Safety Data Sheet Index Binder: Maple Highway Shop - Maple Highway Shop

Product Name CAS Number Manufacturer Version Date Page

#1 Diesel Sinclair Oil Company 01/23/2015 4

#275 Di-Lex Hydraulic Oil SAE 20 Schaeffer Mfg. Company 04/30/2004 12

+22 Degree F Splash Windshield Washer Fluid Splash Products, Inc. 01/06/2012 14

Aeroshell Grease Shell Oil Company 09/22/2003 19

AJAX CLEANER POWDER-OXYGEN BLEACH Colgate-Palmolive Co - Commerical 05/14/2015 24 Consumer Group

Castle Dry Lub Castle Products, Inc. 09/19/2013 34

Castle Thrust Castle Products, Inc. 06/14/2013 37

CITRA CLEAN HAND CLEANER WITH Mark V Products 12/31/2005 40 PUMICE

Citra-Blaze 535 Cleaner Degreaser Nyco Products Company 12/17/2012 42

DIESEL FUEL SUPPLEMENT +CETANE Power Service Products, Inc. 05/30/2015 44 BOOST

DUST MOP / DUST CLOTH TREATMENT Spartan Chemical Company, Inc. 05/01/2015 57 (AEROSOL)

Eagle One ETCHING MAG WHEEL CLEANER Ashland 09/17/2012 62

Eagle One WAX-AS-U-DRY SPRAY WAX Ashland 06/22/2013 76

FARM AND INDUSTRIAL NEW EQUIPMENT SEYMOUR OF SYCAMORE 01/02/2007 87 YELLOW

FAST ORANGE SMOOTH LOTION WITH ITW Permatex 05/15/2015 91 BRUSH 15 FL.OZ

GERMICIDAL CLEANER Claire Manufacturing Company 03/23/2015 98

GLEME GLASS CLEANER Claire Manufacturing Company 05/26/2015 107

GS RESTROOM CLEANER Spartan Chemical Company, Inc. 05/04/2015 117

Hi-lex Bleah HI-LEX CORP 04/05/1999 122

HOSPECO HEALTH GARDS AIR HOSPECO 03/21/2013 123 FRESHENER VINEYARD, 7OZ

Hot Shot Natural Flying Insect Killer CHEMSICO DIV OF UNITED 03/11/2015 125 INDUSTRIES CORP

Industrial Gloss Enamel ARROWHEAD PAINT 10/01/2007 131 PRODUCTS, INC. Product Name CAS Number Manufacturer Version Date Page

Insect Repellent CRC Industries, Inc. 05/21/2015 134

Ivory Original Liquid Hand Soap Procter & Gamble 02/18/2015 144

Kiwi Select All Protector Rain and Stain Sara Lee Household and Body 06/09/2003 150 Protector Care USA

KRYLON Industrial QUIK-MARK Solvent-Based THE SHERWIN-WILLIAMS 05/04/2015 154 Inverted Marking Paint (Fluorescent), Red COMPANY - KRYLON Orange INDUSTRIAL PRODUCTS GROUP

No-Ad SPF 50 Sport Sunblock Lotion Sun & Skin Care Research 07/09/2012 160

OFF! DEEP WOODS INSECT REPELLENT VII S.C. Johnson & Son, Inc. 02/24/2015 162

Orange Away Total Solutions 01/08/2015 174

PARTS MASTER PREMIUM POWER OMNI Specialty Packaging 01/31/2012 175 STEERING FLUID

PEAK BLUE 13463-67-7 Standridge Color Corporation 08/03/2012 181

POLAR WINDSHIELD WASH & DEICER FLUID Old World Industries, LLC 10/29/2014 186 -30 Degree F

PRIME SOURCE SILKY PINK HAND SOAP PRIME SOURCE 04/27/2015 196

Propane 74-98-6 BERNZ-O-MATIC 06/11/2011 208

RAID WASP & HORNET KILLER 33 S.C. Johnson & Son, Inc. 02/23/2015 211

TC Gel Air Neutralizers - All Fragrances Listed Technical Concepts 02/15/2005 225

TWINKLE METAL POLISH & FIBERGLASS JohnsonDiversey 04/19/2000 228 CLEANER

UNITED 166 POWER UP United Laboratories Inc. 03/05/2008 232

UNITED 195 SMELL JEL United Laboratories Inc. 12/22/2012 234

UNITED 77 BIATRON United Laboratories Inc. 02/08/2013 236

Unleaded Gasoline - All Grades Silver Eagle Refining, Inc. 05/18/2015 238

White Lithium Grease (aerosol) CRC Industries, Inc. 06/09/2015 253

Xtreme Gleme All Weather Surface Degreaser Claire Manufacturing Company 10/03/2012 260

Page 2 of 262 Safety Data Sheet #1 Diesel

SECTION 1 IDENTIFICATION

Product Name: #1 Diesel

SDS #: F3.2

Product Use: Fuel Restrictions on Use: Use only as directed

Manufacturer: Sinclair Oil Company P.O. Box 30825 Salt Lake City, Utah 84130

Telephone: General Information: (801) 524-2777 Fax: (801) 524-2740 Contact person: Jeremiah Webster

Emergency Telephone: 800-424-9300 (CHEMTREC) or (703) 527-3887

SDS Date of Preparation: January 23, 2015

SECTION 2: HAZARDS IDENTIFICATION

Classification:

Physical Health Flammable Liquid Category 3 Aspiration Toxicity Category 1 Skin Irritation Category 2 Specific Target Organ Toxicity Single Exposure Category 3 (Nervous System) Carcinogen Category 1A Germ Cell Mutagenicity Category 1B

Label Elements: Danger!

Hazard Phrases: Combustible Liquid. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. May cause cancer. May cause genetic defects.

Precautionary Phrases: Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood

Page 3 of 262 Jet A Fuel January 23, 2015

Keep away from heat, sparks, open flames, and hot surfaces. No smoking. Keep container tightly closed. Ground and bond container and receiving equipment Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing vapors, mists or spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves, skin protection and eye protection.

Response IF SWALLOWED: Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash it before reuse. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF exposed or concerned: Get medical attention. In case of fire: Use water fog, carbon dioxide, dry chemical and foam to extinguish.

Storage and Disposal Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents and container in accordance with local and national regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Chemical name CAS No. Concentration

Kerosene 8008-30-6 95-100% Hydrocarbons C7-C9 68920-06-9 0-15% Naphthalene 91-20-3 0-3% Benzene 71-43-2 0-0.2%

SECTION 4 EMERGENCY and FIRST AID PROCEDURES

Eye Contact: Immediately flush eyes with water for several minutes. Get medical attention if irritation persists.

Skin Contact: Remove contaminated clothing and flush skin with water for several minutes. Wash thoroughly with soap and water. Get medical attention if irritation develops or persists. Launder clothing before reuse. Discard contaminated shoes.

Inhalation: Remove to fresh air. If breathing is difficult have qualified personnel administer oxygen. If breathing has stopped, administer artificial respiration. Get medical attention.

Ingestion: Do not induce vomiting. Rinse mouth with water. Never give anything by mouth to an unconsciousness person. If vomiting occurs spontaneously, keep head below hips to prevent aspiration into the lungs. Get immediate medical attention.

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Page 4 of 262 Jet A Fuel January 23, 2015

Most important symptoms/effects, acute and delayed: May cause eye irritation. Causes skin irritation with redness and drying. Inhalation may cause respiratory irritation and central nervous system effects. Harmful or fatal if swallowed. Aspiration during swallowing or vomiting may cause lung damage. May cause cancer. May cause genetic defects.

Indication of immediate medical attention and special treatment, if necessary: Immediate medical attention is required for ingestion.

SECTION 5 FIRE and EXPLOSION HAZARD DATA

Suitable extinguishing media: Use water fog, alcohol foam, carbon dioxide, or dry chemical. Do not use a steady stream of water. Product may float on the surface of water and create a floating fire hazard. Specific hazards arising from the chemical: This product is flammable and forms explosive mixtures with air. Vapors are heavier than air and will travel along surfaces to remote ignition sources and flash back. Closed containers may explode if exposed to extreme heat. Combustion may produce carbon oxides and other products of incomplete combustion. Special protective equipment and precautions for fire-fighters: Firefighters should wear full emergency equipment and a NIOSH approved positive pressure self-contained breathing apparatus. Cool fire exposed container with water. Do not allow run-off from firefighting to enter drains or water courses.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures: Wear appropriate protective equipment. Eliminate ignitions sources and ventilate the area with explosion proof equipment. Wash thoroughly after handling. Environmental hazards: Avoid release into the environment. Report spill as required by local and federal regulations. Methods and materials for containment and cleaning up: Contain with an inert absorbent and place into a closable container for disposal. Use non-sparking tools and equipment. If spill has not ignited, use water spray to disperse the vapors and protect personnel attempting to stop leak. Prevent entry in storm sewers and waterways. Runoff can cause a fire or explosion hazard in sewers.

SECTION 7 HANDLING and STORAGE

Precautions for safe handling: Avoid contact with the eyes, skin and clothing. Avoid breathing vapors or mists. Wear protective clothing and equipment. Use only with adequate ventilation. Wash thoroughly with soap and water after handling. Keep containers closed when not in use. Keep product away from heat, sparks, flames and all other sources of ignition. Do not permit smoking in use or storage areas. Use with non-sparking tools and explosion proof equipment. Electrically bond and ground containers for transfer.

Do not cut, drill, grind or weld on or near containers, even empty containers. Do not reuse containers. Empty containers retain product residues which can be hazardous. Follow all SDS precautions when handling empty containers.

Refer to OSHA 1910.1028 for requirements for handling and use of benzene.

Conditions for safe storage, including any incompatibilities: Store in accordance with regulations for the storage of flammable liquids. Store in a dry, well ventilated area away from heat, direct sunlight and all sources of ignition. Store away from oxidizers and other incompatible materials. Protect containers from physical damage.

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Page 5 of 262 Jet A Fuel January 23, 2015

SECTION 8 EXPOSURE CONTROLS and PERSONAL PROTECTION

Exposure Guidelines:

INGREDIENTS EXPOSURE LIMITS Kerosene 200 mg/m3, skin TWA ACGIH TLV Hydrocarbons C7-C9 None Established Benzene 1 ppm TWA, 5 ppm STEL OSHA PEL 0.5 ppm TWA, 2.5 ppm STEL ACGIH TLV Naphthalene 10 ppm TWA OSHA PEL 10 ppm, skin TWA ACGIH TLV

29 CFR 1910.1028 is the OSHA regulation on Occupational Exposure to Benzene. Assure compliance with these regulations.

Appropriate engineering controls: Use with local exhaust ventilation to maintain exposures below the occupational exposure limits. Use explosion proof equipment where required

Respiratory protection: If exposures are exceeded, use a NIOSH approved organic vapor respirator appropriate for the form and concentration of the contaminants should be used. Selection of respiratory protection depends on the contaminant type, form and concentration. Select in accordance with OSHA 1910.134 and good Industrial Hygiene practice. Skin protection: Impervious gloves such as nitrile recommended to prevent skin contact. Eye protection: Wear chemical safety goggles to avoid eye contact. Other: Impervious coveralls, apron and boots is required to prevent skin contact and contamination of personal clothing. A safety shower and eye wash should be available in the immediate work area.

SECTION 9 PHYSICAL and CHEMICAL PROPERTIES

Appearance (physical state, color, etc.): Pale yellow Odor: Aromatic hydrocarbon odor.

Odor threshold: Not available pH: Not applicable Melting point/Pourpoint: Not available Boiling Point: Not available Flash point: 141.1°F (60.6°C) PMCC Evaporation rate: Not available Flammability (solid, gas): Not applicable Flammable limits: LEL: 0.6% UEL: 5% Vapor pressure: <1 mmHg Vapor density: <1 Relative density: Not available Solubility: Not available Partition coefficient: n-ctanol/water: Not available Auto-ignition temperature: >410°F (>210°C) Decomposition temperature: Not available Viscosity: 1.3-2.4 @ 104°F

SECTION 10 STABILITY and REACTIVITY

Reactivity: This product is not expected to be reactive. Chemical stability: The product is stable. Possibility of hazardous reactions: None known. Conditions to avoid: Keep away from heat and all sources of ignition. Incompatible materials: Avoid oxidizing agents. Hazardous decomposition products: Thermal decomposition may yield carbon oxides and other products of incomplete combustion.

