Bullet Holes and Chemical Residues in Shooting Cases Joseph T
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Journal of Criminal Law and Criminology Volume 31 Article 13 Issue 4 November-December Winter 1940 Bullet Holes and Chemical Residues in Shooting Cases Joseph T. Walker Follow this and additional works at: https://scholarlycommons.law.northwestern.edu/jclc Part of the Criminal Law Commons, Criminology Commons, and the Criminology and Criminal Justice Commons Recommended Citation Joseph T. Walker, Bullet Holes and Chemical Residues in Shooting Cases, 31 Am. Inst. Crim. L. & Criminology 497 (1940-1941) This Criminology is brought to you for free and open access by Northwestern University School of Law Scholarly Commons. It has been accepted for inclusion in Journal of Criminal Law and Criminology by an authorized editor of Northwestern University School of Law Scholarly Commons. BULLET HOLES AND CHEMICAL RESIDUES IN SHOOTING CASES Joseph T. Walkert Several new and important objec- value in reconstructing the circum- tives are introduced when the medico- stances surrounding the shooting and legal post-mortem examination of the in apprehending the responsible per- victim of a gunshot injury is under- son can hardly be over-estimated. taken. In ordinary practice an autopsy Observations bearing on the answers is performed to secure information of to questions proposed in the preceding medical or scientific interest. In medico- paragraph fall in three categories. legal practice it is performed primarily In the first category are the physical to determine, for legal purposes, the characteristics of the wounds. Excel- cause of death. Although both of these lent descriptions of wounds are to be objectives are important, many medical found in many of the more recent text- examiners and investigating officers are books on legal medicine (84) (85). unfamiliar with certain potentially rich These include descriptions and illustra- sources of information which are ex- tions of the differences between wounds tremely useful in the investigation of of exit and entrance; the characteris- the crime. To determine the cause of tics of the shot canal which indicate the death is, of course, fundamental. But direction of flight of the projectile; the to determine, insofar as possible, the evidences of explosive effects as are to circumstances surrounding the fatal be seen in contact shots; peculiarities acts is often more useful in the admin- of wounds attributable to the form and istration of justice. Among others, an- velocity of the bullet which produced swers to the following questions should them; peculiarities of wounds produced be sought. Was the wound produced by spent bullets or bullets in ricochet. by a bullet? Could the injury have In the second category are the iden- been self-inflicted? From what direc- tifying features of bullets found in, or tion was the shot fired? How far was shell cases found near, the body. The the gun from the victim when the shot matching of bullets or shell cases for was fired? What kind of ammunition the identification or exclusion of ques- was used? What kind of firearm was tioned weapons constitutes a highly used? specialized science which has been ade- The answer to these and other ques- quately presented by many authors tions may depend entirely upon the ex- (83). amination of the body and clothing of It is with the third category of ob- the victim. With the legal status of servations that this paper is principally evidence of this kind already estab- concerned. This has to do with the lished in the higher courts (27), its identification and interpretation of resi- dues of powder, lubricants, and metals t Massachusetts State Police, and Department of Legal Medicine, Harvard University. which may be found on the skin or [ 497 1 JOSEPH T. WALKER clothing of the victim, or in the wound Bullet: The bullet from an automa- itself. It is necessary first to consider tic pistol cartridge generally consists briefly the components of the firearm of a lead core covered with a gilding and the cartridge in order to appreciate metal jacket (copper alloyed with 5 to the significance of these residues. 10% of zinc). This jacket may be bare or Firearm: For the purposes of this plated with tin, or, rarely in this coun- discussion only hand firearms (revol- try, nickel. A bullet of this type is vers and automatic pistols) will be in- designated as "full metal-jacket." In cluded. The barrel is generally made cartridges designed for revolvers the of iron or steel, rifled with from four to seven lands and grooves, twisting bullet is generally soft. It may be com- to either the right or left. Frequently posed of relatively pure lead, lead it is fouled from previous shots, plated with a thin layer of copper, or rusted, or oiled. Examination of the lead alloyed with antimony, tin, or with interior will usually disclose the both antimony and tin. Spectrographic presence of metal fragments de- analysis of lead bullets shows the pres- rived