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Nesosilicate Garnet group A B Si O (nesosilicate) 3 2 3 12

Olivine (Mg,Fe)2SiO4 Diagnostic features: high hardness (6.5-7.5, usually harder than a knife), equant (isometric) habit, vitreous

luster, no distinct . series: Forsterite Mg2SiO4 - Fe2SiO4

NOTE: The use of parenthesis within a chemical formula indicates elements which may be found in variable Habit: equant, consisting of a dodecahedron, a trapezohedron or a combination of these (shown below). Faces proportions within a given structure. In , the tetrahedra are connected by either Mg2+ or may be striated. Fe2+ cations. Colour: highly variable with composition. Many garnets have compositions intermediate between the end- Diagnostic features: hard (6.5-7: harder than knife) but grains are easily detached from the rock; no cleavage but members listed below. (For the test, simply identify any member of this group as "garnet".) pronounced conchoidal ; colour is green but can tend towards yellow or brown. This mineral is found mostly in dark-coloured igneous rocks, like the Hawaiian basalts. Pyrope, Mg3Al2Si3O12 is usually deep red (typical of igneous rocks formed at great depths, under high pressure). 2+ Colour: A perfectly pure forsterite would be colourless. The presence of some Fe in most olivine is Almandine, Fe3Al2Si3O12 is red to black. responsible for its green colour. Fe-poor varieties can be yellow, and Fe-rich varieties can be brown. The Spessartine, Mn3Al2Si3O12 is brownish red to pink. yellow-green, gem-quality variety of olivine is known as . Grossular, Ca3Mg2Si3O12 is colourless to yellow, green or brown (common, often associated with ). Andradite, Ca3Fe2Si3O12 is found in shades of yellow, green or brown to black. Habit: its stubby prismatic crystals usually look like small grains disseminated through the rock. Uvarovite Ca3Cr2Si3O12 has an emerald-green colour.

Look alikes: epidote, diopside. Unlike epidote, green olivine is not found with . It lacks the twinning and prismatic cleavage that are commonly seen in diopside. Right: Garnet often occurs in schists, i.e. metamorphic rocks showing a strong foliation caused by the alignment of platy mica crystals or prismatic amphiboles.

Nesosilicate Nesosilicate

Topaz Al2SiO4(F, OH)2 Staurolite Fe2Al9O6(SiO4)4(OH) 2

Diagnostic features: high hardness (8), perfect basal {001} cleavage, and prismatic crystals with a rhombic cross-section. Diagnostic features: characteristic cross-shaped twins and crystal form, high hardness (7-7.5 is harder than a knife) and occurrence in metamorphic schists and gneisses. Habit: commonly euhedral (i.e. well-developed faces), in prismatic crystals terminated by dipyramids, {0kl} and {h0l} prisms and basal pinacoids. The faces of the vertical prism give each crystal its rhombic cross Habit: the {110} prism (see below) gives it a characteristic rhombic outline. Cruciform twins are common. section. These faces are commonly striated vertically. There is no distinct cleavage.

Colour: very variable, from colourless to pink, yellow, green or blue. Rarely dark. Colour: red brown to brownish black. Luster: vitreous to resinous when fresh, dull to earthy when altered or impure. Luster: vitreous, especially on a freshly broken cleavage face. Often found with garnet and mica in metamorphic rocks.

Topaz is a mineral formed by the fluorine-rich vapours given off during the last stages of crystallization of siliceous igneous rocks. It is found in cavities of silica-rich lavas (rhyolites) and , and in pegmatites (very coarse-grained ). Associated with quartz, mica and feldspar and commonly found with tourmaline, apatite and fluorite.

Nesosilicate Nesosilicate Sillimanite Al2SiO5 Andalusite Al2SiO5

This is one of three geologically important aluminosilicate polymorphs. Andalusite, sillimanite and kyanite are This is one of three geologically important aluminosilicate polymorphs. Andalusite, sillimanite and kyanite are identical in composition but the geometry of their internal arrangement is different. Sillimanite is an indicator of identical in composition but the geometry of their internal arrangement is different. Andalusite is an indicator of a medium- to high-grade of . low-pressure metamorphism. Diagnostic features: slender crystals with one direction of cleavage. Can be difficult to tell apart from . Diagnostic features: hard (7.5, harder than knife), prismatic crystals with nearly square cross-sections. Colour: A perfectly pure sillimanite would be colourless. The mineral is typically light-coloured, brown, pale- Colour: A perfectly pure andalusite would be colourless but the natural mineral can be anything from reddish green or white. tends to turn the surface rusty. brown to olive-green. The variety chiastolite includes carbon-rich material on some faces during its growth, giving rise to a cross-like pattern visible on cut and polished crystals (see below, on the left). Habit: long, slender crystals without clear terminations. Often in parallel groups, frequently fibrous.

