Diverse Bonding Activations in the Reactivity of a Pentaphenylborole Toward Sodium Phosphaethynolate : Heterocycle Synthesis and Mechanistic Studies
This document is downloaded from DR‑NTU (https://dr.ntu.edu.sg) Nanyang Technological University, Singapore. Diverse bonding activations in the reactivity of a pentaphenylborole toward sodium phosphaethynolate : heterocycle synthesis and mechanistic studies Li, Yan; Siwatch, Rahul Kumar; Mondal, Totan; Li, Yongxin; Ganguly, Rakesh; Koley, Debasis; So, Cheuk‑Wai 2017 Li, Y., Siwatch, R. K., Mondal, T., Li, Y., Ganguly, R., Koley, D., & So, C.‑W. (2017). Diverse bonding activations in the reactivity of a pentaphenylborole toward sodium phosphaethynolate : heterocycle synthesis and mechanistic studies. Inorganic chemistry, 56(7), 4112–4120. doi:10.1021/acs.inorgchem.7b00128 https://hdl.handle.net/10356/139442 https://doi.org/10.1021/acs.inorgchem.7b00128 This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.7b00128 Downloaded on 28 Sep 2021 11:54:28 SGT Diverse Bonding Activations in the Reactivity of a Pentaphenylborole toward Sodium Phosphaethynolate: Heterocycle Synthesis and Mechanistic Studies Yan Li,a Rahul Kumar Siwatch,a Totan Mondal,b Yongxin Li,a Rakesh Ganguly,a Debasis Koley*band Cheuk-Wai So*a aDivision of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371 Singapore bDepartment of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur 741 246, India ABSTRACT The reaction of the pentaphenylborole [(PhC)4BPh] (1) with sodium phosphaethynolate·1,4- dioxane (NaOCP(1,4-dioxane)1.7) afforded the novel sodium salt of phosphaboraheterocycle 2.
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