Spontaneous Emission Stimulated Emission E E E E Before After

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Spontaneous Emission Stimulated Emission E E E E Before After LECTURE 8 How a Laser Works Laser is an acroynm that stands for Light Ampli cation by Stimulated Emission of Radiation. A maser is the corresp onding system for microwaves. To understand how a laser works, consider an atom with 2 energy levels and one electron. Let's call this a two level system. Let E be the energy of the ground state and E be the energy of 1 2 the excited state. Supp ose the electron is in the lower energy state. If the atom absorbs a photon of frequency = E E =h, the electron makes a transition to the excited 2 1 state. From there it can decaybacktothelower state by emitting a photon of frequency = E E =h. There are 2 typ es of emission pro cesses. In stimulated emission, 2 1 an incident photon of frequency stimulates the atom to make a transition from the higher state to the lower energy state and emit another photon of frequency that is in phase with the rst photon. The second photon is in phase b ecause the rst photon causes the electron charge of the atom to oscillate in phase with it and this oscillation causes the second photon to b e in phase with the rst. So one photon comes in and two photons leave. In sp ontaneous emission the excited atom sp ontaneously decays to the lower energy state and emits a photon of frequency . One can regard this as emission stimulated by zero pointvacuum uctuations of the electromagnetic eld. Before After E 2 E 1 Stimulated Emission E 2 E 1 Spontaneous Emission Now supp ose we start with an inverted p opulation of atoms which are each in their excited state. This can b e accomplished by optically pumping the atoms into their excited state with incident radiation. Now an incident photon of frequency = E E =h, 2 1 which may have b een pro duced by sp ontaneous emission, stimulates one of the excited atoms to emit a photon in phase with it. These two photons of frequency then pro duce stimulated emission from other excited atoms. If we put the system in a cavity with re ecting walls at the ends, the photons bounce back and forth, gaining more and more cohorts via stimulated emission. If one of the walls is slightly transparent, rather than b eing totally re ecting, part of this coherent mono chromatic b eam escap es as a laser beam. Mono chromatic means the photons are all of one frequency and coherent means that the photons are all in phase. The fact that the photons are in phase means that the amplitudes of the electromagnetic waves add constructively, and this enhances the intensity and energy density concentration of the b eam. In fact a laser with less power than a typical light bulb can burn a hole in a metal plate. In contrast, white light is incoherent and nonmono chromatic b ecause there is no correlation in the times that the atoms make transitions. Let's make this more quantitative. Consider a set of twolevel systems atoms in the presence of electromagnetic radiation. Let N be the number of photons of frequency . Let there be n atoms in energy state E and n atoms in energy state E , where 1 1 2 2 E >E and =E E =h. The rate of absorption of photons is prop ortional to the 2 1 2 1 numb er of photons of frequency and to the concentration of atoms in state 1 whichcan absorb photons: ! dN = Bn N 1 1 dt absorption where B is a constant of prop ortionality that dep ends on the prop erties of states 1 and 2. The minus sign indicates that the photon density decreases due to absorption by the atoms. The rate of stimulated emission is prop ortional to the number of photons of frequency and to the concentration of atoms in state 2 which can be induced to emit photons of frequency : ! dN =+Bn N 2 2 dt stimulated emission The plus sign indicates that emission increases the number of photons. Sp ontaneous emission can o ccur even when there are no photons and the corresp onding rate is ! dN = An 3 2 dt sp ontaneous emission So the total rate of change of the number of photons is the sum of all these pro cesses. ! dN = B n n N + An 4 2 1 2 dt total This is an example of a rate equation. It tells us the rate of change of a p opulation due to emission and absorption. A and B are called the Einstein co ecients. 2 Let us consider the steady state where the system is in equilibrium. This is not the case for a laser, but let's lo ok at it anyway. In steady state the number of photons do es not change with time, so ! dN =0 5 dt total or B n n N + An =0 6 2 1 2 Solving for N , we obtain A N = 7 n 1 1 B n 2 In equilibrium the ratio of the p opulations of the excited and lower states is given bythe Boltzmann probability distribution n 2 E E 2 1 = e 8 n 1 or n 1 E E 2 1 = e 9 n 2 Plugging this into 7 yields A 10 N = E E 2 1 B e 1 On the other hand, we already know what the distribution is for photons in equilibrium. It's just the Planck distribution that wederived when we discussed black b o dy radiation 1 1 = 11 N = h E E 2 1 e 1 e 1 Comparing 10 and 11 yields A = B 12 Thus the co ecient in the sp ontaneous emission rate is exactly the same as in the induced emission rate; the total emission rate is ! dN = Bn N +1 13 2 dt total emission Note that the form of the emission rate was deduced without knowing the actual value of B ;onlydetailedbalancing arguments were used. Detailed balancing is simply the idea that in equilibrium the amount of energy absorb ed and emitted must b e equal. Now let's consider the case of the laser. This is not an equilibrium situation. The ratio of the emission and absorption of photons is given by dN A + BN n dt 2 emission = 14 dN BN n 1 dt absorption 3 In equilibrium dN dt emission =1 15 dN dt absorption but in a laser we have p opulation inversion n >n and 2 1 dN n dt 2 emission 16 dN n 1 dt absorption So when the p opulation is inverted, the rate of emission is greater than the rate of absorption. This means that the applied radiation of frequency =E E =h will b e 2 1 ampli ed in intensity b ecause of stimulated emission with much more radiation emerging than entering. Of course, such a pro cess will reduce the p opulation of the upp er state until equilibrium is established. In order to sustain the pro cess, p opulation inversion must be maintained. One common way to do this is via optical pumping. As an example let's consider a solid state laser that op erates with a ruby crystal in which some of the Al atoms in the Al O molecules are replaced by Cr atoms. These 2 3 \impurity" chromium atoms account for the laser action. The energy level scheme of chromium has 3 energy levels E <E <E . 2 3 E 1 3 Spontaneous Emission E 2 Pumping Stimulated Radiation Emission E 1 The energy di erence E E corresp onds to a wavelength of ab out 5500 A. Optical 3 1 pumping o ccurs in the following way. Pumping radiation with a wavelength 5500 A is sent in and absorb ed by Cr atoms which make a transition from their ground state 8 to the level with energy E . This is a short lived state lifetime is ab out 10 seconds 3 which decays sp ontaneously to the intermediate excited state which is long lived ab out 3 3 10 seconds. The net result of the optical pumping is to invert the p opulation such that n > n . So when a Cr atom makes a transition from state 2 to state 1, 2 1 it emits a photon of wavelength 6943 A which will stimulate transitions in other Cr atoms. Because n >n , emission dominates over absorption and an intensi ed coherent 2 1 mono chromatic b eam results. The ruby laser consists of a cylindrical ro d with parallel, 4 optically at re ecting ends, one of which is only partly re ecting. The laser b eam exits through this partially re ecting end. The emitted photons that do not travel along the axis escap e through the sides b efore they are able to cause much stimlated emission. But those photons that move exactly in the direction of the axis are re ected several times, and they are capable of stimulating emission rep eatedly. Thus the numb er of photons is built up rapidly, those escaping from the partially re ecting end giving a unidirectional beam of great intensity and sharply de ned wavelength. There are many kinds of lasers{gas lasers, liquid lasers, semiconductor lasers, and solid state lasers made from crystals. These cover a wide range of the electromagnetic sp ectrum. Lasers have a wide range of uses including medical physics, biophysics, com- munications, and data storage CD players. For example, semiconductor lasers that are the size of a grain of sand are used to send signals down optic b ers.
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