations describ e nonrelativistic quantum particles Exp er imentally we learnt that a particle with denite momentum p and energy E could b e asso ciated with a plane wave p E i(k xw t) e k w h h To extract E and p from the wave we use operators d E ih p ih r dt 2 Classically we know that E p m V so we arrive at the Schro edinger equation 2 d h 2 ih r V dt m Equally we can write the Schro edinger equation quite generally with h as ih H t where H is the Hamiltonian ie the energy op erator Probability Density dx as the probability that the particle will b e found Rememb er that we interpret b etween x and x x Probability is a conserved quantity there is always probability one that the particle will b e somewhere This means that if the probability of the particle b eing in some area decreases w then the probability that it lies outside must increase In other words there is a o of probabilitycurrent density satisfying the usual conservation equation cf electric charge I Z ρ Z q = d V dV d J A t S R R Using the divergence theorem rA dV we have the continuity equa AdS tion rJ t wherein J is the probability densitycurrent Now we can show using the Schro edinger equation that satises such a relation We add two copies of the Schro edinger equation as follows i SE SE i This gives 2 i h 2 h h r i V t t 2m 2 ih 2 r i V 2m and hence ih r r r t m which indeed has the form of a conservation equation with Relativity Review In relativity an event is describ ed by the four co ordinates of a fourvector x x ct Under Lorentz transformations LT it transforms a familiar example of a LT is a b o ost along the z axis for which B C B C B C A 2 2 1 LTs can b e thought of as generalized with as usual v c and rotations x is then a contravariant vector since it transforms as x x x f g denote Lorentz indices and the summation The Greek lab els convention is used 2 2 2 The length of the vector c t jxj is invariant to LTs In general we dene the Minkowski scalar pro duct of two vectors x and y as x y x y g x y where the metric if g g g diag g if has b een intro duced The last step in is nothing but the denition of a covariant vector sometimes referred to as covector g x x To formulate a coherent relativistic theory of dynamics we dene kinematic vari ables that are also vectors ie transform as describ ed ab ove For example we dene a velo city dx u d where is the proper time measured by a clo ck moving with the particle Everyone will agree as to what the clo ck says at a particular event so this measure of time is Lorentz invariant and u transforms as x Note dx dt c v u d dt and has invariant length 2 2 2 2 u u c jv j c Similarly momentum provides a relativistic denition of energy and momentum p mu E c p The invariant length gives us the crucial relation 2 2 2 2 2 p p E c jpj m c Note that is a covariant vector x x i i 0 so r and r I will use natural units in this course This rstly means redening the unit of distance so that c Secondly I shall redene the unit of energy so that E h ie seth So mass energy inverse length and inverse time all have the same dimensions Generally think of energy E as the basic unit eg mass m has units of 1 GeV and distance x has unit GeV The Klein Gordon Equation For a free relativistic particle the total energy E is no longer given by the equation we used to derive the Schro edinger equation Instead it is given by the Einstein equation 2 2 2 E p m In p osition space we write the energymomentum op erator as ir p i E p i t so that the KG equation b ecomes 2 2 m x where we have intro duced the b ox notation 2 2 2 2 t r and x is the vector t x The KleinGordon equation has plane wave solutions i(E tpx) x N e p 2 2 where N is a normalization constant and E p m There are two problems with this equation though Firstly there are b oth p ositive and negative energy solutions The negative energy solutions p ose a severe problem if you try to interpret as a wave function as indeed we are trying to do The sp ectrum is no longer b ounded from b elow and you can extract arbitrarily large amounts of energy from the system by driving it into ever more negative energy states Any external p erturbation capable of pushing a particle across the energy gap of m b etween the p ositive and negative energy continuum of states can uncover y Furthermore we cannot just throw away these solutions as unphysical this dicult since they app ear as Fourier mo des in any realistic solution of A second problem with the wave function interpretation arises when trying to 2 nd a probability density Since is Lorentz invariant jj do es not transform like a density so we will not have a Lorentz covariant continuity equation r J t To search for a candidate we derive such a continuity equation Start with the KleinGordon equation multiplied by and subtract the complex conjugate of the KG equation multiplied by Dening and J by i t t J i r r you obtain a covariant conservation equation J where J is the vector J It