Herbicide Mode of Action Table
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2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
Common and Chemical Names of Herbicides Approved by the WSSA
Weed Science 2010 58:511–518 Common and Chemical Names of Herbicides Approved by the Weed Science Society of America Below is the complete list of all common and chemical of herbicides as approved by the International Organization names of herbicides approved by the Weed Science Society of for Standardization (ISO). A sponsor may submit a proposal America (WSSA) and updated as of September 1, 2010. for a common name directly to the WSSA Terminology Beginning in 1996, it has been published yearly in the last Committee. issue of Weed Science with Directions for Contributors to A herbicide common name is not synonymous with Weed Science. This list is published in lieu of the selections a commercial formulation of the same herbicide, and in printed previously on the back cover of Weed Science. Only many instances, is not synonymous with the active ingredient common and chemical names included in this complete of a commercial formulation as identified on the product list should be used in WSSA publications. In the absence of label. If the herbicide is a salt or simple ester of a parent a WSSA-approved common name, the industry code number compound, the WSSA common name applies to the parent as compiled by the Chemical Abstracts Service (CAS) with compound only. CAS systematic chemical name or the systematic chemical The chemical name used in this list is that preferred by the name alone may be used. The current approved list is also Chemical Abstracts Service (CAS) according to their system of available at our web site (www.wssa.net). -
Response of Multiple Herbicide Resistant Strain of Diazotrophic Cyanobacterium, Anabaena Variabilis , Exposed to Atrazine and DCMU
Indian Journal of Experimental Biology Vol. 49, April 2011, pp.298-303 Response of multiple herbicide resistant strain of diazotrophic cyanobacterium, Anabaena variabilis , exposed to atrazine and DCMU Surendra Singh, Pallavi Datta * & Archna Tirkey Algal Biotechnology Laboratory, Department of Biological Sciences, Rani Durgavati University, Jabalpur 482 001, India Received 1 June 2010; revised 24 January 2011 Effect of two photosynthetic inhibitor herbicides, atrazine (both purified and formulated) and [3-(3,4-dichlorophenyl)- 1,1-dimethyl urea] (DCMU), on the growth, macromolecular contents, heterocyst frequency, photosynthetic O 2 evolution and dark O 2 uptake of wild type and multiple herbicide resistant (MHR) strain of diazotrophic cyanobacterium A. variabilis was studied. Cyanobacterial strains showed gradual inhibition in growth with increasing dosage of herbicides. Both wild type and MHR strain tolerated < 6.0 mg L -1 of atrazine (purified), < 2.0 mg L -1 of atrazine (formulated) and < 0.4 mg L -1 of DCMU indicating similar level of herbicide tolerance. Atrazine (pure) (8.0 mg L -1) and 4.0 mg L -1 of atrazine (formulated) were growth inhibitory concentrations (lethal) for both wild type and MHR strain indicating formulated atrazine was more toxic than the purified form. Comparatively lower concentrations of DCMU were found to be lethal for wild type and MHR strain, respectively. Thus, between the two herbicides tested DCMU was more growth toxic than atrazine. At sublethal dosages of herbicides, photosynthetic O 2 evolution showed highest inhibition followed by chlorophyll a, phycobhiliproteins and heterocyst differentiation as compared to carotenoid, protein and respiratory O 2 uptake. Keyword s: Atrazine, Cyanobacteria, DCMU, Herbicides, Mutants, Photosynthesis In modern agriculture weed control by herbicides is a tolerate or resist toxic actions of various rice field common practice to increase in crop productivity 1. -
Glufosinate-Tolerant Cotton: Tolerance and Weed
GLUFOSINATE-TOLERANT COTTON: TOLERANCE AND WEED MANAGEMENT by LESLI KRISTEN BLAIR, B.S. A THESIS IN CROP SCIENCE Submitted to the Graduate Faculty of Texas Tech University in Partial Fulfillment of the Requirements for the Degree of MASTER OF SCIENCE Approved Accepted Deamof the Graduate School December, 1991 ^^•ft:;^ ACKNOWLEDGEMENTS 1i would like to extend my heartfelt gratitude to the members that served on 7 '^ '^* my advisory committee for their time, effort, and assistance. I would like to thank Dr. Dotray for his guidance and direction in the preparation of this thesis; Dr. Keeling for his instruction and support in monitoring these experiments; Dr. Gannaway for his knowledge and assistance in the biotechnology and breeding associated with this project; and Dr. Thompson for her friendship and support in