DOCSLIB.ORG

Isocyanic Acid, 3,4- Dichlorophenyl Ester

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Isocyanic Acid, 3,4- Dichlorophenyl Ester Common Name: ISOCYANIC ACID, 3,4- DICHLOROPHENYL ESTER CAS Number: 102-36-3 DOT Number: UN 2250 RTK Substance number: 0658 DOT Hazard Class: 6.1 (Poisonous) Date: October 2001 Revision: April 2007 ------------------------------------------------------------------------- ------------------------------------------------------------------------- HAZARD SUMMARY * Isocyanic Acid, 3,4-Dichlorophenyl Ester can affect you * Exposure to hazardous substances should be routinely when breathed in. evaluated. This may include collecting personal and area * Contact can severely irritate the skin and eyes. air samples. You can obtain copies of sampling results * Breathing Isocyanic Acid, 3,4-Dichlorophenyl Ester can from your employer. You have a legal right to this irritate the nose and throat. information under the OSHA Access to Employee * Breathing Isocyanic Acid, 3,4-Dichlorophenyl Ester can Exposure and Medical Records Standard (29 CFR irritate the lungs causing coughing and/or shortness of 1910.1020). breath. Higher exposures may cause a build-up of fluid in * If you think you are experiencing any work-related health the lungs (pulmonary edema), a medical emergency, with problems, see a doctor trained to recognize occupational severe shortness of breath. diseases. Take this Fact Sheet with you. * Isocyanic Acid, 3,4-Dichlorophenyl Ester may cause a skin allergy. If allergy develops, very low future exposure WORKPLACE EXPOSURE LIMITS can cause itching and a skin rash. No occupational exposure limits have been established for * Isocyanic Acid, 3,4-Dichlorophenyl Ester may affect the Isocyanic Acid, 3,4-Dichlorophenyl Ester. This does not liver and kidneys. mean that this substance is not harmful. Safe work practices should always be followed. IDENTIFICATION Isocyanic Acid, 3,4-Dichlorophenyl Ester is a white to WAYS OF REDUCING EXPOSURE yellow sand-like solid. It is used to make other chemicals. * Where possible, enclose operations and use local exhaust ventilation at the site of chemical release. If local exhaust REASON FOR CITATION ventilation or enclosure is not used, respirators should be * Isocyanic Acid, 3,4-Dichlorophenyl Ester is on the worn. Hazardous Substance List because it is cited by DOT, DEP * Wear protective work clothing. and EPA. * Wash thoroughly immediately after exposure to Isocyanic * Definitions are provided on page 5. Acid, 3,4-Dichlorophenyl Ester and at the end of the workshift. HOW TO DETERMINE IF YOU ARE BEING * Post hazard and warning information in the work area. In EXPOSED addition, as part of an ongoing education and training The New Jersey Right to Know Act requires most employers effort, communicate all information on the health and to label chemicals in the workplace and requires public safety hazards of Isocyanic Acid, 3,4-Dichlorophenyl employers to provide their employees with information and Ester to potentially exposed workers. training concerning chemical hazards and controls. The federal OSHA Hazard Communication Standard (29 CFR 1910.1200) requires private employers to provide similar training and information to their employees. ISOCYANIC ACID, 3,4-DICHLOROPHENYL ESTER page 2 of 6 This Fact Sheet is a summary source of information of all Any evaluation should include a careful history of past and potential and most severe health hazards that may result from present symptoms with an exam. Medical tests that look for exposure. Duration of exposure, concentration of the substance damage already done are not a substitute for controlling and other factors will affect your susceptibility to any of the exposure. potential effects described below. -------------------------------------------------------------------------- Request