DOCSLIB.ORG

1770 Date: May 2000 Revision: August 2009 DOT Number: UN 2967

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
1770 Date: May 2000 Revision: August 2009 DOT Number: UN 2967 Right to Know Hazardous Substance Fact Sheet Common Name: SULPHAMIC ACID Synonyms: Amidosulfonic Acid; Sulfamidic Acid CAS Number: 5329-14-6 Chemical Name: Sulfamic Acid RTK Substance Number: 1770 Date: May 2000 Revision: August 2009 DOT Number: UN 2967 Description and Use EMERGENCY RESPONDERS >>>> SEE LAST PAGE Sulphamic Acid is an odorless, white, crystalline (sand-like) Hazard Summary solid. It is used in cleaning metal and ceramics, dye Hazard Rating NJDOH NFPA manufacturing, for stabilizing Chlorine in swimming pools, in HEALTH 3 - electroplating, and as a bleaching agent. FLAMMABILITY 0 - REACTIVITY 0 - CORROSIVE POISONOUS GASES ARE PRODUCED IN FIRE Reasons for Citation Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious; f Sulphamic Acid is on the Right to Know Hazardous 4=severe Substance List because it is cited by DOT. f This chemical is on the Special Health Hazard Substance f Sulphamic Acid can affect you when inhaled. List. f Sulphamic Acid is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. f Inhaling Sulphamic Acid can irritate the nose and throat. f High exposure to Sulphamic Acid can irritate the lungs. SEE GLOSSARY ON PAGE 5. Higher exposures may cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency. FIRST AID f Sulphamic Acid can cause nausea, vomiting and stomach pain. Eye Contact f Repeated exposure to Sulphamic Acid may affect the liver f Immediately flush with large amounts of water for at least 30 and kidneys. minutes, lifting upper and lower lids. Remove contact lenses, if worn, while flushing. Seek medical attention immediately. Workplace Exposure Limits Skin Contact f Quickly remove contaminated clothing. Immediately wash No occupational exposure limits have been established for contaminated skin with large amounts of water. Seek Sulphamic Acid. However, it may pose a health risk. Always medical attention. follow safe work practices. Inhalation f Remove the person from exposure. f Begin rescue breathing (using universal precautions) if breathing has stopped and CPR if heart action has stopped. f Transfer promptly to a medical facility. f Medical observation is recommended for 24 to 48 hours after overexposure, as pulmonary edema may be delayed. EMERGENCY NUMBERS Poison Control: 1-800-222-1222 CHEMTREC: 1-800-424-9300 NJDEP Hotline: 1-877-927-6337 National Response Center: 1-800-424-8802 SULPHAMIC ACID Page 2 of 6 Determining Your Exposure Reproductive Hazard f According to the information presently available to the New f Read the product manufacturer’s Material Safety Data Jersey Department of Health, Sulphamic Acid has not been Sheet (MSDS) and the label to determine product tested for its ability to affect reproduction. ingredients and important safety and health information about the product mixture. Other Effects f Sulphamic Acid can irritate the lungs. Repeated exposure f For each individual hazardous ingredient, read the New may cause bronchitis to develop with coughing, phlegm, Jersey Department of Health Hazardous Substance Fact and/or shortness of breath. Sheet, available on the RTK website f Repeated exposure to Sulphamic Acid may affect the liver (www.nj.gov/health/eoh/rtkweb) or in your facility’s RTK and kidneys. Central File or Hazard Communication Standard file. f You have a right to this information under the New Jersey Worker and Community Right to Know Act, the Public Medical Employees Occupational Safety and Health (PEOSH) Act Medical Testing if you are a public worker in New Jersey, and under the If symptoms develop or overexposure is suspected, the federal Occupational Safety and Health Act (OSHA) if you following are recommended: are a private worker. f Lung function tests f The New Jersey Right to Know Act requires most f Consider chest x-ray after acute overexposure employers to label chemicals in the workplace and f Liver and kidney function tests requires public employers to provide their employees with information concerning chemical hazards and controls. Any evaluation should include a careful history of past and The federal OSHA Hazard Communication Standard (29 present symptoms with an exam. Medical tests that look for CFR 1910.1200) and the PEOSH Hazard Communication damage already done are not a substitute for controlling exposure. Standard (N.J.A.C. 12:100-7) require employers to provide similar information and training to their employees. Request copies of your medical testing. You have a legal right to this information under the OSHA Access to Employee This Fact Sheet is a summary of available information Exposure and Medical Records Standard (29 CFR 1910.1020). regarding the health hazards that may result from exposure. Duration of exposure, concentration of the substance and other Mixed Exposures factors will affect your susceptibility to any of the potential f Smoking can cause heart disease, lung cancer, effects described below. emphysema, and other