making career decisions. Without all of their guidance, I could never have achieved the goals that we set. I wish to thank all of my fellow graduate students in Weed Science for their help in completing this project. I would especially like to thank Alan Helm for his endless help collecting all of the first year data, Ginger Light for her help in clarifying concepts, and LeAnna Lyon for her help with the last year's project. Their support, friendship, and help on this project have been immeasurable. I would like to express my sincerest thanks to AgrEvo and TxCot for their funding of this research. My thanks also go to the people at the USDA-ARS in Lubbock for all of their help before and after I became involved with this research. -
Herbicide Mode of Action Table High Resistance Risk
Herbicide Mode of Action Table High resistance risk Chemical family Active constituent (first registered trade name) GROUP 1 Inhibition of acetyl co-enzyme A carboxylase (ACC’ase inhibitors) clodinafop (Topik®), cyhalofop (Agixa®*, Barnstorm®), diclofop (Cheetah® Gold* Decision®*, Hoegrass®), Aryloxyphenoxy- fenoxaprop (Cheetah®, Gold*, Wildcat®), fluazifop propionates (FOPs) (Fusilade®), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) Cyclohexanediones (DIMs) butroxydim (Factor®*), clethodim (Select®), profoxydim (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) Phenylpyrazoles (DENs) pinoxaden (Axial®) GROUP 2 Inhibition of acetolactate synthase (ALS inhibitors), acetohydroxyacid synthase (AHAS) Imidazolinones (IMIs) imazamox (Intervix®*, Raptor®), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, Lightning®*, Midas®* OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) Pyrimidinyl–thio- bispyribac (Nominee®), pyrithiobac (Staple®) benzoates Sulfonylureas (SUs) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*, Trimac Plus®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron (Logran®, Logran® B-Power®*), tribenuron (Express®), -
Acifluorfen Sorption, Degradation, and Mobility in a Mississippi Delta Soil
Acifluorfen Sorption, Degradation, and Mobility in a Mississippi Delta Soil L. A. Gaston* and M. A. Locke ABSTRACT repulsion effects, acifluorfen is sorbed by soil or soil Potential surface water and groundwater contaminants include her- constituents (Pusino et al., 1991; Ruggiero et al., 1992; bicides that are applied postemergence. Although applied to the plant Pusino et al., 1993; Gennari et al., 1994b; NeÁgre et al., canopy, a portion of any application reaches the soil either directly 1995; Locke et al., 1997). Although the extent of sorp- or via subsequent foliar washoff. This study examined sorption, degra- tion in soil is generally proportional to OC content dation, and mobility of the postemergence herbicide acifluorfen (5-[2- (Gennari et al., 1994b; NeÁgre et al., 1995; Locke et al., chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoic acid) in Dundee 1997), sorption likely involves processes other than par- silty clay loam (fine-silty, mixed, thermic, Aeric Ochraqualf) taken titioning between aqueous and organic matter phases. from conventional till (CT) and no-till (NT) field plots. Homogeneous In particular, acifluorfen forms complexes with divalent surface and subsurface samples were used in the sorption and degrada- tion studies; intact soil columns (30 cm long and 10 cm diam.) were and trivalent cations (Pusino et al., 1991; Pusino et al., used in the mobility study. Batch sorption isotherms were nonlinear 1993) that may be sorbed or precipitated. Complex for- (Freundlich model) and sorption paralleled organic C (OC) content. mation and subsequent sorption may partially account All tillage by depth combinations of soil exhibited a time-dependent for increased acifluorfen sorption with decreasing soil approach to sorption equilibrium that was well described by a two- pH or increasing cation exchange capacity (Pusino et site equilibrium±kinetic model. -
40 CFR Ch. I (7–1–18 Edition) § 455.61
§ 455.61 40 CFR Ch. I (7–1–18 Edition) from: the operation of employee show- § 455.64 Effluent limitations guidelines ers and laundry facilities; the testing representing the degree of effluent of fire protection equipment; the test- reduction attainable by the applica- ing and emergency operation of safety tion of the best available tech- showers and eye washes; or storm nology economically achievable water. (BAT). (d) The provisions of this subpart do Except as provided in 40 CFR 125.30 not apply to wastewater discharges through 125.32, any existing point from the repackaging of microorga- source subject to this subpart must nisms or Group 1 Mixtures, as defined achieve effluent limitations rep- under § 455.10, or