copies of your medical testing. You have a legal right to this information under the OSHA Access to Employee HEALTH HAZARD INFORMATION Exposure and Medical Records Standard (29 CFR 1910.1020). Acute Health Effects Mixed Exposures The following acute (short-term) health effects may occur * Because smoking can cause heart disease, as well as lung immediately or shortly after exposure to Isocyanic Acid, 3,4- cancer, emphysema, and other respiratory problems, it may Dichlorophenyl Ester: worsen respiratory conditions caused by chemical exposure. Even if you have smoked for a long time, stopping now will * Contact can severely irritate the skin and eyes. reduce your risk of developing health problems. * Breathing Isocyanic Acid, 3,4-Dichlorophenyl Ester can * Because more than light alcohol consumption can cause irritate the nose and throat. liver damage, drinking alcohol may increase the liver * Breathing Isocyanic Acid, 3,4-Dichlorophenyl Ester can damage caused by Isocyanic Acid, 3,4-Dichlorophenyl irritate the lungs causing coughing and/or shortness of Ester. breath. Higher exposures may cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency, with WORKPLACE CONTROLS AND PRACTICES severe shortness of breath. Unless a less toxic chemical can be substituted for a hazardous Chronic Health Effects substance, ENGINEERING CONTROLS are the most The following chronic (long-term) health effects can occur at effective way of reducing exposure. The best protection is to some time after exposure to Isocyanic Acid, 3,4- enclose operations and/or provide local exhaust ventilation at Dichlorophenyl Ester and can last for months or years: the site of chemical release. Isolating operations can also reduce exposure. Using respirators or protective equipment is Cancer Hazard less effective than the controls mentioned above, but is * According to the information presently available to the New sometimes necessary. Jersey Department of Health and Senior Services, Isocyanic Acid, 3,4-Dichlorophenyl Ester has not been In evaluating the controls present in your workplace, consider: tested for its ability to cause cancer in animals. (1) how hazardous the substance is, (2) how much of the substance is released into the workplace and (3) whether Reproductive Hazard harmful skin or eye contact could occur. Special controls * According to the information presently available to the New should be in place for highly toxic chemicals or when Jersey Department of Health and Senior Services, significant skin, eye, or breathing exposures are possible. Isocyanic Acid, 3,4-Dichlorophenyl Ester has not been tested for its ability to affect reproduction. In addition, the following control is recommended: Other Long-Term Effects * Where possible, automatically transfer Isocyanic Acid, 3,4- * Isocyanic Acid, 3,4-Dichlorophenyl Ester may cause a Dichlorophenyl Ester from drums or other storage skin allergy. If allergy develops, very low future exposure containers to process containers. can cause itching and a skin rash. * Isocyanic Acid, 3,4-Dichlorophenyl Ester may affect the Good WORK PRACTICES can help to reduce hazardous liver and kidneys. exposures. The following work practices are recommended: MEDICAL * Workers whose clothing has been contaminated by Isocyanic Acid, 3,4-Dichlorophenyl Ester should change into clean clothing promptly. Medical Testing * Do not take contaminated work clothes home. Family If symptoms develop or overexposure is suspected, the members could be exposed. following are recommended: * Contaminated work clothes should be laundered by individuals who have been informed of the hazards of * Consider chest x-ray after acute overexposure exposure to Isocyanic Acid, 3,4-Dichlorophenyl Ester. * Liver and kidney function tests * Eye wash