respiratory problems. It may worsen respiratory conditions caused by chemical exposure. Even if you have smoked for a long time, stopping now will reduce Health Hazard Information your risk of developing health problems. Acute Health Effects f More than light alcohol consumption can cause liver The following acute (short-term) health effects may occur damage. Drinking alcohol can increase the liver damage immediately or shortly after exposure to Sulphamic Acid: caused by Sulphamic Acid. f Contact can severely irritate and burn the skin and eyes with possible eye damage. f Inhaling Sulphamic Acid can irritate the nose and throat. f High exposure to Sulphamic Acid can irritate the lungs causing coughing and/or shortness of breath. Higher exposures may cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency, with severe shortness of breath. f Sulphamic Acid can cause nausea, vomiting and stomach pain. Chronic Health Effects The following chronic (long-term) health effects can occur at some time after exposure to Sulphamic Acid and can last for months or years: Cancer Hazard f According to the information presently available to the New Jersey Department of Health, Sulphamic Acid has not been tested for its ability to cause cancer in animals. SULPHAMIC ACID Page 3 of 6 Workplace Controls and Practices Eye Protection Very toxic chemicals, or those that are reproductive hazards or f Wear eye protection with side shields or goggles. sensitizers, require expert advice on control measures if a less f Wear a face shield along with goggles when working with toxic chemical cannot be substituted. Control measures corrosive, highly irritating or toxic substances. include: (1) enclosing chemical processes for severely irritating and corrosive chemicals, (2) using local exhaust Respiratory Protection ventilation for chemicals that may be harmful with a single Improper use of respirators is dangerous. Respirators exposure, and (3) using general ventilation to control should only be used if the employer has implemented a written exposures to skin and eye irritants. For further information on program that takes into account workplace conditions, workplace controls, consult the NIOSH document on Control requirements for worker training, respirator fit testing, and Banding at www.cdc.gov/niosh/topics/ctrlbanding/. medical exams, as described in the OSHA Respiratory The following work practices are also recommended: Protection Standard (29 CFR 1910.134). f Label process containers. f At any detectable concentration, use a NIOSH approved f Provide employees with hazard information and training. negative pressure, air-purifying, particulate filter respirator f Monitor airborne chemical concentrations. with an N95 filter. More protection is provided by a full f Use engineering controls if concentrations exceed facepiece respirator than by a half-mask respirator, and even recommended exposure levels. greater protection is provided by a powered-air purifying f Provide eye wash fountains and emergency showers. respirator. f Wash or shower if skin comes in contact with a hazardous f Leave the area immediately if (1) while wearing a filter or material. cartridge respirator you can smell, taste, or otherwise detect f Always wash at the end of the workshift. Sulphamic Acid, (2) while wearing particulate filters f Change into clean clothing if clothing becomes abnormal resistance to breathing is experienced, or (3) eye contaminated. irritation occurs while wearing a full facepiece respirator. f Do not take contaminated clothing home. Check to make sure the respirator-to-face seal is still good. f Get special training to wash contaminated clothing. If it is, replace the filter or cartridge. If the seal is no longer f Do not eat, smoke, or drink in areas where chemicals are good, you may need a new respirator. being handled, processed or stored. f Consider all potential sources of exposure in your workplace. f Wash hands carefully before eating, smoking, drinking, You may need a combination of filters, prefilters or cartridges applying cosmetics or using the toilet. to protect against different forms of a chemical (such as vapor and mist) or against a mixture of chemicals. In addition, the following may be useful or required: f Where the potential for high exposure exists, use a NIOSH approved supplied-air respirator with a full facepiece operated in a pressure-demand or other positive-pressure f Use a vacuum to reduce dust during clean-up. DO NOT mode. For increased protection use in combination with an DRY SWEEP. auxiliary self-contained breathing apparatus or an emergency escape air cylinder. Personal Protective Equipment The OSHA Personal Protective Equipment Standard (29 CFR Fire Hazards 1910.132) requires employers to determine the appropriate If employees are expected to fight fires, they must be trained personal protective equipment for each hazard and to train and equipped as stated in the OSHA Fire Brigades Standard (29 CFR 1910.156). employees on how and when to use protective equipment. f Sulphamic Acid may burn, but does not readily ignite.
