Safety Data Sheet Technical Benzylamine

SAFETY DATA SHEET TECHNICAL BENZYLAMINE

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Chemical name: Benzylamine Registration no.: 01-2119492620-39-0001 Index number: 612-047-00-X EC (EINECS) number: 202-854-1 CAS number: 100-46-9 Other names of the substance: Phenylmethylamine, Phenylaminomethane, ααα-Aminotoluol, 1-Aminomethylbenzol

1.2 Relevant identified uses of the substance or mixture and uses advised against Uses of the substance: Benzylamine is used for production of pharmaceutical substances, dyes, corrosion inhibitors and during organic syntheses (the overview of exposure scenarios is set out in Annex 1). Uses advised against: other than industrial uses

1.3 Details of the supplier of the safety data sheet Name: BorsodChem MCHZ, s.r.o. Name or business name: BorsodChem MCHZ, s.r.o. Place of business or headquarters: Chemická 2039/1, 709 00 Ostrava – Mariánské Hory, Czech Republic Identification number: 26019388 Telephone: +420 596 641 111 Fax: +420 596 642 040 E-mail of the technically competent person responsible for the safety data sheet : [email protected]

1.4 Emergency telephone number Company telephone number: +420/ 596 643 221 or 596 620 794 non-stop 24-hours emergency contact CHEMTREC: 001-703-527-3887, company code CCN 206 072 The National Poisons Information Service (NPIS), City Hospital, Birmingham, B18 7QH, UK Tel: +44 121 507 4123, fax: +44 121 507 5580, e-mail: [email protected], www.npis.org National Capital Poison Center, 3201 New Mexico Ave, Suite 310 Washington, DC 20016 Emergency Line: 1-800-222-1222, fax: 202-362-8377, e-mail: [email protected], www.poison.org

SECTION 2: Hazards identification 2.1 Classification of the substance or mixture According to Regulation (EC) no. 1272/2008: Acute Tox. 4; H302 Harmful if swallowed. Acute Tox. 4; H312 Harmful in contact with skin. Skin Corr. 1B; H314 Causes severe skin burns and eye damage.

The most important human health adverse effects during use of the substance or preparation: Corrosive. Contact with skin causes burns. Vapours highly irritating to mucous membranes.

The most important adverse effects to environment during use of the substance/preparation:

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not specified

2.2 Label elements According to Regulation (EC) no. 1272/2008: Symbols:

Signal word: DANGER

H phrases: H302+H312 Harmful if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage.

P phrases: P280 Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

2.3 Other hazards The substance is not identified as persistent, bio-accumulative and toxic (PBT) or very persistent, very bio-accumulative (vPvB) under Annex XIII of Regulation 1907/2006/EC.

SECTION 3: Composition/information on ingredients 3.1 Substances Chemical name Benzylamine Index number 612-047-00-X EC No. 202-854-1 CAS No. 100-46-9 Substance content (% w.) 99.0 Phenylmethylamine, Phenylaminomethane, ααα-Aminotoluol, Synonyms 1-Aminomethylbenzol Impurities: < 1 % w., CMR impurities < 0.1 % w.