Habit: usually forms distinct prismatic crystals, with nearly square cross-sections, terminated by {001}. The Hardness: 6-7 (scratches the knife sometimes). prismatic {110} cleavage is good but not perfect (not as obvious as in hornblende, for example). Look-alikes: Wollastonite, tremolite, anthophyllite can all crystallize as fibrous masses. Look-alikes: Orthoclase. Wollastonite and tremolite are frequently associated with calcite.

(below: sillimanite-garnet schist)

Nesosilicate + Mixed nesosilicate-sorosilicate Kyanite Al2SiO5

Epidote Ca2(Al,Fe)Al2O(SiO4)(Si2O7)(OH) This is one of three geologically important aluminosilicate polymorphs. Andalusite, sillimanite and kyanite are identical in composition but the geometry of their internal arrangement is different. Kyanite is generally an Diagnostic features: moderately high hardness (6-7: harder than knife); perfect platy cleavage parallel to the b indicator of high-pressure metamorphism. axis; peculiar green colour.

Diagnostic features: blue colour, bladed crystals, good cleavage and different hardness in different directions. Colour: a peculiar yellow-green or pistachio-green that often distinguishes from other that it may resemble. Habit: long, tabular or bladed crystals with perfect {100} cleavage. Habit: tabular or prismatic monoclinic crystals are commonly elongated and striated parallel to the b axis. Hardness: 5 parallel to the length of the crystals, 7 at right angle to the length. Look-alikes: Olivine, augite. Unlike green olivine, epidote can be found with quartz. The many edges of faces give the epidote crystals the appearance of being striated along their long axis. Colour: usually blue, with different shades from rim to center. Luster is vitreous to pearly. Epidote is an abundant and widespread metamorphic mineral, occurring in calcium-rich rocks derived from impure or in igneous rocks. Clinozoisite is a pale coloured variety of epidote that has very little Fe; it Look-alikes: none. occurs as a secondary mineral in metamorphosed igneous rocks.

Cyclosilicate (ring silicate) Cyclosilicate (ring silicate)

Beryl, Be3Al2Si6O18 Tourmaline (Na,Ca)(Li, Mg, Al)3(Al, Fe, Mn)6(BO3)3Si6O18(OH)4 Diagnostic features: high hardness (7.5-8, harder than quartz and knife), hexagonal prismatic habit, and a poor platy cleavage.

Diagnostic features: high hardness (7-7.5, can be harder than quartz but always harder than the knife), trigonal Habit: hexagonal prisms terminated by a pinacoid (less commonly by dipyramidal faces) are common. prismatic habit with a slightly rounded triangular section, conchoidal fracture. Striations, when present, are parallel to the long axis of the prism. Habit: trigonal prisms, often terminated by trigonal pyramids. The prism is usually vertically striated. Colour: usually bluish green or light yellow, but it may be emerald green, pink, white or colourless. Colour: can take a wide range of colours. One of the most common variety is schorl, coloured black by Fe. Various names are given to gem-quality crystals: AQUAMARINE is the clear blue-green variety, coloured by Pink tourmaline is elbaite, coloured by Li. There are many more. Tourmaline sometimes varies in colour from small amounts of Fe, EMERALD is coloured deep green by chromium or vanadium, MORGANITE is pale pink one end of the prism to another, or from the core to the rim. Crystals that are pink inside with a green outer rim to deep rose, and GOLDEN BERYL is clear yellow. (You do not need to remember these variety names for the are sometimes called “watermelon” tourmaline. test.)

Look-alikes: beryl, apatite.

