Deconvolution of Spectral Voigt Profiles Using Inverse Methods And
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Modern Quantum Kinetic Theory and Spectral Line Shapes
LOUIS MONCHICK MODERN QUANTUM KINETIC THEORY AND SPECTRAL LINE SHAPES The modern quantum kinetic theory of spectral line hapes i outlined and a typical calculation of a Ra man scattered line hape described. The distingui hing feature of thi calculation i that it was completely ab initio and therefore con tituted a test of modern quantum kinetic theor ,the tate of the art in computing molecular-scattering cross sections, and novel method of olving kinetic equation. The computation em ployed a large assortment of tools: group theory finite-element method. cIa ic method of solving cou pled sets of ordinary differential equations, graph method of combining angular momenta, and matrix methods of solving integral equations. Agreement with experimental re ult wa excellent. THE PROBLEM Almo t with the inception of quantum mechanics, parison. 1 the a ailability of an extremely good model of theorists-mostly nuclear and atomic physici t -had the interaction of helium ith two deuterium atoms, and developed the general scattering equations neces ary to the feasibilit of carrying out the calculation in a finite describe collision between fundamental particles. With time and at a rea onable co t. The goal which we did not almost no exception, however, only a few angular quite reach. a an entirely ab initio computation con momentum and spin states were invol ed; as a re ult, taining a umption only about the rate of convergence these calculations were not computationally intensive. In of the numerical procedure u ed, ith no e peri mental principle, the general methodology was applicable to the quantitie except Planck' and Boltzmann' con tant calculation of molecular inela tic and reactive colli ion, and the electronic charg and mas of the electron, deuter which are important ingredients of reaction rates. -
Pulse Shaping and Ultrashort Laser Pulse Filamentation for Applications in Extreme Nonlinear Optics Antonio Lotti
Pulse shaping and ultrashort laser pulse filamentation for applications in extreme nonlinear optics Antonio Lotti To cite this version: Antonio Lotti. Pulse shaping and ultrashort laser pulse filamentation for applications in extreme nonlinear optics. Optics [physics.optics]. Ecole Polytechnique X, 2012. English. pastel-00665670 HAL Id: pastel-00665670 https://pastel.archives-ouvertes.fr/pastel-00665670 Submitted on 2 Feb 2012 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. UNIVERSITA` DEGLI STUDI DELL’INSUBRIA ECOLE´ POLYTECHNIQUE THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF PHILOSOPHIÆ DOCTOR IN PHYSICS Pulse shaping and ultrashort laser pulse filamentation for applications in extreme nonlinear optics. Antonio Lotti Date of defense: February 1, 2012 Examining committee: ∗ Advisor Daniele FACCIO Assistant Prof. at University of Insubria Advisor Arnaud COUAIRON Senior Researcher at CNRS Reviewer John DUDLEY Prof. at University of Franche-Comte´ Reviewer Danilo GIULIETTI Prof. at University of Pisa President Antonello DE MARTINO Senior Researcher at CNRS Paolo DI TRAPANI Associate Prof. at University of Insubria Alberto PAROLA Prof. at University of Insubria Luca TARTARA Assistant Prof. at University of Pavia ∗ current position: Reader in Physics at Heriot-Watt University, Edinburgh Abstract English abstract This thesis deals with numerical studies of the properties and applications of spatio-temporally coupled pulses, conical wavepackets and laser filaments, in strongly nonlinear processes, such as harmonic generation and pulse reshap- ing. -
Stark Broadening Measurements in Plasmas Produced by Laser Ablation of Hydrogen Containing Compounds Miloš Burger, Jorg Hermann