3.2 Mixtures The product is a chemical substance.

SECTION 4: First aid measures 4.1 Description of first aid measures

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Inhalation: Move the victim quickly and considering own safety to fresh air, do not let the victim walk! Loosen clothing, depending on situation it is recommended to rinse oral cavity and, if necessary, nose with water. If the victim’s clothing is contaminated, change the victim and protect him/her against cold. Ensure breathing. Call a physician! If on skin: Remove contaminated clothing immediately; before washing or during washing, remove any rings, watches, bracelets that are in places of contact of the substance with skin. Rinse affected areas with stream of lukewarm water, if possible, for 10 to 30 minutes; do not use a brush, soap or neutralising agents! Cover burned areas of skin with a sterile dressing, do not use any ointments or other medical and pharmaceutical products. Cover the victim to protect him against cold. Call a physician! If in eyes: Rinse eyes immediately under running water, open eyelids (even by force); if the victim wears contact lenses, remove them immediately. Do never neutralise! Rinse for 10 to 30 minutes from the inner to the outer ocular angle to prevent running of water in the other eye. Ensure as soon as possible medical treatment by an expert, if possible; the victim must get medical attention even in case of small injury. If swallowed: DO NOT INDUCE VOMITING - higher risk of harm to digestive tract!!! Risk of perforation of oesophagus and stomach! RINSE MOUTH IMMEDIATELY WITH WATER AND GIVE TO DRINK 2—5 dl of cold water to alleviate thermal effect of the caustic. Due to almost immediate effect to mucous membranes, it is suitable to offer immediately tap water than loose time by looking for chilled liquid – each minute of delay causes irreversible harm to mucous membranes! Soda water or mineral waters are not recommended, as they may release gaseous carbon dioxide. It is not recommended to consume a lot of liquid, as it could induce vomiting and possible aspiration of the caustic in lungs). Do not force the victim to drink, especially if he/she feels pain in mouth or throat. In this case, make the victim rinse his/her mouth. DO NOT ADMINISTER ACTIVATED CARBON! (blackening will make examination of mucous membranes more difficult and activated carbon has no positive effect in case of acids and lye). Do not give anything to eat. Do not administer anything by mouth if the victim is unconscious or has convulsions. Call a physician immediately!

4.2 Most important symptoms and effects, both acute and delayed Vapours irritate eyes and airways, liquid burns skin and mucous membranes. Contact with the substance may manifest itself by burning of eyes, nasal and palate mucous membranes, headache, nausea, breathlessness or even by loss of consciousness.

4.3 Indication of any immediate medical attention and special treatment needed Symptomatic treatment. In case of very heavy inhalation exposition with high concentration of vapours and in case heating up, beware of pulmonary oedema with latency (poor in symptoms) of up to two days. WARNING! Savers and helping persons must wear complete protective clothing when giving first aid.

SECTION 5: Firefighting measures 5.1 Extinguishing media

Suitable extinguishing media: water mist, powder, foam, CO 2 Unsuitable extinguishing media: water

5.2 Special hazards arising from the substance or mixture: Flammable liquid. Warning up or combustion may make containers containing the substance blow due to pressure increase with a risk of explosion. Cool down the containers in the vicinity of fire using water mist. Possibility of release of carbon monoxide and nitrogen oxides. Formation of corrosive, toxic and explosive mixtures.

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5.3 Advice for firefighters: Self-contained breathing apparatus, special protective clothing! (Hazchem. Code: 3W)

SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Protection of air ways, protection of non-protected body parts, protection of eyes. Ensure ventilation. Avoid contact with spilled substance, do not breathe vapour. Prevent contact of the substance with sources of ignition. 6.2 Environmental precautions: Prevent contamination of soil and water in vicinity of accident. 6.3 Methods and material for containment and cleaning up: Cover with an absorbent material (Vapex, Vermikulit) and sweep up into a waste container. For methods of disposal see Section 13. 6.4 Reference to other sections: see Section 10 and Section 13.

SECTION 7: Handling and storage 7.1 Precautions for safe handling: Packaged and transported in rail and road tankers, steel drums and IBC containers. Ventilation provided during emptying. Do not breathe vapour. Use suitable personal protective equipment when handling the substance. 7.2 Conditions for safe storage, including any incompatibilities: Store in rooms that may be easily ventilated in original closed packaging or in steel tanks, if possible in nitrogen atmosphere, out of range heat, sparks, open flame or other source of ignition. Do not store together with foodstuffs, strong oxidising agents and concentrated inorganic acids. The substance reacts in contact or when mixed with ammonia salts and forms gaseous ammonia. 7.3 Specific end use(s): Use only in industry under strictly controlled conditions or while observing conditions stated in the exposure scenario.

