Beverage Clouding Agent Based on Carnauba Wax

Patentamt JEuropaischesJ) European Patent Office © Publication number: Q ^ g

Office europeen des brevets g 1

(45) Dateof publication of patent specification: 10.08.88 ® Int. CI.4: A 23 L 2/00

(zj) Application number: 84902485.6 @ Date of filing: 06.06.84 (88) International application number: PCT/US84/00887

® International publication number: WO 85/00005 03.01.85 Gazette 85/01

(54) BEVERAGE CLOUDING AGENT BASED ON CARNAUBA WAX.

(30) Priority: 15.06.83 US 504457 @ Proprietors The Coca-Cola Company 310 North Avenue Atlanta Georgia 30313 (US) (43) Date of publication of application: 03.07.85 Bulletin 85/27 (72) Inventor: KRUGER, Albert, Joseph, Jr. 649 Wheeling Avenue (§) Publication of the grant of the patent: Altamonte Springs, FL 32701 (US) 10.08.88 Bulletin 88/32 Inventor: JOHNSON, John, Kenneth 5888 Par Three Court Decatur, GA 30038 (US) (§) Designated Contracting States: BE CH DE FR LI SE @ Representative: Abitz, Walter, Dr.-lng. et al Abitz, Morf, Gritschneder, Freiherr von (58) References cited: Wittgenstein Postfach 86 01 09 GB-A-1 537 160 D-8000 Miinchen 86 (DE) GB-A-1 569 292 US-A-3 652291 US-A-3 658 552 CO US-A-3 660 105 US-A-3 959 510 00 US-A-3 988 512 US-A-4 093 750 US-A-4143174 CO US-A-4 187 326 to US-A-4 279 940 US-A-4 335 143 No relevant documents have been disclosed Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall a. be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been UJ paid. (Art. 99(1 ) European patent convention). Courier Press, Leamington Spa, England. 0 146 618 Description

The present invention relates to an edible stable clouding agent to be used in a beverage. More specifically, the invention relates to a stable clouding agent to be used in a beverage. More specifically, the 5 invention relates to a stable clouding agent comprised of a water soluble gum, carnauba wax, a polyhydric alcohol of two to six carbons, and an edible salt. Many natural juices, including all freshly expressed citrus juices, have a characteristic turbidity or "cloudiness." It is desirable to maintain this cloudiness when processing natural juices, and to emulate it when preparing formulated beverages. w In a natural citrus juice, "cloud" is provided by minute,suspended or colloidal particles of citrus tissue and cell contents. In formulated beverages, however, various "clouding agents" have been utilized to stimulate a natural cloud. For example, one known clouding agent is based on brominated oils of specific gravity greater than 1.00 g/ml in combination with lower density flavor oils or vegetable oil, such as citrus oils which have a specific gravity of about 0.85; see U.S. Patent No. 3,353,961, issued November 21, 1967 to 15 Simon. Such a blend of oils is "balanced" so as to have a density close to that of the beverage in which it is to be suspended. (As an example, sugar sweetened drinks have a preferred specific gravity of about 1.03 — 1.06 while dietetic drinks have a specific gravity of about 1.0.). By balancing the relatively low density flavor oil, such as citrus oils, with the high density brominated oil, it is possible to inhibit the highly insoluble citrus oils from floating to the top of the particular 2a formulated beverage and from forming a "ring." Instead, the dispersion of the balanced oil in aqueous solutions has a desirable cloudy appearance. However, brominated vegetable oils may now constitute only 15 ppm of a finished formulated beverage. This amount is about 10% of the concentration formerly used to prepare effective clouding agents. Consequently, brominated vegetable oils are now less effective as clouding agents. 25 As a substitute for brominated vegetable oils, the beverage industry generally turned to glyceryl abietate, or "Ester Gum", which is an F.D.A. approved oil-soluble material also of density greater than 1.00 g/ml; see U.S. Patent No. 3,959,510, issued May 25, 1976 to Felton and Kapp. Although glyceryl abietate, like brominated vegetable oils, can be effectively utilized to prepare an adequate clouding agent, it does have objectionable features. Since its specific gravity is 1.08 as compared to approximately 1.30 for 30 brominated vegetable oils, about three times as much Ester Gum is required to achieve the same degree of balancing as is achieved by use of brominated oils. If too much Ester Gum were used, the taste of the finished beverage could possess a bitter character which is often undesirable. Another difficulty arises from the fact that although both glycerol and abietic acid are natural products. Ester Gum is nevertheless produced synthetically from abietic acid, which precludes its use in those beverages which the producer 35 wishes to label as natural. A desirable clouding agent for use in a formulated beverage will avoid the difficulties associated with the aforementioned known clouding agents, as well as possess various other advantages. Specifically such a clouding agent would be non-toxic, impart little or no taste to the final beverage, and be effective in producing a non-ringing, cloudy beverage. Also important to such a desirable agent would be its ability to 40 produce a final cloudy beverage which is non-ringing for significant periods of time, specifically at least three months.