is thus natural to interpret as a probability density 2 and J as a probability current However for a plane wave solution jN j E so is not p ositive denite since weve already found E can b e negative Feynman Stueckelb erg Interpretation We have found that the KleinGordon equation a candidate for describing the quan tum mechanics of spinless particles admits unacceptable negative energy states when is interpreted as the single particle wave function There is another way forward this is the way followed in the textb o ok of Halzen Martin due to Stueckelb erg and Feynman Causality forces us to ensure that p ositive energy states propagate for wards in time But if we force the negative energy states only to propagate backwards in time then we nd a theory that is consistent with the requirements of causality and that has none of the aforementioned problems In fact the negative energy states cause us problems only so long as we think of them as real physical states propagat ing forwards in time Therefore we should interpret the emission absorption of a negative energy particle with momentum p as the absorption emission of a p ositive energy antiparticle with momentum p + In order to get more familiar with this picture consider a pro cess with a and a + photon in the initial state and nal state In gure a the starts from the p oint + A and at a later time t emits a photon at the p oint x If the energy of the is 1 1 still p ositive it travels on forwards in time and eventually will absorb the initial state photon at t at the p oint x The nal state is then again a photon and a p ositive 2 2 + energy There is another pro cess however with the same initial and nal state shown in + gure b Again the starts from the p oint A and at a later time t emits a 1 photon at the p oint x But this time the energy of the photon emitted is bigger 1 + + than the energy of the initial Thus the energy of the b ecomes negative and it time t it absorbs the initial is forced to travel backwards in time Then at an earlier 2 state photon at the p oint x thereby rendering its energy p ositive again From there 2 it travels forward in time and the nal state is the same as in gure a namely a + photon and a p ositive energy B B time (t 1, x 1) (t 2, x 2) (t 1, x 1) (t 2, x 2) A A (a) (b) Figure Interpretation of negative energy states In to days language the pro cess in gure b would b e describ ed as follows in + the initial state we have an and a photon At time t and at the p oint x the 2 2 + + photon creates a pair Both propagate forwards in time The ends up in the nal state whereas the is annihilated at a later time t at the p oint x by 1 1 + the initial state thereby pro ducing the nal state photon To someone observing in real time the negative energy state moving backwards in time lo oks to all intents and purp oses like a negatively charged pion with p ositive energy moving forwards in time We have discovered antimatter Dirac Equation Historically the Klein Gordon equation was b elieved to b e sick although now we understand it is telling us ab out antiparticles To try to solve the problem of negative energy solutions
Recommended publications
  • A Study of Fractional Schrödinger Equation-Composed Via Jumarie Fractional Derivative
    A Study of Fractional Schrödinger Equation-composed via Jumarie fractional derivative Joydip Banerjee1, Uttam Ghosh2a , Susmita Sarkar2b and Shantanu Das3 Uttar Buincha Kajal Hari Primary school, Fulia, Nadia, West Bengal, India email- [email protected] 2Department of Applied Mathematics, University of Calcutta, Kolkata, India; 2aemail : [email protected] 2b email : [email protected] 3 Reactor Control Division BARC Mumbai India email : [email protected] Abstract One of the motivations for using fractional calculus in physical systems is due to fact that many times, in the space and time variables we are dealing which exhibit coarse-grained phenomena, meaning that infinitesimal quantities cannot be placed arbitrarily to zero-rather they are non-zero with a minimum length. Especially when we are dealing in microscopic to mesoscopic level of systems. Meaning if we denote x the point in space andt as point in time; then the differentials dx (and dt ) cannot be taken to limit zero, rather it has spread. A way to take this into account is to use infinitesimal quantities as ()Δx α (and ()Δt α ) with 01<α <, which for very-very small Δx (and Δt ); that is trending towards zero, these ‘fractional’ differentials are greater that Δx (and Δt ). That is()Δx α >Δx . This way defining the differentials-or rather fractional differentials makes us to use fractional derivatives in the study of dynamic systems. In fractional calculus the fractional order trigonometric functions play important role. The Mittag-Leffler function which plays important role in the field of fractional calculus; and the fractional order trigonometric functions are defined using this Mittag-Leffler function.
