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Ffimbasf the Chemicaf Contpany /"¡ 4l 7) ffiMBASF The Chemicaf Contpany Safety data sheet PHANTOM@ % Revlsion date : 20 Page: Version: 3.1 1/8 62151/MDS CPA US/ËN 1. Substance/preparation and company identifÍcation Company 24"HpUr_E¡n_ergencv Response lnformation BASF CORPORATION CHEMTREC: 1-800-424-9300 100 Carnpus Drive BASF HOTLINE; 1-800-832-HELp - Florham Park, NJ 07332, USA Substance number; 0000000621 51 Molecular formula: c(15) H(11 ) Br cl F(3) N(2) o Molecular welght: 407.6 g/mot Chem¡cal famity: pyrrole derivative Synonyms: chlorfenapyr 2. Gompos ition/information on lngredients ÇAS NumþgI Content IW/W) Chemical namg 122453-73-0 21.45 % Chlorfenapyr 57-55-6 .7.5 % Propylene glycol 70.97 0/o Proprietary ingredienls 3. Hazard identification Emg¡qencv. overvielg CAUTJON: Causes eye irritation. HARMFUL IF SWALLOWED. HARMFUL IF ¡NHALED. HARMFUL IF ABSORBÊD THROUGH SKIN. KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REAÇH OF DOMESTIC ANIMALS. Do not get in eyes, on skln, or on clothing. Avoid inhafation of mists/vapours. Folential health effects See Product Label for additional precautionary statements. Prlmary routes of exposure Routes of entry for sollds and liquids include eye and skin contact, ingestion and inhalation. Routes of for gases include inhalation entry and eye contact. drtn may be â routs of entry for liquifìed gases. "ontärt Acute toxicity: Slightþ toxic after single ingestion, Slightly toxic after short-term inhalalion. Slighily contact. toxlc afier shorþterm skin lrritation: Safety data sheet PHANTOIVI@ Revision Aatê: nddioUn Version:3.1 Page:2/B 51/MDS.CPA US/E May cause slight ¡rritat¡on to the skin. May cause slight but temporary ir¡itation to the eyes. Sensitization: Skin sensitizing effects were not observed jn animal studies. ,Mgliqut condifions aggravated by overexposure: ois!äiËt-oiiiräffii:i;,.r, skin or eyes rnay ng:1''flt"î||rre'exisino have increased suscepribir'y to Potential environ[nental effects Aquatic toxicity: Very toxic (acute effect) to aquatic organisms. : . Terrestrlal toxicitv: Acutely very toxic ío terrestrial organisrns. 4. First-aid rneasures General advice: Fkst aid providers shoutd crothins, i',;;öäå;iJ',#!îiü'lJ'1:fl:i'i,"oi,'å,',î,i.Ï,':ji respirailon, preferabrv mnu*r+o-moúilr slîïi:ffi:i:? i,ï;ï;J:i;;i$."0 ;;;;;bË: öu"ri u põ¡lon product.onru¡nuiãiiålËiliin for ,x1Tå:,Hili.e vl,íir,,d ";;iliär.ä-onyr,.iun rrearmenr ",rfi,s;;;ì;;'äåni..ol.unt", or doctor or soins lf inhalcd: Remove the affected individual Into fresh air and keep the person calm. Assist in breathing if necessary. lf on skin: Rlnse skin immediatery wiür prenty of waterfor rs - z0 rninutes. ff in eyes: for 15 ro 20 minutes. iå:ïiï,ijï,îTJil.,.,"i:ä,å",ijf,ilt:1iltJii:rer Remove contacr renses, if lf swallowed: if abre ro swa'où. Do v-omirins unress åii:,.t""J:.å,:i. í,glïì.,T,ï".r--'-"''-JcevomitingorgiveanlTthingbymouth¡r-ttä"¡Ëti,ìr'¡rrn.onr.¡ourorhaving i:l.i?9,g9 rord to by a poison contror convulsions. N.ots to.phvslcian A¡tidote: No known specific antidote, I reatment: rreat symptãrnäî;i;.""