Disclosure of the invention The clouding agent of the present invention is an emulsified composition of finely divided particles of 45 carnauba wax, a water soluble gum, a polyhydric alcohol of two to six carbons, water, and an edible salt. An edible essential oil distillate such as orange oil distillate and additional resins such as gum elemi may also be incorporated. Important features of the invention include the size distribution of the carnauba wax particles, as well as the weight ratio of wax to alcohol and wax to salt. These features combine to produce the non-ringing stability of the final beverage cloud for periods of at least three months. so The wax particle size, as determined by Coulter Counter, is represented herein by specific interfacial area, which is the measured area in square meters of the oil/water interface per cubic centimeter of disperse phase. As the interfacial area increases, the particle size decreases. The wax particle size will range from an interfacial aera of 12.5 meterVcentimeter3 to 15.0 m2/cm3, and preferably from 13.0 to 13.6 m2/cm3. The weight ratio of wax to salt will be from 1:2 to 2:3 with 2:3 being preferred. The weight ratio of 55 carnauba wax to alcohol will be from 1 :4 to 1 :3, with 1 :4 being preferred. The carnauba wax will comprise 5.0 to 8.0, preferably about 6.0, percent by weight of the clouding agent. The water-soluble gum usually comprises 15.0 to 30.0, preferably 18.0 to 22.0, percent by weight of the emulsified clouding agent. The alcohol typically comprises 20.0 to 24.0, preferably about 22.0, percent by weight of the emulsion. The salt typically comprises 8.0 to 12.0, preferably about 9.0, percent by weight 60 of the emulsion. If an essential oil distillate is used, it may comprise up to about 3.0, preferably 1.0 to 2.0, percent by weight of the emulsion. Also, if a purified gum elemi is used, it may comprise up to about 6.0, preferably up to about 4.0, percent by weight of said emulsion. The water-soluble gum is preferably gum acacia. Other gums and suitable hydrocolloids may also be used. A preferred edible salt is sodium chloride. Another suitable salt is potassium chloride. 65 The polyhydric alcohol should have a chain length of two to six carbons, or alternatively, a molecular

2 0 146 618

weight up to 6b0. A preferred alcohol is glycerol although other suitable alcohols include propylene glycol and sorbitol. The clouding agent herein disclosed is an emulsion which is prepared by combining the wax with a heated solution of the other ingredients. If optional ingredients such as an essential oil distillate and/or 5 purified gum elemi are used, they are first blended with the carnauba wax. To form such a blend, the wax plus optional oil distillate and/or elemi are combined by heating the mixture to a temperature sufficient to melt the carnauba wax; usually a temperature of about 85°C will be sufficient. The wax or wax blend is then emulsified with a solution of water, water-soluble gum, alcohol and an edible salt. To perform the emulsification process, the homogeneous solution of water, a water-soluble gum, 10 alcohol, and an edible salt is prepared, then the solution is heated to a temperature sufficient to permit the wax or wax blend to melt when it is stirred into the solution. A temperature of 95 — 100°C is preferred. The resultant mixture of wax, water, alcohol, gum, and salt is subsequently emulsified by any conventional means capable of producing a final emulsion wherein the particle size of the carnauba wax is characterized by an interfacial area of 12.5 to 15.0 m2/cm3, preferably 13.0 to 13.6 m2/cm3. A preferred 15 method of emulsification involves the use of a conventional heat jacketed, 2 stage pressure homogenizer, maintained at a temperature between 92— 100°C, and a total pressure of 3000 to 7500 psig (2x107 to 5x107 Pa), preferably 4500 to 6000 psig (3x107 to 4x107 Pa). The emulsified clouding agent thus obtained is capable of being used in a number of ways well known in the beverage industry art. One example is to prepare a beverage syrup by mixing the clouding agent with 20 a sugar-in-water syrup and other conventional ingredients. Such a beverage syrup may in turn be converted into a final, cloudy beverage by the addition of still or carbonated water. This final, cloudy beverage will be stable against ring formation or settling out for periods of at least three months.

