Atmos. Chem. Phys., 17, 8939–8958, 2017 https://doi.org/10.5194/acp-17-8939-2017 © Author(s) 2017. This work is distributed under the Creative Commons Attribution 3.0 License. Speciation of organic aerosols in the Saharan Air Layer and in the free troposphere westerlies M. Isabel García1,2, Barend L. van Drooge3, Sergio Rodríguez1, and Andrés Alastuey3 1Izaña Atmospheric Research Centre, AEMET, Joint Research Unit to CSIC Studies on Atmospheric Pollution, Santa Cruz de Tenerife, 38001, Spain 2Department of Chemistry (T.U. Analytical Chemistry), Faculty of Science, University of La Laguna, La Laguna, 38206, Spain 3Institute of Environmental Assessment and Water Research, CSIC, Barcelona, 08034, Spain Correspondence to: Sergio Rodríguez (
[email protected]) Received: 3 February 2017 – Discussion started: 27 February 2017 Revised: 14 June 2017 – Accepted: 16 June 2017 – Published: 25 July 2017 Abstract. We focused this research on the composition of eral primary sources and SOA). When the Saharan Air Layer the organic aerosols transported in the two main airflows of shifted southward, Izaña was within the westerlies stream the subtropical North Atlantic free troposphere: (i) the Sa- and organic matter accounted for ∼ 28 % of the bulk mass haran Air Layer – the warm, dry and dusty airstream that of aerosols. In the westerlies, the organic aerosol species de- expands from North Africa to the Americas at subtropical termined accounted for 64 % of the bulk organic matter, with and tropical latitudes – and (ii) the westerlies, which flow SOA ISO and dicarboxylic acids being the most abundant; from North America over the North Atlantic at mid- and sub- the highest concentration of organic matter (3.6 µg m−3) and tropical latitudes.