Inosilicate Inosilicate

(single-chain ) pyroxenes (single-chain silicates)

Augite: (Ca,Na)(Fe,Mg,Al)(Al,Si)2O6 series: Diopside CaMgSi2O6 - Hedenbergite CaFeSi2O6

Diagnostic features: stubby prismatic habit with an octogonal cross-section, moderate hardness (5.5, about same as a steel blade) and dark colour (deep green to black). Cleavage is imperfect, at angles of 87° and 93°. Diagnostic features: prismatic habit, octogonal section, moderate hardness (5.5, about same as knife) and colour

(white to green). Cleavage is imperfect, at angles of 87° and 93°. A well-developed parting parallel to the basal Habit: stubby prismatic crystals very similar to those of diopside. The cross section seen perpendicular to the pinacoid c is sometimes visible. prism is often eight-sided, because the faces m, a and b in the prism zone make angles of nearly 45° with each

other. Habit: prismatic crystals are common. The cross section seen perpendicular to the prism is usually eight-sided, because the faces m, a and b in the prism zone make angles of nearly 45° with each other. Colour: deep green to black. Its luster is rarely as vitreous as that of hornblende.

Cleavage: prismatic, parallel to the length of the prisms, at angles of 87° and 93°. Colour: white to green, varying with the amount of Fe present. : colourless (unless the mineral contains inclusions of oxide minerals). Cleavage: prismatic, parallel to the length of the prisms, at angles of 87° and 93°.

Look-alikes: altered or smaller crystals can be mistaken for olivine (lacks good cleavage) and/or augite (usually darker).

Inosilicate Inosilicate

Pyroxenes (single-chain silicates) Amphiboles (double-chain silicates)

Spodumene: LiAlSi2O6 Anthophyllite (Mg, Fe)7Si8O22 (OH) 2

Diagnostic features: flattened prismatic habit, vertical striations and light colour. The crystal surface alters Diagnostic features: "clove-brown" colour (i.e. beige brown like clove, the spice) and easily, giving it a dull, woody aspect which is very different from the vitreous luster of a fresh parting surface. often softer than its "official" hardness (5.5-6: barely scratched by a knife) because it Be careful: it is easy to mistake one cleavage direction and the parting with the angle typical of amphiboles. alters so easily to ,. Prismatic to fibrous habit (fairly similar to those of actinolite and tremolite). The perfect prismatic cleavage of amphibole (two planes at angles of Habit: prismatic crystals, often flattened on {100} and usually deeply striated vertically. Parting (a smooth 124° and 56°) gives a “splintery” look to broken surfaces. surface along which the crystal has broken) is sometimes well developed on {100}, the largest parallelohedron on the drawing below. Habit: prismatic to fibrous. The crystals are generally too small to recognize the cleavage angle or rhombic cross section. Hardness: 6.5-7 (harder than knife, but possible softer on weathered surfaces). Colour: beige to brown, less commonly shades of green. Luster should be vitreous but is often pearly or silky Colour: typically light coloured but in various shades of gray, yellow, green or pink. Among the gem varieties, because the mineral is partly altered to talc. kunzite is lilac and hiddenite is emerald-green.

As in all amphiboles, the prismatic cleavage NOTE: its unusual composition, i.e. the presence of lithium, is due to the composition is parallel to the direction of elongation of of watery fluids concentrated in the last stages of crystallization of a . the crystal. Spodumene generally crystallizes from this magmatic waters with other Li-bearing minerals like rubellite (a variety of pink tourmaline) and lepidolite.

Inosilicate Inosilicate

amphiboles (double-chain silicates) amphiboles (double-chain silicates)

Tremolite, Ca2Mg5Si8O22 (OH) 2 Hornblende, NaCa2(Mg, Fe, Al)5(Si, Al)8O22 (OH) 2 - Actinolite, Ca2Fe5Si8O22 (OH) 2 Diagnostic features: moderate hardness (5-6: barely scratched by a knife), perfect Diagnostic features: moderate hardness (5-6: barely scratched by a knife), perfect prismatic cleavage (two planes at angles of 124° and 56°) which gives a “splintery” prismatic cleavage (with angles of 124° and 56°) gives a “splintery” look to broken look to its broken surfaces. Found as prismatic crystals, dark green to black. surfaces. Found in prismatic crystals, sometimes bladed. Habit: prismatic crystals with a six-sided, nearly rhombic cross section. Colour: varies with iron content. Pure tremolite is white but even a small amount of iron gives it a greenish tinge. The green colour of pure actinolite is so dark that the crystals looks black. Luster, generally Colour: dark green to black. Vitreous luster. vitreous. Silky in fibrous varieties. Habit: Slender bladed prisms or fibrous radiating bunches. Streak: white (colourless, unless the mineral contains small inclusions of opaque oxide minerals).