Load more

Recommended publications
  • DUDA ENERGY LLC Safety Data Sheet Urea (Prilled)
    DUDA ENERGY LLC Safety Data Sheet Urea (Prilled) SECTION 1: Identification 1.1 Product identifier Product name Urea (Prilled) Product number Unavailable Brand Unavailable Substance name UREA EC no. 200-315-5 CAS no. 57-13-6 1.2 Other means of identification None 1.3 Recommended use of the chemical and restrictions on use Fertilizer, animal feed, plastics, chemical intermediate, stabilizer in explosives, medicine, adhesives, separation of hydrocarbons (as urea adducts), sulfamic acid production, flame proofing agents, viscosity modifier for starch, casein-based paper coatings, reported helpful in treatment of sickle-cell anemia, diuretic, and antiseptic. 1.4 Supplier's details Name Duda Energy LLC Address 1112 Brooks St. Decatur, AL 35601 USA Telephone 256.340.4866 Fax Unavailable email Unavailable 1.5 Emergency phone number(s) 800.255.3924 (Chemtel) SECTION 2: Hazard identification 2.1 Classification of the substance or mixture GHS classification in accordance with: UN GHS rev. 5 Not a hazardous substance or mixture. 2.2 GHS label elements, including precautionary statements Not a hazardous substance or mixture. 2.3 Other hazards which do not result in classification None known Statement regarding ingredients of unknown toxicity None SECTION 3: Composition/information on ingredients 3.1 Substances Substance name UREA EC no. 200-315-5 CAS no. 57-13-6 Formula CH4N2O Molecular weight 60.07 Other names / synonyms CARBAMIMIDIC ACID; UREA Impurities and stabilizing additives N/A SECTION 4: First-aid measures 4.1 Description of necessary first-aid measures General advice Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.
    [Show full text]
  • Material Safety Data Sheet
    Material Safety Data Sheet Issuing Date 2/25/2010 Revision Number 0 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Sulfamic Acid Powder Product Code(s) 6286 Recommended Use Laboratory chemicals. Industrial (not for food or food contact use). Company LaMotte Company, Inc. 802 Washington Avenue P.O. Box 329 Chestertown, MD 21620 USA Emergency Telephone Number 24 Hour Emergency Number (CHEM-TEL): USA, Canada, Puerto Rico 1-800-255-3924 Outside North American Continent (Call collect) 813-248-0585 2. HAZARDS IDENTIFICATION DANGER! Emergency Overview Corrosive Causes SEVERE IRRITATION and BURNS to EVERY AREA of contact. Harmful or fatal if swallowed May cause lung damage Appearance White Physical State Crystalline Odor Odorless OSHA Regulatory Status This product is an article which contains a chemical substance. Safety information is given for exposure to the article as sold, but considers exposure to the chemical if user has direct eye and skin contact with the chemical. Potential Health Effects Principle Routes of Exposure Skin contact, Eye contact, Ingestion, and, Inhalation Acute Toxicity Eyes Causes burns. May cause irreversible damage to eyes. Skin Contact causes severe skin irritation and possible burns. Inhalation Inhalation of corrosive dusts can be extremely destructive to tissues of the mucous membranes and upper respiratory tract. Can cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting. May cause pulmonary edema, a medical emergency. Ingestion Ingestion causes burns of the upper digestive and respiratory tract. May be fatal if swallowed. Chronic Effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula H2NSO3H Chemical Name CAS-No Weight % Sulfamic acid 5329-14-6 100 _____________________________________________________________________________________________ Published Date: 26-Feb-2010 Page 1 / 6 Sulfamic Acid Powder Product Code(s) 6286 _____________________________________________________________________________________________ 4.
