OAR 340-245-8010 Table 1 Risk Action Levels†
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Report of the Advisory Group to Recommend Priorities for the IARC Monographs During 2020–2024
IARC Monographs on the Identification of Carcinogenic Hazards to Humans Report of the Advisory Group to Recommend Priorities for the IARC Monographs during 2020–2024 Report of the Advisory Group to Recommend Priorities for the IARC Monographs during 2020–2024 CONTENTS Introduction ................................................................................................................................... 1 Acetaldehyde (CAS No. 75-07-0) ................................................................................................. 3 Acrolein (CAS No. 107-02-8) ....................................................................................................... 4 Acrylamide (CAS No. 79-06-1) .................................................................................................... 5 Acrylonitrile (CAS No. 107-13-1) ................................................................................................ 6 Aflatoxins (CAS No. 1402-68-2) .................................................................................................. 8 Air pollutants and underlying mechanisms for breast cancer ....................................................... 9 Airborne gram-negative bacterial endotoxins ............................................................................. 10 Alachlor (chloroacetanilide herbicide) (CAS No. 15972-60-8) .................................................. 10 Aluminium (CAS No. 7429-90-5) .............................................................................................. 11 -
Listed Toxic Air Contaminants and Common Chemicals
Listed Toxic Air Contaminants and Common Chemicals (sorted by Chemical name) CHEMICAL NAME CAS # Listed Air Toxic 1,1,1,2-Tetrachloroethane 630206 Y 1,1,1,2-Tetrafluoroethane 811972 Y 1,1,2,2-Tetrachloroethane 79345 Y 1,1,2-Trichloroethane 79005 Y 1,1-Difluoroethane (HCFC 152a) 75376 Y 1,1-Dimethyl hyrazine 57147 Y 1,2,4 Trimethylbenzene 95636 N 1,2,4-Trichlorobenzene 120821 Y 1,2-Dibromo-3-chloropropane 96128 Y 1,2-Dichlorobenzene 95501 Y 1,2-Dimethyl hyrazine 540738 Y 1,2-Diphenylhydrazine (Hydrazobenzene) 122667 Y 1,2-Epoxybutane 106887 Y 1,2-Propylenimine (2-Methyl aziridine) 75558 Y 1,3-Butadiene 106990 Y 1,3-Dichloropropene 542756 Y 1,3-Propane sultone 1120714 Y 1,4-Dichlorobenzene (p-Dichlorobenzene) 106467 Y 1,4-Dioxane (1,4-Diethyleneoxide) 123911 Y 1-Chloro-1,1-difluoroethane (CFC 142B) 75683 Y 2,2,4-Trimethylpentane 540841 Y 2,4,5-Trichlorophenol 95954 Y 2,4,6-Trichlorophenol 88062 Y 2,4-and 2,6-Toluene diisocyanateh 26471625 Y 2,4-Diaminoanisole 615054 Y 2,4-Diaminotoluene 95807 Y 2,4-Dichlorophenoxyacetic acid, salts & esters 94757 Y (2,4-D) 2,4-Dimethylphenol 105679 Y 2,4-Dinitrophenol 51285 Y 2,4-Dinitrotoluene 121142 Y 2,4-Toluene diamine (2,4-Diaminotoluene) 95807 Y 2-Acetylaminofluorene 53963 Y 2-Aminoanthraquinone 117793 Y CHEMICAL NAME CAS # Listed Air Toxic 2-Chloroacetophenone 532274 Y 2-Chlorophenol 95578 Y 2-Nitropropane 79469 Y 3,3'-Dichlorobenzidene 91941 Y 3,3'-Dimethoxybenzidine 119904 Y 3,3'-Dimethyl benzidine 119937 Y 4,4-Methylene bis (2-chloroaniline) 101144 Y 4,4-Methylenedianiline 101779 Y 4,6-Dinitro-o-cresol -
Sulfuric Acid Aerosol Is Formed by the Oxidation of SO in Standard, NH /N ) Diluted to 2 RELATIVE HUMIDITY (RH) 3 2 Gas/Aqueous/Aerosol Phase
