Comments on Units in Magnetism*
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JOURNAL OF RESEARCH of the National Bureau of Standards Vo lume 83, No.1 , Jonuary- February 1978 Comments on Units in Magnetism* L. H. Bennett, C. H. Page, and L. J. Swartzendruber Institute for Materials Research, National Bureau of Standards, Washington, D.C. 20234 (August 26, 1977) Suggestions are give n on how to express magne ti c qua ntities in 51 units . Key words: Magneti sm; units . 1. Introduction mass s usceptibility for y-Fe in cmJ/g, and the rationalized volume susceptibility for Li (d im e nsionless). Since these Perus in g the 1974 M3 Co nference Proceedings indicates differences in units are not li sted in the table, a n unsus pect that, at the present time, Systeme Internationale (S l) units ing user could eas il y be mi sled. As most commonl y used are avo id ed by most lead in g scientis ts and engineers in the with sr, the re la ti on be tween B, H, and M is defin ed as B = fi eld of magneti sm. Throughout the Proceedings, almost /1-0 (H + M) , X = M/H. Some a uthors [3] exh ibit the /1-0 universal preference is di s played for th e cgs e lectromagneti c assoc iated with the sr explic itly by re plac in g, H by B//1-o , system (or for the Gaussian system, whic h gives an equ ivalent giving X = /1-oM / B. This is, of course, approximately correct description of magneti c quantities). However, usage of SI for th e small s usceptibilities found in most diamagneti c and units in the fi eld of magneti sm will undoubtedly in crease paramagneti c mate ri als, but could be mi sappl ied to super with time. One barrier to in creased usage is the present lack paramagneti c or fe rromagneti c materi als. of standardized and agreed upon relationships be tween magne ti c quantities within the SI. In this paper we will 3. Recommendations tentatively propose notati on and definiti ons for those relation ships most freque ntl y used by experimentalists, with the In orde r to ease conversion from Gaussian (and cgs emu) hope that this will help stimulate the magneti sm community to SJ units, the names, definitions, and symbols for magneti c to make their vi ews known on preferred definitions. quantities should be s tandardized. This requires agreement within the magneti sm community. Our curre nt recomme nda 2. Some Considerations on the Two Systems tions are summarized in the tables. Table 1 lists recommend ed symbols a nd names for mag One major property of the Gaussian (and the cgs emu) neti c quantities in SI a nd cgs emu. Whe n using SI units to system, considered an advantage by some and a disadvantage express susceptibility, we believe it would be useful to label by others, is that Band H have the same numeri cal va lue in it 'rationalized' and give it the sy mbol K , reserving X for the empty s pace. Changing to the SI , whe re not only do Band non-rationalized cgs e mu system. What we have labeled the H have different units in empty space, but also different "volume susceptibility" in table 1 is ofte n referred to simply numerical magnitudes, puts one somewhat in the position of as just "susceptibility." The introduc ti on of the symbol J Casimir's [1 p mythical tangenometrists who decided that, (where J = /1-oM) in the SI is useful due to the controversy " The volumetric displacement of empty space - although [4] over wh ether one s hould defin e B = /1-0 (H + M) or B = equal to unity - had the dimension Archimedes per Euclid." /1- 0 H + M. Furthe r, the symbol J and the associated name The Sl is a "rationalized" syste m, wh ereas the Gaussian ' magnetic polarization', are in current use [5]. is unrationalized. Thus, when magneti c susceptibilities are Table 2 compares several of the more important equations converted between the two systems a fac tor of 47T is involved. in the fi e ld of magneti sm. Equations (1) and (2) define the Fut·th er factors of 10 are involved de pending on wh ether recommended usage of the symbols M and J in sr, as vo lume, mass, or molar s usceptibility is in question. This mentioned above. In both Gaussian and SI units, the volume gives consid erable latitude for errors and ambiguities in data susceptibility, defin ed by eq (3), is dime nsionless and is the compilations, handbooks, and treati ses