    [Show full text]
  • New Metal Extractants and Super-Acidic Ionic Liquids Derived from Sulfamic Acid† Cite This: Chem
    ChemComm COMMUNICATION New metal extractants and super-acidic ionic liquids derived from sulfamic acid† Cite this: Chem. Commun., 2016, 52,7032 David Dupont, Evelien Renders, Stijn Raiguel and Koen Binnemans* Received 17th March 2016, Accepted 4th May 2016 DOI: 10.1039/c6cc02350a www.rsc.org/chemcomm Sulfamic acid (NH3–SO3) is an acidic zwitterion with many applications. of interest because of their very high solubility, due to the N-Alkylated derivatives are introduced, which can be used as a new zwitterionic nature of sulfamic acid.1 In fact, many sulfamate 2+ class of metal extractants R2NH–SO3 and as new super-acidic ionic salts are amongst the most soluble metal salts known (e.g. Ni , 2+ liquids [R2NH–SO3H][Tf2N]. The synthesis, properties and novel appli- Pb ), making it an ideal counterion for high current density cationsofthisversatileplatformarediscussed. electroplating.2,3,13 Metal sulfamates can be prepared by reaction between sulfamic acid and a metal carbonate or oxide (eqn (2)): Sulfamic acid is an interesting compound due to its zwitter- 1 - ionic nature and relatively strong acidity (pKa E 1). It is closely NiO + 2NH3–SO3 Ni(NH2SO3)2 +H2O (2) related to sulfuric acid, but it is a solid, making it unique among the strong inorganic acids. It is prepared industrially by Sulfamate ions are ambivalent ligands, which leads to a rich 1 reacting urea with sulfur trioxide and sulfuric acid (eqn (1)).2,3 coordination chemistry. For example, sulfamate complexes of Zn(II), Co(II), Ni(II) and rare-earth ions (La–Lu, Y) are bonded - II OQC(NH2)2 +SO3 +H2SO4 CO2 + 2NH3–SO3 (1) through the oxygen atom, while sulfamate complexes of Pt( ), Pt(IV), Cr(III), and Ru(III) are bonded through the nitrogen + À 1,14–18 Sulfamic acid is best described by the formula NH3–SO3 and atom.
    [Show full text]
  • Lawrence Berkeley Laboratory UNIVERSITY of CALIFORNIA APPLI ED SCI ENCE .]
    Lawrence Berkeley National Laboratory Recent Work Title Reaction of Ferrous Chelate Nitrosyl Complexes with Sulfite and Bisulfite Ions Permalink https://escholarship.org/uc/item/4172g03z Journal Industrial and engineering chemistry research, 29(1) Authors Littlejohn, D. Chang, S.-G. Publication Date 2017-12-04 eScholarship.org Powered by the California Digital Library University of California LBL-17962 Preprint Lawrence Berkeley Laboratory UNIVERSITY OF CALIFORNIA APPLI ED SCI ENCE .] .. DIVISION L18RARY AND Submitted to the Journal of the American. DOCUMENTS SECTION Chemical Society REACTION OF FERROUS NITROSYL CHELATES WITH SULFITE AND BISULFITE IONS D. Littlejohn and S.G. Chang November 1984 'i: TWO-WEEK LOAN COpy' This is a Library Circulating Copy '~~j ,.~ which' m~y$;I.!~~bJ;)frowed' fof'fw"Q' we1~ .~ . ~:~~~- -~<~~.;. :- .\(~"':"'~':"~:; " '''J!: ,~,~,i • ~I c~--,~~)- .7..1~:--;(; ~ , ,,'>:&:-}:?, :'~'T1~; , ~' APPLIED SCIENCE DIVISION Prepared for the U.S. Department of Energy under Contr2ct DE-AC03-76SF00098 DISCLAIMER This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain COlTect information, neither the United States Government nor any agency thereof, nor the Regents of the University of California, nor any of their employees, makes any warranty, express or implied, or assumes any legal responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by its trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof, or the Regents of the University of California.
    [Show full text]
  • SDS: Sulfamic Acid, Powder Pack Reagent
    YSI sells this product under agreement with the original manufacturer. YSI assumes no legal liability or responsibility for the accuracy, completeness or usefulness of any information set forth in this MSDS. Page 1/8 Safety Data Sheet acc. to ISO/DIS 11014 Printing date 04/24/2014 Reviewed on 04/24/2014 * 1 Identification · Product identifier · Trade name: Vario Sulfamic Acid F10 · Catalogue number: 251395Y · Relevant identified uses of the substance or mixture and uses advised against: No further relevant information available. · Application of the substance / the mixture: Reagent for water analysis · Manufacturer/Supplier: Distributor/Supplier: YSI, Inc Tintometer Inc. Address 1700/1725 Brannum Lane 6456 Parkland Drive Yellow Springs, Ohio 45387 Sarasota, FL 34243 Telephone (937) 767-7241 USA E-mail [email protected] phone: (941) 756-6410 fax: (941) 727-9654 www.lovibond.us Made in Germany ® · Emergency telephone number: Chemtrec : (US & Canada) 800-424-9300 (International) +1 (703) 527-3887 * 2 Hazard(s) identification · Classification of the substance or mixture US-GHS ~ GHS07 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC ?@G Xi; Irritant R36/38: Irritating to eyes and skin. R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS07 · Signal word Warning · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. · Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection.