from previous shots embedded ence of other elements in traces: cop- in the depressions of the gun bar- per, bismuth, silver and, occasionally, rel. This is particularly true near thallium (18) (75). Some revolver the breech where erosion of the barrel bullets have a copper or plated jacket is likely to be greatest (86) and where extending about halfway back from the surface of the bullet has been sub- the tip to the base. The soft metal of jected to the greatest stress at its cir- the core is exposed on the circumfer- cumference. Here the metal may often ence of the bullet near the base. In be seen to lie in strips at the edges of others, such as hollow point and soft the lands which impart the rotational point bullets, the jacket covers the base thrust to the bullet. Moreover, foul- and cylindrical portion, leaving soft ing from the powder charge and primer metal exposed at the tip. In all bullets, charge is frequently present and can be including jacketed bullets, the soft easily proved chemically. It is there- metal of the core is exposed at the fore possible that a bullet fired from base, or at the tip, or both. such a gun may carry with it traces of Lubrication: In general lead bullets any or all of the materials present on designed for revolvers are lubricated the interior of the gun barrel-iron, by means of a semi-solid waxlike lubri- rust, oil and metals, as well as powder cant. Jacketed bullets designed for au- and primer fouling of previous shots. tomatic pistols are not so lubricated Cartridge Case: The cartridge case in (36). Spectrographic analyses con- most instances is of brass. Within re- ducted in this laboratory have shown cent years the primer cap at the base that the lubrication is generally con- of the cartridge has been nickel-plated. taminated with lead, either mechanic- Occasionally one also finds the brass ally or by the formation of lead com- case nickel-plated. pounds. BULLET HOLES AND CHEMICAL RESIDUES Powder: Formerly the propellant compounds, including lead azide and charge in a cartridge was composed of lead styphnate; and potassium chlorate black powder. Since the introduction has been replaced by barium nitrate. of smokeless powder, black powder So where the residue of an old type charges have gradually disappeared, primer characteristically contains mer- until at present it is rare to find black cury and potassium, the residue of a powder cartridges. Black powder is modern primer characteristically con- a mixture of about 75% potassium ni- tains lead and barium. Antimony in trate, 15% sulfur and 10% charcoal. the form of stibnite is generally found Upon explosion it yields as solid resi- in both old and new primers. Zirconium dues mainly potassium sulfate, potas- metal is the latest element to be en- sium sulfide and potassium carbonate, countered. Recent analysis of the together with traces of the original primer residues of ninety-six makes components and nitrites, thiocyanates, and types of cartridges representing and thiosulfates (39) (68). both old and new ammunition with Smokeless powder is composed es- black and smokeless powder showed sentially of cellulose nitrate (single that the following elements were pres- base powder) or cellulose nitrate with ent in the percentage of residues in- nitroglycerine (double base powder) dicated. (68). The powder grains are generally Percentageof coated with graphite and are in the Element PrimerResidues form of disks or squares. Upon explo- Barium ................ 90% Antimony .............. 87% sion, smokeless powders leave very Lead .................. 75% little solid residue. That which is left Mercury ............... 67% consists of carbonized matter or graph- Potassium .............. 31% Tin .................... 9% ite in the form of a fine dust and un- Manganese ............. 4% burned or partially-burned grains of Zirconium .............. 1% powder, ranging in size from large Subsequent information received from visible particles to fine dust. Nitrites cartridge manufacturers indicates that and cellulose nitrate are the detectable tin compounds are not incorporated in chemical entities in this residue. primer mixtures, as the spectrographic Primer: Some years ago a typical analyses of the residues above would primer mixture contained mercury ful- imply. Primers leaving tin in the resi- minate, stibnite (native antimony sul- due of the explosion were therefore fide), potassium chlorate and powdered removed from the cartridges by the glass. Subsequently attempts were method of Chamot (82). In each in- made to eliminate mercury and to re- stance the primer compound was found duce the rust-producing properties of to be sealed into the cup with a small the residue of potassium chlorate. (26). disk of soft metal foil. The foil was This has resulted in the production of composed of a lead tin alloy, weighing primers in which the mercury has been about 10 mg The disintegration of partially or entirely replaced by lead this foil upon firing doubtless gave rise JOSEPH T.