Appendix I Constants
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Quantum Theory of the Hydrogen Atom
Quantum Theory of the Hydrogen Atom Chemistry 35 Fall 2000 Balmer and the Hydrogen Spectrum n 1885: Johann Balmer, a Swiss schoolteacher, empirically deduced a formula which predicted the wavelengths of emission for Hydrogen: l (in Å) = 3645.6 x n2 for n = 3, 4, 5, 6 n2 -4 •Predicts the wavelengths of the 4 visible emission lines from Hydrogen (which are called the Balmer Series) •Implies that there is some underlying order in the atom that results in this deceptively simple equation. 2 1 The Bohr Atom n 1913: Niels Bohr uses quantum theory to explain the origin of the line spectrum of hydrogen 1. The electron in a hydrogen atom can exist only in discrete orbits 2. The orbits are circular paths about the nucleus at varying radii 3. Each orbit corresponds to a particular energy 4. Orbit energies increase with increasing radii 5. The lowest energy orbit is called the ground state 6. After absorbing energy, the e- jumps to a higher energy orbit (an excited state) 7. When the e- drops down to a lower energy orbit, the energy lost can be given off as a quantum of light 8. The energy of the photon emitted is equal to the difference in energies of the two orbits involved 3 Mohr Bohr n Mathematically, Bohr equated the two forces acting on the orbiting electron: coulombic attraction = centrifugal accelleration 2 2 2 -(Z/4peo)(e /r ) = m(v /r) n Rearranging and making the wild assumption: mvr = n(h/2p) n e- angular momentum can only have certain quantified values in whole multiples of h/2p 4 2 Hydrogen Energy Levels n Based on this model, Bohr arrived at a simple equation to calculate the electron energy levels in hydrogen: 2 En = -RH(1/n ) for n = 1, 2, 3, 4, . -
Relaxation Time
Today in Astronomy 142: the Milky Way’s disk More on stars as a gas: stellar relaxation time, equilibrium Differential rotation of the stars in the disk The local standard of rest Rotation curves and the distribution of mass The rotation curve of the Galaxy Figure: spiral structure in the first Galactic quadrant, deduced from CO observations. (Clemens, Sanders, Scoville 1988) 21 March 2013 Astronomy 142, Spring 2013 1 Stellar encounters: relaxation time of a stellar cluster In order to behave like a gas, as we assumed last time, stars have to collide elastically enough times for their random kinetic energy to be shared in a thermal fashion. But stellar encounters, even distant ones, are rare on human time scales. How long does it take a cluster of stars to thermalize? One characteristic time: the time between stellar elastic encounters, called the relaxation time. If a gravitationally bound cluster is a lot older than its relaxation time, then the stars will be describable as a gas (the star system has temperature, pressure, etc.). 21 March 2013 Astronomy 142, Spring 2013 2 Stellar encounters: relaxation time of a stellar cluster (continued) Suppose a star has a gravitational “sphere of influence” with radius r (>>R, the radius of the star), and moves at speed v between encounters, with its sphere of influence sweeping out a cylinder as it does: v V= π r2 vt r vt If the number density of stars (stars per unit volume) is n, then there will be exactly one star in the cylinder if 2 1 nV= nπ r vtcc =⇒=1 t Relaxation time nrvπ 2 21 March 2013 Astronomy 142, Spring 2013 3 Stellar encounters: relaxation time of a stellar cluster (continued) What is the appropriate radius, r? Choose that for which the gravitational potential energy is equal in magnitude to the average stellar kinetic energy. -
In-Class Worksheet on the Galaxy
Ay 20 / Fall Term 2014-2015 Hillenbrand In-Class Worksheet on The Galaxy Today is another collaborative learning day. As earlier in the term when working on blackbody radiation, divide yourselves into groups of 2-3 people. Then find a broad space at the white boards around the room. Work through the logic of the following two topics. Oort Constants. From the vantage point of the Sun within the plane of the Galaxy, we have managed to infer its structure by observing line-of-sight velocities as a function of galactic longitude. Let’s see why this works by considering basic geometry and observables. • Begin by drawing a picture. Consider the Sun at a distance Ro from the center of the Galaxy (a.k.a. the GC) on a circular orbit with velocity θ(Ro) = θo. Draw several concentric circles interior to the Sun’s orbit that represent the circular orbits of other stars or gas. Now consider some line of sight at a longitude l from the direction of the GC, that intersects one of your concentric circles at only one point. The circular velocity of an object on that (also circular) orbit at galactocentric distance R is θ(R); the direction of θ(R) forms an angle α with respect to the line of sight. You should also label the components of θ(R): they are vr along the line-of-sight, and vt tangential to the line-of-sight. If you need some assistance, Figure 18.14 of C/O shows the desired result. What we are aiming to do is derive formulae for vr and vt, which in principle are measureable, as a function of the distance d from us, the galactic longitude l, and some constants. -
