SEEPL/EIA/F/IND/ALL /001/2017-18/00

Environmental Impact Assessment Report For Expansion of Pesticides, Chemical Intermediates Manufacturing and Formulation unit Of

M/s Astec LifeSciences Ltd Plot no. B-16, 17, 18, & 21, MIDC, , Raigad, . .

EIA Consultant

M/s Sadekar Enviro Engineers Pvt. Ltd.

QCI QCI-NABET Accredited EIA Consultancy for Schedule 5 (b) Cat ‘A’. Certificate No – NABET/EIA/1518/RA 020

NABL Accredited Laboratory, Valid up to 29.06.2020 Lab. Recognized by MoEFCC, GOI, Valid up to 2.01.2019 Certified by ISO 9001:2008 & BS OHSAS 18001:2007

310, Dempo Towers, EDC Patto, Panaji, state, India. PIN: 403001 Email : [email protected] / [email protected] Web site:-www.sadekarenviro.com Telephone : 0832-2437048/ 2437164

Baseline monitoring period: December 2017 to February 2018 December, 2018

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Project Team

Project Team

Declaration by Experts contributingto the EIA of M/s. Astec LifeSciences Ltd. I, hereby, certify that I was a part of the EIA Team in the following, capacity that developed the above EIA

EIA Coordinator : 5 (b) Name : Mr. P.R Sadekar

Signature & Date :

Period of Involvement: Oct. 2017 to till EIA completion

Contact Information : [email protected]

Functional Area Experts: Sr. Involveme Function Name of the Name of the No nt Period Signature & Date al Areas Expert/s Team Member/s . & Task Oct. 2017

till date Mr. P.R. Task: 1 HG -- Impact Sadekar Assessment of HG Oct. 2017 till 15th June 2018 Mr. Vinay Task: 2 AP -- Gupta Impact Assessment of Air Pollution

Sadekar Enviro Engineers Pvt. Ltd. 1 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Project Team

Oct. 2017 till date Task: Mr. P. R. 3 WP -- Impact Sadekar Assessment of Water Pollution

Oct. 2017 till date Mr. Task: 4 SHW BhaskarYeng -- Impact al Assessment of SHW Oct. 2017 Mr. till date Task: 5 SE -- PrasanjeetKhander Impact ao Assessment of SE Oct. 2017 till date Mr. Task: 6 EB BhaskarYeng -- Impact al Assessment of EB Oct. 2017 till date Task: 7 GEO -- Mr. VivekNavare Impact Assessment of GEO Oct. 2017

till date Dr. Naraina Task: 8 SC -- PS Varde Impact Assessment of SC

Sadekar Enviro Engineers Pvt. Ltd. 2 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Project Team

Oct. 2017 till date Mr. Vinay Task: 9 AQ -- Gupta Impact Assessment of AQ Oct. 2017 till date Task: Mr. Vinay 10 NV Impact Gupta -- Assessment of Noise &Vibration Oct. 2017 till date Mr. Task: 11 LU BhaskarYeng -- Impact al Assessment of LU Oct. 2017 till date Mr. Dilip Task: 12 RH -- Joshi Impact Assessment of RH

Sadekar Enviro Engineers Pvt. Ltd. 3 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Project Team

Declaration by the Head of the Accredited Consultant Organization /authorized person

I, Prabhakar R Sadekar, hereby, confirm that the above mentioned experts prepared the EIA of M/s. Astec LifeSciences Ltd., I also confirm that the consultant organization shall be fully accountable for any misleading information mentioned in this statement.

Signature : Name : Mr. P.R Sadekar Designation : Director Name of the EIA Consultant Organization : M/s Sadekar Enviro Engineers Pvt. Ltd. Head Office: Plot no. A-95, Road no. 16, Kisan Nagar road, MIDC Wagle Industrial Area, - 400604 Branch office: 310, Dempo Towers, EDC Patto, Panaji – 403001. Goa State India

NABET Certificate No.& Issue Date : NABET/EIA/1518/RA020 was earlier valid up to 14thOctober 2018 & have applied for renewal

Sadekar Enviro Engineers Pvt. Ltd. 4 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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LIST OF ABBREVATIONS

LIST OF ABBREVIATIONS SEEPL : Sadekar Enviro Engineers Pvt. Ltd. EIA : Environmental Impact Assessment ALL : Astec LifeSciences Ltd. QCI : Quality Council of India NABET : National Accreditation Board for Education and Training NABL : National Accreditation Board for Testing and Calibration Laboratories MoEFCC : Ministry of Environment, Forest and Climate Change ISO : International Organization for Standardization BS OHSAS : British Standard Occupational Health and Safety Assessment Series PIN : Postal Index Number MIDC : Maharashtra Industrial Development Corporation MPCB : Maharashtra Pollution Control Board CETP : Common Effluent Treatment Plant CHWTSDF : Common Hazardous Waste Treatment Storage and Disposal Facility H2 : Hydrogen CO : Carbon monoxide CPCB : Central Pollution Control Board SO2 : Sulphur dioxide NO : Nitric Oxide NO2 : Nitrogen dioxide N2O : Nitrous oxide ALOHA : Aerial Locations of Hazardous Atmospheres NGOs : Non Governmental Organizations SEAC : State Expert Appraisal Committee SEIAA : State Environment Impact Assessment Authority GPS : Global Positioning System ECG : Electrocardiography NH3 : Ammonia HCl : Hydrochloric acid HBr : Hydrobomic acid H2S : Hydrogen sulfide HF : Hydrogen fluoride SOI : Survey Of India IMD : Indian Meteorological Department NAAQS : National Ambient Air Quality Standard

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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LIST OF ABBREVATIONS

FAE : Functional Area Expert ICAR : Indian Council of Agricultural Research US EPA : United States Environmental Protection Agency

LIST OF SYMBOLS/NOTATIONS F : Final IND : Industry Lab. : Laboratory GOI : Government Of India MT : Metric Ton M : Month ES : Executive Summary kVA : Kilovotl-ampere CMD : Cubic Meter Per Day T : Ton kg/hr. : Kilogram Per Hour TPH : Ton Per Hour kilocal./hr. : Kilocalorie Per Hour D.G : Diesel Generator KL : Kilo Liter ETP : Effluent Treatment Plant Dia. : Diameter m3/day : Meter cube per day SEE : Single Effect Evaporator CAGR : Compounded Annual Growth Rate PPEs : Personal Protective Equipments PM10 : Particulate matter of size less than 10 micron PM2.5 : Particulate matter of size less than 2 micron SOx : Oxides of Sulphur NOx : Oxides of Nitrogen RO : Reverse Osmosis TPM : Total Particulate Matter VOCs : Volatile Organic Compounds mm : Millimeter THF : Thermic Fluid Heater km : Kilometer

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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LIST OF ABBREVATIONS

µg/m3 : Micorgram per meter cube db (A) : Weighted decibels mg/l : Milligram per liter TDS : Total Dissolved Solids BOD : Biochemical Oxygen Demand COD : Chemical Oxygen Demand SW : Surface water GW : Ground water E-coli : Escherichia coli pH : Potential of Hydrogen IS 10500:2012 : Indian Standard Drinking Water - Specification kg/ha. : Kilogram per hectare PUC : Pollution Under Control LCOD & LTDS : Low Chemical Oxygen Demand & Low Total Dissolved Solids LCOD & HTDS Low Chemical Oxygen Demand & High Total Dissolved Solids MCLS : Maximum Credible Loss Scenario MSDs : Material Safety Data Sheets CSR : Corporate Social Responsibility ESC : Environment Social Commitment H.W : Hazardous Waste EMP : Environmental Management Plan sq. m : Square meter TOR : Terms Of Reference EC : Environmental Clearance CTE : Consent To Establish CTO : Consent To Operate FY : Financial Year SPCB : State Pollution Control Board w.r.t : With respect/reference to lat-long : Latitude-Longitude R&R : Resettlement & Rehabilitation AAQ : Ambient Air Quality NAAQM : National Ambient Air Quality Monitoring MOU : Memorandum Of Understanding ha. : Hectare PEL : Permissible Exposure Limit

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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LIST OF ABBREVATIONS

TSDF : Transport Storage Disposal Facility PP : Project Proponent CMSWMF : Common Municipal Solid Waste Management Facility SEZs : Special Economic Zones STP : Sewage Treatment Plant FO : Furnace Oil DMW : De Mineralized Water F.G : Finished Goods ENGG. : Engineering APCDs : Air Pollution Control Devices TR : Ton Refrigeration hp : Horse Power kg/cm2 : Kilogram per centimeter square QMS : Quality Management System MIN : Minimum MAX : Maximum Avg. : Average 0C : Degree Celsius km/hr : Kilometer per hour HDPE : High-density polyethylene ppm : Parts per million BDL : Below Detection Limit IRC : Indian Road Congress TS : Traffic study location PCUs : Passenger car units AP : Air Pollution TSPM : Total Suspended Particulate Matter

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Component Regulations Air  Air (Prevention and Control of Pollution) Act, Rules and Amendments - 1981, 1982, 1983, 1987  Central Motor Vehicle Rules, 1989  Indian Boiler Act, 1923  Motor Vehicles (Amendment) Act, 1988  National Ambient Air Quality Standards, 2009  Static and Mobile Pressure Vessels (Unfired) Rules, 1981 Noise  Noise Pollution (Regulation and Control) Rules and Amendments - 2000, 2006, 2010 Water  Environmental (Protection) Rules, 1991  Water (Prevention and Control of Pollution) Act, Rules and Amendments - 1974, 1977, 1978,1988  Water (Prevention and Control of Pollution) Cess Act, Rules and Amendments - 1977, 2003 Flora and Fauna  Wildlife (Protection) Act, Rules and Amendments - 1972, 1973, 1991, 1995,2002  Forest (Conservation) Act and Rules and Amendments - 1980, 1981, 2003  Biological Diversity Act, Rules - 2002, 2004 Hazardous  Explosives Act, 1884 substances  Hazardous and Other Wastes (Management and Trans0-boundary Movement) Rules, 2016  Manufacture, Storage and Import of Hazardous Chemical Rules -

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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1989, 2000 Wastes  Hazardous and Other Wastes (Management and Trans0-boundary Movement) Rules, 2016  Construction and Demolition Waste Management Rules 2016  Solid Waste Management Rules - 2000, 2016 Others  The Environment (Protection) Act and Rules - 1986, 1991  Environment Impact Assessment Notification 1994, 2006 & Amendments  Factories Act and Amendments - 1948, 1987  Maharashtra Industrial Development Corporation - Revised Development Control Regulations 2009  Standard Terms of Reference[TOR] for EIA/EMP Report for Projects/Activities Requiring Environmental Clearance Under EIA Notification, 2006

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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CONFIGURATION OF THE EIA REPORT

Executive Summary:

Executive summary is the brief summarization of introduction, history, salient features, justification, process description of the project, baseline environmental status, anticipated impacts & respective mitigation measures, brief of risk assessment study, disaster management plan, CSR aspects, post project environmental monitoring plan, details of EMP budgetary allocation and the findings of EIA report.

Chapter 1: Introduction

This is an introductory chapter describing purpose of project, information about project proponent, brief description of - nature, size, location of the project and its importance to the country, region, scope of study, details of the EIA consultant including NABET accreditation.

Chapter 2: Project description

This chapter provides information on type, need, history, size or magnitude, location of the project, description of the project layout plan, schedule for approvals & implementation status of land acquisition, production related details such as products to be manufactured, raw materials to be used, technology - equipments and/or machinery to be used for manufacturing process & overview of mitigation measures.

Chapter 3: Description of the environment

This chapter provides the scenario of the baseline environment status for various environmental & physical components such as meteorology, air, surface & ground water, noise, soil, geology & hydrogeology, traffic, land use land cover assessment, biotic environment, socio economics, industrial workplace environment along with the description of methodologies, criteria for

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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sampling and/or monitoring, sources of secondary data and environmental component wise interpretation w.r.t ground conditions at the time of study & statutory standards.

Chapter 4: Anticipated environmental impacts & mitigation measures

The chapter deals with the identification of project activity specific anticipated impacts, quantification of the same, assessment of probable impacts on the environment & provisions of mitigation measures to mitigate the same.

Chapter 5: Analysis of alternatives

This chapter provides information on analysis of alternatives considered for the location of set up of project & for technology used for manufacturing process & allied operations along with justification.

Chapter 6: Environmental monitoring programme

This chapter gives the importance of environmental monitoring during pre & post project stages and also delineates the parameters & frequency of monitoring.

Chapter 7: Additional studies

This chapter covers aspects related to additional studies/activities such as public hearing (recommendations if any), risk assessment (raw material storage related risk scenarios), disaster management plan (onsite & offsite emergency preparedness plan) and recommendations related to safe storage & handling of chemicals at site.

Chapter 8: Project benefits

This chapter highlights the locale specific & overall benefits of the project.

Chapter 9: Environmental cost benefit analysis

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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This chapter usually provides a scenario of cost benefits which can be achieved by adopting sustainable measures or otherwise which may be not be achieved if resources optimization is not considered.

Chapter 10: Environmental management plan

This chapter details all the project specific measures to be adopted as a part of environmental management plan along with budgetary allocations.

Chapter 11: Summary & conclusion

This chapter provides summary of all project related activities and conclusion.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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INDEX

INDEX Sr. No Components Page No. EXECUTIVE SUMMARY ES-1 to ES -25 ES-1 Introduction ES-1 ES-2 History of the project ES-1 ES-3 Justification of project ES-5 ES-4 Process description ES-6 ES-5 Baseline Environmental Status ES-7 ES-6 Prediction of Impacts & its mitigation ES-15 ES-7 Risk Assessment Study ES-21 ES-8 Disaster Management Plan ES-22 ES-9 CSR Activity ES-22 ES-10 Occupational Health Measures ES-23 ES-11 Post Project Monitoring Plan ES-24 ES-12 EMP Cost & Budgetary Allocation ES-25

1) CHAPTER 1 - INTRODUCTION 1.1 Purpose of the project 1-1 1.2 Information about project proponent 1-2 1.3 Brief description of nature, size, location of the project and its 1-3 importance to the country, region 1.4 Scope of the study 1-5 1.5 Details of the EIA Consultant including NABET Accreditation 1-22

2) CHAPTER 2 – PROJECT DESCRIPTION 2.1 Type of project 2-1 2.2 Need for the project 2-1 2.3 History of the project 2-1 2.4 Size or magnitude of operation 2-2 2.5 Location of the project 2-7 2.6 Proposed schedule for approval and implementation 2-17 2.7 If expansion project, details of existing products with capacities and 2-27 whether adequate land is available for expansion, reference of earlier EC if any 2.8 Description of mitigation measures 2- 28

3) CHAPTER 3 – DESCRIPTION OF THE ENVIRONMENT 3.1 Introduction 3-1 3.2 Meteorology 3-2 3.3 Ambient Air Quality Monitoring 3-11

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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INDEX

3.4 Surface Water Quality 3-20 3.5 Ground Water Quality 3-29 3.6 Noise Level Monitoring 3-35 3.7 Soil Quality 3-39 3.8 Environmental Conditions at Industry 3-46 3.9 Geology & Hydrogeology of the study area 3-49 3.10 Traffic Study 3-53 3.11 Land use Pattern 3-61 3.12 Biotic environment 3-67 3.13 Socio economic status of the study area 3-73

4) CHAPTER 4 - ANTICIPATED ENVIRONMENTAL IMPACTS & MITIGATION MEASURES 4.1 Air Environment 4-1 4.2 Water Environment 4-23 4.3 Noise Environment 4-44 4.4 Details of hazardous and non-hazardous waste generation and their 4-53 storage, utilization and management 4.5 Soil environment 4-60 4.6 Biotic environment 4-69 4.7 Land environment 4-74 4.8 Socio economic environment 4-74 4.9 Odour 4-75

5) CHAPTER 5 – ANALYSIS OF ALTERNATIVE 5.1 Introduction 5-1 5.2 Analysis of alternative site 5-1 5.3 Analysis of alternative technology 5-2

6) CHAPTER 6 – ENVIRONMENTAL MONITORING PROGRAM 6.1 Introduction 6-1 6.2 Monitoring points/locations and components 6-1 6.3 Post project monitoring parameters & frequency 6-5 6.4 Monitoring methodologies 6-6 6.5 Documentation and Reporting 6-6 6.6 Budget & procurement schedule 6-6

7) CHAPTER 7 – ADDITIONAL STUDIES 1 to 68 7.1 Public Hearing 1

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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INDEX

7.2 Risk Assessment 1-22 7.3 HAZOP Study 23 7.4 Aerial Location of Hazardous Atmosphere (ALOHA) 2-16 7.5 DOW Fire and Explosion Index 16-20 7.6 Toxicity (Monds) Index 21-22 7.7 Disaster Management Plan 24-68 7.8 Off-Site Emergency Preparedness Plan 63-68

8) CHAPTER 8 – PROJECT BENEFITS 8-1

9) CHAPTER 9 – ENVIRONMENTAL COST 9-1 BENEFIT ANALYSIS

10) CHAPTER10 – ENVIRONMENTAL 1 to 29 MANAGEMENT PLAN 10.1 Introduction 1 10.2 Organizational Structure Of Environment Management 2 10.3 Budget for Environmental Management / Environmental Pollution 3 Control Measures 10.4 Details of EMP Budgetary Allocation 3-4 10.5 Details of Environmental Mitigation Measures 4-10 10.6 Fly Ash utilization as per Fly Ash Notification, 2009. 10 10.7 Action Plan for Green Belt Development 11-21 10.8 Storm Water Management 21-22 10.9 Rain Water Harvesting 22 10.10 Solvent Management System 22-23 10.11 CSR Activity (Enterprises Social Commitment) 23 -25 10.12 Occupational Health 25-26 10.13 Corporate Environmental Policy 26-29

11) CHAPTER 11 – SUMMARY & CONCLUSION 1 to 4 11.1 Salient Features Of The Project 1-3 11.2 Conclusion 3-4

12) CHAPTER 12 – DISCLOSURE OF CONSULTANT 1 to 4

LIST OF TABLES Table Name of Table Page No. no.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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INDEX

EXECUTIVE SUMMARY ES-1 Salient Features of the Project ES-2 ES-2 Pearson’s correlation among variables (N=50)1 ES-14 ES-3 Summary of Impacts & Mitigation Measures ES-15 ES-4 Year wise Details of CSR Activities ES-23 ES-5 Environmental Monitoring Program ES-24 ES-6 Cost details for Environmental Management ES-25

1) CHAPTER 1 - INTRODUCTION 1.1 Compliance of Standard TOR 1-6 1.2 Compliance of Specific TOR by MoEF & CC 1-19 1.3 Compliance of SEAC-1 Additional TOR 1-20 1.4 Details of Accreditation of SEEPL 1-22

2) CHAPTER 2 - PROJECT DESCRIPTION 2.1 Project details 2-2 2.2 Latitude & Longitude of factory corners 2-8 2.3 Immediate surroundings to the project site 2-8 2.4 List of major industries 2-8 2.5 List of environmental sensitive areas 2-9 2.6 Land use break up details of the project site 2-12 2.7 Description of Project Plot Layout plan 2-16 2.8 Schedule for approval and implementation 2-18 2.9 List of raw materials 2-20 2.10 List of products 2-22 2.11 List of existing & proposed major equipments & machineries 2-24 2.12 Impact Evaluation Matrix 2-31 2.13 Severity criteria for magnitude of impacts 2-33 2.14 Severity criteria for magnitude of impacts 2-33

3) CHAPTER 3 - DESCRIPTION OF THE ENVIRONMENT 3.1 Monthly data from IMD 2012 to 2016 3-6 3.2 Site Specific Micro Meteorology Data (March to May, 2017) 3-9 3.3 Methodology Used for Ambient Air Analysis 3-12 3.4 Details of Selected Sampling Locations 3-14 3.5 Ambient Air Quality Status (Criteria Pollutants) 3-16

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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INDEX

3.6 Results of Additional Air Quality Parameters at Project Site 3-19 3.7 Methodologies Used for Surface Water Analysis 3-24 3.8 Details of Surface Water Quality Monitoring Stations 3-25 3.9 IS: 2296–1982_Inland_Surface_Water_Stds 3-25 3.10 Surface Water Quality Results 3-27 3.11 Details of Sampling Locations for Ground Water samples 3-30 3.12 Parameters and Methodologies for Analysis of Ground Water Samples 3-31 3.13 Ground Water Quality Results 3-33 3.14 IS:10500:2012 Standards for Drinking Water 3-34 3.15 Details of Noise Quality Monitoring Stations 3-38 3.16 Result of Ambient Noise Monitoring 3-38 3.17 Details of Soil Quality Sampling Stations 3-42 3.18 Methodology of soil quality analysis 3-42 3.19 Analysis of Soil Samples 3-44 3.20 Chemical Classification of Soil Quality 3-45 3.21 Monitoring at Workplace of Astec LifeSciences Ltd. 3-46 3.22 Results of Monitoring for Astec LifeSciences Ltd. 3-47 3.23 Results of Noise Monitoring at Various locations at the project site 3-47 3.24 Characteristics of Waste Water from Effluent Treatment Plant 3-48 3.25 Statigraphic sequences of the geological formation in the district 3-49 3.26 Traffic study observation locations 3-55 3.27 Recommended PCU factors for various types of vehicles on urban roads 3-55 Summary of traffic in terms of PCUs observed at observation point (TS1) - during (08: 3.28 3-57 00 to 10: 00 AM) & (04: 00 to 06:00 PM) Summary of traffic in terms of PCUs observed at observation point (TS2) - during (08: 3.29 3-58 00 to 10: 00 AM) & (04: 00 to 06:00 PM) Summary of traffic in terms of PCUs observed at observation point (TS3) - during (08: 3.30 3-60 00 to 10: 00 AM) & (04: 00 to 06:00 PM) 3.31 Summary of increased traffic in terms of PCUs at TS1 due to the expansion project 3-60 3.32 Summary of increased traffic in terms of PCUs at TS2 due to the expansion 3-61 3.33 Summary of increased traffic in terms of PCUs at TS3 due to the expansion project 3-61 3.34 Categorization of land use & land cover pattern of the study area 3-63 3.35 Descriptive Statistics indicating mean and standard deviation (N=50) 3-74 3.36 Indicating Pearson’s correlation among variables (N=50) 3-75 CHAPTER 4 - ANTICIPATED ENVIRONMENTAL IMPACTS & MITIGATION 4) Page No. MEASURES 4.1 Atmospheric inversion level at Dombivli, Thane, Maharashtra 4-5 4.2 Model input parameters for proposed boiler & thermic fluid heater stack modelling 6 4.3 Interpretation of the Incremental Values 8 4.4 Existing Water Balance 19 4.5 Total Water Balance (After expansion) 19

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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INDEX

4.6 Characteristics of the LCOD-TDS wastewater 23 4.7 Predicted characteristics of the treated effluent 23 4.8 Dimensions of existing ETP 25 4.9 Dimensions of proposed ETP for treatment of LCOD/LTDS & LCOD/HTDS effluent 25 streams 4.10 Noise level generated during Operational Phase 35 4.11 Anticipated noise level during operational phase at nearest sensitive receptor and the 36 MIDC boundary 4.12 Sources of hazardous waste generation 41-42 4.13 Solid waste generation and disposal method 43

6) CHAPTER 6 – ENVIRONMENTAL MONITORING PROGRAMME 6.1 Pre project monitoring parameters 6-2 6.2 Post project monitoring parameters & frequency 6-5

7) CHAPTER 7 – ADDITIONAL STUDIES 7.1 Details of Raw Materials/Bi products/ Products Stored in Above Ground Tank 3-5 7.2 ALOHA Summary Sheet 6-12 7.3 Interpretation Table 16 7.4 DOW Index Summary Sheet For Raw Materials 18 7.5 DOW Index Summary Sheet For Products 19 7.6 DOW Index Summary Sheet For Fuel Storages 19-20 7.7 Mond's Index Summary Sheet 21-22 7.8 Emergency Do’s & Don’ts 31-32 7.9 List of companies under mutual aid group 33 7.10 List of Important Personnel 35 7.11 Detailed list of Hazardous Chemicals 37-42 7.12 Threshold limits Hazardous Raw Material 43-45 7.13 Toxicological Data of the Raw Materials 46-56 7.14 Likely Dangers to the Plant 56-57 7.15 Alarm Code 57 7.16 Communication facilities available during Onsite emergency 59 7.17 Fire Fighting Tank Details 59-60 7.18 List of Existing fire extinguishers & fire buckets provided 60 7.19 Location of Existing Fire Hydrants 60-61 7.20 Type of protective & rescue equipment 61 7.21 First Aid Kit Location 62 7.22 External agencies contact details involved during emergency 67-68

10) CHAPTER10 – ENVIRONMENTAL

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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INDEX

MANAGEMENT PLAN 10.1 Cost details for environmental management 3 10.2 Justification of EMP budgetary allocation 3-4 Overview of probable environmental pollution & mitigation measures during 5-6 10.3 construction phase Overview of probable environmental pollution & mitigation measures during 6-10 10.4 operational phase

10.5 Project plot area break up details 11-12 10.6 Description of Figure No. 10.2 14-15 10.7 Description of Figure No. 10.3 16-17 10.8 Break up of proposed green belt area within & outside the project plot 19 10.9 Action plan for proposed green belt development/plantation 19 10.10 Recurring cost for maintaining green belt 20 10.11 List of suggested plant species 20-21 10.12 Solvent use & recovery summary 23 10.13 List of CSR Activity 24-25 10.14 List of SOP’s to be framed 27

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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INDEX

LIST OF FIGURES Figure no. Name of Figure Page No. EXECUTIVE SUMMARY ES-1 AstecLifeScineces Ltd. (Google Earth Imagery) ES-1 ES-2 Process Description Diagram ES-6 ES-3 Maximum credible Loss Scenario: AstecLifeScineces Ltd. ES-21

2) CHAPTER 2 - PROJECT DESCIRPTION 2.1 Google Earth Image depicting plot boundary of AstecLifeScineces 2-7 Ltd.Ltd. 2.2 Layout of Mahad MIDC Industrial Area depicting project plot of 2-13 AstecLifeScineces Ltd. 2.3 Location of AstecLifeScineces Ltd. on SOI Toposheet 2-14 2.4 Plot layout of AstecLifeScineces Ltd. 2-15 Overview of environmental aspects & respective mitigation measures 2.5 2-29 during operational phase. Overview of environmental aspects & respective mitigation measures 2.6 2-30 during construction phase

3) CHAPTER 3 -PREVAILING ENVIRONMENTLA STATUS 3.1 Methodology For EIA 3-3 3.2 Methodology for Obtaining Environmental Clearance 3-5 3.3 Windrose from Secondary for year, 2012-2016 3-8 3.4 Windrose from Secondary data for Sampling Period 3-8 3.5 Windrose from Primary data for Sampling Period 3-8 3.6 Air Monitoring Locations On SOI Toposheet 3-15 3.7 Surface Water Monitoring Locations on SOI Toposheet 3-22 3.8 Ground Water Monitoring Locations on SOI Toposheet 3-32 3.9 Sampling Locations for Noise Monitoring on SOI Toposheet 3-37 3.10 Soil Quality Sampling Locations (SOI map) 3-41 3.11 Geological Map of Maharashtra State 3-50 3.12 Depth of Ground Water Level 3-52 3.13 Traffic Observation Locations 3-54 Percentage of vehicle count - (TS1) Junction joining the internal MIDC road 3.14 3-56 and State Highway 76 at Viko Naka (8 AM to 9 AM) and (9 AM to 10 AM) Percentage of vehicle count - (TS1) Junction joining the internal MIDC road 3.15 3-56 and State Highway 76 at Viko Naka (4 PM to 5 PM) and (5 PM to 6 PM) Percentage of vehicle count - (TS2) Junction joining the MIDC internal road 3.16 and State Highway 76 near Savitri Phule Stadium (8 AM to 9 AM) and (9 3-57 AM to 10 AM) 3.17 Percentage of vehicle count - (TS2) Junction joining the MIDC internal road 3-58

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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and State Highway 76 near Savitri Phule Stadium (4 PM to 5 PM) and (5 PM to 6 PM) Percentage of vehicle count - (TS3) Junction joining the MIDC internal road 3.18 and State Highway 76 near Monarch Catalyst (8 AM to 9 AM) and (9 AM to 3-59 10 AM) Percentage of vehicle count - (TS3) Junction joining the MIDC internal road 3.19 and State Highway 76 near Monarch Catalyst (4 PM to 5 PM) and (5 PM to 6 3-59 PM) 3.20 Land Use Land Cover Map of the Study Area 3-62 3.21 Percentage wise Land Use classification of the study area 3-64 3.22 Percentage wise Land Cover classification of the study area 3-64 3.23 Map depicting Drainage Pattern of the study area 3-67 3.24 10 km radial study area (Google Earth Imagery) 3-68

4) CHAPTER 4 - ANTICIPATED IMPACTS & MITIGATION

MEASURES 4.1 Proposed water balance 22 4.2 Flow chart of the effluent treatment plant for LCOD/LTDS effluent 26 4.3 Flow chart of the effluent treatment plant for LCOD/HTDS effluent 27

7) CHAPTER 7 ADDITIONAL STUDIES 7.1 Key personnel of the organization and responsibility assigned 26 7.2 Establishment of Safety Committee 34 7.3 Offsite Emergency Plan 65

10) CHAPTER10 – ENVIRONMENTAL

MANAGEMENT PLAN 10.1 Schematic representation of organizational structure of environment 2 management 10.2 Project plot layout depicting proposed green belt within the plant 12 premises 10.3 Layout plan depicting proposed green belt within & outside plant 13 premises 10.4 MIDC permission for plantation/green belt development outside the 14 project premises

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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10.5 Schematic representation of administrative order of company to deal 23 with environmental issues

LIST OF ANNEXURES Annexure Name of Annexure Page No. no. 2.1 Affidavit of non violation of EIA Notification and 2.1- 1 MPCB consent conditions 2.2 Manufacturing process and mass balances Annexure 2.2-10 - Annexure 2.2-10 2.4 Project plot layout plan Annexure 2.4-10 2.5 Consent To Operate Annexure 2.5-10 - Annexure 2.5-10 2.6 Compliance of existing Consent To Operate Annexure 2.9 - 1 to Annexure 2.9 - 23 3.1 Flora and Fauna Inventory Annexure 3.1-10 - Annexure 3.1-10 4.1 Air modeling output images depicting incremental Annexure 4.1-10 - predicted values Annexure 4.1-10 4.2 CETP Membership Annexure 4.2-10 - Annexure 4.2-10 4.5 Annexure 4.5: Noise modeling contours Annexure 4.5-1 4.6 Waste Management - CHWTSDF, Taloja Annexure 4.6-1- Membership Annexure 4.6-10 7.1 ALOHA Footprints Annexure 7.1-1 - 7.1-10 7.2 DOW Index Annexure 7.2-1 - Annexure 7.2-10 7.3 MONDs Index Annexure 7.3-1 - Annexure 7.3-6 7.4 HAZOP Study Report Annexure 7.4 -1 - Annexure 7.4 -39

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

EXECUTIVE SUMMARY

ES-1 Introduction

The proposed expansion activity by Astec LifeSciences Ltd. is a brownfield activity and as per the Environment Impact Assessment Notification 2006 & recent amendments till date, project activity by ALSLcomes under Schedule 5 (b) & Category - AasPesticides industry and pesticide intermidates (excluding formulations). ALSL has been categorized Red/LSI (Large Scale Figure ES -1: AstecLifeSciences Ltd. (Google Earth Imagery) Industry)industry by Maharashtra Pollution Control Board. Manufacturing unit of ALSL is located at Plot no B-16,17, 18, &21, MIDC Mahad, Mahad, Dist. -Raigad, Maharashtra.

ES-2 History of the project Astec LifeSciences Limited has been incorporated under the Companies Act, 1956 on 25th January 1994 at the time of inception in the year 1994, ALSL was incorporated in the name and style of Urshilla Traders Private Limited subsequently company’s name was changed to Astec Chemicals Private Limited with effect from 19th August 1994 further Astec Chemicals private Limited was renamed to AstecLifeSciences Pvt. Ltd. with effect from 3rd March 2006 & Astec LifeSciences Private Limited was changed to AstecLifeSciences Limited with effect from 27th

Sadekar Enviro Engineers Pvt. Ltd. ES- 1

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

April 2007 wherein the total capital investment of Astec Chemicals Private Limited which was in existence in the year 1995 was less than Rs. 1 Crore hence as per EIA Notification 1994 Astec Chemicals Private Limited was exempted from obtaining environmental clearance.

ALSL has obtained Maharashtra Pollution Control Board’s Consent To Operate “Consent order No: - Format1.0/AS/(T)/EIC No. RD-3108-15/Amend/CC-3030” dtd. 25/07/2016 and “Consent No: RO-Raigad/Consent/1803000437” dtd. 08-03-2018 for manufacture of 219 T/M pesticides & chemical intermediates and 700 T/M pesticide formulations respectively.

Now ALSL has envisaged pesticides& chemical intermediates production capacity enhancement from existing 219 MT/M to 781 MT/M and formulation products to the tune of 700.0 MT/M along with generation of bi-products to the tune of 1773 MT/Mwithin the existing manufacturing plant located at Plot No. -16, 17, 18 and B-21, MIDC Mahad, District Raigad, Maharashtra with an estimated budgetary project cost of Rs. 10.17 Crore, thus ALSL has not violated EIA Notification 1994 &/or 2006.

The salient feature of the project are presented in Table ES-1.

Table No. ES-1: Salient Features of the Project

Sr. Particulars Details No. 1 Name M/s Astec LifeSciences Ltd.

Plot No. B-16, 17, 18 & 21, MIDC Mahad,Mahad, Dist. - 2 Location Raigad, Maharashtra. 3 Product Type Pesticides, Chemical Intermediates & Formulations 4 Project Type Expansion 5 Schedule 5 (b)

Sadekar Enviro Engineers Pvt. Ltd. ES- 2

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

6 Category A Land use Existing Proposed Total Area Details wise (Sq. m.) (Sq. m.) (Sq. m.) percentage 7 Total Plot Area 13,950.00 -- 13950.00 -- Built up Area 8544.00 -- 8544.00 61.24% Parking Area 166.00 -- 166.00 1.18% Green Belt Area 343.52 518.75 862.27 6.18 % Existing Proposed Total Production Capacity (MT/M) (MT/M) (MT/M) Pesticide Products 219.00 562.00 781.00 8 Pesticide Formulation 700.00 -- 700.00 Bi-Products -- 1773.00 1773.00 Total 919 2335 3254 9 Project cost (Indian Rs.) 10.17 Crore Capital cost: 60.0 Lakh, Recurring cost: 25.10 10 EMP cost (Indian Rs.) Lakh/Annum Existing Proposed Total Connected load: Connected Load: 11 Power Requirement (kVA) 1600 1600 -- Maximum Maximum demand: demand: 900 900 756.53 Recycled water = 309.3 CMD thus total water 12 Water Requirement (CMD) 352.67 403.63 requirement for expansion activity will be 447 CMD Furnace Oil 125.0 l/day 3483.12l/day 3608.12 l/day Fuel 13 Requirement Coal 22.0 MT/day 35.0 MT/day 57.0 MT/day HSD 110 l/day 2700 l/day 2810 l/day

Sadekar Enviro Engineers Pvt. Ltd. ES- 3

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

1 x 6 TPH 1 x 850 kg/hr. 1 x 15 TPH 1 x 2.5 TPH Steam 1 x 6 TPH 1 x 15 TPH Boiler Note: Existing 1 x 850 Kg/hr. boiler of 2 TPH will be discontinued 1 x 6 lakh kilo 1 x 6 lakh kilo Thermic cal./hr. cal./hr. -- fluid heater 1x 2 lakh kilo 1x 2 lakh kilo cal./hr. cal./hr. 1 x 250 1x 500 1 x 125 15 D.G. (kVA) 1 x 500 1 x 250 Note: Existing D.G of 125 kVA will be discontinued Existing Proposed Total Stack No.1: 30 m Stack No.1: 30 m Stack for 6 TPH Stack for 6 TPH boiler boiler

Stack No.1: Stack No.2: 25 m Stack No.2: 24m Boiler 39 m stack for stack for 2.5 TPH stack for 850 kg/hr 15 TPH boiler boiler boiler

Stack No.3: 24m Stack No.3: 39 m 16 Stack details stack for 850 kg/hr stack for 15 TPH boiler boiler Stack No.2: 27 m common Stack No.4: 27 m Thermic stack for common stack for -- fluid heater TFH’s of 6 & TFH’s of 6 & 2 2 lackhkilo. lackh kilo. cal./hr. cal./hr. Stack No1: 3.5 m Stack No1: Stack No. 5: 4.5 m D.G Set above roof for D.G 4.5 m above stack above roof for

Sadekar Enviro Engineers Pvt. Ltd. ES- 4

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

of 125 kVA roof for D.G D.G of 250 kVA of 500 kVA Stack No. 2: 3.5 m Stack No. 6: 4.5 m above roof for D.G stack above roof for of 250 kVA D.G of 500 kVA Stack No.7: 5.0 mstack above roof Stack No.1: Stack for process scrubber of 5 m above roof Scrubber -- for process Note: Existing scrubber boiler of 2.5 TPH & D.G of 125 kVA will be discontinued 17 Effluent Generation (CMD) 46.43 408.57 455.00

18 Sewage Generation (CMD) 15.0 -- 15.0 ETP of 55 CMD In wake of 55 CMD, capacity along expansion Evaporator of with installation activity in 100 CMD & of in plant 19 ETP Capacity plant stripper 54 CMD stripper evaporator of Evaporator for evaporator of 150 CMD will Cooling Tower 250 CMD be installed capacity 36 CMD LCOD-LTD effluent along with domestic sewage 15 CMD will be treated in full-fledged ETP of 55 CMD capacity from which 46.43 CMD effluent will be sent to CETP for further treatment & disposal as per valid C.T.O & 4. 57 CMD treated effluent will be reused.

20 Effluent Treatment Scheme 241 CMD effluent process will be subjected in plant stripper evaporator of 250 CMD capacity from which 184 CMD condensate will be reused & 54 T/D salts will be sold as bi-products.

120.73 CMD Cooling tower & Boiler blow down will be

Sadekar Enviro Engineers Pvt. Ltd. ES- 5

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

reused.

21 Man Power 160 -- 160 Hazardous *Category UOM Existing Proposed Total Disposal Waste of waste Used/ spent oil 5.1 Sale to Authorized l/Month 50.0 950.0 1000.00 recycler / CHWTSDF Residues & 29.1 MT/Mo 204.0 207.0 411.0 CHWTSDF Waste nth Chemical 29.2 MT/D 2.7 -- 2.7 sludge residue CHWTSDF from Pesticides Discarded 33.1 Nos./M Sale to 22 containers onth Authorized 78.0 1172.00 1250.0 recycler / CHWTSDF Chemical 35.3 MT/Mo CHWTSDF sludge from nth 1.12 67.88 69.0 ETP Filter & filter 36.2 kg/Mon CHWTSDF material having th 12.0 488.0 500.0 organic liquid Spent carbon 36.2 kg/Mon CHWTSDF 10.0 190.0 200 th Asbestos 15.2 kg/Mon -- 100.0 100.0 CHWTSDF gaskets th Non-hazardous UOM Existing Proposed Total Disposal waste Paper waste kg/Month (paper boxes 150.00 5450.00 5600.00 23 and bags) Sale to Plastic waste kg/Month 50.00 5450.00 5600.00 recycler Metal scrap kg/Month 100.00 4900.00 5000.00 Wooden pellets Nos./Mont 25.00 975.00 1000.00 h

Sadekar Enviro Engineers Pvt. Ltd. ES- 6

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

Coal ash kg/Day Sale to registered 2700.00 5850.00 8550 brick manufacture r *Schedule I: Hazardous and other Wastes (Management and Transboundary Movement) Rules, 2016

ES-3 Justification of project

M/s. AstecLifeSciences Ltd. is currently engaged in manufacture of Pesticides & Formulation products& is a global supplier of pesticides &chemical intermediatesacross the world, with an operational experience of more than 24 years company has witnessed a steady increase in demand of products manufactured by Astec in domestic as well as international markets.

AstecLifeSciences Ltd. aims to expand its manufacturing portfolio by increasing the production quantity of its existing products & by addition of new productsin order to cater domestic & international market needs. Products manufactured by ALSL will serve to cut the supply of imports from foreign countries thus saving currency and at the same time will earn valuable foreign currency by export of the proposed products. These business sustenance measures by ALSL justify the purpose of project.

ES-4 Process Description:The process of the company is depicted in Figure. ES -2.

Sadekar Enviro Engineers Pvt. Ltd. ES- 7

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

FigureNo.ES-2: Process Description Diagram

ES-5Baseline Environmental Status

The study area is 10 km radial distance from centre of existing plant site. All the monitoring has been completed in various locations within the study area during the period of Dec 2017 to feb 2018. The findings of the baseline environmental status on Land (Topography, Soil Quality, Land Use Pattern), Micrometeorology (Temperature, Humidity, Rainfall, Wind Speed), Air

(Ambient Air Quality- PM10, PM2.5, SO2, NOX, CO), Noise Level, Biotic Environment (flora,

Sadekar Enviro Engineers Pvt. Ltd. ES- 8

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

fauna& assessment of conservation aspects), Socio Economic conditions are presented in the report and interpreted with reference to Standards.

ES-5.1 Air Environment

Figure ES-3:Air Monitoring Locations on Google Earth

PM10

Table ES-5: Ambient Air Quality Status (PM10)

Sampling Sampling Value in PM Locations Locations Interpretation 10 (µg/m3) Code Name

Sadekar Enviro Engineers Pvt. Ltd. ES- 9

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

The highest 24-hourly concentration was recorded at sampling location Highest Conc. A1 Project Site 96.0 A1. whereas the minimum concentration was observed at location A8.

The average concentration of PM10 can be said to be ranged between Near 71.3-87.9 µg/m3. Lowest Conc. A8 Dharwali 68.5 Village The high concentration of particulate matter recorded at project site (A1) may be due to various vehicular emissions and urban activity like construction etc,.

The minimum concentration at Max. Average location A8 can be said due to its A1 Project Site 87.9 Conc. remote location and minimal human activity in and around the monitoring station. Therefore experiences minimal levels of pollution.

PM2.5

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

Table ES-6: Ambient Air Quality Status (PM2.5) Sampling Sampling Value in PM Locations Locations Interpretation 2.5 (µg/m3) Code Name

Project The major source of PM2.5 is said to be Highest Conc. A1 51.8 Site the combustion of fossil fuels, fire Near wood, etc. The maximum of PM2.5 3 Lowest Conc. A8 Dharwali 17.0 (51.8 µg/m ) during the study period Village was recorded at location A1, whereas the minimum 17.0 µg/m3 concentration was recorded at A8 location which is a remote area. The minimum concentration indicates that the area Max. Average experiences minimal combustion and A1 Project 44.2 Conc. Site vehicular activity. The average concentration of PM2.5 during the study period was computed to be in the range of 21.7-44.2 µg/m3.

Sulphur dioxide (SO2)

Table ES-7: Ambient Air Quality Status (SO2) Sampling Sampling Value in SO Locations Locations Interpretation 2 (µg/m3) Code Name Project . The ambient air monitoring results Highest Conc. A1 36.5 Site indicate that the highest average Near concentration of SO2 is experienced at Lowest Conc. A8 Dharwali 14.0 location A1. Village Max. Average The average concentration of SO2 A1 Project 29.1 Conc. Site recorded at all the monitoring locations

Sadekar Enviro Engineers Pvt. Ltd. ES- 11

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

Sampling Sampling Value in SO Locations Locations Interpretation 2 (µg/m3) Code Name during the study period ranged between 18.9-29.1 µg/m3 respectively

Oxides of Nitrogen (NOX)

Table ES-8: Ambient Air Quality Status (NOx) Sampling Sampling Value in NO Locations Locations Interpretation X (µg/m3) Code Name

Highest Conc. A1 Project Site 50.5 The maximum 24 hourly value of NOX Near was recorded at the monitoring location Lowest Conc. A8 Dharwali 18.0 A1 (50.5µg/m3) & A5 (50 µg/m3) Village whereas the minimum concentration of NOx was recorded at location A8 (18 µg/m3). It should be noted that the location A8 was observed to have Max Average A1 Project Site 43.6 Conc. minimal vehicular activity resulting in minimal concentration of pollutants. The average concentrations were in the range of 22.1-43.6 µg/m3.

Carbon monoxide (CO) Table ES-9: Ambient Air Quality Status (CO)

Sadekar Enviro Engineers Pvt. Ltd. ES- 12

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

Sampling Sampling Value in CO Locations Locations Interpretation (mg/m3) Code Name Highest Conc. A1 Project Site 2.1 The anthropogenic source of CO is due Dahivad to incomplete combustion of fuel Lowest Conc. A3 0.5 Village majorly in absence of air. The maximum concentration of CO estimated at all locations during the study period can be observed to be Max Average 3 A1 Project Site 1.5 within 1.2 to 2.1 mg/m respectively. Conc. The minimum concentration at all locations ranged between 0.5 - 0.9 mg/m3.

Monitoring of Additional Parameters:

The monitoring for additional parameters in ambient air namely Ozone, Lead, Ammonia, Arsenic, Benzene, Nickel &Benzo(a)pyrene was conducted within the project premises (A1 location). It can be stated that concentration of Benzene, Benzo(a) pyrene & Ammonia was found to be below the detection limit. The values of Ground level ozone were estimated to be within the range of 21 to 30.6 µg/m3. The average concentration was computed to be 25.5 µg/m 3. The presence of heavy metals such as lead, arsenic and nickel were estimated to be below the detectable limits and thus their presence can be said to be negligible. As mentioned earlier the concentration of VOCs was also monitored at the project site. The results revealed that the concentration was found to be below the detection limit as presently. The analysis of additional parameters monitored for ambient air quality at the location A1 reveals that the values did not exceed the limits prescribed by CPCB, during the sampling period.

Sadekar Enviro Engineers Pvt. Ltd. ES- 13

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

ES-5.2 Noise Environment

Noise monitoring was conducted as per the standard operating procedures.

Industrial Zone The day time noise level at the project premises was observed to be 72.0 dB (A) while during night time the noise level was recorded to be 61.0 dB (A). It should be noted that the noise levels during the day time as well as night time were estimated to be under the prescribed standards by Central Pollution Control Board. Residential Zone The noise monitoring conducted at seven locations for 24hr, once in a week and average hourly readings were recorded. The minimum noise level recorded during the daytime was observed at location N4, where as the maximum noise levels can be observed at location N5. The location N5 is densely populated and hence can give rise to high noise level in the surroundings. It should be noted that the permissible limits for noise did not exceed at any of the locations selected for sampling.

Sadekar Enviro Engineers Pvt. Ltd. ES- 14

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

Figure No.ES-4: Noise Monitoring Locations on Google Earth

Table ES-10 Noise Monitoring Results Daytime/ Night Time/ Location Code Location Code Noise in dB(A) Leq 72.0/N1 61.0/N1 (Industrial Zone) Highest Noise indB(A) Leq 55.0/N5 44.7/N5

Sadekar Enviro Engineers Pvt. Ltd. ES- 15

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

(Residential Zone) Lowest Noise in dB(A) Leq 50.2/N4 40.3/N4 (Residential Zone) NAAQ Noise Limit 75 70 (Industrial Area) NAAQ Noise Limit (Residential Area) 55 45 Interpretation: Noise monitoring was conducted as per the standard operating procedures. The noise monitoring conducted at seven locations for 24hr, once in a week and average hourly readings were recorded. It should be noted that the noise levels during the day time as well as night time were estimated to be under the prescribed standards by Central Pollution Control Board. The minimum noise level recorded during the daytime was observed at location N4, where as the maximum noise levels can be observed at location N5. The location N5 is densely populated and hence can give rise to high noise level in the surroundings.

Note: Monitoring & Analysis performed by Sadekar Enviro Engineers Pvt. Ltd, Laboratory.

ES-5.3 Water Environment

 Surface Water Study

Sadekar Enviro Engineers Pvt. Ltd. ES- 16

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

Figure No.ES-5: Surface Water Monitoring Locations on Google Earth

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

Table ES-11:Surface Water Quality Results

Lowest Conc./ Highest Conc./ SW Parameters Unit Location Code Location code pH - 7 / (SW-1) 8.2/(SW-5) Total Dissolved Solids mg/lit 180/ (SW-6) 319/(SW-3) Chlorides as Cl- mg/lit 21/ (SW-7) 64/(SW-3)

- Sulphate as SO4 mg/lit 2.7/ (SW-7) 20.8/(SW-5)

Total Hardness as CaCO3 mg/lit 81.6/ (SW-8) 130/(SW-3)

Nitrate as NO3 mg/lit 2.3/ (SW-8) 7/(SW-1) Fluoride as F- mg/lit 0.227/ (SW-8) 0.454/(SW-3) Arsenic as As mg/lit <0.01 at all locations

PO4-- mg/lit 41/ (SW-8) Bicarbonates mg/lit 71/ (SW-8) 102/(SW-2) Calcium as Ca mg/lit 16.5/ (SW-2) 30.18/(SW-7) Cadmium as Cd mg/lit <0.03 at all locations Iron as Fe mg/lit <0.30 at all locations Lead as Pb mg/lit <0.01 at all locations Magnesium as Mg mg/lit 8.3/(SW-2) 17/(SW-5) Chromium as Cr mg/lit <0.05 Present at all locations Mercury as Hg mg/lit <0.001 at all locations K+ mg/lit 0.33/(SW-1) 1.7/(SW-2 & SW-5) Nickel as Ni mg/lit <0.02 Present at all locations Na+ mg/lit 8.3/(SW-3) 32.6/(SW-2)

Sadekar Enviro Engineers Pvt. Ltd. ES- 18

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Executive Summary

Zinc as Zn mg/lit <0.1 at all locations Total coliforms at 370C for Org/100ml 13/(SW-6) 92/ (SW-4) 48 hrs. Present (SW-2 to SW-5) Ecoli at 44.50C for 24hrs. Org/100ml Absent ( SW-6 to SW8 & SW-1) COD mg/lit <4.0/(SW-6 & SW-8) 90/(SW-4) BOD mg/lit <3.0/( SW-6 & SW-8) 32.1/(SW-4) DO mg/lit 6.1/(SW-4) 6.7/(SW-5)

Interpretation: The values obtained are compared with the IS: 2296–1982_Inland_Surface_Water_standards prescribed for the respective designated use of the water body. (Mentioned in the chapter 3, Table No. 3.10.

