Crystallography Reports, Vol. 50, Suppl. 1, 2005, pp. S1–S9. Original Russian Text Copyright © 2005 by Tauson, Sapozhnikov. STRUCTURE OF INORGANIC COMPOUNDS Stability of the Modulated Structure of BaÏkal Lazurite and Its Recrystallization at a Temperature of 600°C over a Wide Range of Sulfur Dioxide Fugacities V. L. Tauson and A. N. Sapozhnikov Vinogradov Institute of Geochemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1a, Irkutsk, 664033 Russia e-mail:
[email protected] Received February 8, 2005 Abstract—The stability of three-dimensional incommensurate modulation in cubic lazurite from the BaÏkal region is experimentally investigated at T = 600°C. It is found that the X-ray photoelectron spectra of the annealed samples exhibit a peak corresponding to sulfite and a split peak associated with the (Na,Ca)SO4 sul- fate. It is assumed that the splitting is caused by the ordering of the complexes not involved in the framework. This assumption is confirmed by the presence of a similar split peak in the X-ray photoelectron spectra of tri- clinic lazurite. It is demonstrated that the initial modulation is retained at the fugacity f = 8 × 10–3 bar. The SO2 decisive factors responsible for the retention of the three-dimensional incommensurate modulation are the tem- perature and the fugacity of sulfur dioxide. The latter quantity should be close to the stability boundary of the basic lazurite structure. The growth and transformation mechanisms of the modulation formation are consid- ered. © 2005 Pleiades Publishing, Inc. INTRODUCTION mum concentrations of sulfide sulfur and potassium are typical of the monoclinic modification.