    [Show full text]
  • Introductory Lectures on Quantum Field Theory
    Introductory Lectures on Quantum Field Theory a b L. Álvarez-Gaumé ∗ and M.A. Vázquez-Mozo † a CERN, Geneva, Switzerland b Universidad de Salamanca, Salamanca, Spain Abstract In these lectures we present a few topics in quantum field theory in detail. Some of them are conceptual and some more practical. They have been se- lected because they appear frequently in current applications to particle physics and string theory. 1 Introduction These notes are based on lectures delivered by L.A.-G. at the 3rd CERN–Latin-American School of High- Energy Physics, Malargüe, Argentina, 27 February–12 March 2005, at the 5th CERN–Latin-American School of High-Energy Physics, Medellín, Colombia, 15–28 March 2009, and at the 6th CERN–Latin- American School of High-Energy Physics, Natal, Brazil, 23 March–5 April 2011. The audience on all three occasions was composed to a large extent of students in experimental high-energy physics with an important minority of theorists. In nearly ten hours it is quite difficult to give a reasonable introduction to a subject as vast as quantum field theory. For this reason the lectures were intended to provide a review of those parts of the subject to be used later by other lecturers. Although a cursory acquaintance with the subject of quantum field theory is helpful, the only requirement to follow the lectures is a working knowledge of quantum mechanics and special relativity. The guiding principle in choosing the topics presented (apart from serving as introductions to later courses) was to present some basic aspects of the theory that present conceptual subtleties.
    [Show full text]
  • What Is the Dirac Equation?
    What is the Dirac equation? M. Burak Erdo˘gan ∗ William R. Green y Ebru Toprak z July 15, 2021 at all times, and hence the model needs to be first or- der in time, [Tha92]. In addition, it should conserve In the early part of the 20th century huge advances the L2 norm of solutions. Dirac combined the quan- were made in theoretical physics that have led to tum mechanical notions of energy and momentum vast mathematical developments and exciting open operators E = i~@t, p = −i~rx with the relativis- 2 2 2 problems. Einstein's development of relativistic the- tic Pythagorean energy relation E = (cp) + (E0) 2 ory in the first decade was followed by Schr¨odinger's where E0 = mc is the rest energy. quantum mechanical theory in 1925. Einstein's the- Inserting the energy and momentum operators into ory could be used to describe bodies moving at great the energy relation leads to a Klein{Gordon equation speeds, while Schr¨odinger'stheory described the evo- 2 2 2 4 lution of very small particles. Both models break −~ tt = (−~ ∆x + m c ) : down when attempting to describe the evolution of The Klein{Gordon equation is second order, and does small particles moving at great speeds. In 1927, Paul not have an L2-conservation law. To remedy these Dirac sought to reconcile these theories and intro- shortcomings, Dirac sought to develop an operator1 duced the Dirac equation to describe relativitistic quantum mechanics. 2 Dm = −ic~α1@x1 − ic~α2@x2 − ic~α3@x3 + mc β Dirac's formulation of a hyperbolic system of par- tial differential equations has provided fundamental which could formally act as a square root of the Klein- 2 2 2 models and insights in a variety of fields from parti- Gordon operator, that is, satisfy Dm = −c ~ ∆ + 2 4 cle physics and quantum field theory to more recent m c .