The presence of heavy metals like Arsenic, Mercury, Lead, Chrominum, Zinc, Nickel & Cadmium were found out be below the detection limit for all the water samples. It should be noted that the iron content in all the samples of surface water bodies were below the detection limit. Fluoride was detected in lower concentrations ranging from 0.227-0.454 mg/l. The nitrate concentration was observed to be in the range of 2.3 – 7.5 mg/l. Surface runoff from agricultural fields using the fertilizers can be the major source of nitrate. The microbiological samples for total coliforms were in the range of 13-92 org/100 ml and E-coli was found to be present in SW-2 to SW-5 in the rest of the samples it was absent.

It should be noted that in case of the selected water bodies (SW-1 to SW-5) classified under category “E”, the parameters were found to be within the prescribed limits. The results for location SW-6 , SW-7 & SW8 categorized in category “B” indicated that all the parameters were found to be within the prescribed limits except for SW-7 the BOD value was above the prescribed limit. Hence for SW-7 the water can be continued for its designed use as per Inland Surface Water Standards after disinfection and necessary treatment.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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 Ground Water Study

Figure No.ES-6: Ground Water Monitoring Locations on Google Earth

Table ES-12:Ground Water Quality Results Lowest Conc./ Highest Conc./ SW Parameters Unit Location Code Location code

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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pH - 7.8/(GW-7) 8.5/(GW-1) Total Dissolved Solids mg/lit 258/(GW-4) 390/(GW-3) Chlorides as Cl- mg/lit 17/(GW-8) 42/(GW-4)

- Sulphate as SO4 mg/lit 1.6/(GW-3) 56.2/(GW-6) Total Hardness as mg/lit 104/(GW-2) 177/(GW-3) CaCO3

Nitrate as NO3 mg/lit 2/(GW-5) 9.3/(GW-2) Fluoride as F- mg/lit 0.20/(GW-8) 0.434/(GW-4) Arsenic as As mg/lit <0.01 at all locations Cadmium as Cd mg/lit <0.003 at all locations Calcium as Ca mg/lit 13.1/(GW-3) 52.2/(GW-6) Iron as Fe mg/lit <0.3 at all locations Nickel as Ni mg/lit <0.02 at all locations Lead as Pb mg/lit <0.01 at all locations Mercury as Hg mg/lit <0.001 at all locations Magnesium as Mg mg/lit 8.4/(GW-4) 17.8/(GW-1) Zinc as Zn mg/lit <0.1 at all locations Total coliforms at 370C Org/100ml 15/(GW-5) 26/(GW-2) for 48 hrs. E.-coli at 44.50C for Org/100ml Absent 24hrs. COD mg/lit <4.00 at all locations BOD mg/lit <3.00 at all locations Sodium mg/lit 12.2/(GW-8) 30.2/(GW-4) Potassium mg/lit 0.3/(GW-3) 5.4/(GW-6)

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Phosphate mg/lit 8.6/(GW-7) 27.6 (GW-4) Bicarbonate mg/lit 78/(GW-7) 190(GW-6) Chromium mg/lit <0.05 at all locations

Interpretation: The values obtained are compared with the IS: 10500:2012.

The concentration of heavy metals like arsenic, zinc, chromium, lead, mercury, nickel & cadmium were below detection limit. Iron was not detected in any of the ground water samples. The hardness of all the ground water samples was found to be ranging between 104-177 mg/lit. The value of hardness was within the acceptable limit at all the locations. It can be observed that the values for total dissolved solids in all the sampling locations were estimated to be under the acceptable standards for drinking water. The concentration of total dissolved solids ranged between 258-390 mg/lit. The maximum concentration was observed at location GW 3 whereas the minimum concentration was observed at GW4. It should be noted that the microbiological analysis of allthe samples indicate that e-coli was absent in all the ground water samples. The presence of total coliforms except for GW1 ,GW6& GW8 were in the range from 15-26 Org/100 ml indicate that the anthropogenic activity in the surrounding area can be a possible source of contamination. It should be noted that the concentration of the coliforms were higher in the dugwell compared to the concentrations observed in the borewell samples. The fluoride concentrations are ranging between 0.20 - 0.434 mg/l. The presence of the fluoride in all the water samples is mostly due to geogenic in nature. The nitrates concentrations were ranging between 2.0 - 9.3 mg/l well below the acceptable limits of drinking water. The probable sources of nitrates in the ground water could be the use of fertilizers in the nearby agricultural activity. The COD and BOD values of all the ground water samples were found to be below the detection limit. Thus based on the above results it can be stated that the water from the said samples can be considered fit for consumption and potable purpose with basic primary treatment. The water can be used for domestic utilization and gardening without any treatment.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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ES-5.4 Soil Environment

Figure No.ES-7:Soil Quality Sampling Locations on Google Earth

Table ES-13: Analysis of Soil Samples Parameters Unit LowestConcentration HighestConcentration pH - 7.4 8.0

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Moisture Content % 3.8 5.3 Organic matter % 1.6 41.8 Exchangeable Calcium as mg/kg 35.3 47 Ca Color - Reddish brown at all the locations

Soil texture - Sandy Loam at all the locations

Electrical Conductivity mS/cm 0.50 0.61

Water holding Capacity % 50 63

Arsenic as As mg/kg ND at all the locations

Cadmium as Cd mg/kg ND at all the locations

Chromium as Cr mg/kg ND at all the locations

Lead as Pb mg/kg ND at all the locations

Magnesium as Mg mg/kg 65.4 79.6

Iron as Fe mg/kg 1.19 2.92

Potassium as K Kg/ha. 63 81

Total Nitrogen Kg/ha. 179 272

Phosphate as PO4- Kg/ha. 2.1 4.1

Cation exchange capacity me/100g 20.3 30.6

SAR - 13.3 21.4

Interpretation: The findings of the study reveal that pH of the soil in the study area ranged between 7.4 – 8 which is an indicative of the neutral to moderately alkaline nature of soil. The values for Nitrogen at all locations varied between 179 to 272 kg/ha. Maximum concentration of nitrogen was observed at location S3.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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The concentration of phosphate was estimated to be between 2.1 to 4.1Kg/ha.The highest concentration can be observed at location S7, while the lowest concentration can be observed at location S1. It is important to note that the concentration of potassium was found to be high at all locations ranging between 63 to 81 Kg/ha. Based on the above findings it can be concluded that the soil samples can be classified as per soil classification given by Tondon H.L.S. (2005). The samples fall under very low to medium low fertile soils. The presence of heavy metals like arsenic, cadmium, lead & chromium in all the soil samples were below the detection limit. Note: Monitoring & Analysis performed by Sadekar Enviro Engineers Pvt. Ltd, Laboratory.

ES-5.5 Biological Environment

The proposed project is located in notified MIDC Mahad and being an expansion project does not involves any sort of clearing/felling activities. The project during operational phase does not envisage discharge/disposal of any sort of liquid (effluent) or solid (hazardous waste) on the ground or in the water bodies within the study area since the additional effluent generated from the expansion will be completely reused & hazardous waste will be disposed to Mumbai Waste Management Ltd. - CHWTSDF, Taloja also any species of conservation concern is not present within the study area & moreover & the project plot being located well within precincts of MIDC area no adverse impacts are anticipated on the biotic environment.

ES-5.6 Socio Environment

The data collected by the assessment tool had three variables namely; accessibility of public resources and its satisfaction, impact of expansion activity and attitude towards expansion project of AstecLifesciences Ltd. The data of 50 participants was put for correlation analysis.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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The data was found to be normally distributed hence; the data fulfils the assumptions of parametric statistics. Based on this information Pearson product-moment correlation was conducted.

It is found that accessibility of public resources and its satisfaction is significantly correlated in positive direction with impact of AstecLifesciencesLtd.activity (r = 67; p = .02). This indicates that accessibility of public resources will lead to low impact of industry activities and vice versa. Accessibility of public resources and its satisfaction is also found to be significantly correlated with attitude towards AstecLifesciencesLtd.activity (r = -.46; p = .04) but in negative direction. This indicates that accessibility to public resources there is positive inclination for AstecLifesciencesLtd.activity in the study area. Further, it is also found that impact of expansion project activity is significantly correlated with attitude towards industrial activity (r = -.45; p = .01). This indicates that due to low impact there is positive attitude towards among the participants in the study area (Table ES-14).

Table No. ES -14Indicating Pearson’s correlation among variables (N=50)1 Attitude towards Accessibility & Impact proposed activity of satisfaction AstecLifesciencesLtd. Accessibility & Satisfaction 1.2 - - Impact 0.69** 1 - Attitude towards proposed activity of -.45* -.46 1.3 AstecLifesciencesLtd. * Correlation is significant at the 0.05 level. ** Correlation is significant at the 0.01 level.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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ES-6Prediction of Impacts & Mitigation Measures

The summary of mitigation measures is presented in tabulated format in Table ES-3

Table No. ES-15: Summary of Impacts & Mitigation Measures

Operational Phase

Sr. Environmental Aspect Anticipated Impacts Proposed Mitigation No. Parameters Attributes Measures 1. Air Quality Operation of The Maximum To ensure proper Boilers, Thermic Incremental dispersion of flue gases in fluid heaters, concentration of 3 atmosphere, provision of D.G sets and PM10 -2.22821ug/m 3 stacks of following height Gaseous SO2 -4.63488 ug/m emission from NOx- 1.70747 ug/m3 as per CPCB guidelines: manufacturing CO - 29.3269ug/m3 process, Non 1. Stack No. 1 : 30 m spontaneous The Health effects Stack for 6 TPH boiler emissions from related to particulate transportation of matter are majorly 2. Stack No. 2 : 24m raw materials & respiratory, stack for 850 kg/hr boiler finished goods. pulmonary injury VOC emission &lung cancer etc. generated due to Exposure to SO2 and 3. Stack No. 3 : 39 m the handling and NOx majorly leads to stack for 15 TPH boiler storage of the respiratory problems. solvents & other Carbon monoxide 4. Stack No.4: 27 m raw materials. decreases the oxygen common stack for TFH’s carrying capacity of of 6 & 2 lackhkilo.cal./hr. the blood by reducing the hemoglobin. The health effects related 5. Stack No. 5 : 3.5 m to VOC emission are stack above roof for D.G eye, nose and throat of 250 kVA irritation headaches, loss of coordination 6. Stack No. 6 : 4.5 m and nausea, damage to

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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liver, kidney and stack above roof for D.G central nervous of 500 kVA system etc. Exposures to high 7. Stack No.7: 5.0 m concentrations of stack above roof for ammonia in air may process scrubber. cause immediate burning of nose, 8. Roads within plot throat & respiratory premises will be tract which may cause concreted / paved to bronchiolar and avoid the dust generation alveolar edema and from day to day vehicular airway destruction activity. resulting in respiratory disease or 9. It will be ensured that failure. Inhalation of all the vehicles used for lower concentrations transportation activity can cause coughing have a valid PUC and nose and throat (Pollution under Control) infection. Certificate.

The air emissions in 10. Proper servicing & long course of time maintenance of vehicles may affect the is carried out. Same vegetation stature practice will be continued physically (leaf in future. senescence, hampered growth etc.)& 11. Regular sweeping of biologically in all the roads & floors is downwind direction being /will be done. which may result in affecting overall 12. Development of the ecology of the region green belt along the plant in consideration. boundary will help to capture the fugitive emission.

13. To control VOC

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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emission carbon adsorption system can be implemented.

14. Industry to ensure that at no point of time the air emission concentrations does not exceed the prescribe standards. 2. Noise Quality Operation of The impacts of high 1. Acoustic enclosure will D.G sets, noise level can be be provided to D.G set for Boilers, Thermic Temporary/Permanent attenuation of noise level fluid heaters, hearing loss, during operation. Reactors, Mental disturbance 2. Boiler and Thermic ancillary utilities Increase in heart rate, fluid heaterwillbe placed & transportation Decrease in workers in a confined space viz. activity. performance due to boiler house where the psychiatric disorder, surrounding walls acts as Workers developing a barrier for noise Tinnitus due to high propagation. level of noise 3. Isolation of high exposure on regular intensity noise generating basis. equipment’s. 4. Appropriate traffic management to be implemented. 5. Green belt developed around the plot boundary will help to minimize the noise intensity propagating outside factory premises. 6. Appropriate PPEs should be provided to workers.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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3. Water Quality 1. Effluent from Unscientific/accidenta LCOD-LTDS effluent manufacturing l release/discharge of comprising of domestic process. effluents if finds its 2. Effluent from way to surrounding sewage & process Scrubber soils,surface/groundw effluent to the tune of operations. atermay lead to 3. Blow down contamination of the 51.3 CMD will be treated water from same there by in existing ETP 55 CMD Boiler and affecting the overall Cooling Tower. ecology & agricultural capacity comprising of 4.Domestic productivity of the primary, secondary & wastewater. area concerned. tertiary treatment scheme, permitted quantity of treated effluent will be sent to CETP for further treatment & disposal and remaining effluent will be recycled.

1.0 2. HCOD-HTDS effluent from manufacturing process will be subjected in plant stripper evaporator & condensate will be reused.

3. Cooling tower & boiler

Sadekar Enviro Engineers Pvt. Ltd. ES- 30

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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blow down will be reused for cooling tower operations.

4. Thus except for the consented treated effluent discharge quantity the additional treated effluent generated from the project activity will be reused.

Thus it will be ensured there will be no unscientific /accidental release/discharge of effluentsoutside the project premises. 4. Solid Waste 1. Used/ spent Unscientific handling 1. Hazardous Management - oil. may affect the health wastesgenerated from the Hazardous of workers coming in process such asResidues Waste 2. Residues & direct contact with the & Waste, Chemical Waste hazardous waste and sludge residue from may lead to skin pesticides, Asbestos 3.Chemical allergies/rashes/burns gaskets and Spent sludge residue etc.andindiscriminate/ Carbonwill be disposed to from pesticides accidental disposal of Mumbai Waste hazardous waste if Management - 4.Discarded finds its way to CHWTSDF, Taloja. containers surrounding soils, surface/groundwaterm 2. Hazardous wastes 5.Chemical ay lead to generated from effluent

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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sludge from ETP contamination of the treatment process such as same there by Chemical sludge from 6. Filter & filter affecting the overall ETP will be disposed to material having ecology & agricultural Mumbai Waste organic liquid productivity. Management - 7. Spent carbon CHWTSDF, Taloja.

8. Asbestos 3. Filter & filter material gaskets having organic liquid, will be disposed to 9. Spent Mumbai Waste Solvents Management - CHWTSDF, Taloja.

4. Hazardous wastes such as Used/ spent oil, Discarded containers, Spent Solvents will be reused/recycled/sold to Authorized Parties or will be disposed to Mumbai Waste Management - CHWTSDF, Taloja. Solid Waste 1. Paper waste 1.Hap-Hazard Designated area for Scrap Management - (paper boxes and handling & storage materials will be provided Non Hazardous bags). may lead to in the plant. waste 2. Plastic waste. inadequate open space Scrap materials will be 3. Metal scrap. in plant premises & it recycled through 4.Wooden may lead to rodent registered scrap vendors. pellets. breeding Coal ash will be sold to 5. Coal ash. registered brick manufacturer. Daily housekeeping waste and food waste will be disposed through municipal waste management facility.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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ES-7 Risk Assessment Study Risks likely to pose harm to man, environment or property associated with various activities are addressed in this report. Such activities include transport, storage; handling and usage of hazardous raw materials &fuels etc. To calculate the risk involved in the process of the proposed project; ALOHA 5.2.2 is Figure No.ES-8:- Maximum credible Loss Scenario: performed for all storages in tank AstecLifeSciences Ltd. farm area. The MCLS (Maximum Credible Loss Scenario) for the factory works out to about 6 miles in case of Bromine (Evaporating puddle - Toxic area of vapour cloud). The Dow index has been calculated for storages of raw materials ingodown area and for fuel storages. Dow Index has been calculated separately for raw materials and fuel storages which are found to show Intermediatepotential. Mond's Index for the toxic material was performed and the toxicity falls in moderateof the Toxicity Index for all the chemicals. Appropriate preventive and mitigation measures have been provided to cater all the hazards. Hazop Study has been prepared for the products.

ES-8Disaster management plan In view of the chemical industry, Onsite and Offsite Emergency Plans are important hence, has been prepared for the industry. Duringoperational phase, surrounding population shall be made aware of safety precautions to be taken in case of any emergency situation due to the overall

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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project activity. On-site disaster management plan and Off-site emergency management plan, commands communication and controls will be established and maintained. Adequate provisions like emergency response, response organization, response plan, Material Safety Data Sheets (MSDs), command and control, capabilities, transportation, medical facilities, mitigation measures, training, education, public awareness emergency plan review etc. to control any disaster situation will be made available.

ES-9CSR Activity

After accomplishment of proposed expansion company is willing to do following ESC activities:

Education & skill development

 Provision of need based amenities to school in project area. Health awareness

 Provision of need based amenities to Rural Government Hospital in project area.

The proposed CSR activities and the budgetary allotment for the same is presented in Table ES- 16 Table No. ES-16: Year wise details of CSR Activities

Year of Implementation Amount in Lakhs Activity Providing basic amenities to the ZP School of GandharpaleAdiWadi as under: 2019 5 Lakh 1. Safe Drinking water System. 2. Providing new benches 5.17 Lakh Providing basic amenities to the Mahad 2020 Government Rural hospital.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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ES-10Occupational Health Measures

The company will strictly adhere to the rules of Factories Act 1948 & the Maharashtra Factories Rules, 1963 regarding the occupational health facilities to be provided to the workers of the company. The industry has provided decontamination facilities for the workers. The health records of the workers would be maintained. For the continuous and continual development, the company will train &educate the operators and workers with the environment, health &safety rules & regulation, procedure and measures.

ES -11Post Project Monitoring Plan

Monitoring of environmental parameters shall be done as per the guidelines provide by MoEF&CC/CPCB/MPCB. The method followed shall be recommended / standard method approved/recommended by MoEF&CC/CPCB. The Table ES-17 explains the approach for environmental monitoring program.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Table No. ES-17: Environmental Monitoring Program

Number Sr. Particulars Pollutant Pollutant Characteristics of Frequency No Samples CO, SO2, NOX, PM,CO, Benzene, Ammonia, 1 Ambient Air Air Emission Benzopyrene, Lead, Nickel, 3 Quarterly Arsenic, Ozonein Ambient Air DG Set, Boilers SO , NO , SPM 2 Stack 2 X 2 &TFHs Monitoring Scrubber Acid Mist 1 Air emissions Quarterly Methanol, Ammonia, Volatile 3 Work place Sulphuric acid, Methyl Organic 1 Chloride, Toluene, Compounds Chloroform & Xylene Boiler/TFH area, D.G Set, 3 Sound Noise Level dB (A) 4 Quarterly ETP, Work Place Area

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Number Sr. Particulars Pollutant Pollutant Characteristics of Frequency No Samples pH, O & G, TDS, TSS, 4 Effluent Treatment Plant All parameters COD, BOD & Bioassay 1 Weekly specific to project Used/ spent oil, Residues & Waste, Chemical sludge residue from Pesticides, Chemical sludge from Once in a 5 Hazardous Wastes H.W. characteristics 5 ETP, Filter & filter material having Year organic liquid, Spent carbon, Asbestos gaskets & Spent Solvents

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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ES - 12 EMP Cost& Budgetary Allocation

The proposed capital investment of the company is envisaged to be 10.17 Crore and the proposed capital investment for Environmental Pollution Control Measures is around 60 lakhs.The cost details for Environmental Management are as under in Table ES-18

Table No. ES-18: Cost details for Environmental Management Sr. Particulars Capital Cost Recurring Cost No. (Rs.) per annum (Rs.) 1 Air Pollution Control 32,00,000.00 1,13,000.00

2 Water Pollution Control 13,00,000.00 2,50,000.00

3 Noise Pollution Control 2,00,000.00 47,000.00

4 Environment Monitoring and -- 15,00,000.00 Management 5 Occupational Health 4,00,000.00 1,00,000.00

6 Green Belt 6,00,000.00 3,50,000.00

7 Solid Waste Management 3,00,000.00 1,50,000.00

Total (Rs.) 60,00,000.00 25,10,000.00

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B‐16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 1: Introduction

Chapter 1 – Introduction

1.1 Purpose of the project

M/s. Astec LifeSciences Ltd. (ALL) incorporated under the Companies Act 1956 on 25th January 1994 as is currently engaged in manufacture of Pesticides& Formulation products& is a global supplier of pesticides &chemical intermediatesacross the world, with an operational experience of more than 24 years company has witnessed a steadyincrease in demand of products manufactured by Astec in domestic as well as international markets.

Astec LifeSciences Ltd. aims to expand its manufacturing portfolio by increasing the production quantity of its existing products & by addition of new productsin order to cater domestic & international market needs. Products manufactured by ALL will serve to cut the supply of imports from foreign countries thus saving currency and at the same time will earn valuable foreign currency by export of the proposed products. These business sustenance measures by ALL justify the purpose of project.

1.2 Information about project proponent

Mr. Ashok Hiremath, Managing Director, Astec LifeSciences Ltd., is a Masters of Arts from University of Oxford and Post Graduate Diploma holder in Chemical Engineering from University College, University of London. He started his career as Project Engineer in 1978 with GEA Air exchangers Ltd., London. He returned to India in 1980 and joined Hiremath Chemicals Ltd., a company promoted by his brother as Technical Manager where he was responsible for manufacturing and business development. After leaving this company in 1994 from the post of Technical Manager, he established Astec LifeSciences Ltd. as one of the promoters and since then he has been actively involved and played a key role in the growth of the Company with his inputs in strategic planning and business development.

Through the efforts of continuous development the company plans to strengthen its position in international market. The list of directors as on date is attached is Annexure 1.1.

Sadekar Enviro Engineers Pvt. Ltd Chapter 1‐1 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B‐16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 1: Introduction

1.3 Brief description of nature, size, location of the project and its importance to the country, region.

1.3.1 Nature of the project

Nature of the project in consideration is of pesticides & chemical intermediates manufacturing type which involves chemical reactions like bromination, hydrolysis and physical processes like quenching, distillation, crystallization, solvent recovery, washing, separation & drying. Since the proposed activity of production capacity enhancement is to be executed within an existing manufacturing unit, it is a brown field activity.

1.3.2 Size of the project

The proposed activity is of production capacity enhancement from existing production capacity of 219.00 MT/M to total 781.00 T/M of pesticides & chemicals intermediatesalong with bi-products to the tune of 1,774.00 will also be generated and existing production of formulation products to the tune of 700 MT/M will be continued, however of the 4 formulation products, production Wettable Powder (WP/SP) will be reduced from 150 to 100 MT/M & subsequently production of Liquid Products (SC/SL) will be increased from 200 to 250 MT/M.

The production capacity enhancement will be achieved within existing manufacturing unit of ALL located at plot no. B-16, 17, 18 & 21 MIDC Mahad Dist. - Raigad, Mahharashtra admeassuring an area of 13,950.0 sq.m.and the estimatedbudgetary cost for expansion activity is 10.17 Crore.

1.3.3 Location of the project

The proposed expansion activity will be achieved within existing manufacturing unit located atplot no. B-16, 17, 18 & 21 MIDC Mahad Dist. - Raigad, Maharashtra, the center point GPS coordinates of the project site are Latitude: 18° 6'3.46"N& Longitude: 73°29'23.54"E and project site is covered under Survey Of India toposheet no. 47F/8.

Sadekar Enviro Engineers Pvt. Ltd Chapter 1‐2 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B‐16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Mahad is accessible by National Highway 66 whichis further connectedMahad MIDC industrial area by Mahad – Solamkund Road & the further access to project site is led by internal MIDC road. Project location is also accessible through Veer railway station and the nearest airport is Pune airport which is approximately 129 km from Mahad city.

1.3.4 Importance to the country

India's Chemical industry is the third largest in the world in terms of volume & is ranked 14 in terms of value. India is also one of the top five active Chemical ingredients producers (with a share of about 6.5%). The ever-increasing demand for Pesticides and Intermediated in India and abroad as well as changing market conditions requisite Indian Chemical industries to grow further. ALL is a global supplier of Pesticides and chemical intermediate to the other chemical companies worldwide and aims to expand its product portfolio further in order to cater to Domestic &International markets by expanding its production capacities. These products will serve to cut the supply of imports from foreign countries thus saving currency and at the same time will earn valuable foreign currency by export of the proposed products.

1.4 Scope of the study

As per the Environment Impact Assessment Notification dated 14th September 2006 the proposedexpansion activity of manufacturing pesticides & chemical intermediates comesunder Schedule 5(b) -Pesticides industry and pesticide specific intermediates (excluding formulations), Category - A which entail prior Environmental Clearance from Expert Appraisal Committee, however project site being located within Mahad MIDC which was notified before EIA Notification 2006 being coming into force hence the proposed activity is exempted from public hearing the relevant documents justifying the same are attached as Annexure 1.2. None of theproject related activities can be carried out except securing the land until the project is accorded prior Environmental Clearance from Expert Appraisal Committee as per the EIA Notification dated14th September 2006 hence in order to

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assess the probable environmental impacts due to the proposed expansion activity; preparation of Environmental Impact Assessment (EIA) report is requisite.

Accordingly application seeking prior environmental clearance was submitted to MoEF&CC on 23rd December 2017& project was accorded ToR vide No.IA-J-11011/584/2017-IA- II(I)by MoEF&CC on 15th February 2018 wherein MoEF&CC has accorded standard ToR with public consultation being prescribed for preparation of EIA report.

Thus Environment Impact Assessment report is prepared based on Standard ToR by MoEF& CC dated April 2015 with objectives as follows in order to assess the probable environmental impacts due to the proposed project:

 Assessment of the background concentration of the pollutants around the 10 km study area of the project site.

 Ensuring environmental factors are considered in the decision-making process during the planning and designing stage of the project.

 Avoid serious and irreversible damage to the environment.

 Identify and quantify potential sources and determine the significance of impacts on sensitive receptors.

 Identify and quantify any potential losses or damage to flora, fauna and natural habitats.

 Identify any impacts on sites of cultural heritage and to propose measures to mitigate these impacts.

 Identify, describe and quantify any potential landscape and visual impacts and evaluate the significance of impacts on sensitive receivers.

 Identify & quantify anticipated risk & hazard in the operating phase of the project & recommending appropriate mitigation measures to minimize the impact.

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 Identify, predict and evaluate the environmental impacts and the cumulative effects expected to arise during the construction and operation phases of the proposed developments in relation to the sensitive receptors.

 Identify, assess and specify methods, measures and standards, to be included in the detailed design, construction and operation of the proposed developments which are necessary to mitigate these environmental impacts and reducing them to acceptable levels.

 Delineation of environmental management plan (EMP) outlining prevention and control strategies for minimizing adverse impacts of the project.

 Formulation of environmental quality monitoring program for operational phases to be pursued by the project proponent.

1.4.1 Standard ToR by MoEF& CC dated April 2015

Table No.1.1: Compliance of Standard TOR Sr. Standard TOR Compliance No. 1 ExecutiveSummary of EIA report 2 Introduction Details of the EIA Consultant including NABET accreditation Chapter 1 Information about the project proponent Chapter 1 Importanceandbenefitsoftheproject Chapter 1 & Chapter 8 3 Project Description Cost of project and time of completion. Chapter -2 Products with capacities for the proposed project Chapter - 2. If expansion project, details of existing products with capacities Chapter - 2 and whetheer adequate land is available for expansion, reference of earlier EC if any. List of raw materials required and their source along with mode Chapter - 2 of transportation Other chemicals and materials required with quantities and storage capacities Details of Emission, effluents, hazardous waste generation and Chapter - 2. their management.

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Requirement of water, power, with source of supply, status of Chapter - 2 approval, water balance diagram, man-power requirement (regular and contract) Process description along with major equipment’s and Chapter - 2 and machineries, process flow sheet (quantitative) fromo raw Annexure 2.5 material to products to be provided. Hazard identification and details of proposed safety systems Chapter - 7 Expansion/modernizationproposals: Copy of all the Environmental Clearance(s) including Chapter - 2 and Amendments thereto obtained for the project from Annexure – 2.3 MOEF/SEIAA shall be attached as an Annexure. A certified copy of the latest Monitoring Report of the Regional Office of the Ministry of Environment and Forests as per circulaar dated 30thMay, 2012 on the status of compliance of conditions stipulated in all the existing environmental clearances including Amendments shall be provided. In addition,statusofcomplianceofConsenttoOperatefortheongoing/ existingoperationof the project from SPCB shall be attached with the EIA-EMP report In case the existing project has not obtained environmental Chapter - 2 and clearance, reasons for not taking EC under the provisions of Annexure – 2.3 the EIANotification1994and/orEIANotification2006 shall be provided. Copies of Consent to Establish/No Objection Certificate and Consent to Operate (in case of units operating prior to EIA Notification 2006, CTE and CTO of FY2005- 2006)obtained from the SPCB shall be submitted. Further, compliance report to the conditions of consents from the SPCB shall be submitted. 4 Site Details Location of the project site covering village, Taluka/Tehsil, Chapter - 2 and Chapter District and State, Justification for selecting the site, whether - 5 other sites were considered. A toposheet of the study area of radius of 10 km and site Chapter - 2. locationon1:50,000/1:25,000scale on anA3/A2 sheet. (including all eco-sensitive areas and environmentally sensitive places) Details w.r.t. option analysis for selection of site Chapter - 5 Co-ordinates (lat-long) of all four corners of the site Chapter - 2 Google map-Earth downloaded of the project site. Chapter - 2 Lay out maps indicating existing unit as well as proposed unit Chapter - 2 indicating storage area, plant area, green beelt area, utilities etc. If located within an Industrial area/Estate/Complex, layout ofIndustrialAreaindicatinglocationofunitwithintheIndustrialarea/

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Estate. Photographs of the proposed and existing (if applicable) plant site. If existing, show photographs of plantation/greenbelt, in particular. Land use break up of total land of the project site (identified and Chapter - 2. acquired),government/ private-agricultural, forest, wasteland, water bodies, settlements, etc shall be included.(not required for industrial area) A list of major industries with name and type within study area Chapter - 2. (10kmradius) shall be incorporated. Land use details of the study area Geological features and Geo-hydrological status of the study Chapter - 3 area shall be included Details of Drainage of the project up to 5 km radius of study Chapter - 3 area. If the site is within1km radius of any major river, peak and lean season river discharge as well as flood occurrence frequency based on peak rainfall data of the past 30 years. Details of Flood Level of the project site and maximuum Flood Level of the river shall also be provided. (mega greenfield projects) Status of acquisition of land. If acquisition is not complete, Chapter 2 stage of the acquisition process and expected time of complete possession of the land. R&R details in respect of land in line with state Government policy. 5 Forest and wildlife related issues (if applicable): Chapter - 3

6 Environmental Status Determination of atmospheric inversion level at the project site Chapter - 4 and site-specific micrometeorological data using temperature, relative humidity, hourly wind speed and direction and rainfall. AAQ data (except monsoon) at 8 locations for PM10, PM2.5, Chapter - 3 SO2, NOX, CO and other parameters relevant to the project shall be collected. The monitoring stations shall be based on CPCB guidelines and take into account the pre-dominant wind direction, population zone and sensitive receptors including reserved forests. Raw data of all AAQ measurement for 12 weeks of all stations Chapter 3 as per frequency given in the NAQQM Notification of Nov. 2009 along with - min., max., average and 98% values for each of the AAQ parameters from data of all AAQ stations should be provided as an annexure to the EIA Report.

Sadekar Enviro Engineers Pvt. Ltd Chapter 1‐7 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B‐16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Surface water quality of nearby River (100m upstream and Chapter – 3 downstream of discharge point) and other surface drains at eight locations as per CPCB/MoEF& CC guidelines. Whether the site falls near to polluted stretch of river identified Chapter - 3. by the CPCB/MoEF&CC, if yes give details. Ground water monitoring at minimum at 8 locations shall be Chapter - 3 included. Noise levels monitoring at 8 locations within the study area. Chapter - 3 Soil Characteristic as per CPCB guidelines. Chapter -3 Traffic study of the area, type of vehicles, frequency of vehicles Chapter - 3. for transportation of materials, additional traffic due to proposed project, parking arrangement etc. Detailed description of flora and fauna (terrestrial and aquatic) Chapter - 3 existing in the study area shall be given with special reference to rare, endemic and endangered species. If Schedule-I fauna are found within the study area, a wildlife Conservation Plan shall be prepared and furnished. Socio-economic status of the study area. Chapter - 3

7 Impact and Environment Management Plan Assessment of ground level concentration of pollutants from the Chapter - 4 and stack emission based on site-specific meteorological features. In Annexure 4.1 case the project is located on a hilly terrain, the AQIP Modelling shall be done using inputs of the specific terrain characteristics for determining the potential impacts of the project on the AAQ. Cumulative impact of all sources of emissions (including transportation) on the AAQ of the area shall be assessed. Details of the model used and the input data used for modelling shall also be provided. The air quality contours shall be plotted on a location map showing the location of project site, habitation nearby, sensitive receptors, if any. Water Quality modelling - in case of discharge in water body Chapter - 4 Impact of the transport of the raw materials and end products on the surrounding environment shall be assessed and provided. In Chapter - 4 this regard, options for transport of raw materials and finished products and wastes (large quantities) by rail or rail-cum road transport or conveyor cum rail transport shall be examined. A note on treatment of wastewater from different plant Chapter 4 operations, extent recycled and reused for different purposes shall be included. Complete scheme of effluent treatment. Characteristics of untreated and treated effluent to meet the prescribed standards of discharge under E(P) Rules.

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Details of stack emission and action plan for control of Chapter 3 and Chapter emissions to meet standards. 4 Measures for fugitive emission control Chapter 4 Details of hazardous waste generation and their storage, Chapter 4 and Chapter utilization and management. Copies of MOU regarding 10 utilization of solid and hazardous waste in cement plant shall also be included. EMP shall include the concept of waste- minimization, recycle/reuse/recover techniques, Energy conservation, and natural resource conservation. Proper utilization of fly ash shall be ensured as per Fly Ash Chapter -10 Notification, 2009. A detailed plan of action shall be provided. Action plan for the green belt development plan in 33 % area Chapter - 10 i.e. land with not less than1,500 trees per ha. Giving details of species, width of plantation, planning schedule etc. shall be included. The green belt shall be around the project boundary and a scheme for greening of the roads used for the project shall also be incorporated. Action plan for rainwater harvesting measures at plant site shall Chapter - 10 be submitted to harvest rainwater from the roof tops and storm water drains to recharge the ground water and also to use for the various activities at the project site to conserve fresh water and reduce the water requirement from other sources. Total capital cost and recurring cost/annum for environmental pollution control measures shall be included. Chapter - 10 Action plan for post-project environmental monitoring shall be Chapter - 6 submitted. Onsite and Offsite Disaster (natural and Man-made) Chapter - 7 Preparedness and Emergency Management Plan including Risk Assessment and damage control. Disaster management plan should be linked with District Disaster Management Plan. 8 Occupational health Plan and fund allocation to ensure the occupational health & Chapter 10 safety of all contract and casual workers

Details of exposure specific health status evaluation of worker.

If the workers' health is being evaluated by pre designed format, chest x rays, Audiometry, Spirometry, Vision testing (Far & Near vision, colour vision and any other ocular defect) ECG, during pre placement and periodical examinations give the details of the same. Details regarding last month analyzed data of above mentioned parameters as per age, sex, duration of exposure and department wise. Details of existing Occupational & Safety Hazards. What are

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the exposure levels of hazards and whether they are within Permissible Exposure level (PEL). If these are not within PEL, what measures the company has adopted to keep them within PEL so that health of the workers can be preserved. Annual report of heath status of workers with special reference to Occupational Health and Safety. 9 Corporate Environment Policy Does the company have a well laid down Environment Policy Chapter - 10 approved by its Board of Directors? If so, it may be detailed in the EIA report. Does the Environment Policy prescribe for standard operating process / procedures to bring into focus any infringement / deviation / violation of the environmental or forest norms / conditions? If so, it may be detailed in the EIA. What is the hierarchical system or Administrative order of the company to deal with the environmental issues and for ensuring compliance with the environmental clearance conditions? Details of this system may be given. Does the company have system of reporting of non compliances / violations of environmental norms to the Board of Directors of the company and / or shareholders or stakeholders at large? This reporting mechanism shall be detailed in the EIA report 10 Details regarding infrastructure facilities such as sanitation, fuel, restroom etc. to be provided to the labour force during construction as well as to the casual workers including truck drivers during operation phase. 11 Enterprise Social Commitment (ESC) Adequate funds (at least 2.5 % of the project cost) shall be earmarked towards the Enterprise Social Commitment based on Public Hearing issues and item-wise details along with time bound action plan shall be included. Socio-economic development activities need to be elaborated upon. Action Plan for CSR Activity Chapter - 10 12 Any litigation pending against the project and/or any direction/order passed by any Court of Law against the project, if so, details thereof shall also be included. Has the unit received any notice under the Section 5 of Environment (Protection) Act, 1986 or relevant Sections of Air and Water Acts? If so, details thereof and compliance/ATR to the notice(s) and present status of the case.

Sadekar Enviro Engineers Pvt. Ltd Chapter 1‐ 10 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B‐16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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1.4.2 Specific TOR by MoEF& CC dated April 2015

Table No.1.2: Compliance of Specific TOR by MoEF& CC Sr. No. Specific TOR Compliance 1 Commitment that no banned pesticides will Annexure 2.5 be manufactured. 2 Details on solvents to be used measures for Chapter 10 solvent recovery and for emissions control. 3 Details of process emissions from the Annexure 2.4 proposed unit and its arrangement to control. 4 Ambient air quality data should include Chapter 3 VOC, other process- specific pollutants* like NH3*, chlorine*, HCl*, HBr*, H2S*, HF*,etc.,(* as applicable) 5 Work zone monitoring arrangements for Chapter 3 hazardous chemicals. 6 Detailed effluent treatment scheme including Chapter 4 segregation of effluent streams for units adopting 'Zero' liquid discharge. 7 Action plan for odour control to be Chapter 4 submitted. 8 A copy of the Memorandum of -- Understanding signed with cement manufacturers indicating clearly that they co-process organic solid/hazardous waste generated. 9 Authorization/Membership for the disposal Annexure 4.2 of liquid effluent in CETP and solid/hazardous waste in TSDF, if any. 10 Material Safety Data Sheet for all the Chapter 7 Chemicals are being used/will be used. 11 Authorization/ Membership for the disposal Annexure 4.5 of solid/hazardous waste in TSDF 12 Details of incinerator if to be installed -- 13 Risk assessment for storage and handling Chapter 7 chemicals/solvents. Action plan for handling and safety system to be incorporated.

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14 Arrangement for ensuring health and safety Chapter 7 & Chapter 10 of workers engaged in handling of toxic materials.

1.5 Details of the EIA Consultant including NABET Accreditation

M/s Sadekar Enviro Engineers Pvt. Ltd. (SEEPL) established in the year 1998 is a NABET accredited EIA consultant Certificate No.NABET/EIA/1518/RA-020 valid up to14th, October 2018. The registered office of SEEPL is at 310, Dempo Towers, EDC Patto, Panaji – 403001, Goa State, India.

M/s SEEPL is accredited by QCI-NABET for the following sectors:

Table No.1.4: Details of Accreditation of SEEPL Sr. Name of Sectors Project/Activity as Category No per Schedule of EIA . Notification 1 MMining of Minerals 1 (a) i A 2 Offshore and onshore oil and gas exploration, 1 (b) A development & production 3 PPesticide Industry and pesticide specific 5 (b) A intermediates (excluding formulations) 4 Synthetic organic chemicals industry (dyes & 5 (f) A dye intermediates; bulk drugs and intermediates excluding drug formulations; synthetic rubbers; basic organic chemicals, other synthetic organic chemicals and chemical intermediates 5 Sugar industry 5 (j) B 6 Oil & gas transportation pipeline (crude and 6 (a) A refinery/ petrochemical products), passing through national parks/ sanctuaries/ coral reefs/ ecologically sensitive Areas including LNG terminal 7 Industrial estates/ parks/ complexes/Areas, 7 (c) A export processing Zones(EPZs), Special economic zones(SEZs), Biotech Parks, Leather Complexes 8 PPorts, Harbours, Jetties, marine terminals, break 7 (e) A waters and dredging

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9 Common municipal solid waste management 7 (i) B facility (CMSWMF) 10 BBuilding and large construction projects 8 (a) B including shopping malls, multiplexes, commercial complexes, housing estate 11 Township and area Development projects (8 (b) B

M/s SEEPL has a highly qualified team of Subject Experts. SEEPL has full-fledged laboratory recognized by Ministry of Environment, Forest and Climate Change (MoEFCC) & accredited by National Accreditation Board for Testing and Calibration Laboratories, (NABL). M/s SEEPL is also certified by ISO 9001:2008 and BS OHSAS 18001:2007.

M/s SEEPL is engaged in providing Turnkey projects of ETP & STP along with their Operation & Maintenance. Analytical Laboratoory Services of various elements and environmental parameters. Fabrication of air & water pollutions control devices. Annual monitoring as per MoEF&CC/CPCB (Central Pollution Control Board)/SPCBs (State Pollution Control Boards) guidelines, Consultancy for Hazardous waste management etc.

The NABET Certificate is attached herewith.

Sadekar Enviro Engineers Pvt. Ltd Chapter 1‐ 13 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B‐16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 2: Project Description

2.1 Type of project The project in consideration is of pesticides & chemical intermediates manufacturing type which involves chemical reactions like bromination, hydrolysis and physical processes like quenching, distillation, crystallization, solvent recovery, washing, separation & drying. Since the proposed activity of production capacity enhancement is to be executed within an existing manufacturing unit, it is a brown field activity and as per EIA Notification of 14th September 2006 the project activity comes under Schedule 5 (b) & Category A.

2.2 Need of the project Need of the project, can be justified by intention of the project proponent to manufacture pesticides products to reduce the existing market demand and supply gap. There are very few manufacturers of these products across the world. The consumption of these pesticides is increasing globally and is expected to increase further in the coming years.

Company management wants to manufacture pesticides and chemical intermediate at large capacity since the pesticides demand is increasing for agricultural and domestic use as well, company plans to enter in this field in future to capture vast market potential of technical grade pesticides.

The project will provide direct & indirect employment opportunities to local people and as the industry has the export market, it will add to the net foreign exchange earning of the country.

2.3 History of the project Astec LifeSciences Limited has been incorporated under the Companies Act, 1956 on 25th January 1994 at the time of inception in the year 1994, ALL was incorporated in the name

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and style of Urshilla Traders Private Limited subsequently company’s name was changed to Astec Chemicals Private Limited with effect from 19th August 1994 further Astec Chemicals private Limited was renamed to Astec LifeSciences Pvt. Ltd. with effect from 3rd March 2006 & Astec LifeSciences Private Limited was changed to Astec LifeSciences Limited with effect from 27th April 2007 wherein the total capital investment of Astec Chemicals Private Limited which was in existence in the year 1995 was less than Rs. 1 Crore hence as per EIA Notification 1994 Astec Chemicals Private Limited was exempted from obtaining environmental clearance.

The Certificate of Incorporation is attached as Annexure 2.1 & the balance sheet of company for the financial year ended 31st March 1995 is attached as Annexure 2.2.

ALL has obtained Maharashtra Pollution Control Board’s Consent To Operate “Consent order No: - Format1.0/AS/(T)/EIC No. RD-3108-15/Amend/CC-3030” dtd. 25/07/2016 and “Consent No: RO-Raigad/Consent/1803000437” dtd. 08-03-2018 for manufacture of 219 T/M pesticides & chemical intermediates and 700 T/M pesticide formulations respectively & compliance of consents is attached is Annexure2.6.

Now ALL has envisaged pesticides& chemical intermediates production capacity enhancement from existing 219 MT/M to 781 MT/M and formulation products to the tune of 700.0 MT/M along with generation of bi-products to the tune of 1773 MT/M within the existing manufacturing plant located at Plot No. B-16, 17, 18 & 21, MIDC Mahad, District Raigad, Maharashtra with an estimated budgetary project cost of Rs. 10.17Crore, thus ALL has not violated EIA Notification 1994 &/or 2006.

2.4 Size &magnitude of the project

Table2.1: Project details Sr. Particulars Details No. 1 Name M/s Astec LifeSciences Ltd.

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Plot No. B-16, 17, 18 & 21, MIDC Mahad,Mahad, Dist. - 2 Location Raigad, Maharashtra. 3 Product Type Pesticides, Chemical Intermediates & Formulations 4 Project Type Expansion 5 Schedule 5 (b) 6 Category A Land use Existing Proposed Total Area Details wise (Sq. m.) (Sq. m.) (Sq. m.) percentage 7 Total Plot Area 13,950.00 -- 13950.00 -- Built up Area 8544.00 -- 8544.00 61.24% Parking Area 166.00 -- 166.00 1.18% Green Belt Area 343.52 518.75 862.27 6.18 % Existing Proposed Total Production Capacity (MT/M) (MT/M) (MT/M) Pesticide Products 219.00 562.00 781.00 8 Pesticide Formulation 700.00 -- 700.00 Bi-Products -- 1773.00 1773.00 Total 919 2335 3254 9 Project cost (Indian Rs.) 10.17 Crore Capital cost: 60.0 Lakh, Recurring cost: 25.10 10 EMP cost(Indian Rs.) Lakh/Annum Existing Proposed Total Connected load: Connected Load: 11 Power Requirement (kVA) 1600 1600 -- Maximum Maximum demand: demand: 900 900 756.53 Recycled water = 309.3 CMD thus total water 12 Water Requirement (CMD) 352.67 403.63 requirement for expansion activity will be 447 CMD

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Furnace Oil 125.0 l/day 3483.12l/day 3608.12 l/day Coal 22.0 MT/day 35.0 MT/day 57.0 MT/day HSD 110 l/day 2700 l/day 2810 l/day 1 x 6 TPH 1 x 850 kg/hr. 1 x 15 TPH 1 x 2.5 TPH Fuel Steam 13 1 x 6 TPH 1 x 15 TPH Requirement Boiler Note: Existing 1 x 850 Kg/hr. boiler of 2 TPH will be discontinued 1 x 6 lakh kilo 1 x 6 lakh kilo Thermic cal./hr. cal./hr. -- fluid heater 1x 2 lakh kilo 1x 2 lakh kilo cal./hr. cal./hr. 1 x 250 1x 500 1 x 125 15 D.G. (kVA) 1 x 500 1 x 250 Note: Existing D.G of 125 kVA will be discontinued Existing Proposed Total Stack No.1: 30 m Stack No.1: 30 m Stack for 6 TPH Stack for 6 TPH boiler boiler Stack No.1:

39 m stack for Stack No.2: 25 m Stack No.2: 24m Boiler 15 TPH boiler stack for 2.5 TPH stack for 850 kg/hr

boiler boiler

16 Stack details Stack No.3: 24m Stack No.3: 39 m stack for 850 kg/hr stack for 15 TPH boiler boiler Stack No.2: 27 m common Stack No.4: 27 m Thermic stack for common stack for -- fluid heater TFH’s of 6 & TFH’s of 6 & 2 2 lackhkilo. lackh kilo. cal./hr. cal./hr. D.G Set Stack No1: 3.5 m Stack No1: Stack No. 5: 4.5 m

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above roof for D.G 4.5 m above stack above roof for of 125 kVA roof for D.G D.G of 250 kVA of 500 kVA Stack No. 2: 3.5 m Stack No. 6: 4.5 m above roof for D.G stack above roof for of 250 kVA D.G of 500 kVA Stack No.7: 5.0 mstack above roof Stack No.1: Stack for process scrubber of 5 m above roof Scrubber -- for process Note: Existing scrubber boiler of 2.5 TPH & D.G of 125 kVA will be discontinued 17 Effluent Generation (CMD) 46.43 408.57 455.00

18 Sewage Generation (CMD) 15.0 -- 15.0 ETP of 55 CMD In wake of 55 CMD, capacity along expansion Evaporator of with installation activity in 100 CMD & of in plant 19 ETP Capacity plant stripper 54 CMD stripper evaporator of Evaporator for evaporator of 150 CMD will Cooling Tower 250 CMD be installed capacity 36 CMD LCOD-LTD effluent along with domestic sewage 15 CMD will be treated in full-fledged ETP of 55 CMD capacity from which 46.43 CMD effluent will be sent to CETP for further treatment & disposal as per valid C.T.O & 4. 57 CMD treated effluent will be reused.

20 Effluent Treatment Scheme 241 CMD effluent process will be subjected in plant stripper evaporator of 250 CMD capacity from which 184 CMD condensate will be reused & 54 T/D salts will be sold as bi-products.