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Archive Ouverte en Sciences de l'Information et de la Communication Stark broadening measurements in plasmas produced by laser ablation of hydrogen containing compounds Miloš Burger, Jorg Hermann To cite this version: Miloš Burger, Jorg Hermann. Stark broadening measurements in plasmas produced by laser ablation of hydrogen containing compounds. Spectrochimica Acta Part B: Atomic Spectroscopy, Elsevier, 2016, 122, pp.118-126. 10.1016/j.sab.2016.06.005. hal-02348424 HAL Id: hal-02348424 https://hal.archives-ouvertes.fr/hal-02348424 Submitted on 5 Nov 2019 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Stark broadening measurements in plasmas produced by laser ablation of hydrogen containing compounds Milosˇ Burgera,∗,Jorg¨ Hermannb aUniversity of Belgrade, Faculty of Physics, POB 44, 11000 Belgrade, Serbia bLP3, CNRS - Aix-Marseille University, 13008 Marseille, France Abstract We present a method for the measurement of Stark broadening parameters of atomic and ionic spectral lines based on laser ablation of hydrogen containing compounds. Therefore, plume emission spectra, recorded with an echelle spectrometer coupled to a gated detector, were compared to the spectral radiance of a plasma in local thermal equi- librium. -
Frequency Generation (HD 2D SFG) Spectroscopy
Adding a dimension to the infrared spectra of interfaces using heterodyne detected 2D sum- frequency generation (HD 2D SFG) spectroscopy Wei Xiong, Jennifer E. Laaser, Randy D. Mehlenbacher , and Martin T. Zanni1 Department of Chemistry, University of Wisconsin-Madison, Madison, WI 53706 Edited by Michael L. Klein, Temple University, Philadelphia, PA, and approved October 13, 2011 (received for review September 13, 2011) In the last ten years, two-dimensional infrared spectroscopy has of carbon monoxide on polycrystalline platinum. Pt-CO is studied become an important technique for studying molecular structures extensively to better understand electrochemical catalysis (13– and dynamics. We report the implementation of heterodyne de- 16). The linear SFG spectrum of Pt-CO has been measured many tected two-dimensional sum-frequency generation (HD 2D SFG) times previously. The spectrum is almost always fit to a Lorent- spectroscopy, which is the analog of 2D infrared (2D IR) spectro- zian line shape (14–16), from which one concludes that Pt-CO is scopy, but is selective to noncentrosymmetric systems such as vibrationally narrowed, meaning that the structural dynamics interfaces. We implement the technique using mid-IR pulse shap- of the CO and its surrounding environment are so fast that the ing, which enables rapid scanning, phase cycling, and automatic system is homogeneous. By resolving the 2D line shape of Pt-CO, phasing. Absorptive spectra are obtained, that have the highest we find that there is a significant inhomogeneous contribution, frequency resolution possible, from which we extract the rephas- which indicates that there is a slow component to the vibrational ing and nonrephasing signals that are sometimes preferred. -
Development of an Ultrasensitive Cavity Ring Down Spectrometer in the 2.10-2.35 Μm Region : Application to Water Vapor and Carbon Dioxide Semen Vasilchenko
Development of an ultrasensitive cavity ring down spectrometer in the 2.10-2.35 µm region : application to water vapor and carbon dioxide Semen Vasilchenko To cite this version: Semen Vasilchenko. Development of an ultrasensitive cavity ring down spectrometer in the 2.10- 2.35 µm region : application to water vapor and carbon dioxide. Instrumentation and Detectors [physics.ins-det]. Université Grenoble Alpes, 2017. English. NNT : 2017GREAY037. tel-01704680 HAL Id: tel-01704680 https://tel.archives-ouvertes.fr/tel-01704680 Submitted on 8 Feb 2018 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. THÈSE Pour obtenir le grade de DOCTEUR DE LA COMMUNAUTE UNIVERSITE GRENOBLE ALPES Spécialité : Physique de la Matière Condensée et du Rayonnement Arrêté ministériel : 25 mai 2016 Présentée par Semen VASILCHENKO Thèse dirigée par Didier MONDELAIN codirigée par Alain CAMPARGUE préparée au sein du Laboratoire Interdisciplinaire de Physique dans l'École Doctorale Physique Development of an ultrasensitive cavity ring down spectrometer in the 2.10-2.35 µm region. -
Field Guide to Continuous Probability Distributions