fountains should be provided in the immediate * Evaluation by a qualified allergist, including careful work area for emergency use. exposure history and special testing, may help diagnose * If there is the possibility of skin exposure, emergency skin allergy. shower facilities should be provided. * On skin contact with Isocyanic Acid, 3,4-Dichlorophenyl Ester, immediately wash or shower to remove the chemical. ISOCYANIC ACID, 3,4-DICHLOROPHENYL ESTER page 3 of 6 At the end of the workshift, wash any areas of the body that respirator manufacturer to determine which respirator is may have contacted Isocyanic Acid, 3,4-Dichlorophenyl appropriate for your facility. Ester, whether or not known skin contact has occurred. * If while wearing a filter or cartridge respirator you can * Do not eat, smoke, or drink where Isocyanic Acid, 3,4- smell, taste, or otherwise detect Isocyanic Acid, 3,4- Dichlorophenyl Ester is handled, processed, or stored, Dichlorophenyl Ester, or if while wearing particulate since the chemical can be swallowed. Wash hands filters abnormal resistance to breathing is experienced, or carefully before eating, drinking, applying cosmetics, eye irritation occurs while wearing a full facepiece smoking, or using the toilet. respirator, leave the area immediately. Check to make sure * Use a vacuum or a wet method to reduce dust during clean- the respirator-to-face seal is still good. If it is, replace the up. DO NOT DRY SWEEP. filter or cartridge. If the seal is no longer good, you may need a new respirator. PERSONAL PROTECTIVE EQUIPMENT * Be sure to consider all potential exposures in your workplace. You may need a combination of filters, WORKPLACE CONTROLS ARE BETTER THAN prefilters or cartridges to protect against different forms of a PERSONAL PROTECTIVE EQUIPMENT. However, for chemical (such as vapor and mist) or against a mixture of some jobs (such as outside work, confined space entry, jobs chemicals. done only once in a while, or jobs done while workplace * Where the potential for high exposure exists, use a NIOSH controls
Load more

Recommended publications
  • Urea Decomposition and SCR Performance at Low Temperature
    Urea Decomposition and SCR Performance at Low Temperature Scott Sluder, John Storey, Sam Lewis, Linda Lewis, Oak Ridge National Laboratory 10th Annual DEER Workshop Coronado, CA September 2, 2004 Sponsors: DOE-OFCVT, Steve Goguen and Kevin Stork OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY 1 Why study urea decomposition? • Under light-duty conditions (< 250 °C), there is negligible urea decomposition in the gas phase. Current models assume NH3 as input to catalyst. • It appears that urea decomposition kinetics on catalyst surfaces has to be understood. This will affect the length of the catalyst that is used for urea decomposition. OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY 2 Urea/SCR Chemistry Ideally, injected urea decomposes to NH3 O Heat NH3 + HCNO H2O, O2 isocyanic acid H 2N NH2 Heat HCNO NH3 + CO2 isocyanic acid H2O then reacts with NOX to form N2. 2 NH3 + NO + NO2 ⇔ 2 N2 + 3 H2O OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY 3 Unusual things can happen, such as ammonium nitrate formation and decomposition at T < 200 °C. 2NH3 + 2NO2 →NH4NO3 + N2 + 3 H2O NH4NO3 ⇔ NH3 + HNO3 2HNO3 + NO → 3 NO2 + H2O M. Koebel et al. in Ind.Eng.Chem.Res.: 39,p. 4120; 40, p. 52; 41, p.4008; 42, p.2093 Also in Catal.Today, 73, p.239 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY 4 Experimental Approach • Use engine controls to: − Vary temperature − Keep constant: NOX and exhaust flow. • Investigate urea decomposition (if any) upstream of SCR catalyst. • Analyze exhaust products exiting undersized monoliths to elucidate urea decomposition − 3” and 6” monoliths = space velocities of 25K and 50K − const.