    [Show full text]
  • 2016 Chemengj 3 Soler-Et-Al.Pdf
    Chemical Engineering Journal 287 (2016) 720–726 Contents lists available at ScienceDirect Chemical Engineering Journal journal homepage: www.elsevier.com/locate/cej Importance of abiotic hydroxylamine conversion on nitrous oxide emissions during nitritation of reject water Aina Soler-Jofra a,b, Berber Stevens a, Maaike Hoekstra a, Cristian Picioreanu a, Dmitry Sorokin a,c, ⇑ Mark C.M. van Loosdrecht a, Julio Pérez a, a Department of Biotechnology, Faculty of Applied Sciences, Delft University of Technology, Julianalaan 67, 2628 BC Delft, The Netherlands b Department of Chemical, Biological and Environmental Engineering, Universitat Autonoma de Barcelona, 08193 Cerdanyola del Valles, Spain c Winogradsky Institute of Microbiology Research Centre of Biotechnology, Russian Academy of Sciences, Moscow, Russia highlights Abiotic reaction of NH2OH with HNO2 can contribute to N2O emissions in nitritation. The abiotic N2O emission was measured at the conditions of sidestream nitritation. Residual NH2OH concentration was measured in a full scale nitritation reactor. article info abstract Article history: The spontaneous abiotic (or chemical) reaction of hydroxylamine (NH2OH) at low concentrations Received 25 September 2015 (<0.4 mg N/L) with free nitrous acid (HNO2) was investigated at the conditions of partial nitritation of Received in revised form 13 November 2015 reject water. An abiotic batch reactor test was used to quantitatively assess the kinetics of the nitrous Accepted 21 November 2015 oxide (N O) emission. The estimated chemical N O emission rate was 0.16 mg N/L/h. In addition, the con- Available online 2 December 2015 2 2 centration of NH2OH in a full scale nitritation reactor, Single reactor High Activity ammonium Removal over Nitrite (SHARON) was measured in the range ca.
    [Show full text]
  • Material Safety Data Sheet Sulfamic Acid, ACS Section 1
    ISO9001:2000 Certified Material Safety Data Sheet Sulfamic acid, ACS Section 1 - Chemical Product and Company Identification MSDS Name: Sulfamic acid, ACS Catalog Numbers: LC25420 Synonyms: Amidosulfonic acid, amidosulfuric acid, aminosulfonic acid, sulfamidic acid, sulphamic acid. Company Identification: LabChem, Inc. 200 William Pitt Way Pittsburgh, PA 15238 Company Phone Number: (412) 826-5230 Emergency Phone Number: (800) 424-9300 CHEMTREC Phone Number: (800) 424-9300 Section 2 - Composition, Information on Ingredients CAS# Chemical Name: Percent 5329-14-6 Sulfamic acid 100% Section 3 - Hazards Identification Emergency Overview Appearance: White powder Warning! Causes eye, skin, and respiratory tract irritation and possible burns. Corrosive to metal in aqueous solution. Target Organs: Eyes, skin, mucous membranes. Potential Health Effects Eye: Causes eye irritation. Concentrated solutions may produce corrosive effects. Skin: Causes skin irritation. Concentrated solutions may produce corrosive effects. Ingestion: May cause irritation or burns of the digestive tract with nausea, vomiting, and diarrhea. Inhalation: Cause respiratory tract irritation. Chronic: Chronic inhalation or ingestion may cause effects similar to those of acute inhalation and ingestion. - 1 - Material Safety Data Sheet Sulfamic acid, ACS Section 4 - First Aid Measures Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids until no evidence of chemical remains. Get medical aid at once. Skin: Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid at once. Ingestion: Do not induce vomiting. If victim is conscious, give 2-4 glasses of water or milk. Get medical aid at once.