Rydberg Constant and Emission Spectra of Gases
Page 1 of 10 Rydberg constant and emission spectra of gases ONE WEIGHT RECOMMENDED READINGS 1. R. Harris. Modern Physics, 2nd Ed. (2008). Sections 4.6, 7.3, 8.9. 2. Atomic Spectra line database https://physics.nist.gov/PhysRefData/ASD/lines_form.html OBJECTIVE - Calibrating a prism spectrometer to convert the scale readings in wavelengths of the emission spectral lines. - Identifying an "unknown" gas by measuring its spectral lines wavelengths. - Calculating the Rydberg constant RH. - Finding a separation of spectral lines in the yellow doublet of the sodium lamp spectrum. INSTRUCTOR’S EXPECTATIONS In the lab report it is expected to find the following parts: - Brief overview of the Bohr’s theory of hydrogen atom and main restrictions on its application. - Description of the setup including its main parts and their functions. - Description of the experiment procedure. - Table with readings of the vernier scale of the spectrometer and corresponding wavelengths of spectral lines of hydrogen and helium. - Calibration line for the function “wavelength vs reading” with explanation of the fitting procedure and values of the parameters of the fit with their uncertainties. - Calculated Rydberg constant with its uncertainty. - Description of the procedure of identification of the unknown gas and statement about the gas. - Calculating resolution of the spectrometer with the yellow doublet of sodium spectrum. INTRODUCTION In this experiment, linear emission spectra of discharge tubes are studied. The discharge tube is an evacuated glass tube filled with a gas or a vapor. There are two conductors – anode and cathode - soldered in the ends of the tube and connected to a high-voltage power source outside the tube. -
Improving the Accuracy of the Numerical Values of the Estimates Some Fundamental Physical Constants
Improving the accuracy of the numerical values of the estimates some fundamental physical constants. Valery Timkov, Serg Timkov, Vladimir Zhukov, Konstantin Afanasiev To cite this version: Valery Timkov, Serg Timkov, Vladimir Zhukov, Konstantin Afanasiev. Improving the accuracy of the numerical values of the estimates some fundamental physical constants.. Digital Technologies, Odessa National Academy of Telecommunications, 2019, 25, pp.23 - 39. hal-02117148 HAL Id: hal-02117148 https://hal.archives-ouvertes.fr/hal-02117148 Submitted on 2 May 2019 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Improving the accuracy of the numerical values of the estimates some fundamental physical constants. Valery F. Timkov1*, Serg V. Timkov2, Vladimir A. Zhukov2, Konstantin E. Afanasiev2 1Institute of Telecommunications and Global Geoinformation Space of the National Academy of Sciences of Ukraine, Senior Researcher, Ukraine. 2Research and Production Enterprise «TZHK», Researcher, Ukraine. *Email: [email protected] The list of designations in the text: l -
Chapter 09584
Author's personal copy Excitons in Magnetic Fields Kankan Cong, G Timothy Noe II, and Junichiro Kono, Rice University, Houston, TX, United States r 2018 Elsevier Ltd. All rights reserved. Introduction When a photon of energy greater than the band gap is absorbed by a semiconductor, a negatively charged electron is excited from the valence band into the conduction band, leaving behind a positively charged hole. The electron can be attracted to the hole via the Coulomb interaction, lowering the energy of the electron-hole (e-h) pair by a characteristic binding energy, Eb. The bound e-h pair is referred to as an exciton, and it is analogous to the hydrogen atom, but with a larger Bohr radius and a smaller binding energy, ranging from 1 to 100 meV, due to the small reduced mass of the exciton and screening of the Coulomb interaction by the dielectric environment. Like the hydrogen atom, there exists a series of excitonic bound states, which modify the near-band-edge optical response of semiconductors, especially when the binding energy is greater than the thermal energy and any relevant scattering rates. When the e-h pair has an energy greater than the binding energy, the electron and hole are no longer bound to one another (ionized), although they are still correlated. The nature of the optical transitions for both excitons and unbound e-h pairs depends on the dimensionality of the e-h system. Furthermore, an exciton is a composite boson having integer spin that obeys Bose-Einstein statistics rather than fermions that obey Fermi-Dirac statistics as in the case of either the electrons or holes by themselves. -
1. Physical Constants 1 1