    [Show full text]
  • This Item Was Submitted to Loughborough University
    This item was submitted to Loughborough University as an MPhil thesis by the author and is made available in the Institutional Repository (https://dspace.lboro.ac.uk/) under the following Creative Commons Licence conditions. For the full text of this licence, please go to: http://creativecommons.org/licenses/by-nc-nd/2.5/ LOUGHBOROUGH UNIVERSITY OF TECHNOLOGY LIBRARY AUTHOR/FILING TITLE . -------------~§'~£~~~-~-;::r------_...: __________ i , ----------------!.------------------------ -- ----- - .....- , ACCESSION/COPY NO. --------------___ _L~~~~~/~~-----~- _____ ______ _ VOL. NO. CLASS MARK ISO C YA N I C ACID B Y D. J. BEL SON N .rkl ' A'~OCIORAL THESIS SUBMITTED IN PARTIAL FULFILMENT OF THE REQUIREMENTS FOR , . ." , THE AWARD OF ~,_~,.' , ~ kf\S-r.. tt ; ~eCTeR OF PHILOSOPHY OF THE LOUGHBOROUGH UNIVERSITY OF TECHNOLOGY - 1981\ SUPERVISOR: DRI A, N, STRACHAN DEPARTMENT OF CHEM I STRY © BY D. J. BELSON J 1981. ..... ~- ~~c. \0) 'to 'b/O"2- .-'-' , C O,N TEN T S Chapter 1 Intr6duction .. 1 2 Preparation and storage of isocyanic acid.­ 3 3 Physical properties and structure of isocyanic acid. 11 4 Methods of analysis for isocyanic acid. 17 5 The polymerisation of isocyanic acid. 21 6 Pyrolysis and photolysis of isocyanicacid. 34 7 Reactions in water. 36 8: Reaction 'with alcohols. 48 9 Reactions with ammonia and amines. 52 10 Other addition reactions across th'e N=C double bond. 57· 11 Addition of isocyanic acid to unsaturated molecules. 65 12 Summary and conclUsions. 69 Acknowledgements. 82 Ref erenc es. 83 Figures Opposite Page 1 Van't Hoff equation plot for the gas- 23 phase depolymerisation of cyanuric acid. 2 Values of pKfor isocyanic acid 37 dissociation~;'- plotted against temperature.
    [Show full text]
  • Sources of Isocyanic Acid (HNCO) Indoors: a Focus on Cigarette Smoke
    TSpace Research Repository tspace.library.utoronto.ca Sources of isocyanic acid (HNCO) indoors: a focus on cigarette smoke Rachel F. Hems, Chen Wang, Douglas B. Collins, Shouming Zhou, Nadine Borduas-Dedekind, Jeffrey A. Siegel, Jonathan P.D. Abbatt Version Post-print/Accepted Manuscript Citation Hems, R.F., Wang, C., Collins, D.B., Zhou, S., Borduas-Dedekind, N., (published version) Siegel, J.A., Abbatt, J.P.D., 2019. Sources of isocyanic acid (HNCO) indoors: a focus on cigarette smoke. Environ. Sci.: Processes Impacts, 21, 1334. https://doi.org/10.1039/C9EM00107G. How to cite TSpace items Always cite the published version, so the author(s) will receive recognition through services that track citation counts, e.g. Scopus. If you need to cite the page number of the author manuscript from TSpace because you cannot access the published version, then cite the TSpace version in addition to the published version using the permanent URI (handle) found on the record page. This article was made openly accessible by U of T Faculty. Please tell us how this access benefits you. Your story matters. 1 Sources of isocyanic acid (HNCO) indoors: a focus on cigarette smoke 2 Rachel F. Hems,† Chen Wang,† Douglas B. Collins,ǂ Shouming Zhou,† Nadine Borduas- 3 Dedekind,† Jeffrey A. Siegel,‡ Jonathan P.D. Abbatt*† 4 †Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 5 3H6, Canada. 6 ‡Department of Civil and Mineral Engineering, University of Toronto, 35 Street George Street, 7 Toronto, Ontario M5S 1A4, Canada. 8 ǂDepartment of Chemistry, Bucknell University, 1 Dent Drive, Lewisburg, PA 17837, USA.