SECTION 8: Exposure controls/personal protection 8.1 Control parameters Czech Republic: not established EC countries (2000/39/EC): not established

8.1.1 DNEL (Derived No Effect Level) for exposure of workers Prolonged exposure (systemic effects) – inhalation: 14.7 mg/m³ Prolonged exposure (systemic effects) – dermal: 8.3 mg/kg of weight/day Prolonged exposure (local effects) – inhalation: 1 mg/kg Prolonged exposure (local effects) – dermal: not established, corrosive

8.2 Exposure controls Use in a closed area, ensure exhaustion of vapours, use personal protective equipment. Engineering controls: Ensure ventilation. Respiratory protection: protective mask or half mask with filter (EN 140) against organic vapours - type A/P2 Hand protection: protective gloves (EN 374) Eye protection: protective goggles or face shield (e.g. EN 166) Skin protection: protective clothing

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Other data: Do not eat, drink and smoke during work. Wash your hands with hot water and soap after work, apply suitable reparative preparations.

Environmental exposure controls: Use in a closed circuit, waste gases burnt in a fire crack or cleaned by adsorption (activated carbon), wastewater treated biologically.

SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: colourless to slightly yellowish liquid Odour: like amines Odour threshold: not established pH: 13.4 Melting point/freezing point (°C): < -30.0 Initial boiling point (at 1013 hPa in °C) 185.0 Flash point (at 1013 hPa in °C): 65.0 Evaporation rate: not established Flammability (°C): not established Upper/lower explosive limits (% vol.): 8.2/0.7 Vapour pressure (Pa at 30 °C): 130.0 Vapour density: not established Relative density (at 20 °C): 0.9813 -1 Solubility at 20 °C (g.l ): completely soluble Partition coefficient n-octanol/water 1.03 (log pow at 20 °C and pH > 11): Auto-ignition temperature (at 1013 hPa in °C): 390.0 Decomposition temperature: not established Viscosity (mPa.s at 21,2 °C): 1.78 Explosive properties: none Oxidising properties: none

9.2 Other information Surface tension (mN/m at 25,1 °C): 64.9

SECTION 10: Stability and reactivity 10.1 Reactivity: Non-reactive under normal conditions. 10.2 Chemical stability: Stable under normal conditions. 10.3 Possibility of hazardous reactions: The substance reacts in contact or when mixed with ammonia salts and forms gaseous ammonia.

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10.4 Conditions to avoid: In case of heating up formation of irritating and explosive mixtures. Thermal decomposition with formation of nitrogen oxides and carbon monoxide occurs at higher temperatures. 10.5 Incompatible materials: Reacts vigorously with strong oxidising agents and inorganic acids. Avoid contact with food. 10.6 Hazardous decomposition products: Combustion may produce toxic carbon monoxide and nitrogen oxides.

SECTION 11: Toxicological information Information on toxicological effects CLP evaluation 11.1 Acute toxicity: category 4 -1 • LD 50 (oral, rat) = 552 mg.kg -1 • LD 50 (dermal, rabbit) > 1350 mg.kg

11.2 Irritation: skin causticity 1B Dermal irritation (rabbit): not established, corrosive substance Eye irritation (rabbit): not established, corrosive substance

11.3 Sensitisation Skin sensitisation: not established, corrosive substance

11.4 Mutagenicity (in vitro and in vivo studies): not mutagenic

11.5 Carcinogenicity: following a sub-acute test, no subsequent tests performed

11.6 Reproductive toxicity: not toxic for reproduction

11.7 Specific target organs toxicity – single exposure: not classified

11.8 Specific target organs toxicity - repeated exposure: not classified

11.9 Aspiration hazard: data not available

SECTION 12: Ecological information 12.1 Toxicity 12.1.1 Aquatic toxicity -1 Fish (96 h) : LC 50 = 102 mg.l -1 EC 50 = 98 mg.l -1 Daphnia magna (48 h) : EC 50 > 100 mg.l