120.73 CMD Cooling tower & Boiler blow down will be reused. 21 Man Power 160 -- 160

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Hazardous *Category UOM Existing Proposed Total Disposal Waste of waste Used/ spent oil 5.1 Sale to Authorized l/Month 50.0 950.0 1000.00 recycler / CHWTSDF Residues & 29.1 MT/Mo 204.0 207.0 411.0 CHWTSDF Waste nth Chemical 29.2 MT/D 2.7 -- 2.7 sludge residue CHWTSDF from Pesticides Discarded 33.1 Nos./M Sale to 22 containers onth Authorized 78.0 1172.00 1250.0 recycler / CHWTSDF Chemical 35.3 MT/Mo CHWTSDF sludge from nth 1.12 67.88 69.0 ETP Filter & filter 36.2 kg/Mon CHWTSDF material having th 12.0 488.0 500.0 organic liquid Spent carbon 36.2 kg/Mon CHWTSDF 10.0 190.0 200 th Asbestos 15.2 kg/Mon -- 100.0 100.0 CHWTSDF gaskets th Non-hazardous UOM Existing Proposed Total Disposal waste Paper waste kg/Month (paper boxes 150.00 5450.00 5600.00 and bags) Sale to Plastic waste kg/Month 50.00 5450.00 5600.00 recycler Metal scrap kg/Month 100.00 4900.00 5000.00 23 Wooden pellets Nos./Mont 25.00 975.00 1000.00 h Coal ash kg/Day Sale to registered 2700.00 5850.00 8550 brick manufacture r *Schedule I of The Hazardous and Other Wastes (Management and Transboundary Movement) Rule, 2016.

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Chapter 2: Project Description

2.5 Location of the project

The proposed expansion activity will be achieved within existing manufacturing unit located at plot no. B-16, 17, 18 & 21 MIDC Mahad Dist. - Raigad, Maharashtra, the center point GPS coordinates of the project site are Latitude: 18° 6'3.46"N& Longitude: 73°29'23.54"E and project site is covered under Survey Of India Toposheet no. 47F/8.

Mahad is accessible by National Highway 66 which is further connected Mahad MIDC industrial area by Mahad – Solamkund Road & the further access to project site is led by internal MIDC road. Project location is also accessible through Veer railway station and the nearest airport is Pune airport which is approximately 129 km from Mahad city.

The Google Earth imagery, Mahad MIDC layout map & SOI Toposheeet (with 10 km radial area) depicting project location are given below.

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Chapter 2: Project Description

Figure 2.1: Location of M/s Astec LifeSciences Ltd.

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Chapter 2: Project Description

Figure 2.2: MIDC Mahad layout map

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Figure2.1 : Location of Astec LifeSciences Ltd. & 10 km radial study area on SOI Toposheet

Table2.2 : Latitude& Longitude of factory corners

Project plot corner Latitude Longitude A 18° 6'5.39"N 73°29'21.79"E B 18° 6'1.18"N 73°29'22.28"E C 18° 6'1.52"N 73°29'25.43"E D 18° 6'5.32"N 73°29'25.16"E E 18° 6'5.60"N 73°29'27.26"E F 18° 6'6.34"N 73°29'27.19"E G 18° 6'6.19"N 73°29'25.08"E

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H 18° 6'5.89"N 73°29'25.10"E

Table2.3: Immediate surroundings to the project site

Sr. Direction Particular No. 1 North OdessyOrganics Pvt. Ltd. 2 South TritechCatalyst and Intermediates Pvt. Ltd. 3 East CaprolactumChemicals Pvt. Ltd. 4 West Vinati Organics Pvt. Ltd.

2.5.1 List of major industries within the 10 km radial study area

Mahad MIDC is a Chemical industry cluster which houses several polymers, pharmaceutical, organic, pigments, fertilizers manufacturing industries. List of some of the major industries located within the 10 km radial study area is given in the following table.

Table2.4:List of some of the major industries within the 10 km radial study area

Approximate aerial Sr. Name of industry Type of industry distance from project No. site& direction 1 Sequent Scientific Ltd. Pharmaceutical 0.21 km toward NE 2 Steel Infoline Com Pvt. Ltd. Engineering 0.23 km towards NW 3 Odessy Organics Pvt. Ltd. Chemical 0.18 km towards N Tritech Catalyst and 4 Chemical 0.02 km towards S Intermediates Pvt. Ltd. 5 Caprolactum Chemicals Pvt. Chemical 0.19 km towards E

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Chapter 2: Project Description

Ltd. 6 Vinati Organics Pvt. Ltd. Chemical 0.22 km towards SW

2.5.2 Land use details of the project plot area The proposed expansion activity will be executed within existing manufacturing unit located at plot no. B-16, 17, 18 & 21 MIDC Mahad, Dist. -Raigad, Maharashtra admeasuring 13950.00 Sq. m. and the land use details are given in below table.

Table2.5: Land use details of project plot area

Particulars Existing Proposed Total Land use wise (Sq. m.) (Sq. m.) (Sq. m.) percentage Total Plot 13950.00 -- 13950 -- Area Built up area 8544.00 -- 8544.00 61.24

Parking area 166.00 -- 166.00

Green belt 343.52 518.75 518.75 862.27

Note: In addition green belt development/plantation will be done in 20,200.00 sq. m. within Mahad MIDC

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Chapter 2: Project Description

Figure2.2 : Project plot layout plan of Astec LifeSciences Ltd.

2.5.3 Details of environmental sensitivity within 15 km radius from the project boundary location

Table2.6: Details of environmental sensitivity within 15 km radius from project boundary location

Name/ Aerial distance (with 15 km.) Sr.No. Areas Identity Proposed project location boundary

1 Areas protected under international Yes Several patches of Reserve Forest are

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Chapter 2: Project Description

conventions, national or legislation for present with 15 km from the boundary of their ecological, Landscape, cultural or project site of which the nearest are listed other related value as below:

1. Reserve Forest near Khaire Village at an approximate aerial distance of 0.4 km towards NE from the project site.

2. Reserve Forest near Boargaon Village at an approximate aerial distance of 1.8 km towards S from the project site.

3. Reserve Forest near Kharvali Village at an approximate aerial distance of 2.4 km towards SE from the project site.

4. Reserve Forest near Kondivae Village at an approximate aerial distance of 3.5 km towards SW from the project site. Reserve Forests: Several Reserve Forest patches are

Areas which are important or sensitive for present within the 15 km boundary from ecological reasons- Wetlands, watercourses the project site of which Reserve Forests 2 Yes or other water bodies, coastal zone, near Khaire, Boargaon, Kharvali & biospheres, mountains, forests Kondivae Villages are the nearest to the project site Mountains:

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Several dense vegetation clad hills are present within the 15 km distance from the project site. Wetlands/Watercourses: Several water bodies such as BhaoviraNadi, BhaluViraNadi, Kal River, Gandhari River and Savitri River flows within 15 km from the boundary of the project site, of these rivers Kal River is the nearest which flows at an approximate aerial distance of 0.64 km towards south of the project site. Reserve Forests: Several Reserve Forest patches are present within the 15 km boundary from the project site of which Reserve Forests near Khaire, Boargaon, Kharvali &

Areas used by protected, important or Kondivae Villages are the nearest to the sensitive species of flora or fauna for project site 3 Yes breeding, nesting, foraging, resting, over Mountains: wintering, migration Several dense vegetation clad hills are present within the 15 km distance from the project site. These area may be used by protected, important or sensitive species of flora or fauna

4 Inland, coastal, marine, or underground Yes Several water bodies such as Bhaovira

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waters Nadi, BhaluVira Nadi, Kal River, Gandhari River and Savitri River flows within 15 km from the boundary of the project site, of these rivers Kal River is the nearest which flows at an approximate aerial distance of 0.64 km towards south of the project site. 5 State, National boundaries No State boundary is beyond 15 km.

Raigadh fort and Shivatharghal are Routes or facilities used by the public for 6 Yes access to recreation or tourist, pilgrim areas approximately 14.8 km away at aerial distance. No defense installations are within 15 km 7 Defense installations No area. Nearest village Asanpoi is approximately 8 Densely populated or built-up area Yes 660 m at SSW from project site. Areas occupied by sensitive man-made Present in and around 15 km distance 9 land uses (hospitals, schools, places of Yes from project site. worship, community facilities)

Reserve Forests: Several Reserve Forest patches are present within the 15 km boundary from Areas containing important, high quality or the project site of which Reserve Forests near Khaire, Boargaon, Kharvali & scarce resources Kondivae Villages are the nearest to the 10 (ground water resources, surface Yes project site Mountains: resources, forestry, agriculture, fisheries, Several dense vegetation clad hills are tourism, minerals) present within the 15 km distance from the project site. Wetlands/Watercourses: Several water bodies such as BhaoviraNadi, BhaluViraNadi, Kal

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River, Gandhari River and Savitri River flows within 15 km from the boundary of the project site. Agricultural areas: The 15 km radial area from the project boundary had presence of several agricultural areas of which the nearest agricultural area was present at an approximate aerial distance of 0.34 km towards S from the project site. Areas already subjected to pollution or Not applicable, project is in Mahad, environmental damage. (those where MIDC area which is not declared as 11 No existing legal environmental standards are critically polluted area by CPCB O.M. J- exceeded) 11013/5/2010-IA.II(I) dated 17/09/2013.

Areas susceptible to natural hazard which could cause the project to present environmental problems 12 Yes Not applicable (earthquakes, subsidence, landslides, erosion, flooding Or extreme or adverse climatic conditions)

2.6 Proposed schedule for approval and implementation The project activity in consideration is an expansion activity and anticipated schedule for approval and implementation after grant of EC is as tabulated below.

Table2.7:Schedule for approval and implementation

Sr. No Description Time Period Cost in % 1 Obtaining all statutory permission 7 Month 10% with respect to factory inclusive of processing fees, plot development fees of MIDC etc.

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Chapter 2: Project Description

Sr. No Description Time Period Cost in % 2 Design and Engineering plan 3 Month 10% 3 Factory Set up 8 Month 70% 4 Training & Commissioning 1 Month 5% 5 Actual Start 1 Month 5%

2.6.1 Status of acquisition of land Since the expansion activity is to be achieved within an existing operational unit the project plot in consideration viz. B-16, 17, 18 & 21 is currently under the possession of Astec LifeSciences Ltd.

2.6.2 Technology & process description The manufacturing process related information such as reaction scheme, process flow & mass balance are detailed in section in 2.6.3. The list of raw materials, products and machineries & equipment’s are tabulated in the below section.

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Table2.8: List of raw materials

Sr. No. Description Status Location Storage Maximum Consumption Source Means of Capacity in Quantity of /Month in of transportation MT Storage at MT Supply any point of time in MT 1 1,2 propanediol Liquid Drum 20 20.0 55 Imported Sea/Road 2 1,4 Liquid Drum 20 20.0 45 Local Road Dichlorobenzene 3 1-chloro-2- Liquid Drum 10 10 10 local Road nitrobenzene 4 2,3- Liquid Drum 10 10 10 Local Road Dichloropropane 5 2,4 Liquid Tank 20 20.0 125 Local Road Dichloroacetophen one 6 2,6 Xylidine Liquid Drum 10 10 10 Local Road 7 2-Bromopropane Liquid Drum 10 10 15 Local Road 8 2-Methylfurfural Liquid Drum 12 12 10 Imported Sea/Road 9 2-Methylfuron Liquid Drum 12 12 10 Imported Sea/Road 10 4-Chlorobenzyl Liquid Drum 20 20.0 20 Imported Sea/Road chloride 11 4-trifluro methyl Liquid Drum 20 20 15 Imported Sea/Road

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benzyl chloride 12 Acetic acid Liquid Carboy 5 5.0 10 Local Road solution 13 Acetonitrile Liquid Drum 20 20.0 15 Imported Sea/Road 14 Allyl Chloride Liquid Drum 20 20 25 Imported Sea/Road 15 Ammonia soln Liquid Drum 5 5 10 Local Road 16 BE(t-butyl ester p- Liquid Drum 10 10 10 Imported Sea/Road toloic acid) 17 Benzyl nitrile Liquid Drum 10 10 5 Local Road 18 Biphenyl Liquid Drum 10 10 10 Local Road 19 Liquid Tank 24 24.0 50 Local ISO tank by Bromine Road 20 Bromoethane Liquid Drum 5 5 5 Local Road 21 BTBE)Methyl t- Liquid Drum 20 20 15 Local Road Butyl ether) 22 Butanol Liquid Drum 10 10 10 Local Road 23 Butydine Gas Tonner 2 2 2 Imported Sea/Road 24 C9(Trimehyl Liquid Tank 20 20.0 20 Local Tanker benzene) 25 Catalyst– Solid Bag 1 1 1 Local Road (Triphenylphosphin e) 26 Cat-RPotasium Solid Bag 1 1 1 Local Road iodide.

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27 Caustic lye Liquid Tank 44 44 60 Local Tanker Road 28 CCP-2 : (2-Chloro- Solid Carboy 20 16.0 30 Imported Sea/Road 4’-(4- chlorophenoxy) acetophenone) 29 CCP-4 : 2- Liquid Drum 30 30.0 30 Imported Sea/Road (Bromomethyl -2- [2-Chloro-4-(4- Chlorophenoxy) Phenyl] -4-Methyl -1, 3-Dioxolane) 30 Celite Solid Bag 2 2 1 Local Road 31 Chlorobenzaldehyd Liquid Drum 10 10 10 Local Road e 32 Chloroform Liquid Drum 20 20.0 20 Local Road 33 CO2 gas Gas Cylinder 2 2 15 Local Road 34 Cyclohexane Liquid Tank 8 8.0 15 Local Tanker-Road 35 Dichloro Benzyl Liqid Drum 10 10 10 Local Road nitrile 36 Dichloroacetophen Liquid Tank 20 20 125 Local Tanker-Road one 37 Dichloromethane Liquid Drum 10 10.0 20 Local Road 38 Diethyl Ketone Liquid Drum 10 10 10 Imported Sea-Road 39 Dimethyl 4-chloro Liquid Drum 10 10 10 Imported Sea-Road

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pyrazole formaldehyde 40 Dimethyl Liquid Drum 20 20.0 40 Imported Sea-Road Acetamide 41 Dimethyl Adipate Liquid Drum 10 10 10 Imported Sea-Road 42 Dimethyl Liquid Drum 20 20.0 30 Imported Sea-Road Formamide 43 Dimethyl Sulphate Liquid Tank 30 30.0 160 Local Tanker-Road 44 Dimethyl Sulphide Liquid Drum 20 20.0 30 Imported Sea-Road 45 Dimethyl Liquid Drum 20 20.0 20 Imported Sea-Road sulphoxide 46 Dioxane Liquid Drum 20 20.0 20 Imported Sea-Road 47 Distilled DMPF Liquid Drum 20 20.0 20 Inhouse Tank 48 DK-2(3-methyl 3- Liquid Tank 20 20 30 Inhouse Tank pentanol) 49 DK-3(3-methyl 3- Liquid Tank 20 20 30 Inhouse Tank chloropentane) 50 DMCC(2,3 Liquid Drum 10 10 10 Imported Sea-Road dichloropropane) 51 DMPO(1,3 Liquid Drum 10 10 5 Imported Sea-Road Dimethyl-4- phenoxy pyrazoleoxime) 52 Ethylene Oxide Gas Tonner 5 5 5 Local Road

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53 Formaldehyde Liquid Drum 10 10 10 Imported Sea-Road 54 Formic acid Liquid Carboy 10 10 10 Local Road 55 Hexane Liquid Tank 10 10 20 Local Road 56 HMBT(4-methyl- Liquid Drum 10 10 10 Imported Sea-Road 2-benzothiazole hydrazine) 57 Hydrobromic acid Liquid Drum 30 30.0 30 Imported Sea-Road 58 Hydrochloric acid Liquid Drum 20 20.0 30 Inhouse Tank 59 Hydroxylamine Liquid Drum 20 20.0 20 Imported Sea-Road hydrochloride 60 Intermediate(Benze Liquid Tank 20 20 20 Inhouse Tank neacetonitrile, α- butyl-4-chloro-α- (chloromethyl) 61 Isobutidine Gas Cylinder 2 2 2 Local Road 62 Ketone M Liquid Drum 20 20.0 20 Imported Sea-Road 63 Ketone-K Liquid Drum 20 20.0 20 Imported Sea-Road 64 LiNH2(Lithium solid Carboy 2 2 4 Local Road Hydride) 65 Magnesium Solid Bag 4 4 12 Local Road 66 Methanol Liquid Tank 12 12.0 20 Local Tanker-Road 67 Methoxy acetyl Liquid Drum 15 15 15 Imported Sea-Road chloride 68 Methyl Bromide Liquid Drum 10 10 10 Local Road

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69 Methyl chloride Gas Tonner 2 2 10 Local Road 70 Methyl chloro Liquid Drum 10 10 10 Imported Sea-Road propionate 71 Methyl Liquid Tank 15 15.0 30 Local Tanker-Road Cyclohexane 72 Methyl Liquid Drum 20 20 20 Imported Sea-Road Furfuryldehyde 73 N-butyl lithium Liquid Cylinder 2 2 4 Local Road 74 Oxirane Liquid Drum 20 20.0 90 Imported Sea-Road 75 P-chloro benzyl Liquid Drum 20 20.0 20 Imported Sea-Road chloride 76 PCl3–(Phosphorus Liquid Drum 10 10 20 Local Road trichloride) 77 Pd-C(Paladium Solid Carboy 0.2 0.2 0.2 Local Road carbon) 78 p-Dichloro Liquid Drum 15 15 15 Imported Sea-Road Benzene 79 Pentanone Liquid Drum 20 20 80 Imported Sea-Road 80 Pentanone (mix of Liquid Drum 20 20.0 20 Imported Sea-Road 2,3) 81 Phenol Liquid Drum 10 10 15 Local Road 82 Phosgene Gas Cylinder 2 2 5 Local Road 83 Potassium Solid Bag 20 20 40 Imported Sea-Road Carbonate

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84 Potassium Solid Bag 60 60 150 Imported Sea-Road Hydroxide 85 Pottasium Solid Bag 30 20 30 Local Road Hydroxide 86 Propygil Chloride Liquid Drum 10 10 10 Local Road 87 PTC-l:(2-(1- Liquid Drum 20 20 20 Imported Sea-Road chlorocyclopropyl )-2-[(2- chlorophenyl) methyl ] oxirane 88 p-Toluic chloride Liquid Drum 10 10 10 Imported Sea-Road 89 Sodium bisulphide Solid Bag 10 5 5 Local Road 90 Sodium Bromide Solid Bag 10 5 5 Local Road 91 Sodium hydride Solid Bag 10 5 5 Local Road 92 Sodium Hydroxide Solid Bag 20 20 30 Local Road 93 Sodium hydroxide Solid Bag 20 20 30 Local Road 94 Sodium methoxide Liquid Drum 20 20.0 20 Local Road 28% 95 Sodium Liquid Drum 20 20 20 Local Road thiomethoxide 96 Sodium Solid Bag 10 10 20 Local Road Thiosulphate 97 Sodiumbi Solid Bag 20 20 20 Local Road carbonate

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98 SPT Liquid Drum 20 20.0 20 Inhouse Drum OxiraneOxirane, 2- (4-chlorophenyl)-2- (1- cyclopropylethyl) 99 Sulphur Solid Bag 10 10 10 Local Road 100 Sulphuric Acid Liquid Carboy 5 5.0 10 Local Road 101 T-Butyl Solid Bag 5 5 10 Local Road Ammonium Bromide 102 Tetrahydrofuron Liquid Drum 20 20.0 25 Imported Sea-Road (THF) 103 Thionyl Chloride Liquid Drum 10 10 10 Local Road 104 Toluene Liquid Tank 8 8.0 20 Local Tanker-Road 105 Triacetonalkamine Liquid Drum 10 10 10 Local Road 106 Triazole Solid Bag 50 50 120 Imported Sea-Road 107 Trichloroacetophen Solid Carboy 20 20 40 Imported Sea-Road one 108 Trimethyl Borate Solid Bag 10 10 10 Local Road 109 ValerylOxirane Liquid Drum 20 20.0 50 Imported Sea-Road 110 Valeryl ketone Liquid Drum 20 20.0 40 Imported Sea-Road 111 Xylene Liquid Drum 20 20 20 Local Road 112 Zinc Solid Bag 10 10 10 Local Road 113 Zinc chloride Solid Bag 10 10 10 Local Road

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Table2.9: List of products, Byproducts & Formulations

Existing Total Sr. No. Product (MT/M) (MT/M) 1 Propiconazole 15.00 165.00 2 Hexaconazole 14.00 100.00 3 Tebuconazole 60.00 150.00 4 Dextrinol 6.00 2.00 5 3,4-Chlorostyrene 30.00 25.00 6 Metalaxyl 5.00 10.00 7 4-Hydroxy 3-Methyl-2- 12.00 12.00 (Propinyl)-2-Cyclopentene-

Dichlo1-rLo oBne nzyl Cyanide/4- 5.00 5.00 8 ChlorophenylEthyl Chloride

9 Bromuconazole 30.00 40.00 10 Cyproconazole 25.00 25.00 11 Prallethrine 12.00 12.00 12 Difenoconazole 5.00 30.00 13 Tricyclazole -- 30.00

2-Ethyl 2- 10.00 14 MethylButanoicAcid -- 15 Metconazole -- 20.00

5-Methyl-Α-(2-Propinyl)-5- 10.00 16 FurfurylAlcohol -- 17 Myclobutynil -- 25.00 18 DimethoxyBenzoic Acid -- 20.00 19 Boscalid -- 20.00 20 Prothiconazole -- 20.00

21 Ipconazole -- 20.00

4-Trifluromethyl Benzyl 20.00 22 Alcohol -- 23 Fenpyroximate -- 10.00 Total 219 781

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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List of Bi-products

Sr. Bi-Product MT/month No. 1 Aliphatic Hydrocarbon 114.00 2 Biphenyl 2.00 3 HCL sol. 49.00 4 H3PO3 solution 2.00 K2CO3,K2SO4,KTMI,KBr,KOH,KCL 5 805.00 solution Lithium hydroxide monohydrate 6 3.00 solution 7 MGCl2, MgBr2,MgSO4 solution 242.00 8 Na2SO4,NaCl,NaBr,NaOH solution 536.00 9 ZnCl2,Zn,Zn(CH3CO)2 solution 21.00 Total 1773.00

List of formulation products

Sr. Existing Proposed Total No. Product (MT/M) (MT/M) (MT/M) 50 MT will be 1 Wettable Powder (WP/SP) 150 100 reduced 2 Granular Products (CG/G) 150 -- 150 3 Liquid Product EC 200 -- 200 4 Liquid Product (SC/SL) 200 50MT will be 250 increased Total 700 -- 700

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Chapter 2: Project Description

Table2.10: List of major equipment’s& machineries

Sr. No. Equipment No. Equipment Name Location Existing/New 1 U2004 IBR Boiler 6 TPH MR 16599(B1 U201) IBR Boiler B17 Existing 2 U2011 Coal Crusher (CC1 U201)(6TPH) IBR Boiler B17 Existing 3 U2013 IBR Boiler Bag filter(6TPH) IBR Boiler B17 Existing 4 U2014 IBR Boiler Mechanical dust IBR Boiler B17 Existing collector(6TPH) 5 U2025 Cooling Tower Process 700 TR B17 Plant Existing 6 U2029 Cooling Tower B17 Utility 250TR B17 Plant Existing 7 U2031 Pump Cooling Tower 02( Standby) IBR Boiler B17 Existing (P2 U205) 250TR 8 U2032 Cooling Tower Br2 Process B17 Plant Existing 9 U2033 Cooling Tower B17 Ejector no.1 B17 Plant Existing 100TR 10 U2034 Cooling Tower B17 Ejector no.2 B17 Plant Existing 100TR 11 U2035 Cooling Tower BRL3 Ejector 100 TR B17 Plant Existing 12 U2036 Cooling tower 33 KL Cond. Water B17 Plant Existing 100TR 13 U2038 Cooling Tower Water Spray 100 TR B17 Plant Existing 14 U2040 Cooling Tower B17 New Utility B17 Plant Existing 1000 TR 15 U2052 THERMOPACK (2 Lkcal/hr) B17 Utility New 16 U2053 THERMOPACK (6 Lkcal/hr) B17 Utility New 17 U2063 Diesel Generator set (63 kva) B24 Plant Existing 18 U2064 Diesel Generator set (500 KVA) B17 Utility New 19 U2065 Transformer 960 KVA B17 Utility Existing 20 U2078 NITROGEN GENERATOR - B17 Utility Existing 20Nm3/hr 21 U2079 NITROGEN GENERATOR - B17 Utility Existing 40Nm3/hr 22 U2080 NITROGEN GENERATOR - B17 Utility Existing 100Nm3/hr 23 U2092 Condenser 40TR B17 New Utility Existing 24 U2093 Chiller 40TR B17 New Utility Existing 25 U2094 Condenser (100 TR B17) B17 New Utility Existing 26 U2095 Chiller( 100 TR B17) B17 New Utility Existing 27 U2096 Condenser (150 TR B17) B17 New Utility Existing

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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28 U2097 Chiller( 150 TR B17) B17 New Utility Existing 29 U2099 Ammonia Receiver 150TR B17 Utility Existing 30 U2148 Cooling tower 50 TR for BRL 0 mtr B17 plant Existing III Expansion for BRL III Expansion project 31 R2201 Reactor R201 B17 Plant Existing 32 R2202 Reactor R202 B17 Plant Existing 33 R2203 Reactor R203 B17 Plant Existing 34 R2204 Reactor R204 B17 Plant Existing 35 R2205 Reactor R205 B17 Plant Existing 36 R2206 Reactor R206 B17 Plant Existing 37 R2207 Reactor R207 B17 Plant Existing 38 R2208 Reactor R208 B17 Plant Existing 39 R2209 Reactor R209 B17 Plant Existing 40 R2210 Reactor R210 B17 Plant Existing 41 R2211 Reactor R211 B17 Plant Existing 42 R2212 Reactor R212 B17 Plant Existing 43 R2213 Reactor R214 B17 Plant Existing 44 R2214 Reactor R215 B17 Plant Existing 45 R2215 Reactor R216A - Replacement B17 Plant Existing of R216 A 1 KL SS -PGMF 46 R2216 Reactor R216B 3.0 KL SS316 B17 Plant Existing 47 R2217 Reactor R216C B17 Plant Existing 48 R2218 Reactor R217 B17 Plant Existing 49 R2219 ReactorR218 B17 Plant Existing 50 R2220 Reactor R219 B17 Plant Existing 51 R2221 ReactorR220 B17 Plant Existing 52 R2222 Reactor R221 B17 Plant Existing 53 R2223 ReactorR222 B17 Plant Existing 54 R2224 Reactor R223 B17 Plant Existing 55 R2225 ReactorR224 B17 Plant Existing 56 R2226 Reactor R225 B17 Plant Existing 57 R2227 Reactor -R401 SC Plant Existing 58 R2228 Reactor -R402 SC Plant Existing 59 R2229 Reactor -R404 SC Plant Existing 60 R2230 Reactor -R405 SC Plant Existing

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 2: Project Description

61 R2231 Tile line Reactor Br2 plant Br2 Plant Existing 62 R2232 Toluene rec. column of PIOL III- B17 plant Existing 3 KL SS 63 R 2233 R 205 new Reactor replaced B17 plant Existing 64 R 2234 R 218 new Reactor replaced B17 plant Existing 65 R2235 Replacement of R216B New 4.5 KL B17 Plant Existing 66 R2236 New GLR 8 KL by replacing of R 220 B17 Plant Existing 67 D2001 Dynomill No.1 (R &D) 1 lit. R&D Existing 68 D2002 Dynomill No.2 (SC) 60 lit. SC Plant Existing 69 B2001 Bottle Filling Machine No.1 SC plant SC Plant Existing 70 B2002 Bottle Filling Machine No.2 SC plant SC Plant Existing 71 A2001 Aggitated filter dryer (Old PCS IV) B17 Plant Existing 72 A2002 Aggitatednutsch filter dryer (BRL1) B17 Plant Existing 73 A2003 Aggitatednutsch filter dryer (PCS IV) B17 Plant New 74 A2004 Aggitatednutsch filter dryer (KBr) B17 Plant Existing 75 N2005 Nutch Filter 8 kl (R218) B17 plant Existing (Ground Floor) 76 F2001 Filter Press. No.1 B17 Plant Existing 77 L2001 Powder Packing Unit (new) B17 Plant Existing 78 Q2003 Br2 plant Scrubber No.1 (PPFRP) B17 Plant Existing 79 Q2004 R205 Scrubber M.S. B17 Plant Existing 80 C2006 Tolune Recovery Column (Piollll) B17 3rd floor New 81 B2001 ClorineTunner Blower Br2 plant Br2 Plant Existing 82 B2002 ClorineTunner Shed Blower Br2 plant Br2 Plant Existing 83 Z2001 D.M. Plant (20 kl) SC Plant Existing 84 O2001 Centrifuge No.1 B17 B17 Ground Existing Floor 85 R1101 Reactor R101 B16 Plant Existing 86 R1102 Reactor R102 B16 Plant Existing 87 R1103 Reactor R103 B16 Plant Existing 88 R1104 Reactor R104 B16 Plant Existing 89 R1105 Reactor R105 B16 Plant Existing 90 R1106 Reactor R108 B16 Plant Existing 91 R1107 Reactor R110 B16 Plant Existing 92 R1108 Reactor R109 B16 Plant Existing 93 R1109 Reactor OLD R 102 B16 Plant Existing 94 A1001 ANFD B16 B16 Plant New

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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95 O1001 Centrifuge 1 B16 B16 Plant Existing 96 O1002 Centrifuge 2 B16 B16 Plant Existing 97 Q1001 R102 Scrubber No.1 B16 Plant Existing 98 Q1002 BRL1 Scrubber No.2 BRL1 Ground Existing Floor 99 W1001 Calendria no.1 MEE plant 1st Existing floor 100 W1002 Calendria no.2 MEE plant 1st Existing floor 101 W1003 Calendria no.3 MEE plant 1st Existing floor 102 W1004 Calendria no.4 MEE plant 1st Existing floor 103 N1001 Nutch Filter B16 no.1 (1.5 kl) BRL1 Ground Existing Floor 104 N1002 Nutch Filter B16 no.2 (1.5 kl) BRL1 Ground Existing Floor 105 N1003 Nutch Filter MEE No.1 2 kl MEE 1st floor Existing 106 N1004 Nutch Filter MEE No.2 2 kl MEE 1st floor Existing 107 R3301 Reactor R301 BRL1 Plant Existing 108 R3302 Reactor R302 BRL1 Plant Existing 109 R3303 Reactor R303 BRL1 Plant Existing 110 R3304 Reactor R304 BRL1 Plant Existing 111 R3305 Reactor R305 BRL1 Plant Existing 112 R3306 Reactor R306 BRL1 Plant Existing 113 R3307 Reactor R307 - Replacement of reactor BRL1 Plant Existing new code R-3307 under modification to increasing BRL-II batch size. 114 R3308 Reactor R308 BRL1 Plant Existing 115 R3309 Reactor R309 BRL1 Plant Existing 116 R3310 Reactor R310 - R310 New reactor of BRL1 Plant Existing PGMF 1 KL SS 117 R 3311 Reactor R307 SS 6 KL - Replacement BRL 1 Existing of rector new code R-3307 under modification to increasing BRL-II batch size. 118 U1001 Non-IBR Boiler 850 Kg/hr B16 Utility G.F. Existing 119 U1002 Non-IBR Boiler 1000 Kg/hr B16 Utility G.F. Existing 120 U1003 New Non-IBR Boiler 850 Kg/hr B16 Utility G.F. Existing

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 2: Project Description

121 U1014 B16/BRL1 Process Cooling Tower 400 BRL1 Ground Existing TR Floor 122 U1015 B16 Utility Cooling Tower 300 TR B16 Utility G.F. Existing 123 U1016 B16 Utility Cooling Tower 60 TR B16 Utility G.F. Existing (25TR brine) 124 U1020 Transformer(500KVA) B16 Utility G.F. Existing 125 U1031 D.G.Set (250KVA) B16 Utility G.F. Existing 126 U1032 Transformer(1600KVA) B16 Utility G.F. Existing 127 U1038 Chiller 100TR B16 Chilling B16 Utility Existing 128 U1040 Amonnia 100 TR Brine plant B16 B16 Utility Existing 129 U1045 Condenser (25 TR Brine B16) B16 Utility Existing 130 U1046 Chiller( 25 TR Brine B16) B16 Utility Existing 131 U2004A IBR Boiler 10 TPH MR 16599 IBR Boiler B17 New (B1 U201) 132 U2011A Coal Crusher (CC1 U201)(10TPH) IBR Boiler B17 New 133 U2013A IBR Boiler Bag filter(10TPH) IBR Boiler B17 New 134 U2014A IBR Boiler Mechanical dust IBR Boiler B17 New collector(10TPH)

2.6.3 Details of manufacturing process

The manufacturing process involves chemical reactions like Bromination, Hydrolysis and Physical process like Quenching, Distillation, Crystallization, Solvent Recovery, Washing, Separation and Drying.

2.6.3.1 Manufacturing process Product: Hexaconazole

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 2: Project Description

Reaction:

Process Description

Material Balance

Step -I

1 CLS -I 1003.12 3480.82 Reaction mass

2 FFB 1705.30

3 Saturn 4.55 R-01

4 Water 36.47 Reaction

5 DMS 731.36

Total 3480.82 3480.82 Total

Reaction mass 3480.82 R-02 2769.27 Organic Layer

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 2: Project Description

HOT 650.43 Quenching 2273.77 Aqueous layer

Water 911.84

Total 5043.08 5043.05 Total

Organic Layer 2769.27 1063.97 CLS-II (Crude)

1637.09 FFB

Recovery 68.21 FFB loss

Total 2769.27 2769.27 Total

Aqueous layer 2273.77 948.31 Water recover

1008.94 K2SO4

185.78 CH3OH

104.37 H2O Recovery 4.55 Saturn

21.93 Residue

Total 2273.77 2273.89 Total

Step -II

1 CLS -II (Crude) 1063.97 R-03 water wash 1040.24 CLS -II pure 2 Water 690.15 and separation 713.92 water recover

Sadekar Enviro Engineers Pvt. Ltd Chapter 2-35

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 2: Project Description

Total 1754.12 1754.16 Total

Step -III CLS -II pure 1040.24 1426.19 CLS -III crude

DMF 2280.09 2211.69 DMF

TMI 299.93 68.40 DMF loss R-04 Reaction K2CO3 86.02

Total 3706.28 3706.28 Total

Step -IV CLS -III crude 1426.19 1000.00 CLS -III pure

Water 1735.40 877.29 MeOH

Methanol 913.84 36.55 MeOH loss

1735.40 Water

R-05 Cystalization 340.79 Impurity

9.17 K-TMI

76.24 K2CO3

Total 4075.43 4075.43 Total

The manufacturing process of all other products is given as Annexure 2.4.and undertaking into the effect that ALL located at plot no. B-16, 17, 18 & 21, MIDC Mahad, Mahad, Dist. - Raigad, Maharashtra will not manufacture any of the banned pesticides is attached as Annexure 2.5.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 2: Project Description

2.7 If expansion project, details of existing products with capacities and whether adequate land is available for expansion, reference of earlier EC if any

The existing production capacity is 219 T/M & detailed product list is given in Table No. 2.9, the total project plot area is 13950.00 Sq. m. wherein the expansion activity will be achieved by installing reactors/machineries of high volume capacity thereby increasing batch size.

2.8 Description of mitigation measures

The overview of probable environmental pollution & respective mitigation measures during the operational phase of the project is depicted diagrammatically in the following figure.

Figure No. 2.5: Overview of environmental aspects & respective mitigation measures during operational phase

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s AstecLifesciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 3 –Description of the Environment

CHAPTER 3: DESCRIPTION OF THE ENVIRONMENT

3.1 Introduction An overview of the process of EIA is depicted in the Fig. 3.1. The methodology of the consultant organization to carry out the EIA study is presented in Fig. 3.2. Out of the above mentioned aspects the present section focuses on monitoring of present environmental conditions such as air quality, water quality, soil and noise pollution levels. The monitoring duration for the study was considered for three months as per guidelines. The season in which the data was collected for the study area was winter.Including the collection of onsite meteorological data during the study period.The study also encompasses the ecological biodiversity of the 10 Km study area. Other aspects which are indirectly related to the environment such as traffic conditions, hydro- geology, socio-economical status of the population and land use and land cover details are also discussed in the present study. The Standard Operating Procedures (SOPs) for all the functional areas applicable in this study are followed from SEE-METH-EIA-01 to SEE-METH-EIA-12 as per the QMS of the organization. It should be noted that the sampling locations for the study will be selected in such a manner which will suffice the sampling requirement for all the projects adhering to the NABET guidelines.Based on the understanding and experience of the Functional Area Experts environmental monitoring was conducted in the months of Dec-17 to Feb 18. Therefore in the case of sampling locations for groundwater, surface water, soil and noise are common. For ambient air quality, for monitoring the conditions at the project site individual monitoring was conducted at the premises of each industry keeping the rest of the sampling locations common as inferred from the wind pattern from the secondary data. 3.2 Meteorology It is known that meteorological conditions around us influence not only the levels of pollution but also their dispersion on local, regional, national as well as global scale. Moreover these

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Chapter 3 –Description of the Environment meteorological conditions also vary spatially and temporally. Hence it is important to study the meteorological conditions around the study area in order to estimate their level of influence in dispersion of pollutants. For the present study primary data was collected for duration of three months from site and additional secondary data period of five years was obtained from Indian Meteorological Department (IMD) forRaigaddistrict.

Figure 3.1 Methodology for EIA

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s AstecLifesciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 3 –Description of the Environment

Contd.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s AstecLifesciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 3 –Description of the Environment

- Figure 3.2Methodology for Obtaining Environmental Clearance

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Chapter 3 –Description of the Environment

3.2.1 Secondary Data from IMD

As mentioned earlier the secondary data was obtained for selected parameters from the IMD from Jan 2012 to Dec 2016. The parameters selected for the study were Temperature, Ambient Barometric Pressure, Relative Humidity, Wind speed, Wind direction and Precipitation (rainfall). The data for Cloud Cover has been compiled from the climatological tables of the IMD. The descriptive statistics of the selected meteorological parameters is presented in Table 3.1. The statistics of the primary data monitored during the sampling duration at the monitoring station at project site and is presented in Table 3.2. Table 3.1Monthly data from IMD 2012 to 2016 Rainfall Pressure Temperature C Relative humidity % Month (mm) (mb) Min Max Min Max Avg. Avg. Jan. 14.4 32.0 20.0 98 0 1011.8 Feb. 13.4 31.5 23.0 92 0 1010.5 Mar. 14.1 31.9 23.0 90 6 1009.6 Apr. 21.4 33.6 38.0 95 0 1007.9 May. 23.8 34.7 39.0 88 0 1006.4 Jun. 21.6 35.0 53.0 95 110 1001.7 Jul. 15.3 31.4 69.0 98 980 1003.4 Aug. 17.3 31.2 68.0 98 324 1005.2 Sep. 14.1 31.9 29.0 95 351 1006.2 Oct. 20.6 35.3 33.0 92 60 1008.4 Nov. 18.0 35.0 20.0 89 3 1009.6 Dec. 14.4 33.6 23.0 93 16 1010.8

a. Temperature: The present data enables to conclude that the study area can be categorized into typical tropical type of climatic conditions experiencing four distinct seasons. The change in temperature is experienced with respect to change in subsequent season. The summer season is followed with monsoon season which provides the supply of fresh water in the form of precipitation during June to September.

The monsoon is followed by winter season starts from December and lasts up to mid February. During this season minimum temperature can be observed to drop down to 13.4 C. The maximum temperature

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Chapter 3 –Description of the Environment of the winter season is recorded to be 33.6 C in the month of December. The winter season ends in February with the on-set of summer season which lasts till month of early June. During summer season maximum temperature was recorded to be 35.0 C whereas the minimum ambient temperature was observed to be 14.1 C. During monsoon season (Mid June to September) maximum temperature were observed to reach 31.9C while minimum temperature was observed as 14.1C.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s AstecLifesciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 3 –Description of the Environment

- Figure 3. 3 Windrose from Secondary for year, - Figure 3. 4 Windrose from Secondary data 2012-2016 for Sampling Period

- Figure 3. 5 Windrose from Primary data for Sampling Period

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Chapter 3 –Description of the Environment

b. Relative Humidity: The presence of relative humidity indicates the level of water vapour in the atmosphere. From the data it can be inferred that relative humidity was observed to be lowest in winter season and highest in the monsoon season. The highest average of relative humidity was observed to be up to 98 % in the monsoon season during July and August. It should be noted that on rare occasions in the winter season relative humidity was observed to reach the maximum of 98%. c. Rainfall: The months of July and August are considered to be the months which receive maximum rainfall of the year. The data indicates that average annual rainfall received amounts to 1850 mm each year. d. Atmospheric Pressure: Changes in pressure influence the vertical mixing of the air. Thus variation in pressure is important for vertical as well as horizontal mixing of pollutants present in the atmosphere. The change in atmospheric pressure is experienced diurnally, nocturnally as well as seasonally. The maximum average atmospheric pressure is experienced during the winter season while minimum average atmospheric pressure is experienced in the rainy season during the months of June. e. Wind direction and Wind speed: The data for wind speed and wind direction is presented separately using wind rose diagrams in Fig. 3.3 to 3.5. The wind dispersion during 2012- 2016 is presented in Fig. 3.3, while the wind pattern during Dec - Feb (sampling period) during 2012 - 2016 is presented in Fig. 3.4. The Fig. 3.5 presents the meteorological conditions during the study period of Dec17 to Feb 18.

3.2.2 Site Specific Meteorological Data Monitoring for micro meteorological data was carried out on continuous basis at the project site. The parameters selected were wind- speed, wind-direction, rainfall, temperature and relative humidity. Monitoring was carried out using an automatic weather monitoring station at the project site. The station was installed keeping in view the free exposure of sensors to atmosphere and minimum interference from the nearby structures. The monitoring was carried out for a period of 3 months from Dec17 to Feb 18. The variations in the meteorological data are

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s AstecLifesciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 3 –Description of the Environment presented in Table 3.2. The highlights of the meteorological factors considered for monitoring for the present study are discussed as under: Table 3.2 Site Specific Micro Meteorology Data (Dec17 to Feb, 2018) Temperature Relative Wind Speed Dominant Wind Rainfall Months (OC) Humidity (%) (Km/hr) Direction mm Min Max Min Max Min Max (Blowing from) Dec 17 16 14.6 34.6 24 94 0 14 North West to Jan 18 00 14.2 32 21 98 0 18 South East Feb 18 00 13.6 31.8 24 93 0 18

Temperature Temperature during the study period was found to vary from 13.60C to 34.60C during the study period. Relative Humidity Relative humidity during the study period was found to be maximum 98 % & minimum 21 % Wind Speed and Wind Direction The wind rose diagram representing the summer season is shown in Fig 3.5. A review of wind rose diagram shows that predominant winds are mostly from North West to South East. The hourly minimum wind speed was recorded to be 0 Km/hr & maximum was observed around 18 Km/hr. Interpretation: Meteorology forms the base of any dispersion studies. With this understanding Windrose diagrams using secondary data obtained from Indian Meteorological Department (IMD) for annual data (5 Years) & sampling period (Dec to Feb of year 2012 to 2016) have been plotted. The wind rose prepared from secondary data for sampling period of Dec to Feb, indicates that about 44% of the time, wind was observed to be blowing from North West direction. At the same time the windrose diagram based on primary data (for the monitoring period) indicates that around 42% of the time the wind is blowing from the North West direction. For determining the sampling locations of air quality monitoring it is important to understand the distribution of wind direction during the monitoring period, i.e. during the months of Dec to Feb.

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Chapter 3 –Description of the Environment

According to the interpretation of the secondary data for meteorology it is concluded that the prominent upwind direction is North West. Therefore the monitoring stations can be selected based on the prominent wind direction identified.

Comments: The collected secondary data and the primary data have been compared and analyzed to verify the quality of the data. The comparison of the secondary meteorological data (for Dec to Feb, 2012-2016) with the primary data (Dec 17 to Feb 18 2017) monitored at site is summarized as under:  Minimal variation in the values is observed in the two data sets. For instance the minimum temperature recorded at the monitoring site was 13.6C and the same from the secondary data was observed to be 13.4 C, while the maximum temperature at project site was measured to be 34.6C and that from the meteorological data from IMD was observed to be 33.6C.  The data for minimum relative humidity recorded at site was noted to be 21% and that from secondary data was observed to be 20%. At the same time maximum relative humidity recorded at site was 98 % while the same according to the secondary data was 98%. It can be inferred from the above data that the pre-dominant wind direction during the monitoring period is similar in the secondary as well as primary data collected from the monitoring station.

3.3 Ambient Air Quality Monitoring The baseline data for the proposed project is collected during month of Dec 17 - Feb 18. The monitoring of ambient air quality around the project site provides an understanding about the prevailing level of environmental pollution in the atmosphere. For the purpose of air quality monitoring a study area of 10 km radius from project site has been considered. Based on the observations of study area from satellite imagery it can be said that the

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Chapter 3 –Description of the Environment study area mainly comprises of vegetation followed by scattered settlements of Industrial, Residential & Commercial areas and small agricultural areas and open- scrub land. The ambient air quality monitoring was carried out at selected locations in 10 km radial distance of the project site. The study area can be categorized as a rural area.

Probable Sources of Air Pollution: From the field investigations & reconnaissance surveys the various sources identified that can contribute to air pollution in the study area:  Industrial activities in MIDC Area,  Transport activities all along the road  Rural activities in the vicinity of the MIDC area etc  Construction activities in the residential or MIDC areas  Agricultural activities such as biomass burning, combustion of wood and other waste, etc.

3.2.1 Sampling Details The ambient air quality monitoring network of eight locations as per Standard ToR was designed based on the prominent wind direction as per the analysis of meteorological data (from secondary source). The sampling was carried out twice a week as per the NAAQS Notification of November 2009. The Ambient Air Quality Monitoring was carried out for VOC & all the 12 parameters for which standards are prescribed by the CPCB at location A1 (project premises), and criteria pollutants namely PM2.5, PM10, NOx, SO2 & CO at remaining 7 stations. The details of the parameters monitored are provided in Table 3.3. The criteria applied for selection of the monitoring location is discussed as under.

3.2.2. Criteria for selection of ambient air monitoring locations The ambient air quality monitoring locations were selected considering the following criterion: i. Prevailing prominent wind direction in the study area as examined form the Windrose distribution prepared from the secondary data. ii. Location of sensitive receptors such as reserved forests, national Parks, hospitals, archeological sites, etc. in the vicinity of the study area. iii. Topography of the study area.

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Chapter 3 –Description of the Environment iv. Site feasibility related to accessibility, security, distances from nearest shades and trees, etc. iv. Availability of electrical supply and supplementary arrangements.

3.3.4Methodology for Sampling The sampling was carried out at selected locations as per the CPCB guidelines. The standard methodology used for analysis is presented in Table 3.3. The details of the detection limits and the standard methods are provided subsequently.

Table No.3.3 Methodology Used for Ambient Air Analysis Sr. Minimum Parameters Analysis No. Detection limit 3 3 1. PM10µg/m IS 5182( Part 23): 2006 5.0 µg/m USEPA Quality assurance handbook 2. PM µg/m3 2.0 µg/m3 2.5 VOL-II part II 3 3 3. SO2µg/m IS 5182 (Part 02): 2001 Reaff.2006. 3 µg/m 4. NOxµg/m3 IS 5182 (Part 06): 2006 9 µg/m3 5. CO mg/m3 Based On Instrument ACE 9000XT 0.02 mg/m3 Method 411,Air Sampling and analysis , 6. Ozone (O ) µg/m3 20 µg/m3 3 3rd edition EPA Inorganic Compendium method IO- 7. Lead (Pb) ng/m3 0.10 ng/m3 3.2 Ammonia (NH ) Method 401,Air Sampling and analysis , 8. 3 20.0 µg/m3 µg/m3 3rd edition Benzo(a)pyrene 9. IS 5182 (Part 12): 2004 Reaff.2009 0.20 ng/m3 (BaP) Based On CPCB guidelines for 10. Arsenic (As) ng/m3 measurement of ambient air pollutant 5.0 ng/m3 Vol..I May 2011 EPA Inorganic Compendium method IO- 11. Nickel (Ni) ng/m3 5.0 ng/m3 3.2 12. Benzene) µg/m3 IS 5182 (Part 11) 1 µg/m3 Volatile Organic 13. Compounds (VOCs) EPA Compendium Method TO-17 1 ppb (ppb)

Equipment used for sampling: The sampling of PM10 was conducted using Envirotech make sampler (model no.: APM-460), while the sampling of PM2.5 was carried out using Envirotech make sampler (model no. APM550). The monitoring of carbon monoxide was conducted by

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Chapter 3 –Description of the Environment online instruments of Rave innovations instruments (model no.: COA-109). The monitoring of ambient VOC was carried out using Envirotech make portable sampler with model no.: APM 802. Sample Transportation and Sample Preservation: Proper preservation of samples was done after sampling. The Gaseous samples were preserved in an ice box (below 4°C) and transported to the laboratory for analysis. The filter papers were collected using forceps and stored in polythene bags and stored in cool and dry containers during transportation. Based on the above understanding the nine locations selected for ambient air quality monitoring are presented on Google earth imagery. The locations are fixed considering the up-wind and down-wind direction of wind pattern and sensitive receptors. The details of the sampling locations identified for the present study are presented in Table 3.4.