    [Show full text]
  • Dirac Equation - Wikipedia
    Dirac equation - Wikipedia https://en.wikipedia.org/wiki/Dirac_equation Dirac equation From Wikipedia, the free encyclopedia In particle physics, the Dirac equation is a relativistic wave equation derived by British physicist Paul Dirac in 1928. In its free form, or including electromagnetic interactions, it 1 describes all spin-2 massive particles such as electrons and quarks for which parity is a symmetry. It is consistent with both the principles of quantum mechanics and the theory of special relativity,[1] and was the first theory to account fully for special relativity in the context of quantum mechanics. It was validated by accounting for the fine details of the hydrogen spectrum in a completely rigorous way. The equation also implied the existence of a new form of matter, antimatter, previously unsuspected and unobserved and which was experimentally confirmed several years later. It also provided a theoretical justification for the introduction of several component wave functions in Pauli's phenomenological theory of spin; the wave functions in the Dirac theory are vectors of four complex numbers (known as bispinors), two of which resemble the Pauli wavefunction in the non-relativistic limit, in contrast to the Schrödinger equation which described wave functions of only one complex value. Moreover, in the limit of zero mass, the Dirac equation reduces to the Weyl equation. Although Dirac did not at first fully appreciate the importance of his results, the entailed explanation of spin as a consequence of the union of quantum mechanics and relativity—and the eventual discovery of the positron—represents one of the great triumphs of theoretical physics.
    [Show full text]
  • 5 the Dirac Equation and Spinors
    5 The Dirac Equation and Spinors In this section we develop the appropriate wavefunctions for fundamental fermions and bosons. 5.1 Notation Review The three dimension differential operator is : ∂ ∂ ∂ = , , (5.1) ∂x ∂y ∂z We can generalise this to four dimensions ∂µ: 1 ∂ ∂ ∂ ∂ ∂ = , , , (5.2) µ c ∂t ∂x ∂y ∂z 5.2 The Schr¨odinger Equation First consider a classical non-relativistic particle of mass m in a potential U. The energy-momentum relationship is: p2 E = + U (5.3) 2m we can substitute the differential operators: ∂ Eˆ i pˆ i (5.4) → ∂t →− to obtain the non-relativistic Schr¨odinger Equation (with = 1): ∂ψ 1 i = 2 + U ψ (5.5) ∂t −2m For U = 0, the free particle solutions are: iEt ψ(x, t) e− ψ(x) (5.6) ∝ and the probability density ρ and current j are given by: 2 i ρ = ψ(x) j = ψ∗ ψ ψ ψ∗ (5.7) | | −2m − with conservation of probability giving the continuity equation: ∂ρ + j =0, (5.8) ∂t · Or in Covariant notation: µ µ ∂µj = 0 with j =(ρ,j) (5.9) The Schr¨odinger equation is 1st order in ∂/∂t but second order in ∂/∂x. However, as we are going to be dealing with relativistic particles, space and time should be treated equally. 25 5.3 The Klein-Gordon Equation For a relativistic particle the energy-momentum relationship is: p p = p pµ = E2 p 2 = m2 (5.10) · µ − | | Substituting the equation (5.4), leads to the relativistic Klein-Gordon equation: ∂2 + 2 ψ = m2ψ (5.11) −∂t2 The free particle solutions are plane waves: ip x i(Et p x) ψ e− · = e− − · (5.12) ∝ The Klein-Gordon equation successfully describes spin 0 particles in relativistic quan- tum field theory.