25 Best modes for carrying out the invention The clouding agent of the present invention provides several advantages over known clouding agents. For example, it imparts little or no taste a final beverage in which it is placed. Moreover, all of the ingredients of the agent are naturally-occurring and non-toxic. The clouding agent of the present invention is intended for use in the preparation of still or carbonated 30 aqueous beverages. A clouding agent prepared in accordance with the present disclosure, comprises in part carnauba wax. It has been found that other edible waxes, e.g. candela and bees wax, do not perform in a manner equivalent to the carnauba wax. Carnauba wax is a natural, non-toxic wax having a specific gravity of about 0.995 and a melting point of about 82— 86°C. Two types of carnauba wax are known— "raw" and "purified." 35 Both function equally well in the invention. The carnauba wax may optionally be blended with certain ingredients known in the art, such as an essential oil distillate, e.g. an orange distillate, and/or natural resins such as purified solid gum elemi, to produce a distillate-wax-resin blend having a density of 0.993 g/ml to 0.987 g/ml. If elemi is added, it is preferred that it be purified first so as to remove any volatile oils which would impart an undesirable taste 40 to the final product. The gum elemi which may be used in the present invention is derived from resins obtained from a tree of the Kanarium family. Although many kinds of elemi resins exist, they are all characterized by the constituent triterpene, amyline (C30H49OH), which, it is speculated, contributes to emulsion stability. Elemi resins and their purified fractions are non-toxic. t5 The elemi may be purified by resort to any of a number of conventional means such as distillation, extraction, chromatography and precipitation. For example, it may be steam distilled or it may be purified by solubilizing the natural gum elemi with 1.6 parts by weight isopropyl alcohol, isolating the non-soluble portion by filtration, and finally evaporating any alcohol in the filtrate to produce a purified elemi with a density of 1.02 g/ml and a melting point of 130— 142°C. If the jo carnauba wax is blended with purified elemi and/or an essential oil distillate, it is not necessary to heat the distillate-wax-resin combination beyond 79— 83°C in order to effect solution of the elemi and distillate into the carnauba wax. Upon cooling, such a blend will for a solid having a meltinq point of 68— 75°C. This distillate-wax-resin blend or the pure carnauba wax is then converted to a clouding agent >5 emulsion by emulsification with water, a water-soluble gum, preferably a preservative, alcohol and salt. The salt will typically be sodium chloride, however, any edible inorganic salt of alkali or alkaline earth metals and halides, or sulfate may be used in the present invention. The halide salts of the alkali metals are preferred, especially sodium and potassium chlorides. The emulsion is prepared by heating a homogeneous solution of the water, gum, alcohol and salt to a o temperature high enough to melt the carnauba wax or wax blend when it is added, preferably between 95— 100°C. The resultant mixture of wax and water, gum, alcohol and salt is then emulsified by any means sufficient to produce an emulsion in which the particle size of the carnauba wax is characterized by an interfacial area of 12.5 to 15.0 m2/cm3, preferably 13.0 to 13.6 m2/cm3. Methods of emulsification known in the art include simple stirring, aeration, propeller agitation, turbine agitation, use of a colloid mill, use of 5 ultrasonics, and homogenization. For a more detailed description of those various emulsification 0 146 618 methodologies, see Griffin, "Emulsions," in a 8 Kirk-Othmer Encyclopedia of Chemical Technology 900 — 930 (3d ed. 1979). One good emulsification technique is to employ a shear homogenizer. A preferred method involves the use of a conventional heat jacketed, 2 stage pressure homogenizer maintained at a temperature between 92 — 100°C (high enough to maintain the wax in its molten state) and a total pressure 5 of 3000 to 7500 psig (2x107 to 5x107 Pa), preferably 4500 to 6000 psig (3x107 to 4x107 Pa). Although the exact means by which the clouding agent functions is not known, it does not utilize the aforementioned "balancing" of a relatively low density oil with a heavier oil or gum in order to produce a blend having a density close to that of the beverage in which it is to be suspended. It is believed that the functioning of the clouding of the invention involves cooperation of the carnauba wax and salt plus 10 agent alcohol to form a "micelle-like" structure wherein a microparticle of carnauba wax is suspended in water as a consequence of being surrounded by the salt ions and/or hydrogen bonded alcohol molecules. While true micelles are much smaller than the microparticles of the carnauba wax, the cooperative behavior of the wax particles, salt and alcohol may be similar to that of true miscelles. Moreover, it is believed that the salt ions and alcohol produce an electrostatic effect around the wax particles, rather than functioning merely as solution density modifiers. This is because the ability of the clouding agent to avoid ringing decreases rather sharply outside the range of disclosed weight ratios of wax-to-salt and wax-to-alcohol. The clouding agent emulsion so produced may be used in a number of conventional ways. For example, it may be mixed with syrup (either sugar in water or artificial sweetener in water) and other 20 conventional ingredients to prepare a beverage syrup, which beverage syrup may in turn be converted into the final cloudy beverage by addition of still or carbonated water. Suggested concentrations of the clouding agent emulsion in the finished beverage correspond to about 0.05 — 0.20% by weight of the emulsion, based on the total weight of the final beverage. Such a suggested usage concentration range is only related to anticipated commercial desirability and in no way should be deemed a limitation on the effective 25 concentration of emulsion in an aqueous beverage. It also is possible to dry the clouding agent emulsion by such conventional methods as spray, freeze drum, or foam-mat drying to form a dry mix having a moisture content no higher than about 5%. Such a dry mix may be optionally mixed with a solid edible acid, dry color, and/or sweetener to form a beverage powder, which may be converted to a final cloudy beverage by the addition of water. The nature of the present invention may be further understood by the following examples of specific embodiment. Unless stated otherwise, all proportions here and elsewhere are in weight percent, based on the weight of the final clouding agent emulsion.