Soil organisms: -1 Pseudomonas putida : LC 0 = 400 mg.l

Plants and land animals: -1 Scenedesmus quadricauda (96 h) : LC 0 = 6 mg.l

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-1 Desmodus subspicatus (72 h): EC 50 = 50 mg.l -1 (72 h): ErC 10 = 17 mg.l

Classification conclusion: not classified as hazardous for environment

12.1.3 PNEC (Predicated No Effect Concentration) PNEC aqua (freshwater): 0.05 mg/l PNEC aqua (marine water): 0.005 mg/l PNEC sediment: 3.4 mg/kg of weight of dry sediment PNEC sewage treatment plant: 18.6 mg/l PNEC soil: 0.648 mg/kg of weight of dry soil PNEC plants: not established PNEC oral: not established

12.2 Persistence and degradability Evaluation: Readily degradable in aquatic environment BSK 5/CHSK Cr = 0.65; readily degradable Testing method: OECD 301C, OECD 302B

12.3 Bio-accumulative potential : BCF = 2-6 Evaluation: The substance is not a high bio-accumulation potential substance.

12.4 Mobility in soil: May enter the environment from waste water. Stability: Soluble in water

Adsorption: Possible in soil, adsorption coefficient value: Log K oc = 2.590

12.5 Results of PBT and vPvB assessment: not included

12.6 Other adverse effects: not specified

SECTION 13: Disposal considerations 13.1 Waste treatment methods: Incineration in a hazardous waste incineration plant in accordance with Act on Wastes under the catalogue numbers 160305, 160508 or 150202. Disposal of contaminated packaging: Rinse with water, dispose the caught water and packaging in accordance with valid regulations.

SECTION 14: Transport information Land transport (ADR/RID) Marine transport (IMDG): Air transport (ICAO/IATA)

14.1 UN number: 2735 14.2 UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (Benzylamine) 14.3 Transport hazard class(es): 8, C7 Hazard identification number 80 (Kemler code): 14.4 Packing group: III

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14.5 Environmental hazards: No Marine pollutant: is not “Marine pollutant” 14.6 Special precautions for user: included in ”Segregation Groups-18 Alkalis” EMS: F-A, S-B 14.7 Transport in bulk according to Annex II Irrelevant of MARPOL and the IBC Code

SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1 EU regulations concerning safety, health and environment/specific legislation concerning substances or mixtures, as amended: • Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006; • Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC; • Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste and repealing certain Directives; • Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances.

15.1.2 Regulations valid in CR and concerning safety, health and environment/specific legislation concerning substances or mixtures, as amended: • Act 350/2011 Coll., on chemical substances and chemical mixtures and on amendments to some acts; • Decree of Ministry of Environment no. 93/2016 Coll. laying down Waste Catalogue; • Governmental decree no. 361/2007 Coll., laying down occupational health and safety conditions.

15.2 Chemical safety assessment Chemical safety assessment is part of the chemical safety report for benzylamine - the overview of risk management measures is provided in Annex 1. Detailed information on exposure scenarios will be contained in Annex 2 available at the customer’s request.

SECTION 16: Other information 16.1 This safety data sheet supersedes all previous versions. 16.2 List of abbreviations Carc.: Carcinogenicity CAS: Chemical Abstracts Service CLP: Classification, labelling, packaging regulation CSR: Chemical safety report

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DNEL: Derived no-effect level ES: Exposure scenario EC: European Commission EC 50 : Median effective concentration EC 50 – used in toxicity tests. Median effective concentration EC 50 is the concentration of substance that causes 50 % mortality or 50 % decrease of growth or growth rate with reference to the control sample. EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances Irrit.: Irritant LC 50 : Lethal concentration, 50 % (lethal concentration) is used for toxicity tests LD 50 : Absolute lethal dose that kills 50 % of members of population LOAEC: Lowest observed adverse effect concentration NOAEC: No observed adverse effect concentration NOEC: No observed effect concentration OECD: Organisation for Economic Cooperation and Development PBT: Persistent, bio-accumulative and toxic PNEC: Predicted no-effect concentration REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals Sens.: Sensitivity STOT: Specific target organs toxicity STOT SE: Specific target organs toxicity - single exposure STOT RE: Specific target organs toxicity - repeated exposure STP: Sewage treatment plant SU: Sector of use Tox.: Toxicity vPvB: Very persistent and very bio-accumulative