INVESTIGATIONS OF THE HETEROGENEOUS REACTION BETWEEN AMMONIA AND SULFURIC/SULFUROUS ACID AEROSOLS Thomas Townsend, Colette Noonan and John R. Sodeau Centre for Research into Atmospheric Chemistry, Department of Chemistry, University College Cork, and Environmental Research Institute, Cork, Ireland. [email protected] INTRODUCTION EXPERIMENTAL SET-UP AMMONIA (100ppm Sulfuric acid aerosol is formed by the oxidation of SO in standard, NH /N ) diluted to 2 RELATIVE HUMIDITY (RH) 3 2 gas/aqueous/aerosol phase. The preferred form of sulfuric acid tuned between 1% and 70%. ppb range. Admitted to flow AEROSOL GENERATION tube via a 6mm diameter in the aerosol phase is ammonium sulfate (NH4)2SO4. If there H2SO4 /C2H2O4 aerosol Dilution Unit movable, glass injector. is not enough ammonia present, sulfuric acid exists either as generated by passing a flow (200-500 ccm) of air over a P H2SO4(aq) or NH4HSO4. heated solution or via a nebuliser. AEROSOL FLOW-REACTOR Aerosols AerosolAerosol Humidifier Generator Made of glass, ID: 10cm, maximal ….are tiny particles suspended in the air. Those larger than reactive length Z: 80cm. Aerosol Flow Carrier Flow Operated at room temperature and Soluble trace gases such as Ammonia, about 1μm in size are mainly produced by windblown dust Comp. Air atmospheric pressure. NH3, are produced from agricultural and sea-spray. Aerosols smaller than 1μm are mostly formed Unit by condensation processes e.g. conversion of SO gas released PARTICLE SIZER (SMPS) sources and represents a significant 2 from volcanic eruptions to sulfate-type particles. Monitors aerosol fraction, NH3/N2 atmospheric pollutant in Ireland. particle size, mass, surface SMPS CHEMILUMINESCENCE area, volume. -
Orca Corrosion Chart
Unsaturated Polyester Vinylster (Epoxy Acrylate Resins) CHEMICAL Conc Resins NO ISO BIS Novolac Bromine ENVIRONMENT % 511/512 301 585 570 545/555 A 1 Acetaldehyde 20 NR 40 40 40 2 Acetic Acid 10 80 100 100 100 3 Acetic Acid 15 60 100 100 100 4 Acetic Acid 25 60 100 100 100 5 Acetic Acid 50 - 80 80 80 6 Acetic Acid 75 NR 65 65 65 7 Acetic Acid, Glacial 100 NR NR 40 NR 8 Acetic Anhydride 100 NR NR 40 NR 9 Acetone 10 NR NR 80 80 10 Acetone 100 NR NR NR NR 11 Acetonitrile 20 - 40 40 40 12 Acetyl Acetone 20 - 40 50 40 13 Acrolein (Acrylaldehyde) 20 - 40 40 40 14 Acrylamide 50 NR 40 40 40 15 Acrylic Acid 25 NR 40 40 40 16 Acrylic Latex All - 80 80 80 17 Acrylonitrile Latex Dispersion 2 NR 25 25 25 Activated Carbon Beds, Water 18 - 80 100 80 Treatment Adipic Acid(1.5g solution in 19 23 - 80 80 80 water at 25℃, sol in hot water) 20 ALAMINE amines - 65 80 65 21 Alkyl(C8-10) Dimethyl Amine 100 - 80 100 80 22 Alkyl(C8-10) Chloride All - 80 100 95 23 Alkyl Benzene Sulfonic Acid 90 NR 50 50 50 Alkyl Tolyl Trimethyl 24 - - 40 50 40 Ammonium Chloride 25 Allyl Alcohol 100 NR NR 25 NR 26 Allyl Chloride All NR 25 25 25 27 Alpha Methylstyrene 100 NR 25 50 25 28 Alpha Oleum Sulfates 100 NR 50 50 50 29 Alum Sat'd 80 100 120 100 30 Aluminum Chloride Sat'd 80 100 120 100 31 Aluminum Chlorohydrate All - 100 100 100 32 Aluminum Chlorohydroxide 50 - 100 100 100 33 Aluminum Fluoride All - 25 25 25 34 Aluminum Hydroxide 100 80 80 95 80 35 Aluminum Nitrate All 80 100 100 100 36 Aluminum Potassium Sulfate Sat'd 80 100 120 100 37 Aluminum Sulfate Sat'd 80 100 120 100 -
United States Patent (19) (11 3,954,955 Furkert (45) *May 4, 1976