1. Physical constants 1 1. PHYSICAL CONSTANTS Table 1.1. Reviewed 1998 by B.N. Taylor (NIST). Based mainly on the “1986 Adjustment of the Fundamental Physical Constants” by E.R. Cohen and B.N. Taylor, Rev. Mod. Phys. 59, 1121 (1987). The last group of constants (beginning with the Fermi coupling constant) comes from the Particle Data Group. The figures in parentheses after the values give the 1-standard- deviation uncertainties in the last digits; the corresponding uncertainties in parts per million (ppm) are given in the last column. This set of constants (aside from the last group) is recommended for international use by CODATA (the Committee on Data for Science and Technology). Since the 1986 adjustment, new experiments have yielded improved values for a number of constants, including the Rydberg constant R∞, the Planck constant h, the fine- structure constant α, and the molar gas constant R,and hence also for constants directly derived from these, such as the Boltzmann constant k and Stefan-Boltzmann constant σ. The new results and their impact on the 1986 recommended values are discussed extensively in “Recommended Values of the Fundamental Physical Constants: A Status Report,” B.N. Taylor and E.R. Cohen, J. Res. Natl. Inst. Stand. Technol. 95, 497 (1990); see also E.R. Cohen and B.N. Taylor, “The Fundamental Physical Constants,” Phys. Today, August 1997 Part 2, BG7. In general, the new results give uncertainties for the affected constants that are 5 to 7 times smaller than the 1986 uncertainties, but the changes in the values themselves are smaller than twice the 1986 uncertainties. -
Opacity and Emissivity in Spectral Lines (Cont)
PHYS 7810 / COLLAGE2021: Solar Spectral Line Diagnostics Lecture 05: Opacity and Emissivity in Spectral Lines (cont) Ivan Milic (CU Boulder) ; ivan.milic (at) colorado.edu Plan for today: ● On Tuesday we entered the discussion talking about emissivity and deriving an expression ● Today we are first going to do the same for opacity (but much faster) ● Then we are going to investigate some relationships between the two ● And to analyze, through equations how each physical parameter (T, p, v, B), influences opacity/emissivity. Once again, this is equation that includes it all This whole equation tells us how the things behave on big scales. (dl is geometrical length, and light propagates over very large distances inside of astrophysical objects. These two coefficients, on the other side, depend on specific physics of emission and absorption. We talk about them now Emissivity due to spectral line transitions ● This is only due to bound-bound processes, other sources would look differently ● Finding the number density of the atoms that are in the upper energy state (population of the upper level) will be the most cumbersome task. ● Also, line emission/absorption profile (often the same) contains many dependencies The absorption coefficient (opacity) ● We can have a very similar story here: ● The intensity should have units of inverse length. What if we relate it somehow to number density of absorption events (absorbers?) ● This is more “classical” than the previous argument, but it very intuitively tells us what opacity depends on! Let’s write -
Research Article Electron Density from Balmer Series Hydrogen Lines
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Crossref Hindawi Publishing Corporation International Journal of Spectroscopy Volume 2016, Article ID 7521050, 9 pages http://dx.doi.org/10.1155/2016/7521050 Research Article Electron Density from Balmer Series Hydrogen Lines and Ionization Temperatures in Inductively Coupled Argon Plasma Supplied by Aerosol and Volatile Species Jolanta Borkowska-Burnecka, WiesBaw gyrnicki, Maja WeBna, and Piotr Jamróz Chemistry Department, Division of Analytical Chemistry and Chemical Metallurgy, Wroclaw University of Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland Correspondence should be addressed to Wiesław Zyrnicki;˙ [email protected] Received 29 October 2015; Revised 15 February 2016; Accepted 1 March 2016 Academic Editor: Eugene Oks Copyright © 2016 Jolanta Borkowska-Burnecka et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Electron density and ionization temperatures were measured for inductively coupled argon plasma at atmospheric pressure. Different sample introduction systems were investigated. Samples containing Sn, Hg, Mg, and Fe and acidified with hydrochloric or acetic acids were introduced into plasma in the form of aerosol, gaseous mixture produced in the reaction of these solutions with NaBH4 and the mixture of the aerosol and chemically generated gases. The electron densities measured from H ,H,H,andH lines on the base of Stark broadening were compared. The study of the H Balmer series line profiles showed that the values from H and H were well consistent with those obtained from H which was considered as a common standard line for spectroscopic 15 15 −3 measurement of electron density. -
How the Saha Ionization Equation Was Discovered