Cleavage: Obvious parallel to their lengths; the two sets intersect at nearly 120º on basal sections Look-alikes: augite. Hardness: should be moderate (5-6). May be difficult to test because the crystals tend to break or detach rather than powder. Both minerals alter easily to talc which is much softer. Hornblende is the most common of the amphiboles and occurs in a variety of igneous rocks. Look-alikes (Actinolite): Hornblende. Look-alikes (Tremolite): Anthophyllite, sillimanite and wollastonite. The prismatic cleavage is parallel to the direction of elongation of the crystal.

Inosilicate Phyllosilicate amphiboles (double-chain silicates) Talc Mg3Si4O10(OH) 2

Glaucophane NaCa2(Mg, Fe, Al)5(Si, Al)8O22 (OH) 2 Diagnostic features: low hardness (1: softest on Moh’s scale, scratched by fingernail), soapy feel and pearly luster.

Diagnostic features: blue colour and fibrous habit. Habit: crystals are rare. Found most commonly in foliated or compact masses. When talc separates in plates, the plates are not elastic, i.e. once it has been bent, the plate does not snap back. Habit: slender acicular crystals (with typical amphibole cleavage) or an asbestiform (i.e. flexible fibers) habit. Colour: white, gray or greenish. Its luster is non-metallic and often described as pearly or silky. Colour: blue colour. Silky luster when asbestiform, vitreous when acicular. Look-alikes: Serpentine and fine grained muscovite (sericite). Hardness: 6 (same or slightly harder than a knife) but cannot be tested accurately on asbestiform samples! Soapstone, used for carving, is a rock largely made of compact, fine-grained Occurrence: found mostly in high-pressure metamorphic rocks (once buried deep in subduction zones), but also talc. seen in some igneous rocks.

phyllosilicate phyllosilicate

chlorite group serpentine group

Chlorite (Mg, Fe)3(Si, Al)4O10(OH) 2·(Mg, Fe) 3(OH) 6 Antigorite/lizardite Mg3Si2O5(OH) 4

Diagnostic features: pale green colour appears when scratched, micaceous habit and cleavage, folia are not elastic. Diagnostic features: variegated green colour (i.e. not uniform) and greasy to waxlike luster. Habit: Large crystals are rare. Found most commonly as small scales dispersed in metamorphic rocks, giving them a greenish colour. The perfect {001} cleavage often makes it easy to detach small platelets by scraping the Habit: usually massive and fine-grained (the individual crystals cannot be distinguished). rock with the knife. Chlorite is often found as pseudomorphs of other ferromagnesian silicate minerals, and the crystals may be submicroscopic. Scratching the specimen will leave a pale green groove. Colour: often variegated, with mottling in lighter and darker shades of green.

Colour: various shades of green (pale to nearly black), depending on the relative amounts of Mg and Fe. Hardness: more variable than most minerals, 3-5 (usually 4) but softer than olivine (6.5-7).

Other properties: low hardness (2-2.5: close to fingernail). May be hard to test if small chloride crystals are The text calls these minerals polymorphs of (the fibrous mineral of this group), but crystallographers dispersed among harder minerals in a rock, or if a thin layer of chlorite covers a much harder mineral. would disagree. Recent techniques have shown that antigorite and lizardite differ slightly in composition and structure from chrysotile. However the differences are too subtle to be recognized in hand specimen. This is This mineral is a common product of the alteration of other ferromagnesian minerals (e.g., olivine, augite, why the more general term “serpentine” is used for hand specimens that contain either antigorite or lizardite. hornblende, actinolite and some garnets among those seen last week). The green colour of many igneous rocks is due to the alteration to chlorite of the original amphiboles (e.g. hornblende) and/or pyroxenes (e.g. augite) in Minerals of the serpentine group are a common alteration mineral of olivine and magnesian pyroxenes or these rocks. The green colour of many schists and slates (metamorphic rocks) is due to disseminated chlorite. amphiboles.