    [Show full text]
  • Chapter 5 ANGULAR MOMENTUM and ROTATIONS
    Chapter 5 ANGULAR MOMENTUM AND ROTATIONS In classical mechanics the total angular momentum L~ of an isolated system about any …xed point is conserved. The existence of a conserved vector L~ associated with such a system is itself a consequence of the fact that the associated Hamiltonian (or Lagrangian) is invariant under rotations, i.e., if the coordinates and momenta of the entire system are rotated “rigidly” about some point, the energy of the system is unchanged and, more importantly, is the same function of the dynamical variables as it was before the rotation. Such a circumstance would not apply, e.g., to a system lying in an externally imposed gravitational …eld pointing in some speci…c direction. Thus, the invariance of an isolated system under rotations ultimately arises from the fact that, in the absence of external …elds of this sort, space is isotropic; it behaves the same way in all directions. Not surprisingly, therefore, in quantum mechanics the individual Cartesian com- ponents Li of the total angular momentum operator L~ of an isolated system are also constants of the motion. The di¤erent components of L~ are not, however, compatible quantum observables. Indeed, as we will see the operators representing the components of angular momentum along di¤erent directions do not generally commute with one an- other. Thus, the vector operator L~ is not, strictly speaking, an observable, since it does not have a complete basis of eigenstates (which would have to be simultaneous eigenstates of all of its non-commuting components). This lack of commutivity often seems, at …rst encounter, as somewhat of a nuisance but, in fact, it intimately re‡ects the underlying structure of the three dimensional space in which we are immersed, and has its source in the fact that rotations in three dimensions about di¤erent axes do not commute with one another.
    [Show full text]
  • Representations of U(2O) and the Value of the Fine Structure Constant
    Symmetry, Integrability and Geometry: Methods and Applications Vol. 1 (2005), Paper 028, 8 pages Representations of U(2∞) and the Value of the Fine Structure Constant William H. KLINK Department of Physics and Astronomy, University of Iowa, Iowa City, Iowa, USA E-mail: [email protected] Received September 28, 2005, in final form December 17, 2005; Published online December 25, 2005 Original article is available at http://www.emis.de/journals/SIGMA/2005/Paper028/ Abstract. A relativistic quantum mechanics is formulated in which all of the interactions are in the four-momentum operator and Lorentz transformations are kinematic. Interactions are introduced through vertices, which are bilinear in fermion and antifermion creation and annihilation operators, and linear in boson creation and annihilation operators. The fermion- antifermion operators generate a unitary Lie algebra, whose representations are fixed by a first order Casimir operator (corresponding to baryon number or charge). Eigenvectors and eigenvalues of the four-momentum operator are analyzed and exact solutions in the strong coupling limit are sketched. A simple model shows how the fine structure constant might be determined for the QED vertex. Key words: point form relativistic quantum mechanics; antisymmetric representations of infinite unitary groups; semidirect sum of unitary with Heisenberg algebra 2000 Mathematics Subject Classification: 22D10; 81R10; 81T27 1 Introduction With the exception of QCD and gravitational self couplings, all of the fundamental particle interaction Hamiltonians have the form of bilinears in fermion and antifermion creation and annihilation operators times terms linear in boson creation and annihilation operators. For example QED is a theory bilinear in electron and positron creation and annihilation operators and linear in photon creation and annihilation operators.
    [Show full text]
  • Second Quantization
    Chapter 1 Second Quantization 1.1 Creation and Annihilation Operators in Quan- tum Mechanics We will begin with a quick review of creation and annihilation operators in the non-relativistic linear harmonic oscillator. Let a and a† be two operators acting on an abstract Hilbert space of states, and satisfying the commutation relation a,a† = 1 (1.1) where by “1” we mean the identity operator of this Hilbert space. The operators a and a† are not self-adjoint but are the adjoint of each other. Let α be a state which we will take to be an eigenvector of the Hermitian operators| ia†a with eigenvalue α which is a real number, a†a α = α α (1.2) | i | i Hence, α = α a†a α = a α 2 0 (1.3) h | | i k | ik ≥ where we used the fundamental axiom of Quantum Mechanics that the norm of all states in the physical Hilbert space is positive. As a result, the eigenvalues α of the eigenstates of a†a must be non-negative real numbers. Furthermore, since for all operators A, B and C [AB, C]= A [B, C] + [A, C] B (1.4) we get a†a,a = a (1.5) − † † † a a,a = a (1.6) 1 2 CHAPTER 1. SECOND QUANTIZATION i.e., a and a† are “eigen-operators” of a†a. Hence, a†a a = a a†a 1 (1.7) − † † † † a a a = a a a +1 (1.8) Consequently we find a†a a α = a a†a 1 α = (α 1) a α (1.9) | i − | i − | i Hence the state aα is an eigenstate of a†a with eigenvalue α 1, provided a α = 0.