*' 5. Fire-fighting measures Flash polnt: Not applicable, Non-flammable. Suitable extinguishing media; loam, dry extingulshing media, carbon dioxide, water spray Hazards during fire.fightíng: acid, Hydroruoric acid, hydrosen,uoride, Ëiil,ü,"Jîff;::li3i,:'íi'ff.itifff:product î;iide,Ìrvdrochiorjc lf is heated above i ",iostanià"rg,ã-uîs"å,î0".åiiîo#:'#1.:.fli.îi:1?,:"#ÉJ?ü:î,.îlL:i,,""fí;ñ:ill? n* equrpmenr for fire_fishtins: Frrerghters:l:1,1j":- shourd be equipped liitn seii-conta;ned breathing apparatus and turn_out gear. Fuñher informafion: ln case of fire and/or explosiondo not breathe fumeé. Keep containers cool by spraying with exposed to fire. coilect contaminated.ext¡nsuÈning water if ;atàr separatety, do not árow i; reach sewage Dispose or rne oe¡i¡s åno"ãåîiääilåtå or i#iiJì1.T.:ttts' exiinsuisÁíns w"täi i. ärã",on"ce wth orriciar 6. Accidental release measures Personal precautions: Take appropriate protective measures. clear area. shut off sou¡ce of leak only under safe conditions. ;åÏ::lil'J.',,',iïiJ,.,itJl|iffiñ'.bv;nl¿;*;;ilol'Ën.u,* adequate ventirái¡Jn. wea,,uituui"õäi,onur Environmental precautions: Do not discharge into the t:::iiy-Ì?l. Do nct discherrge into drains/surface waters/grouncjwater. contaminated water/firefighting water. contain Gleanup: Dike spillage' Pick up with sultable absorbent material. Place into suitable containers a licensed facilitv' spiiled suostanc-e/piód;;lsh;b tor reuse or disposal in ü recovered and appried according whenever possibre. rf aoorication to raber rares conrained, ¡s not possibre, then spi¡s shourd be solidiried, ano'ptaceo ¡À"t"¡,iËJ;;;;"t.*ãräro¿r.t srir:i;i.;ï"rä#¿io, washed oirpo.äi'Äri.i!äìiiä,iri,[u.n, spin area can be with water. Coilecr wash wat", ro, uópiòväã' jiró0..r, 7. Handling and storage 'Handlinq 'General advice: RECOMMENDATIONS ATFJg¡ COMMERC¡AL woRKERs' PEsrlclDE V4NUFACÏURING, BLENDING, AND PACKAGING APPLtcAiôFiõ d \ño"nir<lis must rere, to ir," use attached to the Ëiåài.iL"oer and Direcrions ror oroduc_t for ngricurtuiaì ú;; rid;;r"runts in Protection standard accordance with the EpA worker 40 cIR pãì;ó:'ä;;äüËi" u*ntirriion. Þiåuilã!åää'ventiration (iocal exhaust vent¡ration it¡d."."arv).ïãJp-aiä"vïã*_rorrr.. orworkins area of ignition - No smoking. Keep container tishtlv sealed' Protect conte¡ts t¡om iÁe ,,irJ.Ëãliiöñi. prorect open container asaiñst ¡ôat, ÊrJät rrom air. Handre and with care' Do not open until ready to"use. once as soon as possible' cõnt.¡nuil, åp"nàî, content shoutd be used Avoid ae¡osoi formation, Àíoi¿ ousr rormatron.'Þioì¡oeïãäi. spills' Do not return residues ro'- conrro¡ing reaks and to the storajeconiuinãrî.rorro* rabel warnings emptied' The substance/ product even after container is tuv uËLnJllä'o"nti.uy uppropriatety contact w¡th traiñed personne¡. Avoid ail direct the substance/product. Ávoid co;ì; the dusrs/misrs/vapours. ;iÅ skin, eves ánà iroì¡riñõ. ivoio inhalarion of wear suitaore peiion;iil"äil; ¿i;ú.ì1;s ;;ö;þ;;;i. "., Frotection aga¡nst fire and exploslon: The relevant fire protectlon measures should be noted. Fire extingu¡shers should be soulces of ignition: heal' soarks, kept handy, Avoid ãlJ open name. sãúi-.!ïor ignition should heat' Keep away from be kept welt clear. Avoid extreme oxid'izable ,rb.tun..r. eì".ir¡.