which attempt to ratio of M to H , (both with magnitudes which will change by convert existing numeri cal values to SI units, and numerous a factor of 47T upon rationalization). Equation (4) giv es the examples of such e rrors can be found . For example, in the force on a material placed in a magnetic field gradient. recent treatise on magne ti c materials by Heck [2], who (This equation involves certain assumptions and is most endeavors to use SI units as much as possible, a table of useful for small samples with small susceptibilties.) Equation paramagnetic susceptibilties apparently gives the rational (5) gives the energy of a (point) magnetic moment in a ized mass susceptibility for Pt in cm3/g, the unrationalized magnetic field , and eq (6) gives the volume energy density associated with a magneto static fi eld. * Reprinlt:d from AlP Conference Preceedings, No. 29, (2 1st Annual Conference- Philadelphia), Table 3 gives numerical factors for converting between beca use of il s interest 10 lIsers of magnetic un its. 1 Figures in brackets indicate the litera ture references at the e nd of th is paper. the two unit systems. The conversions for flux density, B, 9 TABLE I TABLE 2 Symbols and names for magneti c quantities in S I a nd cgs, Gaussian (or Corresponding equation s in SI and cgs Gaussian (o r cgs e mu). In this cgs emu). table, F refers to force, W refers to the e ne rgy of a magneti c dipole in a fi led , w refe rs to the volume e nergy densit y. Othe r symbols are defined in Name table 1. Symbol cgs emu S I Gaussian (or cgs e mu) Sl B nux de nsity magneti c nux densit y (magnetic induc- B = H + 47TM B = /1-0 (H + M) (1) induction tion) B = /1-o H + J (2) x = M/ H K = M/ H (3) H magnet ic field s tre ngt h magnetic field stre ngth iiH F = /1-oKVH aH/iix (4) F= XVH - ax M magnetization magnetization W = - mBcosli W = - mBcos li (5) BH w = ~BH (6) magn etic polarization w= 8 7T x vo lume susceptibility K rat iona lized volume susce pti and s usceptibility, X and K, are inde pende nt of the conven bility tions adopted, i. e. whether B = H + M, B = JLo H + M, mass susceptibility etc. Other conversions will depend on these conve ntions . One problem for th ose not thoroughly fam ilar with current rationalized mass susce ptibil magnetic unit usage is that 'emu' is not reall y a unit but it y rathe r a nag to describe the unit system be ing used. Often, Xmole molal' susceptibilit y though not always, a dimensional anayls is on s usceptibility units may be performed if 'emu' is re placed by c m3. Another Kmole rational ized mo lar suscept i problem which undoubtedly gives further difficulty to the bility uninitiated is the variety of units used for the same quantity m magneti e moment magn et ie mom ent in the Gaussian sys tem. For example, in the 1974 M3 conference proceedings we find the following units used for /1-B Bohr magneton Bohr magneton " magnetization": G, Oe, emu/g, JLB/atom, B.M./FORMULA TABLE 3. Conve rsion from. Gaussian to 51 Units Multipl y the Numbe r for To Obtain the Number for by Gaussian Quantity Un it SI Quantity Un it nux densit y, B G 10 4 nux de nsity, B T( = Wb/ m' = Vs/m2) magneti c field strength, H Oe 1Q3/4 7T magneti c fi eld stre ngth, H A/ m volume susceptibility, X e mu/c lII 3 (dime ns ionless) 47T rationalized vo lume susce pti- dimension less b ilit y, K mass susceptibilit y, Xp e mu/g (=cm3/g) 4 7T . 10- 3 rat iona} izecl mass susceptibil- m3/ kg ity, Kp molar suscept ibility, * Xmole e mu/ mol ( = c Ill3/ mol) 4 7T · 1O- 6 rationalized molar susceptibil- m3/ mol ity, Km ul e G or Oe 10 3 magnetization, M Aim magnetization, M 4 7T . 10- 4 magnetic polari zation, J T G 01' Oe 10"/47T magnetization, M Aim magneti zation,47TM 10- 4 magnetic polarization, J T /1-B /atom or /1- B/ fol'm. unit, I magnetization, M /1-B /atom or magnetization, M elc . ** /1-B /form. un it , e tc . ** magneti c moment of a e rglG 10- 3 magneti c moment of a J/T (= An?) dipole, m clipole, m dimensionless 1/47T rati onalized de magnetizing fac- d imensionless de magnetizing fac tor. N tor, N a Also called atomi c susceptibil it y. Molar suscepllbillty IS preferred s ince atomiC suscepti bi lity has also been used to refe r to the susceptibility pe r atom. ** " Natura l" units, inde pende nt of unit syste m.