United States Patent (19) (11 3,954,955 Furkert (45) *May 4, 1976 54 PROCESS FOR WORKING UP THE WASH Engineering, Duan Nostrand Co., N.Y., N.Y., 1932, SOLUTION OBTAINED IN THE WASHING pp. 1-3. OF SOCONTAINING OFF-GASES 75) Inventor: Herbert Furkert, Grosskonigsdorf, Primary Examiner-Oscar R. Vertiz Germany Assistant Examiner-Gary P. Straub 73) Assignee: Davy Powergas GmbH, Attorney, Agent, or Firm-Millen, Raptes & White Cologne-Braunsfeld, Germany * Notice: The portion of the term of this patent subsequent to Mar. 5, 1991, 57 ABSTRACT has been disclaimed. In a process which comprises scrubbing an SO 22 Filed: Aug. 30, 1972 containing gas with an aqueous ammonia solution to form ammonium sulfite and ammonium bisulfite as re (21) Appl. No.: 284,709 action products, neutralizing said reaction products Related U.S. Application Data with sulfuric acid to form SO, and aqueous ammo nium sulfate, and concentrating the resultant aqueous 63 Continuation-in-part of Ser. No. 228,258, Feb. 22, ammonium sulfate by evaporation, the improvement 1972, Pat. No. 3,795,731. which comprises: 30 Foreign Application Priority Data a heating the concentrated aqueous ammonium sulfate to a temperature of 900-1250°C in a Aug. 31, 197 Germany............................ 2143444 combustion chamber burning a carbon or sulfur containing fuel, in the presence of sufficient 52 U.S. Cl.............................. 423/541 A; 423/242 oxygen to maintain an oxygen content of 1-10 vol (5) Int. Cl..................... C01B 17160; C01B 17/50 % in the gas exiting from the combustion (58) Field of Search........... 423/522,539, 541, 542, chamber, to form a hot split gas consisting 4231544, 545, 547, 550, 242, 523 essentially of sulfur dioxide, sulfur trioxide, molecular nitrogen, molecular oxygen and water (56) References Cited vapor; and UNITED STATES PATENTS b. -
List of Lists
United States Office of Solid Waste EPA 550-B-10-001 Environmental Protection and Emergency Response May 2010 Agency www.epa.gov/emergencies LIST OF LISTS Consolidated List of Chemicals Subject to the Emergency Planning and Community Right- To-Know Act (EPCRA), Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and Section 112(r) of the Clean Air Act • EPCRA Section 302 Extremely Hazardous Substances • CERCLA Hazardous Substances • EPCRA Section 313 Toxic Chemicals • CAA 112(r) Regulated Chemicals For Accidental Release Prevention Office of Emergency Management This page intentionally left blank. TABLE OF CONTENTS Page Introduction................................................................................................................................................ i List of Lists – Conslidated List of Chemicals (by CAS #) Subject to the Emergency Planning and Community Right-to-Know Act (EPCRA), Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and Section 112(r) of the Clean Air Act ................................................. 1 Appendix A: Alphabetical Listing of Consolidated List ..................................................................... A-1 Appendix B: Radionuclides Listed Under CERCLA .......................................................................... B-1 Appendix C: RCRA Waste Streams and Unlisted Hazardous Wastes................................................ C-1 This page intentionally left blank. LIST OF LISTS Consolidated List of Chemicals -
A Personal History of the Benzidine Rearrangement