3.3.5 Ambient Air Quality Status Table 3.4 Details of Selected Sampling Locations M/s Astec Life Sciences Ltd. Sr. Sampling Location & Aerial Dist. Coordinates Type of Area No. Codes Direction (Km) Latitude Longitude 1 A1 Project Site - - 18° 6'3.49"N 73°29'23.79"E Industrial Near Dhamane 2 A2 N 2.72 18° 7'34.06"N 73°29'24.71"E Vegetated Village 3 A3 Dahivad Village NNE 6.20 18° 8'36.69"N 73°31'40.64"E Vegetated 4 A4 Bhavepathar E 6.00 18° 6'15.38"N 73°32'49.36"E Residential 5 A5 Birwadi E 1.95 18° 6'2.36"N 73°30'29.94"E Residential Near Warandh 6 A6 NEE 9.70 18° 7'41.58"N 73°34'37.06"E Residential Village Near Bhogaon 7 A7 NW 2.75 18° 6'42.93"N 73°27'59.73"E Residential Village Near Dharwali 8 A8 S 4.89 18° 3'24.36"N 73°29'20.14"E Residential Village

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s AstecLifesciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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The ambient air quality monitoring was carried out at nine locations including the project site for a period of three months from Dec to Feb, 2018. The results of ambient air quality.monitoring provided in Table 3.5.

Fig No. 3.6 Air Monitoring Locations on Google Earth Imagery

Table No. 3.5 Ambient Air Quality Status (Criteria Pollutants)

Values in Sr. Sampling Location Values in µg/m3 Stats mg/m3 No. Code & Name PM 10 PM 2.5 SO2 NOx CO Min 79.8 35.0 25.0 37.0 0.8 At Project Max 96.0 51.8 36.5 50.5 2.1 1 *A1 Site Avg. 87.9 44.2 29.1 43.6 1.5 98th Percentile 96.0 51.3 36.1 50.5 2.1 Near Min 77.8 21.0 18.0 22.3 0.7 2 A2 Dhamane Max 87.5 31.5 30.2 35.2 1.2

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Village Avg. 80.9 23.8 22.0 27.3 1.0 98th Percentile 87.2 30.6 29.6 34.6 1.2 Min 75.2 18.0 16.0 21.6 0.5 Dahivad Max 84.8 29.0 28.0 34.0 1.2 3 A3 Village Avg. 78.8 22.0 22.9 28.1 1.1 98th Percentile 84.6 29.0 27.4 34.0 1.2 Min 70.0 18.0 15.0 19.0 0.7 Max 84.8 28.0 26.8 29.0 1.5 4 A4 Bhavepathar Avg. 77.6 21.9 23.3 22.1 1.2 98th Percentile 84.6 28.0 26.7 29.0 1.5 Min 75.0 26.0 22.0 31.0 0.9 Max 88.0 40.0 31.0 50.0 2.0 5 A5 Birwadi Avg. 79.4 34.0 26.3 40.8 1.3 98th Percentile 86.9 39.9 30.9 49.1 1.9 Min 71.2 19.0 16.0 20.0 0.8 Near Max 85.0 29.0 27.6 30.0 1.7 6 A6 Warandh Avg. Village 76.1 22.2 18.9 23.5 1.1 98th Percentile 84.3 29.0 26.6 29.5 1.6 Min 74.0 19.9 17.0 21.1 0.6 Near Max 84.4 31.2 29.9 34.5 1.2 7 A7 Bhogaon Avg. Village 78.9 23.5 22.5 31.6 0.9 98th Percentile 84.2 30.1 29.8 34.3 1.2 Min 68.5 17.0 14.0 18.0 0.6 Near Max 83.0 27.5 25.3 29.2 1.4 8 A8 Dharwali Avg. Village 71.3 21.7 21.4 22.2 1.0 98th Percentile 78.9 27.4 25.2 29.1 1.4 NAAQ Standard 100 60 80 80 4.0 Note: *Monitoring & Analysis performed by Sadekar Enviro Engineers Pvt. Ltd, Laboratory.

3.3.6 Interpretation of Primary Data

PM10 The study reveals that maximum concentration was observed to be in the range of 83 & 96 µg/m3. The highest 24-hourly concentration was recorded at sampling location A1. whereas the minimum concentration was observed at location A8. The average concentration of PM10 can be said to be ranged between 71.3-87.9 µg/m3. The high concentration of particulate matter recorded at project site (A1) may be due to various vehicular emissions and urban activity like

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Chapter 3 –Description of the Environment construction etc,.The minimum concentration at location A8 can be said due to its remote location and minimal human activity in and around the monitoring station. Therefore experiences minimal levels of pollution.

PM2.5

The major source of PM2.5 is said to be the combustion of fossil fuels, fire wood, etc. The 3 maximum of PM2.5 (51.8 µg/m ) during the study period was recorded at location A1, whereas the minimum 17.0 µg/m3 concentration was recorded at A8 location which is a remote area. The minimum concentration indicates that the area experiences minimal combustion and vehicular activity. On the other hand high concentration at location A1 indicates that the area experiences high emissions from combustion of fossil fuel and vehicular movement in the surroundings. It is important to note that location A1 lies in the surrounding of heavy urbanization which experiences constant movement of vehicles which can be said to be the major cause for increase in the concentration of PM2.5. The average concentration of PM2.5 during the study period was computed to be in the range of 21.7-44.2 µg/m3.

Sulphur dioxide (SO2)

High level of SO2 in ambient air indicates the presence of combustion of fossil fuel in the vicinity. The ambient air monitoring results indicate that the highest average concentration of

SO2 is experienced at location A1. The emission from other industries & constant traffic and regular movement of heavy vehicles which are diesel driven around the MIDC area can be considered as the principle source of emission for SO2. The average concentration of SO2 recorded at all the monitoring locations during the study period ranged between 18.9-29.1 µg/m3 respectively. It should be noted that maximum average concentration was recorded at location A1 while the lowest can be observed at location A6. The location A6 is scarcely populated and is remotely located. Hence low levels of anthropogenic activities and emissions are observed in the area. The concentration of SO2 were within the CPCB limit at all the location.

Oxides of Nitrogen (NOX)

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The various forms of Nitrogen in NO, NO2 and N2O are collectively called as Oxides of

Nitrogen. The highest value of NOX during the monitoring period was observed at location A1 & A5 while the minimum average was recorded at A8. The average concentrations were in the 3 range of 22.1-43.6 µg/m . The maximum 24 hourly value of NOX was recorded at the monitoring location A1 (50.5µg/m3) & A5 (50 µg/m3) whereas the minimum concentration of NOx was recorded at location A8 (18 µg/m3). It should be noted that the location A8 was observed to have minimal vehicular activity resulting in minimal concentration of pollutants.

Carbon monoxide (CO) The anthropogenic source of CO is due to incomplete combustion of fuel majorly in absence of air. The maximum concentration of CO estimated at all locations during the study period can be observed to be within 1.2 to 2.1 mg/m3 respectively. The minimum concentration at all locations ranged between 0.5 - 0.9 mg/m3. The highest average is calculated at location A1 and the lowest average was estimated to be at location A7.

Monitoring of Additional Parameters: The monitoring for additional parameters in ambient air namely Ozone, Lead, Ammonia, Arsenic, Benzene,Nickel &Benzo(a)pyrene was conducted within the project premises (A1 location). The results for these parameters are presented in Table 3.6. It can be stated that concentration of Benzene, Benzo(a)pyrene& Ammonia was found to be below the detection limit. The values of Ground level ozone were estimated to be within the range of 21 to 30.6 µg/m 3. The average concentration was computed to be 25.5 µg/m3. The presence of heavy metals such as lead, arsenic and nickel were estimated to be below the detectable limits and thus their presence can be said to be negligible. As mentioned earlier the concentration of VOCs was also monitored at the project site. The results revealed that the concentration was found to be below the detection limit as presently.

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The analysis of additional parameters monitored for ambient air quality at the location A1 reveals that the values did not exceed the limits prescribed by CPCB, during the sampling period.

Table 3.6 Results of Additional Air Quality Parameters at Project Site

A1- Premises of AstecLifesciencesLtd NAAQ Sr. No. Parameters Min. Max. Avg. Standards 3 1. Ozone (O3) µg/m 21 30.6 25.5 100 (8 Hourly) 2. Lead (Pb) ng/m3 <0.10 <0.10 <0.10 1.0 (24 Hourly) 3 3. Ammonia (NH3) µg/m <20.0 <20.0 <20.0 400 (24 Hourly) 4. Benzo (a) pyrene (BaP) ng/m3 <0.20 <0.20 <0.20 1.0 (Annual) 5. Arsenic (As) ng/m3 <5.00 <5.00 <5.00 6.0 (Annual) 6. Nickel (Ni) ng/m3 <5.00 <5.00 <5.00 20 (Annual) 3 7. Benzene (C6 H6) µg/m <1.0 <1.0 <1.0 5 (Annual) Volatile Organic Compounds 8. (VOCs) (ppb) <1 *Note: Monitoring & Analysis performed by Sadekar Enviro Engineers Pvt. Ltd., Laboratory. ** N.S.: Not Specified

Conclusion: The descriptive statistics of the monitoring at all the locations are indicating that pollution levels did not exceed the standards prescribed by the CPCB. It should be noted that 98th Percentile values computed at all the sampling locations were similar to the maximum value observed at most of the locations indicating a negligible variance in the observations obtained.Furthermore, the additional parameters monitoredat thesampling location no. A1 also indicated that the parameters monitored did not exceed the standards provided by CPCB. The lowest level of pollution is experienced at location A8 which is located in a remote location because of minimal anthropogenic activity. It can be concluded that the background air quality around the project area is not polluted as the parameters were well within the prescribed CPCB limits.

3.4 Surface Water Quality 3.4.1 Surface water sources in the study area

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The surface water resources in the study area as studied from the satellite imagery appear to be few in number, especially for the purpose of drinking water. The primary surface water bodies in the study area are Kal & Savitri river’s in the south direction. Apart from this the study area has presence of reservoirs, lakes, located within the 10km radius or the study area. The Savitri receives water on its course from different streams and rivulets on its course from North of the project site to South West of project site. The sampling locations for the water bodies were finalized after reconnaissance survey and consultation with the functional area experts from the respective areas. 3.4.2 Probable sources of surface water pollution in the study area The Savitri River Stretch in the study area is subjected to industrial and domestic discharges from the MIDC area. It is to be noted that the river stretch is also subjected to discharge of domestic effluent from the residential area of Mahad, Birwadi and other surrounding villages.

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Fig No. 3.7 Surface Water Monitoring Locations

3.3.3 Sampling Methodology

a. Criteria for Selection of water quality sampling locations While selecting a sample it is always important to take care that the sample should be representative of the selected water body. In order to remove the bias in sample selection, grab samples were collected on random basis considering the following key aspects: 1. The sampling locations were selected based on upstream and downstream uses of the water body.

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2. Drainage Pattern of study area in general. 3. Discharge points of local and/or CETP treated effluents from MIDC into the water bodies 4. Location, use and importance of Lake, Dam or other reservoirs in the study area 5. Water bodies or streams which may be affected due to the proposed activity. Based on the above understanding and guidance from the functional area experts, selected sampling locations are presented on Google Earth Imagery in Fig. 3.8 and on SOI Toposheet in Fig. 3.9. A total of eight sampling locations were selected for the present study. The details of the sampling locations are highlighted in Table 3.9. 3.3.4 Sampling Details Grab samples were collected from the identified surface water bodies located in the study area. The sampling frequency was once during the sampling period of the proposed project (study period – Dec. 17 to Feb. 2018). 3.3.5 Sample Collection, Preservation and Transportation: Sampling was carried out in presence of FAE and trained personnel having training and experience. The necessary procedures were followed during the process of sample transport and storage in order to maintain homogeneity of the samples and to avoid any significant alterations in their condition thereby rendering them in an unacceptable state for analysis at the laboratory. In order to comply with the above statement some of the important points focused while sample transportation and storage are highlighted as under: • Samples were collected in HDPE containers and packed to avoid breakage and cross- contamination.

• Sample degradation was reduced through appropriate preservation and 1ml 1N HNO3 per liter of sample was added for analysis of selected metals. • Sample containers were sealed, labeled and carefully packed with an appropriate packing material and stored in chilled containers (around 4C). The chain of custody records was also maintained as per standard protocol. • Microbiology samples were collected in sterile Pyrex-glass bottles

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• The pH and Temperature were monitored at the time of collection and the DO was fixed on site. The list of parameters assessed and the methodologies for analysis of water samples are presented in Table 3.7. The method detection limits are also provided in the table with respective units of measurement. The details of sampling locations are provided in Table 3.8.

Table No.3.7:Methodologies Used for Surface Water Analysis Sr. No. Parameter Method Detection Limit/ Unit 1 pH APHA 4500 H+ - B 0.01-14 2 Total Dissolved Solids APHA 2540 - C 5.00 mg/lit 3 Chlorides as Cl- APHA 4500 Cl- - B 10.00 mg/lit - 2 4 Sulphate as SO4 APHA 4500 SO4 - E 1.00 mg/lit 5 Total Hardness as CaCO3 APHA 2340 - C 2.00 mg/lit 6 Nitrate as NO3 APHA-4500-NO3-B 1.00 mg/lit 7 Fluoride as F- APHA-4500-F- - D 0.02 mg/lit 8 Phosphate APHA-4500-PC 1.00 mg/lit 9 Bicarbonate APHA 2340 - B 1.00 mg/lit 10 COD APHA-5220-B 4.00 mg/lit 11 BOD APHA-5210-B 3.00 mg/lit 12 DO APHA-4500-C 1.00 mg/lit 13 Arsenic as As APHA- 3114-B 0.01 mg/lit 14 Calcium as Ca APHA- 3500-B 1.00 mg/lit 15 Cadmium as Cd APHA- 3111-B 0.003 mg/lit 16 Chromium as Cr APHA- 3112-B 0.05 mg/lit 17 Iron as Fe APHA- 3111-B 0.3 mg/lit 18 Lead as Pb APHA- 3111-B 0.01 mg/lit 19 Magnesium as Mg APHA- 3111-B 1.00 mg/lit 20 Mercury as Hg APHA- 3112-B 0.001 mg/lit 21 Nickel as Ni APHA- 3111-B 0.02 mg/lit 22 Potassium as K APHA- 3111-B 0.1 mg/lit 23 Sodium as Na APHA- 3111-B 0.1 mg/lit 24 Zinc as Zn APHA- 3111-B 0.1 mg/lit 25 Total coliforms at 370C for 48 hrs. APHA-9221-B Absent 26 Ecoli at 44.50C for 24hrs. APHA-9221-G Absent

The results for the samples are provided in Table 3.9.

Table No. 3.8 Details of Surface Water Quality Monitoring Stations

Sr. Sampling Location AstecLifesciences ltd

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No. Dist. Direction Lat Long (Km) Kal River Upstream of 1 SW1 NE 5.6 18° 7'6.90"N 73°32'23.88"E MIDC area Kal River near 2 SW2 NE 3.48 18° 6'22.02"N 73°31'20.63"E Additional MIDC area Kal River Downstream 3 SW3 SEE 0.9 18° 5'52.35"N 73°29'52.23"E of Birwadi Savirti River tributary 4 SW4 Downstream of Mahad West 1.46 18° 6'3.59"N 73°28'34.07"E CETP Savirti River Near 5 SW5 SWW 4.71 18° 4'43.16"N 73°25'51.17"E Mahad City Stream at Bhorao 6 SW6 SW 2.35 18° 5'5.38"N 73°28'31.73"E Village Stream at 7 SW7 North 8.29 18°10'31.56"N 73°29'51.48"E WalanBudruk 8 SW8 Waland Dam NE 9.96 18° 8'17.47"N 73°34'33.73"E

During the sampling it was observed that the water from the selectedwater bodies was used for various purposes. Based on their usage& information provided by the locals these water bodies.The categorization is confirmed based on the analysis performed on the sample to conclude its fit for the said usage. The criteria for classification of the water bodies are provided in Table 3.10. Based on the results and observations during sampling, it can be stated that, the locations SW1 to SW5 to can be classified into the “E” category whereas the water bodies SW6, SW7 &SW8 can be categorized into category “B”.

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Table No. 3.9 Surface Water Quality Results

Sr. Locations Parameters Unit No. SW-1 SW-2 SW-3 SW-4 SW-5 SW-6 SW-7 SW-8 1. pH 7 7.5 7.1 7.7 8.2 7.2 7.7 7.4 - 2. Total Dissolved Solids 281 243 319 218 260 180 245 154 mg/lit 3. Chlorides as Cl- 28 42 64 23 39 26 21 23 mg/lit - 4. Sulphate as SO4 9.9 5.3 6.8 15.8 20.8 10.7 2.7 9.1 mg/lit

5. Total Hardness as CaCO3 100 114 130 107 91 85 103 81.6 mg/lit

6. Nitrate as NO3 7 6.7 5.4 6.8 6 4.8 5.2 2.3 mg/lit 7. Fluoride as F- 0.254 0.416 0.454 0.41 0.276 0.274 0.274 0.227 mg/lit 8. Arsenic as As <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 mg/lit

9. PO4-- 48 56 60 65 68 44 61 41 mg/lit 10. Bicarbonates 76 102 100 96 84 87 88.9 71 mg/lit 11. Calcium as Ca 27.67 16.5 24.06 20.3 23.66 17.5 30.18 22 mg/lit 12. Cadmium as Cd <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 mg/lit 13. Iron as Fe <0.30 <0.3 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 mg/lit 14. Lead as Pb <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 mg/lit 15. Magnesium as Mg 12.8 8.3 12.5 13.3 17 9.8 14.8 11 mg/lit 16. Chromium as Cr <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 mg/lit 17. Mercury as Hg <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 mg/lit 18. K+ 0.33 1.7 0.6 0.74 1.7 1.5 1.35 1.1 mg/lit 19. Nickel as Ni <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 mg/lit 20. Na+ 14.4 32.6 8.3 31.5 22.8 17.8 18.3 13.4 mg/lit 21. Zinc as Zn <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 mg/lit 22. Total coliforms at 370C for 48 hrs. 22 82 41 92 50 13 26 18 Org/100ml 23. Ecoli at 44.50C for 24hrs. Absent Present Present Present Present Absent Absent Absent Org/100ml 24. COD 10 42 26 90 16 <4 8.6 <4 mg/lit 25. BOD 3.6 14.7 9.7 32.1 4.4 <3 3.7 <3 mg/lit 26. DO 6.2 6.5 6.2 6.1 6.7 6.4 6.2 6.6 mg/lit Note: Monitoring & Analysis performed by Sadekar Enviro Engineers Pvt. Ltd., Laboratory

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Table No. 3.10 IS: 2296–1982_Inland_Surface_Water_Stds

Parameter A B C D E Unit pH 6.5-8.5 EC - - 1000 2250 mS/c Color 10 300 300 - - Hazen Odor Agreeable - - - - - TSS - - - - - mg/l TDS 500 - 1500 - 2100 mg/l Turbidity - - - - - mg/l AlkalinityasCaCO3 - - - - - mg/l Chloride as Cl 250 - 600 - 600 mg/l SulphateasSO4 400 - 400 - 1000 mg/l NitratesasNO3 20 - 50 - - mg/l HardnessasCaCO3 300 - - - - mg/l CalciumasCaCO3 200 - - - - mg/l MagnesiumasCaCO3 100 - - - - mg/l Sodium as Na - - - - - mg/l Potassium as K - - - - - mg/l Fluoride as F 1.5 1.5 1.5 - - mg/l Iron as Fe 0.3 - 50 - - mg/l DO 6 5 4 - - mg/l COD - - - - - mg/l BODat27oC 2 3 3 - - mg/l A-Drinking water without conventional treatment but after disinfection B-Outdoor bathing(organized) C-Drinking water source with conventional treatment followed by disinfection D - Propagation of wild life, fisheries E -Irrigation, industrial, cooling, controlled waste disposal

3.3.6 Interpretation The results presented in the earlier section are discussed and concluded in this section. The values obtained are compared with the standards prescribed for the respective designated use of the water body as categorized in the earlier part of the study.The analysis helps to concluded that the pH of all the samples was found to vary between: 7–8.2. It should be noted that the values obtained were within the desirable limit for pH as prescribed by CPCB. The total hardness was

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It should be noted that in case of the selected water bodies (SW-1 to SW-5) classified under category “E”, the parameters were found to be within the prescribed limits. The results for location SW-6 , SW-7 & SW8 categorized in category “B” indicated that all the parameters were found to be within the prescribed limits except for SW-7 the BOD value was above the prescribed limit. Hence for SW-7 the water can be continued for its designed use as per Inland Surface Water Standards after disinfection and necessary treatment.

3.3.7 Whether the site falls near to the polluted stretch of river identified by the CPCB/MoEF& CC The proposed project of M/s Asteclifesciences Ltd. falls at a distance of 2.70km from the stretch of Savitri River which is identified as polluted by the CPCB. The identified polluted stretch of

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Savitri River is around 2 km, from Dandi to Muthavali. (DADLI, MUTHAVALI, RAJEWADI, KEMBURLI). It has been classified under priority class III having the BOD values in the range of 4.4 to 15 mg/l. Another river in the study area i.e. Kal River is not identified as polluted river by CPCB. The distance of the Kal River from the project site is around 870 m. (Reference: Series: MINARS/37 /2014-15 RIVER STRETCHES FOR RESTORATION OF WATER QUALITY by CPCB, dated Feb 2015.)

3.5 Ground Water Quality 3.5.1 Ground water sources in the study area Although, fresh water is supplied by the pipeline in the Mahad city, ground water is used as an alternate source in surrounding villages for domestic purposes. Therefore it is important to assess the existing baseline status of the ground water quality. 3.5.2 Probable sources of ground water pollution in the study area Ground water can be said to be affected by activities such as uncontrolled discharge of treated and/or untreated industrial effluent, open discharge of treated and/or untreated sewerage in the surrounding area. Apart from the above ground water can be polluted by other activities such as excessive use of chemical fertilizers in farming, leaching from landfills having toxic or municipal solid waste, etc. 3.5.3 Sampling Details The section discusses regarding the sampling related procedures, methodologies and parameters selected for analysis. The section also highlights the criteria adopted for selection of ground water sampling locations. The selected sampling locations and their coordinates are presented in Table 3.11. Table No. 3.11 Details of Sampling Locations for Ground Water samples

M/s AstecLifesciences Ltd Sr. Sampling Location Dist. Source of No. Direction Lat Long (Km) Sampling 1 GW1 Mahad SW 6.61 18° 4'58.97"N 73°25'48.85"E Borewell 2 GW2 KambetarfBirw NW 2.54 18° 6'45.08"N 73°28'8.96"E Open Well

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adi 3 GW3 Dhamane-gaon North 2.96 18° 7'39.79"N 73°29'28.39"E Open Well 4 GW4 Warandh NE 9.5 18° 8'4.54"N 73°34'21.48"E Open Well 5 GW5 Padavi NE 9.27 18° 8'57.66"N 73°33'41.21"E Open Well 6 GW6 Kiye SE 9.89 18° 5'8.87"N 73°34'55.82"E Borewell 7 GW7 Wadghar SE 5.05 18° 4'7.61"N 73°31'25.71"E Open Well 8 GW8 Birwadi E 2.15 18° 6'2.11"N 73°30'36.59"E Borewell

As per the Standard ToR sampling was decided to be carried out at 8 locations. The sampling locations were selected on random basis subject to the availability and feasibility. The water quality monitoring network was designed with the intention to evaluate the prevailing ground water quality in the study area. The sampling frequency was once in a season (study period – Dec 17 to Feb, 2017). The details of the methodology for ground water sampling is provided in Table No. 3.12 3.5.4 Selection criteria for water quality sampling locations The sampling sites were selected considering the following criteria - 1. Topography of the study area Pattern. 2. Areas which may be affected due to the activity. 3. Any probable locations with open discharge of sewage or waste water. 4. Location of any solid waste dumping facility in the vicinity of the project site. In cases where the sampling locations are situated close to MIDC areas, ground water pollution can be said to be affected by underground (illegal) discharging of waste water by the industrial units. If any such cases are reported then sampling is conducted in the surrounding area. Based on the above criteria eight sampling locations were selected for the present study. These locations are marked on SOI map in 3.11. The results for analysis conducted are presented in Table 3.13. These results are compared with the drinking water standards provided by IS (Table 3.14). The aspects related to Sample Collection, Preservation and Transportation are described in detail in the above section 3.4.5.

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Table.3.12 Parameters and Methodologies for Analysis of Ground Water Samples Sr. No. Parameter Method Detection Limit/Unit 1. pH APHA 4500 H+ - B 0.01-14 2. Total Dissolved Solids APHA 2540 - C 5.00 mg/lit 3. Chlorides as Cl- APHA 4500 Cl- - B 10.00 mg/lit - 2 4. Sulphate as SO4 APHA 4500 SO4 - E 1.00 mg/lit 5. Total Hardness as CaCO3 APHA 2340 - C 2.00 mg/lit 6. Nitrate as NO3 APHA-4500-NO3-B 1.00 mg/lit 7. Fluoride as F- APHA-4500-F- - D 0.02 mg/lit 8. Phosphate APHA-4500-PC 1.00 mg/lit 9. Bicarbonate APHA 2340 - B 1.00 mg/lit 10. COD APHA-5220-B 4.00 mg/lit 11. BOD APHA-5210-B 3.00 mg/lit 12. Arsenic as As APHA- 3114-B 0.01 mg/lit 13. Calcium as Ca APHA- 3500-B 1.00 mg/lit 14. Cadmium as Cd APHA- 3111-B 0.003 mg/lit 15. Chromium as Cr APHA- 3112-B 0.05 mg/lit 16. Iron as Fe APHA- 3111-B 0.3 mg/lit 17. Lead as Pb APHA- 3111-B 0.01 mg/lit 18. Magnesium as Mg APHA- 3111-B 1.00 mg/lit 19. Mercury as Hg APHA- 3112-B 0.001 mg/lit 20. Nickel as Ni APHA- 3111-B 0.02 mg/lit 21. Potassium as K APHA- 3111-B 0.1 mg/lit 22. Sodium as Na APHA- 3111-B 0.1 mg/lit 23. Zinc as Zn APHA- 3111-B 0.1 mg/lit 24. Total coliforms at 370C for 48 hrs. APHA-9221-B Absent 25. Ecoli at 44.50C for 24hrs. APHA-9221-G Absent

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Fig No. 3.8 Ground Water Monitoring Locations

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Table No. 3.13 Ground Water Quality Results

Results Sr. No. Parameter Unit GW-1 GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 1. pH 8.5 8.2 8.3 8.1 8 8.4 7.8 8.2 - 2. Total Dissolved Solids 353 267 390 258 268 387 277 322 mg/lit 3. Chlorides as Cl- 33.2 25 23 42 36 31 19.7 17 mg/lit 4. Sulphate as SO4- 5.4 5.1 1.6 12.4 50.2 56.2 12.2 2.7 mg/lit 5. Total Hardness as CaCO3 106 104 177 122 111 151 127 128 mg/lit 6. Nitrate as NO3 8.4 9.3 7.4 6.4 2 2.8 4.1 4.6 mg/lit 7. Fluoride as F- 0.434 0.378 0.334 0.214 0.36 0.28 0.24 0.20 mg/lit 8. Arsenic as As <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 mg/lit 9. Cadmium as Cd <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 mg/lit 10. Calcium as Ca 26.8 20.3 13.1 30.3 44.2 52.2 36.7 45 mg/lit 11. Iron as Fe <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 mg/lit 12. Nickel as Ni <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 mg/lit 13. Lead as Pb <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 mg/lit 14. Mercury as Hg <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 mg/lit 15. Magnesium as Mg 17.8 12.3 10.6 8.4 12.4 10 11.3 17.1 mg/lit 16. Zinc as Zn <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 mg/lit 17. Total coliforms at 370C for 48 hrs. Absent 26 20 16 15 Absent 19 Absent Org/100ml 18. E.-coli at 44.50C for 24hrs. Absent Absent Absent Absent Absent Absent Absent Absent Org/100ml 19. COD <4.00 <4.00 <4.00 <4.00 <4.00 <4.00 <4.00 <4.00 mg/lit 20. BOD <3.00 <3.00 <3.00 <3.00 <3.00 <3.00 <3.00 <3.00 mg/lit 21. Sodium 25.4 14 14.3 30.2 20.2 20.2 15.2 12.2 mg/lit 22. Potassium 1.7 0.5 0.3 0.4 1.8 5.4 1.5 2 mg/lit 23. Phosphate 21.5 11.1 13 27.6 17.1 17.7 8.6 10.5 mg/lit 24. Bicarbonate 148 140 177 92 84 190 78 128 mg/lit 25. Chromium <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 mg/lit Note: *Monitoring & Analysis performed by Sadekar Enviro Engineers Pvt. Ltd., Laboratory

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Table 3.14 IS: 10500:2012 Standards for Drinking Water Permissible in the Sr. No. Parameter Acceptable Absence of Alternate Unit source 1 pH 6.5-8.5 No relaxation 2 Total Dissolved Solids 500 2000 mg/l 3 Chlorides as Cl- 250 1000 mg/l - 4 Sulphate as SO4 200 400 mg/l 5 Phosphate NS NS mg/l 6 Total Hardness as CaCO3 200 600 mg/l 7 Nitrate as NO3 45 No relaxation mg/l 8 Bicarbonate NS NS mg/l 9 Arsenic as As 0.01 0.05 mg/l 10 Calcium as Ca 75 200 mg/l 11 Sodium NS NS mg/l 12 Potassium NS NS mg/l 13 Cadmium as Cd 0.003 No relaxation mg/l 14 Iron as Fe 0.3 No relaxation mg/l 15 Lead as Pb 0.01 No relaxation mg/l 16 Chromium 0.05 No relaxation mg/l 17 Mercury as Hg 0.001 No relaxation mg/l 18 Nickel as Ni 0.02 No relaxation mg/l 19 Zinc as Zn 5 15 mg/l Total coliforms at 370C for 48 20 Absent Absent Org/100ml hrs. 21 Ecoli at 44.50C for 24hrs. Absent Absent Org/100ml 22 COD NS NS mg/l 23 BOD NS NS mg/l 24 Fluoride F- 1.0 1.5 mg/l 25 Magnesium Mg++ 30 100 mg/l * NS: Not Specified

3.5.5 Interpretation: The above results indicate that the pH of all the ground water samples was within the prescribed standards. The concentration of heavy metals like arsenic, zinc, chromium, lead, mercury, nickel & cadmium were below detection limit. Iron was not detected in any of the ground water samples. The hardness of all the ground water samples was found to be ranging between 104-177 mg/lit. The value of hardness was within the acceptable limit at all the locations. It can be observed that the values for total dissolved solids in all the sampling locations were estimated to be under the acceptable standards for drinking water. The concentration of total dissolved solids ranged between 258-390 mg/lit. The maximum concentration was observed at location GW 3 whereas the minimum concentration was observed at GW4.

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It should be noted that the microbiological analysis of allthe samples indicate that e-coli was absent in all the ground water samples. The presence of total coliforms except for GW1 ,GW6& GW8 were in the range from 15-26 Org/100 ml indicate that the anthropogenic activity in the surrounding area can be a possible source of contamination. It should be noted that the concentration of the coliforms were higher in the dugwell compared to the concentrations observed in the borewell samples. The fluoride concentrations are ranging between 0.20 - 0.434 mg/l. The presence of the fluoride in all the water samples is mostly due to geogenic in nature. The nitrates concentrations were ranging between 2.0 -9.3 mg/l well below the acceptable limits of drinking water. The probable sources of nitrates in the ground water could be the use of fertilizers in the nearby agricultural activity. The COD and BOD values of all the ground water samples were found to be below the detection limit. Thus based on the above results it can be stated that the water from the said samples can be considered fit for consumption and potable purpose with basic primary treatment. The water can be used for domestic utilization and gardening without any treatment.

3.6 Noise Level Monitoring Noise can be defined as a sound, especially one that is loud or unpleasant or that causes disturbance. High and prolonged or continuous exposure to noise levels is known to cause deleterious effects on the humans, plants and animals. In some cases short term exposure to high noise levels has been considered equally dangerous for humans and animals. In future Noise level pollution in the rural or urban areas can be of great concern. Monitoring of Noise level provides an insight pertaining to the prevailing conditions of noise in the surrounding areas. This data when available is considered as a baseline data for a given area and based on the data predictions in increase in noise levels are carried out. 3.6.1 Noise generation sources in the study area As the project site is located in the notified industrial area, various sources of noise generation can be said to be arising from the various industrial activities carried out in the surroundings. Other sources contributing to high noise levels can be attributed to movement

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Chapter 3 –Description of the Environment of heavy vehicles in the nearby areas. Apart from the heavy vehicles, the number of public and private vehicles plying in the region can be said to contributing towards noise pollution. The stone mining activities were identified in the study area which can be potential source of noise pollution. Noise can be said to generate through various industrial processes and machineries operating in the industries. 3.6.2 Monitoring Details For the present study Noise monitoring was carried out as per the Central Pollution Control Board guidelines on 24-hourly basis at 8 locations in 10 km radius of the study area. Monitoring was carried out on weekly basis (once in a week). The locations were decided as per the guidance of the Functional Area Experts and are presented in Fig 3.9 on Google Earth Img. The noise levels monitored were grouped into day and night time noise levels. The day time is considered to be during 6 am to 10 pm and night noise time is considered between 10 pm to 6 am at all the locations in the study area. The noise monitoring was carried out by a precision integrated noise meter of baseline technology Model No. 2511. It should be noted that location N1 is situated in the industrial area while rest of the locations are categorized into rural and residential areas. The standards used for comparison of the noise levels are therefore used as per the standards prescribed regulations of CPCB. 3.6.3 Criteria for selection of noise level monitoring locations The locations for representative noise monitoring were selected considering the following criteria:- 1. Identification of probable sources. 2. Identification of Sensitive Receptors around the project area. 3. Individuals/Areas likely to be affected due to the expansion activity. 4. Topography of the study area. 5. Site feasibility related to accessibility, etc. The details of the monitoring locations are provided in Table 3.15.

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Fig. 3.9: Sampling Locations for Noise Monitoring

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Table No. 3.15 Details of Noise Quality Monitoring Stations

M/s AstecLifesciences Ltd Sr. Sampling Location Dist. No. Direction Lat Long Type of Area (Km) 1 N1 Project Site -- -- 18° 6'3.56"N 73°29'23.84"E MIDC Near Dhamane 2 N2 N 2.66 18° 7'30.25"N 73°29'19.93"E Agricultural Village

3 N3 Dahivad Village NNE 6.25 18° 8'36.04"N 73°31'44.40"E Residential 4 N4 Bhavepathar E 6 18° 6'15.12"N 73°32'47.58"E Residential 5 N5 Birwadi E 2.10 18° 6'3.11"N 73°30'35.26"E Residential Near Warandh 6 N6 NEE 9.56 18° 7'38.71"N 73°34'33.48"E Agricultural Village Near Bhogaon 7 N7 NW 2.65 18° 6'42.82"N 73°28'3.62"E Residential Village Near Dharwali 8 N8 S 4.97 18° 3'21.93"N 73°29'18.09"E Residential Village

The ambient noise quality monitoring results for all the monitoring locations is presented in Table 3.15. Table No. 3.16 Result of Ambient Noise Monitoring

Noise in dB(A) Leq Noise in dB(A) Leq Code Monitoring Location Daytime Night Time N1 Project Site 72 61 N2 Near Dhamane Village 52.6 43 N3 Dahivad Village 51.4 42.6 N4 Bhavepathar 50.2 40.3 N5 Birwadi 55 44.7 N6 Near Warandh Village 50.8 42 N7 Near Bhogaon Village 52.8 43.2 N8 Near Dharwali Village 50.6 41.7 NAAQ Noise Limit (Industrial Area) 75 70 NAAQ Noise Limit (Residential Area) 55 45 Note: Monitoring & Analysis performed by Sadekar Enviro Engineers Pvt. Ltd, Laboratory.

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3.6.4 Interpretation Industrial Zone The day time noise level at the project premises was observed to be 72.0 dB (A) while during night time the noise level was recorded to be 61.0 dB (A). It should be noted that the noise levels during the day time as well as night time were estimated to be under the prescribed standards by Central Pollution Control Board. Residential Zone The noise monitoring conducted at seven locations for 24hr, once in a week and average hourly readings were recorded. The minimum noise level recorded during the daytime was observed at location N4, where as the maximum noise levels can be observed at location N5. The location N5 is densely populated and hence can give rise to high noise level in the surroundings. It should be noted that the permissible limits for noise did not exceed at any of the locations selected for sampling.

3.7 Soil Quality 3.7.1 Probable sources of soil pollution/contamination in the study area Soil can be said to be polluted due to the discharge of treated or un-treated effluent, hazardous waste generated, solid waste by various industries located in the industrial cluster. If the industrial wastes are not disposed off scientifically they may leach into soil and affect the soil quality adversely. This problem can also arise by uncontrolled disposal of municipal solid waste or sewage inhabited or vacated land. 3.7.2 Sampling Techniques:  The soil samples were collected from 1.5 m depth  The samples were stored in 1Kg. HDPE zip-lock bags and transported to laboratory in cool and dry containers.  The samples were analyzed for physical & chemical characteristics. The samples have been analyzed as per the established methods for physico-chemical parameters & heavy metals.

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3.7.3 Sampling Details  The sampling frequency was once a season (study period Dec.2017 to Feb.2018) from eight locations. 3.7.4 Criteria for soil sampling location The locations for collection of representative sample were selected considering - 1. From different types of land uses in the study area. 2. From possible polluted & comparatively controlled locations in the study area. 3. From the leeward and downward of the prominent wind direction Based on the above understanding the eight sampling locations were identified for the purpose of sampling is presented in Fig. 3.14 and Fig. 3.15 on Google Earth Image and SOI maps. The coordinates of the sampling locations are provided in Table 3.16.

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Fig. No. 3.10 Soil Quality Sampling Locations

Table No.3.17 Details of Soil Quality Sampling Stations Sr. Sampling Code & Dist. Coordinates Area/Land Direction No. Location (Km) North East use type 1. S1 Project Site - - 18° 6'44.79"N 73°31'4.19"E Industrial 2. S2 Near CETP W 4.1 18° 6'10.91"N 73°28'50.43"E Industrial Dhamane- 3. S3 NW 3.4 18° 7'41.79"N 73°29'27.00"E Agricultural gaon 4. S4 Warandh NE 6.4 18° 8'4.63"N 73°34'26.16"E Agricultural 5. S5 Taliye E 6.8 18° 6'38.32"N 73°34'55.67"E Agricultural 6. S6 Kive SE 6.8 18° 5'14.52"N 73°34'40.90"E Agricultural VadgharKhu 18° 3'40.35"N 73°31'59.31"E Agricultural 7. S7 S 5.9 rd 8. S8 Birwadi SW 1.64 18° 6'2.68"N 73°30'29.65"E Agricultural

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The parameters for the analysis and the corresponding methodologies are presented in Table 3.18. The results are provided in Table 3.19 Table No. 3.18 Methodology of soil quality analysis

Sr. Parameters Units Method No.

1. pH - IS:2720 (PART 26)-1987 2. Moisture Content % Procedure for Soil Analysis by Food and Agriculture 3. Organic matter % Organization of United nations /International soil reference & Exchangeable Calcium as information center compiled under Edited by LP Vanreeuwijk 4. mg/kg Ca 6 Edition 2002 5. Color - SW 846 6. Soil texture mg/kg Trivedi&Goel 7. Electrical Conductivity mS/cm IS :14767 : 2000 8. Water holding Capacity % Hand book of methods in envt studies vol-II by S K Maiti Lab SOP no. SEE/LD/SOP-SA/28 issue dt 29/03/2014 based on procedure of soil Analysis by Food and Agriculture 9. Phosphorus as P mg/kg Organization of United nations /International soil reference & information center compiled under Edited by LP Vanreeuwijk 6 Edition 2002 Lab SOP No. SEE/LD/SP-SA/04 (Based on procedure for Soil Analysis by Food and Agriculture Organization of United 10. Total Nitrogen mg/kg nations /International soil reference & information center compiled under Edited by LP Vanreeuwijk 6 Edition 2002) Leachate Preparation - Soil Analysis by Food and Agriculture 11. Nitrite as NO - mg/kg 2 Organization and rest as per APHA 4500- NO2-B 22 nd Edition 12. Arsenic as As mg/kg EPA - 3050 B 7000-B 13. Cadmium as Cd mg/kg EPA - 3050 B 7000-B 14. Chromium as Cr mg/kg EPA - 3050 B 7000-B 15. Lead as Pb mg/kg EPA - 3050 B 7000-B 16. Magnesium as Mg mg/kg EPA - 3050 B 7000-B 17. Iron as Fe mg/kg EPA - 3050 B 7000-B 18. Potassium as K mg/kg EPA - 3050 B 7000-B 19. Sodium as Na mg/kg EPA - 3050 B 7000-B

3.7.5 Interpretation The findings of the study reveal that pH of the soil in the study area ranged between 7.4 – 8 which is an indicative of the neutral to moderately alkaline nature of soil. The values for Nitrogen at all locations varied between 179 to 272 kg/ha. Maximum concentration of nitrogen was observed at location S3.

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The concentration of phosphate was estimated to be between 2.1 to 4.1Kg/ha.The highest concentration can be observed at location S7, while the lowest concentration can be observed at location S1.

It is important to note that the concentration of potassium was found to be high at all locations ranging between 63 to 81 Kg/ha.

Based on the above findings it can be concluded that the soil samples can be classified as per soil classification given by Tondon H.L.S. (2005). The samples fall under very low to medium low fertile soils (Table 3.20 and table 3.21). The presence of heavy metals like arsenic, cadmium, lead & chromium in all the soil samples were below the detection limit.

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Table 3.19 Analysis of Soil Samples

Location Sr. No. Parameters Units S1 S2 S3 S4 S5 S6 S7 S8 1 pH 7.5 7.7 8.0 7.8 7.7 7.6 7.4 7.9 - 2 Moisture Content 3.8 4 4.4 4.1 4.6 5 5.3 4.8 % 3 Organic matter 1.6 1.6 41.8 2 1.5 3 2.4 2.9 % 4 Exchangeable Calcium as Ca 35.3 43.3 41 45.6 43.8 43 40.7 47 mg/kg Reddish Reddish Reddish Reddish Reddish Reddish Reddish Reddish 5 Color - brown brown brown brown brown brown brown brown Sandy Sandy Sandy Sandy Sandy 6 Soil texture Loam Loam Loam - Laom Laom Laom Laom Laom 7 Electrical Conductivity 0.61 0.50 0.54 0.58 0.57 0.51 0.55 0.60 mS/cm 8 Water holding Capacity 50 55 54 51 56 58 60 63 % 9 Arsenic as As ND ND ND ND ND ND ND ND mg/kg 10 Cadmium as Cd ND ND ND ND ND ND ND ND mg/kg 11 Chromium as Cr ND ND ND ND ND ND ND ND mg/kg 12 Lead as Pb ND ND ND ND ND ND ND ND mg/kg 13 Magnesium as Mg 73 79.1 68.8 65.4 70.8 74.4 77.8 79.6 mg/kg 14 Iron as Fe 1.19 1.90 2.86 2.66 2.35 2.92 1.70 1.72 mg/kg Kg/ha. 15 Potassium as K 63 80 81 81 76 75 71 77 Kg/ha. 16 Total Nitrogen 179 200 272 248 240 228 232 250 Kg/ha 17 Phosphate as PO4- 2.1 2.8 3.0 3.8 3.5 3.4 2.9 4.1 18 Cation exchange capacity 20.3 25.4 30.6 27.6 30.0 31.7 33.3 26.6 me/100g 19 SAR 13.3 14.8 17.8 15.4 19.1 20.8 19.6 21.4 - Note: Monitoring & Analysis performed by Sadekar Enviro Engineers Pvt. Ltd, Laboratory.

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Table 3.20 Chemical Classification of Soil Quality Sr. No. Soil Test Classification 4.5 Extremely acidic 4.51- 5.50 Very strongly acidic 5.51-6.00 moderately acidic 6.01-6.50 slightly acidic pH 1 6.51-7.30 Neutral 7.31-7.80 slightly alkaline 7.81-8.50 moderately alkaline 8.51-9.0 strongly alkaline 9.01 very strongly alkaline

Upto 1.00 Average Salinity Electrical Conductivity 1.01-2.00 harmful to germination 2 (mmhos/cm) 2.01-3.00 harmful to crops (1ppm = 640 mmho/cm) (sensitive to salts) Upto 0.2: very less 0.21-0.4: less 0.41-0.5 medium, 3 Organic Carbon (%) 0.51-0.8: on an average sufficient 0.81-1.00: sufficient >1.0 more than sufficient Upto 50 very less 51-100 less Nitrogen (Kg/ha) 4 101-150 good 151-300 Better >300 sufficient Upto 15 very less 16-30 less 5 Phosphorus (Kg/ha) 31-50 medium 51-65 on an average sufficient 66-80 sufficient >80 more than sufficient 0 -120 very less 120-180 less 6 Potash (Kg/ha) 181-240 medium 241-300 average 301-360 better >360 more than sufficient Source: Hand Book of Agriculture, ICAR, New Delhi

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Table 3.21 Levels of Soil Fertility Soil Fertility Organic Available Available Available Level Carbon (%) N kg/ha P2O5 kg/ha K2O kg/ha Very high > 1.00 > 700 > 80.0 > 360 High 0.81- 1.00 561 – 700 64 – 80 301 – 360 Medium 0.61-0.80 421 – 560 48 – 64 241 – 300 Medium Low 0.41-0.60 281 – 420 32 – 48 181 – 240 Low 0.21-0.40 141 – 280 16 – 32 121 – 180 Very Low 0.20 140 16.0 120 Source : Tondon H.L.S.( 2005 )

3.8 Environmental Conditions at Industry

3.8.1 Workplace Air Quality

For the purpose of estimating levels of pollutants at the workplace, monitoring was conducted inside the factory premises. The work place monitoring for VOC was carried out in the month of Feb 2018. The parameters selected for the said monitoring were decided by consultation of Functional Area Expert. The details of the parameters monitored and the results are presented in Table 3.21. The monitoring of the parameters was conducted as per the standard guidelines for eight hours using Envirotech make portable sampler with model no.: APM 802.

Table 3.21 Monitoring at Workplace of Astec LifeSciences Ltd.

Sr. Avg. Parameters *Limit Unit Method No. Conc. 1. Sulphuric acid <0.01 1.0 mg/m3 NIOSH 7903 Methyl mg/m3 NIOSH 7903 2. <0.01 207 Chloride 3 3. Toluene 3 754 mg/m NIOSH 7903 3 4. Ammonia 7 35 mg/m NIOSH 7903 3 5. Chloroform 2 240 mg/m NIOSH 7903

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3 6. Xylene 2 435 mg/m NIOSH 7903 Note: Monitoring & Analysis performed by Sadekar Enviro Engineers Pvt. Ltd, Laboratory. The results reveal that all the parameters considered for the study are under the minimum detection limit as well as under permissible limits for the workplace. Therefore, the operations and methodology currently used by the company is efficient. The environmental damage from handling of the solvents and other raw materials are insignificant.

3.8.2 Stack Air Monitoring

For the purpose of environmental pollution testing, Stack air monitoring was conducted for the stacks present in the factory premises during Feb. 2018. The results of the monitoring are presented in Table 3.22. Table 3.22 Results of Stack Monitoring of Boiler for Astec Life Sciences Ltd. Stack Stack Stack No. No. 2- No. 1- S-3: D. G MPCB Stack Details Unit Boiler Method Boiler Set (250 Limit (850 (6TPH) KVA) kg/hr) Flue Gas 143 C 158 134 -- -- Temperature Stack 0.4 M 1.160 0.15 -- -- Diameter Flue Gas 5.16 m/s 7.32 7.66 -- -- Velocity Total Gas 19245.8 1683.48 Nm3/hr 356.61 -- -- Quantity 9 Particulate mg/Nm 75.2 108.6 71.2 150 IS – 11255 (Part 1) Matter (PM) 3 Boiler stack 1 - NS Boiler stack Sulphur IS – 5182 (Part 2) Kg/d 42.3 5.46 4.98 2 – 9.8 dioxide (SO2) kg/day 1969 12.25- D.G Set

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Stack Stack Stack No. No. 2- No. 1- S-3: D. G MPCB Stack Details Unit Boiler Method Boiler Set (250 Limit (850 (6TPH) KVA) kg/hr) -- mg/Nm IS – 5182 (Part 6) NOx 33.8 -- NS 3 2975 Note: Monitoring & Analysis performed by Sadekar Enviro Engineers Pvt. Ltd, Laboratory.

Table 3.23 Results of Stack Monitoring of Scrubber for Delta Astec Life Sciences Ltd. MPCB Stack Details Unit Results Method Limit Flue Gas C 34 -- -- Temperature Stack m 0.25 -- -- Diameter Flue Gas m/s 8.25 -- -- Velocity Total Gas Nm3/ 1455 -- -- Quantity hr Ammonia (N mg/N IS – 11255 (Part 6) 3 <0.8 N.S H3) m 1999 mg/N Acid Mist 19.7 35 IS – 3025 (Part 32) m3

It can be observed from the table no. 3.22 &3.23, that all the values monitored for the parameters provided are within the limits prescribed by the MPCB. Thus, it can be stated that, the present practices of air pollution control technology are sufficient for the current stacks. Apart from the above Noise monitoring was also carried out at workplace in the month Feb. 2018. The results for the same are presented in the Table 3.24. Table 3.24 Results of Noise Monitoring at Various locations at M/s Astec LifeSciences Ltd

Sr. No. Monitoring Location Noise in dB(A) Leq

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1 Near Main Gate 70.0 2 ETP Area 64.0 3 Manufacturing Area 68 4. Boiler Area 71 (Source: Noise monitoring carried out by SEEPL Laboratory)

The above results reveal that the noise level at all the locations was under the permissible limits provided by the CPCB for the Industrial premises. Thus, the workplace conditions can be said to be safe in terms of noise levels. 3.8.3Industrial Effluent Analysis The sample of waste water was collected and analyzed in order to understand the efficiency of the present effluent treatment system as well as to understand the characteristics of the waste water. The results for waste water from the factory premises are provided in this section from Table 3.25.