    [Show full text]
  • Surface Chemistry and Kinetics of the Hydrolysis of Isocyanic Acid on Anatase
    Technische Universität München Lehrstuhl 2 für Technische Chemie Surface chemistry and kinetics of the hydrolysis of isocyanic acid on TiO2 anatase Philipp Christian Dino Patrick Hauck Vollständiger Abdruck der von der Fakultät für Chemie der Technischen Universität München zur Erlangung des akademischen Grades eines Doktors der Naturwissenschaften (Dr.rer.nat.) genehmigten Dissertation. Vorsitzender: Univ.-Prof. Dr. Klaus Köhler Prüfer der Dissertation: 1. Univ.-Prof. Dr. Johannes A. Lercher 2. Univ.-Prof. Dr. Kai-Olaf Hinrichsen Die Dissertation wurde am 14.02.2007 bei der Technischen Universität München eingereicht und durch die Fakultät für Chemie am 16.04.2007 angenommen. Gott sei Dank! Nun ist’s vorbei mit der Übertäterei! Meine Damen und Herren, vielleicht hat niemand mehr damit gerechnet. Um so größer wird die Überraschung sein: Ich komme jetzt zum Ende. Wilhelm Busch (1832-1908) Acknowledgements Finally the PhD time has drawn to its close and the tamer of the isocyanic acid would like to say a few words of thank to a bunch of people who made a substantial contribution to the ultimate thesis. First of all I would like to thank Johannes (Prof. J.A. Lercher) for inviting me into his group and thus giving me the opportunity to work in a fairly international team on an adventurous project. Thank you for all the guidance, trust, fruitful, but also sharp- tongued discussions during the last three years three months and the sufficient freedom and independence with regard to structuring my work. The time at TC 2 has been an important and joyful part of my life for sure.
    [Show full text]
  • Arxiv:1510.07052V1 [Astro-Ph.EP] 23 Oct 2015 99 Lae Ta.20,Adrfrne Therein)
    A Chemical Kinetics Network for Lightning and Life in Planetary Atmospheres P. B. Rimmer1 and Ch Helling School of Physics and Astronomy, University of St Andrews, St Andrews, KY16 9SS, United Kingdom ABSTRACT There are many open questions about prebiotic chemistry in both planetary and exoplane- tary environments. The increasing number of known exoplanets and other ultra-cool, substellar objects has propelled the desire to detect life and prebiotic chemistry outside the solar system. We present an ion-neutral chemical network constructed from scratch, Stand2015, that treats hydrogen, nitrogen, carbon and oxygen chemistry accurately within a temperature range between 100 K and 30000 K. Formation pathways for glycine and other organic molecules are included. The network is complete up to H6C2N2O3. Stand2015 is successfully tested against atmo- spheric chemistry models for HD209458b, Jupiter and the present-day Earth using a simple 1D photochemistry/diffusion code. Our results for the early Earth agree with those of Kasting (1993) for CO2, H2, CO and O2, but do not agree for water and atomic oxygen. We use the network to simulate an experiment where varied chemical initial conditions are irradiated by UV light. The result from our simulation is that more glycine is produced when more ammonia and methane is present. Very little glycine is produced in the absence of any molecular nitrogen and oxygen. This suggests that production of glycine is inhibited if a gas is too strongly reducing. Possible applications and limitations of the chemical kinetics network are also discussed. Subject headings: astrobiology — atmospheric effects — molecular processes — planetary systems 1. Introduction The input energy source and the initial chem- istry have been varied across these different ex- The potential connection between a focused periments.
    [Show full text]
  • Investigating Diesel Engines As an Atmospheric Source of Isocyanic Acid in Urban Areas
    Atmos. Chem. Phys., 17, 8959–8970, 2017 https://doi.org/10.5194/acp-17-8959-2017 © Author(s) 2017. This work is distributed under the Creative Commons Attribution 3.0 License. Investigating diesel engines as an atmospheric source of isocyanic acid in urban areas Shantanu H. Jathar1, Christopher Heppding1, Michael F. Link2, Delphine K. Farmer2, Ali Akherati1, Michael J. Kleeman3, Joost A. de Gouw4,5, Patrick R. Veres4,5, and James M. Roberts4 1Department of Mechanical Engineering, Colorado State University, Fort Collins, CO 80523, USA 2Department of Chemistry, Colorado State University, Fort Collins, CO 80523, USA 3Department of Civil and Environmental Engineering, University of California Davis, Davis, CA 95616, USA 4NOAA Earth System Research Laboratory, Chemical Sciences Division, Boulder, CO 80305, USA 5Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80305, USA Correspondence to: Shantanu H. Jathar ([email protected]) Received: 20 January 2017 – Discussion started: 22 February 2017 Revised: 18 May 2017 – Accepted: 19 May 2017 – Published: 26 July 2017 Abstract. Isocyanic acid (HNCO), an acidic gas found in implied that diesel-powered engines were the largest source tobacco smoke, urban environments, and biomass-burning- of HNCO in urban areas. The CTM also predicted that daily- affected regions, has been linked to adverse health outcomes. averaged concentrations of HNCO reached a maximum of Gasoline- and diesel-powered engines and biomass burning ∼ 110 pptv but were an order of magnitude lower than the are known to emit HNCO and hypothesized to emit pre- 1 ppbv level that could be associated with physiological ef- cursors such as amides that can photochemically react to fects in humans.
