The Geology and Geochemistry of Cenozoic Topaz Rhyolites from the Western United States
Total Page:16
File Type:pdf, Size:1020Kb
The Geology and Geochemistry of Cenozoic Topaz Rhyolites from the Western United States Eric H. Christiansen Department of Geology University of Iowa Iowa City, Iowa 52242 Michael F. Sheridan Donald M. Burt Arizona State University Tempe, Arizona 85287 SFEE'It':' FAFE., 205 © 1986 The Geological Society of America, Inc. All rights reserved. All materials subject to this copyright and included in this volume may be photocopied for the noncommercial purpose of scientific or educational advancement. Published by The Geological Society of America, Inc. 3300 Penrose Place, P.O. Box 9140, Boulder, Colorado 80301 GSA Books Science Editor Campbell Craddock Printed in U.S.A. Library ofCongress Cataloging-in-Publication Data Christiansen, Eric H The geology and geochemistry of Cenozoic topaz rhyolites from the western United States. (Special paper; 205) Bibliography: p. 1. Rhyolite-West (U.S.) 2. Topaz. 3. Ore deposits-West (U.S.) 4. Geology, Stratigraphic Crenozoic. 5. Geology-West (U.S.) I. Sheridan, Michael F. II. Burt, Donald M., 1943- . m. Title. IV. Series: Special paper (Geological Society of America); 205. QE462.R4C48 1986 552'.2 86-273 ISBN 0-8137-2205-5 Contents Acknowledgments v Abstract I Introduction ;................................................ 3 Cenozoic topaz rhyoUtes from the western United States 3 1. Thomas Range, west-central Utah 3 2. Spor Mountain, west-central Utah 10 3. Honeycomb Hills, west-central Utah ........................•......... 13 4. Smelter Knolls, west-central Utah 14 5. Keg Mountain, west-central Utah 15 6. Mineral Mountains, western Utah 15 7. Wah Wah Mountains and vicinity, southwestern Utah and southeastern Nevada 17 8. Wilson Creek Range, southeastern Nevada 19 9. Kane Springs Wash, southeastern Nevada......... .. 19 Topaz rhyolites in the eastern Great Basin: A summary 21 10. Cortez Mountains, north-central Nevada 21 11. Sheep Creek Range, north-central Nevada 23 12. Jarbidge, northern Nevada '" 24 13. Blackfoot lava field, southeastern Idaho 25 14. Elkhorn Mountains, western Montana 26 15. Little Belt Mountains, central Montana 27 16. Specimen Mountain, north-central Colorado 29 17. Chalk Mountain, central Colorado 30 18. Nathrop, central Colorado 31 19. Silver Cliff-Rosita, central Colorado 32 20. Tomichi Dome, central Colorado 34 21. Boston Peak, central Colorado. ................ .. .................. .. 35 22. Lake City, southwestern Colorado 36 Topaz rhyolites in Colorado: A summary 37 23. East Grants Ridge, west-central New Mexico ....•...................... 37 24. Black Range, southwestern New Mexico 39 25. Saddle Mountain, eastern Arizona 41 26. Burro Creek, western Arizona 41 Other "topaz rhyolite" occurrences 42 Other Cenozoic occurrences, western United States 42 Mexican topaz rhyolites '. .......................... .. 42 Precambrian topaz rhyolites -. ................. .. 42 iii iv Contents Principal characteristics of topaz rhyolites 43 Distribution and ages .....................................•......... 43 Mode of emplacement 44 Mineralogy 46 Fe-Ti oxides and titanite 46 Feldspar 47 Mafic silicates 48 Geochemistry and differentiation trends 50 Isotopic composition 59 Magma-tectonic setting 59 Ore deposits 61 Beryllium 61 Climax-type molybdenum deposits 62 Tin ' 63 Uranium 64 Fluorite 64 Comparison with other types ofrhyolitic rocks 64 Calc-alkaline rhyolites 64 Peralkaline rhyolites 66 Aluminous bimodal rhyolites 67 Ongonites 67 Petrogenetic modelfor topaz rhyolites 69 References cited 74 Acknowledgments . This work was partially supported by U.S. DOE Subcontract #79-270-E from Bendix Field Engineering Corporation. Additional support was provided by Arizona· State Univer sity, the University of Iowa, the U.S. Geological Survey, and the National Aeronautics and Space Administration (grant NAGW-537). A large number of people have helped with the new analytical work presented in this report. They include D. McRoberts, M. Druecker, J. Edie, J. V. Bikun, B. Correa, K. Evans, A. Yates, R. Satkin, K. Hon, D. Lambert, C. E. Hedge, K. Futa, A. Bartel, D. R. Shawe, J. S. Stuckless, L. Jones, R. T. Wilson, W. Rehrig, G. Goles, and G. Pine. The technical reviews by W. Nash and W. Hildreth, and editorial assistance of C. Craddock and L. Gregonis are greatly appreciated. We are also indebted to the authors of many of the articles cited herein for helpful discussions and for recording the presence of topaz in the rhyolites they have studied. v Geological Society of America Special Paper 205 1986 The Geology and Geochemistry ofCenozoic Topaz Rhyolites from the Western United States ABSTRACT High-silica, topaz-bearing rhyolites of Cenozoic age are widely distributed across the western United States and