Table 3.25 Characteristics of Waste Water from Effluent Treatment Plant

MPCB Parameter Results unit Method standards APHA(22ndEdition ) pH 7.35 6.5 to 8.5 -- 4500 H+-B : 2012 Total Dissolved APHA(22ndEdition ) 774 2100 mg/L Solids 2540 C : 2012 Total Suspended APHA(22ndEdition ) 58 100 mg/L Solids 2540-D : 2012 BOD(3 day @ 65 100 mg/L IS 3025 (Part 44) : 1993 27 0C) APHA(22ndEdition ) COD 152 250 mg/L 5220-B : 2012 APHA(22ndEdition ) Oil and Grease 1.3 10 mg/L 5520-O &G : 2012 mg/L Cyanide Nil 0.2 -- Nil mg/L Phenolics 1.0 --

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MPCB Parameter Results unit Method standards Benzene Nil mg/L 10.0 -- Hexachloride Nil mg/L DDT 10.0 -- Nil mg/L Dimethoate 450 -- Copper Nil mg/L 9600 -- Oxychloride Nil mg/L Ziram 1000 -- Nil mg/L Paraquat 2300 -- Nil mg/L Proponil 7300 -- Nil mg/L Nitrofen 780 --

N.S: Not Specified. The above results reveal that the parameters from the Treated Effluent are within the permissible limit as provided by MPCB.

3.9.Geology & Hydrogeology of the study area The geological & hydrogeology aspects are often associated with the comparatively larger expanse of land areas & since the expansion project in consideration is a brown field project; hence the geomorphologic aspects of entire Raigad District are considered as described below as per the secondary sources.

3.9.1Geology of Raigad District The steep scarps facing the coast and some-what gentle slopes towards the east believed to be due to extensive faulting of the Ghat-region. The geology of entire study area is consisting of dark basalt and laterite. These are spread out in the form of horizontal sheets and beds and have innumerable spurs, hills, ridges, peaks and plateau.

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Geologically lowland is a platform of marine denuation raised to form a narrow plain. The steep scarps facing the coast and some-what gentle slopes towards the east believed to be due to extensive faulting of the ghat region. The geology of the entire district consists of dark colored volcanic lava and laterites which date back to Mesozoic period. These are spread out in the form of horizontal sheets and beds and have innumerable spurs, hills, ridges, peaks and plateaus. In the plains and valleys, the lava flows occurred below a thin blanket of soil which varies in thickness from place to place. Petro logically the lava flows in the district are in horizontal way with incredible uniformity in their composition, appearance and texture corresponding to basalt with an average specific gravity of 2.9. The basalt is a predominant rock formation of the district. The basalts are usually dark grey to grey in color and are hard compact and tough and fine to medium grained structure. Deccan Trap rock which is completely impervious to percolation, these causing an accuse shortage of water in summer. Beds of laterite can be said to be, usually formed by mechanical and chemical disintegration brought by atmospheric agencies on the underlying trap, cap of several picks and lofty ridges in the district.

The types of rocks present in the Raigad region can be highlighted as under:

Deccan Trap Basalt Ground water in Deccan Trap Basalt occurs mostly in the upper weathered and fractured parts down to 10 – 15 m bgl under unconfined condition. The water bearing strata at deeper depth exists under semi confined to confined conditions. The dugwells in these areas show rapid decline in water level during post-monsoon period and practically go dry in peak summer. In foot hill zones the water table is relatively shallower near water course. The yield of dugwells tapping upper phreatic aquifer ranges between 45 to 60 m3/day, whereas that of borewells varies from 0.50 to > 20 m3/hr. depending upon the location.

Beach Sand/Alluvium

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The Alluvial deposits are found along the coastal areas in few isolated patches having limited areal extent as Beach Sand and along the course of major rivers. In the alluvial deposits, primary porosity is due to the inter-granular pore spaces making sands and gravels good water bearing formations. The ground water occurs under phreatic/unconfined aquifer at relatively shallow depths of 3-5 m and their yield ranges from about 18 to 43 m3/hr.

Fig 3.11 Geological Map of Raigad District, Maharashtra State Source: Ground Water Information Raigarh District Maharashtra, Central Ground Water Board, 2013

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3.9.2 Hydrogeology of Raigad District

The district is drained by short westwards flowing parallel streams, which originate in the Sahyadri Mountains in the east and flow into the Arabian Sea. Ulhas, Patalganga, Amba, Kundlika, Savitri, Kal, Gandhari and Ghod are the major rivers in the district. The district has experienced hot and humid climate.

Central Ground Water Board periodically monitors 28 National Hydrograph Network Stations (NHNS) in Raigarh district, four times a year i.e. January, May, August and November

Depth to Water Level (May – 2011)

The depth to water levels in major parts of the district during May 2011 ranges between 0.95 m bgl (Jite) and 7.70 m bgl (Chinchwad). Depth to water levels during pre-monsoon (May 2007) has been depicted in. The water level in major part of the district ranges from 2-5 mbgl. The water level ranging from 5 to 10 mbgl are observed in northern and in southern part of the district i.e around Poladpur, Chandore and Temple also as scattered patches across the district. Shallow water levels of less than 2 mbgl are also found across the district as isolated patches.

Source: Ground Water Information Raigarh District Maharashtra, Central Ground Water Board, 2013

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Figure 3.12 Depth of Ground Water Level

Source: Groundwater Survey & Development Agency

3.10 Traffic Study The purpose of this study is to assess the local transportation connectivity to the project site and to estimate the current traffic scenario for assessing whether the existing infrastructure viz. local road network & access ways in the project affected corridors are sufficient or not to bear with the additional vehicular mobility due to the expansion project & is also able to have access to infrastructures needed for the future developments & its functionality. 3.10.1. Objective The objective of the study is to assess & study the present traffic pattern on the main access roads to the project site in order to estimate the traffic flow pattern during the operational phase of the proposed expansion project. 3.10.2. Methodology Generally traffic surveillance study involves one or other survey technique either by manual observation or automatic method by using instruments. The traffic survey methodology adopted for

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Chapter 3 –Description of the Environment current study is Classified Traffic Volume Count Survey. The sampling locations for the study are depicted in Fig. 3.13 and provided in Table 3.24. 3.10.3. Method of Counting The counting of vehicles was achieved by following one method: 1) Manual Method The survey by this method mainly involves visual counts by the survey team. a. Equipments used i.) Garmin GPS Garmin e-trex 10 GPS was used to locate the pre decided observation points. ii.) Measuring Tape A measuring tape was used to measure the road breadth.

Figure 3.13: Traffic Observation Locations 3.10.4. Data Collection

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The transport roads for the proposed project have been identified; transportation of material carrying vehicles will mainly take place through National Highway No. 66 (Mumbai – Chennai road). Further access up to project site is achieved by internal road connecting MIDC and Main Road. The important traffic junctions identified on the above road are:

i) Junction joining the National Highway No.66 and MIDC ii) Junction joining the MIDC main road and feeder road to internal road of MIDC.

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Table 3.26 Traffic study observation locations

Sr. No. Observation Point Code Observation Point Details Aerial Distance from Project site (Km) 1 TS1 Junction joining the National 3.09 KM Highway No.66 and MIDC

2 TS2 Junction joining the MIDC 4.64 KM main road and feeder road to internal road ofMIDC.

3.10.5. Categorization of Traffic To establish effective vehicle count during the survey the traffic was categorized into Heavy Vehicles (Multi Axle Vehicles), Truck, Tempo, Bus, Car, Auto (Three Wheelers), Motorcycle (Bike) & Cycle. The results of vehicle count are converted into Passenger Car Units (PCU’s) as per the equivalent PCUs prescribed by Indian Road Congress (IRC) guidelines (Table 3.25). The equivalency factor for various types of vehicles is as given in the below table. Table 3.27 Recommended PCU factors for various types of vehicles on urban roads Equivalent PCU’s Type of Vehicle 5% 10% & above Two Wheelers, Motor Cycle or Scooter etc. 0.5 0.75 Passenger Car, Pick-up Van 1.0 1.0 Auto-Rickshaw 1.2 2.0 Light Commercial Vehicle 1.4 2.0 Truck or Bus 2.2 3.7 Agricultural Tractor Trailer 4.0 5.0 Cycle 0.4 0.5 Cycle Rickshaw 1.5 2.0 Tonga (Horse drawn vehicle) 1.5 2.0 Hand Cart 2.0 3.0 Source IRC: 106-1990

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3.10.6. Observation & Assessment The traffic flow pattern observed at traffic observation point - TS1 during morning & evening peak hours is as shown in the following figures Fig. (3.14 to 3.19). The results obtained thereby are summarized in Table 3.28

3.10.7 Observation at (TS1):Junction joining the National Highway No.66 and MIDC during morning peak hours.

Figure 3.14: Percentage of vehicle count - (TS1) Junction joining the National Highway No.66 and MIDC (8 AM to 9 AM) and (9 AM to 10 AM)

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Figure 3.15: Percentage of vehicle count - (TS1Junction joining the National Highway No.66 and MIDC(4

PM to 5 PM) and (5 PM to 6 PM)

Table 3.28 Summary of traffic in terms of PCUs observed at observation point (TS1) - during (08: 00 to 10: 00 AM) & (04: 00 to 06:00 PM)

Observation Time No. of PCUs Morning hours 08: 00 Am to 09: 00 AM 442 09: 00 AM to 10: 00 AM 486 Average 464

Evening hours 04: 00 PM to 05.00 PM 392 05: 00 PM to 06.00 PM 477 Average 435 Average PCUs during peak hours 450

3.10.8 Observation at (TS2):Junction joining the MIDC main road and feeder road to internal road ofMIDC.

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Figure 3.16: Percentage of vehicle count - (TS2) Junction joining the MIDC main road and feeder road to internal road ofMIDC. (8 AM to 9 AM) and (9 AM to 10 AM)

Figure 3.17: Percentage of vehicle count - (TS2) Junction joining the MIDC main road and feeder road to internal road ofMIDC.(4 PM to 5 PM) and (5 PM to 6 PM)

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Table 3.29 Summary of traffic in terms of PCUs observed at observation point (TS2) - during (08: 00 to 10: 00 AM) & (04: 00 to 06:00 PM)

Observation Time No. of PCUs Morning hours 08: 00 Am to 09: 00 AM 99 09: 00 AM to 10: 00 AM 104 Average 102

Evening hours 04: 00 PM to 05.00 PM 120 05: 00 PM to 06.00 PM 113 Average 117 Average PCUs during peak hours 120

Interpretation

The analysis reveals that TS 1 is subjected to heavy and continuous traffic which is acceptable as it is a junction which is connected to the National Highway. While the location TS2 being located at junction of feeder road and MIDC road is estimated to receive low traffic as compared to TS1.

3.10.10 Increased traffic scenario due to the expansion project The transportation of raw materials & finished goods for the existing unit in operation and the production enhancement activity will be mainly done by tankers/trucks.It is estimated that 30 trucks per day will make to and fro trip from the project site. As described in the above section the transportation activity will mainly take place by National Highway 66. As an initiative for efficient traffic management the project proponent will ensure that transportation activity will be done mainly during non peak hours to avoid the peak hour traffic, however to assess the increased traffic scenario due to the project the increased fleet of 30 trucks/tankers per day has been considered during the peak hours at all the two junctions.It is estimated that due to the proposed activity increased PCUs will be as given in Tables 3.31 and Table 3.32.

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A) Increased traffic scenario at (TS1)

The increased Traffic scenario is explained by segregating the peak hours temporally and is presented in Table 3.31 and 3.32.

Table 3.31 Summary of increased traffic in terms of PCUs at TS1 due to the expansion project Location Time Present Proposed Estimated Increase

Morning 464 465 1 TS 1 Evening 435 438 3

Table 3.32 Summary of increased traffic in terms of PCUs at TS2 due to the expansion project

Location Time Present Proposed Estimated Increase

Morning 102 112 10 TS 2 Evening 117 126 9

3.11 Land use Pattern

The Land Use & Land Cover (LULC) pattern in the 10 km radial study area were assessed based on remote sensing technique using satellite imagery & by conducting ground verification surveys.

3.11.1 Details of Satellite & Imagery Data Used For assessing the land use land cover aspects of the study area satellite imagery was procured from National Remote Sensing Center (NRSC), ISRO Hyderabad. The technical details of the satellite are as under. Table 3.35 Technical specifications/details of the satellite Name of Satellite IRS - Resourcesat-2 No. of sensors 3 (AWIFS, LISS - III & LISS - IV) Specifications of sensors AWIFS LISS - III LISS - IV

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No. of bands 4 4 1(Mono), 3 (MX) B2 0.52 - 0.59 B2 0.52 - 0.59 B2 0.52 - 0.59 B3 0.62 - 0.68 B3 0.62 - 0.68 B3 0.62 - 0.68 Spectral bands (µ) B4 0.77 - 0.86 B4 0.77 - 0.86 B4 0.77 - 0.86 B5 1.55 - 1.70 B5 1.55 - 1.70 Resolution (m) 56 23.5 5.8 Swath (km) 740 140 70/23 Revisit (days) 5 24 5

Of the above mentioned details, data of LSS - IV sensor dated was used. The processing & interpretation of satellite image was done in succession stages as described below. Satellite data processing The multispectral data was processed using ERDAS image processing software to classify various land use land cover classes by running supervised classification & thematic LULC map was developed on ARC GIS software, the thematic LULC map thus developed was used for ground verification for doubtful features.

Ground verification Ground verification surveys to confirm some the doubtful elements/features following which the earlier developed LULC map was corrected. Thus the generated LULC map of the study area is given below.

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3.11.1 Prevailing LULC in the study area

Fig No 3.20: Land Use Land Cover Map of the Study Area

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3.11.2 Observation & Assessment of LULC

To assess the land use classification of the study area two level approach viz. Level - I & Level - II classification was used based on the classification scheme developed by National Remote Sensing Center as under (Parthasarathy et al., 2012). Based on the image analysis land use/ land cover classes in the study area can be categorized as presented in Table 3.34. The area is distributed in as per Land use classification and is provided in Fig. 3.20 whereas the Land cover classification is depicted in Fig. 3.29.

Table 3.34 Categorization of land use & land cover pattern of the study area

Sr. Land Use Classes Area in No. Sq.km. Level - I Level - II Classification Classification 1 Built up Other than industrial area: Habitation/Settlement, 10.65 Developmental Setups (Roads, Commercial setups, Educational Institutes, Offices etc.) Industrial Area 4.58 2 Agricultural Land Crop land 79.20 Fallow land 4.87 Orchard/Plantation 2.18 3 Mining Stone quarries 0.24 4 Artificial Water Surface Water Tank Reservoir/Dam 0.13 Reservoir Land Cover Classes 1 Barren land Barren rocky surface areas & land without scrub 24.1 2 Scrub land Open areas with scrub vegetation 3.02 3 Vegetation Reserve Forest 11.93 Naturally growing vegetation in the study area in the 163.91 form of thickets, dense vegetation strands 4 River Kharak Nadi, BhaoVira Nadi, Kal Nadi, Savitri 9.34 River & respective tributaries

Total 314.15

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3.11.3 Percentage wise LULC assessment of the study area

The percentage wise land use & land cover pattern of the study areas is represented in the figures 3.27 & 3.28 respectively.

Fig No 3.21: Percentage wise Land Use classification of the study area

Fig No 3.22: Percentage wise Land Cover classification of the study area

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3.11.4 Interpretation

3.11.4.1 Land Use

The study area encompassing radial area of 314.15 sq. km. from the project site as center, broadly had 4 types of land use classes such as Built up (other than industrial & industrial area), Agriculture, Mining and Artificial Water Reservoir of these various land use classes Agriculture was the dominant land use class with 86. 25 sq. km. which accounted for 85% of the total land use pattern, followed by Built up (Other than industrial) with 10.65 sq. km. which accounted for 10% of the total land use pattern followed by industrial area with 4.58 sq. km. which accounted for 5% of the total land use pattern whereas Mining & Artificial Water Reservoir had a meager presence with 0.24 sq.km and 0.13 sq.km. respectively in the study area.

3.11.4.2 Land Cover

The study area prevailed 4 types of land cover classes such as Barren land, Scrub land, Vegetation & River of which Vegetation covering 175.84 sq.km of the study area was the dominant land cover class which accounted for 83% of the total land cover of the study area followed by Barren land with 24.1 sq.km, River with 9.34 sq.km and Scrub land with 3.02 sq.km which accounted for 11%, 4% and 2% of the total land cover classes of the study area respectively.

3.11.5 Drainage Pattern of the Study Area

The drainage pattern of the study area has been determined by using remote sensing technique. Satellite imagery has been processed by using ERDAS software to obtain drainage pattern map of the study area.

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3.11.5.1 Observation & assessment of drainage pattern in study area

The study area is largely an undulating terrain characterized by hills & hillocks of the Sahyadri ranges on the western edge. The surface drainage in the study area is largely represented by the westerly meandering KharakNadi, BhaoViraNadi, KalNadi, Savitri River & respective tributaries except for the presence of small artificial surface water body in foot hills of Pathar Village. The prevailing drainage pattern in the study area is of dendritic type as depicted in the following drainage pattern map:

Fig No 3.23: Map depicting Drainage Pattern of the study area

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3.12. Biotic environment

The biotic studies were conducted to assess the prevailing baseline ecological data in terms of terrestrial biodiversity status within the project plot & study area with a view to identify, quantify the impacts associated with the proposed project activity & to advocate suitable mitigation measures for the such anticipated impacts.

3.12.1 Study Area

The study area was 10 km radial distance from the project site considering inner 5 km radial distance as core area & outer 10 km radial distance as the buffer study area as depicted in the following figure:

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Figure 3.25: 10 km radial study area (Google Earth Imagery)

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Scope of the study To assess the implications of the proposed project on the surrounding ecology within study area following attributes were considered & executed:

 To identify & assess habitat loss if any due to the proposed project.  Negative impacts if any on the existing ecologically sensitive areas/potential habitats in the study area due to the proposed project.

3.12.2 Primary Baseline Data

General features of the prevailing terrestrial ecosystem in study area

The 10 km radial study area viz. Mahad MIDC & surrounding area comes under the jurisdiction of Mahad Municipal Council. The study area visited was a region characterized by the hills & hillocks of the Sahyadri ranges along the western edge. As observed during the reconnaissance survey major part the of the inner 5 km study area was an highly undulating terrain wherein the industrial area in the Kalij Village is situated on a strip of flat land along the eastern bank of Kal River, along with hosting the industrial cluster the inner 5 km study area was subjected to other developmental activities (settlements, commercial establishments etc.) by virtue of Birwadi & other villages. Also major part of inner & outer 5 km radial study area was subjected to agricultural activities. Now since the proposed project activity being located in notified industrial area & does not involve any sort of clearing/felling activities however so as to comply to Standard TOR, for delineation of prevailing flora & fauna, conservation related status has been done in the prevailing potential habitats around the industrial area in the core study area & buffer study area thus the prevailing potential habitats in the study area as detailed herewith.

Prevailing potential habitats in the study area

Core study area

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Prominent vegetation existed all along the Solamkond to Kijaloli Mohalla hill running north of the project site. Also vegetation clad hills existed in the along the Bhave, Kharvali and Borgaon villages towards East, SSE & South directions from the project site in the inner 5 km radial study area which are mainly Reserve Forest patches.

Buffer study area

The major part of the outer 5 km radial study area was also a hilly tract with moreover uniform cover of vegetation spread along the entire outer 5 km radial study area.

The observed vegetation along these hills & hillocks was of Southern Tropical Dry Deciduous forest type as found across the entire range in the Raigad District.

General features of the prevailing aquatic ecosystem in study area

The aquatic system in the study area is largely represented by westerly meandering Kal River which is joined by several other rivers during its course in the study area such as right tributary also known as Kal River joining at Amshet, left tributary viz. Bhaovira River joining at Birwadi, further right tributary viz. Savitri River joining at Bhorao thus the Kal River while escaping the study area is known as Savtri River which continues it further meander and drains into Arabian Sea at Harihareshwar approximately at an aerial distance of 43.0 km from the study area. Apart from the above mentioned rivers one artificial surface water reservoir is present near Warandh Village.

Note: Since any of the project related activities during commissioning & operation phase will not be associated with the prevailing surface water bodies in the study area in terms of withdrawal or disposal/discharge hence no impact is envisaged on the water bodies so the studies pertaining to aquatic ecology such as Plankton, Chlorophyll, Benthos, Fisheries etc. have been kept out the purview of this study.

3.12.3 Project site specific floral assessment

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The project site admeasuring 13,950.00 sq. m. was currently in use by virtue of existing manufacturing & formulations within an existing unit hence project site was deprived of any natural vegetation however the vegetation existed on project plot was by virtue of green belt developmental activity done in 679 sq. m. The list of plants present on project plot is given in Annexure 3.1.

3.12.4 Floral diversity & status in the study area

As discussed earlier, the study area had vast presence of vegetation clad hills & hillocks accordingly surveys were mainly conducted in & around such features in the core & buffer study area.

Floral diversity in the core study area

The field studies conducted in and around the prominent habitats within the core & buffer study area viz. vegetation clad hills & hillocks resulted in recording 90 plant species which comprised of various habit forms viz. 18 herbs, 11 climbers, 9 shrubs & 52 trees. The floral species recorded during the study are commonest for the region in consideration & have wide range of presence & abundance in the entire Raigad District.

3.12.5 Status evaluation

The project plot had presence of uneven presence of ground dwelling herbaceous & shrub scrub flora accounting to 10 no. of species of which 2 species were assessed as Least Concern ver 3.1 whereas remaining 8 species were yet to be assessed as per the International Union for Conservation of Nature and Natural Resources (IUCN).

To identify whether any plant species of conservation importance exists in the study area the status evaluation of the floral species has been established as per the IUCN assessment as a compliance to Standard TOR. Of the observed 90 plant species in the core & buffer study area 76 species are yet to be assessed, 9 species are assessed as Least Concern ver 3.1, 2 species as Lower Risk/least concern ver2.3, 1 species as Data Deficient ver 2.3 as per the IUCN assessment. However status of two remaining 2 plant species could not be assessed since both these species not being in IUCN database.

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3.12.6 Faunal diversity & status in the study area

a. Avifauna: The field visits in and round the prominent habitats within the core and buffer study area resulted in recording 29 bird species comprising of aquatic & terrestrial habitat dwelling belonging to 26 genera & 22 families. The recorded bird species are resident & commonest for the study region in consideration and have a wide range of presence & abundance across the Raigad District.

b. Reptiles: Solitary individuals of Brahminy skink, Forest calotes and Oriental garden lizard were observed amongst the bushes during the study. c. Mammals: Apart from the Indian Palm Squirrel some stray & domesticated animals such Dog, Pig, Buffalo none other animals were observed during the study.

However interactions with the locals also revealed presence of other wild fauna comprising of reptiles such as Rat snake, Indian spectacled cobra, Russels viper & Vine snake and mammals viz. Black naped hare, Indian boar & spotted deer along the vegetated hills in the outer buffer study area.

3.12.7 Secondary Data

There was tremendous paucity of published literature for the study area & surrounding region. The only source of secondary data was the information gathered from the interactions held with the locals. On the basis of description & information of provided by locals presence of wild fauna such as Wild boar, Indian Crested Porcupine, Spotted deer, Barking deer, Black Naped Hare, Indian Cobra, Russell’s viper, Saw-scaled viper & Indian rat snake could be concluded from the study area.

3.12.8 Status Evaluation

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Of the recorded 29 bird species the IUCN assessment of 28 species is as Least Concern ver 3.1, 2 and 1 species as Not Assessed whereas as per the WPA 17 species are listed as Schedule-IV & 1 species as Schedule - V and remaining 11 bird species are not listed in any Schedule.

Of the other observed fauna only Indian Palm Squirrel, Brahminy Skink and Forest Calotes are assessed as Least Concern ver 3.1 and none of the faunal species is listed as Schedule - I as per WPA & also does not belongs to any categories of concern as per IUCN.

Interpretation of primary and secondary data

The proposed project activity being a brown field activity any sort of habitat loss is involved also of the record 90 floral species, 36 faunal species from primary data and 9 faunal species from secondary data none belongs to the categories of concern as per IUCN assessment and nor is listed as Schedule -I (fauna) as per the WPA.

3.12.9 Applicability of forest & wild life related clearances

The proposed project is located in notified Additional Mahad MIDC industrial area and does not involve use of any forest land in whatsoever manner also none of the Protected Area exists within 5 km radial distance of the project site hence forestry & wild life related clearances are not applicable.

3.13 Socio economic status of the study area 3.13.1 Part A- Introduction Social Impact Assessment (SIA) is an integral part of project planning and policy evaluation and part of environmental impact assessment (EIA) due the importance that social considerations must be included in the decision process.

3.13.2 Purpose of the present study To carry out Social Impact Assessment (SIA) Study of proposed activity by M/s. Astec LifeSciences Ltd. located at Plot No. B-16, 17, 18, 21, MIDC Mahad ,Mahad, Dist. - Raigad, Maharashtra.

3.13.3 Aim of the study

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This study aims to assess the scenario of socio-economic aspects near to the project area due to proposed activity of project of Astec LifeSciences Ltd.

3.13.4 Objectives of the study 1. To determine the socio-economic and demographic profile of the study area. 2. To determine the people’s satisfaction towards accessibility of public resources within the study area. 3. To study the impact of activity of Astec LifeSciences Ltd. within the study area. 4. To investigate the people’s attitude towards project of Astec LifeSciences Ltd. within the study area. 5. To prepare the suggestions and positive plan for mitigation 3.13.5 Part B- Method The study will focus on how the socio-economic aspects will be changed due to activities of Astec LifeSciences Ltd representative sample constituted of 50 participants those working as (proponent’s managers, supervisors, technicians, drivers, labors, official from the local Panchayat Office) and people in the vicinity. A cross-sectional survey research design was adopted for the socio-economic impact assessment study.

By assuring confidentiality a verbal consent with the respondents were sorted for general interaction. During general interaction the main focus was to collect information based on the assessment tool developed for data collection.

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3.13.6 Part 3 Results and Discussion

The objective was achieved analyzing the data collected through the assessment tool mentioned in method section above. To avoid repetition and to maintain simplicity the findings of the actual survey are presented in tabular form.

Table No. 3.35: Descriptive Statistics indicating mean and standard deviation (N=50) Std. Variables Minimum Maximum Mean Deviation Age 21 65 37 12 Accessibility & 13 25 14 9 satisfaction Impact 19 36 23 6 Attitude towards M/s. Astec 17 33 25 3 LifeSciences Ltd.

Correlation analysis & interpretation: The data collected by the assessment tool had three variables namely; accessibility of public resources and its satisfaction, impact of expansion activity and attitude towards expansion project of Astec LifeSciences Ltd. The data of 50 participants was put for correlation analysis. The data was found to be normally distributed hence; the data fulfils the assumptions of parametric statistics. Based on this information Pearson product-moment correlation was conducted.

It is found that accessibility of public resources and its satisfaction is significantly correlated in positive direction with impact of Astec LifeSciences Ltd. activity (r = 67; p = .02). This indicates that accessibility of public resources will lead to low impact of industry activities and vice versa. Accessibility of public resources and its satisfaction is also found to be significantly correlated with attitude towards Astec LifeSciences Ltd. activity (r = -.46; p = .04) but in negative direction. This indicates that accessibility to public resources there is positive inclination for Astec LifeSciences Ltd. activity in the study area. Further, it is also found that impact of expansion project activity is

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Chapter 3 –Description of the Environment significantly correlated with attitude towards industrial activity (r = -.45; p = .01). This indicates that due to low impact there is positive attitude towards among the participants in the study area (Table 3.36). Table No. 3.36: Indicating Pearson’s correlation among variables (N=50)1 Attitude towards Accessibility & Impact proposed activity of satisfaction Astec LifeSciences Ltd. Accessibility & Satisfaction 1.2 - - Impact 0.69** 1 - Attitude towards proposed activity of Astec LifeSciences -.45* -.46 1.3 Ltd. * Correlation is significant at the 0.05 level. ** Correlation is significant at the 0.01 level.

Conclusion: The findings of the study indicate that the sample population which was surveyed is satisfied in terms of accessibility to the public resources and is of view that that the activity of Astec LifeSciences Ltd. will not hamper or impact in any way to them. Hence it can be summarized that the attitude of people towards expansion project of Astec LifeSciences Ltd. is found to be favorable.

3.13.7 Part 4 Mitigations and Environmental Management Plan (EMP) The third and the last objective are driven by the findings of the first and second objective. The objective is to prepare the suggestions and positive plan for mitigation measures for Astec LifeSciences Ltd. based on the findings it is indicated that there is no major considerable impact on the socio- economic aspects. The individual profiles of the participants in the study do indicate some variations. However, the overall impression is indicative of positive picture as far as socio economic impact is considered. Still it is expected that the industry owner/s should engage in social welfare, appropriate industrial activities and precautionary measures to avoid any kind of impact on the socio-cultural and economic milieu. Suggestions and positive plan for Astec LifeSciences Ltd.

1 Please refer the scoring system and interpretation section given in appendix.

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It is suggested that the industry should meticulously follow all the statutory guidelines as applicable.

The industry should work to minimize its impact on Air, Water, Noise and Soil environment as much as possible by implementing suitable pollution prevention technologies and other methods.

Over and above, any issues generated in the community due to any of the activities of the industry needs to be actively attended and intervened by the proponents. It is also expected that the regulatory agencies in these regards should keep vigilance and monitoring to keep a check on the industrial activity.  References: 1. Economic Survey of Maharashtra 2014-15, Directorate of Economics and Statistics, Planning Department 54th Issue, Government of Maharashtra

2. District Census Handbook Thane, 2011

3. District wise skill gap study for the State of Maharashtra, 2013 by National Skill Development Corporation.

Appendix- A

Tool for assessment of socio-economic impact of project by Astec Lifesciences Ltd.

Method for conducting the administration of the interview schedule:

The following tool can be administered in group or individual setting. If the informant is literate he can self-administer the tool. However, it is advisable that the items should be read and explained with all possible clarifications to the informant so that the response can be beyond the given scale (key). Hence, the information generated can also be treated as an interview.

Instructions to be followed or explained during conduction: You may be associated with the project as an owner, employee, worker or a person in close proximity of the project. Below are some statements and questions which intend to explore your opinion about theproject in your locality. A key is provided to you have to writing a number for your opinion according to the key below.

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Key 5= strongly satisfied 4= satisfied 3= moderately satisfied 2= dissatisfied 1= strongly dissatisfied

Section I. Accessibility of public resources & its satisfaction

Sr. No. Items Response 1 Are you satisfied with the educational facilities in your locality? 2 Are you satisfied with the health facilities in your locality? 3 Are you satisfied with the water facilities in your locality? 4 Are you satisfied with the transport facilities in your locality? Are you satisfied with the local government functioning & support in your 5 locality?

Section II. Impact of project of Astec Lifesciences Ltd.

Key 5= strongly agree 4= agree 3= moderately agree 2= disagree 1= strongly disagree

Sr. No. Items Response Do you think dust generated due to the proposed activity of Astec 1 LifeSciences Ltd. will affect your locality? Do you think noise due to the proposed activity of Astec LifeSciences Ltd. 2 will impact in any manner you could make out? Do you think due to the proposed activity of Astec LifeSciences Ltd. 3 transport/traffic scenario will be impacted in any way? Do you think due to the proposed activity of Astec LifeSciences Ltd. 4 physical health will be impacted? 5 Do you think due to proposed activity of Astec LifeSciences Ltd. mental

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health will be impacted? Do you think community environment due to the proposed activity of 6 Astec LifeSciences Ltd. will be negatively impacted? Do you think sources of livelihood due to the proposed activity of Astec 7 LifeSciences Ltd. will be impacted? Do you think the proposed activities of Astec LifeSciences Ltd. will 8 negatively impact development of your locality? Do you think the proposed activity of Astec LifeSciencesLtd. will impact 9 farming/agriculture of your locality? 10 Do you think the proposed activity of Astec LifeSciences Ltd. will impact trees/plants/forest of your locality? 11 Do you think the proposed activity of Astec LifeSciences Ltd. will impact air quality of your locality? 12 Do you think the proposed activity of AstecLifeSciences Ltd. will impact water consumption of your locality? 13 Do you think due to the proposed activity of Astec LifeSciences Ltd. the industrial operations like boiler, etc. will impact the locality?

Section III. Attitude towards the proposed activity of Astec LifeSciences Ltd.

Instructions: You may be associated with the project as an owner, employee, worker or a person in close proximity of the project. Below are some statements and questions which intend to explore your opinion about the project in your locality. A key is provided to you from strongly agree to strongly disagree with the statements and questions; you have to writing a number for your opinion according to the key below.

Key 1= strongly agree 2= agree 3= moderately agree 4= disagree 5= strongly disagree

Sr. No. Statements and questions (items) Response 1 Are you aware of Astec LifeSciences Ltd. in your locality? The proposed activity of Astec LifeSciences Ltd. is a necessary activity for 2 development? 3 Do you believe that in general the proposed project activity of Astec

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LifeSciences Ltd. will always have a negative impact on the environment? The proposed activity of Astec LifeSciences Ltd. will have a negative 4* impact on children? The proposed activity of AstecLifeSciences Ltd. will have a negative 5* impact on women? The proposed activity of Astec LifeSciences Ltd. will have a negative 6* impact on elderly population? Utilization of the natural resources should be balanced according to 7 development requirements or vice-versa? The operations of Astec LifeSciences Ltd. must be restricted to certain 8 period in the year? The operations of Astec LifeSciences Ltd. must be restricted to certain 9 time in the day? The proposed activity of Astec LifeSciences Ltd. will generate 10 employment to the local population? 11* The owners are coercive and problematic? Do you think that the Astec LifeSciences Ltd. owners must be following 12 rules and regulations? 13* Migrated laborers are a problem to the locality? Do you believe that in general there will be some socio-economic benefits 14 due to the proposed activity of Astec Lifesciences Ltd.

Scoring system and interpretation: Sum all the responses given by the informant to obtain a single raw score for each section i.e. one and two independently. For third section first reverse score the seven items indicated by an asterisk (*) then sum all scores. Higher the score on satisfaction for public resources indicate satisfaction, high score on impact of Astec LifeSciences Ltd. indicate low impact and high score on attitude towards Astec LifeSciences Ltd. indicate negative attitude respectively. Compute mean and standard deviation, if required compute other statistical procedures. Further, individual cases and group data may be interpreted on the basis of these computations.

Table for calculation:

Section Area Score of item Total Mean SD

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Accessibility of I public resources & 1+2+3+4+5 its satisfaction Impact due to the II activities of Astec 1+2+3+4+5+6+7+8+9+10+11+12+13 Lifesciences Ltd. Attitude towards the activities of III 1+2+3+4*+5*+6*+7+8+9+10+11*+12+13*+14 Astec LifeSciences Ltd. (*) = reverse score these items

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4.0 CHAPTER 4: ANTICIPATED ENVIRONMENTAL IMPACTS & MITIGATION MEASURES

Classifying the sources, estimating the quantity of pollutant, impact of pollution & mitigating them is the most important component in the Environmental Impact Assessment process. This chapter quantifies the environmental impacts of various project related activities on various receptors of environment.

The predictions estimated are superimposed on the baseline value for achieving the resultant value which signifies the overall impact. It also suggests the various mitigation measures which can be advocated to minimize the adverse impacts of the project activity.

4.1 Air Environment

4.1.1 Construction phase

4.1.1.1. Identification of Source

The proposed production capacity enhancement project is a brown field project activity to be executed within the premises of existing manufacturing unit located at Plot No B-16, 17, 18 and B-21, MIDC Mahad, District Raigad, Maharashtra, India.

Astec Life Sciences Ltd. has envisaged Pesticides and Chemical Intermediates production capacity enhancement from existing 219 MT/M to a of 781 MT/M along with formulation products to the tune of 700.0 MT/M and bi-products to the tune of 1773 MT/M within the existing manufacturing plant located at Plot No. -16, 17, 18 and B-21, MIDC Mahad, District Raigad, Maharashtra, with an estimated budgetary project cost of Rs. 10.17Crore. The proposed activity is a production capacity expansion of the existing unit located at Plot No. B-16, 17, 18 and 21, which will be achieved by installing reactors/machineries of high volume capacity there by increasing the batch size.

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4.1.2 Operation phase

4.1.2.1. Identification of Sources

Emissions from fuel burning For operational phase of the project stack attached to 6 TPH steam boiler (Stack No.1), stack attached to 850 kg/hr. steam boiler (Stack No.2), stack proposed to 15 TPH steam boiler (Stack No.3) & common stack proposed to 6 & 2 lack kilo. cal./hr. themic fluid heaters (Stack No. 4) are considered as point sources of emission. The primary fuel that would be used for boilers & thermic fluid heaters operations will be Indonesian Coal & Furnace Oil, the Sulphur content of Indonesian Coal & F.O is 0.56% & 4% respectively.

Gases and vapors from manufacturing process are identified as a second source of emission, which will be passed through process scrubbers to mitigate the process emissions. Scrubbed gases from scrubber will be released through a stack of 5.0m above roof level.

One of the major sources of fugitive emission generation can be due to handling, storage and transportation activity of raw materials. All raw materials & fuel will be stored in tanks, drums &bags. Sources of VOC emissions from the project would be from storage area due to handling & operating the solvent drums, loading unloading of solvents etc. Vehicle used for transporting raw materials & finished products also contributes to dust generation & emissions of gases like NOx due to fossil fuel burning.

4.1.2.2. Prediction of Impacts

For quantitative impact analysis on air quality due to expansion activity, air dispersion modeling is performed. Criteria pollutants like PM10, PM2.5, SO2, NOx & CO generated from operation of steam boiler & TFH were considered for air modeling.

AERMOD 8.2 developed by USEPA and authorized by CPCB is used for air modeling simulation which is based on steady state Gaussian plume equation.

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I. Model Options Used for Computation  Plume rise is estimated by Briggs formulae, but final rise is always limited to that of mixing layer;

 Stack tip down-wash is not considered;

 Point Source Modeling is considered;

 Calms processing routine is used by default;

 Wind profile exponents is used by default;

 Flat terrain is used for computations;

 It is assumed that pollutants do not undergo any physico-chemical transformation and that there is no pollutant removal by dry deposition;

 Washout by rain is not considered; and

 Cartesian co-ordinate system has been used for computations.

 Uniform polar receptor grid is used. Grid consists of 180 receptors each assumed to be at ground level.

II. Modeling Procedure Ground Level Concentrations (GLC’s) predictions due to proposed activity have been computed by AERMOD version 8.2 as per CPCB guidelines. While performing model, rural dispersion and regulatory defaults options were selected as per guidelines on air quality models (PROBES/70/1997- 1998).

III. Meteorological Data Processing Surface synoptic meteorological data of Raigad District for year 2012 - 2016 were obtained from Indian Meteorological Department, Mumbai. Meteorological observation station of IMD for Raigad District is located at Alibaug. Quality assurance process was undertaken as required by EPA (EPA-

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454/R-99-005) to identify and fill missing data for preparation of hourly surface meteorological data. Surface and profile met data were prepared for use in AERMOD using AERMET meteorological data preprocessor of Lakes Environmental. Processing the surface file indicated more than 90% data availability. Onsite meteorological data collected for three months were used to process AERMET file and not upper air meteorological data. Meteorological inputs required are hourly wind speed and direction, ambient temperature, pressure, precipitation, cloud cover, stability class and mixing height. The atmospheric inversion level at Raigad during pre monsoon period for 12 hours from 6:00 hour to 20:00 hour is represented in the below table No4.1. The data has been compiled from IMD manual.

Table No. 4.1: Atmospheric inversion level at Mahad, Raigad, Maharashtra. Sr. No Time Mixing Height, Meter 1 6.00 90-110 2 7.00 100-110 3 8.00 275-350 4 9.00 815-770 5 10.00 935-1220 6 11.00 1100-1300 7 12.00 1375-1500 8 13.00 1550-1880 9 14.00 1750-2050 10 15.00 1550-1850 11 16.00 1360-1700 12 17.00 1250-1500 13 18.00 1200-1475 14 19.00 1120-1350 15 20.00 975-1525 Source: (Hourly Mixing Height &Assimilative capacity of Atmosphere in India) by IMD

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IV. Model Input Data Emission factor used in air dispersion modeling for estimating pollutants from boilers is calculated using the document (EPA) AP-42 chapter no. 1 External Combustion Sources, Section 1.1 for Bituminous and Sub bituminous Coal combustion & Section 1.3 fuel oil combustion. Table 4.2 represents input data required for describing sources in model.

Table 4-1: Stack details for modeling

Sr. No. Parameters Values for Boiler- Stack 1 Values for Boiler-Stack2 1. Source 6 TPH Steam Boiler 850 kg/hr Boiler 2. Fuel Used Indonesian Coal FO 3. Base Elevation (m) 19 19 4. Stack Height (m) 30 m 24 m 5. Exist velocity of gas (m/s) 7.32 5.16 6. Exit Temp OC 158 143 7. Stack inside diameter (m) 1.16 0.4 8. Gas quantity m3/s 5.34 4.67

9. Emission Factors g/s PM10 - 0.53 g/s PM10 - 0.0103 g/s

SO2 - 0.4 g/s PM2.5 – 0.00755 g/s

NOx - 0.4 g/s SO2 - 0.2 g/s CO - 5.2 g/s NOx - 0.0967 g/s

Sr. Parameters Values for TFH- Stack 3 Values for TFH-Stack 4 No. 1. Source 15 TPH Steam Boiler 6 & 2 lakh kilocal/hr thermic fluid heater 2. Fuel Used Indonesian Coal FO 3. Base Elevation (m) 19 19 4. Stack Height (m) 39 m 27 m 5. Exist velocity of gas 7 5.43 (m/s) 6. Exit Temp OC 190 135 7. Stack inside diameter 1.485 0.4 (m) 8. Gas quantity m3/s 12.1239 4.98

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9. Emission Factors g/s PM10 – 1.331 g/s PM10 - 0.0191 g/s SO2 - 0.5 g/s PM2.5 – 0.0139 g/s NOx - 0.8 g/s SO2 - 0.5 g/s CO - 6.1 g/s NOx - 0.09 g/s 15 TPH Steam Boiler CO - 0.016 g/s

The total workers in the factory premises will be around 160 Nos. who may be affected due to the unscientific operation of boiler. Mostly the health effects associated with particulate matter are respiratory, pulmonary injury, lung cancer etc. Exposure to SO2 and NOx also lead to respiratory problems. Carbon monoxide decreases the oxygen carrying capacity of blood by reducing the hemoglobin. Since the company is handling some highly volatile solvents the VOC emission can have an adverse affect’s on worker’s health if present in higher concentration. The health effects related to VOC’s emission are eye, nose and throat irritation headaches, loss of coordination and nausea, damage to liver, kidney and central nervous system etc.

The incremental values at all monitoring stations are predicted and integrated with the baseline value for PM10, SO2, NOx & CO is tabulated in the below Table 4.3. The output image of the dispersion modeling describing the incremental predictive values for the selected pollutants is attached as Annexure 4.1.

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Table 4-2: Interpretation of the Incremental Values

Sr. Sampling Location PM10 (ug/m3) PM2.5 (ug/m3) SO2 (ug/m3) NOx (ug/m3) CO (ug/m3) No. Code & Name BV IV RV BV IV RV BV IV RV BV IV RV BV IV RV 1 *A1 Project Site 96.0 1.0 97.0 51.3 0.03 51.33 36.1 2.00 38.1 50.5 0.5 51 2.1 10.00 12.1 Near Dhamane 2 A2 87.2 0.00 87.2 30.6 0.00 30.6 29.6 0.00 29.6 34.6 0.00 34.6 1.2 0.00 1.2 Village 3 A3 Dahivad Village 84.6 0.00 84.6 29.0 0.00 29.0 27.4 0.00 27.4 34.0 0.00 34.0 1.2 0.00 1.2 4 A4 Bhavepathar 84.6 0.00 84.6 28.0 0.00 28.0 26.7 0.00 26.7 29.0 0.00 29.0 1.5 0.00 1.5 5 A5 Birwadi 86.9 0.06 86.96 39.9 0.001 39.901 30.9 0.06 30.96 49.1 0.05 49.15 1.9 1.00 1.9 Near Warandh 6 A6 76.1 0.00 76.1 29.0 0.00 29.0 26.6 0.00 26.6 29.5 0.00 29.5 1.6 0.00 1.6 Village Near Bhogaon 7 A7 84.2 0.2 84.4 30.1 0.005 30.105 29.8 0.2 30.0 34.3 0.08 34.38 1.2 3.00 4.2 Village Near Dharwali 8 A8 78.9 0.02 78.92 27.4 0.00 27.4 25.2 0.00 25.2 29.1 0.02 29.12 1.4 1.00 2.4 Village NAAQS Standards 100 (24hrouly) 60 (24hrouly) 80 (24hrouly) 80 (24hrouly) 4000 (1 hourly) BV: Baseline Value IV: Incremental Value RV: Resultant Value

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4.1.2.3. Interpretation of incremental values

The incremental value of the specific pollutant at the particular monitoring station is added to the baseline value of that specific pollutant measured during the monitoring period of the project. The resultant value thus calculated used for predicting the impacts of the expansion project on the air environment in the study area.

 Emissions from manufacturing process

The nature of the proposed project for manufacturing pesticides is of Synthetic Organic Chemicals. The manufacturing process involves chemical reactions like Bromination, Hydrolysis and Physical process like Quenching, Distillation, Crystallization, Solvent Recovery Washing, Separation and Drying. The manufacturing process related emissions will be routed to scrubber following which clean gas will be released though scrubber stack of 5 m above roof.

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 Impact of raw materials transport on surrounding environment:

In most cases, transport of raw materials, general supplies and final products causes an increase in traffic around the facility. It is anticipated that 10 trucks per day would be used for transportation of raw materials and final product. Transportation and environment are paradoxical in nature. The transportation activities convey substantial socio-economic benefits, but at the same time transportation is impacting environmental systems.

The impacts of the transportation can be minimized by following aspcets.

 Planning Transport development:

The transportation of the raw materials and final product will be done mostly by road. Road transportation would be the most feasible option available for the project proponent as it will be the least expensive in terms of investment, maintenance and security.

 Construction of transport infrastructures:

The project is located in notified MIDC Mahad industrial area hence the existing transport infrastructures such as MIDC roads & city roads around the project will be utilized.

 Maintenance and operation of transport infrastructures:

Maintenance & operation of the transport infrastructure would be carried out by the MIDC/ Local Administration. Facilities like street lighting, traffic management in the peak hours and maintenance of the road will be taken care by the MIDC/Local Administration.

 Use of transport infrastructures and vehicle maintenance:

The transportation of raw hazardous, flammable and toxic materials (Raw materials & Products) would be done according to the rule of Central Motor Vehicle Rule, (CMVR) 1989. Transportation of material carrying vehicles will mainly take place through National Highway 66.

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4.1.2.4. Mitigation Measures

The prominent pollutants like PM10, PM2.5, SO2, NOx& CO will be generated due to the fuel combustion from operation of units like Boiler, Thermic fluid heater. The mitigation measure that will be adopted is providing an appropriate stack height for dispersion of pollutants. The stack height calculation is shown below,

 Stack Height Calculation for Boiler

H=14(Q) 0.3 Where, H= Stack height Q= Emission rate for SO2 (Kg/hr)

 Stack Height Calculation – 6 TPHSteam boiler (Existing)

H=14(Q) 0.3

Where,

H= Stack height Q= Emission rate for SO2 (Kg/hr)

Now,

Coal (Indonesian Coal) consumption is 16.37 T/day for 6 TPH Boiler, now since the Boiler will be operated for 24 hours a day, fuel consumption per hour will be = 682.1 kg/hr. The Sulphur content of Coal is 0.56%

Hence

682.1 kg of Coal will contain 3.82kg of Sulphur Now stoichiometric conversion of Sulphur to SO2= 3.82 * 2 = 7.64

H = 14*(7.64)0.3 = 14 x 1.84

= 25.76 m

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Required stack height as per CPCB guideline is 25.76 m however stack of 30 m height is provided hence stack height is justified.

 Stack Height Calculation -850 kg/hr. Steam boiler (Existing)

FO consumption is 1229.46 kg/day for 850kg/hr Boiler, now since the Boiler will be operated for 21 hours a day, fuel consumption per hour will be = 58.5 kg/hr. The Sulphur content of FO is 4%

Hence

58.5 kg of FO will contain 2.34 kg of Sulphur Now stoichiometric conversion of Sulphur to SO2= 2.34 * 2 = 4.68

H = 14*(4.68)0.3 = 14 x 1.59

= 22.26 m

Required stack height as per CPCB guideline is 22.26 m however stack of 24 m height is provided hence stack height is justified.

 Stack Height Calculation – 15 TPH Steam boiler (Proposed)

Coal (Indonesian Coal) consumption is 40.9 T/day for 15 TPH Boiler, now since the Boiler will be operated for 24 hours a day, fuel consumption per hour will be = 1705.26 kg/hr. The Sulphur content of Coal is 0.56%

Hence

1705.26 kg of Coal will contain 9.54 kg of Sulphur Now stoichiometric conversion of Sulphur to SO2= 9.54 * 2 = 19.08

H = 14*(19.08)0.3 = 14 x 2.42

= 33.88 m

Required stack height as per CPCB guideline is 33.88m however stack of 39 m height will be provided hence stack height is justified.