16.3 List of mentioned phrases H phrases: H302+H312 Harmful if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage.

16.4 Sources used Material safety data sheet – Technical benzylamine, BC MCHZ, 4th version from 06/2015

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16.5 History of revisions

Issue Date Change 1.0 30.11.2010 Preparation of the safety data sheet according to Regulation (EC) No 1907/2006 of the European Parliament and of the Council 2.0 17.08.2011 Overall revision of all sections of the safety data sheet according to Regulation (EC) No 453/2010 of the European Parliament and of the Council 3.0 01.12.2012 Update of classification (use of a combination of H-phrases), update of the regulations valid in the Czech Republic, and revisions according to Regulation (EC) No 286/2011 of the European Parliament and of the Council 4.0 01.06.2015 Modification of Section 2 (deletion of classification under DSD) and other sections according to regulations 2015/830/EU 5.0 17.10.2016 Revision according to Commission Regulation (EU) no. 918/2016, adding a registration number and exposure scenarios overwiew

Prepared by: Ing. Zuzana Svobodová – IT & Quality, ecology and safety department Approved by: Ing. Stanislav Pekara, MBA - Head of IT & Quality, ecology and safety department

Version: English Date: 17 th October 2016 Safety Data Sheet Benzylamine www.borsodchem-cz.com The mentioned data reflect the present state of knowledge and experience and they are in compliance with valid legislation of the Czech Republic. The client is responsible for observing valid national legislation in the place of use.

Manufactured by:

BorsodChem MCHZ, s.r.o. Chemická 2039/1 709 00 Ostrava – Mariánské Hory Telephone: +420 596 641 111 Fax: +420 596 626 258

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Annex No. 1

SUMMARY OF EXPOSURE SCENARIOS

Identified uses Life cycle stage

for for articles) Wastestage Exposure scenariono. Volume(t/y) Formulation Enduse Consumers Servicelife ( Sectorsof Use (SU) Chemical Product Category(PC) or ArticleCategory Process category (PROC) Environmental Release Category(ERC) ES2 PROC1, 2, N/A X SU3 PC19 ERC6a Intermediate 3, 4, 5 ES3 Pouring and filling of PROC8a, N/A X SU3 ERC8c, 8f the substance/mixture 8b, 9 - in industry ES4 Pouring and filling of PROC8a, N/A X SU22 ERC8c, 8f the substance/mixture 8b, 9 - professional ES5 Formulation of SU3, PROC1, 2, mixtures and N/A X ERC2 10 3, 4, 5 repacking - in industry ES6 Formulation of PROC3, 4, mixtures and N/A X SU22 ERC8c, 8f 5, 19 repacking - professional ES7 Use in laboratories N/A X SU3 PC15 ERC2, 5 - in industry ES8 Use in laboratories N/A X SU22 PC15 ERC8c, 8f - professional ES9 PROC1, 2, Use as monomer – N/A X SU3 PC 32 3, 4, 5, 7, ERC6c polymerisation 10, 13 reaction in industry ES10 Use as monomer – PROC10, polymerisation N/A X SU22 PC 32 ERC8c, 8f 11, 13, 14 reaction - professional ES11 Intermediate including PROC1, 3, N/A X SU3 PC19 ERC6a pouring/filling in 8b, 9 industry N/A – not available (confidential information)

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SUMMARY OF RISK MANAGEMENT MEASURES

Use Risk management measures (RMM) (description, chemical product category, process category and environmental release category)

Intermediate – Exposure scenario 2 (ES2) Use in industry as an All persons are trained in emergency preparedness. Workers must intermediate always use protective working clothes and other specified personal (100% BZA) protective equipment. Extraction of emissions of the substance is required in all handling stages (LEV, 90% efficiency). Due to corrosive

effects, it is necessary to use protective gloves (90% efficiency) and PROC1, 2, 3, 4, 5 goggles. Waste water (e.g. from cleaning) shall be collected and disposed of via a ERC6a professional company dealing with waste water. Water including sludge shall not be disposed into soil or rivers.

