REVIEW ARTICLE Optical properties of gyroid structured materials: from photonic crystals to metamaterials James A. Dolan1;2;3, Bodo D. Wilts2;4, Silvia Vignolini5, Jeremy J. Baumberg3, Ullrich Steiner2;4 and Timothy D. Wilkinson1 1 Department of Engineering, University of Cambridge, JJ Thomson Avenue, CB3 0FA, Cambridge, United Kingdom 2 Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, CB3 0HE, Cambridge, United Kingdom 3 NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, CB3 0HE, Cambridge, United Kingdom 4 Adolphe Merkle Institute, University of Fribourg, Chemin des Verdiers 4, CH-1700 Fribourg, Switzerland 5 Department of Chemistry, University of Cambridge, Lensfield Road, CB2 1EW, Cambridge, United Kingdom E-mail:
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[email protected] Abstract. The gyroid is a continuous and triply periodic cubic morphology which possesses a constant mean curvature surface across a range of volumetric fill fractions. Found in a variety of natural and synthetic systems which form through self-assembly, from butterfly wing scales to block copolymers, the gyroid also exhibits an inherent chirality not observed in any other similar morphologies. These unique geometrical properties impart to gyroid structured materials a host of interesting optical properties. Depending on the length scale on which the constituent materials are organised, these properties arise from starkly different physical mechanisms (such as a complete photonic band gap for photonic crystals and a greatly depressed plasma frequency for optical metamaterials). This article reviews the theoretical predictions and experimental observations of the optical properties of two fundamental classes of gyroid structured materials: photonic crystals (wavelength scale) and metamaterials (sub- wavelength scale).