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 Stack Height Calculation – 2 lakh kilo cal./hr. & 6 lakh kilo cal./hr.Thermic fluid heaters (Proposed)

FO consumption is 2339 kg/day for 6 lakh kilo cal./hr.& 2lakh kilo cal./hr. thermic fluid heaters, now since the TFHs will be operated for 22 hrs& 23 hrs respectively a day, fuel consumption per hour will be = 76.5 kg/hr& 25.5 kg/hr. The Sulphur content of FO is 4%

Hence

102 kg of FO will contain 4.08kg of Sulphur Now stoichiometric conversion of Sulphur to SO2= 4.08 * 2 = 8.16

H = 14*(8.16)0.3 = 14 x 1.87

=26.18 m

Required stack height as per CPCB guideline is 26.18m however stack of 27m height will be provided hence stack height is justified.

Air Pollution Control Devices (APCD’s)

Bag filter is provided existing boiler of 6 TPH & Cyclone dust collector & Bag filter will be provided to proposed boiler of 15 TPH.

The manufacturing process related emissions will be routed to scrubber following which clean gas will be released though scrubber stack of 5 m above roof. Certain measures such as carbon adsorption systems, design changes, operation and maintenance controls as leak prevention etc. can be adopted to reduce the VOC emission in the plant premises and control measures for dust emission control. The following measures should be adopted for controlling the dust generation and emission,

 The roads within the premises should be sprinkled with water at a regular interval to avoid the dust generation.

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 It should be ensured that for transportation activity only vehicles having with valid PUC certificate are used.  Timely proper servicing & maintenance of vehicles is being carried out.  Adequate green belt viz. 33% of the total project plot area should be developed. Green belt may act as surface for settling of dust particles and thus will help to reduce the concentration of particulate matter in the ambient air.  Regular ambient air quality monitoring should be carried out to check the efficiency of installed pollution control devices and adopted pollution control measures. From the above, it can be concluded during the operational phase of the project and implementation of mitigation measures in an appropriate manner, the Ambient Air Quality will not exceed NAAQ Standards.

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4.1.3 Impact Matrix

Environmental Aspects Receptors Anticipated Mitigation measures Scoring the anticipated impact components Impacts No Yes 1 2 3 4 Insignifi Signifi Severely cant cant Significa nt Ambient Air1,2 1. 1. Soils in If at all these 1. Appropriate stack height --  -- --

Emissions the study gaseous emissions in will be provided as per CPCB such as area any form gets guidelines which will help in

(PM10, deposited on the dispersion of pollutants at

PM2.5, prevailing soils in proper height which will

SO2, NOx prominent wind hence the impact will be & CO) direction within the substantially reduced. from study area, then such

boiler and soils may get thermic contaminated 2. One process scrubber fluid thereby affecting the having stack of 5 m height heater soil quality & may (above roof level for

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operations also have adverse processemissions is installed effect on the biotic to effectively scrub the 2. Process environment such emissions from the emissions subject areas. manufacturing process. 3. Fugitive 2. Water The prevailing --  -- -- emissions bodies in surface water bodies (VOCs) 3. It will be ensured that the study in the study area if transportation activity takes area comes in contact place only by vehicles having with such air valid PUC certification and emissions , the internal roads within the water bodies may project plot will be paved to get polluted & may avoid dust generation. have adverse effect on the biotic environment associated with such water bodies.

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3. If gaseous emissions --  -- -- Agricultural get deposited on the

fields in the prevailing study area agricultural fields in prominent wind direction within the study area, then productivity of such soils may be adversely affected.

4. Biotic In any case if the --  -- -- environmen identified prevailing

t potential habitats within the study area get exposed to such air emissions then the prevailing potential habitats

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may be adversely affected thereby affecting the overall ecology of the study area in consideration.

5. Human Minor impact on --  -- -- habitation human health like

within the short term headache, study area dizziness, breathing issues etc.

6. Deposition of --  -- -- Monuments Particulate matter on

and the surface, acid archeologic leaching of rocks & al sites structure due to SO2, NOx& acid

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mist and minor impact on people visiting the site.

1. Ambient air quality monitoring carried by Sadekar Enviro Engineers Pvt. Ltd. at Project Site and in Dhamane, Dahivad, Bhavepathar, Birwadi, Bhogaon, &Dharwali villages & Work place monitoring at project site carried by Sadekar Enviro Engineers Pvt. Ltd.

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Probability of impact occurrence Scenarios Chance of Occurrence Scoring 1. Air emissions coming in contact with the soils in the study area >90 % Chance of Occurrence 4 2. Air emissions coming in contact with the prevailing surface water bodies in the study area 50-90 % chance of Occurrence 3 3. Air emissions coming in contact with the agricultural fields in the study area 20 - 50 % chance of Occurrence 2 4. Prevailing habitats within the study area coming in contact with air emissions <10 % chance of Occurrence 1 5. Human habitations within the study area coming in contact with the air emissions 6. Air emissions coming in contact with the monuments & archeological sites within the study area

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Impact severity score Scenario Scoring for chance of Scoring for Overall score for occurrence impact severity of impact Air emissions coming in contact with soils 2 2 4 Air emissions coming in contact with prevailing surface water 3 2 6 bodies Air emissions coming in contact with agricultural fields 2 2 4 Prevailing habitats within study area coming in contact with air 3 2 6 emissions Human habitations within the study area coming in contact with the 2 2 4 air emissions Air emissions coming in contact with the monuments & 1 2 2 archeological sites Note: The scoring for chance of occurrence & the scoring for impact has been given taking into the terrain conditions of the study area, project activities specific mitigation measures & subject understanding by the functional area expert.

Score Type of Risk 1-4 Negligible 5-8 Less Severe 9-12 Highly Severe 13-16 Extremely Severe

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Interpretation:

Taking into consideration the terrain conditions of the study area, prominent wind direction and the project activities specific mitigation measures, the maximum score for overall severity of the anticipated impacts is 6 and the risk type assessed is as less severe.

4.2 Water Environment

4.2.1 Anticipated impacts (Construction phase)

No construction activity is required as the production enhancement will be carried out using high volume capacity reactors replacing existing reactors of less capacity.

4.2.2 Anticipated impacts (Operational phase)

4.2.2.1 Probable Source

The proposed expansion activity for manufacturing of Pesticides and Chemical Intermediates involves generation of effluent from manufacturing process. The other sources of effluent generation are domestic activities and utilities effluent. The water requirement of the project will be fulfilled from Mahad MIDC itself.

Total effluent generation after expansion activity will be 455 CMD of which 51.0 CMD low TDS effluent comprising of domestic sewage & process effluent will be treated in existing ETP 55 CMD capacity comprising of primary, secondary & tertiary treatment scheme from which 4.57 CMD will be recycled back to plant & 46.43 treated effluent will be sent to CETP for further treatment & disposal as per valid C.T.O. 241 CMD HCOD-HTDS effluent will be subjected to in plant stripper evaporator from which 184 CMD condensate will be recycled back to plant & 54 T/D salts will be sold as bi-product. 120.73 cooling tower & boiler blow down will be recycled back to cooling tower. The CETP membership is attached as Annexure 4.2.

Water balance after expansion activity is given in Table 4-4.

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Table 4-4: Total Water Budget (After expansion) Components Consumption Losses Effluent Remark Treatment Recycle

Domestic 20 5 15 Nil Explained below

Process 216 (Process + -- 241 61 CMD A. 241 CMD from process will be 184 CMD Formulation) Aqueous + generated in subjected to in plant stripper condensate 36 (Access Process evaporator of 250 CMD from Water ) capacity from which 3 CMD evaporator will be recovered solvents for reuse in plant, 184 CMD condensate will be recycled for process & 54 T/D salts will be sold as Bi-product.

B. 15 CMD (Domestic) + 36 CMD(From Process) = 51 CMD treated in ETP of 55 CMD capacity, 46.43 CMD 4.57 CMD treated effluent will be sent to from ETP CETP as per valid CTO & remaining 4.57 CMD will be recycled to Cooling Tower

Cooling 261 207 54 Nil A. Cooling Tower blow down of 68.73 Tower (Evaporation) 54 CMD + 12 CMD Boiler blow down + 97 CMD = 163

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Boiler 255 24 12 Blow 122 CMD CMD of which 68.73 will be (Flash Steam down + 97 Condensate recycled to Cooling Tower Losses) recovery

B. Further Cooling Tower blow 52 CMD down of 54 CMD will be Evaporator subjected to in plant evaporator Condensate from which 52 CMD condensate will be recycled to Cooling Tower & 2 T/day salt will be disposed to CHWTSDF

Garden 4.3 4.3 Nil Nil -- -- Total 756.3 240.3 455 183 309.3

Water requirement for initial cycle = 756.3 CMD Total recycled water = 309.3 CMD Fresh water requirement = 756.3 – 309.3 = 447 CMD

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4.2.2.2 Effluent streams and treatment

The total effluent generation during the operational phase after expansion activity will be 455 CMD.

4.2.2.3 Treatment scheme

5.0 1. Total effluent generation after expansion activity will be 455 CMD. 6.0 7.0 2. LCOD-LTDS effluent from process (36 CMD) & Domestic sewage (15) a total of 51 CMD effluent will be treated in ETP of 55 CMD capacity from which 46.43 CMD will be sent to CETP for further treatment & 4.57 CMD treated effluent will be recycled. 8.0 3. HCOD-HTDS effluent form manufacturing process (241 CMD) will be subjected to in plant stripper evaporator of 250 CMD capacity from which 184 CMD condensate will be recycled & 54 T/D salts generated will be sold as bi-products.

4. 120.73 CMD cooling tower & boiler blow down will be recycled to plant.

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4.2.2.2 Impact predicted

The wastewater generated from the project activity if discharged to the Common Effluent Treatment Plant (CETP) without prior in-situ treatment, it can cause the breakdown of the common effluent treatment plant as it will contain high TDS concentrations. Also if the untreated waste water is by passed to the MIDC drains it will results in the contamination or polluting the water body at final discharge point. The prolonged unscientific discharge of the untreated waste water may lead to the contamination of the nearby surface water bodies, soils in the near vicinity and ultimately resulting in polluting the underground water reserves through percolation from soil. The release of untreated effluent will ultimately affect the overall ecology & agricultural productivity in the surrounding area.

Table 4-3: Treated effluent characteristics MPCB Sr. No. Details Units Result Standard 1. pH -- 7.35 6.5 to 8.5 2. Total Dissolved solids mg/lit. 774.0 2100.0 3. Total Suspended Solids mg/lit 58.0 100.0 4. Chemical Oxygen Demand mg/lit. 152.0 250.0 5. Biochemical Oxygen Demand, 3 day, 27 mg/lit. 65.0 100.0 °C

4.2.2.3 Proposed Mitigation

The effluent loads generated are segregated into two broad streams,

1.0 1. Total effluent generation after expansion activity will be 455 CMD. 2.0 3.0 2. LCOD-LTDS effluent from process (36 CMD) & Domestic sewage (15) a total of 51 CMD effluent will be treated in ETP of 55 CMD capacity from which 46.43 CMD will be sent to CETP for further treatment & 4.57 CMD treated effluent will be recycled.

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4.0 3. HCOD-HTDS effluent form manufacturing process (241 CMD) will be subjected to in plant stripper evaporator of 250 CMD capacity from which 184 CMD condensate will be recycled & 54 T/D salts generated will be sold as bi-products.

4. 120.73 CMD cooling tower & boiler blow down will be recycled to plant.

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4.2.2.3.1 Flow Chart Effluent treatment plant for LCOD-LTDS & HCOD-HTDS streams of effluent.

Effluent Condensate for reuse

Effluent from manufacturing process Cooling tower & Boiler blow In plant downs Evaporator Oil Trap

Evaporator Salts will be sold Collection cum neutralization as bi-products

Condensate Recycled back for Flash Mixer Cooling Tower Operations

Primary Clarifier

Bio reactor 1

Secondary Clarifier

Bio reactor 2

Tertiary Clarifier

Sand filter & Carbon filter Disposal to CETP

Sludge drying bed

Filter press

To CHWTSDF Figure No. 4.2: Flow chart of the effluent treatment plant

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4.2.3 Water quality modeling

Astec Life Sciences Ltd. as per the valid Consent to Operate have permission to discharge the treated effluent to Mahad Common Effluent Treatment Plant (CETP) from existing activities. The effluent which will be generated from the proposed expansion activity will be treated within in situ full-fledged effluent treatment plant comprising of primary, secondary and tertiary treatment and the treated effluent will be completely reused thereby making the proposed project as a ZLD project. As it is evident that the wastewater generated from the proposed expansion activity will not be discharged into any river/water channel/surface water body, the water quality modeling is not mandatory for this project as per the Standard TOR prescribed by MoEF&CC.

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4.2.4 Impact Matrix

Environmental Anticipated Aspects Receptors Mitigation measures Scoring the anticipated impact components Impacts No Yes 1 2 3 4 Insignifi Signifi Severely cant cant Significant

# Surface & * Unforesee 1. Soils in If at all theses The effluents to be generated from --  -- -- Ground water and n/deliberat the study treated the overall project related soils in the study e release area effluents in activities for efficient treatment area of treated whatsoever effluent manner comes will be categorized into following from in contact with streams: industrial the prevailing 1. LCOD-LTDS effluent operations soils in the such as: study area, comprising of domestic sewage & then such soils process effluent to the tune of 51.3 1. Process may get CMD will be treated in existing effluent polluted which may further ETP 55 CMD capacity comprising 2. Boiler lead to of primary, secondary & tertiary & cooling contamination

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tower of ground treatment scheme, permitted blow down water through quantity of treated effluent will be percolation sent to CETP for further treatment 3. thereby having Scrubber potentiality to & disposal and remaining effluent blow down indirectly will be recycled. affect the 5.0 4. agricultural Domestic activity & 2. HCOD-HTDS effluent from effluent biotic manufacturing process will be environment subjected in plant stripper 2. Water If the treated --  -- -- bodies in effluent in evaporator & condensate will be the study whatsoever reused. area manner comes in contact with the prevailing 3. Cooling tower & boiler blow surface & down will be reused for cooling ground water tower operations. bodies in the

study area then such water 4. Thus except for the consented bodies may get

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contaminated treated effluent discharge quantity & thereby may the additional treated effluent affect the generated from the project activity biotic environment. will be reused. 3. If these treated - Astec Life Sciences Ltd. during --  -- -- Agricultur effluents in any its existing operations does not al fields way come in discharge any kind of treated or in the contact with untreated effluent in whatsoever study area the agricultural manner in the surrounding area fields in the and same practice will be followed study area, even after achieving the proposed then expansion activity hence productivity of contamination of soils & such agricultural fields & humans agricultural coming in contact with the same fields may be area not envisaged. adversely affected. 4. Biotic In any case if --  -- -- environm the identified ent prevailing potential

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habitats within the study area get exposed to such effluent releases then such habitats may be adversely affected thereby resulting in adversely affecting overall ecology of the study area in consideration. 5. Human Adverse health --  -- -- habitation impacts due to within the contact with study area polluted water bodies. # Surface water monitoring at Kal River Uptstream ,Kal River At Additional MIDC, Kal River Downstream of Birwadi, Savirti River tributary Downstream of Mahad CETP, Savirti River Near Mahad City, Stream at Bhorao Village, Stream at WalanBudruk, Waland Dam & Ground water

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Chapter 4: Anticipated Environmental Impacts & Mitigation Measures monitoring at Mahad ,KambetarfBirwadi , Dhamane-gaon ,Warandh , Padavi , Kiye , Wadghar , Birwadi carried out by Sadekar Enviro Engineers Pvt. Ltd.

Probability of impact occurrence

Scenarios Chance of Occurrence Scoring  Treated effluents comes in contact with the soils >90 % Chance of Occurrence 4 in the study area  Treated effluents comes in contact with the 50-90 % chance of Occurrence 3 water prevailing surface water bodies & ground water in the study area 20 - 50 % chance of Occurrence 2  Treated effluents comes in contact with the agricultural fields in the study area <10 % chance of Occurrence 1  Prevailing habitats within the study area coming in contact with treated effluents  Human habitations within the study area coming in contact treated effluent

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Impact severity score

Overall score for Scoring for chance of Scoring for Scenario severity of occurrence impact impact Treated effluents comes in contact with the soils in the study area 2 2 4 Treated effluents comes in contact with the water prevailing surface 3 2 6 water bodies & ground water in the study area Treated effluents comes in contact with the agricultural fields in the 2 2 4 study area Prevailing habitats within the study area coming in contact with 3 2 6 treated effluents Human habitations within the study area coming in contact treated 2 2 4 effluent Note: The scoring for chance of occurrence & the scoring for impact has been given taking into the terrain conditions of the study area, project activities specific mitigation measures & subject understanding by the functional area expert.

Score Type of Risk 1-4 Negligible 5-8 Less Severe 9-12 Highly Severe 13-16 Extremely Severe

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Assessment of probable impacts of waste water generated due to project specific activities:

Taking into consideration the terrain conditions of the study area and the project activities specific mitigation measures, the maximum score for overall severity of the anticipated impacts is 6 and the risk type assessed is as less severe.

5.1 Noise Environment

1.3.1 Construction phase

1.3.1.1 Probable Sources

No construction activity is required as the production enhancement will be carried out using high volume capacity reactors replacing existing reactors of less capacity.

1.3.2 Operation phase

1.3.2.1 Model options used/assumed for computation

 Flat terrain is assumed

 Point Source emission is computed

 Atmospheric sound attenuation is considered

 Barrier are not used for computation for worst case scenario

 Solid angle of the propagation is contemplated as 2 pi

 Temporal average is not considered

 Simulation calculation is done at surface height

 The isolines are used as output inter phase

 Classic custic model (Linear sound propagation equation) is used for simulation

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1.3.2.2 Modeling Procedure

The propagation of the noise generated due to proposed expansion has been made by CUSTIC version 3.2. The step wise method subjected in the user manual is followed for performing the model.

1.3.2.3 Probable Sources

Any industrial plant in general consists of various sources of noise in clusters or single. These clusters/single sources may be housed in buildings of different dimensions made of different materials or installed in open or under sheds. Generally the plant noise sources include Air Compressors, Feed Pumps, Condensate Pumps, Recycle Pumps, Boiler ID Fans, air blowers, cooling towers etc.

Table 4-4: Noise level generated during Operational Phase

Sr. No. Monitoring Location Noise in dB(A) Leq

1 Near Main Gate 70.0 2 ETP Area 64.0 3 Manufacturing Area 68 4. Boiler Area 71 (Source: Noise monitoring carried out by SEEPL Laboratory)

1.3.2.4 Impact Prediction

In order to predict noise levels due to the plant operations, which will be contributing to the ambient noise levels, a sound propagative modeling has been carried out. For predicting the noise levels at various distances with respect to the plant site, noise levels are predicted using a user friendly model CUSTIC 3.2 the details of which are elaborated above.

The noise modeling is performed considering the values obtained from the sound level meter during the monitoring phase of the project. The modeling parameters & procedure are explained

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in the above section. Same methodology is adopted for simulating the model considering 4 nos. of point source.

Effects/Impacts of High Noise Level on Workers during the operational phase

 Temporary/Permanent hearing loss

 Mental disturbance

 Increase in heart rate

 Decreasing in workers performance due to psychiatric disorder

 Workers developing Tinnitus due to high level of noise exposure on regular basis.

1.3.2.5 Interpretation

The distance wise drop down in anticipated noise level during operational phase are computed in below table.

Sr. No. Distance (m) from dB(A) project plot 1 573.975 22.75 2 601.59 18.96 3 637.09 15.17 4 739.655 11.38 5 842.225 7.58 6 940.845 3.79

The noise contour plotted by the CUSTIC 3.2 is graphically represented in Annexure: 4.4.

Vibration: Since the proposed project is an expansion project to be executed within the premises of existing manufacturing plant no major construction activity is envisaged hence the only source of vibrations will be due to machinery operations (new reactors, condensers, fans, blowers, compressors etc.) during the operational phase.

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The vibrations are envisaged due to the above mentioned activities, in long course of time may result in damage to infrastructure & also affect the health of the workers. To overcome such impacts, the grouting of these instruments/machineries shall be made free from vibration by providing shock absorbing pads and firmly mounted on the surface. Routine maintenance should be practiced.

1.3.2.6 Proposed Mitigation

To reduce the Noise level in the company premises following mitigation is/will be provided.

 Thick green belt developed along the factory boundary will help to minimize the noise intensity propagating out of the factory premises. To curb the noise levels the company is recommended to develop the green belt area around the boundary of the company.

 Isolation of the high noise generating equipments.

 Workers should work in shifts to avoid the long durations of exposure to high noise level.

 Implementation of noise absorbing sheets on the walls of building/facilities hosting high noise generating equipments/machinery.

 Acoustic enclosures to be provided Compressors & high noise generating equipments.

 Anti vibration pads to be installed for high vibration generating machines. Enclosure wherever necessary.

 Regular/routine maintenance of various equipments should be carried out.

 Regular Oiling and greasing for equipments should be done.

 The proposed equipments would be provided with proper enclosure, anti vibration pads, acoustic enclosure wherever required.

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1.3.3 Impact Matrix:

Environmental Anticipated Aspects Receptors Mitigation measures Scoring the anticipated impact components Impacts No Yes 1 2 3 4

Insignifi Signi Severely

cant ficant Significant Noise and Noise and 1. Human Minor impact on human 1. It will be ensured that noise --  -- -- vibrations vibrations habitations health like temporary generating form the @ hearing loss, temporary machines/equipments will be industrial headache, temporary placed within enclosed area & operations psychological even noise generating such as: disturbance etc. operations area will also be 1. carried out in enclosed areas Manufacturi Minor impact on quality only. ng process of life e.g. disturbance issues in the immediate 2. Noise damping pads, shock 2. Operation surroundings of the absorbing pads will be of utilities travelling route. provided to all noise & such as vibrations generating boiler/thermi 2. Biotic As per the model equipments/machineries.  ------c fluid environmen computations it is heater, t anticipated that noise 3. Adequate PPE’s will be

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effluent during the operational provided to workers working treatment phase of the project will within the factory premises. plant not propagate up to important/potential 3. habitats within the Transportati study area hence no on activity impact is envisaged on the surrounding biotic environment due to noise and vibrations

Noise levels monitored by SEEPL at different locations such as Project Site and in villages Near Dhamane Village, Dahivad, Bhavepathar, Birwadi, Warandh, Bhogaon, Dharwali.

Probability of impact occurrence

Scenarios Chance of Occurrence Scoring Human habitations coming in contact with the noise and vibrations >90 % Chance of Occurrence 4 generated from the project activities The noise & vibrations 50-90 % chance of Occurrence 3 generated from the project activities reaching up to prevailing 20 - 50 % chance of Occurrence 2 important/potential habitats within the study area <10 % chance of Occurrence 1

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Impact severity score Scoring for chance Scoring for Overall score for Scenario of occurrence impact severity of impact Human habitations coming in contact with noise and vibrations generated 4 2 8 from project activities Noise & vibrations generated from project activities reaching up to 1 1 1 prevailing important/potential habitats within study area Note: The scoring for chance of occurrence & the scoring for impact has been given taking into the terrain conditions of the study area, project activities specific mitigation measures & subject understanding by the functional area expert.

Score Type of Risk Score Type of Risk 1-4 Negligible 9-12 Highly Severe 5-8 Less Severe 13-16 Extremely Severe

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Assessment of probable impacts of noise & vibrations generated due to project specific activities:

Taking into consideration the terrain conditions of the study area such as location of human habitations & prevailing important/potential habitats and the project activities specific mitigation measures, the maximum score for overall severity of the anticipated impact is 8 and the risk type assessed is as less severe.

4.4 Details of hazardous and non-hazardous waste generation and their storage, utilization and management

4.4.1 Construction phase

No construction activity is required as the production enhancement will be carried out using high volume capacity reactors replacing existing reactors of less capacity.

4.4.2 Operation phase

Any industry during operational phase will have multiple sources of waste generation such as:

 Offices & Canteens  Unpacking of raw materials  Manufacturing processes  From operation of utilities  Treatment process  Packaging of finished products  Maintenance activities The wastes generated from the above mentioned sources on the basis of nature & chemical properties can be broadly categorized as Solid non hazardous waste & Solid hazardous waste.

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Scenario of waste generation during operational phase due to project specific activities The non hazardous & hazardous wastes which will be generated due the project specific activities/operations will be as described here under:

Non hazardous waste:  Non hazardous waste such as Paper waste (paper boxes and bags), Plastic waste, Metal scrap, Wooden pellets & Coal ash will be generated.

Hazardous waste:  The manufacturing process involves chemical reactions like Bromination, Hydrolysis and Physical process like Quenching, Distillation, Crystallization, Solvent Recovery, washing, separation and drying.

 During manufacturing & allied activities hazardous waste such as Used/ spent oil, Residues & Waste, Chemical sludge residue from herbicides, Chemical sludge from ETP, Discarded containers, Filter & filter material having organic liquid, Spent carbon, Asbestos gaskets & Spent Solvents.

Precautionary management/mitigation measures to be employed for handling of hazardous & non hazardous wastes during operational phase Industry will provide/adopt following precautionary measures for handling of hazardous & non hazardous wastes during operational phase:

 The inert recyclable wastes such as Paper waste (paper boxes and bags), Plastic waste, Metal scrap, Wooden pellets will be sold to recyclers & Coal ash will be sold to registered brick manufacturer.

 The hazardous wastes such as Residues & Waste, Chemical sludge residue from herbicides, Chemical sludge from ETP, Filter & filter material having organic liquid, Spent carbon & Asbestos gaskets will be sent to Mumbai Waste Management Ltd. – CHWTSDF, Taloja

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whereas hazardous wastes such as Used/ spent oil, Discarded containers & Spent Solvents will be collected & stored in dedicated hazardous waste storage area and either will be sold to sold to MPCB authorized recyclers or will be sent to Mumbai Waste Management - CHWTSDF at Taloja for further processing.

 Project proponent has been made aware with the Hazardous & Other Wastes (Management, Handling and Trans-boundary Movement) Rules, 2016 and has been advised to abide by the same.

 Project proponent will scrupulously ensure that the waste hazardous waste transported from the industry is reaching only at the designated place viz. Mumbai Waste Management - CHWTSDF at Taloja.

The membership of Mumbai Waste Management - CHWTSDF, Taloja is attached as Annexure - 4.5.

Assessment of probable impacts due to waste generation during operational phase Taking into consideration the above mentioned precautionary management/mitigation measures to be provided/adopted by the project proponent it can be asserted that non hazardous & hazardous wastes generated during the operational phase in whatsoever manner will not be directly subjected to soils & water bodies in the study area hence no impact is envisaged on environment due to operational phase related wastes generation and management activities.

The list of hazardous waste along with name, quantities, category of waste as per Hazardous & Other Wastes (Management, Handling and Trans-boundary Movement) Rules, 2016 & respective mode of management is given in the following table.

The manufacturing of Pesticides andChemical Intermediateswill generate various hazardous wastes, the manufacturing process consists of various unit operations as listed under.

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Table 4-5: Waste generation and disposal method

Hazardous *Category UOM Existing Proposed Total Management Waste of waste Used/ spent 5.1 Sale to oil Authorized l/Month 50.0 950.0 1000.00 recycler / Disposal to CHWTSDF Residues & 29.1 Disposal to MT/Month 204.0 207.0 411.0 Waste CHWTSDF Chemical 29.2 MT/D 2.7 -- 2.7 sludge residue Disposal to from CHWTSDF herbicides Discarded 33.1 Nos./Month Sale to containers Authorized 78.0 1172.00 1250.0 recycler / Disposal To CHWTSDF Chemical 35.3 MT/Month Disposal To sludge from 1.12 67.88 69.0 CHWTSDF ETP Filter & filter 36.2 kg/Month Disposal To material CHWTSDF 32.0 468.0 500.0 having organic liquid Spent carbon 36.2 kg/Month Disposal To 10.0 190.0 200 CHWTSDF Asbestos 15.2 Disposal To kg/Month -- 100.0 100.0 gaskets CHWTSDF Spent 29.4 MT/Month Sale to Solvents Authorized 28.0 112.0 140.0 recycler / Disposal To CHWTSDF Non- hazardous UOM Existing Proposed Total Disposal waste Paper waste kg/Month 150.00 5450.00 5600.00 Sale to recycler (paper boxes

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and bags)

Plastic waste kg/Month 50.00 5450.00 5600.00 Metal scrap kg/Month 100.00 4900.00 5000.00 Wooden Nos./Month 25.00 975.00 1000.00 pellets Coal ash kg/Day Sale to registered 2700.00 5850.00 8550 brick manufacturer *Schedule I of The Hazardous and Other Wastes (Management and Transboundary Movement) Rule, 2016.

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5.2 Soil environment

The soils in the study area can be adversely affected during the activities associated with construction and/or operational phase of the project as detailed here under:

Anticipated impacts during Construction phase

No construction activity is required as the production enhancement will be carried out using high volume capacity reactors replacing existing reactors of less capacity.

Anticipated impacts during Operation phase

The possible adverse impacts on soil within and beyond the project plot area during the operational phase can be as under.

1) Pollution/Contamination of soils if the treated/untreated effluent in any way finds its way to ground through unforeseen disposal/spillage/leakage within the project plot & study area.

2) Accidental spillage of chemicals (raw material/product) & hazardous waste during storage, handling, gland leakage of pumps and flange leakage in pipelines within the project plot.

3) Accidental spillage of chemicals (raw materials/products) & hazardous waste during transportation to & form the project site.

4) Deposition of particulate matter from stack/chimney on the soils located in the windward direction from the project site.

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Precautionary management/mitigation measures to be adopted for prevention of soil contamination

 In order to avoid risk of soil contamination within the project plot & study area due to unforeseen leakage the project proponent is robustly advised to concrete pave the entire ETP area. Also project proponent to ensure safe working & periodic maintenance of ETP by establishing written SOPs (Standard Operating Procedures) & training the ETP operating staff with the same.

 All raw materials & products should be stored in dedicated closed warehouses/storage areas with leak proof flooring & walls. Production area should be covered with “Acid/Alkali” proof bricks with adequate drainage system connected to ETP.

 Transportationof chemicals (raw materials/products) & hazardous waste will be mainly done by trucks/tempos however the unforeseen events of accidental spillage are not predictable which makes it difficult to install pre event control measures. However for such instances project proponent is robustly advised to develop & deploy Offsite Emergency Contingency Plan & develop related Standard Operating Procedures & provide training about the same concerned personnel to tackle any unforeseen event.

 Hazardous waste will be stored in dedicated hazardous waste storage area made of thick concrete paved flooring with HDPE lining & in any case hazardous waste should not be stored more than 90 days & to be disposed off to CHWTSDF. Other industrial waste such as plastic waste, packing material, cleaned empty drums/carboys/containers will be stored in a dedicated waste storage area & such waste will be returned to supplier/sold to authorized recycler.

 For proper dispersion of pollutants in atmosphere, stack with appropriate height will be provided as per the CPCB guidelines.

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4.4.3 Impact matrix

Environmental Anticipated Aspects Receptors Mitigation measures Scoring the anticipated impact components Impacts No Yes 1 2 3 4

Insignifi Signi Severely

cant ficant Significant Soil$ 1. 1. Soils in If at all air emissions 1. Appropriate stack --  -- -- Deposition the study in any form get height will be provided of air area deposited on the as per CPCB guidelines emissions prevailing soils in so that the pollutants will on the prominent wind disperse effectively in the prevailing direction within the atmosphere at proper soils in the study area, then such height which will reduce study area. soils may get the impact substantially. contaminated there by 2. affecting the soil 2. The effluent will be Unforesee fertility & may also treated within in house n or have indirect adverse ETP, Hazardous wastes deliberate effect on the biotic will be stored in release of environment. dedicated & demarcated effluent. 2. Water The prevailing surface impermeable waste --  -- -- bodies in water bodies in the storage area. 3. the study study area may get

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Accidental area polluted due to surface 3. Standard Operating spillage of runoff from the Procedures (SOP’s) will chemicals contaminated soils and be developed & deployed (raw percolation activity as a part of Onsite & materials/p may result in polluting Offsite Emergency roducts) & the ground water. Contingency Plan to hazardous 3. If deposition of air tackle unforeseen events --  -- -- wastes. Agricultural emissions/unforeseen of accidental spillage of fields in the or deliberate release of hazardous chemicals & study area treated wastes. effluents/accidental spillage of hazardous 4. AstecLifesciences Ltd. wastes, chemicals on during its existing the agricultural fields operations does not occurs then discharge any kind of productivity of such treated or untreated agricultural fields may effluent in whatsoever be adversely affected. manner 4. Biotic The areas with --  -- -- environmen contaminated soils in t the study area may render them as unfit for growth of natural vegetation and may also be un favored by

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faunal species which may result in affecting the overall biotic environment near such contaminated areas. 5. Human Adverse health --  -- -- habitation impacts due to contact within the with contaminated study area soils, loss of property, loss of source of income $ Soil monitoring done by SEEPL within study area at Project site,Near CETP , Dhamane-gaon ,Warandh , Padavi , Kiye , Wadghar , Birwadi , Tahiye

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Probability of impact occurrence

Scenarios Chance of Occurrence Scoring Deposition of air emissions on the prevailing soils in >90 % Chance of Occurrence 4 the study area.The noise & vibrations generated from the project activities reaching up to prevailing 50-90 % chance of Occurrence 3 important/potential habitats within the study area 20 - 50 % chance of Occurrence 2 Unforeseen or deliberate release of effluent. <10 % chance of Occurrence 1 Accidental spillage of chemicals (raw materials/products) & hazardous wastes.

Impact severity score

Scoring for Overall score Scoring for Scenario chance of for severity of impact occurrence impact Deposition of air emissions on the prevailing soils in the study area. The noise & vibrations generated from the project activities reaching up to prevailing 2 2 4 important/potential habitats within the study area Unforeseen or deliberate release of effluent 1 2 2 Accidental spillage of chemicals (raw materials/products) & hazardous wastes 2 2 4 Note: The scoring for chance of occurrence & the scoring for impact has been given taking into the terrain conditions of the study area, project activities specific mitigation measures & subject understanding by the functional area expert.

Score Type of Risk

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1-4 Negligible 5-8 Less Severe 9-12 Highly Severe 13-16 Extremely Severe

Assessment of probable impacts on soil quality within study area due to waste generations (solid & liquid) & its management during the operational phase

Taking into consideration management/mitigation measures to be provided/to be adopted by the project proponent during operational phase for management of solid & liquid wastes the maximum score for overall severity of the anticipated impacts is 4 & the risk type assessed is as negligible.

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5.3 Biotic environment

Nevertheless the impacts associated with any kind of proposed activity on the environment cannot be completely nullified however the severity of such impacts can be minimized to a great extent by advocating suitable mitigation measures.

4.4.4 Anticipated impacts (Construction phase)

Impacts during construction phase

No construction activity is required as the production enhancement will be carried out using high volume capacity reactors replacing existing reactors of less capacity.

Evaluation of vegetation felling/clearing activity

The project in consideration is a brown field activity which will be executed within the premises of an existing manufacturing plant by replacing existing reactors with high volume capacity reactors. Hence any sort of vegetation felling/clearing activity is not involved.

Evaluation of habitat loss

The project plot in consideration was already subjected to industrial type of use and was not inhabited by any faunal species hence habitat loss is anticipated.

4.4.5 Anticipated impacts (Operational phase)

Generally the activities which may have adverse impact on the biotic environment during the project operational phase may be due to unforeseen / deliberate release of treated/untreated effluent, disposal of hazardous waste on the ground or in the water bodies in the study area. However the proposed project has made following provisions for the effluent & hazardous waste management.

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The hazardous wastes generated during project operational will be either sold to authorized recyclers or will be sent to Mumbai Waste Management Ltd. - CHWTSDF at Taloja for further processing & disposal.

The only direct possible impacts from the proposed project activities may be due to following activities:

1) Air emissions from burning of fuel for operation of utilities like Boiler, D.G set & manufacturing process related emissions if at all escapes the industrial area.

2) Accidental/Unforeseen disposal of hazardous chemicals (raw materials & finished products) & hazardous wastes within the study area.

Precautionary measures to be adopted during the operational phase 1) AstecLifesciences Ltd. will ensure that the during the operational phase at no point of time in whatsoever manner untreated/treated effluent will be subjected to disposal on land or in water bodies within the study area.

2) ALSL will ensure that permitted quantum of treated effluent is sent to CETP & additional effluent is recycled and also it will be ensured that the hazardous waste is not disposed of at any other place except the designated CHWTSDF.

2) In order to minimize the air emissions at the source itself provision of APCD’s (Air Pollution Control Devices) such as Process scrubbers (proposed) is made for manufacturing process related emissions & adequate stack height for existing & proposed boiler stacks will be provided as per CPCB guidelines.

3) As a precautionary measure industry should ensure that at no point of time during the operational phase of the project the concentrations of air emissions should not exceed the prescribed levels.

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4) The transportation of chemicals (raw materials/products) & hazardous waste will be mainly done by trucks/tempos however the unforeseen events of accidental spillage are not predictable which makes is difficult to install pre event control measures. However for such instances the project proponent is robustly advised to develop & deploy Offsite Emergency Contingency Plan & related Standard Operating Procedures to tackle any such unforeseen event.

Assessment of presence of any endemic, conservation importance species in the study area

The recorded 85 plant species, 29 bird species, 1 mammal and 6 reptiles are fairly common and have a wide range of presence and abundance across the entire Raigad District, moreover any of the floral & faunal species in the study area does not belong to any categories of conservation concern as per the IUCN & WPA 1972.

Impact assessment

Proposedproject activity does not pose any threat to any species of conservation importance also does not involve any sort of liquid or solid discharge/disposal on the ground or in the water bodies within the study area & project plot being located well within the precincts of an area which already prevails industrial type of use no adverse impacts are anticipated on the surrounding biotic environment.

5.4 Land environment

5.4.1 Impact identification

Generally the developmental activities such as construction & development of Building/Township/Industrial Estate/Special Economic Zones which involve comparatively larger areas tend to change the prevailing land use & land cover aspects directly.

Also the influx of people associated with such project activities has the potentiality of changing surrounding land use & land cover aspects by way of new settlements/setups & thus promoting various other infrastructural activities there by inducing land use/land cover changes indirectly.

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The proposed activity is a production capacity expansion of the existing unit located at Plot No. -16, 17, 18 and B-21 and will be carried out by replacing existing equipment by new higher capacity equipment.

Since there is no requirement of any new/ additional land hence none alternative sites were considered for the proposed expansion project.

This is industrial type of land use hence no changes in the existing land use - land cover aspects of the study area are anticipated.

5.5 Socio economic environment

It is envisaged that the existing project & the proposed expansion activity will help to some improvements in the locale specific socio-economic aspects in the nearby human habitations to the MIDC area. Since the proposed expansion will be carried out within the existing plant areaand hence no impact on external human settlements is envisaged also project will not have any major impact on the local level population growth, since existing 160 no. man power is sufficient for the expansion activity. Hence increase in the population and related strain on infrastructure of the study area is not envisaged. Better literacy rates are possible due to assumed better economic conditions of the people in the project concerned area. Better literacy means better social status and thereby improved lifestyle. This will be a positive impact due to the existing and proposed capacity expansion.

5.6 Odour

5.6.1 Identification of source

Odour sources can be continuous or intermittent, point sources (for example chimneys, stacks or building vent/exhaust pipes), area sources (for example stockpiles, ponds or open-topped tanks) or volume sources (for example, a building with many openings from which odour escapes). The

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Chapter 4: Anticipated Environmental Impacts & Mitigation Measures sources within the site boundary and any nearby sources beyond the boundary they could contribute to cumulative odour impacts. It is important to include fugitive sources as these often make an important contribution to the odour impacts. In the operational phase the component which will contribute to the odour generations are working of waste water treatment plant, raw materials and chemicals handling in the industry, working emission of the solvents storage tanks etc. Sources which will lead to the generation of odour are leakage of solvent/chemical from the storage drums/pipeline/reactors, evaporation of acid as acid fumes, domestic waste, handling of raw materials, also handling of sludge and reaction waste etc.

5.6.2 Impact prediction

Exposure to odors could result in health effects ranging from none, to mild discomfort, to more serious symptoms. Some chemicals with strong odors may cause eye, nose, throat or lung irritation. Strong odors may cause some people to feel a burning sensation that leads to coughing,wheezing or other breathing problems. Workers/People coming in contact who smell strong odors may get headaches or feel dizzy or nauseous. If an odor lasts a long time or keeps occurring, it also could affect mood, anxiety and stress level.

5.6.3 Mitigation measures

Mitigation measures that can be implemented for controlling the odour are given below,

 Provision of Ventilation and Exhaust: The flow of air and exchange in plant area where chemicals are handled will largely impact odour. Storage conditions of volatile organic compounds with odour will also significantly contribute to odour. In normal circumstances it is best to keep the odour emanating materials under closed conditions. Also providing adequate exhaust in the area can control odour. Well documented SOPs on chemicals handling and trained operators can hugely control the release of odour in plant  Supervision and maintenance: Equipments are very well maintained and the company has strong Asset Integrity plan philosophy and plan. A well documented Preventive, and predictive maintenance plan is prepared for all equipment, machines, and assets. Good

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Housekeeping: Decay Evaporation of odorants from stored decaying material may often lead to odour emission. Good housekeeping may eliminate the problems.  Provision of Containment: The preventive measures or changed process parameters are not enough to avoid annoying emissions of odorous compounds from a plant, it must be placed in a building equipped with ventilation and, where required, air cleaning equipment. It may be necessary to have non-opening windows and automatic gate and door closing devices, and to provide a negative pressure in the building. Odour nuisances can be prevented either by cleaning of exhaust air or by dilution in outlets.  Increasing Air Exchange: The exchange of air surrounding an odorous process is large the emitted odorants will be diluted. But if the odour comes from evaporated material, the emission may increase. In normal circumstances it is best to reduce the amount of air which gets in contact with odorous materials. In this way odour control equipment will be required.  Good Housekeeping: Decay Evaporation of odorants from stored decaying material may often lead to odour emission. Good housekeeping may eliminate the problems.

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Chapter 5: Analysis of Alternative

5.0 CHAPTER 5: ANALYSIS OF ALTERNATIVE

5.1 Introduction

Astec LifeSciences Ltd. proposes expansion of existing manufacturing unit located at Plot No B-16, 17, 18 & 21, MIDC Mahad, District Raigad, Maharashtra. The project site is well connected by Mumbai- Goa highway (NH 66). The national highway is approximately 9 km away and can be reached by state road network. The nearest railway station is Veer which is approximately 18 km away from site. The MIDC Mahad have excellent internal and connecting road network therefore no additional connectivity infrastructure will be constructed.

The industrial area hosts small, medium & large scale industrial units of various categories such as chemical, polymer, pharmaceutical, organic, pigments, fertilizers manufacturing industries. Mahad is part of proposed Panvel-Mahad-Chiplun-Panjim Economic corridor under Bharatmala Project. The major physical infrastructure like road, water supply is provided by additional MIDC Mahad. The electricity will be supplied by MSEDCL by means of continuous feeder substation. MIDC has developed a separate supply water scheme by construction a Dam having a capacity of 29 million cubic meters on Savitri River. A 24 MLD water treatment plant has been constructed to meet the requirement of industrial Area. This water Treatment plant has an excess capacity of 8 MLD. Apart of from MIDC's water supply scheme there are two more water supply scheme developed by irrigation department.

Considering above mentioned points and availability of land required for proposed activity with lower price, no any alternative site was considered.

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5.2 Analysis of Alternative Site

This is an expansion project for existing products and new products along with byproducts will be manufactured on existing plot. The expansion will be done by replacing equipment by new higher capacity equipment, also current site is in approved chemical zone of MIDC and is well connected to get raw material by road / railway and carry on the manufacturing activities. The MIDC have all adequate facilities viz. good road and rail network, 24 hour electricity, water supply, MIDC roads, CETP etc. and therefore no alternate site has been considered for the expansion. Since there is no requirement of any new/ additional land hence none alternative sites were considered for the proposed expansion project.

5.3 Analysis of Alternative Technology

Company’s Research and Development department has been a foremost pillar of success. It is equipped with various requisite testing equipments and tools for proper testing and analysis. R&D experts have continuously adopted modern techniques and regularly improvise company’s product range as per the market demands.

Company will replace existing equipments with equipments of high volume capacity wherein the reaction chemistry & physical processes used for manufacture of pesticides is the advanced technology & no other alternative reaction chemistry is available.

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Chapter 6: Environmental Monitoring Programme

CHAPTER 6: ENVIRONMENTAL MONITORING PROGRAMME 6.1 Introduction Environmental Monitoring Program is an essential tool for sustainable development. An Environmental Monitoring Program provides a delivery mechanism to address the adverse environmental impacts of a project during its execution, to enhance project benefits, and to introduce standards of good practice to be adopted for all project works. An environmental monitoring program is important as it provides useful information and helps to:

• Assist in detecting the development of any unwanted environmental situation, and thus, provides opportunities for adopting appropriate control measures. • Monitoring & tracking the effectiveness of Environment Management Plan & implementation of mitigation measures planned. • Define the responsibilities of the project proponents, contractors and environmental monitors and provides means of effectively communicating environmental issues among them. • Define monitoring mechanism and identify monitoring parameters. • Evaluate the performance and effectiveness of mitigation measures proposed in the Environment Management Plan (EMP) and suggest improvements in management plan, if required. • Identify training requirement at various levels. • Identification of any significant adverse transformation in environmental condition to Plan additional mitigation measures

6.2 Monitoring points /locations and components Environmental monitoring plan is decided considering the environmental impacts likely to occur due to operation of the project as the main scope of monitoring program is to track timely and regularly change in the environmental condition and to take timely action to protect the environment.

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6.3 Post project monitoring parameters &frequency Table No. 6.1 Post Project Monitoring Parameters & Frequency Number Sr. Particulars Pollutant Pollutant Characteristics of Frequency No Samples CO, SO2, NOX, PM,CO, Benzene, Ammonia, 1 Ambient Air Air Emission 3 Quarterly Benzopyrene, Lead, Nickel, Arsenic, Ozonein Ambient Air DG Set, Boilers SO , NO , SPM 2 Stack 2 X 2 &TFHs Monitoring Scrubber Acid Mist 1 Air emissions Quarterly Methanol, Ammonia, Volatile 3 Work place Sulphuric acid, Methyl Organic 1 Chloride, Toluene, Chloroform Compounds & Xylene Boiler/TFH area, D.G Set, 3 Sound Noise Level dB (A) 4 Quarterly ETP, Work Place Area pH, O & G, TDS, TSS, COD, 4 Effluent Treatment Plant All parameters 1 Weekly BOD & Bioassay specific to

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Number Sr. Particulars Pollutant Pollutant Characteristics of Frequency No Samples project

Used/ spent oil, Residues & Waste, Chemical sludge residue from Pesticides, Chemical Once in a 5 Hazardous Wastes sludge from ETP, Filter & filter material H.W. characteristics 5 Year having organic liquid, Spent carbon, Asbestos gaskets&Spent Solvents

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6.4 Monitoring methodologies: Monitoring of environmental samples shall be done as per the guidelines provide by MoEF/CPCB/SPCB. The method followed shall be recommended / standard method approved/recommended by MoEF/CPCB.

6.5 Documentation and reporting The records of the monitoring program shall be kept on regular basis for all aspects of the monitoring. Separate records for water, wastewater, solid wastes (Slag & Collected Dust, Recycled Dust-Scales etc.), air, emission, soil & manure/compost shall be prepared and preserved regularly. Immediately upon the completion of monitoring as per the planned schedule, report shall be done & necessary documents shall be forwarded to the concern person. Methodology of monitoring (sampling & analysis) shall be prepared as separate documents as SOP (standard Operating Procedure) wherever required. The records showing results/outcome of the monitoring programs shall be prepared as per the requirement of the schedule mentioned above. Regularly these documents & records shall be reviewed for necessary improvement of the monitoring plan/mitigation measures/environmental technologies as well as for necessaryactions of environmental management cell.

6.6 Budget &procurement schedule On regular basis, Environment Management Cell shall inspect the necessity & availability of the materials, technologies, services & maintenance works. The Cell shall made appropriate budget for the purpose. Regular record review for change in financial requirement of environment management shall be done and appropriate budgetary provisions shall be made. Along with other budgets, Budget for environmental management shall be prepared and revised regularly up on requirement. The budget shall include provisions for:

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 Environmental Monitoring Program  Operation & Maintenance of environmental Technologies/Equipments  Laboratory works for Environmental management activities  Emergency Purchase of necessary material, equipments, tools, services, protective equipment.  Greenbelt development  Social & Environmental Welfare & Awareness programs/training & Health related issues.  Annual Environmental Audit

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Chapter 7: Additional Studies

CHAPTER 7 – ADDITIONAL STUDIES

7.1 Public Hearing

“Public Consultation” refers to the process by which the concerns of locals likely to be affected/all the stakeholders who have plausible stake in the environmental impacts due to the project or activity are ascertained with a view to taking into account all the material concerns in the project or activity design as appropriate. M/s.AstecLifeSciencesLtd.willexecute the proposed capacity enhancement activity within the existing manufacturing facility located at Plot No. B-16, 17, 18& 21, MIDC Mahad, Mahad, Dist. -Raigad, Maharashtra, India.

Now since project site being located within Mahad MIDC which was notified before EIA Notification 2006 being coming into force hence the proposed activity is exempted from public hearing the relevant documents justifying the same are attached as Annexure 1.2.