ï uqr¡pment shourd co;ã;i" natronar e/ectric code. all lransrer equipment properli, to prevãniiìecìro¡iai¡c f;lt,,Tåi oisórrarge. eiãäirå.i.t¡" discharse may cause Storaqe General advice: Keep only in the original cóntainer in a cool, dry, welJ-ventilated place away from ignition sources, flame' Protect containers from. physical heat or d*rgäl Ëråiuãt uguin.i conram:nåtion. iñe authortty permits slorage regulafions must be obseryed. and Keep away from heat. Frotect against mo¡sture. protect from direct sunrighl. S g tora e inco mpati b i llty: Safety data sheet PHANTOM@ Revision ¿i ate : ZOOet OZ tn Version; 3.1 Page: 4tB 151/MDS CP textÍJes and simllar materials. 'il; Temperature tolerance P¡otect from temperatures below: O "C g"n crystailize betow the timit temperature. rrurecrll1g:,q!d rrom temperatures above: 40 "C occuf 8i#;ì,'å'[erKÏffå'åî;åii:s::l*':." if subsrance/producr is srored above indicated B. Exposure controls and personalprotection product should refer to the product i"iffi"||:"i3:ticidal raber for personar proteuive equipment Advice on system design: engi"neering controls should be äi,i;;Hl.tt*ible' used to minimize rhe need for perso4ar prolecr¡ve P.ersonãl protective eouipment FoR MAN uF^cruRlNc' coMMER.TAL firãi?ëHsi'ArroNs B LE NDrNG; AN D pAcKAGTN c Respiratory protection: wear respiratory pfotect¡on if ventilation js inadequate. chemicar/Mechanicar wear a NIosH-certified (or equivalent) tvoe nrter sviiem io Ërä"äät"roination TC23c situatlons oliartiã"r,îär"* vapours. For where the aiibornc con-cenkations ,näv *äJ',ã i;;.i'rärï'hi;i;îïir erfective' orwlrere puriffins resprraror is rhe levels are unknown o,. iri,ãJiärurv oungeioli cerlifÌed full facepiece pressure iå'läåä," Härrn (rDr_H), use NrosH_ demand ."ir-öniu-i'ìä ¡r"uthÌng. pressure demand supptied_air apparatus (sceÀl or a fu¡ facepiece respiratoi tsÄnif¡;';;"rpe provisions. Hand prolection: protective gloves, Prolective gtove serection must be fi:t#:#:iiant based on rhe user,s assessment of Eye protection: sido+hields. rishtlv rttins sarety (chemicatsogsres). :;::T,:iï:::with sossres wear race shietd ir Body protectionì on activitv and possibre exposure, å,',,g"tiiiiïl Ti:H:"',iå',J.i:iîîlï e.s. head prorection, apron, General safety and hyg¡ene measures: vvear long sleeved work shirt and long work pants in addition to other work place should be stated personar protective equjpment. equipp^ed w¡tn ã snïwðr ånî'"n-äyu wu.r,. nygrene and safety pracrice. personat Hanore in ãõcåiiance wirh good industríal p.ì.ài¡"ä"ìriiñent shourd O" ¿*ioÃtrÃinãieo must be inspected resurarrv prioi prior to reuse. Gloves ano tõ ãàcî'r.u.'riËprr"u if necessary tmmediatelv all contam¡nate¿ (e.g. pinhore reaks). Take off cloitring' sfc;;n;;k'Jùi.g separatery. Éuno. ,inJiài race should be washed &"'.J",ff;Hrffå:iHffil,lli:i*k *:xÏilr,í"g.i;;"ki'íd;;üäilî" attne prace of woirl­ 9. Physical and chemical properties Forrni liguid Odour: sweetish Colour: white to llght brown pH value: 6.5 - 7.2 Boíling point: (20'c) apÞrcx,212 "F ( 760 mmHg) Safety data sheet PHANTOM@ Version: 3.1 Page; 5/B 62151iMDS CPA US/E DensiÇ: 1.106 - 1.126 ( 20 "c) g/cm3 Bulk density: dropped Partitioning coefficient n­ Not applicable octanol/water (log pow): Solubility ín water: dispersible 10.
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