Bull. Hist. Chem. 19 (1996) 77 A PERSONAL HISTORY OF THE BENZIDINE REARRANGEMENT nr . Shn, x h Unvrt What I have to say today amounts more to a personal pounds) and which I had been studying with E. E. Turner account rather than an honest-to-goodness history of the at Bedford College in London during the years benzidine rearrangements. Interest in the mechanism of 1945-1947. My arrangement with Henry Gilman broke these rearrangements spans this century from the early up in the fall, 1948, and I became an independent re- 1900s to the present day. Prominent in studies of the search associate supported by the Department of Chem- rearrangements and their mechanisms during these istry. In return for that support, I became an instructor ninety years is the name of the man whose memory we of a quiz section in sophomore organic chemistry when honor today, C. K. Ingold, associated also with his the section's graduate-student instructor left Ames on long-time colleague and collaborator E. D. Hughes and short notice. During one of the quiz-section periods a their younger coworker Derek Banthorpe. Also promi- student asked how the benzidine rearrangement, men- nent in these studies are the names of Paul Jacobson, tioned only briefly in his book, occurred (Eq. 1) this Michael Dewar, Robert Carlin, Miroslav Vecera, and equation shows two products, as is correct. George Hammond and me. I don't know how or why Carlin and Vecera took up the benzidine rearrangements. Carlin, of course, was much interested in the Fischer indole reaction, and that is connected with benzidine rearrangements, as you know. -
Investigation of the Solar Hybrid Photo-Thermochemical Sulfur-Ammonia Water Splitting Cycle for Hydrogen Production Agni E
361 A publication of CHEMICAL ENGINEERING TRANSACTIONS The Italian Association VOL. 45, 2015 of Chemical Engineering www.aidic.it/cet Guest Editors: Petar Sabev Varbanov, Jiří Jaromír Klemeš, Sharifah Rafidah Wan Alwi, Jun Yow Yong, Xia Liu Copyright © 2015, AIDIC Servizi S.r.l., ISBN 978-88-95608-36-5; ISSN 2283-9216 DOI: 10.3303/CET1545061 Investigation of the Solar Hybrid Photo-Thermochemical Sulfur-Ammonia Water Splitting Cycle for Hydrogen Production Agni E. Kalyvaa, Ekaterini Ch. Vagiaa, Athanasios G. Konstandopoulosb, Arun R. Srinivasac, Ali T-Raissid, Nazim Muradovd, Konstantinos E. Kakosimos*,a aTexas A&M University at Qatar, Chemical Engineering Department, Sustainable Energy Research Laboratory (SERL), PO Box 23874, Doha, Qatar bChemical Process Engineering Research Institute, Aerosol and Particle Technology Laboratory (APTL), Center for Research and Technology-Hellas (CERTH/CPERI), P.O. Box 361, 57001 Thermi-Thessaloniki, Greece cTexas A&M University, Department of Mechanical Engineering, College Station, TX 77843-3123, USA dFlorida Solar Energy Center, University of Central Florida, Cocoa, FL 32922, USA [email protected] Hydrogen is currently being used in many industries, from chemical and refining to metallurgical, glass and electronics, while being at the same time a promising energy carrier. Therefore the need for hydrogen is experiencing a very rapid growth. At the same time, the traditional hydrogen production methods (e.g., steam methane reforming, water electrolysis) are energy and resources intensive. Thus, research focus is on sustainable technologies that can produce hydrogen in an economic and environmental friendly way. Hydrogen production via a solar driven hybrid sulfur-ammonia water splitting cycle (HySA) developed at Florida Solar Energy Center is such a promising technology. -
Thermodynamic Properties of Isoprene- and Monoterpene-Derived Organosulfates Estimated with Cosmotherm