35 Example 1 A carnauba wax, sodium chloride glycerol gum acacia clouding agent

Weight percent, based on the total weight of the clouding 40 Ingredients agent emulsion Water 40.00 Sodium Benzoate (a preservative) 0.20 45 Sodium Chloride 9.00 Glycerol 22.80 Spray-dried gum acacia 20.00 Carnauba wax 6.00 Orange oil distillate 2.00 50 The carnauba wax was melted at a temperature of about 79— 83°C. While the molten wax was kept at a temperature sufficient to maintain it in its molten state, the orange oil distillate was stirred into the molten wax in orderto solubilize it. The heat source was subsequently removed to allow the distillate-wax blend to solidify. The blend had a melting point of 68— 75°C. 55 The final clouding agent emulsion was prepared by adding the water, preservative, salt, glycerol, and gum acacia together and stirring at room temperature to form a homogeneous solution. This solution, while continuously stirred, was heated to a temperature of between 95° to 100°C. While maintaining this temperature, the distillate-wax blend was stirred into said solution until the blend had melted, thereby forming a cloudifier premix. 60 This premix was then introduced into a conventional heat jacketed 2-stage pressure homogenizer maintained at a temperature of between 92 to 100CC, so that the cloudifier premix was a liquid during homogenization. The total homogenization pressure was 6000 psi (4x107 Pa). After homogenization, the cloudifier emulsion was cooled to room temperature. The resultant clouding agent had a specific gravity of about 1.20 at 25°C, as well as an interfacial area of 13.6 m2/cm3, created a stable long-lasting cloud when 65 utilized as part of an aqueous beverage, and imparted no significant taste.

4 0 146 618

Example 2 A carbnauba wax clouding agent containing citric acid

Weight percent, based on the 5 total weight of the clouding Ingredient agent emulsion Water 40.25 Sodium Benzoate 0.10 io Glycerol 20.00 Citric Acid 0.13 Sodium Chloride 9.00 Gum acacia 20.00 Carnauba wax 7.89 15 . Orange oil distillate 2.63

The carnauba wax and orange oil distillate were combined in the same fashion as in Example 1. The distillate-wax blend was then combined with the remaining ingredients also as in Example 1 to form a clouding agent having an interfacial area of 12.4 m2/cm3 and showing good stability when used in an 20 aqueous beverage.

Example 3 A carnauba wax clouding agent outside the invention

25 Weight percent, based on the total weight of the clouding Ingredient agent emulsion

Orange oil distillate 2.63 30 Carnauba wax 7.89 Water 44.25 Sodium benzoate 0.10 Citric Acid 0.13 Spray-dried gum acacia 20.00 35 Glycerol 20.00 Sodium Chloride 5.00

The ingredients were generally combined as in Example 1 to form an emulsion, however the homogenization parameters were adjusted so that the interfacial area of the final emulsion was only 11.4 40 m2/cm3, which is outside the scope of the present invention. This clouding agent, when utilized as part of an aqueous beverage, produced a cloud which was not long-lasting, but rather was stable only for about 5 days.