non-agricultural pes- resenting the degree of effluent reduc- ticide products. tion attainable by the application of the best available technology economi- § 455.61 Special definitions. cally achievable: There shall be no dis- Process wastewater, for this subpart, charge of process wastewater pollut- means all wastewater except for sani- ants. tary water and those wastewaters ex- § 455.65 New source performance cluded from the applicability of the standards (NSPS). rule in § 455.60. Any new source subject to this sub- § 455.62 Effluent limitations guidelines part which discharges process waste- representing the degree of effluent water pollutants must meet the fol- reduction attainable by the applica- lowing standards: There shall be no dis- tion of the best practicable pollut- charge of process wastewater pollut- ant control technology (BPT). ants. Except as provided in 40 CFR 125.30 through 125.32, any existing point § 455.66 Pretreatment standards for existing sources (PSES). -
WO 2013/037955 Al 21 March 2013 (21.03.2013) P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization I International Bureau (10) International Publication Number (43) International Publication Date WO 2013/037955 Al 21 March 2013 (21.03.2013) P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every A01N 25/00 (2006.01) A OIN 43/653 (2006.01) kind of national protection available): AE, AG, AL, AM, A0 41/06 (2006.01) A01N 37/50 (2006.01) AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, (21) Number: International Application DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, PCT/EP2012/068096 HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KM, KN, KP, (22) International Filing Date: KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, 14 September 2012 (14.09.2012) ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, (25) Filing Language: English RW, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, (26) Publication Language: English TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: 1118 1702.9 16 September 201 1 (16.09.201 1) EP (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, (71) Applicant (for all designated States except US): BAYER GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, INTELLECTUAL PROPERTY GMBH [DE/DE]; Al- UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, fred-Nobel-Str. -
R Graphics Output
Dexamethasone sodium phosphate ( 0.339 ) Melengestrol acetate ( 0.282 ) 17beta−Trenbolone ( 0.252 ) 17alpha−Estradiol ( 0.24 ) 17alpha−Hydroxyprogesterone ( 0.238 ) Triamcinolone ( 0.233 ) Zearalenone ( 0.216 ) CP−634384 ( 0.21 ) 17alpha−Ethinylestradiol ( 0.203 ) Raloxifene hydrochloride ( 0.203 ) Volinanserin ( 0.2 ) Tiratricol ( 0.197 ) trans−Retinoic acid ( 0.192 ) Chlorpromazine hydrochloride ( 0.191 ) PharmaGSID_47315 ( 0.185 ) Apigenin ( 0.183 ) Diethylstilbestrol ( 0.178 ) 4−Dodecylphenol ( 0.161 ) 2,2',6,6'−Tetrachlorobisphenol A ( 0.156 ) o,p'−DDD ( 0.155 ) Progesterone ( 0.152 ) 4−Hydroxytamoxifen ( 0.151 ) SSR150106 ( 0.149 ) Equilin ( 0.3 ) 3,5,3'−Triiodothyronine ( 0.256 ) 17−Methyltestosterone ( 0.242 ) 17beta−Estradiol ( 0.24 ) 5alpha−Dihydrotestosterone ( 0.235 ) Mifepristone ( 0.218 ) Norethindrone ( 0.214 ) Spironolactone ( 0.204 ) Farglitazar ( 0.203 ) Testosterone propionate ( 0.202 ) meso−Hexestrol ( 0.199 ) Mestranol ( 0.196 ) Estriol ( 0.191 ) 2,2',4,4'−Tetrahydroxybenzophenone ( 0.185 ) 3,3,5,5−Tetraiodothyroacetic acid ( 0.183 ) Norgestrel ( 0.181 ) Cyproterone acetate ( 0.164 ) GSK232420A ( 0.161 ) N−Dodecanoyl−N−methylglycine ( 0.155 ) Pentachloroanisole ( 0.154 ) HPTE ( 0.151 ) Biochanin A ( 0.15 ) Dehydroepiandrosterone ( 0.149 ) PharmaCode_333941 ( 0.148 ) Prednisone ( 0.146 ) Nordihydroguaiaretic acid ( 0.145 ) p,p'−DDD ( 0.144 ) Diphenhydramine hydrochloride ( 0.142 ) Forskolin ( 0.141 ) Perfluorooctanoic acid ( 0.14 ) Oleyl sarcosine ( 0.139 ) Cyclohexylphenylketone ( 0.138 ) Pirinixic acid ( 0.137 ) -
Ecological Risk Assessment for Saflufenacil
TEXT SEARCHABLE DCOUMENT 2011 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 OFFICE OF CEMICAL SAFETY AND POLLUTION PREVENTION PC Code: 118203 DP Barcode: 380638 and 381293 Thursday, April 07, 2011 MEMORANDUM SUBJECT: Ecological Risk Assessment for Saflufenacil Section 3 New Chemical Uses as a harvest aid on dry edible beans, dry peas, soybean, oilseeds "sunflower subgroup 20B", oilseeds "cotton subgroup 20C", and oilseeds canola "subgroup 20A". TO: Kathryn Montague, M.S., Product Manager 23 Herbicide Branch Registration Division (RD) (7505P) FROM: ~ Mohammed Ruhman, Ph.D., Agronomist 2 :4- . ""=- ........ 