Mexico. Topaz rhyolites are characteristically enriched in fluorine (>0.2 wt%) and contain topaz crystallized during post-magmatic vapor-phase alteration. In the United States, their ages span much of the Cenozoic Era (50 to 0.06 Ma). Their emplacement followed or was contemporaneous with calc-alkaline and ba saltic magmatism in the Basin and Range province, along the Rio Grande rift, and in Montana, and coincided with episodes of extensional tectonism in these regions. Nearly all topaz rhyolites extruded as small, endogenous lava domes with or with out lava flows; no topaz-bearing ash-flow tuffs have yet been identified with certainty in the western United States. Most domes are underlain by a precursory blanket of non welded tephra. A few are small, shallowly emplaced intrusive plugs. Volumes of rock «1 to 100 km3) in individual complexes composed of 1 to many separate extrusions suggest that the lavas were erupted from small to medium sized magma bodies. In addition to topaz, these rhyolites also contain garnet, bixbyite, pseudobrookite, hematite, and fluorite in cavities or in their devitrified groundmasses. All ofthese phases may form during vapor-phase crystallization. Magmatic phenocrysts include sanidine (ca. Orso), quartz, sodic plagioclase (usually oligoclase), and F- and Fe-rich biotite in order of usual abundance. Fe-rich hornblende or clinopyroxene occur in a few lavas. Common magmatic accessory minerals include magnetite, ilmenite, zircon, apatite, allan ite, and fluorite. Titanite and REE-rich phosphates have been identified in a few lavas. The rhyolites crystallized over a wide temperature interval (850 to 600°C, with most at the lower end of this range) and at variable oxygen fugacities. Titanite-bearing lavas crystallized above the NNO buffer under oxidizing conditions. Most others appear to have crystallized near the QFM oxygen buffer. For individual complexes, temperatures correlate negatively with F-content. All topaz rhyolites are high-SiOz rhyolites with elevated F, Na, K, Fe/Mg and low Ti, Mg, Ca, and P. Samples with F concentrations of about 1% have notably lower Si and higher AI and Na than other topaz rhyolite glasses. Most glasses from topaz rhyo lites are metaluminous, but many appear to be slightly peraluminous. Fluorine concen trations in glasses range from slightly less than 0.2 to more than 1.0 wt%, and F/ Cl ratios are high (3 to 10) compared to F-rich peralkaline glasses «3). Topaz rhyolites are characteristically enriched in incompatible lithophile elements (Rb, U, Th, Ta, Nb, Y, Be, Li, and Cs). Elements compatible in feldspars (Sr, Eu, Ba), ferromagnesian minerals (Ti, . Co, Ni, Cr), and zircon (Zr, Hi) are depleted. The REE patterns ofmost topaz rhyolites are almost flat (La/YbN = 1 to 3) and have pronounced negative Eu anomalies (Eu/Eu* = 0.01 to 0.02). Both of these parameters decrease with differentiation as indicated by increasing F, U, Cs, and other incompatible elements. Titanite-bearing rhyolites have prominent middle REE depletions. Initial Sr-isotope ratios range from 0.705 to over 0.710. Geochemical trends at individual complexes are interpreted as arising from frac tional crystallization of an initially more "mafic" rhyolite with about 0.2% fluorine. Extensive fractionation of sanidine, quartz, plagioclase, biotite, and Fe-Ti oxides (in 1 2 Christiansen, Sheridan, and Burt proportions consistent with their modes) produced much ofthe trace element patterns. Zircon, apatite, and a REE-rich phase (allanite, monazite, or titanite) were minor but important fractionating phases. No liquid-state fractionation is required to explain the geochemical trends. The high F content and FICI ratios oftopaz rhyolite melts may have modified phase relations so as to produce Na and AI enrichments for highly evolved magmas. Topaz rhyolites are intimately related to economic deposits of lithophile elements (i.e. Be, U, F, Li, and Sn). The volcanic rocks were probably ore- and, in some cases, fluid-sources for these mineral deposits. In their age, tectonic setting, mineralogy, chem istry, and style ofemplacement, topaz rhyolites bear resemblance to the rhyolitic stocks associated with Climax-type Mo deposits, and some may be surface manifestations of such deposits. In their chemical composition and mineralogy, topaz rhyolites are distinct from both peralkaline rhyolites and calc-alkaline rhyolites with which they may be spatially and temporally associated. Some of the compositional differences between topaz rhyolites and peralkaline rhyolites may be attributed to the relative effects of F and CI, on melt structure and phase relationships in their parental magmas. The F/CI ratios ofthe melt or its source may determine the alumina saturation ofthe magma series. Topaz rhyolites are distinguishable from calc-alkaline rhyolites by lower Sr, Ba, and Eu,