Claims 45 1. An edible clouding agent which comprises finely divided carnauba wax particles in an emulsion base comprising water, a water-soluble gum, a polyhydric alcohol of two to six carbons chosen from the group consisting of propylene glycol, sorbitol, glycerol and combinations thereof and an edible salt, wherein the size of the wax particles is characterized by an interfacial area of 12.5 m2/cm3 to 15.0 m2/cm3, wherein the so weight ratio of wax to salt is 1:2 to 2:3, and the weight ratio of wax to alcohol is 1:4 to 1:3. 2. An edible beverage clouding agent of claim 1, wherein the salt is an alkali metal salt. 3. An edible beverage clouding agent of claim 1 , wherein the salt is sodium chloride and the polyhydric alcohol is glycerol. 4. An edible beverage clouding agent of claim 1, wherein the Carnauba wax is blended with at least one 55 of the group consisting of purified gum elemi and an essential oil distillate. 5. An edible beverage clouding agent of claim 1 or 4 wherein the emulsion base further comprises a preservative. 6. An edible beverage clouding agent of claim 4 wherein the essential oil distillate is a natural orange oil distillate. 60 7. An edible beverage clouding agent of claim 5 wherein the preservative is sodium benzoate. 8. An edible beverage clouding agent of claim 1 wherein the water-soluble gum is gum acacia. 9. An edible beverage clouding agent of claim 1, comprising the following:

5 0 146 618 Weight percent, based on the Ingredient total weight of ingredients

water 40.00 Preservative 0.20 Sodium Chloride 9.00 Glycerol 22.80 Gum acacia 20.00 Carnauba wax 6.00 Orange oil distillate 2.00

10. An edible beverage clouding agent comprising the following:

Weight percent, based on the Ingredient total weight of ingredients

Water 40.25 Preservative 0.10 Glycerol 20.00 Citric Acid 0.13 Sodium Chloride 9.00 Gum acacia 20.00 Carnauba wax 7.89 Orange oil distillate 2.63

11. A beverage syrup comprising a beverage clouding agent of claims 1 and 10 comprising 0.05—0.20 percent by weight of the total weight of the beverage and flavored syrup. 12. A cloudy beverage, comprising a beverage syrup of claim 11 and still or carbonated water. 13. A clouding agent of claim 1, wherein the agent has been dried to form a dry mix having a moisture content no higher than about 5%. 14. A process of preparing a beverage clouding agent, comprising the steps of heating a homogeneous solution of water, a water-soluble gum, a polyhydric alcohol of two to six carbons chosen from the group consisting of propylen glycol, sorbitol, glycerol and combinations thereof and an edible salt to a temperature sufficient to melt carnauba wax, stirring in carnauba wax until melted, and finally emulsifying the entire mixture to produce an emulsion having a wax interfacial area of 12.5 m2/cm3 to 15.0 m2/cm3. 15. A process of preparing a beverage clouding agent, comprising the steps of heating a homogeneous solution of water, a water-soluble gum, a polyhydric alcohol of two to six carbons chosen from the group consisting of propylen glycol, sorbitol, glycerol and combinations thereof and an edible salt to a temperature of 92— 100°C stirring in carnauba wax until melted, and finally homogenizing the entire mixture in a heat jacketed, 2 stage pressure homogenizer, maintained at a temperature between about 95 — 100°C, and also having a total pressure of between 3000—7500 psi (2x107 to 5x107 Pa). 16. A process of claim 15, wherein the weight ratio of wax to salt is 1 :2 to 2:3 and the weight ratio of wax to alcohol is 1:4 to 1:3. 17. A process of claim 15 wherein, prior to mixing with the other ingredients, the Carnauba wax is blended with at least one compound selected from the group consisting of an essential oil distillate and purified gum elemi. 18. A process of preparing a beverage syrup as defined in claim 11, comprising the step of adding a clouding agent emulsion of claim 1 to a flavored syrup. 19. A process of preparing a cloudy beverage as defined in claim 12, comprising the step of adding still or carbonated water to the beverage syrup of claim 11. 20. A process of preparing a cloudy beverage comprising the steps of drying a beverage clouding agent of claims 1 and 10 to form a dry mix having a moisture content no higher than about 5%, optionally mixing therewith a solid edible acid, dry color, and/or sweetener to form a beverage powder, and finally converting said powder to a cloudy beverage by the addition of water. 21 . A dry beverage powder prepared by drying a beverage clouding agent of claims 1 and 10 to form a dry mix having a moisture content no higher than about 5%, and optionally mixing therewith a solid edible acid, dry color and/or sweetener. Patentanspruche