    [Show full text]
  • Chemical Denitrification of Nitrate from Groundwater Via Sulfamic Acid and Zinc Metal
    Iran. J. Environ. Health. Sci. Eng., 2006, Vol. 3, No. 3, pp. 141-146 CHEMICAL DENITRIFICATION OF NITRATE FROM GROUNDWATER VIA SULFAMIC ACID AND ZINC METAL *A. Sabzali, M. Gholami, A. R. Yazdanbakhsh, A. Khodadadi, B. Musavi, R. Mirzaee Department of Environmental Health, School of Public Health, Isfahan University of Medical Science, Isfahan, Iran Received 19 Jaunuary 2006; revised 5 March 2006; accepted 20 May 2006 ABSTRACT Nitrate contamination in drinking water can cause methemoglobinemia, which is especially detrimental to infants and nursing mothers. Batch experiments in two units for catalytic reduction of nitrate from groundwater with Zn catalyst and sulfamic acid were conducted. The system includes chemical denitriphication (ChemDen reactor) and electrolytic recovery reactoers. A batch study was conducted to optimize parameters like pH, sulfamic acid concentration, Zn concentration, temperature and reaction time governing the ChemDen process. The concentrations of remained nitrate and Zn were measured at the end of the reactions. Results showed that near to 100% of nitrate decreased and the quantity of remained nitrate was <1 mg/L. pH and agitation had great effect on denitrification, and the nitrate removal rate changed rapidly when pH value ranged between 3-4. Two water quality parameters which limit this process were sulfate and chloride ions concentrations in nitrate contaminated water. Key words: Chemical denitrification, groundwater, zinc, sulfamic acid, electrolytic reactor INTRODUCTION - Nitrate (NO3 ) concentrations in groundwater organic carbon is present. Water treatment have increased globally (Kapoor and Viraragh- processes stimulate denitrification by injection of avan 1997). Wastewater, fertilizers, and livestock nutrients. Such organic compounds as methanol, farming are major sources of nitrate in groundwater methane, glucose, and starch or mixtures of these supplies.
    [Show full text]
  • Reply to Dr. Wolfgang Wanek We Are Grateful for the Constructive Comments and Helpful Suggestions of Dr
    Reply to Dr. Wolfgang Wanek We are grateful for the constructive comments and helpful suggestions of Dr. Wanek. Below are detailed responses to all the comments and corresponding explanations of the revisions made to the manuscript. Line numbers cited in the replies (highlighted) refer to the revised manuscript document with tracked changes displayed (attached with this reply). Please refer to our replies to Referee #1 for other revisions of the manuscript. The paper reports on the isotopic fractionation of source and sink processes underlying soil NO emissions, NO emissions being important for atmospheric chemistry and as a soil N loss pathway. I am impressed by this study, proving in-depth analysis of isotopic constraints on formation and consumption pathways of soil NO, and partitioning the contribution of nitrifiers and denitrifiers as well as abiotic reactions. The approach taken with aerobic, suboxic and anoxic soil incubations combined with inorganic N additions in live and sterile soils, N and O isotope measurements in inorganic soil N and NO, amended by isotope fractionation and flux modeling provides a most complete assessment of NO source and sink processes. This study therefore highlights that stable isotope measurements in inorganic soil N with those in NO and N2O can help in source attribution of these important atmospheric gases. Reply: We are grateful for the encouraging remarks and positive feedback. Comment 1: Minor corrections can be found in the annotated PDF. Reply: We have incorporated all the corrections and edits into the revised manuscript. Thank you. Comment 2: Lines 59-61: There are also complete ammonia oxidizing Nitrospira, that catalyze the whole nitrification reaction sequence from ammonia to nitrate in one organism (comammox bacteria).
    [Show full text]
  • Lawrence Berkeley National Laboratory Lawrence Berkeley National Laboratory
    Lawrence Berkeley National Laboratory Lawrence Berkeley National Laboratory Title REACTIONS OF SULFITE AND NITRITE IONS IN AQUEOUS SOLUTIONS Permalink https://escholarship.org/uc/item/5b71j9dv Author Chang, S.G. Publication Date 1980-11-01 eScholarship.org Powered by the California Digital Library University of California LBL-11800 Invited paper presented at the Department of Energy/Advanced Environmental Control Technology Program, Morgantown, WV, November 6-7, 1980 REACTIONS OF SULFITE AND NITRITE IONS IN AQUEOUS SOLUTIONS S. G. Chang November 1980 TWO-WEEK LOAN COPY This is a Library Circulating Copy which may be borrowed weeks. a copy)' call Info. Division)' Ext. 6782. Prepared for the U.S. Department of Energy under Contract W-7405-ENG-48 DISCLAIMER This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United States Government nor any agency thereof, nor the Regents of the University of California, nor any of their employees, makes any warranty, express or implied, or assumes any legal responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by its trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof, or the Regents of the University of California. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Govemment or any agency thereof or the Regents of the University of Califomia.