How the Saha Ionization Equation Was Discovered Arnab Rai Choudhuri Department of Physics, Indian Institute of Science, Bangalore – 560012 Introduction Most youngsters aspiring for a career in physics research would be learning the basic research tools under the guidance of a supervisor at the age of 26. It was at this tender age of 26 that Meghnad Saha, who was working at Calcutta University far away from the world’s major centres of physics research and who never had a formal training from any research supervisor, formulated the celebrated Saha ionization equation and revolutionized astrophysics by applying it to solve some long-standing astrophysical problems. The Saha ionization equation is a standard topic in statistical mechanics and is covered in many well-known textbooks of thermodynamics and statistical mechanics [1–3]. Professional physicists are expected to be familiar with it and to know how it can be derived from the fundamental principles of statistical mechanics. But most professional physicists probably would not know the exact nature of Saha’s contributions in the field. Was he the first person who derived and arrived at this equation? It may come as a surprise to many to know that Saha did not derive the equation named after him! He was not even the first person to write down this equation! The equation now called the Saha ionization equation appeared in at least two papers (by J. Eggert [4] and by F.A. Lindemann [5]) published before the first paper by Saha on this subject. The story of how the theory of thermal ionization came into being is full of many dramatic twists and turns. -
Galactic Rotation in Gaia DR1
Mon. Not. R. Astron. Soc. 000,1{6 (2017) Printed 10 February 2017 (MN LATEX style file v2.2) Galactic rotation in Gaia DR1 Jo Bovy? Department ofy Astronomy and Astrophysics, University of Toronto, 50 St. George Street, Toronto, ON M5S 3H4, Canada and Center for Computational Astrophysics, Flatiron Institute, 162 5th Ave, New York, NY 10010, USA 30 January 2017 ABSTRACT The spatial variations of the velocity field of local stars provide direct evidence of Galactic differential rotation. The local divergence, shear, and vorticity of the velocity field—the traditional Oort constants|can be measured based purely on astrometric measurements and in particular depend linearly on proper motion and parallax. I use data for 304,267 main-sequence stars from the Gaia DR1 Tycho-Gaia Astrometric Solution to perform a local, precise measurement of the Oort constants at a typical heliocentric distance of 230 pc. The pattern of proper motions for these stars clearly displays the expected effects from differential rotation. I measure the Oort constants to be: A = 15:3 0:4 km s−1 kpc−1, B = 11:9 0:4 km s−1 kpc−1, C = 3:2 0:4 km s−1 kpc−1 ±and K = 3:3 0:6 km s−−1 kpc−1±, with no color trend over− a wide± range of stellar populations.− These± first confident measurements of C and K clearly demonstrate the importance of non-axisymmetry for the velocity field of local stars and they provide strong constraints on non-axisymmetric models of the Milky Way. Key words: Galaxy: disk | Galaxy: fundamental parameters | Galaxy: kinematics and dynamics | stars: kinematics and dynamics | solar neighborhood 1 INTRODUCTION use Cepheids to investigate the velocity field on large scales (> 1 kpc) with a kinematically-cold stellar tracer population Determining the rotation of the Milky Way's disk is diffi- (e.g., Feast & Whitelock 1997; Metzger et al. -
345B 2011.Pdf
What a student can learn from the Saha Equation Jayant V. Narlikar IUCAA, Purie 1. Introduction sulting frequent collisions, it would be impossible The seminal contribution of Meghnad Saha was for the typical atoms to retain all of their orbital his ionization equation, now well known as Saha's electrons and so they would be ionized and the lonization Equation. To say that it was an impor- matter would be in a state of plasma. How would tant work in astrophysics would be understating it the state of equilibrium be in such circumstances? Naturally we expect some of the atoms of the mat- " : for, the subject of astrophysics really got going only as a result of the Saha Equation. Let us be- ter to remain unchanged, while some would exist gin with an examination of this assertion. For, to as ions and free electrons. But what would be 5 a student of physics the equation provides a menu the proportions of these three ingredients? The / Saha equation answered this important question "' of delicious results to be enjoyed and appreciated. by giving the following relation: Till the second decade of the last century the main observational handle on studies of stars had B been their luminosities and spectra. While the lu- N (1) minosity could give a crude estimate of the star's distance using the inverse square law of illumina- Here the number Ne, Ni, N denote the num- tion, the spectrum contained a lot more informa- ber densities of free electrons, ions and neutral tion. atoms at temperature T, B being the binding en- For example, the continuum spectrum did, in ergy of the atom.