    [Show full text]
  • Angular Momentum 23.1 Classical Description
    Physics 342 Lecture 23 Angular Momentum Lecture 23 Physics 342 Quantum Mechanics I Monday, March 31st, 2008 We know how to obtain the energy of Hydrogen using the Hamiltonian op- erator { but given a particular En, there is degeneracy { many n`m(r; θ; φ) have the same energy. What we would like is a set of operators that allow us to determine ` and m. The angular momentum operator L^, and in partic- 2 ular the combination L and Lz provide precisely the additional Hermitian observables we need. 23.1 Classical Description Going back to our Hamiltonian for a central potential, we have p · p H = + U(r): (23.1) 2 m It is clear from the dependence of U on the radial distance only, that angular momentum should be conserved in this setting. Remember the definition: L = r × p; (23.2) and we can write this in indexed notation which is slightly easier to work with using the Levi-Civita symbol, defined as (in three dimensions) 8 < 1 for (ijk) an even permutation of (123). ijk = −1 for an odd permutation (23.3) : 0 otherwise Then we can write 3 3 X X Li = ijk rj pk = ijk rj pk (23.4) j=1 k=1 1 of 9 23.2. QUANTUM COMMUTATORS Lecture 23 where the sum over j and k is implied in the second equality (this is Einstein summation notation). There are three numbers here, Li for i = 1; 2; 3, we associate with Lx, Ly, and Lz, the individual components of angular momentum about the three spatial axes.
    [Show full text]
  • 13 the Dirac Equation
    13 The Dirac Equation A two-component spinor a χ = b transforms under rotations as iθn J χ e− · χ; ! with the angular momentum operators, Ji given by: 1 Ji = σi; 2 where σ are the Pauli matrices, n is the unit vector along the axis of rotation and θ is the angle of rotation. For a relativistic description we must also describe Lorentz boosts generated by the operators Ki. Together Ji and Ki form the algebra (set of commutation relations) Ki;Kj = iεi jkJk − ε Ji;Kj = i i jkKk ε Ji;Jj = i i jkJk 1 For a spin- 2 particle Ki are represented as i Ki = σi; 2 giving us two inequivalent representations. 1 χ Starting with a spin- 2 particle at rest, described by a spinor (0), we can boost to give two possible spinors α=2n σ χR(p) = e · χ(0) = (cosh(α=2) + n σsinh(α=2))χ(0) · or α=2n σ χL(p) = e− · χ(0) = (cosh(α=2) n σsinh(α=2))χ(0) − · where p sinh(α) = j j m and Ep cosh(α) = m so that (Ep + m + σ p) χR(p) = · χ(0) 2m(Ep + m) σ (pEp + m p) χL(p) = − · χ(0) 2m(Ep + m) p 57 Under the parity operator the three-moment is reversed p p so that χL χR. Therefore if we 1 $ − $ require a Lorentz description of a spin- 2 particles to be a proper representation of parity, we must include both χL and χR in one spinor (note that for massive particles the transformation p p $ − can be achieved by a Lorentz boost).