Charging/discharging of the substance/mixture in industry – Exposure scenario 3 (ES3) Pouring/filling of the All persons are trained in emergency preparedness. Workers must substance/mixture in industry always use protective working clothes and other specified personal (100% BZA) protective equipment (max. 4 hours of work/day). Extraction of emissions of the substance is required in all handling stages (LEV, min.

90% efficiency). Due to corrosive effects, it is necessary to use PROC 8a,8b,9 protective gloves (90% efficiency) and goggles.

Waste water (e.g. from cleaning) shall be collected and disposed of via a

professional company dealing with waste water. Water including sludge ERC8c, 8f shall not be disposed into soil or rivers.

Charging/discharging of the substance/mixture, professional use – Exposure scenario 4 (ES4) Charging/discharging of the All persons are trained in emergency preparedness. Workers must substance/mixture, always use protective working clothes and other specified personal professional use protective equipment (max. 4 hours of work/day). Extraction of (100% BZA) emissions of the substance is required in all handling stages (LEV, min. 80% efficiency). Due to corrosive effects, it is necessary to use

protective gloves (90% efficiency) and goggles. Pouring/filling from/into PROC 8a,8b,9 small containers requires the use of respiratory protection (95% efficiency).

Waste water (e.g. from cleaning) shall be collected and disposed of via a ERC8c, 8f professional company dealing with waste water. Water including sludge shall not be disposed into soil or rivers.

Mixture preparation in industry – Exposure scenario 5 (ES5) Mixture preparation in industry All persons are trained in emergency preparedness. Workers must (100% BZA) always use protective working clothes and other specified personal protective equipment. For mixing in batch processes, exposure shall be PROC1, 2, 3, 4, 5 limited to 1 hour/day. Extraction of emissions of the substance is required in all handling stages (LEV, 90% efficiency). Due to corrosive effects, it is necessary to use protective gloves (90% efficiency) and goggles.

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Use Risk management measures (RMM) (description, chemical product category, process category and environmental release category) ERC2 Waste water (e.g. from cleaning) shall be collected and disposed of via a professional company dealing with waste water. Water including sludge shall not be disposed into soil or rivers.

Mixture preparation, professional use – Exposure scenario 6 (ES6) Mixture preparation, All persons are trained in emergency preparedness. Workers must professional use always use protective working clothes and other specified personal protective equipment. (100% BZA) Extraction of emissions of the substance is required in all handling PROC3, 4, 5, 19 stages (LEV, min. 80% efficiency). Due to corrosive effects, it is necessary to use protective gloves (90% efficiency) and goggles. Use and mixing in batch processes (PROC4, PROC5) and hand mixing (PROC19) requires respiratory protection (95% efficiency). ERC8c, 8f Waste water (e.g. from cleaning) shall be collected and disposed of via a professional company dealing with waste water. Water including sludge shall not be disposed into soil or rivers.

Laboratory use in industry – Exposure scenario 7 (ES7) Laboratory use in industry All persons are trained in emergency preparedness. Workers must always use protective working clothes and other specified personal (100% BZA) protective equipment (max. 1 hour of work/day).

PROC15 Extraction of emissions of the substance is required in all handling ERC2, 5 stages (LEV, min. 90% efficiency). Due to corrosive effects, it is necessary to use protective gloves (90% efficiency) and goggles.

Laboratory use, professional – Exposure scenario 8 (ES8) Laboratory use, professional All persons are trained in emergency preparedness. Workers must always use protective working clothes and other specified personal (100% BZA) protective equipment (max. 15 minutes of work/day).