phyllosilicate phyllosilicate

serpentine group Muscovite, KAl2(AlSi3O10)(OH) 2

Chrysotile: Mg Si O (OH) Muscovite is also called white mica and potash mica. 3 2 5 4

Diagnostic features: micaceous habit; perfect platy cleavage; coloured in thick blocks but colourless and transparent in thin sheets. Low hardness (2-2.5). BE CAREFUL when handling CHRYSOTILE or ANY FIBROUS MINERAL. Any fibrous mineral will release microscopic fibers if it is scratched or shaken. Breathing mineral fibers or dust irritates the lung tissues. Habit: monoclinic, but euhedral crystals are rare and their cross-section is nearly rhombic or pseudo-hexagonal. Most commonly occurs in scales or sheets without any regular form, simply filling space between surrounding Diagnostic features: fibrous to asbestiform habit, greenish colour. minerals. When it occurs as compact masses of minute scales, as an alteration product of potassic feldspar, it is known as sericite. Habit: asbestiform (long, flexible fibers), usually interbedded with other massive minerals of the serpentine group. (The fibers actually consists of layer-like crystals rolled up like miniature carpets.) Colour: transparent and colourless in thin sheets. Thicker plates are commonly smoky brown but they may also be pink, yellow or green. You should detach plates from any dark mica to make sure that it is not this Fe-poor Colour: shades of green, pearly luster. mica.

Hardness: 3-4, but hard to test on asbestiform specimens because the fibers separate so easily.

This is a common alteration mineral of olivine and magnesian or amphibole. It is one of the minerals called "asbestos" (a general term for fibrous silicate minerals used in industry for fire- and earthquake-proofing materials), but probably the least harmful of them all because the fibers can dissolve in the lung fluids.

phyllosilicate

Lepidolite, K(Li, Al)2-3(AlSi3O10)(O, OH, F) 2 phyllosilicate

Biotite, KMg3(AlSi3O10)(OH) 2 Diagnostic features: micaceous habit and cleavage; pink to lilac colour in thick books but colourless and transparent in thin sheets. Low hardness (2-2.5). Diagnostic features: micaceous habit and cleavage; dark green or brown to black, even in thin sheets. Low hardness (2-2.5). Habit: monoclinic, but euhedral crystals are rare and their cross-section is nearly rhombic or pseudo-hexagonal. Found most commonly in coarse to fine-grained scaly aggregates. Habit: monoclinic, the cross-section of euhedral crystals is nearly rhombic or pseudo-hexagonal. Also commonly found in coarse to fine-grained scaly aggregates (in metamorphic schists and gneisses). Occurrence: lepidolite is a relatively rare mineral, found in pegmatites, and usually associated with other lithium-bearing minerals such as pink and green tourmaline and spodumene. Colour: varies with Fe content, from light yellow (rare) to deep green, brown or black. Thin sheets usually have a smoky colour (differing from the almost colourless muscovite and lepidolite). Luster is splendent (i.e. even brighter than vitreous) on fresh surfaces.

Occurrence: biotite is a common mineral, found in metamorphic rocks (schists and gneisses) and a wide range of igneous rocks. It is not found immediately next to muscovite or lepidolite (these other micas crystallize from rocks or than are iron-poor and more aluminous).

Tectosilicate Tectosilicate

The potassic feldspars: Orthoclase/microcline KAlSi3O8 Albite NaAlSi3O8 sodic feldspar/plagioclase:

Diagnostic features: moderately high hardness (6: barely scratched or harder than knife), two directions of cleavage that are mutually perpendicular (parallel to faces b and c), vitreous luster. Diagnostic features: moderately high hardness (6: barely harder than knife), two directions of cleavage mutually

perpendicular (parallel to faces b and c), vitreous luster, striations due to polysynthetic twinning. Habit: euhedral crystals have a tabular to prismatic habit.

Habit: euhedral crystals have a tabular to prismatic habit. Colour: very variable. Often pinkish or light orange but may also be white, pale yellow, reddish, greenish, or gray. The variety AMAZONITE has a blue-green colour related to the presence of small amounts of Pb. Colour: variable.