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Page 6 of 262 Jet A Fuel January 23, 2015

SECTION 11 TOXICOLOGICAL INFORMATION

Health Hazards:

Inhalation: Vapors may cause respiratory irritation and central nervous system effect including headache, dizziness, headaches, giddiness, euphoria, vertigo, blurred vision, nausea, numbness, drowsiness, anesthesia, and coma. . Overexposure to benzene by inhalation may cause exhilaration, nervous excitation, and/or giddiness, followed by a period of depression, drowsiness, or fatigue, tightness of the chest, unconsciousness, tremors or death.

Skin Contact: Skin contact may cause irritation, redness and defatting of the skin.

Eye Contact: Eye contact may cause mild irritation with redness, tearing and pain.

Ingestion: Swallowing may cause gastrointestinal irritation, nausea, vomiting, diarrhea, vertigo, drowsiness, mental confusion, staggering gait, slurred speech, convulsions, unconsciousness and death due to circulatory failure. Aspiration during swallowing or vomiting may cause lung damage.

Chronic Effects of Overexposure: Prolonged occupational overexposure may cause dermatitis. Reports have associated repeated and prolonged overexposure to petroleum distillates with adverse liver, kidney and bone marrow effects and with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the product may be harmful or fatal. Repetitive direct skin application of kerosene over a two year period resulted in skin cancer in laboratory animals. Petroleum hydrocarbons of similar composition and boiling ranges have been known to product kidney damage and tumors in male rats following prolonged inhalation exposures. Benzene has been shown to cause damage to the blood forming system with anemia, leukopenia and thrombocytopenia by all routes of exposure.

Mutagenicity: Benzene did not induce in vitro mutation in bacteria using standard AMES test conditions. Mammalian cell gene mutation tests carried out in various human, mouse and Chinese hamster cells resulted in mixed results. Benzene is an in vivo mutagen in mammals, especially when chromosomal aberrations and micronuclei are induced. It has been reported that benzene exposure in humans induces genotoxic effects in lymphocytes in vivo.

Reproductive Toxicity: In a reproductive study, rats were administered 250 and 1000 mg/kg of petroleum distillates for at least 70 days prior to mating and during the 14 day mating cycle. The absence of adverse effects on in-life parameters (such as body weight, feed consumption, and clinical observations), a dosage level of 1000 mg/kg/day was considered to be the no-observed-adverse-effect level (NOAEL) for reproductive and systemic toxicity.

Carcinogenicity: Kerosene is listed as a “Confirmed Animal Carcinogen with Unknown Relevance to Humans: A3 by ACGIH. Benzene is listed by IARC as “Carcinogenic to Humans” Group 1, by NTP as “Known to Be a Human Carcinogen” and as a “Confirmed Human Carcinogen”, A1 by ACGIH. Naphthalene is listed by IARC as “Possibly Carcinogenic to Humans”, Group 2B, as “Reasonably Anticipated to be a Human Carcinogen” and as a “Confirmed Animal Carcinogen with Unknown Relevance to Humans”, A3 by ACGIH.

Acute Toxicity Values: Kerosene: Oral rat LD50 >5000 mg/kg, Inhalation rat LC50 >5.28 mg/L/4 hr, Dermal rabbit LD50 >2000 mg/kg Hydrocarbons C7-C9: >5000 mg/kg, Inhalation rat LC50 >5.28 mg/L/4 hr, Dermal rabbit LD50 >2000 mg/kg (structurally similar chemical) Benzene: Oral rat LD50 >2000 mg/kg, Inhalation rat LC50 41690 mg/m3/ 4 hr, Dermal rabbit LD50 > 8260 mg/kg Naphthalene: Oral rat LD50 533 mg/kg, Inhalation rat LC0 0.4 mg/L (highest attainable concentration), Dermal rat LC50 >2500 mg/kg

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Page 7 of 262 Jet A Fuel January 23, 2015

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity: Kerosene: 96 hr LL50 Oncorhynchus mykiss 2.5 mg/kg, 48 hr EL50 1.4 mg/L, 72 hr EL50 Pseudokirchnerella subcapitata 1.3 mg/L Hydrocarbons C7-C9: 96 hr LL50 Oncorhynchus mykiss 2.5 mg/kg, 48 hr EL50 1.4 mg/L, 72 hr EL50 Pseudokirchnerella subcapitata 1.3 mg/L (structurally similar chemical) Benzene: 96 hr LC50 Oncorhynchus mykiss 5.3 mg/L, 48 hr EC50 daphnia magna 10 mg/L, 72 hr EC50 Pseudokirchnerella subcapitata 32 mg/L Naphthalene: 96 hr LC50 Pimephales promelas 6.08 mg/L, 48 hr EC50 daphnia magna 2.16 mg/L

Persistence and degradability: Kerosene is inherently biodegradable. Bioaccumulative potential: The BCF for kerosene is 70-5000 which suggest the potential for bioconcentration is moderate to high. Mobility in soil: Some components of kerosene will display low mobility and some will be essentially immobile in soil. Other adverse effects: This product is classified as toxic to the aquatic environment with long-term adverse effects. Releases to the environment should be avoided.

SECTION 13: DISPOSAL INFORMATION

Waste Disposal Method: Dispose in accordance with all local, state and federal regulations.

SECTION 14: TRANSPORTATION INFORMATION

UN Number Proper shipping name Hazard Packing Environmental Class Group Hazard DOT UN1223 Kerosene 3 PG III No TDG UN1223 Kerosene 3 PG III No IMDG UN1223 Kerosene 3 PG III No IATA UN1223 Kerosene 3 PG III No

Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code): Not applicable.

Special precautions: None known.

SECTION 15: REGULATORY INFORMATION

Safety, health, and environmental regulations specific for the product in question.

CERCLA Hazardous Substances (Section 103)/RQ: This product has a Reportable Quantity (RQ) of 3,333 lbs. (based on the RQ for Naphthalene of 100 lbs). Releases above the RQ must be reported to the National Response Center. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations.

EPA SARA 311 Hazard Classification: Acute Health, Chronic Health, Fire Hazard

SARA 313: This product contains the following chemicals subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372):

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Page 8 of 262 Jet A Fuel January 23, 2015

Benzene 71-43-2 0-0.5% Naphthalene 91-20-3 0-3%

CALIFORNIA PROPOSITION 65: This product contains the following chemicals known to the State of California to cause cancer or reproductive toxicity.

Benzene 71-43-2 0-0.5% Cancer, developmental, male reproductive toxicity Naphthalene 91-20-3 0-3% Cancer

WHMIS CLASSIFICATION: Class B, Division 3 (Combustible Liquid), Class D, Division 2A (Very Toxic Material Causing Other Toxic Effects)

This product has been classified in accordance with the hazard criteria in the CPR and the MSDS contains all the information required by the CPR.

Australia AICS: All of the components are listed on the Australian Inventory of Chemical Substances.

Canada DSL: All of the components are listed on the Canadian Domestic Substances List.

China: All the components are listed on Inventory of Existing Chemical Substances in China.

European EINECS: All of the ingredients are listed on the EINECS inventory.

New Zealand: All the components are listed on the New Zealand Inventory of Chemicals.

Philippines: All the components are listed on the Philippine Inventory of Chemical and Chemical Substances inventory.

US EPA Toxic Substances Control Act: All of the components of this product are listed on the TSCA inventory.

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Page 9 of 262 MATERIAL SAFETY DATA SHEET

MATERIAL IDENTITY: +22° F Splash Windshield Washer Fluid

SECTION 1 – PRODUCT IDENTIFICATION & COMPANY INFORMATION

Manufacturer: SPLASH PRODUCTS, INC. Telephone: (651) 489-8211 51 East Maryland Avenue St. Paul, MN 55117-4615 Facsimile: (651) 489-8247

Transportation Emergency for immediate information about a chemical or to seek assistance from a manufacturer: 1-800-535-5053

Date Updated: January 6, 2012

SECTION 2 - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION

Hazardous Approximate OSHA NIOSH REL ACGIH Threshold IDLH Component* Composition Permissible Limit Value (NIOSH) Exposure Limit** Methanol (Methyl Alcohol) <8 percent 200 ppm (260 200 ppm (260 200 ppm (260 mg/m3) 6,000 ppm 3 3 -CAS 67-56-1 by weight mg/m ) 8-Hour mg/m ) 8-Hour 8-Hour TWA (0.6 percent -UN 1230 TWA (Skin) TWA in air) (DOT Guide 28) 250 ppm (310 mg/m3) 250 ppm (310 Short-term Exposure mg/m3) Ceiling Limit (15-minute TWA) (Skin) (Skin)

HMIS: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0 SPECIAL: NONE

RATING SCALE: 0=MINIMAL 1=SLIGHT 2=MODERATE 3=SERIOUS 4=SEVERE

SECTION 3 – HAZARDOUS IDENTIFICATION

The hazardous component listed is not a known or suspected human carcinogen as listed or determined by the National Agency for Research on Cancer, National Toxicological Program “NTP Seventh Annual Report on Carcinogens,” or International Agency for Research on Cancer (IARC) monograph reviews. In addition, it is not considered a carcinogen by the Occupational Safety and Health Administration or the National Institute for Occupational Safety and Health.

Can cause eye and skin irritation. HARMFUL IF SWALLOWED. DANGER POISON. FLAMMABLE. CANNOT BE MADE NONPOISONOUS. Irritation to respiratory track.

INGESTION: Can cause blindness.

INHALATION: May cause headaches, dizziness, nausea, incoordination, drowsiness, visual impairment and unconsciousness

EYE CONTACT: Irritating to eyes; may cause severe and permanent damage.

SKIN CONTACT: Prolonged or repeated contact without rinsing with water may cause irritation.

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Page 11 of 262

MATERIAL SAFETY DATA SHEET

MATERIAL IDENTITY: +22° F Splash Windshield Washer Fluid

SECTION 4 – FIRST AID MEASURES

INGESTION: Do not give liquid if victim is unconscious or drowsy. Otherwise, give 1 or 2 glasses of water. Call doctor, hospital emergency room or poison control center for instructions to induce vomiting. When medical advice is not available, induce vomiting using syrup of ipecac according to direction. If ipecac not available, induce vomiting with finger or back of spoon by touching the back of the victim’s throat. Get medical attention.

INHALATION: If exposed to excessive levels of vapors. Remove to fresh air.

EYE CONTACT: Immediately flush eye with plenty of cool, running water. Remove contact lenses if applicable, and continue flushing for at least 15 minutes, holding eyelids apart to ensure thorough rinsing of the entire eye. Speed is essential to minimize injury. Call a physician immediately.

SKIN CONTACT: immediately flush skin with plenty of cool running water for at least 15 minutes. Wash with soap and water. If irritation develops or persists, get medical attention. Remove contaminated clothing and shoes; wash before reuse.

SECTION 5 – FIRE FIGHTING MEASURES

FLASH POINT: 130°F

FLAMMABLE LIMITS: In air % by volume, LEL: 6% UEL: 36%

EXTINGUISHING MEDIA: Use of dry chemical, carbon dioxide, water spray, alcohol foam.

SPECIAL FIRE FIGHTING PROCEDURES: Use fog or spray to prevent flooding. Be prepared to use MSHA-NIOSH self contained breathing apparatus and protecting clothing.

FIRE AND EXPLOSION HAZARDS: Treat as flammable liquid. There is a chance of moderate explosion and/or dangerous fire hazard.

SECTION 6 – ACCIDENTAL RELEASE MEASURES

RESPONSE TO SPILLS: Eliminate all sources of ignition immediately. Mop up residue and rinse area thoroughly with water. Contain run-off with absorbent material such as sand or clay and diking. Transfer liquid and absorbent material in approved container. Flush and mop area with water allowing to air dry. Keep spill out of sewers and open bodies of water.

SECTION 7 – HANDLING AND STORAGE

HANDLING PRECAUTIONS: Follow directions on label. Wash after handling and before eating.

STORAGE PRECAUTIONS: Store container upright. Tighten cap securely. Avoid heat, sparks, and flames. Protect container from physical damage. KEEP AWAY FROM CHILDREN

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Page 12 of 262 MATERIAL SAFETY DATA SHEET

MATERIAL IDENTITY: +22° F Splash Windshield Washer Fluid

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION

HYGIENIC PRACTICES: Avoid breathing vapors. Use with adequate ventilation. Wash thoroughly with soap and water after handling. Follow direction on label. Do not store near food stuffs, water or feed.

SKIN PROTECTION: Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure.