PROC15 Extraction of emissions of the substance is required in all handling ERC8c, 8f stages (LEV, min. 80% efficiency). Due to corrosive effects, it is necessary to use protective gloves (90% efficiency) and goggles.

Use as monomer / polymerisation agent in industry – Exposure scenario 9 (ES9) Use as monomer or All persons are trained in emergency preparedness. Workers must polymerisation agent in always use protective working clothes and other specified personal industry protective equipment. For mixing in batch processes, exposure shall be (100% BZA) limited to 1 hour/day. Extraction of emissions of the substance is required in all handling stages (LEV, 90% efficiency). Due to corrosive PROC1, 2, 3, 4, 5, 7, 10, 13 effects, it is necessary to use protective gloves (90% efficiency) and goggles. Spraying techniques (PROC7), roller application and brushing require respiratory protection (95% efficiency).

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Use Risk management measures (RMM) (description, chemical product category, process category and environmental release category) ERC6c Waste water (e.g. from cleaning) shall be collected and disposed of via a professional company dealing with waste water. Water including sludge shall not be disposed into soil or rivers.

Use as monomer / polymerisation agent, professional use – Exposure scenario 10 (ES10) Use as monomer or All persons are trained in emergency preparedness. Workers must polymerisation agent, always use protective working clothes and other specified personal professional protective equipment. For spraying techniques (PROC11), exposure shall be limited to 2 hours/day. Extraction of emissions of the substance (5-25% BZA) is required in all handling stages (LEV, min. 80% efficiency). Due to corrosive effects, it is necessary to use protective gloves (90% efficiency), goggles and respiratory protection (95% efficiency). PROC10, 11, 13, 14 Waste water (e.g. from cleaning) shall be collected and disposed of via a professional company dealing with waste water. Water including sludge shall not be disposed into soil or rivers. ERC8c, 8f

Intermediate including charging/discharging – Exposure scenario 11 (ES11) Use in industry as an All persons are trained in emergency preparedness. Workers must intermediate always use protective working clothes and other specified personal (100% BZA) protective equipment. For filling/pouring, exposure shall be limited to 1 hour/day.

PROC1, 3, 8b, 9 Extraction of emissions of the substance is required in all handling stages (1–3 air changes per hour). Due to corrosive effects, it is

necessary to use protective gloves (90% efficiency), goggles and ERC6a respiratory protection (90% efficiency). Waste water (e.g. from cleaning) shall be collected and disposed of via a professional company dealing with waste water. Water including sludge shall not be disposed into soil or rivers.

List of Abbreviations:

ERC2 Formulation of preparations* ERC5 Industrial use resulting in inclusion into or onto a matrix

ERC6a Industrial use resulting in manufacture of another substance (use of intermediates)

ERC6c Industrial use of monomers for manufacture of thermoplastics

ERC8c Wide dispersive indoor use resulting in inclusion into or onto a matrix

ERC8f Wide dispersive outdoor use resulting in inclusion into or onto a matrix

LEV Local exhaust ventilation PC19 Intermediate PC32 Polymer preparations and compounds

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PROC1 Use in closed process, no likelihood of exposure PROC2 Use in closed, continuous process with occasional controlled exposure PROC3 Use in closed batch process (synthesis or formulation) PROC4 Use in batch and other process (synthesis) where opportunity for exposure arises PROC5 Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact) PROC7 Industrial spraying PROC8a Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities PROC8b Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC9 Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC10 Roller application or brushing PROC11 Non industrial spraying PROC13 Treatment of articles by dipping andpouring PROC14 Production of preparations* or articles by tabletting, compression, extrusion, pelletisation PROC15 Use as laboratory reagent PROC19 Hand-mixing with intimate contact and only PPE available SU3 Industrial uses: Uses of substances as such or in preparations* at industrial sites SU22 Professional uses: Public domain (administration, education, entertainment, services, craftsmen)

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