    [Show full text]
  • Evaluation of Chemical and Particle Exposures During Vehicle Fire Suppression Training
    This Health Hazard Evaluation (HHE) report and any recommendations made herein are for the specific facility evaluated and may not be universally applicable. Any recommendations made are not to be considered as final statements of NIOSH policy or of any agency or individual involved. Additional HHE reports are available at http://www.cdc.gov/niosh/hhe/ Workplace Safety and Health Evaluation of Chemical and Particle Exposures During Vehicle Fire Suppression Training Kenneth W. Fent, PhD Douglas E. Evans, PhD James Couch, MS, CIH Health Hazard Evaluation Report HETA 2008-0241-3113 Miami Township Fire and Rescue Yellow Springs, Ohio July 2010 Department of Health and Human Services Centers for Disease Control and Prevention National Institute for Occupational Safety and Health The employer shall post a copy of this report for a period of 30 calendar days at or near the workplace(s) of affected employees. The employer shall take steps to insure that the posted determinations are not altered, defaced, or covered by other material during such period. [37 FR 23640, November 7, 1972, as amended at 45 FR 2653, January 14, 1980]. CONTENTS REPO R T Abbreviations .......................................................................ii Highlights of the NIOSH Health Hazard Evaluation ............iv Summary ............................................................................vi Introduction ..........................................................................1 Assessment .........................................................................3
    [Show full text]
  • Isocyanic Acid and Ammonia in Vehicle Emissions ⇑ ⇑ R
    View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Elsevier - Publisher Connector Transportation Research Part D 49 (2016) 259–270 Contents lists available at ScienceDirect Transportation Research Part D journal homepage: www.elsevier.com/locate/trd Isocyanic acid and ammonia in vehicle emissions ⇑ ⇑ R. Suarez-Bertoa , C. Astorga European Commission Joint Research Centre Ispra, Institute for Energy and Transport, Sustainable Transport Unit, 21027 Ispra, VA Italy article info abstract Article history: Vehicles are considered to be an important source of ammonia (NH3) and isocyanic acid Available online 22 October 2016 (HNCO). HNCO and NH3 have been shown to be toxic compounds. Moreover, NH3 is also a precursor in the formation of atmospheric secondary aerosols. For that reason, real- Keywords: time vehicular emissions from a series of Euro 5 and Euro 6 light-duty vehicles, including Vehicle emissions spark ignition (gasoline and flex-fuel), compression ignition (diesel) and a plug-in electric HNCO hybrid, were investigated at 23 and À7 °C over the new World harmonized Light-duty NH 3 vehicle Test Cycle (WLTC) in the Vehicle Emission Laboratory at the European WLTC Commission Joint Research Centre Ispra, Italy. The median HNCO emissions obtained for DeNOx the studied fleet over the WLTC were 1.4 mg kmÀ1 at 23 °C and 6 mg kmÀ1 at À7 °C. The À1 À1 fleet median NH3 emission factors were 10 mg km and 21 mg km at 23 and À7 °C, respectively. The obtained results show that even though three-way catalyst (TWC), selec- tive catalytic reduction (SCR), and NOx storage catalyst (NSC) are effective systems to reduce NOx vehicular emissions, they also lead to considerable emissions of the byproducts NH3 and/or HNCO.