1. Geniessbares Trubungsmittel, enthaltend fein verteilte Carnaubawachs-Teilchen in einer Emulsionsbasis, die Wasser, ein wasserlosliches Gummi, einen mehrwertigen Alkohol mit zwei bis sechs Kohlenstoffen, ausgewahlt aus der Gruppe, bestehend aus Propylenglykol, Sorbit, Gycerin und Kombinationen davon, und ein geniessbares Salz enthalt, worin die Grosse der Wachsteilchen 0 146 618

gekennzeichnet ist durch eine Grenzflache von 12,5 m2/cm3 bis 15,0 m2/cm3, wobei das Gewichtsverhaltnis von Wachs zu Salz etwa 1 :2 bis 2:3 und das Gewichtsverhaltnis von Wachs zu Alkohol 1 :4 bis 1 :3 betragt. 2. Geniessbares Trubungsmittel fiir Getranke nach Anspruch 1, in dem das Salz ein Alkalisalz ist. 3. Geniessbares Trubungsmittel fiir Getranke nach Anspruch 1, in dem das Salz Natriumchlorid ist und 5 der mehrwertige Alkohol Glycerin ist. 4. Geniessbares Trubungsmittel fiir Getranke nach Anspruch 1, worin das Carnaubawachs vermischt ist mit mindestens einem aus der Gruppe von gereinigtem Elemi-Gummi und einem Destillat von etherischem Ol. 5. Geniessbares Trubungsmittel fur Getranke nach Anspruch 1 oder 4, worin die Emulsionsbasis 10 daruber hinaus ein Konservierungsmittel enthalt. 6. Geniessbares Trubungsmittel fiir Getranke nach Anspruch 4, worin das etherische Ol-Destillat ein natiirliches Orangenol-Destiliat ist. 7. Geniessbares Trubungsmittel fiir Getranke nach Anspruch 5, worin das Konservierungsmittel Natriumbenzoat ist. 15 8. Geniessbares Trubungsmittel fiir Getranke nach Anspruch 1, worin das wasserlosliche Gummi Gummi Arabikum ist. 9. Geniessbares Trubungsmittel fiir Getranke nach Anspruch 1, umfassend das folgende: Gew.%, basierend auf dem 20 Bestandteil . Gesamtgewicht der Bestandteile Wasser 40,00 Konservierungsmittel 0,20 Natriumchlorid 9,00 25 Glycerin 22,80 Gummi Arabikum 20,00 Carnaubawachs 6,00 Orangenol-Destiliat 2,00

JU 10. Geniessbares Trubungsmittel fur Getranke, umfassend das folgende:

Gew.%, basierend auf dem Bestandteil Gesamtgewicht der Bestandteile

« Wasser 40,25 Konservierungsmittel 0,10 Glycerin 22,00 Zitronensaure 0,13 Natriumchlorid 9,00 *° Gummi Arabikum 20,00 Carnaubawachs 7,89 Orangenol-Destiliat 2,63

n. (jetrankesirup, enthaltend em Getranketrubungsmitte! nach den Anspriichen 1 und 10 in einer w Menge von 0,05 — 0,20 Gew.% des Gesamtgewichts von Getrank und aromatisiertem Sirup. 12. Trubes Getrank, umfassend einem Getrankesirup nach Anspruch 11 und stilles oder kohlensaurehaltiges Wasser. 13. Trubungsmittel nach Anspruch 1, in dem das Mittel unter Bildung eines trockenen Gemisches mit einem Feuchtigkeitsgehalt von nicht grosser als etwa 5% getrocknet wurde. '° 14. Verfahren zur Herstellung eines Triibungsmittels fiir Getranke, umfassend die Stufen des Erwarmens einer homogenen Losung von Wasser, einem wasserloslichen Gummi, einem mehrwertigen Alkohol mit zwei bis sechs Kohlenstoffen, ausgewahlt aus der Gruppe, bestehend aus Propylenglykol, Sorbit, Glycerin und Kombinationen davon, und einem geniessbaren Salz, auf eine ausreichende Temperatur, urn Carnaubawachs zu schmelzen, Einruhren von Carnaubawachs, bis es geschmolzen ist, _5 und schliesslich Emulgieren des gesamten Gemischs, urn eine Emulsion mit einer Wachsgrenzflache von 12,5 m2/cm3 bis 15,0 m2/cm3 zu erzeugen. 15. Verfahren zur Herstellung eines Triibungsmittels fiir Getranke, umfassend die Stufen des Erwarmens einer homogenen Losung von Wasser, einem wasserloslichen Gummi, einem mehrwertigen >o Alkohol mit zwei bis sechs Kohlenstoffen, ausgewahlt aus der Gruppe, bestehend aus Propylenglykol, Sorbit, Glycerin und Kombinationen davon, und einem geniessbaren Salz, auf eine Temperatur von 92— 100°C, Einruhren von Carnaubawachs, bis es geschmolzen ist, und schliesslich Homogenisieren des gesamten Gemischs in einem mit Warmemantel versehenen 2-Stufen-Druckhomogenisator, der bei einer Temperatur zwischen etwa 95— 100°C gehalten wird und auch einem Gesamtdruck von zwischen ?5 3000—7500 psi (2x107 bis 5x107 Pa) hat.