Most feldspars contain sodium as well as potassium and are part of the "alkali feldspar" series orthoclase Albite makes up the lighter-coloured veins of Na-felspar (albite, NaAlSi O ) that often separate from the KAlSi O -albite NaAlSi O . Once they crystallize from magma, feldspars of intermediate composition undergo 3 8 3 8 3 8 darker-coloured K-feldspar (orthoclase or microcline) during its cooling following igneous crystallization. We a chemical unmixing if they are allowed to cool slowly (in an intrusive rock, for example). The mineral already saw that this texture formed by two intergrown feldspar is called PERTHITE. separates into lighter and darker veins, giving rise to a characteristic texture called PERTHITE.

Microcline is the low-temperature version of orthoclase. The bonding angles within their structures are slightly different. Orthoclase and microcline cannot be told apart in hand specimen. Both names (and their synonym, "K-feldspar") will be accepted interchangeably on the test.

Tectosilicate Tectosilicate

Labradorite (Na~.5,Ca~.5)(Al~1.5,Si~2.5)O8 Quartz, SiO2

A member of the plagioclase series (sodic-calcic feldspar): There are several polymorphs of quartz. The most common one is “low-quartz” or “alpha-quartz” which crystallizes in class 32. Diagnostic features: moderately high hardness (6: barely harder than knife), two directions of cleavage mutually A higher-temperature form, "beta-quartz", crystallizes in class 622 but it inverts to alpha-quartz during cooling. Both will be perpendicular (parallel to faces b and c), vitreous luster, striations due to polysynthetic twinning, dark colour referred to as "quartz" during the laboratory exercises and mineral identification tests. and iridescence visible on {010} (i.e. the faces b). Diagnostic features: hardness (7: not scratched by knife), prismatic habit, conchoidal fracture, vitreous luster. Quartz always leaves a white streak, regardless of its colour (unless it contains inclusions of other minerals). Habit: euhedral crystals have a tabular to prismatic habit similar to that of albite. Habit: in euhedral (i.e. well-formed) crystals, the dominant form is generally a hexagonal prism with faces Colour: dark, due to minuscule inclusions of the mineral magnetite. The iridescence is due to the scattering of showing striations perpendicular to the c axis. The "pyramidal" ends are actually two rhombohedra (labelled light by minuscule lamellae that form during cooling of this feldspar after crystallization. The cause is an “r” and “z” on these drawings). In anhedral (i.e. without faces) specimens, the lack of cleavage and hardness are unmixing process (exsolution) of the same type as the one forming perthite in microcline. Here, the unmixing characteristic. gives rise to lamellae of Ca-rich feldspar (anorthite) in a Na-rich feldspar (albite), or vice-versa. Colour: highly variable, from transparent and colourless to black, with nearly every colour in between! Quartz is always very pure but minute amounts of certain impurities can give it vivid colours. Some colours can be modified by irradiation or heating because they are due to the presence of defects in the structure.

The names given to varieties of quartz having specific colours include: amethyst (purple), citrine (yellow), smoky quartz (dark brown), milky quartz (white). Chalcedony is a fibrous variety, often with a botryoidal habit.

Sulfide carbonate (rhombohedral)

Pyrite FeS2 Calcite CaCO3

Diagnostic features: pale brass yellow colour, relatively high hardness, streak is greenish to brownish black. Diagnostic features: noticeable reaction (effervescence) with HCl at room temperature, rhombohedral cleavage, moderate hardness (H = 3-3.5). Habit: crystals are often cubic, and usually striated (one direction on each face). Pyrite can also adopt other regular forms like octahedra and dodecahedra, and some crystals combine two or three forms. Poor Habit: highly variable but a three-fold or six-fold symmetry is often clearly visible. Crystals can be nearly cleavage. acicular or flattened plates. Most are combinations of rhombohedra and prism(s) or scalenohedra..

Colour: pale brass yellow (deeper if tarnished) and metallic luster. Colour: colourless when pure, but highly variable because of the presence of fluid inclusions, organic matter, inclusions of other minerals or substitution of Ca2+ ions by various impurities. Hardness: 6 (unusually high for a sulfide mineral). Cleavage fragments of limpid, colourless calcite crystals displays pronounced double Look-alikes: massive chalcopyrite and other yellow sulfides are easily confused with massive pyrite until your refraction. There is no double refraction if one looks through the crystal down its c eye becomes attuned to their distinctly different colours and hardness. axis.

This is the most common sulfide, found in sedimentary, metamorphic and igneous rocks as well as Calcite is the most common of two geologically important polymorphs of CaCO3. hydrothermal deposits.