EYE PROTECTION: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Clear blue liquid BOILING POINT: 200°F

ODOR: Mild alcohol odor FREEZE POINT: +22°F pH: 8.2 VAPOR PRESSURE (mm of Hg): 97 @20C (68F)

SPECIFIC GRAVITY: (water =1): .986 @60°F VAPOR DENSITY (Air =1): 1.1

SOLUBILITY IN WATER: 100% EVAPORATION RATE (BuAc=1): 5.9

SECTION 10 – STABILITY AND REACTIVITY

CONDITIONS TO AVOID: HEAT, SPARKS, FLAMES. No smoking when using.

INCOMPATIBILITY: Strong oxidizing agents such as nitrates and sulfuric acid.

HAZARDOUS DECOMPOSITION PRODUCTS: Burning can product carbon monoxide and /or carbon dioxide. Carbon monoxide is highly toxic if inhaled. Carbon dioxide in sufficient concentration can act as an asphyziant.

HAZARDOUS POLYMERIZATION: will not occur.

SECTION 11 – TOXICOLOGICAL INFORMATION

CARCINOGENICITY: This product does not contain any known or anticipated carcinogens according to the criteria of the NPT annual report on carcinogens and OSHA 29 CFR 1910, Z.

Methyl Alcohol (Methanol): Oral rat LD50: 5628 mg/kg: inhalation rat LC50: 64000 ppm/4H: skin rabbit LD50: 15800 mg/kg; irritation data-standard Draize test: skin, rabbit: 20mg/24hr. Moderate; eye, rabbit: 100mg/24hr. Moderate. Investigated as a mutagen, reproductive effector.

METHYL ALCOHOL (67-56-1) CARCINOGEN: Known: No. Anticipated: No.

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MATERIAL SAFETY DATA SHEET

MATERIAL IDENTITY: +22° F Splash Windshield Washer Fluid

SECTION 12 – ECOLOGICAL INFORMATION

ENVIRONMENTAL: When released into the soil, this material is expected to readily biodegrade. When released into the soil, this material is expected to leach into groundwater. When released into the soil, this material is expected to quickly evaporate. When released into water, this material is expected to have a half-life between 1 and 10 days. When released into water, this material is expected to readily biodegrade. When released into the air, this material is expected to exist in the aerosol phase with a short half-life. When released into the air, this material is expected to readily degraded by reaction with photo chemically produced hydroxyl radicals. When released into air, this material is expected to have a half-life between 10 and 30 days. When released into the air, this material is expected to be readily removed from the atmosphere by wet deposition.

ENVIRONMENTAL TOXICITY: This material is expected to be slightly toxic to aquatic life.

SECTION 13 – DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: Dispose in accordance with federal, state and local regulations.

SECTION 14 – TRANSPORT INFORMATION

(U.S. D.O.T.) – U.S. Department of Transportation: PROPER SHIPPING NAME: Consumer Commodity ORM-D Exceptions: Per 49 CFR 173.150 (pg III, inner package not over 5.0 L)

SECTION 15 – REGULATORY INFORMATION

THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS:

CHEMICAL NAME CAS NUMBER Methanol 67-56-1

U.S.FEDERAL REGULATIONS TSCA (Toxic Substance Control Act) Status – TSCA (UNITED STATES)

CERCLA RQ – 40 CFR 3.2.1 (a)

Component RQ (lbs) Methyl Alcohol 5,000

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MATERIAL SAFETY DATA SHEET

MATERIAL IDENTITY: +22° F Splash Windshield Washer Fluid

SARA 302 Components – 40 CFR 355 Appendix A None

Section 311/312 Hazard Class – 40CFR 370.2 Immediate (X) Delayed (X) Fire (X) Reactive () Sudden Release of Pressure ()

SARA 313 Components - 40 CFR 372.65 Section 313 Components(s) CAS Number % Methanol 67-56-1 <8

INTERNATIONAL REGULATIONS

Inventory Status – DSL (CANADA) The international ingredients of this are listed. WHMIS Information: B2, D1A

ECL (SOUTH KOREA) The international ingredients of this product are listed.

EINECS (EUROPE) The international ingredients of this product are listed.

ENCS (JAPAN) The international ingredients of this product are listed.

State and Local Regulations – California Proposition 65

New Jersey RTK (Right-To-Know) Label information Methyl Alcohol 67-56-1

Pennsylvania RTK (Right-To-Know) Label information Methanol 67-56-1

Atmospheric Standards: The Clean Air Act Amendments of 1990 list methanol as a hazardous air pollutant.

SECTION 16 – OTHER INFORMATION

Information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The condition or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product.

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AJAX CLEANER POWDER-OXYGEN BLEACH This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000222 Revision Date: 05/14/2015

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : AJAX CLEANER POWDER-OXYGEN BLEACH

Product code : 200000017621

: B01809190000

Manufacturer or supplier's details Company : Colgate-Palmolive Co Commerical Consumer Group 191 East Hanover Avenue Morristown, NJ 07960-3151

Telephone : US: Consumer Affairs - 1-800-468-6502

Emergency telephone : For emergencies involving spill, leak, fire, exposure or acci- number dent call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887.

Medical Emergency For MEDICAL EMERGENCIES involving this product call: (24HR): (888) 489-3861 Recommended use of the chemical and restrictions on use Recommended use : A formulated multi-purpose cleaner

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview Appearance powder

Colour off-white

GHS Classification Acute toxicity (Inhalation) : Category 4

GHS Label element Hazard pictograms :

Signal word : Warning

Hazard statements : H332 Harmful if inhaled.

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Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P271 Use only outdoors or in a well-ventilated area. Response: P304 + P340 + P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell.

Potential Health Effects Inhalation : May be harmful if inhaled.

Skin : May cause skin irritation upon prolonged contact.

Eyes : Causes eye irritation on direct contact.

Ingestion : May be harmful if swallowed in large quantities.

Aggravated Medical Condi- : None known. tion

Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.

OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components Chemical Name CAS-No. Concentration (%) LIMESTONE 1317-65-3 >= 90 - <= 100 SODIUM CARBONATE 497-19-8 >= 5 - < 10

SECTION 4. FIRST AID MEASURES

If inhaled : Remove victim to fresh air. Get medical attention, if symptoms persist.

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In case of skin contact : Flush skin with large amounts of water. If irritation develops and persists, get medical attention.

In case of eye contact : Flush eyes with water at least 15 minutes. Get medical attention if eye irritation develops or persists.

If swallowed : Drink 8 ounces of clear water. Get medical attention.

Most important symptoms : Harmful if inhaled. and effects, both acute and delayed

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Hazardous combustion prod- : No hazardous combustion products are known ucts

Special protective equipment : Self-contained breathing apparatus and full protective clothing for firefighters should be worn when fighting chemical fires.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protection recommended in Section 8 of the tive equipment and emer- SDS. gency procedures

Methods and materials for : Cover with inert, absorbent material and remove to disposal containment and cleaning up container. Spill area may be slippery. Flush with plenty of water.

SECTION 7. HANDLING AND STORAGE

Conditions for safe storage : Store at controlled room temperature at 20-25°C (68-77°F).

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters Components CAS-No. Value type Control parame- Basis (Form of ters / Permissible exposure) concentration LIMESTONE 1317-65-3 TWA (Res- 5 mg/m3 NIOSH REL pirable) TWA (total) 10 mg/m3 NIOSH REL TWA (Res- 5 mg/m3 NIOSH REL pirable)

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TWA (total) 10 mg/m3 NIOSH REL TWA (total 15 mg/m3 OSHA Z-1 dust) TWA (respir- 5 mg/m3 OSHA Z-1 able fraction) TWA (Total 15 mg/m3 OSHA P0 dust) TWA (respir- 5 mg/m3 OSHA P0 able dust fraction) Engineering measures : In an industrial work environment, no special precautions or control measures are required.

Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection.

Protective measures : In an industrial work environment, if a splash is likely, chemical goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary.

Hygiene measures : In an industrial work environment, avoid eye and prolonged skin contact.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : powder

Colour : off-white

pH : 10.4

Flash point : No data available

Density : 1.04 g/cm3

SECTION 10. STABILITY AND REACTIVITY

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Possibility of hazardous reac- : Hazardous polymerisation does not occur. tions

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : None known. products

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity Harmful if inhaled. Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method

Acute inhalation toxicity : Acute toxicity estimate : 1.63 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method

Components: LIMESTONE: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 420

Acute inhalation toxicity : LC50 (Rabbit): > 3 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403

Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402

SODIUM CARBONATE: Acute oral toxicity : LD50 (Rat): 2,800 mg/kg

Acute inhalation toxicity : LC50 (Rabbit): 2.3 mg/l Exposure time: 2 h Test atmosphere: No information available. Method: No information available.

Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Method: No information available.

Skin corrosion/irritation Not classified based on available information. Components: LIMESTONE:

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Result: No skin irritation

SODIUM CARBONATE: Remarks: No data available

Serious eye damage/eye irritation Not classified based on available information. Components: LIMESTONE: Result: No eye irritation

SODIUM CARBONATE: Result: Irritation to eyes, reversing within 21 days

Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Components: LIMESTONE: Exposure routes: Inhalation Result: Does not cause respiratory sensitisation.

Exposure routes: Dermal Result: Does not cause skin sensitisation.

SODIUM CARBONATE: Exposure routes: Inhalation Remarks: No data available

Exposure routes: Dermal Remarks: No data available

Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information.

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Further information

Product: Remarks: This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the SDS.

SECTION 12. ECOLOGICAL INFORMATION

The product has not been tested as a whole for environmental toxicity. However, environmental information on the ingredients in this product have been reviewed by the Environmental, Health and Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This evaluation is based on available information on individual ingredients, interactions of ingredients, and similar ingredients. Biodegradability claims are supported by data on ingredients (i.e., surfactants are biodegradable) or testing conducted on the final product (i.e., This product is biodegradable).

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods Waste from residues : Any disposal practice must be in compliance with local, state and federal laws and regulations (contact local or state environment agency for specific rules). Do not dump in sewers, any body of water or on the ground.

SECTION 14. TRANSPORT INFORMATION

DOT : Not regulated.

TDG : Not regulated.

IATA : Not regulated.

IMDG : Not regulated.

International Regulation

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations

SECTION 15. REGULATORY INFORMATION

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OSHA Hazards : Combustible dust, Moderate skin irritant, Severe eye irritant

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity Components CAS-No. Component RQ Calculated product RQ (lbs) (lbs) SODIUM DODECYL BENZENE 25155-30-0 1000 * SULFONATE *: Calculated RQ exceeds reasonably attainable upper limit.

SARA 304 Extremely Hazardous Substances Reportable Quantity Components CAS-No. Component RQ Calculated product RQ (lbs) (lbs) SULFUR DIOXIDE 7446-09-5 500 * *: Calculated RQ exceeds reasonably attainable upper limit.

SARA 311/312 Hazards : Acute Health Hazard

SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta- ble 116.4A: SODIUM DODECYL 25155-30-0 BENZENE SULFONATE Sulfuric Acid SULFURIC ACID The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: SODIUM DODECYL 25155-30-0 BENZENE SULFONATE Sulfuric Acid SULFURIC ACID This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 Massachusetts Right To Know

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LIMESTONE 1317-65-3 SODIUM DODECYL BENZENE 25155-30-0 SULFONATE Sulfuric Acid SULFURIC ACID SULFUR DIOXIDE 7446-09-5 Pennsylvania Right To Know LIMESTONE 1317-65-3 SODIUM CARBONATE 497-19-8 SODIUM DODECYL BENZENE 25155-30-0 SULFONATE Sulfuric Acid SULFURIC ACID SULFUR DIOXIDE 7446-09-5 SODIUM SULFATE 7757-82-6 New Jersey Right To Know LIMESTONE 1317-65-3 SODIUM CARBONATE 497-19-8 SODIUM DODECYL BENZENE 25155-30-0 SULFONATE

California Prop 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA : All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory.

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)

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SECTION 16. OTHER INFORMATION

Further information

NFPA: HMIS III: Flammability

HEALTH 2 0 Instability

2 0 FLAMMABILITY 0 Health

PHYSICAL HAZARD 0

0 = not significant, 1 =Slight, Special hazard. 2 = Moderate, 3 = High 4 = Extreme, * = Chronic

Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or implied, as to the accuracy, reliability or completeness of the information and assumes no responsibility for injury, damage or loss resulting from the use of the material.

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Page 30 of 262

SAFETY DATA SHEET

SECTION 1 PRODUCT and COMPANY INFORMATION TRADE NAME: Castle® Dry Lub™ PRODUCT TYPE: Dry Lubricant Coating PRODUCT CODE: C2015 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 800-876-0222 • FAX 585-325-4514 EMERGENCY 585-275-3232

SECTION 2 HAZARD IDENTIFICATION

EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant POTENTIAL HEALTH EFFECTS: Eyes: Irritating to eyes. Skin: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation: Irritating to respiratory system. Avoid breathing vapors or mists. Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Potential for aspiration if swallowed.

SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Acetone 67-64-1 1000ppm 750ppm 750ppm 15-40% Toluene 108-88-3 200ppm 20ppm 150ppm 15-40% Propane/Isobutane/N-Butane 68476-86-8 NE NE NE 10-30% Isopropyl Alcohol 67-63-0 400ppm NE 400ppm 5-10% Molybdenum Disulfide 1317-33-5 15 mg/m3(dust) 10 mg/m3 NE 1-5%

SECTION 4 FIRST AID MEASURES First Aid Procedures: Eye contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician if irritation persists. Skin contact: For skin contact flush with large amounts of water. Call a physician if irritation persists. Inhalation: Immediately remove from further exposure. Give supplemental oxygen, if breathing is difficult. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by mouth to an unconscious person.

Note to physician: No information available.

SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: ≥ -141°F (≥-96°C) LOWER EXPLOSIVE LIMIT: ND UPPER EXPLOSIVE LIMIT: ND EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear.

SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area. Keep unnecessary personnel away. Stay upwind. Keep out of low areas. Ventilate spaces before entering. Environmental precautions: Prevent further leakage or spillage if safe to do so. Methods for containment: Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up: Eliminate ignition sources including sources of electrical, static or frictional sparks. Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal.

Dry Lub Product Code: C2015 Page 1 of 3

Page 31 of 262 Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA.

SECTION 7 HANDLING AND STORAGE Handling: Product is extremely flammable. Do not store near ignition sources. Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers tightly closed. Store in a cool, dry place.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established.

Engineering controls: Use local exhaust ventilation. Personal protective equipment: Gloves: Not normally required. Eye/Face Protection: Eye protection not normally required but recommended. Skin Protection: Wear clothing suited to the task being performed. Respiratory Protection: Not normally required if good ventilation is maintained.

SECTION 9 PHYSICAL and CHEMICAL PROPERTIES

BOILING POINT: ND SPECIFIC GRAVITY (H2O=1): ND VAPOR PRESSURE: ND PERCENT VOLATILE BY VOL %: 64.5% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): ND SOLUBILITY IN WATER: ND APPEARANCE & ODOR: Black Powder / Solvent pH: NA

SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. Strong bases. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Sulfur Oxides. HAZARDOUS POLYMERIZATION: Does not occur.

SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: Acetone: Oral LD50 (rat) 5800 mg/kg Toluene: Oral LD50 (rat) 636 mg/kg; Dermal LD50 (rabbit) 8390 mg/kg; Inhalation LC50 (rat) 12.5 mg/L (4h) ISopropanol: Oral LD50 (rat) 4396 mg/kg; Dermal LD50 (rabbit) 12870 mg/kg; Inhalation LC50 (rat) 72.6 mg/L (4h)

Not classified to be a carcinogen to humans.

SECTION 12 ECOLOGICAL INFORMATION Component Test Results: None reported.

SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Dispose according to all applicable Federal, State, and Local regulations.

SECTION 14 TRANSPORT INFORMATION DOT Ground: Consumer Commodity ORM-D, or Limited Quantity.

SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations.

CERCLA (Superfund) reportable quantity: None

SARA (Superfund Amendments and Reauthorization Act of 1986): 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

Section 302 extremely hazardous substance: No

Dry Lub Product Code: C2015 Page 2 of 3

Page 32 of 262 Section 311/312 hazardous chemical: Acute Health Hazard: Yes; Chronic Health Hazard: Yes; Fire Hazard: Yes; Sudden Release of Pressure Hazard: No; Reactive Hazard: No..

Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR.

SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.)

HMIS® ratings Health: 2 Flammability: 4 Physical hazard: 2 NFPA ratings Health: 2 Flammability: 4 Instability: 0

Other: NA-Not Applicable, ND-Not Determined, NE-Not Established.

Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantability or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions.

PREPARED: 11/29/93 UPDATED: 9/19/2013 PRODUCT #: C2015

Dry Lub Product Code: C2015 Page 3 of 3

Page 33 of 262

SAFETY DATA SHEET

SECTION 1 PRODUCT and COMPANY INFORMATION ® TRADE NAME: Castle Thrust™ PRODUCT TYPE: Penetrating Oil PRODUCT CODE: C2005 MANUFACTURED FOR: Castle Products, Inc. 424 St. Paul Street Rochester, NY 14605 800-876-0222 • FAX 585-325-4514 EMERGENCY 585-275-3232

SECTION 2 HAZARD IDENTIFICATION

EMERGENCY OVERVIEW: DANGER: Gases Under Pressure, Flammable, Irritant

POTENTIAL HEALTH EFFECTS: Eyes: May cause irritation. Skin: May cause irritation. Prolonged exposure may cause fatting dermatitis. Inhalation: May cause irritation. Propellant is a simple asphyxiant. Ingestion: May cause headache, nausea, vomiting, and weakness. Effects of chronic exposure: Lifetime skin painting tests indicate that materials of similar composition as kerosene may have produced skin cancer in experimental animals. The relationship of these results to humans has not been fully established.

SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENTS CAS # PEL TLV STEL % Petroleum Oil Blend (Mixture) 64742-52-5 5 mg/m3 NE NE 30-60% Kerosene (Petroleum) 8008-20-6 5 ppm NE NE 10-30% Propane 74-98-6 1000 ppm NE NE 7-15% Isobutane 75-28-5 1000 ppm NE NE 5-10% Ethyl acetate 141-78-6 400 ppm NE NE 1-5%

Note to physician: If the product is ingested, treat the affected person symptomatically.

SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: 25°F (-4°C) LOWER EXPLOSIVE LIMIT: 2.0% UPPER EXPLOSIVE LIMIT: 10.7% [Propellant: ≥-141°F (≥-96°C)] EXTINGUISHING MEDIA: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Appropriate for surrounding fire. UNUSUAL FIRE & EXPLOSION HAZARDS: None SPECIAL FIRE FIGHTING PROCEDURES: Water from fogging nozzles may be used to cool closed containers to prevent pressure build-up if exposed to extreme temperatures. As in any fire, wear pressure-demand self-contained breathing apparatus, MSHA/NIOSH (approved or equivalent) and full protective gear.

Thrust Product Code: C2005 Page 1 of 3

Page 34 of 262 Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for disposal. Large Spills: Dike far ahead of liquid spill for disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA.

SECTION 7 HANDLING AND STORAGE Handling: Avoid breathing mist. Avoid contact with skin and eyes. Wear suitable protective clothing. Wash hands after handling. Storage: Keep from freezing. Keep containers tightly closed. Store in a cool, dry place.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits: None Established.

Engineering controls: Use local exhaust ventilation. Personal protective equipment: General: Eye wash fountain and emergency showers are recommended. Eye/face Protection: Wear safety glasses or goggles. Skin Protection: Wear suitable protective clothing. Wear chemical resistant gloves. Respiratory Protection: When respiratory protection is required, wear a NIOSH/MSHA approved self-contained breathing apparatus with full facepiece operated in a positive-pressure mode.

SECTION 9 PHYSICAL and CHEMICAL PROPERTIES

BOILING POINT: 168°F (76°C) SPECIFIC GRAVITY (H2O=1): 0.88-0.89 (liquid) 0.75-0.79 (aerosol) VAPOR PRESSURE: 55-65 PERCENT VOLATILE BY VOL %: >95% VAPOR DENSITY (air=1) >1 EVAPORATION RATE (Butyl Acetate=1): <1 SOLUBILITY IN WATER: Negligible APPEARANCE & ODOR: Dark amber liquid / characteristic pH: NA

SECTION 10 STABILITY and REACTIVITY DATA STABILITY: Stable under normal conditions. INCOMPATIBILITY (material to avoid): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide, Hydrocarbon fumes and smoke where combustion is incomplete. HAZARDOUS POLYMERIZATION: Will not occur

SECTION 11 TOXICOLOGICAL INFORMATION Components Test Results: No information available.

Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

SECTION 12 ECOLOGICAL INFORMATION Component Test Results: No information available.

SECTION 13 DISPOSAL CONSIDERATIONS Disposal instructions: Do not puncture or incinerate containers, even when empty. Dispose according to all applicable Federal, State, and Local regulations.

SECTION 14 TRANSPORT INFORMATION D.O.T. Classification: Consumer Commodity, ORM-D T.D.G. Classification: Consumer Commodity (Aerosols, UN1950, Class 2.1)

SECTION 15 REGULATORY INFORMATION US federal regulations: All components are listed in the United States TSCA Regulations.

CERCLA (Superfund) reportable quantity: None

Thrust Product Code: C2005 Page 2 of 3

Page 35 of 262 Section 302 extremely hazardous substance: No Section 311 hazardous chemical: No

Canada: This Product has been classified according to the hazard criteria of the CPR and the SDS contains all of the information required by the CPR.

SECTION 16 OTHER INFORMATION Further information: (HMIS® is a registered trade and service mark of the NPCA.)

HMIS® ratings Health: 2 Flammability: 4 Physical hazard: 0

NFPA Code 30B: Level 3

Other: NA-Not Applicable, ND-Not Determined, NE-Not Established.

PREPARED: 9/25/96 UPDATED: 6/14/13 PRODUCT #: C2005

Thrust Product Code: C2005 Page 3 of 3

Page 36 of 262 MATERIAL SAFETY DATA SHEET

Mark V Products Revision Date 12/31/05 400 El Sobrante Road Date Printed: 12/31/05 Corona, CA 92879 Product Number: Citra Clean Hand Cleaner (951) 280-9799 For Chemical Emergency, Call Chemtrec (951) 280-9393 FAX 1-800-424-9300

HEALTH HAZARD 1 - Slight FLAMMABILITY HAZARD 2 - Moderate REACTIVITY HAZARD 0 - Minimal PERSONAL PROTECTION

SECTION 1 - IDENTIFICATION

Product Name: CITRA CLEAN HAND CLEANER WITH PUMICE Product Type: emulsion Description: A thick, orange colored, commercial hand cleaner with an orange fragrance.

SECTION II - HAZARDOUS INGREDIENTS

HAZARDOUS INGREDIENT CAS NUMBER TLV / PEL

D Limonene 5989-27-5 TLV / PEL: None Est. Glycerine 56-81-5 TLV / PEL: None Est. Alkanolamine 102-71-4 TLV / PEL: Dermal LD50 2000 mg / kg Nonionic Surfactant 68081-81-2 TLV / PEL: None Est.

SECTION III - PHYSICAL DATA

Appearance: A thick orange liquid containing pumice Specific Gravity: 0.99 o Boiling Point: > 338 F % Volatile by volume: 92 Water Solubility (%) 89 pH: 7

SECTION IV - FIRE AND EXPLOSION DATA

o Flash Point (method): > 167 F (PMCC) Extinguishing Media: C02, dry chemical, foam, water fog, water spray. NFPA Classification: IIIB NFPA Symbol Codes: Flammability 1, Health 1, Reactivity 0 Fire Fighting Procedures: Wear approved SCBA with full facepiece operated in positive pressure demand mode.

SECTION V - REACTIVITY DATA

Stability: Material is Stable Hazardous Polymerization: Hazardous Polymerization is not expected to occur Incompatibility: Avoid contact with strong oxidizing agents and strong acids. Hazardous Decomposition: Combustion may produce Carbon Monoxide, CO2 and potentially irritating fumes.

Page 37 of 262 SECTION VI - HEALTH DATA

Routes of Entry: Inhalation, skin absorbtion, ingestion Listed Carcinogen: Not listed by IARC, NTP or OSHA Medical Conditions Aggrevated: Pre-existing condtions of the skin & respiratory system. Inhalation: Excessive inhalation of vapors can cause nasal and respiratory irritation. Ingestion: Can cause gastrointestinal irritation, nausea, vomiting & diarrhea. Aspiration of material into lungs may cause chemical pneumonitis. Eyes: May cause irritation, redness, tearing, blurred vision. Skin: May affect pre-existing conditions of dry skin and dermatitis.