    [Show full text]
  • L the Probability Current Or Flux
    Atomic and Molecular Quantum Theory Course Number: C561 L The Probability Current or flux 1. Consider the time-dependent Schr¨odinger Equation and its complex conjugate: 2 ∂ h¯ ∂2 ıh¯ ψ(x, t)= Hψ(x, t)= − 2 + V ψ(x, t) (L.26) ∂t " 2m ∂x # 2 2 ∂ ∗ ∗ h¯ ∂ ∗ −ıh¯ ψ (x, t)= Hψ (x, t)= − 2 + V ψ (x, t) (L.27) ∂t " 2m ∂x # 2. Multiply Eq. (L.26) by ψ∗(x, t), andEq. (L.27) by ψ(x, t): ∂ ψ∗(x, t)ıh¯ ψ(x, t) = ψ∗(x, t)Hψ(x, t) ∂t 2 2 ∗ h¯ ∂ = ψ (x, t) − 2 + V ψ(x, t) (L.28) " 2m ∂x # ∂ −ψ(x, t)ıh¯ ψ∗(x, t) = ψ(x, t)Hψ∗(x, t) ∂t 2 2 h¯ ∂ ∗ = ψ(x, t) − 2 + V ψ (x, t) (L.29) " 2m ∂x # 3. Subtract the two equations to obtain (see that the terms involving V cancels out) 2 2 ∂ ∗ h¯ ∗ ∂ ıh¯ [ψ(x, t)ψ (x, t)] = − ψ (x, t) 2 ψ(x, t) ∂t 2m " ∂x 2 ∂ ∗ − ψ(x, t) 2 ψ (x, t) (L.30) ∂x # or ∂ h¯ ∂ ∂ ∂ ρ(x, t)= − ψ∗(x, t) ψ(x, t) − ψ(x, t) ψ∗(x, t) (L.31) ∂t 2mı ∂x " ∂x ∂x # 4. If we make the variable substitution: h¯ ∂ ∂ J = ψ∗(x, t) ψ(x, t) − ψ(x, t) ψ∗(x, t) 2mı " ∂x ∂x # h¯ ∂ = I ψ∗(x, t) ψ(x, t) (L.32) m " ∂x # (where I [···] represents the imaginary part of the quantity in brackets) we obtain ∂ ∂ ρ(x, t)= − J (L.33) ∂t ∂x or in three-dimensions ∂ ρ(x, t)+ ∇·J =0 (L.34) ∂t Chemistry, Indiana University L-37 c 2003, Srinivasan S.
    [Show full text]
  • Hamilton Equations, Commutator, and Energy Conservation †
    quantum reports Article Hamilton Equations, Commutator, and Energy Conservation † Weng Cho Chew 1,* , Aiyin Y. Liu 2 , Carlos Salazar-Lazaro 3 , Dong-Yeop Na 1 and Wei E. I. Sha 4 1 College of Engineering, Purdue University, West Lafayette, IN 47907, USA; [email protected] 2 College of Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61820, USA; [email protected] 3 Physics Department, University of Illinois at Urbana-Champaign, Urbana, IL 61820, USA; [email protected] 4 College of Information Science and Electronic Engineering, Zhejiang University, Hangzhou 310058, China; [email protected] * Correspondence: [email protected] † Based on the talk presented at the 40th Progress In Electromagnetics Research Symposium (PIERS, Toyama, Japan, 1–4 August 2018). Received: 12 September 2019; Accepted: 3 December 2019; Published: 9 December 2019 Abstract: We show that the classical Hamilton equations of motion can be derived from the energy conservation condition. A similar argument is shown to carry to the quantum formulation of Hamiltonian dynamics. Hence, showing a striking similarity between the quantum formulation and the classical formulation. Furthermore, it is shown that the fundamental commutator can be derived from the Heisenberg equations of motion and the quantum Hamilton equations of motion. Also, that the Heisenberg equations of motion can be derived from the Schrödinger equation for the quantum state, which is the fundamental postulate. These results are shown to have important bearing for deriving the quantum Maxwell’s equations. Keywords: quantum mechanics; commutator relations; Heisenberg picture 1. Introduction In quantum theory, a classical observable, which is modeled by a real scalar variable, is replaced by a quantum operator, which is analogous to an infinite-dimensional matrix operator.
    [Show full text]