Atmos. Chem. Phys., 20, 5679–5696, 2020 https://doi.org/10.5194/acp-20-5679-2020 © Author(s) 2020. This work is distributed under the Creative Commons Attribution 4.0 License. Thermodynamic properties of isoprene- and monoterpene-derived organosulfates estimated with COSMOtherm Noora Hyttinen1, Jonas Elm2, Jussi Malila1, Silvia M. Calderón1, and Nønne L. Prisle1 1Nano and Molecular Systems Research Unit, University of Oulu, P.O. Box 3000, 90014 Oulu, Finland 2Department of Chemistry and iClimate, Aarhus University, Langelandsgade 140, 8000 Aarhus C, Denmark Correspondence: Noora Hyttinen (noora.hyttinen@oulu.fi), and Nønne L. Prisle (nonne.prisle@oulu.fi) Received: 25 November 2019 – Discussion started: 17 December 2019 Revised: 9 April 2020 – Accepted: 10 April 2020 – Published: 13 May 2020 Abstract. Organosulfates make significant contributions 1 Introduction to atmospheric secondary organic aerosol (SOA), but lit- tle is known about the thermodynamic properties of at- mospherically relevant organosulfates. We have used the Organosulfates (R−OSO3H, OS) have been identified as COSMOtherm program to calculate both the gas- and components of atmospheric secondary organic aerosol condensed-phase properties of previously identified at- (SOA) from a variety of environments (Surratt et al., 2007; mospherically relevant monoterpene- and isoprene-derived Glasius et al., 2018a,b). In the Amazon, the contribution organosulfates. Properties include solubilities, activities and of organic sulfate was found to be 3 %–42 % of the total saturation vapor pressures, which are critical to the aerosol- aerosol sulfate for the compounds measured using aerosol phase stability and atmospheric impact of organosulfate mass spectrometry (Glasius et al., 2018a). In Atlanta, Geor- SOA. Based on the estimated saturation vapor pressures, the gia, organosulfates accounted for 16.5 % of the total organic organosulfates of this study can all be categorized as semi- carbon of fine particulate matter (PM2:5)(Hettiyadura et al., volatile or low-volatile, with saturation vapor pressures 4 2019). -
Membrane Separation of Ammonium Bisulfate from Ammonium Sulfate in Aqueous Solutions for CO2 Mineralisation
Article Membrane Separation of Ammonium Bisulfate from Ammonium Sulfate in Aqueous Solutions for CO2 Mineralisation Evelina Koivisto and Ron Zevenhoven * Thermal and Flow Engineering Laboratory, Åbo Akademi University, Piispankatu 8, 20500 Turku, Finland; [email protected] * Correspondence: [email protected]; Tel.: +358-2-215-3223 Received: 24 February 2018; Accepted: 2 April 2018; Published: 4 April 2018 Abstract: The separation of ammonium bisulfate (ABS) from ammonium sulfate (AS) in aqueous solutions by monovalent ion selective membranes was studied. Optimised usage of these chemicals is both an important and challenging step towards a more efficient CO2 mineralisation process route developed at Åbo Akademi University (ÅA). The membranes were placed in a three or five- compartment electrodialysis stack. Silver, stainless steel and platinum electrodes were tested, of which a combination of Pt (anode) and stainless steel (cathode) electrodes were found to be most suitable. Separation efficiencies close to 100% were reached based on ABS concentrations in the feed solution. The tests were performed with an initial voltage of either 10 V–20 V, but limitations in the electrical power supply equipment eventually resulted in a voltage drop as separation proceeded. Exergy calculations for energy efficiency assessment show that the input exergy (electrical power) is many times higher than the reversible mixing exergy, which indicates that design modifications must be made. Further work will focus on the possibilities to make the separation even more efficient and to develop the analysis methods, besides the use of another anode material. Keywords: ammonium (bi)sulfate; CCS; CO2 mineralisation; electrodialysis; ion selective membranes 1. Introduction CO2 mineralisation is one method to sequester CO2, especially at locations where underground storage is impossible or where the market potential of the solid products is recognised. -