SECTION VII - FIRST AID

Inhalation: Remove to fresh air. If problems develop, get medical attention. If breathing is difficult, administer oxygen. If breathing has stopped, give artificial respiration. Ingestion: Do NOT induce vomiting. If conscious, give large quantities of water. Have medical personnel determine if vomiting is necessary. Never give anything by mouth to an unconscious person. Aspiration of material into the lungs due to vomiting can cause chemical pneumonitis, which can be fatal. Eyes: Flush with large amounts of water for 15 minutes. Hold eyelids apart to ensure flushing. Get medical attention. Skin contact: Wash with soap and water. Remove contaminated clothing and wash before re-use.

SECTION VIII - EMPLOYEE PROTECTION

Respiratory Protection: Not usually needed. Protective Clothing: Nitrile gloves and chemical splash goggles. Addtional Measures: Do not place product in unmarked container. Keep away from children. Slippery when spilled.

SECTION IX - SPILL AND DISPOSAL DATA

Spill: Dike to prevent spillage into stream or storm drain system. Recover all material possible. Absorb remaining material with vermiculite or other absorbent material. Waste Disposal: Follow Federal, State and local guidelines. Handling & Storage: Store in a cool, well ventilated area. Avoid freezing or over heating.

SECTION X - OTHER REGULATORY INFORMATION

Shipping Name: Non Regulated UN Listing: Non Regulated Packing Group: Constituent:

SECTION XI - PRECAUTIONARY STATEMENTS

WARNING: This information contained in this MSDS is based on the data available to us from sources we believe to be reliable. No warranty or guaranty expressed or implied is made regarding the accuracy of this data or the results obtained from the reliance on this data. The manufacturer assumes no responsibility for injury from the use of this product. Be safe: Read this safety information and forward it to all persons who may be exposed to this product.

Page 38 of 262

533 2 Dansher Road Countryside, Illinois 60525

MATERIAL SAFETY DATA SHEET

Revision Date: 12/17/2012 MSDS No. N535 Supersedes Date: 8/15/2012

Emergency Phones: 708-579-8100 (NYCO) 800-424-9300 (CHEMTREC)

PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations.

SECTION I - PRODUCT IDENTITY

PRODUCT NAME: Citra-Blaze 535 Cleaner Degreaser Formula: Mixture of terpene solvent, detergent, alkaline builders and water. Chemical Type: As above

HMIS RATINGS Health = 1 (Slight) Flammability = 2 (Moderate) Reactivity = 0 (Minimal) Protection = B (Goggles and gloves)

SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) None no

SECTION III - CHEMICAL AND PHYSICAL Appearance: Orange Liquid Boiling Point: 210OF. Odor: Orange Melting Point: N/A pH: 11.0-11.8 Spec. Gravity (H20 = 1): 1.01 Water Solubility: Complete Vapor Pressure (Mm Hg): N/A Viscosity @ 25oC: < 25 cps (Brookfield) VOC Content: 1.2%

SECTION IV - FIRE AND EXPLOSION HAZARDS Flash Point (Method): 133oF. TCC Explosion Limits: Upper: 7 Lower: 1

Extinguishing Media: Water fog, CO2, halon system, foam for alcohols Special Firefighting Procedures and Hazards: Treat as a combustible liquid fire. May be ignited by heat, sparks, flame or other sources of ignition. Minimize prolonged skin and eye contact. Wear breathing, skin and eye protection if exposure is likely.

SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: Oxidizing agents.

Hazardous Decomposition Products: If in a fire: CO, CO2, hydrocarbons. Hazardous Polymerization: Occurs: Does Not Occur:

N535 Page 1 of 2 Page 39 of 262

SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID

Inhalation: Breathing of mists or vapor causes irritation. Wear approved organic mist respirator if necessary. Provide ventilation in confined spaces. Remove to fresh air. Give artificial respiration or oxygen if needed.

Skin: Extended contact may cause irritation and defatting. Wear protective gloves. Flush skin thoroughly with water for 15 minutes. Remove contaminated clothing and wash before wearing again.

Eyes: May cause irritation from misting. Flush with water for 15 minutes. If irritation persists consult a doctor.

Ingestion: May cause mild gastric disturbances or nausea. Avoid swallowing. Drink lots of water or milk. Do not induce vomiting. If irritation persists get medical attention.

Most likely routes of entry: Skin, Eyes.

Other Important Medical or Precautionary Information: None

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE

Spills and Leaks: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Do not drain to sewer without dilution. Larger spills should be contained by diking or other methods and held for disposal or reuse.

Storage and Handling: Keep away from heat, sparks and open flames. Check daily for any container leaks.

Waste Disposal: May be disposable in sewers if local regulations permit. Otherwise, send to licensed treatment and disposal facility for handling and disposal. Observe label precautions.

Empty Containers: Rinse well before handling and disposal. Observe label precautions.

Other Precautions: N/A

SECTION VIII - REGULATORY INFORMATION

Reportable for SARA Title III, S.313 (Form R): None

The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, Nyco Products cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use.

N535 Page 2 of 2 Page 40 of 262 POWER SERVICE PRODUCTS, INC. SAFETY DATA SHEET

SECTION 1 - IDENTIFICATION

PRODUCT NAME: DIESEL FUEL SUPPLEMENT +CETANE BOOST

Unless otherwise noted, all sections of this SDS apply to each of the following products and part numbers.

PART NUMBERS:

1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-09, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 11080-06 1:1,000 Treatment Ratio 1000, 1128-04, 1060-01 1:1,500 Treatment Ratio 1050-02, 1055-01, 1260-01

COMPANY IDENTIFICATION: Power Service Products, Inc. P.O. Box 1089 Weatherford, TX 76086 Email: [email protected] Phone: 800-643-9089 or 817-599-9486 Fax: 817-599-4893

Emergency Phone Number: Within USA 1-800-424-9300. Outside USA 001-703-527-3887 (Call Collect).

RECOMMENDED USES: Diesel fuel additive

SECTION 2 – HAZARD(S) IDENTIFICATION

CLASSIFICATION UNDER 29 CFR 1910.1200(d)

(NC=product does not meet classification criteria)

1:400 1:1000 1:1500 Treatment Treatment Treatment Ratio Ratio Ratio Health Hazard Criteria Category Category Category Acute Toxicity, Oral: NC NC NC Acute Toxicity, Dermal: NC NC NC Acute Toxicity, Inhalation, Vapors: 3 3 3

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Page 41 of 262 1:400 1:1000 1:1500 Treatment Treatment Treatment Ratio Ratio Ratio Health Hazard Criteria Category Category Category Skin Corrosion/Irritation: 2 2 2 Serious Eye Damage/Eye Irritation: 2 2 2 Respiratory Sensitization: NC NC NC Skin Sensitization: NC NC NC Germ Cell Mutagenicity: NC NC NC Carcinogenicity: 2 2 2 Reproductive Toxicity: NC NC NC Specific Target Organ Toxicity, Single 3 3 3 Exposure: Specific Target Organ Toxicity, Repeated NC NC NC or Prolonged Exposure: Aspiration Hazard: 1 1 1

1:400 1:1000 1:1500 Treatment Treatment Treatment Ratio Ratio Ratio Physical Properties Criteria Category Category Category Explosives: NC NC NC Flammable Gases: NC NC NC Flammable Aerosols: NC NC NC Oxidizing Gases: NC NC NC Gases Under Pressure: NC NC NC Flammable Liquids: 3 3 3 Flammable Solids: NC NC NC Self-Reactive Chemicals: NC NC NC Pyrophoric Liquids: NC NC NC Pyrophoric Solids: NC NC NC Self-Heating Chemicals: NC NC NC Chemicals Which, in Contact with Water, NC NC NC Emit Flammable Gases: Oxidizing Liquids: NC NC NC Oxidizing Solids: NC NC NC Organic Peroxides: NC NC NC Corrosive to Metals: NC NC NC

LABEL SIGNAL WORD, HAZARD STATEMENTS, SYMBOLS AND PRECAUTIONARY STATEMENTS UNDER 29 CFR 1910.1200(f):

Please see the Note regarding product labeling in Section 16.

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Page 42 of 262 1:400 1:1000 1:1500 Treatment Treatment Treatment Ratio Ratio Ratio Signal Word Danger Danger Danger

Hazard Statement(s): Flammable liquid and vapor. Toxic if inhaled. May be fatal if swallowed and enters airways. Harmful if swallowed. Causes skin and serious eye irritation. May cause respiratory irritation and drowsiness or dizziness.

Symbols: The following symbols are for all treatment ratios.

Precautionary Statement(s): Keep away from sparks and open flames. No smoking. Keep container tightly closed. Use only non-sparking tools. Ground/Bond container and receiving equipment. Use explosion-proof pumps when pumping. Take precautionary measures against static discharge. Avoid breathing vapors. Use only outdoors or in a well-ventilated area. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves and eye protection. Store locked up and in cool, well ventilated place. KEEP OUT OF REACH OF CHILDREN.

Hazards Not Otherwise Classified: None

SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS

The specific chemical identity and exact concentration percentage has been withheld as a Trade Secret. Specific chemical information will be made available to health professionals in accordance with 29 CFR 1910.1200.

INGREDIENTS CLASSIFIED AS HEALTH HAZARDS

TREATMENT RATIO 1:400 Common Chemical Name Name/Synonyms CAS Number Concentration (%) Petroleum Distillates Trade secret Trade secret 50 - 90 Hydroxy alkoxylate Trade secret Trade secret 4 - 10 Alkyl Nitrates Trade secret Trade secret 2 - 6 Naphthalene Not available 91-20-3 0.05 – 0.2

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Page 43 of 262 TREATMENT RATIO 1:1000

Common Name/Synonyms Concentration Chemical Name CAS Number (%) Petroleum Distillates Trade secret Trade secret 40 - 90 Alkyl Nitrates Trade secret Trade secret 5 - 15 Aromatic Hydrocarbons Trade secret Trade secret 2 - 5 Hexan-1-ol, 2-ethyl Trade secret Trade secret 1 - 4 Naphthalene Not available 91-20-3 0.1 – 0.5

TREATMENT RATIO 1:1500

Common Concentration Chemical Name Name/Synonyms CAS Number (%) Petroleum Distillates Trade secret Trade secret 20 - 55 Alkyl Nitrates Trade secret Trade secret 10 – 20 Aromatic Hydrocarbons Trade secret Trade secret 3 - 8 Hexan-1-ol, 2-ethyl Trade secret Trade secret 2 – 5 Naphthalene Not available 91-20-3 0.2 – 0.9

SECTION 4 - FIRST AID MEASURES

As a precaution, exposure to liquids, vapors, mists and fumes should be minimized.

EYE CONTACT: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice.

SKIN CONTACT: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs get medical advice/attention.

INHALATION: Remove person to fresh air and keep comfortable for breathing. Call a doctor.

INGESTION: If swallowed, IMMEDIATELY call a doctor. Do NOT induce vomiting.

SECTION 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Use water fog, alcohol-resistant foam, dry chemical or carbon dioxide (CO2) to extinguish flames.

SPECIFIC HAZARDS: Vapors are heavier than air and may travel along the ground to a distant ignition source and flash back. See Section 10 for Stability and Reactivity. NOTE: EMPTY CONTAINERS CONTAIN COMBUSTIBLE VAPORS THAT CAN CAUSE FLASH FIRES OR EXPLOSIONS. CONTAINERS ARE SINGLE-TRIP CONTAINERS AND SHOULD NOT BE USED FOR ANY REASON AFTER BEING EMPTIED. DO NOT USE CUTTING TORCH

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Page 44 of 262 EQUIPMENT OR ANY OTHER FLAME OR OTHER SOURCES OF IGNITION ON ANY EMPTY CONTAINER.

PROTECTIVE EQUIPMENT AND PRECAUTIONS: Use standard protective equipment including self-contained breathing apparatus (SCBA).

SECTION 6 - ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES: Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas. Eliminate all sources of ignition in the vicinity of the spill or released vapor. See Section 2 for Hazards Identification. See Section 4 for First Aid Measures. See Section 5 for Fire Fighting Information. See Section 8 for Personal Protective Equipment.

SPILL CONTAINMENT AND CLEAN-UP: Eliminate potential sources of ignition. Stop leak if it can be done without risk. Dike and contain spill. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. Remove with vacuum trucks or pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. A vapor suppressing foam may be used to reduce vapors. Local, state and federal laws and/or regulations may apply to releases and disposal of this material, as well as those materials and items employed in the clean-up releases. The user/responder will need to determine which local, state and federal laws and/or regulations are applicable. The National Response Center can be reached at 1-800-424-8802.

SECTION 7 - HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Avoid contact with eyes and skin. Use only with adequate ventilation. Use proper bonding and/or grounding procedures. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Keep away from ignition sources such as heat, sparks, and flames. No smoking.