    [Show full text]
  • MSDS 105599 Date Prepared
    World Headquarters Page 1 Hach Company Date Printed 6/13/14 P.O.Box 389 MSDS No: M00007 Loveland, CO USA 80539 (970) 669-3050 MATERIAL SAFETY DATA SHEET _____________________________________________________________________________ 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Sulfamic Acid Catalog Number: 105599 Hach Company Emergency Telephone Numbers: P.O.Box 389 (Medical and Transportation) Loveland, CO USA 80539 (303) 623-5716 24 Hour Service (970) 669-3050 (515)232-2533 8am - 4pm CST MSDS Number: M00007 Chemical Name: Sulfamic Acid CAS Number: 5329-14-6 Additional CAS No. (for hydrated forms): Not applicable Chemical Formula: H3NO3S Chemical Family: Inorganic Acid Intended Use: Laboratory Use _____________________________________________________________________________ 2. HAZARDS IDENTIFICATION GHS Classification: Hazard categories: Corrosive to Metals: Met. Corr. 1 Acute Toxicity: Acute Tox. 4-Orl Skin Corrosion/Irritation: Skin Irrit. 2 Serious Eye Damage/Eye Irritation:Eye Irrit. 2 Hazardous to the Aquatic Environment: Aquatic Chronic 3 GHS Label Elements: WARNING Hazard statements: May be corrosive to metals. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Harmful to aquatic life with long lasting effects. Precautionary statements: Wear protective gloves / protective clothing / eye protection / face protection. Do no eat, drink or smoke when using this product. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Absorb spillage to prevent material damage. HMIS: Health: 1 Flammability: 1 Reactivity: 1 Protective Equipment: X - See protective equipment, Section 8.
    [Show full text]
  • Molybdenum Oxotransferase Active Site Models and Their Oxygen Atom
    Molybdenum Oxotransferase Active Site Models and Their Oxygen Atom Transfer Reactivity By Lee Taylor Elrod B.S. University of Vermont 2010 A Dissertation Submitted in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy in the Department of Chemistry at Brown University Providence, Rhode Island, May 2018 © Copyright 2018 Lee Taylor Elrod This dissertation by Lee Taylor Elrod is accepted in its present form by the Department of Chemistry as satisfying the dissertation requirement for the degree of Doctor of Philosophy Recommended to the Graduate Council Date____________ _____________________________ Eunsuk Kim, Ph.D. Advisor Date____________ _____________________________ Jerome Robinson, Ph.D. Reader Date____________ _____________________________ Paul Williard, Ph.D. Reader Approved by the Graduate Council Date____________ _____________________________ Andrew G. Campbell, Ph.D. Dean of the Graduate School iii Curriculum Vitae Lee Taylor Elrod Education: PhD Inorganic Chemistry with Dr. Eunsuk Kim 2018 Brown University, Providence, RI B.S. Degree in Chemistry 2010 University of Vermont, Burlington, VT High School Diploma 2006 Libertyville High School, Libertyville, IL Academic Accomplishments: • Dissertation Fellowship, Brown University • Recipient Charles E. Braun Award, University of Vermont • Recipient Clinton D. Cook Award in Chemistry, University of Vermont • Recipient Presidential Scholarship (2006-2010), University of Vermont • Recipient Academic Excellence Scholarship (2006-2010), University of Vermont Presentations: Elrod, L. T.; Kim, E. “Oxygen Atom Transfer Mediated By Molybdenum Oxo Complexes and Lewis Acid”. Poster presentation at 252nd ACS National Meeting & Exposition, Philadelphia, PA, August 2016 Publications: • Elrod, L. T.; Robinson, J. R.; Victor, E.; Kim, E. “Lewis Acid Enhanced Nitrate and Perchlorate reduction by Mo(µ-O) Dimer” Manuscript in preparation.
    [Show full text]