Field Guide to Continuous Probability Distributions Gavin E. Crooks v 1.0.0 2019 G. E. Crooks – Field Guide to Probability Distributions v 1.0.0 Copyright © 2010-2019 Gavin E. Crooks ISBN: 978-1-7339381-0-5 http://threeplusone.com/fieldguide Berkeley Institute for Theoretical Sciences (BITS) typeset on 2019-04-10 with XeTeX version 0.99999 fonts: Trump Mediaeval (text), Euler (math) 271828182845904 2 G. E. Crooks – Field Guide to Probability Distributions Preface: The search for GUD A common problem is that of describing the probability distribution of a single, continuous variable. A few distributions, such as the normal and exponential, were discovered in the 1800’s or earlier. But about a century ago the great statistician, Karl Pearson, realized that the known probabil- ity distributions were not sufficient to handle all of the phenomena then under investigation, and set out to create new distributions with useful properties. During the 20th century this process continued with abandon and a vast menagerie of distinct mathematical forms were discovered and invented, investigated, analyzed, rediscovered and renamed, all for the purpose of de- scribing the probability of some interesting variable. There are hundreds of named distributions and synonyms in current usage. The apparent diver- sity is unending and disorienting. Fortunately, the situation is less confused than it might at first appear. Most common, continuous, univariate, unimodal distributions can be orga- nized into a small number of distinct families, which are all special cases of a single Grand Unified Distribution. This compendium details these hun- dred or so simple distributions, their properties and their interrelations. -
Detection of Voigt Spectral Line Profiles of Hydrogen Radio
Detection of Voigt Spectral Line Profiles of Hydrogen Radio Recombination Lines toward Sagittarius B2(N) Azrael A. von Proch´azka1,2, Anthony J.Remijan3,4, Dana S. Balser3, Robert S. I. Ryans1, Adele H. Marshall5 Fredric R.Schwab3, Jan M. Hollis6, Philip R. Jewell3,4, and Frank J. Lovas4,7 ABSTRACT We report the detection of Voigt spectral line profiles of radio recombination lines (RRLs) toward Sagittarius B2(N) with the 100-m Green Bank Telescope (GBT). At radio wavelengths, astronomical spectra are highly populated with RRLs, which serve as ideal probes of the phys- ical conditions in molecular cloud complexes. An analysis of the Hnα lines presented herein shows that RRLs of higher principal quantum number (n > 90) are generally divergent from their expected Gaussian profiles and, moreover, are well described by their respective Voigt profiles. This is in agreement with the theory that spectral lines experience pressure broadening as a result of electron collisions at lower radio frequencies. Given the inherent technical dif- ficulties regarding the detection and profiling of true RRL wing spans and shapes, it is crucial that the observing instrumentation produce flat baselines as well as high sensitivity, high reso- lution data. The GBT has demonstrated its capabilities regarding all of these aspects, and we believe that future observations of RRL emission via the GBT will be crucial towards advancing our knowledge of the larger-scale extended structures of ionized gas in the interstellar medium (ISM). Subject headings: ISM: H II regions — ISM: radio continuum — ISM: radio recombination lines — radiation mechanisms: nonthermal — radiation mechanisms: pressure broadening — line: profiles 1. -
Article Is Available DA8 Spectrometer, J
Atmos. Meas. Tech., 12, 35–50, 2019 https://doi.org/10.5194/amt-12-35-2019 © Author(s) 2019. This work is distributed under the Creative Commons Attribution 4.0 License. Using a speed-dependent Voigt line shape to retrieve O2 from Total Carbon Column Observing Network solar spectra to improve measurements of XCO2 Joseph Mendonca1, Kimberly Strong1, Debra Wunch1, Geoffrey C. Toon2, David A. Long3, Joseph T. Hodges3, Vincent T. Sironneau3, and Jonathan E. Franklin4 1Department of Physics, University of Toronto, Toronto, ON, Canada 2Jet Propulsion Laboratory, Pasadena, CA, USA 3National Institute of Standards and Technology, Gaithersburg, MD, USA 4Harvard John A. Paulson School of Engineering and Applied Sciences, Cambridge, MA, USA Correspondence: Joseph Mendonca ([email protected]) Received: 23 February 2018 – Discussion started: 3 April 2018 Revised: 23 August 2018 – Accepted: 17 September 2018 – Published: 3 January 2019 Abstract. High-resolution, laboratory, absorption spectra of infrared CO2 and O2 spectra to improve the accuracy of 1 3 − the a 1g X 6g oxygen (O2) band measured using cav- XCO2 measurements. ity ring-down spectroscopy were fitted using the Voigt and speed-dependent Voigt line shapes. We found that the speed- dependent Voigt line shape was better able to model the mea- sured absorption coefficients than the Voigt line shape. We 1 Introduction used these line shape models to calculate absorption coeffi- cients to retrieve atmospheric total columns abundances of Accurate remote sensing of greenhouse gases (GHGs) such O2 from ground-based spectra from four Fourier transform as CO2, in the Earth’s atmosphere is important for study- spectrometers that are a part of the Total Carbon Column Ob- ing the carbon cycle to better understand and predict cli- serving Network (TCCON). -
And H 2 -Broadened Line Parameters of Carbon Monoxide in the First
Room Temperature Self- and H 2 -Broadened Line Parameters of Carbon Monoxide in the First Overtone Band: Theoretical and Revised Experimental Results Koorosh Esteki, Adriana Predoi-Cross, Chad Povey, Sergey Ivanov, Aziz Ghoufi, Franck Thibault, Mary Ann H. Smith To cite this version: Koorosh Esteki, Adriana Predoi-Cross, Chad Povey, Sergey Ivanov, Aziz Ghoufi, et al.. Room Tem- perature Self- and H 2 -Broadened Line Parameters of Carbon Monoxide in the First Overtone Band: Theoretical and Revised Experimental Results. Journal of Quantitative Spectroscopy and Radiative Transfer, Elsevier, 2017, 203, pp.309-324. 10.1016/j.jqsrt.2017.04.008. hal-01533342 HAL Id: hal-01533342 https://hal.archives-ouvertes.fr/hal-01533342 Submitted on 7 Jun 2018 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Room Temperature Self- and H2-Broadened Line Parameters of Carbon Monoxide in the First Overtone Band: Theoretical and Revised Experimental Results 1,2 1* 1 3 4 Koorosh Esteki , Adriana Predoi-Cross , Chad Povey , Sergey Ivanov , Aziz Ghoufi , 5 Franck Thibault4, Mary Ann H. Smith 1 Department of Physics and Astronomy, University of Lethbridge, Lethbridge, AB, Canada 2 Present address: Mechanical and Manufacturing Engineering, Schulich School of Engineering, University of Calgary, Calgary, AB, Canada 3 Federal Scientific Research Centre “Crystallography and Photonics” of Russian Academy of Sciences (FSRC “Crystallography and Photonics” RAS), Leninsky pr. -
Title of Thesis Or Dissertation, Worded Exactly As It
PRESSURE BROADENING AND PRESSURE SHIFT OF DIATOMIC IODINE AT 675 NM by ERICH N. WOLF A DISSERTATION Presented to the Department of Chemistry and the Graduate School of the University of Oregon in partial fulfillment of the requirements for the degree of Doctor of Philosophy June 2009 ii “Pressure Broadening and Pressure Shift of Diatomic Iodine at 675 nm,” a dissertation prepared by Erich N. Wolf in partial fulfillment of the requirements for the Doctor of Philosophy degree in the Department of Chemistry. This dissertation has been approved and accepted by: ____________________________________________________________ Dr. David Herrick, Chair of the Examining Committee ________________________________________ Date Committee in Charge: Dr. David R. Herrick, Chair Dr. John L. Hardwick Dr. Michael G. Raymer Dr. Jeffrey A. Cina Dr. David R. Tyler Accepted by: ____________________________________________________________ Dean of the Graduate School Erich N. Wolf / Pressure Broadening and Pressure Shift of I2 at 675 nm / June 2009 iii An Abstract of the Dissertation of Erich N. Wolf for the degree of Doctor of Philosophy in the Department of Chemistry to be taken June 2009 Title: PRESSURE BROADENING AND PRESSURE SHIFT OF DIATOMIC IODINE AT 675 NM Approved: _______________________________________________ Dr. David Herrick, Chair of the Examining Committee 127 Doppler-limited, steady-state, linear absorption spectra of I2 (diatomic iodine) near 675 nm were recorded with an internally-referenced wavelength modulation spectrometer, built around a free-running diode laser using phase-sensitive detection, and capable of exceeding the signal-to-noise limit imposed by the 12-bit data acquisition system. Observed I2 lines were accounted for by published spectroscopic constants. -