CONDITIONS FOR SAFE STORAGE: DO NOT USE OR STORE near heat, sparks, or flame. USE AND STORE ONLY IN A WELL-VENTILATED AREA. Handle containers with care. Keep container tightly closed when not in use. Store locked up.

STORAGE TEMPERATURE:

Storage Treatment Ratio Part Numbers: Temperature: 1:400 Treatment 1016-06, 1016-09, 1025-06, 1025-12, 1080-06, 11016-06, -20F to 104F Ratio 11016-09, 11025-06, 11025-12, 11041-04, 11080-06 (-29C to 40C) 1:1,000 Treatment 1000, 1128-04, 1060-01 0F to 104F Ratio (-18C to 40C)

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Page 45 of 262 1:1,500 Treatment 1050-02, 1055-01, 1260-01 10F to 104F Ratio (-12C to 40C)

EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION HAZARD DATA.

SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE GUIDELINES: OSHA ACGIH NIOSH CAS # PEL TLV STEL REL STEL IDLH Note Ethylbenzene 100-41-4 100 ppm 20 ppm not est. 100 ppm 125 ppm 800 ppm (LEL) n/a

Naphthalene 91-20-3 10 ppm 10 ppm not est. 10 ppm 15 ppm 250 ppm skin

Petroleum Distillates n/a 500 ppm not est. not est. not est. not est. not est. n/a

Cumene 98-82-8 50 ppm 50 ppm not est. 50 ppm not est. 900 ppm (LEL) Skin

Toluene 108-88-3 100 ppm 20 ppm not est. 100 ppm 150 ppm 500 ppm Skin

Hydroxy Alkoxylate Proprietary 50 ppm 20 ppm not est. 5 ppm not est. not est. skin

ENGINEERING CONTROLS: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Local exhaust ventilation is recommended to control exposure.

PERSONAL PROTECTIVE EQUIPMENT (PPE):

Eyes and Face: Eye protection such as safety glasses or chemical goggles is recommended if contact is likely.

Skin: Protective chemical/oil resistant gloves are recommended. Wear additional protective clothing as appropriate.

Respiratory: Wear a NIOSH/MSHA approved respirator as necessary.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Practice good housekeeping.

NOTE: These precautions are for room temperature handling.

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Page 46 of 262 SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

1:400 Treatment 1:1000 Treatment 1:1500 Treatment Ratio Ratio Ratio Appearance Liquid, brown Liquid, brown Liquid, brown Odor Aromatic solvent Aromatic solvent Aromatic solvent Odor Threshold Not available Not available Not available 7 – 8 (slightly 7 – 8 (slightly pH 7 – 8 (slightly basic) basic) basic) Melting point/Freezing point Not available Not available Not available Initial Boiling Point and Boiling 300F (149C) 300F (149C) 300F (149C) Range Flash Point 105F (40.5C) 116F (46.6C) 121F (49.4C) Evaporation Rate Not available Not available Not available Flammability Not available Not available Not available Upper / lower Flammability or Not available Not available Not available Explosive Limits Vapor Pressure 0.2 – 0.95 0.2 – 0.95 0.2 – 0.95 Vapor Density >5.0 >5.0 >5.0 Relative Density/Specific Gravity 0.910 0.912 0.896 (at 60°F) Solubility Not available Not available Not available Partition Coefficient; n-octanol / Not available Not available Not available water Auto-ignition Temperature Not available Not available Not available Decomposition temperature Not available Not available Not available Viscosity Not available Not available Not available Pour Point -55F (-13C) -30F (1.1C) -15F (9.4C)

SECTION 10 - STABILITY AND REACTIVITY

REACTIVITY: see Incompatible Materials below

CHEMICAL STABILITY: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

POSSIBILITY OF HAZARDOUS REACTION: Hazardous polymerization will not occur.

CONDITIONS TO AVOID: Flames, high energy ignition sources, and elevated temperatures.

INCOMPATIBLE MATERIALS: May react with strong oxidizing agents, such as; chlorates, nitrates, peroxides, nitrogen oxides, sulfur oxides, etc.; alkalis; nitric acid; sulfuric acid; aluminum; brass; copper; reducing agents.

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides, products of incomplete combustion.

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Page 47 of 262

SECTION 11 - TOXICOLOGICAL INFORMATION

LIKELY ROUTES OF EXPOSURE

INGESTION INHALATION SKIN EYE SKIN CONTACT CONTACT ABSORPTION 1:400 Treatment Ratio X X X X 1:1000 Treatment Ratio X X X X 1:1500 Treatment Ratio X X X X

SYMPTOMS RELATED TO PHYSICAL, CHEMICAL AND TOXICOLOGICAL CHARACTERISTICS: Breathing of high vapor concentrations may cause dizziness, light- headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. The vapor or fumes from this material may cause respiratory irritation. Breathing this material at elevated concentrations causes central nervous system effects. Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion or disorientation. At extreme exposures, central nervous system effects may include respiratory depression, tremors, or convulsions, loss of consciousness, coma or death.

DELAYED AND IMMEDIATE EFFECTS AND CHRONIC EFFECTS FROM SHORT- AND LONG-TERM EXPOSURE: Repeated skin exposure to a component of this product may cause irritation, even a burn; may cause a more severe response on covered skin, such as under clothing or gloves. Inhalation exposure to a component of this product has caused fetotoxicity in the presence of maternal toxicity in animals.

NUMERICAL MEASURES OF TOXICITY Note: the information provided below are estimates; testing of the product is not available.

Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Treatment Ratio (ATEmix estimate) (ATEmix estimate) (ATEmix estimate) 1:400 Treatment Does not meet criteria Does not meet criteria 7.10 (vapors) Ratio 1:1,000 Treatment Does not meet criteria Does not meet criteria 8.56 (vapors) Ratio 1:1,500 Treatment Does not meet criteria Does not meet criteria 7.48 (vapors) Ratio

SENSITIZATION: No information available.

MUTAGENICITY: No information available.

CARCINOGENICITY LISTINGS – the following chemicals are listed as indicated:

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Page 48 of 262 Chemical List Cumene IARC, NTP Ethylbenzene IARC Naphthalene IARC, NTP

REPODUCTIVE TOXICITY: No information available.

TERATOGENICITY/EMBRYOTOXICITY: Hydroxy Alkoxylate has caused fetotoxicity with maternal toxicity. This product contains a component of a complex mixture (Xylenes (1330-20- 7)) that has been shown to cause teratogenicity and/or embryotoxicity.

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): Respiratory tract irritation, drowsiness/dizziness.

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): No information available

ASPIRATION HAZARD: Aspiration hazard identified.

SECTION 12 - ECOLOGICAL INFORMATION

ECOTOXICITY: This material is expected to be toxic to aquatic organisms.

PERSISTENCE AND DEGRADABILITY: No information available.

BIOACCUMULATIVE POTENTIAL: No information available.

MOBILITY IN SOIL: No information available.

OTHER ADVERSE EFFECTS: No information available.

SECTION 13 - DISPOSAL CONSIDERATIONS

RCRA Information: Disposal of unused product may be subject to RCRA hazardous waste regulations (40 CFR Part 261). Disposal of the used product may also be regulated as hazardous waste due to resulting mixture characteristics, mixture components or product use. Such changes to the product may result in different and/or additional hazardous waste codes. Potential RCRA waste code based on the product as shipped: D001 IGNITABILITY

State or local laws may impose additional regulatory requirements regarding disposal. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator.

EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN COMBUSTIBLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION

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Page 49 of 262 HAZARD DATA. Dispose or recycle empty containers appropriately per local, state and federal regulations.

SECTION 14 - TRANSPORTATION INFORMATION

The following part numbers are not regulated by DOT:

1:400 Treatment Ratio 1016-06, 1016-09, 1025-06, 1025-09, 1025-12, 1080-06, 11016-06, 11016-09, 11025-06, 11025-12, 1080-06 1:1,000 Treatment Ratio 1128-04 1:1,500 Treatment Ratio 1050-02, 1055-01

The following part numbers are regulated by DOT:

1:1,000 Treatment Ratio 1060-01

PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant (2-Ethylhexyl Nitrate) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes

1:1,000 Treatment Ratio 1000

PROPER SHIPPING NAME: Combustible Liquid, N.O.S., (Petroleum Distillates) Marine Pollutant (2-Ethylhexyl Nitrate) RQ (Xylene, Naphthalene) HAZARD CLASS: Combustible Liquid I.D. NUMBER: NA 1993 PACKING GROUP: III PLACARDING: Combustible Liquid MARINE POLLUTANT: Yes PRODUCT RQ: 100 lbs. (45.45 kg) – Xylene, Naphthalene

1:1,500 Treatment Ratio 1260-01

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Page 50 of 262

SECTION 15 - REGULATORY INFORMATION

§14(a) Consumer Product Safety Act General Certificate of Conformity

Power Service Products, Inc. certifies that this product meets the statutory and regulatory requirements of the US Consumer Products Safety Act, the Federal Hazardous Substances Act, and the Poison Prevention Packaging Act of 1970, as applicable. The Power Service products are manufactured in the United States in Weatherford, Texas, unless otherwise indicated on the product label. The product manufacture lot code is stamped on the product container. This Certification is based upon a reasonable testing program conducted by Power Service Products, Inc. which includes a quality control program incorporating, as necessary, confirmation of compliance by component suppliers. Third-party testing is not required to certify compliance. Further details may be obtained by contacting the Power Service Products, Inc. EHS Manager at 1-800-643-9089.

Contents of this SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.

TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control Act inventory reporting requirements.

EPA SARA TITLE III CHEMICAL LISTINGS:

Section 302 Extremely Hazardous Substances: None

Sections 311/ 312 Hazard Class: Acute Health Effects: Yes Sudden Release of Pressure Hazard: No Chronic Health Effects: Yes Reactivity Hazard: No Fire Hazard: Yes

NFPA (NATIONAL FIRE PROTECTION ASSOCIATION) RATING: HEALTH: 2 FIRE: 2 REACTIVITY: 0

Section 313: Specific chemical information is being withheld as a Trade Secret. The following chemicals subject to the reporting requirements of EPCRA Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (40 CFR Part 372) may be present in this product at a concentration that does not exceed the specified upper weight percentage.

Treatment Ratio CAS Number Chemical Name Max % 1:400 Treatment Ratio 100-41-4 Ethylbenzene 24.0 NA Glycol Ether Category 8.0

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Page 51 of 262 Treatment Ratio CAS Number Chemical Name Max % 91-20-3 Naphthalene 1.0 98-82-8 Cumene 4.0 108-88-3 Toluene 4.0 1:1000 Treatment Ratio 100-41-4 Ethylbenzene 19.0 91-20-3 Naphthalene 1.0 98-82-8 Cumene 3.5 108-88-3 Toluene 3.5 1:1,500 Treatment Ratio 100-41-4 Ethylbenzene 12.0 91-20-3 Naphthalene 1.0 98-82-8 Cumene 2.0 108-88-3 Toluene 2.0

State or local laws may impose additional regulatory requirements for components of this material. It is the responsibility solely of the Employer to maintain compliance with State and Local reporting.

This product contains a chemical known to the state of California to cause cancer and/or birth defects or other reproductive harm: ethylbenzene, toluene, cumene, naphthalene.

SECTION 16 – OTHER INFORMATION

DATE OF PREPARATION / REVISION: May 30, 2015

NOTE regarding product labeling: The OSHA Hazard Communication Standard applies to hazardous chemicals known to be present in the workplace. However, the labeling and Safety Data Sheet requirements do not apply to consumer products when they are used in the workplace for the purposes intended by the manufacturer and the use results in a duration and frequency of exposure which is not greater than the range of exposures that could reasonably be experienced by consumers when used for the intended purpose. Power Service Products intends for product packaged in 1 gallon or smaller containers to be used by consumers and has labeled those containers as required under the Consumer Product Safety Commission regulations. Power Service Products intends for product packaged in containers larger than 1 gallon to be used in the workplace and has labeled those products as required by the OSHA Hazard Communication Standard. The Consumer Product Safety Commission and OSHA Hazard Communication Standard labeling requirements are different and variations between the consumer and industrial labels may occur. It is the employer’s responsibility to purchase the appropriate product for use in the workplace.