Chemical Capabilities Listing Laboratory, R&D, Industrial and Manufacturing Applications
Page 1 of 3 Chemical Capabilities Listing Laboratory, R&D, Industrial and Manufacturing Applications Acacia, Gum Arabic Barium Oxide Chromium Trioxide Acetaldehyde Bentonite, White Citric Acid, Anhydrous Acetamide Benzaldehyde Citric Acid, Monohydrate Acetanilide Benzoic Acid Cobalt Oxide Acetic Acid Benzoyl Chloride Cobaltous Acetate Acetic Anhydride Benzyl Alcohol Cobaltous Carbonate Acetone Bismuth Chloride Cobaltous Chloride Acetonitrile Bismuth Nitrate Cobaltous Nitrate Acetyl Chloride Bismuth Trioxide Cobaltous Sulfate Aluminium Ammonium Sulfate Boric Acid Cottonseed Oil Aluminon Boric Anhydride Cupferron Aluminum Chloride, Anhydrous Brucine Sulfate Cupric Acetate Aluminum Chloride, Hexahydrate n-Butyl Acetate Cupric Bromide Aluminum Fluoride n-Butyl Alcohol Cupric Carbonate, Basic Aluminum Hydroxide tert-Butyl Alcohol Cupric Chloride Aluminum Nitrate Butyric Acid Cupric Nitrate Aluminum Oxide Cadmium Acetate Cupric Oxide Aluminum Potassium Sulfate Cadmium Carbonate Cupric Sulfate, Anhydrous Aluminum Sulfate Cadmium Chloride, Anhydrous Cupric Sulfate, Pentahydrate 1-Amino-2-Naphthol-4-Sulfonic Acid Cadmium Chloride, Hemipentahydrate Cuprous Chloride Ammonium Acetate Cadmium Iodide Cuprous Oxide, Red Ammonium Bicarbonate Cadmium Nitrate Cyclohexane Ammonium Bifluoride Cadmium Oxide Cyclohexanol Ammonium Bisulfate Cadmium Sulfate, Anhydrous Cyclohexanone Ammonium Bromide Cadmium Sulfate, Hydrate Devarda's Alloy Ammonium Carbonate Calcium Acetate Dextrose, Anhydrous Ammonium Chloride Calcium Carbide Diacetone Alcohol Ammonium Citrate -
Please Click Here for Chemical Resistance Information Specific To
Technical Service Report No. 15 - Page 1 of 12 Chemical Resistance of Rigid Geon® Vinyls Based on Immersion Test One of the most important properties of PVC material is its exceptional Table 3 gives an indication of the variety of chemicals and mixtures inertness. Rigid Geon® vinyl compounds are part of this group and that appear in commercially available paint removers, solvents, drain they offer excellent resistance to a broad range of reagents and cleaners, spot removers, etc., that are used by the public. This mixtures that are corrosive to many other materials. Their resistance investigation was done to see what effect these products might have to oxidation and moisture make rigid Geon® vinyls useful in outdoor on ASTM D 2665 1½in. Sch. 40 PVC pipe, traps and solvent cement applications and even in the Chemical Processing Industry. joints under stress. Each assembly consisted of a short inlet pipe, a trap with three solvent cement joints plus an 18 in. long outlet pipe. Three generalizations concerning the environmental stability of rigid The assemblies were held in place by clamping the inlet pipe in a PVC can be drawn from these immersion tests. First of all, PVC is vertical position with the trap and outlet pipe cantilevered from it. generally inert to most mineral acids, bases, salts and paraffinic hydrocarbon solutions. Secondly, PVC is not recommended for use To simulate use conditions, each trap was filled with water and then with chlorinated or aromatic hydrocarbons, esters or ketones. Finally, the chemical was poured in until it flowed from the outlet.