Integro-Differential Equations to Model Generalized Voigt Profiles
1 Integro-differential equations to model generalized Voigt profiles: a fractional diffusion approach Gianni Pagnini, Francesco Mainardi CRS4, Polaris Bldg. 1, I-09010 Pula (CA), Italy E-mail: [email protected] Department of Physics, University of Bologna, and INFN, via Irnerio 46, I-40126 Bologna, Italy E-mail: [email protected] URL: www.fracalmo.org Summary. In molecular spectroscopy and atmospheric radiative transfer, the combined effects of Doppler and pressure broadenings lead to the Voigt profile function, which turns out to be the convo- lution of the Gaussian (due to the Doppler broadening) and the Lorentzian (due to the pressure broad- ening) distributions. Here we are interested to study the Voigt profile function when the widths are not constant but depending on a scale-factor with a power law. Since in probability theory the Gaussian and the Lorentzian distributions are known to belong to the class of symmetric L´evy stable distributions, in this framework we propose to generalize the Voigt function by adopting the convolution of two arbitrary symmetric L´evy distributions. Moreover, we provide the integro-differential equations with respect to the scale-factor satisfied by the generalized Voigt profiles. These evolution equations can be interpreted as space-fractional diffusion equations of double order. Key words: Voigt profile function, L´evy stable distributions, integro-differential equations, Riesz space-fractional derivative, Mellin-Barnes integrals 2 Gianni Pagnini, Francesco Mainardi 1 Introduction In the present paper some mathematical aspects of the Voigt profile are discussed. This func- tion emerges as a profile spectrum in molecular spectroscopy and atmospheric radiative trans- fer due to the combined effects of Doppler and pressure broadeningsand it turns out to be the convolution of the Gaussian (due to the Doppler broadening) and the Lorentzian (due to the pressure broadening) probability densities. -
Detecting Damped Ly&Thinsp;Α Absorbers with Gaussian Processes
MNRAS 472, 1850–1865 (2017) doi:10.1093/mnras/stx1958 Advance Access publication 2017 August 2 Detecting damped Ly α absorbers with Gaussian processes Roman Garnett,1‹ Shirley Ho,2 Simeon Bird3 and Jeff Schneider4 1Department of Computer Science and Engineering, Washington University in St Louis, One Brookings Drive, St Louis, MO 63130, USA 2Department of Physics, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213, USA 3Department of Physics & Astronomy, Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD 21218, USA 4School of Computer Science, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213, USA Accepted 2017 July 28. Received 2017 July 28; in original form 2016 November 19 ABSTRACT We develop an automated technique for detecting damped Ly α absorbers (DLAs) along spectroscopic lines of sight to quasi-stellar objects (QSOs or quasars). The detection of DLAs in large-scale spectroscopic surveys such as SDSS III sheds light on galaxy formation at high redshift, showing the nucleation of galaxies from diffuse gas. We use nearly 50 000 QSO spectra to learn a novel tailored Gaussian process model for quasar emission spectra, which we apply to the DLA detection problem via Bayesian model selection. We propose models for identifying an arbitrary number of DLAs along a given line of sight. We demonstrate our method’s effectiveness using a large-scale validation experiment, with excellent performance. We also provide a catalogue of our results applied to 162 858 spectra from SDSS-III data release 12. Key words: methods: statistical – intergalactic medium – quasars: absorption lines – galaxies: statistics. had some success in detecting large DLA catalogues, their reliance 1 INTRODUCTION entirely on templates made them subject to hard-to-quantify sys- The damped Ly α systems (DLAs; Wolfe et al.