The information contained herein is offered in good faith and is believed to be accurate based on the data available to us as of the date of SDS preparation. The information in this document applies to this specific product as supplied. It may not be appropriate for this product if the product is used in combination with other materials. The information in this document is not intended to constitute product performance information. Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product. No statement shall be construed as an endorsement of any product or process. The recommended

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Page 52 of 262 industrial hygiene and safe handling procedures are believed to be valid in the context of the intended use as described in product labeling. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. You are urged to obtain material safety data sheets for all products you buy, process, use or distribute, and are encouraged to advise those who may come in contact with such products of the information contained therein. Regulatory requirements are subject to change and may differ between locations. It is the buyer’s/user’s responsibility to ensure that his activities comply with all federal, state, provincial or local laws. No warranty or guarantee is expressed or implied with respect to this product, the accuracy and sufficiency of the data or recommendations herein, or the results to be obtained from the use of this product. IN NO EVENT SHALL POWER SERVICE PRODUCTS, INC. BE LIABLE FOR ANY LOSS, CLAIM, DAMAGE OR LIABILITY OF ANY KIND, WHICH MAY ARISE FROM OR IN CONNECTION WITH THE INFORMATION CONTAINED IN THIS DOCUMENT OR FROM THE USE, HANDLING OR STORAGE OF THE PRODUCT BY THE BUYER/USER, WHETHER DIRECT, INDIRECT, OR CONSEQUENTIAL, OR FOR ANY CLAIM BY ANY THIRD PARTY, BEYOND THE PURCHASE PRICE OR REPLACEMENT OF THE PRODUCT IN CONNECTION WITH WHICH SUCH LOSS, CLAIM, DAMAGE OR LIABILITY AROSE.

THE FOREGOING LIMITATIONS APPLY REGARDLESS OF THE CAUSES OR CIRCUMSTANCES GIVING RISE TO SUCH LOSS, CLAIM, DAMAGE OR LIABILITY, EVEN IF SUCH LOSS, CLAIM, DAMAGE, OR LIABILITY IS BASED ON NEGLIGENCE OR OTHER TORTS OR BREACH OF CONTRACT.

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Page 53 of 262 Safety Data Sheet Spartan Chemical Company, Inc.

Revision Date: 01-May-2015

1. PRODUCT AND COMPANY IDENTIFICATION

Product Identifier Product Name: DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Product Number: 6099 Recommended Use: Cleaning agent Uses Advised Against: For Industrial and Institutional Use Only

Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA 800-537-8990 (Business hours) www.spartanchemical.com

24 Hour Emergency Phone Numbers: Medical Emergency/Information: 888-314-6171 Transportation/Spill/Leak: CHEMTREC 800-424-9300

2. HAZARDS IDENTIFICATION

GHS Classification Flammable Aerosols Category 1 Gases Under Pressure Liquefied gas

GHS Label Elements Signal Word: Danger Symbols:

Hazard Statements: Extremely flammable aerosol. Contains gas under pressure; may explode if heated Precautionary Statements: Prevention: Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information.

Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in a well-ventilated place Disposal: Not Applicable

Hazards Not Otherwise Classified: Not Applicable

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Page 54 of 262 6099 - DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Revision Date: 01-May-2015 ______Other Information: • May be harmful if swallowed. • May cause eye irritation. • May cause skin irritation. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-% water 7732-18-5 40-70 petroleum distillates 64742-47-8 5-10 white mineral oil 8042-47-5 5-10 N-butane 106-97-8 3-7 propane 74-98-6 1-5 decaglyceryl monooleate 9007-48-1 1-5

Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

-Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media: Water spray (fog), Foam Specific Hazards Arising from the Extremely flammable aerosol. Exposure to high temperature may cause containers to burst. Chemical: Bursting aerosol containers may be propelled from fire at high speed. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors.

Protective Equipment and Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full Precautions for Firefighters: protective gear. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13).

7. HANDLING AND STORAGE

Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly after handling.

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Page 55 of 262 6099 - DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Revision Date: 01-May-2015 ______Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 C°. Exposure to high temperature may cause containers to burst. Keep out of the reach of children.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits: . Chemical Name ACGIH TLV OSHA PEL NIOSH N-butane TWA: 1000 ppm (vacated) TWA: 800 ppm TWA: 800 ppm 106-97-8 (vacated) TWA: 1900 mg/m3 TWA: 1900 mg/m3 propane TWA: 1000 ppm TWA: 1000 ppm IDLH: 2100 ppm 74-98-6 TWA: 1800 mg/m3 TWA: 1000 ppm (vacated) TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1800 mg/m3

Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Not required with expected use. Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance/Physical State: Aerosol Color: White emulsion Odor: Bland pH: 8.0-9.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 132 °C / 270 °F (Product without propellant) Estimated Flash Point: < -58 °C / < -72 °F (Propellant-estimated) Evaporation Rate: < 1 Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 0.95 (Product without propellant) Solubility(ies): No information available. Partition Coefficient: No information available. Autoignition Temperature: No information available. Decomposition Temperature: No information available. Viscosity: No information available.

10. STABILITY AND REACTIVITY

Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids.

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Page 56 of 262 6099 - DUST MOP / DUST CLOTH TREATMENT (AEROSOL) Revision Date: 01-May-2015 ______Hazardous Decomposition May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. Products:

11. TOXICOLOGICAL INFORMATION

Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. Symptoms of Exposure: -Eye Contact: Pain and redness. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification.

Target Organ Effects: Central nervous system. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 27233 mg/kg ATEmix (dermal): 20202 mg/kg ATEmix (inhalation-gas): 3021468 mg/l

Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water > 90 mL/kg ( Rat ) Not Available Not Available 7732-18-5 petroleum distillates > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h 64742-47-8 white mineral oil > 5000 mg/kg ( Rat ) Not Available Not Available 8042-47-5 N-butane Not Available Not Available = 658 mg/L ( Rat ) 4 h 106-97-8 propane Not Available Not Available = 658 mg/L ( Rat ) 4 h 74-98-6

Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA.

12. ECOLOGICAL INFORMATION

Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Crustacea Microorganisms petroleum distillates Not Available 45: 96 h Pimephales Not Available 4720: 96 h Den-dronereides 64742-47-8 promelas mg/L LC50 heteropoda mg/L LC50 flow-through 2.2: 96 h Lepomis macrochirus mg/L LC50 static 2.4: 96 h Oncorhynchus mykiss mg/L LC50 static white mineral oil Not Available 10000: 96 h Lepomis Not Available Not Available 8042-47-5 macrochirus mg/L LC50

Persistence and Degradability: No information available. Bioaccumulation: No information available.

Other Adverse Effects: No information available.

13. DISPOSAL CONSIDERATIONS

Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with federal, state and local regulations.

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14. TRANSPORT INFORMATION

DOT: UN/ID No: UN1950 Proper Shipping Name: Aerosols Hazard Class: 2.1 Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited quantity and may be shipped as a limited quantity.

15. REGULATORY INFORMATION

TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances.

SARA 313 This product does not contain listed substances above the "de minimus" level

SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: Yes Reactive Hazard: No

California Proposition 65 This product does not contain any Proposition 65 chemicals

16. OTHER INFORMATION

NFPA Health Hazards: 1 Flammability: 1 Instability: 0 Special: N/A HMIS Health Hazards: 1 Flammability: 2 Physical Hazards: 2

Revision Date: 01-May-2015 Reasons for Revision: No information available.

Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

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SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL Version: 5.1 CLEANER 836604

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Ashland Regulatory Information Number 1-800-325-3751 P.O. Box 2219 Telephone 614-790-3333 Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-800-274- 5263)

Product name Eagle One™ ETCHING MAG WHEEL CLEANER

Product code 836604

2. HAZARDS IDENTIFICATION

Emergency Overview

Appearance: liquid, colourless

DANGER! CONTAINS HYDROFLUORIC ACID. MAY BE HARMFUL. MAY CAUSE SEVERE BURNS OF RESPIRATORY AND DIGESTIVE TRACTS. MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN. CAUSES SEVERE BURNS OF THE EYES AND SKIN.

Potential Health Effects

Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion

Eye contact Can cause permanent eye injury. Symptoms include stinging, tearing, redness, and swelling of eyes. Can injure the cornea and cause blindness.

Skin contact Can cause permanent skin damage. Symptoms may include redness, burning, and swelling of skin, burns, and other skin damage. Exposure can cause severe irritation and fluoride-like burns which may not be immediately evident.

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Swallowing this material may be harmful or fatal. Symptoms may include severe stomach and intestinal irritation (nausea, vomiting, diarrhea), abdominal pain, and vomiting of blood. Swallowing this material may cause burns and destroy tissue in the mouth, throat, and digestive tract. Low blood pressure and shock may occur as a result of severe tissue injury.

Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing this material may be harmful or fatal. Symptoms may include severe irritation and burns to the nose, throat, and respiratory tract. Symptoms are not expected at air concentrations below the recommended exposure limits, if applicable (see Section 8.).

Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, lung (for example, asthma-like conditions), Upper respiratory tract, skin, Liver, kidney, Central nervous system, bone, Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias., Individuals with preexisting heart disorders maybe more susceptible to arrhythmias (irregular heartbeats) if exposed to high concentrations of this material.

Symptoms Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Cough, sneezing, choking, Headache, Difficulty in breathing, lung edema (fluid buildup in the lung tissue), damage to the mouth, throat, and/or airways

Target Organs Repeated, prolonged overexposure to inorganic fluoride compounds may result in gastrointestinal disturbances, loss of weight, anemia (reduced number of red blood cells), diseases of the teeth,and skeletal fluorosis. Skeletal fluorosis is characterized by bone and joint pain, limited motion in the joints or spine, increased bone density which can cause the bones to become brittle, and hardening of ligaments., Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, nervous system effects, blood abnormalities, liver abnormalities, kidney damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, damage to tooth enamel, effects on lung function, respiratory tract damage (nose, throat, and airways)

Carcinogenicity

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SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL Version: 5.1 CLEANER 836604

This product contains sulfuric acid. The International Agency for Research on Cancer (IARC) and the National Toxicology Program (NTP) have listed strong-inorganic-acid mists containing sulfuric acid as causing cancer in humans.

Reproductive hazard Inhalation of sulfuric acid fumes was not harmful to the fetus in laboratory animal studies even at levels that caused some harm to the pregnant animals., This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain.

Other information Hydrofluoric acid has been shown to cause permanent changes in the DNA of insect germ cells. Changes in these cells can be passed to the next generation. The relevance of this finding to human health is uncertain.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Components CAS-No. / Trade Secret No. Concentration PHOSPHORIC ACID 7664-38-2 >=10-<15% SULFURIC ACID 7664-93-9 >=1.5-<5% HYDROFLUORIC ACID 7664-39-3 >=1.5-<5% ALCOHOL ETHOXYLATE >=1-<1.5% SODIUM 1-OCTANESULFONATE 5324-84-5 >=1-<1.5%

4. FIRST AID MEASURES

Eyes If material gets into the eyes, immediately flush eyes gently with water for at least 15 minutes while holding eyelids apart. If symptoms develop as a result of vapor exposure, immediately move individual away from exposure and into fresh air before flushing as recommended above. Seek immediate medical attention.

Skin

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Immediately flush contaminated skin with large quantities of cool running water for 5 minutes. Remove contaminated clothing while flushing contaminated skin. Immediately after washing, apply 2.5% calcium gluconate gel to all affected skin areas. (Note: If gel is not prepared within 5 minutes, continue flushing until gel is prepared.) The gel should be massaged into the affected skin by personnel wearing gloves to prevent skin contamination during first aid. Gel should be applied every 15 minutes and massaged continuously. Instead of calcium gluconate treatment, the affected areas may be soaked in iced 0.13% benzalkonium chloride solution (Zephiran chloride). Use ice cubes rather than shaved ice to prevent frostbite. If it is not practical to immerse affected area, towels should be soaked with iced 0.13% benzalkonium chloride solution and used as compresses for the burned area. Compresses should be changed every 2-3 minutes and continued until pain is relieved or victim is seen by a physician. If neither calcium gluconate nor benzalkonium chloride is available, use an iced saturated water solution of magnesium sulfate (Epsom salts), or if that is not available, iced 70% alcohol or ice water. Local anesthetics should be avoided since relief of pain indicates success of the treatment. ***Get medical attention as soon as possible.*** ::::NOTE::::Calcium gluconate gel can be prepared by mixing a 10 milliliter ampule of calcium gluconate with a 2-ounce tube of K-Y jelly (Johnson & Johnson). After a jar of this mixture has been opened and used, it should be discarded to prevent bacterial or chemical contamination.

Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.

Inhalation If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen.