04!tJt! (I neith Sappington, Senior Biologist/Science Adviso~.... Vd- Environmental Risk Branch V O'f/ .../ II Environmental Fate and Effects Division (7507P) THROUGH: Mah Shamim, Ph.D., Branch Chief Environmental Risk Branch VI Environmental Fate and Effects Division (7507P) This ecological risk assessment for saflufenacil new uses is relying on the attached previous assessment (Attachment 1). As shown in the usage summary (Table 1), the single and seasonal rate, for all the crops range from 0.045 to 0.089 lbs a.i/A are within the range application rates used in exposure modeling for the 2009 Section 3 New Chemical Environmental Fate and Ecological Risk Assessment (DP Barcode 349855). Therefore, risk findings determined for the 2009 assessment may be used in the assessment for this submittal. Specifically, the 2009 assessment found no chronic risks to avian and mammalian species at an agricultural use rate 0 0.134 lb a.i.lA. Acute risks were not determined for birds and mammals since saflufenacil was not acutely toxic at the highest doses tested. -
Reduction of Nitroaromatic Pesticides with Zero-Valent Iron
Chemosphere 54 (2004) 255–263 www.elsevier.com/locate/chemosphere Reduction of nitroaromatic pesticides with zero-valent iron Young-Soo Keum, Qing X. Li * Department of Molecular Biosciences and Bioengineering, University of Hawaii, 1955 East-West Road, Ag Sci 218, Honolulu, HI 96822, USA Received 5 February 2003; received in revised form 4 June 2003; accepted 4 August 2003 Abstract Reduction of eleven nitroaromatic pesticides was studied with zero-valent iron powder. Average half-lives ranged from 2.8 to 6.3 h and the parent compounds were completely reduced after 48–96 h. The di-nitro groups of the 2,6- dinitroaniline herbicides were rapidly reduced to the corresponding diamines, with a negligible amount of partially reduced monoamino or nitroso products. Low levels of de-alkylated products were observed after 10 days. The nitro group of the organophosphorus insecticides was reduced dominantly to the monoamines but in a slower rate than the 2,6-dinitroanilines. A trace amount of oxon products was found. Reduction of nitro to amino was also the predominant reaction for the diphenyl ether herbicides. Aromatic de-chlorination and de-alkylation were minor reactions. These amine products were more stable than the parent compounds and 60% or more of the amines were detected after two weeks. Humic acid decreased the reduction rates of pendimethalin, and dichlone (a known quinone redox mediator) counteracted the effect of humic acid on the reactivity. Storage of iron powder under air decreased the reactivity very rapidly due to iron oxidation. Repeated use of iron powder also showed similar results. The reduced activity of air- oxidized iron was recovered by purging with hydrogen, but not nitrogen. -
PUBLIC WATER SUPPLY SAMPLING PLAN for Contaminants with a Vermont Health Advisory – May 2020
PROPOSED PUBLIC WATER SUPPLY SAMPLING PLAN For Contaminants with a Vermont Health Advisory – May 2020 Vermont Department of Environmental Conservation Drinking Water & Groundwater Protection Division A Plan to Sample for Chemicals with a Vermont Health Advisory As required by Act 21 (2019), Section 10(b), the Secretary of the Agency of Natural Resources, on or before January 1, 2020, must publish for public review and comment a plan to collect data for contaminants in drinking water from public community water systems and all non-transient non-community water systems, for which a health advisory has been established, but no Maximum Contaminant Level has been adopted. These health advisories are referred to as Vermont Health Advisories (VHAs) in this document. 1 | P a g e TABLE OF CONTENTS I. Executive Summary …………………………………………………………………………………………..Page 3 II. Background ……………………………………………………………………………………………………… Page 4 III. Determining the VHA contaminants for sampling at public water systems ………..Page 6 IV. Sampling Considerations …..…………………………………………………………………………….. Page 10 V. Proposed Sampling Plan ………………………………………………………………………….………..Page 12 Attachments Table 1 Complete List of Vermont Health Advisories (VHAs) …………………………………………..Page 13 Table 2 Proposed List of VHAs with Potential Concern ……………………………………………………Page 18 2 | P a g e I. Executive Summary The Secretary of the Agency of Natural Resources was tasked with developing a sampling plan for public review, for certain drinking water contaminants that have an established health advisory, also known as the Vermont Health Advisory (VHA) but have no Maximum Contaminant Level (MCL). This Sampling Plan (Plan) is targeted to public community and public non- transient non-community water systems. To provide context for public water system regulation, and standards that apply, a discussion of how VHAs and MCLs are determined is given.