    [Show full text]
  • Large Unexplained Suite of Chemically Reactive Compounds Present In
    www.nature.com/scientificreports OPEN Large unexplained suite of chemically reactive compounds present in ambient air due to Received: 2 October 2017 Accepted: 22 December 2017 biomass fres Published: xx xx xxxx V. Kumar , B. P. Chandra & V. Sinha Biomass fres impact global atmospheric chemistry. The reactive compounds emitted and formed due to biomass fres drive ozone and organic aerosol formation, afecting both air quality and climate. Direct hydroxyl (OH) Reactivity measurements quantify total gaseous reactive pollutant loadings and comparison with measured compounds yields the fraction of unmeasured compounds. Here, we quantifed the magnitude and composition of total OH reactivity in the north-west Indo-Gangetic Plain. More than 120% increase occurred in total OH reactivity (28 s−1 to 64 s−1) and from no missing OH reactivity in the normal summertime air, the missing OH reactivity fraction increased to ~40 % in the post-harvest summertime period infuenced by large scale biomass fres highlighting presence of unmeasured compounds. Increased missing OH reactivity between the two summertime periods was associated with increased concentrations of compounds with strong photochemical source such as acetaldehyde, acetone, hydroxyacetone, nitromethane, amides, isocyanic acid and primary emissions of acetonitrile and aromatic compounds. Currently even the most detailed state-of-the art atmospheric chemistry models exclude formamide, acetamide, nitromethane and isocyanic acid and their highly reactive precursor alkylamines (e.g. methylamine, ethylamine, dimethylamine, trimethylamine). For improved understanding of atmospheric chemistry-air quality-climate feedbacks in biomass-fre impacted atmospheric environments, future studies should include these compounds. Biomass burning is a widespread practice globally1, which causes soil nutrient loss and impacts atmospheric chemistry, air quality and climate2–4.
    [Show full text]
  • Investigation of the Hydrolysis of Isocyanic Acid in Urea Scr: Catalyst Screening and Low-Temperature Kinetics
    INVESTIGATION OF THE HYDROLYSIS OF ISOCYANIC ACID IN UREA SCR: CATALYST SCREENING AND LOW-TEMPERATURE KINETICS G. Piazzesi, M. Elsener, O. Kröcher, A. Wokaun Several oxide catalysts were tested for the hydrolysis of isocyanic acid under typical diesel exhaust condi- tions. Among the tested catalysts, TiO 2 and ZrO 2 have been shown to be the most active catalysts. The kinetics of the HNCO hydrolysis over TiO 2 at low temperatures was studied and reaction orders and the activation energy were determined. The effect of NO2 on the catalytic activity of TiO 2 was also investigated, revealing that, at low temperatures, the formation of ammonium nitrate inhibits the reaction. 1 INTRODUCTION The addition of NO 2 to the inlet gas caused a consid- erable decrease of the TiO 2 catalytic activity at low The Selective Catalytic Reduction with harmless urea temperatures (< 200°C). It was proven that, at these (urea SCR) is currently the most attractive method to temperatures, NO 2 reacts with NH 3 to form solid am- reduce NO x emissions from heavy-duty diesel engines monium nitrate that deposits on the catalyst surface [1]. In this process urea is first thermally decomposed blocking the active sites. Since ammonium nitrate is to isocyanic acid (HNCO) by fast heating, then, HNCO not stable at temperatures far above 200°C, the cata- is catalytically hydrolyzed to NH 3: lytic activity was completely restored by thermal treat- NH 2-CO-NH 2 → NH 3 + HNCO ment at 450°C in the absence of NO 2. These results are in good agreement with the findings of Koebel et HNCO + H 2O → NH 3 + CO 2 al.