7.2 Risk Assessment 7.2.1 Introduction As indicated in the earlier chapter the expansion project facilitates to manufacture pesticide products and pesticide formulation chemicals poses various types of hazards due to storage, handling & transportation of various chemicals, which are indicated in Chapter no. 2. In order to study the risks envisaged by the activities, the following methodology was adopted. 7.2.1.1 The factory would be manufacturing different products under the category of pesticide products, pesticide formulation and its byproducts accounting to a total production of 3254MT/M. However HAZOP studies have been carried out for some hazardous operations and process. 7.2.1.2 A detailed scrutiny of rawmaterials was done which would be stored in Tanks on the site. The detailed list of raw materials is tabulated below in Table no. 7.1. 7.2.1.3 M.S.D.S’s:

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 1 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 7: Additional Studies

Brief M.S.D.S.s of all the above chemicals and other raw materials which would be used in the manufacturing processes of products are used as reference for preparation of Quantitative Risk Assessment &HAZOP study.

7.2.1.4 A Quantitative Risk Assessment based on the software ALOHA (Arial Locations of Hazardous Atmospheres) for chemicals storages in tanks was carried out. The criteria failure scenarios considered for ALOHA depend on the type of storage whether above ground/ underground, physical state of the chemical stored, chemical properties of the chemical. Also for raw materials other than storage in tanks Dow‟s Fire & Explosive &Mond‟s Toxicity Index was evaluated.

Note: ALOHA assessment was carried out for all the raw materials stored in tank except 2,4Dichloroacetophenone& Caustic lye since they are not listed in ALOHA database.The summary of the ALOHA footprints are attached as Annexure 7.1

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Chapter 7: Additional Studies

Table 7.1: Details of Raw Materials Stored in Above Ground Tank

Capacity of Maximum Dimensi Tank transfer pump quantity of Dyke Dyke Sr. Storage ons Dyke RM Name UG/AG Capacity from main storage at any (Single/ (Area) No. Type in meters (Yes/No) tank to day point of time common) Dimensions (Tank) tank (MT) Dimethyl Tank AG 25 KL 10 M3/hr 30.00 2.4x5.5 Yes Common 8.3x4.4x0.74 M 1. Sulphate (D x H) (L x W x H)

2,4 Tank AG 15 KL 10 M3/hr 20.0 2.0x5.0 Yes Common 8.3x4.4x0.74 M (D x H) (L x W x H) 2. Dichloroacetophe none

Bromine Tank AG 8 KL 3 M3/hr 24 2.0x3.2 Yes Single 9.6x8.0x0.6 M 3. (D x H) (L x W x H) Caustic lye Tank AG 15 KL 10 M3/hr 22.0 2.0x4.5 Yes Common 6.3x3.9x1.14 M 4. Vertical (D x H) (L x W x H)

Caustic lye Tank AG 15 KL 10 M3/hr 22.0 2.5x3.5 Yes Common 6.3x3.9x1.14 M (D x L) (L x W x H) 5. Horizont al

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 3 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Details of Raw Materials Stored in Under Ground Tank

Capacity of Maximum Dimensi Tank transfer pump quantity of Dyke Dyke Sr. Storage ons Dyke RM Name UG/AG Capacity from main storage at any (Single/ (Area) No Type in meters (Yes/No) tank to day point of time common) Dimensions (Tank) tank (MT) 6. Methanol Tank UG 15 KL 10 M3/hr 12.0 2.0x4.8 Yes Common 9.0x6.3x3 M (D x H) (L x W x H) 7. Cyclohexane Tank UG 10 KL 10 M3/hr 8.0 2.0x3.2 Yes Common 9.0x6.3x3 M (D x L) (L x W x H) 8. Methyl Tank UG 15 KL 10 M3/hr 15.0 2.0x4.8 Yes Common 6.5x3.0x3.5 M Cyclohexane (D x L) (L x W x H)

9. C9 Tank UG 20 KL 10 M3/hr 20.0 2.25x5.0 Yes Common 9.0x6.3x3 M (D x L) (L x W x H) Methyl Tank UG 20 KL 10 M3/hr 20.0 2.25x5.0 Yes Common 9.0x6.3x3 M 10. Cyclohexane (D x L) (L x W x H)

11. Toluene Tank UG 10 KL 10 M3/hr 8.0 2.0x3.2 Yes Common 9.0x6.3x3 M (D x H) (L x W x H)

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 4 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Table 7.2: ALOHA Summary Sheet

Scenario Effects Substance Failure LOC Distance No. considered

Toxic area AEGL-1 0.024 ppm 330 yards of vapor AEGL-2 0.12 ppm 147 yards cloud AEGL-3 1.6 ppm 38 yards Flammable 10% LEL 3600 ppm Less than 10.9 Area of yards Evaporating Vapor 60% LEL 21600 ppm Less than 10.9 DS/ 01 Puddle Cloud yards Overpressur e (blast force) from - - - vapor cloud explosion DIMETHYL Toxic area AEGL-1 0.024 ppm 1.5 miles SULFATE of vapor AEGL-2 0.12 ppm 1529 yards cloud AEGL-3 1.6 ppm 1.5 miles Flammable 10% LEL 3600 ppm 13 yards Area of Vapor 60% LEL 21600 ppm 12 yards Cloud Direct DS/02 Overpressur shatters 1.0 psi 24 yards e (blast glass force) from serious 3.5 psi 11 yards vapor cloud injury explosion likely destruction 8.0 psi LOC was never of exceeded buildings Toxic area AEGL-1 0.033 ppm Greater than 6 Evaporating of vapor miles B/01 Puddle cloud AEGL-2 0.24 ppm 3 miles AEGL-3 8.5 ppm 888 yards AEGL-1 0.033 ppm greater than

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 5 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Direct B/02 Toxic area 6miles BROMINE of vapor cloud AEGL-2 0.24 ppm 3.2 miles

AEGL-3 8.5 ppm 904 yards

Toxic Area AEGL-1 530 ppm 164 yards of vapor AEGL-2 2100 ppm 79 yards cloud AEGL-3 7200 ppm 39 yards

Flammable 10% LEL 7180 ppm 39 yards Area of 60% LEL 43080 ppm 12 yards

Direct Vapor Cloud METHANOL M/01 Overpressure shatters 1.0 psi 15 yards (blast force) glass from vapor serious 3.5 psi LOC was never cloud injury likely explosion exceeded destruction 8.0 psi LOC was never of buildings exceeded

CYCLOHEX Direct CH/01 PAC-1 300 ppm 126 yards ANE Toxic Area PAC-2 1700 ppm 47 yards of vapor PAC-3 10000 ppm 18 yards cloud Flammable 10% LEL 1300 ppm 53 yards Area of Vapor Cloud 60% LEL 7800 ppm 21 yards shatters 1.0 psi 37 yards glass

Overpressure (blast force) from vapor cloud serious 3.5 psi 16 yards explosion injury likely destruction 8.0 psi LOC was never of buildings exceeded METHYLCY Direct MCH/01 Toxic Area PAC-1 1200 ppm 51 yards CLOHEXAN of vapor PAC-2 1700 ppm 43 yards E Cloud PAC-3 10000 ppm 17 yards

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 6 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Flammable 10% LEL 1150 ppm 52 yards Area of Vapor Cloud 60% LEL 6900 ppm 21 yards Overpressure shatters 1.0 psi 37 yards (blast force) glass from vapor serious 3.5 psi 16 yards cloud injury likely destruction 8.0 psi LOC was never explosion of buildings exceeded TOLUENE Direct TOL/01 Toxic area of AEGL-1 67 ppm 298 yards vapor cloud AEGL-2 560 ppm 87 yards AEGL-3 3700 ppm 31 yards Flammable 10% LEL 1100 ppm 60 yards Area of 60% LEL 6600 ppm 23 yards Vapor Cloud Overpressure shatters 1.0 psi 38 yards (blast force) glass from vapor serious 3.5 psi 17 yards cloud injury likely explosion destruction 8.0 psi LOC was never of buildings exceeded AEGL-1 140 ppm 166 yards AEGL-2 360 ppm 96 yards Toxic area of AEGL-3 - No vapor cloud recommended

LOC value

Flammable 10% LEL 900 ppm 58 yards Area of Vapor 60% LEL 5400 ppm 23 yards

Cloud

TRIMETHY shatters 1.0 psi 40 yards LBENZENE Direct TMB/01 glass (C9) Overpressur serious 3.5 psi 18 yards e (blast injury force) from likely vapor cloud destruction 8.0 psi LOC was never explosion of exceeded buildings

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 7 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Interpretation

Based on the unsafe distances identified by the software output, the MCLS (maximum credible loss scenario) for the factory works out to about greater than 6 miles for Bromine. The scenario considered for assessing the impact by quantitative risk assessment was taken from CPR18 E. The probability of occurrence of the scenario is 5 × 10-6 y-1,which is very less. The Disaster management plan highlights the suggestive measures to be taken to avoid occurrence of such an accident.

Table No. 7.3: Interpretation Table

Threat Toxic Level of Concern Receptors Effects zone Red - 904 AEGL-3 –8.5 ppm Factory premises and Human Effects:- yards Susceptibleindividuals could other industries in Eye Contact: experience life-threatening immediate vicinity Check for and remove health effects or death. any contact lenses. In Orange- AEGL-2 –0.24 ppm Limited to the MIDC case of contact, 3.2 miles susceptible individuals, could boundary &Birwadi immediately flush experience irreversible or other Village Other eyes with plenty of serious, long-lasting adverse industries, water for at least 15 health effects or an impaired vegetation. minutes. Cold water ability to escape. may be used. WARM Yellow - AEGL-1 –0.033 ppm Internal MIDC road, water MUST be used. Get medical attention

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 8 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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greater Susceptibleindividuals could Industries in Mahad immediately. than 6 experience notable discomfort, MIDC & Other Skin Contact: miles irritation, or certain industries, In case of contact, asymptomatic nonsensory vegetation, Small immediately flush effects. However, the effects agricultural fields skin with plenty of are not disabling and are near Boregaon water. Cover the transient and reversible upon Village. irritated skin with an cessation of exposure. emollient. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attentionimmediately. Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 9 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to- mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.

However to prevent such worst case scenario following preventive/precautionary measures will be ensured for bromine storage tank.

 Storage MOC will be glass line horizontal cylindrical storage  Tank designed by standard manufacturer  Tested at manufacturer end as well as at site before taken in use  Containment of puddle with water to reduce evaporation  Storage in shelter  Same capacity dump tank fixed nearby in case of emergency transfer  Standard transfer pump (magnetic driven Richter pump) with standby pump  PVDF piping for transferring of bromine

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 10 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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 Water curtain provided to storage to avoid dispersion of vapour cloud outside the storage  Fixed detectors with local display and alarm  Once in 2 year thorough internal inspection practice in place  Competent supervisor in storage area  Continuous monitoring  Emergency PPE (suit, gloves kept nearby and training imparted to people)  SCBA provided near by the storage, and subsequent safe distances

Further the second unsafe distances identified by the software output, the second MCLS (maximum credible loss scenario) for the factory works out to be about 1.5miles (Threat zone –Yellow) for Dimethyl Sulfate for Direct leak scenario (Toxic area of vapor cloud).However to prevent such scenario following preventive/precautionary measures will be ensured for Dimethyl Sulfate storage tank.

 Storage MOC is CS horizontal cylindrical storage  Containment puddle with impervious flooring  SS piping  Inspection practice in place  Continuous monitoring  Emergency PPE (suit, gloves kept nearby and training imparted to people)  SCBA provided near by the storage, and subsequent safe distances For above ground Storage Tanks

 The tanks will be fabricated taking into account the corrosion resistance properties of the material of construction.

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 11 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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 The tank will be provided with water sprinkler arrangement so as to cool the same in summer season.  The tanks will be provided with breather valves and will have nitrogen blanketing arrangement wherever required  Dyke wall of adequate volume (110%) capacity of the tank will be constructed around the tanks.  The dyke enclosure will be lined with impervious coating  Regular inspection of the tank, transfer pipelines and dyke will be done visually and records maintained.  It is recommended to establish foam monitor in the solvent tank yard farm.

For Underground Solvent Storage Tanks

 The tank will be lined with impervious coating.  The tank will be provided with water sprinkler arrangement so as to cool the same in summer season  The tanks are covered under a license under Petroleum Rules from PESO.  It is recommended to establish foam monitor in the solvent tank yard farm.  Flame Proof Pumps and Motor will be provided in the tank farm.  Underground tank will have natural earthing.  Non Sparking Tools will be used the tank farm area.  The gap between tank and RCC wall will be filled with sand.  Spark Arrestor/Muffler will be provided at the security gate to each vehicle which comes in to the tank farm for unloading.  Methanol tanks would be covered under a license under Petroleum Rules from PESO.

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 12 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 7: Additional Studies

7.2.2 DOW Index

The Dow index has been performed for the selective raw materials having Nf value of greater than or equal to 3 however to assess the worst case scenario the total storage quantity of all selected raw materials has been assumed as Dimethyl Sulphide since it is having highest Nf value of 4 amongst the selected raw materials. The DOW summary sheet is displayed below in Table no. 7.4 and Table no 7.5. The DOW index worksheet is attached as Annexure 7.2

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 13 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Table No. 7.4: DOW Index Summary Sheet for Raw Materials

Dimethyl Diethyl Acetonitrile Butanol Dioxane Tetrahydrofuran Xylene Chemical sulphide Ketone

Storage Considered Drums Drums Drums Drums Drums Drums Drums Maximum Quantity stored at any given 20 10 20 10 20 20 20 point of time ( MT)

N h 2 1 2 2 2 2 2

N f 3 3 4 3 3 3 3

N r 0 0 0 0 1 0 0

Material Factor, MF 16 16 21 16 16 16 16 F1 (General Process 2.55 Hazard) F2 (Special Process 2.20 Hazard) F3 (Hazard Factor) 5.61 Fire & Explosion Index 117.81

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 14 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 7: Additional Studies

Degree of Hazard Intermediate

Sadekar Enviro Engineers Pvt. Ltd Chapter 7- 15 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Table No. 7.5: DOW Index Summary Sheet for Fuel Storages

Chemical Furnace Oil HSD

Storage Considered Tank Drums Maximum Quantity 4 KL 400 Lit stored at any given point of time

N h 0 0

N f 2 2

N r 0 0 Material Factor, MF 10 10 F1 (General Process 1.95 1.95 Hazard) F2 (Special Process 1.48 1.3 Hazard) F3 (Hazard Factor) 2.886 2.535 Fire & Explosion Index 28.86 25.35 Degree of Hazard Light Light

Recommendation/Suggestions

1. The raw materials are stored according to their compatibility with other raw materials.

2. Company has adequate written operating instruction and fully documented operating discipline for emergency shutdown, normal operating conditions, routine shutdown etc. which are important for maintaining satisfactory control of a unit.

3. The raw materials are stored in a dedicated area with minimum interference.

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 16 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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4. Appropriate drainage with the slope of 2 % is provided to remove small and large spillage of the chemicals.

5. The provision of fire water supply is provided through the hydrant line passing from the raw material storage area.

6. Provision of hand Extinguishers are provided and found to be adequate with reference to the storage quantity of raw materials.

7. Provision of spill kit is provided to deal with the minor spillage scenario.

The existing safety features provided are satisfactory to tackle the emergency situation raised in the site.

7.2.3 Mond's Index

The principle and general approach used in the DOW method of hazard evaluation have been further developed by ICI Mond Division, Their revised Mond fire, explosive and toxicity index is a series of papers by Lewis (1979). The main developments made to the DOW Index in the Mond Index are:

1. It covers a wider range of process and storage installation 2. It covers the processing of chemicals with explosive properties 3. A calculation procedure is included to allow for the off-setting effects of good design and control and safety instrumentation 4. The procedure has been extended to cover plant layout 5. Separate indices are calculated to access the hazards of fire, internal explosion and aerial explosion.

Some of the raw materials stored in the site are toxic in nature. Hence appropriate standard operating procedures are established by the company for ensuring the safety of the workers handling the raw materials on daily basis. Some selected toxic raw materials are used for

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 17 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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calculating the toxicity index using Mond'sindex.TheMond's index worksheet is attached as Annexure 7.3.

Table 7.6: Mond's Index Summary Sheet

T (Toxicity F1 F2 Toxicity Degree of Chemicals Storage N h MAC Ts h factor) GPH SPH Index Hazard Ethylene Tonner 2 125 1 ppm 125 1.45 1.6 6.31 Moderate Oxide 125 Formaldehyde Drum 2 125 2ppm 1.45 1.6 6.31 Moderate 125 Formic Acid Carboy 3 250 5ppm 1.6 1.8 8 Moderate 125 phenol Drum 4 325 5 ppm 1.6 2 9 Moderate 125 Phosgene Cylinder 4 325 0.1 ppm 1.45 2 8.81 Moderate Sodium 1.22pp 125 Bag 3 250 1.45 1.8 7.8 Moderate Hydroxide m 0.25 125 Suphuric Acid Carboy 3 250 1.95 1.8 8.4 Moderate ppm Thionyl 125 Drum 4 325 1ppm 1.95 1.8 9.18 Moderate Chloride Hydrobromic 125 Drum 3 250 -- 1.5 1.7 7.75 Moderate acid Hydrochloric 125 Drum 3 250 5 ppm 1.5 1.7 7.75 Moderate acid

Interpretation

According to the Mond's Index the toxicity index is calculated for the raw materials. Table No 7.6is indicating moderate degree of hazard for all the raw materials. Material is irritating to mucous membranes and upper respiratory tract. To reduce the intensity of the hazard following recommendation and suggestion should be followed.

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 18 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Toxicity (Mond) Index recommendations:

1. The raw materials are stored according to their compatibility. 2. Toxic materialsare stored in cool place and kept away from heat. 3. Toxic material can cause breathing difficulty therefore storage area is well ventilated. 4. Good housekeeping practice is implemented in storage area. 5. Appropriate drainage with the slope of 2 % is provided to remove small and large spillage of the chemicals. 6. The provision of fire water supply is provided through the hydrant line passing from the raw material storage area 7. PPE‟s are used wherever necessary. 8. MSDS recommendations are strictly followed while chemical storage and handling.

7.3 HAZOP Study

HAZOP study has been carried out for hazardous operations and process. For the preparation of the HAZOP study P & IDs, Operating Procedures, Mass balances and MSDS were used. The HAZOP study is attached as Annexure 7.4. The brief recommendations of the HAZOPstudies are given below.

General recommendations

1. PPE shall be used for handling of chemicals.

2. Spill control equipment and procedure to be defined and shall be provided for all chemicals.

3. Working of the scrubber system to be ensured before starting of all batches.

4. Flange guards to be provided on all flange joints.

5. Design basis of all pressure relief valve to be established.

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 19 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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6. Indication of healthy running of ID fans attached to the scrubbers to be provided at working level.

7. Use of antistatic ball valves to be ensured in pipelines carrying flammable solvents.

8. All flexible earth connections to be checked for continuity every 6 months.

9. Integrity of flame proof equipment to be ensured with the help of check list.

10. SOP to be developed for periodic cleaning of flame arrestor and breather valves.

Specific recommendations

1. SOP to be prepared BMR to include stirring details.

2. Training shall be provided to workers

3. Update BMR accordingly for safe working procedure.

4. Check joints for leakages

5. Ensure that charging stops at desired mass transferred in the reactor.

6. Provide emergency stop button near to the charging vessel.

7. Provide earthing to reactor and check at least once in six months

8. High pressure alarm to be installed on the reactor.

9. Design basis of SRV / rupture discs to be determined and kept on record.

10. Earthing of reactors to be ensured.

7.4 DISASTER MANAGEMENT PLAN

The Disaster Management Plan (DMP) is aimed to ensure safety of life, protection of environment, protection of installation, restoration of production and salvage operations in the

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 20 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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same order of priorities. For effective implementation of the DMP, it should be widely circulated and personnel training through rehearsals/drills should be organized. Further, the management should be able to demonstrate that its assessment of the consequences as good supporting evidence. To tackle the consequences of a major emergency inside the factory or immediate vicinity of the factory, a DMP has to be formulated and this planned emergency document is called "Disaster Management Plan".

Objectives of Disaster Management Plan [DMP] The objective of the Industrial Disaster Management Plan is to make use of the combined resources of the plant and the outside services to achieve the following:  Effect the rescue and medical treatment of causalities  Safeguard other people  Minimize damage to property and the environment  Initially contain and ultimately bring the incident under control  Identify any dead  Provide for the needs of relatives  Provide authoritative information to the news media  Secure the safe rehabilitation of affected area  Preserve relevant records and equipment for the subsequent inquiry into the cause and circumstances of the emergency. In effect, it is to optimize operational efficiency to rescue rehabilitation and render medical help and to restore normalcy.

7.4.1 Onsite Emergency Plan

The Onsite emergency plan is prepared based on the guidelines mentioned under schedule 6 of the rule 12 (1) of the Maharashtra factories (Control of industrial Major Accidents Hazards) Rules 2003. On-Site emergency preparedness plan has the following objectives:

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 21 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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1. Safeguard lives and property at site and in its vicinity area. 2. Contain the incident and bring it under control; 3. Minimize damage to lives, property and environment; 4. Rescue and treat casualties; 5. To train the people to act efficiently and with confidence in an emergency. 6. Evacuate people to safe areas; 7. To minimize its occurrence. 7.4.1.1 Name & Address of the person furnishing the Information. Name:Mr. SubhashGunjal Designation: EHS Manager Address: Plot No. B-16, 17, 18 & 21, MIDC Mahad,Mahad, Dist. - Raigad, Maharashtra 7.4.1.2 Key personnel of the organization and responsibility assigned to them in case of an emergency.

Figure No. 7.1: Key personnel of the organization and responsibility assigned

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 22 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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1) Site Main Controller During the onsite emergency situation the Site Main Controller shall,  Activate the Emergency Control Centre & personnel  Relieve the Site Incident Controller of overall responsibility during off shift hours  Take stock of situation with SIC & direct operations to control the emergency.  Ensure that all the key persons are called on site. Delegate any extra duty to any person depending upon the situation and his judgment.  Verify the head count & arrange for search / rescue  Instruct for shutting & evacuation if required.  Seek assistance from external agencies & Mutual aid  Withdraw the staff in case of the human life is in peril.  Liaison with statutory authorities  Arrange to call the experts/ the supplier.  Give All Clear siren when everything becomes normal.  Works as liaison officer between outside fire brigade & police advice on specialized technical aspects of the materials involved and internal details of the factory.  Report the event to the nearest district police station, fire brigade, civil defense force, district emergency officer, factory Inspectorate and other voluntary body to assist to the task. M/s AstecLifeSciencesLtd.has established an Emergency Control Centre at the cabin of the Site Main Controller (Factory Manager). It has external telephone, telefax and telex facility & contact number of the Incident Controller Officer, Senior Personnel etc. 2) Site Incident Controller  Assume the responsibility of the Site Main Controller till the arrival of the site main controller.  Brief the Site Main Controller on arrival - during off shift hours.

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 23 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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 Be over all in charge of the emergency situation and head of fire fighting team.  Arrive immediately to the site of emergency and issue instructions for speedy combat.  On arrival immediately assess the scale of emergency and decide if a major emergency exists or is likely.  Report head count to Site Main Controller.  Activate the security head to report the emergency to Site Main Controller.  Activate the Onsite action plan depending on the type of emergency.  Direct all operations and call the external help from emergency control center.  Search for the injured and / or casualties.  Direct the shutdown and evacuation of the plant. Identify the areas likely to be affected by the emergency.  Provide information to emergency services about the chemicals / incident.

3) EHS Team.

In addition to his general duties of maintaining order of administration he shall discharge following duties:

 Execute all directions and instruction of site main controller regarding.  Calling mutual aid members.  Specialist from the supplying company.  Lead the fire fighting & rescue operations

For efficient and successful operation of the plan statutory agencies listed below should be actively involved for guidance and help: -

 Fire Brigade  Police Authorities

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 24 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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 Collectorate / revenue officials  Directorate of Industrial Safety and Health  Maharashtra Pollution Control Board.  District Health Authorities  Non Government organization  Local News Media.  Local Leaders  Supervise the duties of Security Personnel.  Supervise rescue & medical operations  If injuries and casualties does occur then he shall obtain names and addresses of the injured and dead.  Arrange for the medical aid. Talk to the hospital and doctors. Report about the type of injury / burn injuries and or toxic effects.  Report to the hospital and make arrangement for likely more cases of injuries.  In consultation with the site main controller he shall identify the antidote or any special medical procedure and report the same to hospitals.

4) Production Manager & Team

(In affected Plant Area)

 Inform EHS Manager / Factory Manager / Plant / Dept Manager or his nominee / Site Main Controller on the telephone immediately.  Assume the role of Site Incident Controller till his arrival.  Direct employees / contractor's workers / visitors at the assembly point.  Take head count of employees.  Deploy trained Emergency Response Team & direct.

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 25 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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 Hold personnel at the Assembly point till „All Clear‟ signal is obtained.  Act as per instructions from Site Incident Controller / Site Main Controller.  Open plant drain valves to FWRB  Provide information to external agency about the chemical involved to control emergency/ treating injured employees.

(Non –affected Plant Area)  Ensure that all employees including contractor‟s workers / visitors assemble at the Assembly Point and take roll call of employees.  Take Head Count & report to SMC at ECC  Switch off all critical operations.  Be Alert for evacuation & evacuate on instructions from SMC  Keep ready - Emergency Response Team members  Provide necessary information and support to affected dept/plant to control emergency.  Hold personnel at Assembly Point till „All Clear” siren is raised

5) Security Personnel

In addition to the normal duties of maintaining security at the place of work they shall discharge following duties:

 On hearing the fire alarm, proceed to the incident immediately.  Be in charge of Fire Fighting and rescue operations with the assistance of essential workers and key personnel till the arrival of Fire Brigade and Police. (These operations shall be under the direct supervision of Site Incident Controller)  Ask the ambulance to proceed to the scene of the incident in case of serious injury.

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 26 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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 Remove obstruction from the road to help Fire brigade to proceed to the scene of fire.  Restrict entry of unauthorized and untrained persons from the scene of incident. Also don't allow unauthorized persons / vehicles to enter the premises. Control traffic movement for smooth & normal flow.  Initiate rescue operation if required.  Call for fire brigade & ambulance during off hours  Depending on seriousness arrange to inform police personnel if instructed by Factory Manager.

7.4.2 General Instructions and Response during the Onsite Emergency Situation

1. Major Fire/ Explosion

 Operate the nearest fire alarm or alert the personnel by raising an audible alarm or by shouting Fire! Fire!!”  Inform the Manager Production / Shift Supervisor available who is in charge of the factory at that time about the  Place of Fire / Explosion  Extent of Fire fighting Action taken by him  The material involved  No. of persons affected.  Try to extinguish the fire with the help of fire extinguishers, if without risk. If he is unable to extinguish the fire, he should see that the fire does not spread to nearby area.

2. Collapse of structure/ Serious Injury

 Inform the Manager Production / Supervisor etc.  Remove the injured person to a safe place. Take help of trained first-aiders.

3. Release of toxic and hazardous material

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 27 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Inform the Manager Production / Supervisor or person available who is in-charge of the factory at that time about the

 Place of Gas leak  Extent of leakage  Action taken by him  The material involved  No. of persons affected. Table No 7.7: Emergency Do’s & Don’ts EMERGENCY DO ‘S DON 'TS ANY ONE NOTICING AN EMERGENCY : DO NOT panic and avoid running all Actuate nearest fire alarm button and /or inform over the place prevent others from the supervisor. Get back to your normal doing so. workstation (if safe) or else report to the assembly DO NOT enter the site unless instructed point. if you are outside and emergency alarm is heard. CONTRACTOR PERSONNEL : DO NOT enter the site until it is cleared Stop work on hearing alarm and assemble at the for the normal work by Incident ASSEMBLY POINT and be ready to evacuate. Controller. SECURITY : DO NOT allow unauthorized visitors to Keep the gate manned. enter. Keep the road clear for movement of fire tenders. Control traffic at gates. VISITORS : DO NOT enter the site if emergency Leave the place and assemble at assembly point. alarm is heard. ALL OTHER EMPLOYEES ON SITE : DO NOT panic/run On hearing Emergency alarm DO NOT go to the scene of emergency Get back to work place (if safe) for head count unless specifically instructed by and get instructions from supervisor. Be alert. Incident Controller.

7.4.2.1 Establishment of the Safety Committee

M/s Astec LifeSciences Ltd. would be having around 160 Nos. of employees after the expansion activity. Since the company deals with the dangerous operations as mentioned in

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 28 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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the section 87 of the Factories Act 1948, it is mandatory for the company to establish a safety committee. The safety committee shall include a senior official, safety officer and representatives of workers & each department. The tenure of the safety committee would be for 2 years. The Roles and responsibility of the safety committee is listed below,

(a) Assisting and co-operating with the management in achieving the aims and objectives outlined in the 'Health and Safety Policy' of the occupier;

(b) Dealing with all matters concerning health, safety and environment and to arrive at practicable solutions to problems encountered;

(c) Creating safety awareness amongst all workers;

(d) Undertaking educational, training and promotional activities;

(e) Deliberating on reports of safety, environmental and occupational health surveys, emergency plans safety audits, risk assessment and implementation of the recommendations made in the reports;

(f) Carrying out health and safety surveys and identify causes of accidents;

(g) Looking into any complaint made on the likelihood of an imminent danger to the safety and health of the workers and suggest corrective measures; and

(h) Reviewing the implementation of the recommendations made by it.

The safety committee established for M/s AstecLifeSciences Ltd is depicted in fig. no.7.2.

7.4.2.2 Establishment of Mutual Aid Response Group

M/s Astec Life Sciences Ltd. has entered into an agreement with the neighboring factoryfor aid and assistance in the event of an emergency.

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 29 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Table7.8. List of companies under mutual aid group Sr. No. Name of Factory Contact Person Contact Number 1 Oddesy Organics Pvt. Ltd Mr.C D Deshmukh 9766614473 2 Mr. Rajesh Khandekar 9225445488 Sequent Pvt. Ltd. 02145 232722/2024 3 Vinati Organics Ltd. Mr. S Kulkarni 8237335853 4 Akzonable Ltd. Mr. A Salagre 9049008519 5 Mahad Manufacture Mr. Bhosle Nikhil 7350004115 Association Mr. Jaydeep Kale

Figure No. 7.2 Establishment of Safety Committee

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 30 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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7.4.2.3 Outside Organization Involvement in assisting during the On-site emergency.

The Outside organization that would be involved during the On-site emergency would be fire, hospital and Police authority. This authority would be contacted when the resources provided within the factory will not fulfill the requirement.

7.4.2.4 Information on the preliminary hazard analysis.

A detailed HAZOP Study for process operations & Risk Assessment have been prepared considering all possible and rare events for raw materials in the above section. Based on the study the maximum credible scenario has been identified for the particular scenario and recommendation to reduce the effect and its occurrence has been suggested/recommended.

7.4.2.5 Details about Safety related features in Plant a) Location of the Dangerous Substances

The dangerous substances are stored in a demarcated area in the plant premises. The raw materials are stored based on their compatibility with other raw materials. The raw materials whose quantities are large are stored in tanks with appropriate safety measures. The plot layout is marked with the locations of such raw materials. b) Seat of Key Personal

Table No. 7.9 List of Important Personnel

Name Designation Seat Location Contact No. Arijit Mukherjee Director Mumbai 9769937069 Arijit Mukherjee Director, Environment, Mumbai 9769937069 Health & Safety Corporate

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 31 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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KishorPawar Factory Manager Mahad 8425850027 ShaileshPadalkar Maintenance Manager Mahad 8425856115 VivekThorat Location Head Mahad 8425856107 c) Emergency Control Room

EMERGENCY CONTROL ROOM as marked on site plan will be focal point in case of an emergency, from where the operations to handle the emergency are directed and co-ordinate by Site Main Controller. The following information and equipment is provided at the Emergency Control Centre (ECC):  Intercom, telephone  P and T telephone  Safe contained breathing apparatus  Fire suit/gas tight goggles/gloves/helmets  Hand tools, wind direction/velocities indicators  Public address megaphone, hand bell, telephone directories  (Internal, P and T) factory layout, site plan  Emergency lamps/torch lights/batteries  Plan indicating locations of hazard inventories, plant control room, sources of safety equipment, work road plan, assembly points, rescue location, vulnerable zones, and escape routes  Hazard chart  Emergency shut-down procedures  Nominal roll of employees  List of key personnel, list of essential employees, list of Emergency Co-ordinators  Duties of key personnel

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 32 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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 Addresses with telephone numbers of key personnel, emergency coordinator, and essential employees.  Important addresses and telephone numbers including Government agencies, neighboring industries and sources of help, outside experts, chemical fact sheets, population details around the factory.

Description of Hazardous chemicals stored at plant site is tabulated in the below table.

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 33 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Table No: 7.10: Detailed list of Hazardous Chemicals

Common Name Molecular Sr. Physical Flash Point Boiling Melting of Raw Weight in Odor Stability No State (°C) Point (°C) Point (°C) Material g/mol Pungent. Stable 1 Bromine 159.808 Liquid. Suffocating. NA 58.78 -7.25 (Strong.) Dimethyl Amine like. 57.778 2 73.09 Liquid. 153 -61 Stable. Formamide (Slight.) Pungent. Hydrochloric Stable 3 NA Liquid. Suffocating. NA 108.58 -62.25 acid (Strong.) Solid. Sodium Stable 4 40 (Deliquescent Odorless NA 1388 323 Hydroxide solid.) Odorless, but has Liquid. (Thick Stable 5 Sulphuric Acid 98.08 a choking odor NA 270 -35 oily liquid.) when hot. Thionyl Stable 6 118.98 Liquid. Suffocating. NA 76 -104.5 Chloride

Aromatic; Ether- 7 Acetonitrile 41.05 Liquid. 2 81.6 -46 Stable like (Strong.)

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 34 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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8 Butanol 74.12 Liquid. (Z) Vinous. (Slight.) 28.9 117.7 -89.5 Stable

Pleasant. Sweetish. 9 Chloroform 119.38 Liquid. NA 61 -63.5 Stable. Etheric. Non- irritating Dichloromethan 10 84.93 Liquid. NA NA 39.75 -96.7 Stable e

Dimethyl Stable 11 -- Liquid. unpleasant odor -38 37 NA sulphide

Liquid. (Oily 12 Ethylene oxide NA Odorless. NA NA NA Stable liquid.)

13 Formaldehyde NA Liquid. NA NA 64.5 97.8 Stable

Pungent. Penetrating. 14 Formic acid NA Liquid. 69 100 8.4 Stable Benzaldehyde- like Liquid. Hydrobromic Pungent. 15 NA (Fuming NA NA NA Stable acid (Strong.) liquid.)

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 35 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Distinct, aromatic, 16 Phenol 94.11 Solid. somewhat 79 182 42 Stable sickening sweet and acrid Hay-like odor, 17 Phosgene 98.91 Gas. NA 8 -126 Stable pungent odor.

18 Diethyl Ketone 86.13 Liquid. Acetone like 13 102.7 -42 Stable

Ethereal. 19 Dioxane 88.11 Liquid. Pleasant. 12 101.1 11.8 Stable (Slight.)

20 Tetrahydrofuran 72.11 Liquid. Ethereal. Fruity. -14.5 65 -108.3 Stable

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 36 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Table No: 7.11 Threshold limits Hazardous Raw Material

Common Name Sr. Exposure Limit of Raw LEL UEL Nh Nf Nr No (TLV) Material 1 Bromine NA NA 0.1 3 0 0 Dimethyl 2 2.20% 15.20% 10 (ppm) 1 2 0 Formamide Hydrochloric 3 NA NA NA 3 0 1 acid Sodium 4 NA NA 2 (mg/m3) 3 0 2 Hydroxide 5 Sulphuric Acid NA NA 3 (mg/m3) 3 0 2 6 Thionyl Chloride NA NA 1 3 0 2 TWA: 40 (ppm) from ACGIH 7 Acetonitrile 4.4% 16% 2 3 0 (TLV) 8 Butanol 1.4% 11.2% NA 1 3 0 STEL: 2 (ppm) from NIOSH 9 Chloroform NA NA 2 0 0 Inhalation TWA: 50 from ACGIH (TLV) 10 Dichloromethane 12% 19% [United States] 2 1 0

Dimethyl 11 2.2% 9.7% NA 2 4 0 sulphide 12 Ethylene oxide NA NA NA 2 1 0 Formaldehyde gas STEL: 0.3 (ppm) from ACGIH (TLV) [United States] STEL: 0.37 13 Formaldehyde NA NA 2 0 0 (mg/m3) from ACGIH (TLV) [United States]

TWA: 5 STEL: 10 (ppm) from 14 Formic acid 18% 57% 3 2 0 ACGIH (TLV) [United States] Hydrobromic 15 NA NA NA 3 0 0 acid TWA: 5 (ppm) from ACGIH 16 Phenol 1.7% 8.6% 3 2 0 (TLV) [United States] 17 Phosgene NA NA 0.1 ppm 4 0 2

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 37 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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18 Diethyl Ketone 1.6% NA TWA: 705 (mg/m3) from OSHA 2 3 0 TWA: 72 (mg/m3) from ACGIH (TLV) [United States] TWA: 20 19 Dioxane 2% 22% 2 3 1 (ppm) from ACGIH (TLV) [United States] TWA: 590 STEL: 737 (mg/m3) 20 Tetrahydrofuran 2% 11.8% from ACGIH (TLV) [United 2 3 0 States]

Table No 7.12: Toxicological Data of the Raw Materials

Sr. Raw Material LD50 LC50 Chronic Effects on Humans No. CARCINOGENIC EFFECTS: Classified 4 (No evidence.) by NTP, None. by OSHA, None. by NIOSH. Causes damage to the 750 1 following organs: mucous 1 Bromine 2600 mg/kg hours membranes. May cause damage to the following organs: kidneys, liver, cardiovascular system, central nervous system (CNS), thyroid. CARCINOGENIC EFFECTS: 3 (Not classifiable for human.) by IARC. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Classified POSSIBLE for human. 9400 1 2 Dimethyl Formamide 2800 mg/kg DEVELOPMENTAL TOXICITY: hours Classified Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE]. Causes damage to the following organs: kidneys, liver, central nervous system (CNS). May cause damage to the following organs:

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 38 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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blood, the nervous system. CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrochloric 1108 ppm, acid]. May cause damage to the 3 Hydrochloric acid 900 mg/kg following organs: kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, Circulatory System, teeth. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the 4 Sodium Hydroxide NA NA following organs: mucous membranes, upper respiratory tract, skin, eyes CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified A2 (Suspected for 320 5 Sulphuric Acid 2140 mg/kg human.) by ACGIH. May cause mg/m3 damage to the following organs: kidneys, lungs, heart, cardiovascular system, upper respiratory tract, eyes, teeth. May cause damage to the following 6 Thionyl Chloride NA 500 organs: upper respiratory tract, skin, eyes. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [SUSPECTED]. Causes damage to the following 7551 8 7 Acetonitrile 269 mg/kg organs: blood, kidneys, lungs, liver, hours mucous membranes, gastrointestinal tract, upper respiratory tract, skin, eyes, central nervous system (CNS). May cause damage to the following organs: the reproductive system. 8 Butanol 790 mg/kg 8000 Not available

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 39 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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4 hours CARCINOGENIC EFFECTS: Classified + (Proven.) by NIOSH. Classified A3 (Proven for animal.) by ACGIH, 2B (Possible for human.) by IARC. Classified 2 36 mg/kg 47702 (Some evidence.) by NTP. 9 Chloroform [Mouse]. mg/m MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. May cause damage to the following organs: kidneys, liver, heart. CARCINOGENIC EFFECTS: Classified + (Proven.) by OSHA. Classified 2B (Possible for 52000 1 human.) by IARC. Causes damage 10 Dichloromethane 1600 mg/kg hours to the following organs: lungs, the nervous system, liver, mucous membranes, central nervous system (CNS). 3300 mg/kg 40250 11 Dimethyl sulphide NA ppm 12 Ethylene oxide 1800 mg/kg NA NA Contains material which may cause damage to the following organs: 42 mg/kg 13 Formaldehyde NA kidneys, liver, central nervous

system (CNS). MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Formic acid]. Mutagenic for Acute oral bacteria and/or yeast. [Formic toxicity (LD50): 14 Formic acid NA acid]. May cause damage to the 729 mg/kg following organs: kidneys, liver, (Mouse upper respiratory tract, skin, eyes, central nervous system (CNS). 15 Hydrobromic acid NA NA The substance is toxic to lungs,

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 40 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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mucous membranes. CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH, 3 (Not classifiable for human.) by IARC. MUTAGENIC EFFECTS: 16 Phenol 270 mg/kg NA Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. May cause damage to the following organs: kidneys, liver, central nervous system (CNS). Repeated overexposure may cause 0.084 irreversible pulmonary injury 17 Phosgene NA mg/L including bronchitis, emphysema and fibrosis. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. 18 2140 mg/kg [Rat NA The substance is toxic to the nervous Diethyl Ketone system. Mutagenic for mammalian somatic 37000 cells. May cause damage to the 19 2000 mg/kg mg/m3 2 following organs: blood, kidneys, hours liver, skin, central nervous system Dioxane (CNS). MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or 24000 yeast. May cause damage to the 20 Tetrahydrofuran 1650 mg/kg mg/m3 following organs: blood, kidneys, lungs, liver, upper respiratory tract, skin, eyes, central nervous system (CNS).

Table No 7.13: Likely Dangers to the Plant

Sr. Accident Scenario Causes Consequence Zone No.

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 41 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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1. Spill Hose failure during road tanker Local unloading to storage tank at tank farm. Spill of - Acetonitrile, Butanol, Dimethyl sulphide, etc 2. Large spill Failure of bottom valve Catastrophic Local failure of storage tank 3. Pressure development Pressure development , Local Uncontrolled reaction exothermic 4. Fire Any spill of flammable chemical, Local e.g. solvent spill finding source catching fire on finding of ignition source. 5. Electric fire At transformer area Local 6. Release of failure of the Storage tank Lead to an off-site Toxic / flammable consequences Vapors 7. Fall of structure Earthquake , poor maintenance Local

7.4.3 Details of Safety Systems in the Plant Premises

The below section will explain about the safety features & measures adopted by M/s AstecLifeSciencesLtd.for dealing with the onsite emergency situation.

A) Alarm / Siren

There are totally 4 nos. of hooters located in the plant premises. Every Saturday at 1130 hours by giving an “All Clear” siren will be sounded for testing purpose. Emergency Alarm annountiator panel is located at gate office building as marked on the site plan.

On hearing alarm the incident controller will activate the action on Disaster control plan by giving proper instructions or predetermined signals the alarm code used in the company is explained below,

Table No: 7.14 Alarm Code

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 42 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Sr. No Situation Type of Siren/Alarm 1. Emergency at Site One Minute waxing and wailing siren 2. All Clear One Minute continuous siren 3. Evacuation Three minutes waxing and wailing siren

B) Assembly Points

Numbers of assemblies depending upon the plant location are identified wherein employees who are not directly connected with the disaster management would be assembled for safety and rescue. Emergency breathing apparatus, minimum facilities like water etc. would be organized. In view of the size of plant, different locations are earmarked as assembly points. Two assembly points are identified by the company i.e. one near the main gate of the company and other one is located near the guest house of the company. Depending upon the location of hazard, the assembly points are to be used.

C) Mock Drills The company organizes periodical mock drill / rehearsal every 6 months as per suggested format by creating an emergency situation so as to verify preparedness and awareness as well as shortcomings on the part of the person to overcome the same. Sufficient time is provided prior to mock drill to the emergency services and public for proper response to exercise and provide training also. Record the deficiencies of the system during the trial and take appropriate actions to improve the efficiency of the plan in terms of preparedness and response.

D) Training

By imparting an effective training from time to time, the awareness is being kept alive all the time to ensure safety awareness, preparedness for emergency situations, good housekeeping, discipline, etc. Display of safety slogans, operative instructions and motivation for safety

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 43 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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should is made the part of the company‟s normal activities. All the persons earmarked for the emergency services are trained to respond to the emergency. The company conducts internal & external training for Environment Health & safety. The training is conducted at a documented frequency. The external training is conducted six monthly and internal training is conducted every month.

Training is imparted to the employees by raising siren in specific pattern. Employees are given training of escape routes, taking shelter, protecting from toxic effects. Employees are provided with information related to fire hazards and first aid measures.

E) Emergency Power Supply Plant facilities would be connected to Generator and is placed in an auto mode. Thus, water pumps, plant‟s lighting and emergency control centre, administrative building and other auxiliary services are connected to emergency power supply. In all the blocks, flameproof type emergency lamps are provided.

F) Wind Sock Wind sock is provided in the company. The workers are trained in the mock drill regarding the usage of the wind sock for identifying the directions for taking shelter or identifying the area of high toxicity in case of emergency.