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16. Verfahren nach Anspruch 15, bei dem das Gewichtsverhalnis von Wachs zu Salz 1 :2 bis 2:3 betragt und das Gewichtsverhaltnis von Wachs zu Alkohol 1:4 bis 1:3 betragt. 17. Verfahren nach Anspruch 15, bei dem vor dem Vermischen mit den anderen Bestandteilen das Carnaubawachs mit mindestens einer Verbindung vermischt wird, die ausgewahlt ist aus der Gruppe von einem etherischen Ol-Destillat und gereinigtem Elemi-Gummi. 18. Verfahren zur Herstellung eines Getrankesirups, wie in Anspruch 1 1 definiert, umfassend die Stufe des Zusatzes einer Trubungsmittelemulision nach Anspruch 1 zu einem aromatisierten Sirup. 19. Verfahren zur Herstellung eines triiben Getranks, wie in Anspruch 12 definiert, umfassend die Stufe des Zusatzes von stillem oder kohlensaurehaltigen Wasser zu dem Getrankesirup von Anspruch 11. 20. Verfahren zur Herstellung eines triiben Getranks, umfassend die Stufen des Trocknens eines Trubungsmittels fiir Getranke nach den Anspriichen 1 und 10, zur Bildung eines trockenen Gemischs mit einem Feuchtigkeitsgehalt von nicht grosser als etwa 5%, gegebenenfalls Vermischen damit von einer festen, geniessbaren Saure, trockener Farbe und/oder Siissungsmittel zur Bildung eines Getrankepulvers, und schliesslich Umwandeln des Pulvers in ein triibes Getrank, durch Zusatz von Wasser. 21. Trockenes Getrankepulver, hergestellt durch Trockenen eines Trubungsmittels fiir Getranke nach den Anspriichen 1 und 10 unter Bildung eines trockenen Gemischs mit einem Feuchtigkeitsgehalt von nicht grosser als etwa 5% und gegebenenfalls Vermischen damit von einer festen, geniessbaren Saure, trockener Farbe und/oder Siissungsmittel.

Revendications

1. Un agent de trouble comestible pour boissons qui comprend de fines particules de cire de carnauba dans une emulsion de base comprenant de I'eau, une gomme hydrosoluble, un polyol ayant de deux a six atomes de carbone, pris parmi le propylene glycol, le sorbitol, le glycerol et des melanges de ces polyols, et un sel comestible, dans lequel la dimension des particles de la cite est caracterisee par une surface interfaciale de 12,5 m2/cm3 a 15,0 m2/cm3, le rapport ponderal de la cire au sel etant compris entre 1 :2 et 2:3 et le rapport ponderal de la cire a I'alcool entre 1:4 et 1:3. 2. Agent de trouble pour boissons selon la revendication 1 , dans lequel le sel est un sel de metal alcalin. 3. Agent de trouble selon la revendication 1 dans lequel le sel est de chlorure de sodium et le polyol est le glycerol. 4. Agent de trouble selon la revendication 1 dans lequel la cire de carnauba est melangee avec de la gomme d'elemi purifiee ou un distillat d'huiles essentielles ou avec les deux a la fois. 5. Agent de trouble selon la revendication 1 ou 4 dans lequel I'emulsion comprend egalement un agent de conservation. 6. Agent de trouble selon la revendication 4 dans lequel le distillat d'huiles essentielles est un distillat d'essence d'orange naturelle. 7. Agent de trouble selon la revendication 5 dans lequel I'agent de conservation est du benzoate de sodium. 8. Agent de trouble selon la revendication 1 dans lequel la gomme hydrosoluble est de la gomme arabique. 9. Agent de trouble selon la revendication 1, comprenant les ingredients suivants:

Pourcentages ponderaux rapportes au poids total ingredients des ingredients

Eau 40,00 Agent de conservation 0,20 Chlorure de sodium 9,00 Glycerol 22,80 Gomme arabique 20,00 Cire de carnauba 6,00 Distillat d'essence d'orange 2,00

10. Agent de trouble comestible pour boissons, comprenant les ingredients suivants:

8 0 146 618

Pourcentages ponderaux rapportes au poids total Ingredients des ingredients s Eau 40,25 Agent de conservation 0,10 Glycerol 22,00 Acide citrique 0,13 Chlorure de sodium 9,00 10 Gomme arabique 20,00 Cire de carnauba 7,89 Distillat d'essence d'orange 2,63

11. Sirup pour boisson comprenant un agent de trouble des revendications 1 et 10, et qui constitue de 15 0,05% a 0,20% du poids total de la boisson, et un sirup aromatise. 12. Une boisson trouble comprenant un sirup selon la revendication 11 avec de I'eau ordinaire ou de I'eau gazeuse. 13. Agent de trouble selon la revendication 1 qui a ete seche de maniere a donner un melange sec dont la teneur en humidite ne depasse par 5% environ. 20 14. Un procede de preparation d'un agent de trouble pour boissons selon lequel on chauffe une solution homogene comprenant de I'eau, une gomme hydrosoluble, un polyol ayant de 2 a 6 atomes de .carbone pris parmi le propylene glycol, le sorbitol, le glycerol et des melanges de ces polyols, et un sel comestible, a une temperature suffisante pour fondre de la cire de carnauba, on agite la solution dans de la cire de carnauba jusqu'a ce que celle-ci soit fondue puis on emulsionne I'ensemble du melange pour en 25 former une emulsion dans laquelle la surface interfaciale de la cire est comprise entre 12,5 m2/cm3 et 15,0 m2/cm3. 15. Un procede de preparation d'un agent de trouble pour boissons selon. lequel on chauffe une solution homogene comprenant de I'eau, une gomme hydrosoluble, un polyol ayant de 2 a 6 atomes de carbone, pris parmi le propylene glycol, le sorbitol, le glycerol et des melanges de ces polyols, et un sel 30 comestible, a une temperature de 92 a 100°C, on agite ensuite la solution dans de la cire de carnauba jusqu'a ce que celle-ci soit fondue puis on homogeneise I'ensemble du melange dans un homogeneiseur sous pression a deux temps equipe d'une chemise de chauffage, qui est maintenu a une temperature d'environ 95 — 100°C, sous une pression totale de 2x107 a 5x107 Pa. 16. Procede selon la revendication 15 dans lequel le rapport ponderal de la cite au sel est compris entre 35 1:2 et 2:3 et le rapport ponderal de la cire a I'alcool entre 1:4 et 1:3. 17. Procede selon la revendication 15 dans lequel, avant de melanger la cire de carnauba avec les autres ingredients, on la melange avec un distillat d'huiles essentielles ou une gomme d'elemi purifiee ou avec les deux a la fois. 18. Un procede de preparation d'un sirop de boisson selon la revendication 11 consistant a ajouter une 40 emulsion d'un agent de trouble selon la revendication 1 a un sirop aromatise. 19. Un procede de preparation d'une boisson trouble selon la revendication 12, consistant a ajouter de I'eau ordinaire ou de I'eau gazeuse au sirop de boisson selon la revendication 11. 20. Un procede de preparation d'une boisson trouble selon lequel on seche un agent de trouble pour boissons des revendications 1 et 10 de maniere a avoir un melange sec dont la teneur en humidite ne 45 depasse pas 5% environ, avec lequel on melange eventuellement un acide comestible solide, un colorant sec et/ou un edulcorant pour obtenir une poudre pour boisson, avec laquelle on prepare une boisson trouble en lui ajoutant de I'eau. 21. Une poudre seche pour boissons qui a ete obtenue par sechage d'un agent de trouble des revendications 1 et 10 pour avoir un melange sec dont la teneur en humidite ne depasse pas 5% environ, et so melange eventuel de celui-ci avec un acide comestible solide, un colorant sec et/ou un edulcorant.