    [Show full text]
  • O Formation in Combustion. the Synthesis and Analysis of HNCO
    I The importance of HNCO as a precursor of N20 formation in combustion. The synthesis and analysis of HNCO Margit Ruutelmann aSTRBUHON OF THIS DOCUMENT IS UNLIMITED --------------------------------------------------------------------------------------------- ------ ---------------------- ■ NUTEK, 117 86 Stockholm, Tel 08-744 95 00 (Fran 1 november 1992 nytt nummer: 08-681 91 00) Rapporterna kan besfallas (ran Studsviksbiblioteket, 611 82 Nykoping. Tel 0155-22 10 90, 22 10 00, Fax 0155-26 30 44 Narings- och teknikutvecklingsverket Titel: The importance of HNCO as a Precursor of NzO Formation in Combustion The Synthesis and Analysis of HNCO Forfattare: Margit Ruutelmann, CTH RAPPORT INOM OMRADET FORBRANNING OCH FORGASNING > . * Rapportnummer: FBT-95/9 Projektledare: Oliver Lindqvist Projektnummer: P276 358-4 och P1282-1 Kemiska forlopp FBC CTH Projekthandlaggare pa NUTEK: Rolf Ingman « Pastadress Besoksadress Telefoti Telefax Telex 117 86 Stockholm Liljeholmsvagen 32 08-681 91 00 08-19 68 26 10840 nutek s ISSN 0283-8575- Report OOK 93:03 The Importance of HNCO as a Precursor of NzO Formation in Combustion The Synthesis and Analysis of HNCO Margit Ruutelmann r ^ DEPARTMENT OF INORGANIC CHEMISTRY CHALMERS UNIVERSITY OF TECHNOLOGY and UNIVERSITY OF GOTEBORG S-412 96 GOTEBORG, SWEDEN Institutionen for Oorganisk Kemi Chalmers Tekniska Hogskola och Goteborgs Universitet Report OOK 93:03 The Importance of HNCO as a Precursor of N2O Formation in Combustion The Synthesis and Analysis of HNCO Margit Ruutelmann DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. The Importance of HNCO as a Precursor ofN20 Formation in Combustion The Synthesis and Analysis of HNCO Margit Riiiitelmann Department of Inorganic Chemistry Chalmers University of Technology and University of Goteborg S-41296 Goteborg Sweden December, 1993 Abstract The atmospheric N%0 concentration increases steadily.
    [Show full text]
  • Solubility and Reactivity of HNCO in Water: Insights Into HNCO’S Fate in the Atmosphere
    Atmos. Chem. Phys., 16, 703–714, 2016 www.atmos-chem-phys.net/16/703/2016/ doi:10.5194/acp-16-703-2016 © Author(s) 2016. CC Attribution 3.0 License. Solubility and reactivity of HNCO in water: insights into HNCO’s fate in the atmosphere N. Borduas, B. Place, G. R. Wentworth, J. P. D. Abbatt, and J. G. Murphy Department of Chemistry, University of Toronto, Toronto, Ontario, Canada Correspondence to: J. G. Murphy ([email protected]) Received: 24 July 2015 – Published in Atmos. Chem. Phys. Discuss.: 7 September 2015 Revised: 2 December 2015 – Accepted: 7 December 2015 – Published: 21 January 2016 Abstract. A growing number of ambient measurements 1 Introduction of isocyanic acid (HNCO) are being made, yet little is known about its fate in the atmosphere. To better understand HNCO’s loss processes and particularly its atmospheric Until recently, the interest in studying HNCO was from a partitioning behaviour, we measure its effective Henry’s fundamental science perspective with research conducted on eff its structure, preparation and physical properties (Belson and Law coefficient KH with a bubbler experiment using chemical ionization mass spectrometry as the gas phase Strachan, 1982) and on its theoretical rovibrational spectra analytical technique. By conducting experiments at different (Mladenovic´ and Lewerenz, 2008). Both theoretical and ex- pH values and temperature, a Henry’s Law coefficient KH perimental data indicate that HNCO is the most stable CHNO of 26 ± 2 M atm−1 is obtained, with an enthalpy of disso- isomer with a near-linear π-bond system (Hocking et al., − ± −1 eff 1975; Jones et al., 1950; Poppinger et al., 1977).
    [Show full text]