G) Communication facilities available during Onsite emergency

Table No: 7.15 Communication facilities available during Onsite emergency

Name Designation Seat Location Contact No. Arijit Mukherjee Director Mumbai 9769937069

Arijit Mukherjee Director, Environment, Mumbai 9769937069 Health & Safety Corporate

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 44 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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KishorPawar Factory Manager Mahad 8425850027 ShaileshPadalkar Maintenance Manager Mahad 8425856115 VivekThorat Location Head Mahad 8425856107

H) Fire Fighting Facilities Firefighting equipment suitable for emergency are maintained well in each section in the plant. This would be developed according to the statutory requirements. However, fire hydrant line covering major areas has been laid. Fire alarms have been located in the bulk storage areas. The below details highlights the fire fighting facilities at site. Table No: 7.16 Fire Fighting Tank Details

Fire Fighting Tank Details Capacity of Fire Fighting tanks 300 m3 Type of tank Overhead/ Below Below Head head

Material of Construction RCC Pump Capacity of fire fighting Jockey : 10.8 m3/hr tank Electrical pump : 171 m3/hr

Diesel operated pump : 171 m3/hr

No of assembly points 2 No of exit points for emergency 2 evacuation Fire Hydrant system Provided No of fire hydrant points in the 27 premises

7.4.4 List of Existing fire extinguishers & fire buckets provided

Table No: 7.17 List of Existing fire extinguishers & fire buckets provided

Sr. Extinguisher Capac Existing Quantity Location Type No. No. ity /Proposed (Numbers) 1 47 R & D DCP 5 Kg Existing 1

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 45 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Near R & D Existing 1 2 46 DCP 5 Kg Entrance 3 35 B-17 Gr. Floor DCP 10 Kg Existing 1 4 36 B-17 Gr. Floor DCP 10 Kg Existing 1 5 48 B-17 Gr. Floor CO2 4.5 Kg Existing 1 6 49 B-17 Gr. Floor DCP 10 Kg Existing 1 7 58 B-17 Gr. Floor MF 50 Kg Existing 1 8 40 B-17 1st Floor DCP 5 Kg Existing 1 9 50 B-17 1st Floor MF 10 Kg Existing 1 10 59 B-17 1st Floor CO2 3.2 Kg Existing 1 11 57 B-17 1st Floor DCP 5 Kg Existing 1 12 41 B-17 2nd Floor DCP 10 Kg Existing 1 13 42 B-17 2nd Floor DCP 5 Kg Existing 1 14 51 B-17 2nd Floor DCP 10 Kg Existing 1 15 60 B-17 2nd Floor CO2 2 Kg Existing 1 16 43 B-17 3rd Floor DCP 5 Kg Existing 1 17 44 B-17 3rd Floor DCP 10 Kg Existing 1 18 45 B-17 3rd Floor DCP 10 Kg Existing 1 19 61 B-17 3rd Floor CO2 3.2 Kg Existing 1 B-17 Utility PCC Existing 1 20 23 CO2 4.5 Kg room B-17 Utility PCC Existing 1 21 56 CO2 3.2 Kg room B-17 Utility PCC Existing 1 22 52 DCP 5 Kg room 23 28 B-17 Solvent storage DCP 10 Kg Existing 1 24 62 B-17 Solvent storage MF 50 Kg Existing 1 25 29 B-17 Solvent storage DCP 10 Kg Existing 1 26 54 B-17 Fab. Work ABC 6 Kg Existing 1

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 46 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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shop 27 11 B-17 Engg. Stores ABC 6 Kg Existing 1 Chlorine Storage Existing 1 28 27 DCP 10 Kg shed 29 31 BTD Storage shed DCP 10 Kg Existing 1 30 32 BTD Storage shed DCP 10 Kg Existing 1 31 33 B-17 RM Stores DCP 10 Kg Existing 1 32 34 B-17 RM Stores DCP 10 Kg Existing 1 33 24 B-17 RM Stores CO2 4.5 Kg Existing 1 34 25 B-17 RM Stores CO2 4.5 Kg Existing 1 35 2 SC Plant ABC 6 Kg Existing 1 36 22 SC Plant MF 6 Kg Existing 1 37 1 B-17 gate ABC 6 Kg Existing 1 38 16 Admin. Office ABC 6 Kg Existing 1 39 14 Admin. Office ABC 6 Kg Existing 1 40 7 B-16 gate ABC 6 Kg Existing 1 41 63 QC Lab CO2 4.5 Kg Existing 1 42 20 B-16 RM stores DCP 5 Kg Existing 1 43 37 B-16 RM stores MF 6 Kg Existing 1 44 53 B-16 Fab. Workshop ABC 6 Kg Existing 1 45 6 B-16 Fab. Workshop ABC 6 Kg Existing 1 46 64 B-16 MCC room CO2 4.5 Kg Existing 1 47 12 B-16 Utility room ABC 6 Kg Existing 1 48 13 B-16 Utility room ABC 6 Kg Existing 1 49 39 B-16 Plant Gr. Floor DCP 10 Kg Existing 1 50 65 B-16 Plant Gr. Floor MF 6 Kg Existing 1 51 15 B-16 Plant 1st Floor ABC 6 Kg Existing 1

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 47 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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52 17 B-16 Plant 1st Floor ABC 6 Kg Existing 1 53 19 B-16 Plant 2nd Floor ABC 6 Kg Existing 1 54 3 BRL Plant Gr. Floor ABC 6 Kg Existing 1 55 18 BRL Plant Gr. Floor ABC 6 Kg Existing 1 56 5 BRL Plant 1st Floor ABC 6 Kg Existing 1 57 4 BRL Plant 1st Floor ABC 6 Kg Existing 1 58 8 BRL Plant 2nd Floor ABC 6 Kg Existing 1 59 9 BRL Plant 2nd Floor ABC 6 Kg Existing 1 60 55 BRL Plant 3rd Floor ABC 6 Kg Existing 1 61 10 BRL Plant 3rd Floor DCP 5 Kg Existing 1 62 26 ETP MCC room CO2 2 Kg Existing 1 63 21 ETP Lab MF 6 Kg Existing 1 Bromine Plant Existing 1 64 30 DCP 10 Kg Gr.Floor 65 38 MEE Plant 1st Floor DCP 10 Kg Existing 1 Spare ETP Lab(SP- Existing 1 66 66 MF 6 Ltr 01) Spare ETP Lab(SP- Existing 1 67 67 MF 6 Ltr 02) Spare ETP Lab(SP- Existing 1 68 68 MF 6 Ltr 03) Spare ETP Lab(SP- Existing 1 69 69 CO2 2 Kg 04) Spare ETP Lab(SP- Existing 1 70 70 CO2 2 Kg 05) 71 71 RM store Gr.Floor DCP 50 Kg Existing 1 72 72 RM store Gr.Floor DCP 50 Kg Existing 1 Walk way near RM Existing 1 73 73 DCP 9 Kg store Walk way near RM Existing 1 74 74 CO2 4.5 Kg store

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 48 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Tank farm near SC Existing 1 75 75 DCP 9 Kg plant North Side of RM Existing 1 76 76 DCP 9 Kg Store New Utility – Front Existing 1 77 77 DCP 9 Kg side New Utility – Front Existing 1 78 78 CO2 4.5 Kg side 79 79 New Utility – In side DCP 9 Kg Existing 1 80 80 New Utility – In side CO2 4.5 Kg Existing 1 81 81 B-24 Fab. Workshop DCP 9 Kg Existing 1 B-24 Store Front Existing 1 82 82 CO2 4.5 Kg side 83 83 B-24 Store In Side DCP 9 Kg Existing 1 84 84 B-24 Store In Side DCP 9 Kg Existing 1 B-24 Inside Ware Existing 1 85 85 DCP 9 Kg house 86 86 B-24 Security Cabin DCP 9 Kg Existing 1 87 87 Server Room CO2 4.5 Kg Existing 1 88 88 Spare DCP 9 Kg Existing 1

7.4.5 Location of Existing Fire Hydrants Table No: 7.18 Locations of Existing Fire Hydrants

Sr. Fire hydrant No. Location Existing / Proposed No. 1 SP-1 Service Point (4 Nos.) Existing 2 DH-1 Front of U/G Solvent yard Existing 3 SH-1 West side of Engg. Stores Existing 4 SH-2 North side of FG warehouse Existing 5 SH-3 N/W entrance of FG Existing

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 49 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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warehouse S/W entrance of FG Existing 6 SH-4 warehouse 7 SH-5 East side of B-17 Utility Existing 8 SH-6 North side of SC Plant Existing 9 DH-2 South side of FG warehouse Existing 10 SH-7 West side of B-17 Utility Existing 11 SH-8 West entrance of B-17 Plant Existing 12 SH-9 South side of B-17 Plant Existing 13 SH-10 S/E side of Q.C. (B-16) Existing 14 SH-11 S/E side of BRL Plant Existing 1st Floor - B-17 Plant Existing 15 FEH-1 (West) 16 FEH-2 1st Floor - B-17 Plant (East) Existing 2nd Floor - B-17 Plant Existing 17 FEH-3 (West) 2nd Floor - B-17 Plant Existing 18 FEH-4 (East) 3rd Floor - B-17 Plant Existing 19 FEH-5 (West) 20 FEH-6 3rd Floor - B-17 Plant (East) Existing 1st Floor - B-16 Plant Existing 21 FEH-7 (West) 2nd Floor - B-16 Plant Existing 22 FEH-8 (East) 23 FEH-9 1st Floor - BRL Plant (East) Existing 24 FEH-10 2nd Floor - BRL Plant (East) Existing 25 FEH-11 3rd Floor - BRL Plant (East) Existing 26 SH -12 RM Store inside Existing

7.4.6Type and no. of protective and rescue equipment on site

Table No.7.19 Type of protective & rescue equipment

Sr. No. Type No Location

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 50 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 7: Additional Studies

1 Self Contained Breathing 01 Security Cabin Apparatus Set

7.4.7 Fire Water Tank Justification

A) The amount of water required for firefighting purpose can be estimated by the below formula:

Water required in liters per minutes = (A + B +C + D)/20

A) The total area in sq.mtr of all Floors including galleries in all building of the Factory

B) The total area in sq.mtr of all Floors and galleries including open spaces in which combustible materials

C) The total area in sq.mtr of all Floors over 15 m above ground level

D) The total area in sq.mtr of all floors of buildings other than those of fire resisting construction of various floors is so certified by any fire association or fire insurance company

Water required in liters per minutes = (2272 +505 + 1097+ 61.15)/20

= 196.73 lit/min

= 0.197 m3/min

The quantity of firefighting tank is 300 m3. Therefore the capacity is justified. As the back-up water supply will last for 25 hours.

Time (min) = [Total water in firefighting tank (m3)]/water required m3/min

= 300/0.197

= 25.42Hrs.

The pump capacity in the plant is 171m3/hr, therefore according to the discharge capacity of the pump installed. The back-up time by which the tank will be empty is calculated below,

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 51 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Time (min) = [Total water in firefighting tank (m3)]/discharge capacity (m3/hr)

= 300/171

= 1.75hours

7.4.8 Medical Facilities The total number of employees in M/s AstecLifeSciences Ltd. after expansion would be around 160 Nos. According to the Factories Act 1948 & Maharashtra Factories Rules, 1963 an Occupational Health Center of 15 sq. m. should be provided in which a part time factory medical officer shall visit the factory at least twice in a week. Also one qualified person on First Aid measures will be on duty. First aid box will be provided in every department of the company. At present there are four first aid box located as per the above table with 10 people trained in using it. Out of which two persons are always on site. Necessary specific medicines for emergency treatment of burns patients and for those affected by toxicity would be maintained. Breathing apparatus and other emergency medical equipment would be provided and maintained in the OHC. Private medical practitioners & government hospital would be approached in case of emergency & short supply in the plant. Names of medical personnel and medical facilities in the surrounding area would be prepared and updated which can be identified in the security office and emergency control center. The help of nearby industrial managements would be taken under mutual aid response group agreement if required.

7.4.8.1 Location of Existing First Aid Kit in the Plant Premises

Table No.7.20 First Aid Kit Location No. Of first aid Existing /proposed Sr.no. First aid kit location kits 1 1 OHC Existing 2 1 B-17 Gate Existing 3 1 Administration Existing

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 52 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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4 1 B-17 Plant Existing

Interpretation Keeping in view the nature of the emergency, two levels of co-ordination are proposed. In the case of an On Site Emergency, resources within the organization would be mobilized as explained in the above section and in the event of an extreme emergency; local authorities‟ help would be sought. In the event of an emergency developing into an offsite emergency, local authority and District Emergency Authority (normally the Collector) would be appraised and under his supervision, the Off Site Disaster Management Plan would be exercised. The detailed risk analysis has indicated that the toxic effects would be felt outside the factory. Hence it is suggested that in case of such an emergency event people (outside the company) are advised to stay indoors, complete evacuation is not recommended. For this purpose, the offsite emergency plan has been highlighted in the below section, for the facilities that are available locally, i.e. medical, transport, personnel, rescue accommodation, voluntary organizations etc. would be mustered. Necessary rehearsals and training in the form of mock drills should be organized in consultation with the district emergency authority.

7.5 Off-Site Emergency Preparedness Plan

The off-site plan will be prepared with the help of the local district authorities. The proposed plan will be based on the following guidelines.

7.5.1 Introduction Off-site emergency plan follows the on-site emergency plan. When the consequences of an emergency situation go beyond the plant boundaries, it becomes an off-site emergency. Off- site emergency is essentially the responsibility of the public administration. However, the

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 53 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 7: Additional Studies

factory management will provide the public administration with the technical information relating to the nature, quantum and probable consequences on the neighboring population. The off-site plan in detail will be based on those events, which are most likely to occur, but other less likely events, which have severe consequence, will also be considered. Incidents, which have very severe consequences yet have a small probability of occurrence, should also be considered during the preparation of the plan. However, the key feature of a good off-site emergency plan is flexibility in its application to emergencies other than those specifically included in the formation of the plan. The roles of the various parties who will be involved in the implementation of an off-site plan are described below. Depending on local arrangements, the responsibility for the off-site plan should either rest with the works management or, with the local authority. Either way, the plan should identify an emergency coordinating officer, who would take the overall command of the off-site activities. As with the on-site plan, an emergency control centre should be set up with whom the emergency coordinating officer & emergency planning officer can operate. An early decision will be required in many cases on the advice to be given to people living "within range" of the accident; in particular, whether they should be evacuated or told to go indoor. In the latter case, the decision can regularly be reviewed in the event of an escalation of the incident. Consideration of evacuation may include the following factors:  In the case of a major fire but without explosion risk (e.g. an oil storage tank), only houses close to the fire are likely to need evacuation, although a severe smoke hazard may require this to be reviewed periodically  If a fire is escalating and in turn threatening a store of hazardous material, it might be necessary to evacuate people nearby, but only if there is time; if insufficient time exists, people should be advised to stay indoors and shield themselves from the fire For release or potential release of toxic materials, limited evacuation may be

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 54 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 7: Additional Studies

appropriate downwind if there is time. The decision would depend partly on the type of housing "at risk". Conventional housing of solid construction with windows closed offers substantial protection from the effects of a toxic cloud, while shanty house, which can exist close to factories, offers little or no protection.

Site Controller

Emergency Co-ordinating Emergency Planning Chief Officer Officer Inspector Appointed by District Authority Appointed by Local Authority Appointed by State Gov.Authority

General Fire Heath Police State Pollution Public Authority Authority Authority Control Board

Figure No7.3:Emergency Offsite Emergency Plan Plan 7.5.2 Role of the Chief Inspector Chief Inspectors are likely to want to satisfy themselves that the organization responsible for producing the off-site plan has made adequate arrangements for handling emergencies of all types including major emergencies. Chief Inspector may verify the documented procedures and evidence of exercise undertaken to test the onsite & offsite plan. The copy of the information furnished to the workers, local authority, general public & District Emergency Authority is submitted to the Chief Inspector for review. If the Chief Inspector is not satisfied

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 55 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 7: Additional Studies

with thecontent, he may direct the occupier to supply further information to the workers, authority, general public & District Emergency Authority as deemed necessary.

7.5.3 Role of the Emergency Coordinating Officer The various emergency services will be coordinated by an emergency coordinating officer (ECO), who is designated by the District Collector. The ECO will liaise closely with the Site Controller. Again, depending on local arrangements, for very severe incidents with major or prolonged off-site consequences, the external control should be passed on to a Emergency Planning Officer of the local authority administrator.

7.5.4 Role of the Local Authority The company will enter into an agreement with the Emergency Planning Officer (EPO) of the area, within whose jurisdiction the factory is situated for the Emergency officer to take appropriate steps to inform the general public outside the factory who likely to be affected by an accident. The information in the prescribed format would be shared with the EPO by the site controller. The duty to prepare the off-site plan lies with the local authorities. The Emergency Planning Officer (EPO) appointed should carry out his duty in preparing for a whole range of different emergencies within the local authority area. The EPO should liase with the site controller for ensuring that the plan is continually updated. It is the responsibility of the EPO to ensure that all those organizations, which will be involved off site in, handling the emergency, know of their role and are able to accept it by having for example, sufficient staff and appropriate equipment to cover their particular responsibilities. Rehearsals for off-site plans are organized by the EPO.

7.5.5 Role of Fire Authorities The control of a fire should normally be the responsibility of the senior fire brigade officer who would take over the handling of the fire from the site incident controller on arrival at the site. The senior fire brigade officer should also have a similar responsibility for other events,

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 56 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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such as explosions and toxic release. Fire authorities in the region should be apprised about the location of all stores of flammable materials, water and foam supply points, and fire- fighting equipment. They should be involved in on-site emergency rehearsals both as participants and, on occasion, as observers of exercises involving on-site personnel.

7.5.6 Role of Health Authorities Health authorities, including doctors, surgeons, hospitals, ambulances, and similar other persons/institutions should have a vital part to play following a major accident, and they should form an integral part of the emergency plan. For major fires, injuries should be the result of the effects of thermal radiation to a varying degree, and the knowledge and experience to handle this in all but extreme cases may be generally available in most hospitals. For major toxic releases, the effects vary according to the chemical in question, and the health authorities should be apprised about the likely toxic releases from the plant, which will enable them to deal with the aftermath of a toxic release with treatment appropriate to such casualties. Major off-site incidents are likely to require medical equipment and facilities inadditional to those available locally, and a medical "mutual aid" scheme shouldexist to enable the assistance of neighboring authorities to be obtained in theevent of an emergency. 7.5.7 Role of Police Authority Formal duties of the police during an emergency include protecting life and property and controlling traffic movements. Their functions should include controlling bystanders, evacuating the public, identifying the dead and dealing with casualties, and informing relatives of dead or injured. 7.5.8 Role of Pollution Control Board On receipt of information officer of the pollution control board shall proceed to the affected site. Conduct investigation including collection of data. Ensure that the spills have been contained with no further damage possible to humans and environment. Further to declare the area fit for re-entry after the decontamination is completed. In case of an environmental

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 57 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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disaster, the pollution control board shall, based on the contaminant released in to the environment, carry out with the help of the industry and other agencies, such investigations as may be necessary to establish the degree of contamination. Arrange for suitable decontamination using resources available in the area as well as with the board.

7.5.9 External agencies contact details involved during emergency Table No. 7.21 External agencies contact details involved during emergency Sr.No. Name of Person /Authority Telephone Nos. Distance (km) 1 Police Station MIDC 02145 233010 3 2 Nearest Fire Brigade 02145 232405 0.5 3 Fire Brigade, Mahad 02145 222116 9 4 Nearest Ambulance services 102 / 02145232405 0.5 5 Regional MIDC Office 02145 232294 3 6 Regional MPCB Office 02145 232372 3 7 Regional Factory Inspector 022 27578587 150 8 MSEB Office 02145 222136/46 1 9 CETP, MIDC 073500 04771 2 Hospitals 10 Hospital (MMA) 02145 222093 2.5 11 Deshmukh N. Home 02145 223086 / 225816 10 12 Primary Health Centre, Birwadi 02145 250265 2 13 Primary Health Centre, Mahad 02145 223047 8

Sadekar Enviro Engineers Pvt. Ltd. Chapter 7- 58 Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 8: Project Benefits

8.0 CHAPTER 8: PROJECT BENEFITS

M/s. Astec LifeSciences Ltd. proposes expansion of existing manufacturing unit located at Plot No B-16, 17, 18 & 21, MIDC Mahad, District Raigad, Maharashtra. India. The proposed expansion project will be beneficial to the surrounding area/communities in terms of employment generation, social development & other indirect benefits. This expansion project will also help to reduce the demand & supply gap of pesticides thus ultimately result in to tap the demand-supply in local as well as international market.

It is anticipated that the proposed expansion activity will provide benefits to locals during both construction & operational phase thereby helping in better socio-economic aspects in the vicinity of the project.

8.1 Overall benefits of the project can be summarized as follows:

1) The plant is located in Notified Industrial Area & the proposed activity being executed with the existing premises, no human displacement or habitat loss is envisaged.

2) Improvement in locale specific socio-economic aspects.

3) Under CER activities the company will focus on locale specific aspects such as education & skill development, health awareness, water, sanitation and various other social activities.

Education & Skill development:

 Provisions of uniform, books and stationary, necessary equipments etc, to the schools of nearby areas.  Conduction of trainings for youth & women empowerment. Health Awareness:  Organize free medical checkup camp for the villagers  Health Awareness campaigns will be organized.

Sadekar Enviro Engineers Pvt. Ltd. Chapter 8- 1

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 8: Project Benefits

4) The project will also contribute in increase in revenue in form of various taxes which will be paid to government time to time. Company will also export their products to other country that also can be benefitted to the country by increase in excise and vat revenues.

5) The CER activities planned by company can be considerably very beneficial for health, education, development of poor people, welfare of women & labor and support to disabled persons etc.

Thus a significant benefit to the socio-economic environment is likely to be created due to the expansion project and the project will help in developing the national income.

Sadekar Enviro Engineers Pvt. Ltd. Chapter 8- 2

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 9: Environmental Cost Benefit Analysis

CHAPTER 9: ENVIRONMENTAL COST BENEFIT ANALYSIS

The proposed project falls under the schedule 5 (b), category ‘A’ as per the EIA Notification, 2006. The application for approval of ToR was submitted to MoEF&CC on MoEF&CC portal dated 23rd December 2017. The environmental cost benefit analysis was not made mandatory in the project specific terms of references accorded to M/s Astec LifeSciences Ltd. by the Expert Appraisal Committee – MoEF&CC

Also the Standard Terms of References published by the MOEF & CC on April 2015 does not include the environmental cost benefit analysis in the general & specific TOR prescribed for pesticide industry which falls under schedule 5 (b).

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 10: Environmental Management Plan

CHAPTER 10: ENVIRONMENTAL MANAGEMENT PLAN 10.1 Introduction Every industrial development is associated with the positive and negative impacts on environmental components.Thoughthe probable negative impacts cannot be nullified completely the much required developmental activities cannot be impeded. Environmental Impact Assessment helps in identifying potentially environmental impacts of a proposed project activity. Based on the finding of the impact assessment, Environment Management Plan is devised to minimize the adverse impacts and enumerate various steps to be taken for improvement of the environment. Environmental Management Plan helps in formulation, implementation and monitoring of environmental parameters during & commissioning of project. Environment Management Plan (EMP) is the tool to ensure a safe and clean environment. A project may have identified proper mitigation measures but without a management plan to execute it, the desired results may not be obtained. The Environment Management Plan envisages proper implementation of mitigation measures to reduce the adverse impacts arising out of the project activities. Some of the major objectives of the EMP are:  Ensure the project implementation with minimal impacts on all environmental components  Minimize the impacts on socio- economic indicators of local and adjoining regions  Maintain the highest level of readiness for meeting the needs of any deviation in sustainability practices  Systematic implementation with adequate manpower, budget and action plan for EMP  To demonstrate the effectiveness of EMP workability along with the project proponent’s commitment.

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 10: Environmental Management Plan

10.2 Organizational structure for environment management

Figure No. 10.1: Schematic representation of organizational structure of Astec LifeSciences Ltd., Mahad for environment management

10.3 Budget for environmental management/environmental pollution control measures The proposed capital investment of the company for expansion activity is envisaged to be 10.17Crore and the proposed capital investment for Environmental Pollution Control Measures is around 60 Lakh and 25.10 Lakh as recurring/operating cost per annum. The cost details for Environmental Management are as below:

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Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Chapter 10: Environmental Management Plan

Table No.10.1: Cost details for environmental management Sr.No. Particulars Capital Cost Recurring Cost (Rs.) per annum (Rs.) 1 Air Pollution Control 32,00,000.00 1,13,000.00

2 Water Pollution Control 13,00,000.00 2,50,000.00

3 Noise Pollution Control 2,00,000.00 47,000.00

4 Environment Monitoring and -- 15,00,000.00 Management 5 Occupational Health 4,00,000.00 1,00,000.00

6 Green Belt 6,00,000.00 3,50,000.00

7 Solid Waste Management 3,00,000.00 1,50,000.00

Total (Rs.) 60,00,000.00 25,10,000.00

10.4 Details of EMP budgetary allocation

The proposed budgetary allocation has been made with a view to install new pollution control devices & management of overall environment during the operational phase the basis and estimated costing of the EMP budget is as depicted in the following table.

Sadekar Enviro Engineers Pvt. Ltd. Chapter 10- 3

Environmental Impact Assessment Report for Expansion of Pesticide Manufacturing and Formulation unit of M/s Astec LifeSciences Ltd., Plot no. B-16, 17, 18, & 21, MIDC, Mahad, Raigad, Maharashtra.

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Table No.10.2: Justification of EMP budgetary allocation Estimated Budgetary Budgetary Sr. Cost Allocation Allocation Component Particulars No. Capital Recurring Investment Expenditure New stack of 39.0 m height for 15 TPH boiler, new common 1 Air 29,00,000.00 32,00,000.00 1,13,000.00 stack of 27 m for TFH’s of 6 & 2 lakh kilo.cal./hr. Installation of two 2 Water psychrometric evaporators of 11,00,000.00 13,00,000.00 2,50,000.00 500 TR each Providing PPE’s for existing employees such as Glares, Occupational Breathing Masks, Gloves, Boots, 3 3,50,000.00 4,00,000.00 1,00,000.00 Health Helmets, Ear Plugs etc. & annual health-medical checkup of workers Installation of anti-vibration pads & Construction of 4 Noise 1,60,000.00 2,00,000.00 47,000.00 enclosures for new DG set & Boiler Concrete paving of hazardous waste storage area,purchase of Solid Waste 5 additional containers/bags for 2,50,000.00 3,00,000.00 1,50,000.00 Management storage of hazardous & non - hazardous solid waste Green belt development & 6 Green Belt 5,90,015.00 6,00,000.00 3,50,000.00 maintenance Quarterly Environment Monitoring Environment Ambient Air PM10, PM2.5, Monitoring 7 Monitoring SO2, NOx, CO -- -- 15,00,000.00 & Management Work place air VOCs & monitoring Fugitive Emissions

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Boilers, THFs TPM, SO2, & DG Sets NOx stack monitoring Effluent pH, COD, (Treated & BOD, TSS, Untreated) TDS, Oil & Grease 53,10,000.00 60,00,000.00 25,10,000.00 Total (Rs.)

10.5 Details of environmental mitigation measures The probable impacts identified & the mitigation measures envisaged for protection of Environmental Components during the operational phase are as tabulated in the table below.

Table No.10.3: Overview of probable environmental pollution & mitigation measures during operational phase Operational Phase

Sr.No Environmental Aspect Anticipated Impacts Proposed Mitigation . Parameters Attributes Measures 1. Air Quality Operation of The Maximum To ensure proper Boilers, Thermic Incremental dispersion of flue gases in fluid heaters, concentration of atmosphere, provision of 3 D.G sets and PM10 -2.22821ug/m stacks of following height 3 Gaseous SO2 -4.63488 ug/m as per CPCB guidelines: emission from NOx- 1.70747 ug/m3 manufacturing CO - 29.3269ug/m3 1. Stack No. 1 : 30 m process, Non Stack for 6 TPH boiler spontaneous The Health effects emissions from related to particulate 2. Stack No. 2 : 24m transportation of matter are majorly stack for 850 kg/hr boiler raw materials & respiratory, finished goods. pulmonary injury 3. Stack No. 3 : 39 m

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VOC emission &lung cancer etc. stack for 15 TPH boiler generated due to Exposure to SO2 and the handling and NOx majorly leads to 4. Stack No.4: 27 m storage of the respiratory problems. common stack for TFH’s solvents & other Carbon monoxide of 6 & 2 lackhkilo.cal./hr. raw materials. decreases the oxygen carrying capacity of 5. Stack No. 5 : 3.5 m the blood by reducing stack above roof for D.G the hemoglobin. The of 250 kVA health effects related to VOC emission are 6. Stack No. 6 : 4.5 m eye, nose and throat stack above roof for D.G irritation headaches, of 500 kVA loss of coordination and nausea, damage to 7. Stack No.7: 5.0 m liver, kidney and stack above roof for central nervous process scrubber. system etc. Exposures to high 8. Roads within plot concentrations of premises will be ammonia in air may concreted / paved to cause immediate avoid the dust generation burning of nose, from day to day vehicular throat & respiratory activity. tract which may cause bronchiolar and 9. It will be ensured that alveolar edema and all the vehicles used for airway destruction transportation activity resulting in have a valid PUC respiratory disease or (Pollution under Control) failure. Inhalation of Certificate. lower concentrations can cause coughing 10. Proper servicing & and nose and throat maintenance of vehicles infection. is carried out. Same practice will be continued The air emissions in in future. long course of time

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may affect the 11. Regular sweeping of vegetation stature all the roads & floors is physically (leaf being /will be done. senescence, hampered growth etc.)& 12. Development of the biologically in green belt along the plant downwind direction boundary will help to which may result in capture the fugitive affecting overall emission. ecology of the region in consideration. 13. To control VOC emission carbon adsorption system can be implemented.

14. Industry to ensure that at no point of time the air emission concentrations does not exceed the prescribe standards. 2. Noise Quality Operation of The impacts of high 1. Acoustic enclosure will D.G sets, noise level can be be provided to D.G set for Boilers, Thermic Temporary/Permanent attenuation of noise level fluid heaters, hearing loss, during operation. Reactors, Mental disturbance 2. Boiler and Thermic ancillary utilities Increase in heart rate, fluid heaterwillbe placed & transportation Decrease in workers in a confined space viz. activity. performance due to boiler house where the psychiatric disorder, surrounding walls acts as Workers developing a barrier for noise Tinnitus due to high propagation. level of noise 3. Isolation of high exposure on regular intensity noise generating basis. equipment’s. 4. Appropriate traffic management to be implemented. 5. Green belt developed

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around the plot boundary will help to minimize the noise intensity propagating outside factory premises. 6. Appropriate PPEs should be provided to workers. 3. Water Quality 1. Effluent from Unscientific/accidenta LCOD-LTDS effluent manufacturing l release/discharge of comprising of domestic process. effluents if finds its 2. Effluent from way to surrounding sewage & process Scrubber soils,surface/groundw effluent to the tune of operations. atermay lead to 3. Blow down contamination of the 51.3 CMD will be treated water from same there by in existing ETP 55 CMD Boiler and affecting the overall Cooling Tower. ecology & agricultural capacity comprising of 4.Domestic productivity of the primary, secondary & wastewater. area concerned. tertiary treatment scheme, permitted quantity of treated effluent will be sent to CETP for further treatment & disposal and remaining effluent will be recycled.

1.0 2. HCOD-HTDS effluent from manufacturing process will be subjected

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in plant stripper evaporator & condensate will be reused.

3. Cooling tower & boiler blow down will be reused for cooling tower operations.

4. Thus except for the consented treated effluent discharge quantity the additional treated effluent generated from the project activity will be reused.

Thus it will be ensured there will be no unscientific /accidental release/discharge of effluentsoutside the project premises. 4. Solid Waste 1. Used/ spent Unscientific handling 1. Hazardous Management - oil. may affect the health wastesgenerated from the Hazardous of workers coming in process such asResidues Waste 2. Residues & direct contact with the & Waste, Chemical Waste hazardous waste and sludge residue from

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may lead to skin pesticides, Asbestos 3.Chemical allergies/rashes/burns gaskets and Spent sludge residue etc.andindiscriminate/ Carbonwill be disposed to from pesticides accidental disposal of Mumbai Waste hazardous waste if Management - 4.Discarded finds its way to CHWTSDF, Taloja. containers surrounding soils, surface/groundwaterm 2. Hazardous wastes 5.Chemical ay lead to generated from effluent sludge from ETP contamination of the treatment process such as same there by Chemical sludge from 6. Filter & filter affecting the overall material having ecology & agricultural ETP will be disposed to organic liquid productivity. Mumbai Waste Management - 7. Spent carbon CHWTSDF, Taloja.

8. Asbestos 3. Filter & filter material gaskets having organic liquid, will be disposed to 9. Spent Mumbai Waste Solvents Management -

CHWTSDF, Taloja. 4. Hazardous wastes such as Used/ spent oil, Discarded containers, Spent Solvents will be reused/recycled/sold to Authorized Parties or will be disposed to Mumbai Waste Management - CHWTSDF, Taloja. Solid Waste 1. Paper waste 1.Hap-Hazard Designated area for Scrap Management - (paper boxes and handling & storage materials will be provided Non Hazardous bags). may lead to in the plant. waste 2. Plastic waste. inadequate open space Scrap materials will be

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3. Metal scrap. in plant premises & it recycled through 4.Wooden may lead to rodent registered scrap vendors. pellets. breeding Coal ash will be sold to 5. Coal ash. registered brick manufacturer. Daily housekeeping waste and food waste will be disposed through municipal waste management facility.

10.6 Fly Ash utilization

The manufacturing plants & evaporators will require steam for operation, to obtain this steam company will operateThreeSteam Boilers (6 TPH, 850 Kg/hr. and 15 TPH) & twoThermic Fluid Heater (6 Lakh kilo cal./hr.& 2 Lakh kilo cal./hr). The fuel used for operations of two steam boilers will be Coal & for One Steam boiler and Two Thermic Fluid Heater will be Furnace Oil, the maximum ash percentage in Furnace Oil is estimated around (0.1%)*& Coal is around (13.99 %).

* Bureau of Energy Efficiency.

Table No.10.4: Ash generation due Boiler & Thermic Fluid Heater operations

Quantity of fuel used per Quantity of ash to be generated Fuel Used Ash Content day per day FO 0.1% 3608.2 L/Day (3.71 T/Day) 0.0037 T/Day Coal 13.99% 57.2 T/Day 8.5463 T/Day 8.55 T/Day Total (Will be sold to registered brick manufacturers)

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The fuel consumption for operation of boiler (Coal) will be 57.2 T/day and FO for thermic fluid heater and Steam boiler will be 3.71 T/day hence through combustion of total 60.91 T/day, 8.55 T/day ash will be generated which will be sold to registered brick manufacturers.

10.7 Action Plan for Green Belt Development

Generally green belt developed along the factory boundary helps to arrest/capture dust emissions thereby avoiding it toescape beyond the factory boundary and also to minimize intensityofnoise propagating out of the factory premises along with improving the aesthetics of project site.

10.7.1 Design and development of green belt

Design: Thick green belt will be developed along the boundary of the project plot as per the Standard TOR prescribed by MoEF& CC.

Area allocation for green belt: Currently ALL has developed green belt in 343.52 sq. m. additionally green belt development will be done in 518.75 sq. m. within the project plot.

In addition ALL has leased two plots from Mahad MIDC for green belt development viz. OS - 5 & OS - 16 admeasuring 10,600.00 & 9,600.00 sq. m. respectively thus total are for green belt development will be 20,200.00 sq. m. The plots OS – 5 & OS – 16 are reserved by MIDC for green belt development/plantation activity only & agreement into the same effect has been prepared.

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Area consideration for growth of individual tree: The area assumption for individual large/medium size growth achieving tree is 2.6 m x 2.6 m= 6.76 sq. m. as per the Standard TOR prescribed by MoEF& CC for Pesticides Industry and pesticide specific intermediates(excluding formulations).

Selection of plant species: Preferably native fast growing, non-fruiting plants having large leaf area will be used for green belt development.

10.7.2 Project plot area breakup details

Table No.10.5: Project plot area break up details Area Details Existing (sq. m.) Proposed (sq. m.) Total (sq. m.)

Total Plot Area 13950 -- 13950 Built Up Area 8544.00 -- 8544.00 Parking Area 166.00 -- 166.00 Green Belt Area 343.52 518.75 862.27 Note: In addition green belt development/plantation will be done in 20,200. sq. m. within Mahad MIDC

10.7.3 Proposed green belt Reconnaissance survey were conducted along with the project proponent to identify sites for proposed green belt & the areas thus demarcated for the proposed green belt were plotted on the Autocad system, the layout plan thus generated is depicted below.

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Figure No. 10.2: Project plot layout depicting proposed green belt within the plant premises

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10.7.4 Area consideration for plantation The area assumption required for individual large tree/medium size growing tree is as follows: 1. Area required for large/ medium size growth achieving tree = 2.6 meter x 2.6 meter

Table No.10.8: Break up of proposed green belt area & no. of trees

Area in No. of plants to be planted Sr. No. Green Belt Site (Sq. m.)

1 Within the factory premises 518.75 76

10.7.5Action plan & estimated budgetary allocation for proposed green belt development Table No.10.9: Action plan for proposed green belt development/plantation

Estimate for block plantation - within during June 2019

Total area: 518.75 sq. m. Estimated Expenditure No. of plants to be planted: 76 Sr. No. Particulars of work Magnitude Rate ( Rs.) per unit Amount (Rs.) 1 Alignment & Digging of pits 76 120 9,120.00 Purchase of plants (saplings of large/medium 2 76 165 12,540.00 size growing trees) Transportation cost (transportation of plants 3 to project site including loading & unloading) 20,000.00 20,000.00 & planting in pits 4 Purchase of soil & fertilizers 85,000.00 85,000.00 Purchase of bricks/fencing material (for 5 15,000.00 15,000.00 green belt bordering/fencing) Total 1,41,660.00

Table No.10.10: Recurring cost for maintaining green belt

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Estimate for maintaining the Green Belt Estimated Expenditure Sr. No. Particular of work Capital Recurring/Annum 1 Watering for 8 months(240 days) -- 17,544.00 862.27 sq. m. of green belt to be watered 4.3 CMD water @ 5 l/sq. m.

Now the charge for 1 m3 water is Rs. 17 (Reference:https://www.midcindia.org/water)

Thus expenses for watering 862.27 sq. m. green belt for 240 days @ Rs. 17/m3 will be:

240 x 4.3 x 17 = 48, 960/annum (240 days) 2 Caretaker 1 Nos. for 12 month @ 1x15,000/month -- 1,80,000.00 Total -- 1,97,544.00

10.7.6 Suggested plant species A mix plantation of native of trees as depicted in the below table is suggested for proposed green belt & replacement of any dead tree in the existing green belt. Table No.10.11: List of suggested plant species Sr. Botanical name Family Common No. of individual plants to be No. name plants 1 Cassia fistula Ceasalpiniaceae Bahava 4 2 Bombax ceiba Bombacaceae Sawar 4 3 Asltonia shcolaris Apocynaceae Saptaparni 4 4 Macaranga peltata Euphorbiaceae Chandwar 4 5 Schleichera oleosa Sapindaceae Kususm 4 6 Microcos paniculata Tiliaceae Shirali 4 7 Terminalia elliptica Combretaceae Ain 4 8 Terminalia paniculata Combretaceae Kindal 4 9 Terminalia bellirica Combretaceae Baheda 4 10 Cordia dichotoma Boraginacea Shelu 4 11 Helictere isora Sterculiacea Murudsheng 4

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12 Holoptelea integrifolia Ulmaceae Ainasadada 4 13 Butea monosperma Fabaceae Palash 4 14 Oroxylumindiccum Bignoniaceae Tetu 4 15 Erythrinasuberosa Fabaceae Pangara 4 16 Azadirachtaindica Meliaceae Kadulimb 4 17 Dalbergiasissoo Fabaceae Shisham 4 18 Tremaorientalis Cannabaceae Ghol 4 19 Neolamarckiacadamba Rubiaceae Kadamba 4

10.8 Storm water management

In developed area like Industrial estate or company premises, impervious surface such as pavements in factory premises prevents precipitation from naturally soaking to the ground, instead of that water runs into storm drains. Managing the quantity and quality of storm water is termed, "Storm water Management." Storm water calculation To assess the worst case scenario for storm water to be received on project plot, the average annual rainfall revived in Raigad District is considered which is 1850 mm (IMD data 2012 -2016).

Thus average rainfall/month = 1850/4 = 462.5 mm (only 4 months of rainy season are considered),accordingly average rainfall/day = 462.5/30 = 15.41 mm/day & average rainfall per hour = 15.41/24 = 0.64 mm/hr. Storm water quantity can be estimated by three methods. 1. SCS Technique: Curve number method of USDA 2. Commercial Software: Storm water management model (SWMM) or STORM 3. Rational Method. In this section of the report rational method has been used to quantify the amount of storm water runoff per hour in the plant premises.

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Rational Method Q = 10 CiA Q= Runoff in m3/hr C = Coefficient of runoff i = intensity of rainfall in mm/hr A = Area of drainage in hectares. Q = 10 x 0.9 x 0.64 x1.395 Q = 8.03m3/hr.

Details of storm water drains present on project plot

Length of storm water drain present on entire project plot = 478.6 m

Width of storm water drain = 0.25 m

Depth of storm water drain = 0.2 m

Capacity of storm water drain = L x W x D = 478.6 x 0.25 x 0.2 = 23.93 m3

Conclusion:

The maximum water that can be received during rainy season on the project plot area plant is calculated to be around 8.03m3/hr.,currently ALL has provided storm water drain of 23.93 m3capacityhence the capacity of existing storm water drains is justified &the storm water drain is connected to MIDC drainage system.

10.9 Rain water harvesting

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The company has provided rooftop rain water harvesting system and the harvested rain water is stored in dedicated underground water tank of 160.0 m3 capacity & the harvested rain water will be utilized for cooling tower or boiler makeup water.

10.10Solvent Management System

Solvents are one of the costly raw materials which get utilized in Pesticides and Chemical intermediates manufacturingindustries.These solvents are very hazardous in nature which may cause harm to environmental components. The main requirement in the industry is minimum inventory maintenance, safe working environment and accurate dispensing. The solvent dispensing system integrates various operations at solvent yard and production blocks like unloading, dispensing etc. solvent management start right from solvent unloading, storage, charging, recovery & reuse of the used solvent. The solvent utilization, recycling and reuse for proposed expansion project are envisaged as follows: 1) Chemicals will be stored in drums& solvent tank farm yardto avoid handling losses closed feed system will be provided for filling and unloading of chemicals from the drums. 2) Products will be purified by using various solvents and use solvents will be collected and recycled. 3) To avoid leakages from drums & pipelines, regular inspection & maintenance will be done. 4) Closed feed system will be adopted for reactor charging 5) Flame proof equipment’s will be used during maintenance 6) Earthing will be provided wherever solvent to be handled.

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Table No.10.12: Solvent use & recovery summary

Solvent % Solvent Recover recover Product Name Solvent Used Consumptio y y of n (MT/M) (MT/M) solvent Dimethyl Sulphide + Propiconazole Cyclohexane + Dimethyl 50.5 1010 95 sulphoxide+Toluene Dimethyl Sulphide + Hexaconazole Dimethyl Formamide + 17.2 344 95 Methanol Methyl Cyclohexane + Tebuconazole Dimethyl acetamide + 57.8 1155 95 Dimethyl sulphide Dextrinol Toluene 0.1 4 98 3,4-Chlorostyrene THF 3.0 99 97 Metalaxyl Xylidene + Cyclohexane 1.0 20 95 4-Hydroxy 3-Methyl-2- (Propinyl)-2-Cyclopentene-1- THF 0.9 31 97 Lon ( LON ) Dichloro Benzyl Cyanide/4- nil 0.0 0 0 Chlorophenyl Ethyl Chloride Methanol + MDC + Dimethyl Bromuconazole 26.4 528 95 formamide +THF + Toluene Dimethyl acetamide + Cyproconazole Cyclohexane + Dimethyl 12.8 256 95 sulphide +Toluene +THF Toluene + Dimethyl Pallerthrin 1.4 47 97 formamide IPA + Toluene + Difenoconazole 16.3 325 95 Cyclohexane Tricyclazole Nil 0.0 0 0

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2-Ethyl 2-Methyl Butanoic THF 2.4 81 97 Acid Metconazole ECH + Toluene 12.7 423 97 5-Methyl-Α-(2-Propinyl) -5- THF+Toluene 4.5 148 97 Furfuryl Alcohol ( PGMF ) Dimethyl acetamide + Myclobutynil 7.8 156 95 Dimethyl sulphoxide Dimethoxy Benzoic Acid Methanol 4.9 98 95 Acetonitrile + Methanol+ Boscalid 7.7 154 95 Toluene + THF Prothiconazole Hexane 4.5 90 95 ECH + Toluene + NMP + Ipconazole 23.0 459 95 IPA 4-Trifluromethyl Benzyl THF 4.5 151 97 Alcohol ( FTBA ) Methanol + Chloroform + Fenpyroximate 2.7 54 95 Toluene

10.11. CER Activity (Corporate Environmental Responsibility) Project undertaking social responsibility is not a business posture, but is the result of market economy development in some stage, is the inner demand of enterprise and self-conscious action. Social responsibility has become a new competition after the talent, technology and management, is the important variable effected enterprise sustainable development, true sustainable and build up harmonious society through undertaking social responsibility.

Since the project comes under notified MIDC industrial areaPublic Hearing (PH) is not applicable as per MoEF&CC O.M dated 27th April 2018, however for development & improvement in socio economic aspects of the surrounding area, company has made provisions for fixed budgetary allocation for social commitment as a part of social responsibility.

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After accomplishment of proposed expansion company is willing to do following ESC activities:

Education & skill development

 Provision of need based amenities to school in project area. Health awareness

 Provision of need based amenities to Rural Government Hospital in project area.

10.11.1 Budgetary allocation for CER Activity

As per O.M issued by MoEF&CC dtd. 1st May 2018 ALL has allocated 1% of proposed capital investment of expansion activity. The proposed capital investment of expansion activity is 10.17 crore thus 10.17 lakhs for expenditure on CER activities is provisioned. The year wise budgetary allocation& anticipated expenditure is given in the following table.

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10.11.2 Action Plan for CER Activity Table No.10.13: List of CER activities to be undertaken Cost of CER Year of Proposed Amount in Budgetary Implementatio Activity Cost Estimate Expansion Lakh Allocation n Activity

Providing basic amenities to Particulars Amount (Approx.) the ZP School of For Water Purification GandharpaleAdiWadi as R.O.+UV purification System 3,40,000/- under: (6 no.) 2019 5.0 Lakh 1. Safe Drinking water Storage Tank (6 no.) 40,000/- System. Fitting charges 20,000/- 2. Providing new

benches 10.17Crore 10.17Lakh Providing benches (20 Nos) 1,00,000/-

Amount Particulars Providing basic amenities to (Approx.) 5.17 Lakh the Mahad Government Sterilizing Equipment (Auto Clave) 2020 2,00,000/- Rural hospital. (6No) Hot Air Owen (4 No) 2,00,000/- Examination Bed (20 No) 1,17,000/-

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10.11.3 Monitoring plan for CER Activity Execution

Post project execution, Project Proponent is advised to maintain a separate dedicated account for CER funds also to designate fix personnel for execution of year wise CER activities & such year wise expenditures made should be made available to Statutory Authorities as & when required.

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10.12 Occupational Health 10.12.1 Plan & fund allocation to ensure the occupation health and safety of all contract and casual workers The objective of occupational health environment is to provide safe working environment to the employees of the company. Good occupational health management keeps workers physical conditions healthy or non-deteriorating in work environment which keeps the worker physically and psychologically sound. It results in

. High productivity . Improved work efficiency . Work satisfaction . Less medical expenses toward employees thereby less recurring cost. The company has planned all the necessary control measures to prevent air pollution, water pollution and degradation of soil in the project surrounding areas. Since all the pollution control measures are planned.Minor accidents, noise, poor ventilation and accidental chemical exposure are the only possible occupational health hazards from the manufacturing activities. For the prevention of it, the company will educate the operators and workers for the safety rules, procedure and preventive measures and to use personnel protective measures. The company has provided budgetary allocation of Rs. 4,00,000/- for purchase of Personal Protective Equipment’s (PPEs) for existingman power & Rs.1,00,000/- as recurring expenditure for annual medical, health checkup& other occupational safety related aspects of workersas a part of Occupational Health & Safety measures.

10.12.2 Details of exposure specific health status evaluation of worker. The company conducts medical health checkup of workers on periodic intervals, the summary of one such medical health checkup is given Annexure - 10.1.

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Chapter 10: Environmental Management Plan

10. 13 Corporate Environmental Policy

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Chapter 10: Environmental Management Plan

10.13.1 Administrative order of the company to deal with the environmental issues

Figure No. 10.4: Schematic representation of administrative order of company to deal with environmental issues

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Chapter 10: Environmental Management Plan

10.13.2 Environmental Policy prescribes for standard operating process/procedure to bring into focus any infringement/deviation/violation of the environmental norms. The company will establish SOP’s for use/handling/operation of various safety & hazard management features during any emergency situation.Some of SOP’s that are in place.

10.13.3 Procedure for reporting accident/incident and attending the injured person

 Incident and Injury reporting system is in place.

10.13.4System of reporting of noncompliance /violations of environmental norms to the Board of Directors of the company and/or shareholders or stakeholders at large  Legatrix (Legal Compliance Monitoring system).  Communication of non-compliance to Legal Cell as and when received from concern authority.  Feedback to non-compliance tracking system.  Review of compliance on monthly basis.

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Chapter 11: Summary & Conclusion

CHAPTER 11: SUMMARY & CONCLUSION

M/s Astec LifeSciences Ltd. proposes expansion of existing manufacturing unit located at Plot No B-16, 17, 18 &21, MIDC Mahad, District Raigad, Maharashtra.

M/s Astec LifeSciences Ltd. has envisaged pesticides& chemical intermediates production capacity enhancement from existing 219 MT/M to a proposed total production capacity of 781 MT/M along with formulation products to the tune of 700.0 MT/M and bi-products to the tune of 1773 MT/M within the existing manufacturing plant located at Plot No. B-16, 17, 18 &21, MIDC Mahad, District Raigad, Maharashtra with an estimated budgetary project cost of Rs. 10.17Crore. The proposed activity is a production capacity expansion of the existing unit located at Plot No. B-16, 17, 18 &21 and will be carried out by replacing existing equipment by new higher capacity equipment’s.

11.1 SALIENT FEATURES OF THE PROJECT

a. Name & Location of the project : M/s AstecLifeSciences Ltd. Plot No B-16, 17, 18 &21, MIDC Mahad, District Raigad, Maharashtra. b. Details of Applicant : Mr. Arijit Mukherjee c. Type of Industry : Small Scale Industry, Pesticides Products Manufacturing Unit. d. Type of Land & Status : The land is located in Mahad MIDC therefore the it is an industrial plot. Project land is leased for M/s AstecLifeSciences Ltd. e. Capital Investment for EMP : 60.00 lakhs f. Recurring Cost for EMP : 7.2 lakh

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Chapter 11: Summary & Conclusion g. Employment Opportunity : Existing :.160 Proposed : -- Total: 160 h. Greenbelt Area : Within project plot 862.27 sq. m. i. Water Pollution Control : 36 CMD LCOD-LTD effluent along with domestic sewage 15 CMD will be treated in full- fledged ETP of 55 CMD capacity from which 46.43 CMD effluent will be sent to CETP for further treatment & disposal as per valid C.T.O & 4. 57 CMD treated effluent will be reused.

241 CMD effluent process will be subjected in plant stripper evaporator of 250 CMD capacity from which 184 CMD condensate will be reused & 54 T/D salts will be sold as bi-products.

120.73 CMD Cooling tower & Boiler blow down will be reused. j. Flue gas emission control :  Stack No.1: 30 m Stack for 6 TPH boiler  Stack No.2: 24m stack for 850 kg/hr boiler  Stack No.3: 39 m stack for 15 TPH boiler  Stack No.4: 27 m commonstack for TFH’s of 6 & 2 lackhkilo. cal./hr.  Stack No. 5: 4.5 m stack above roof for D.G of 250 kVA  Stack No. 6: 4.5 m stack above roof for D.G of 500 kVA  Stack No.7: 5.0 mstack above roof for process scrubber Note: Existing boiler of 2.5 TPH & D.G of 125 kVA will be discontinued k. Process gas emission control : Process Scrubber

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Chapter 11: Summary & Conclusion l. Hazardous waste Management : 1. Hazardous wastes generated from the processsuch as Spent Oil will be sold to MPCB authorized recycler.

2. Chemical Sludge from Wastewater treatment will be disposed to CHWTSDF.

3. Hazardous wastes such as Discarded containers barrels/liners/ plastic bags/PPEs etc will be reused/recycled/sold to Authorized Parties. m. CER budgetary allocation : 10.17 Lakhs n. Rehabilitation & Resettlement Aspects : The proposed production capacity enhancement project is a brown field activity which will be executed within the existing factory premises hence rehabilitation & resettlement aspects are not applicable o. Forestry/Wildlife/ Conservation : The proposed project is located in Notified MIDC related aspects Mahad & does not involve any use of forest land. Also study area is devoid of any species of conservation importance hence forestry/conservation related aspects are not applicable.

11.2 Conclusion

It can be concluded that due to provisions and implementation of efficient environmental management systems including the proposed mitigation measures and environment management plans, the impacts associated with the project activities during the operational phase would be manageable and the proposed expansion activity will be directly & indirectly beneficial to the surrounding people.

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Chapter 12: Disclosure of Consultant

12.0 CHAPTER 12: DISCLOSURE OF CONSULTANT

M/s Sadekar Enviro Engineers Pvt. Ltd. established in the year 1998 is a NABET accredited (NABET Certificate No. NABET/EIA/1518/RA020 was earlier valid up to 14th October 2018 & has applied for renewal ) EIA Consultant Organization having its registered office at 310, Dempo Towers, EDC Patto, Panaji-403001, Goa State, India.

Sadekar Enviro is organized company under three strategic environmental pollution prevention and control activities viz. Air, Water & Hazardous Waste and provides following services:

 Environmental Impact Assessment Study & Environment Management Plan  Execution of Effluent & Sewage treatment plants on turnkey basis  Treatability & Feasibility studies for Waste Water Treatment  Collection & Analysis of water, Wastewater & Hazardous Waste Samples  Ambient Air Quality, Stack Emission, Noise & Work Place monitoring  Environmental Audit reports Preparation & Submission to SPCB

Operation & Maintenance of ETP & STP on contract basis

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