Notes to physician Hazards: This product contains hydrofluoric acid (HF). Acute local effects from HF exposure are concentration-dependent. If untreated or exposure is prolonged, even dilute solutions of HF can cause delayed toxicity following penetration to subcutaneous tissue. Acute systemic toxicity is largely dependent upon the total amount of fluoride ion absorbed. Thus ingestion, skin contact or significant inhalation can cause severe systemic effects including electrolyte (calcium, magnesium, potassium) and acid-base abnormalities with resulting cardiovascular effects. Exposure of >5% of the body surface area with any concentration of HF may predispose the patient to development of hypocalcemia. Chronic exposure to less than acutely toxic amounts of HF is a low toxicity hazard. Repeated exposure and absorption of 10-80 mg of fluoride per day may produce systemic fluorosis.

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Treatment: No information available.

5. FIREFIGHTING MEASURES

Suitable extinguishing media Dry chemical, Foam, Carbon dioxide (CO2)

Hazardous combustion products Oxides of phosphorus, corrosive vapors, sulfur oxides, toxic fumes, acid vapors, Hydrogen fluoride

Precautions for fire-fighting Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes.

NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB

6. ACCIDENTAL RELEASE MEASURES

Personal precautions For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed.

Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system.

Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

Other information Comply with all applicable federal, state, and local regulations.

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7. HANDLING AND STORAGE

Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.

Storage Store in a cool, dry, ventilated area.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

PHOSPHORIC ACID 7664-38-2 ACGIH time weighted average 1 mg/m3 ACGIH Short term exposure limit 3 mg/m3 NIOSH Recommended exposure 1 mg/m3 limit (REL): NIOSH Short term exposure limit 3 mg/m3 OSHA Z1 Permissible exposure limit 1 mg/m3 SULFURIC ACID 7664-93-9 ACGIH time weighted average 0.2 mg/m3 Thoracic fraction. NIOSH Recommended exposure 1 mg/m3 limit (REL): OSHA Z1 Permissible exposure limit 1 mg/m3 HYDROFLUORIC ACID 7664-39-3 ACGIH time weighted average 0.5 ppm ACGIH Ceiling Limit Value: 2 ppm NIOSH Recommended exposure 3 ppm limit (REL): NIOSH Recommended exposure 2.5 mg/m3 limit (REL): NIOSH Ceiling Limit Value and 6 ppm Time Period (if specified): NIOSH Ceiling Limit Value and 5 mg/m3 Time Period (if specified): OSHA Z2 time weighted average 3 ppm

General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect Page 6 / 14

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exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities.

Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Mechanical ventilation systems used to ventilate corrosive storage or process areas must be designed with components that are corrosion resistant.

Eye protection Wear chemical splash goggles and face shield when there is potential for exposure of the eyes or face to liquid, vapor or mist. Maintain eye wash station in immediate work area.

Skin and body protection Wear resistant gloves (consult your safety equipment supplier). Discard gloves that show tears, pinholes, or signs of wear. Wear appropriate chemical impervious clothing and boots whenever there is potential for skin contact with product. Launder clothing before reuse. Maintain safety shower at all locations where skin contact could occur. Contact your local safety equipment supplier to assist the facility in determining proper selection of personal protective equipment for the applications/operations present at your facility.

Respiratory protection A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air- purifying respirators is limited. Use a positive pressure, air-supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air- purifying respirator may not provide adequate protection.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state liquid Colour colourless Boiling point/boiling range 195.1 °F / 90.6 °C @ 1,013.33 hPa Calculated Phase Transition Liquid/Gas pH 1 Flash point > 212 °F / > 100 °C Page 7 / 14

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Evaporation rate (>)1 Ethyl Ether Vapour pressure 23.333 hPa @ 68 °F / 20 °C Calculated Vapor Pressure Density 1.1 g/cm3 9.46 lb/gal @ 60.00 °F / 15.56 °C

10. STABILITY AND REACTIVITY

Stability Stable.

Conditions to avoid excessive heat

Incompatible products Fluorine, nitromethane, Strong oxidizing agents, strong reducing agents, Sulphides, sulphites, Acids, Acid anhydrides, Aldehydes, Alcohols, Amines, Bases, carbide, carbonates, Combustible material, Copper, Cyanides, glycols, halogens, Nitriles, Organic materials, organic nitro compounds, Powdered metals, sulfides

Hazardous decomposition products Oxides of phosphorus, corrosive vapors, Sulphur oxides, toxic fumes, acid vapors, Hydrogen fluoride

Hazardous reactions Product will not undergo hazardous polymerization.

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity Acute oral toxicity - : no data available Product

Acute oral toxicity - Components PHOSPHORIC ACID : LD 50: ca. 2,600 mg/kg Species: Rat Page 8 / 14

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SULFURIC ACID : LD 50: 2,140 mg/kg Species: Rat ALCOHOL : LD50: > 2,000 mg/kg Species: rat Remarks: Based on a ETHOXYLATE similar product formulation.

Acute inhalation toxicity Acute inhalation toxicity - : no data available Product

Acute inhalation toxicity - Components PHOSPHORIC ACID : Remarks: Corrosive to respiratory system

Acute dermal toxicity Acute dermal toxicity - : no data available Product

Acute dermal toxicity - Components PHOSPHORIC ACID : LD 50: 2,740 mg/kg Species: Rabbit HYDROFLUORIC ACID : LD Lo: 500 mg/kg Species: Mouse ALCOHOL : LD 50: 3,300 mg/kg Species: Rat ETHOXYLATE

Acute toxicity (other routes of administration) Acute toxicity (other : no data available routes of administration)

12. ECOLOGICAL INFORMATION

Biodegradability Biodegradability - Product : no data available

Biodegradability - Components ALCOHOL : Remarks: Expected to be biodegradable ETHOXYLATE

Bioaccumulation Page 9 / 14

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Bioaccumulation - Product : no data available

Ecotoxicity effects Toxicity to fish Toxicity to fish - Product : no data available

Toxicity to fish - Components SULFURIC ACID : LC 50: 42 mg/l Exposure time: 96 h Species: Western mosquitofish (Gambusia affinis) Method: Static Remarks: Mortality

ALCOHOL : 8.5 mg/l ETHOXYLATE Exposure time: 96 h Species: Pimephales promelas (fathead minnow) Remarks: Based on a similar product formulation.

Toxicity to daphnia and other aquatic invertebrates Toxicity to daphnia and : no data available other aquatic invertebrates - Product

Toxicity to daphnia and other aquatic invertebrates - Components ALCOHOL : 5.3 mg/l ETHOXYLATE Species: Daphnia Remarks: Based on a similar product formulation.

Toxicity to algae Toxicity to algae - : no data available Product

Toxicity to bacteria Toxicity to bacteria - : no data available Product

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13. DISPOSAL CONSIDERATIONS

Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations.

14. TRANSPORT INFORMATION

REGULATION ID PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE NUMBER CLASS HAZARDS GROUP POLLUTANT / LTD. QTY. U.S. DOT - ROAD 3264 LIQUIDO CORROSIVO, 8 II ACIDO, INORGANICO, N.E.P. (PHOSPHORIC ACID, SULFURIC ACID)

U.S. DOT - RAIL 3264 Corrosive liquid, acidic, 8 II inorganic, n.o.s. (PHOSPHORIC ACID, SULFURIC ACID)

U.S. DOT - INLAND WATERWAYS 3264 Corrosive liquid, acidic, 8 II inorganic, n.o.s. (PHOSPHORIC ACID, SULFURIC ACID)

TRANSPORT CANADA - ROAD UN 3264 CORROSIVE LIQUID, ACIDIC, 8 II LIMITED INORGANIC, N.O.S. QUANTITY (PHOSPHORIC ACID, SULFURIC ACID)

TRANSPORT CANADA - RAIL

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UN 3264 CORROSIVE LIQUID, ACIDIC, 8 II INORGANIC, N.O.S. (PHOSPHORIC ACID, SULFURIC ACID)

TRANSPORT CANADA - INLAND WATERWAYS UN 3264 CORROSIVE LIQUID, ACIDIC, 8 II INORGANIC, N.O.S. (PHOSPHORIC ACID, SULFURIC ACID)

INTERNATIONAL MARITIME DANGEROUS GOODS UN 3264 CORROSIVE LIQUID, ACIDIC, 8 II INORGANIC, N.O.S. (PHOSPHORIC ACID, SULFURIC ACID)

INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO UN ORM-D, CONSUMER ORM COMMODITY

INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER UN ORM-D, CONSUMER ORM COMMODITY

MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES UN ORM-D, CONSUMER ORM COMMODITY *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID

Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment.

15. REGULATORY INFORMATION

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California Prop. 65WARNING! This product contains a SULFURIC ACID chemical known to the State of California to cause cancer.

SARA Hazard Classification SARA 311/312 Classification Acute Health Hazard Chronic Health Hazard

SARA 313 Component(s) SULFURIC ACID 2.35 % HYDROFLUORIC ACID 1.60 %

New Jersey RTK Label Information WATER 7732-18-5 PHOSPHORIC ACID 7664-38-2 SULFURIC ACID 7664-93-9 SURFACTANT HYDROFLUORIC ACID 7664-39-3

Pennsylvania RTK Label Information WATER 7732-18-5 PHOSPHORIC ACID 7664-38-2 SULFURIC ACID 7664-93-9 HYDROFLUORIC ACID 7664-39-3

Notification status US. Toxic Substances Control Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). y (positive listing) Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) Australia. Industrial Chemical (Notification and Assessment) y (positive listing) Act New Zealand. Inventory of Chemicals (NZIoC), as published n (Negative listing) by ERMA New Zealand Japan. Kashin-Hou Law List n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Philippines. The Toxic Substances and Hazardous and Nuclear y (positive listing) Waste Control Act

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SAFETY DATA SHEET Revision Date: 09/17/2012 Print Date: 1/13/2015 MSDS Number: R0336576 Eagle One™ ETCHING MAG WHEEL Version: 5.1 CLEANER 836604

China. Inventory of Existing Chemical Substances y (positive listing)

Reportable quantity - Product US. EPA CERCLA Hazardous Substances (40 CFR 302) 6250 lbs

Reportable quantity-Components HYDROFLUORIC ACID 7664-39-3 100 lbs

HMIS NFPA Health 3 3 Flammability 0 0 Physical hazards 0 Instability 0 Specific Hazard -- --

16. OTHER INFORMATION

The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-800-325-3751).

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SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX Version: 4.1 E12089244

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Ashland Regulatory Information Number 1-800-325-3751 P.O. Box 2219 Telephone 614-790-3333 Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-800-274-5263)

Product name Eagle One™ WAX-AS-U-DRY® SPRAY WAX

Product code E12089244

2. HAZARDS IDENTIFICATION

Emergency Overview

Appearance: liquid, white

CAUTION! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. PROLONGED OR REPEATED CONTACT MAY DRY THE SKIN AND CAUSE IRRITATION AND BURNS.

Potential Health Effects

Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion

Eye contact May cause mild eye irritation. Symptoms include stinging, tearing, and redness.

Skin contact May cause slight skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may include redness, burning, and drying and cracking of skin, skin burns, and other skin damage.

Ingestion Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful.

Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. Symptoms are not expected at air concentrations below the recommended exposure limits, if applicable (see Section 8.).

Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, Skin

Symptoms

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SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX Version: 4.1 E12089244

Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness)

Target Organs Exposure to this material (or a component) has been found to cause kidney damage in male rats. The mechanism by which this toxicity occurs is specific to the male rat and the kidney effects are not expected to occur in humans.

Carcinogenicity This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA).This product (or a component) is a petroleum-derived material. Similar materials and certain compounds occurring naturally in petroleum oils have been shown to cause skin cancer in laboratory animals following repeated exposure without washing or removal.

Reproductive hazard There are no data available for assessing risk to the fetus from maternal exposure to this material.

Other information When heated to temperatures above 150 degrees C in the presence of air, this product can form formaldehyde vapors. Formaldehyde has been identified as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) and the Occupational Safety and Health Administration (OSHA). Formaldehyde is irritating to the eyes, nose, throat, and airways, and in rare cases, can cause an allergic reaction (causes narrowing of the air passages of the lungs, sweating, flushing, hives, rapid heart rate, and lowered blood pressure). In addition, formaldehyde can cause an allergic skin reaction (delayed skin rash which may be followed by blistering, scaling and other skin effects). It is harmful if inhaled, swallowed or absorbed through skin.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Components CAS-No. / Trade Secret Concentration No. SOLVENT NAPHTHA (PETROLEUM), HEAVY 64742-96-7 >=5-<10% ALIPHATIC DIMETHYL SILICONES AND SILOXANES 63148-62-9 >=1.5-<5%

4. FIRST AID MEASURES

Eyes If symptoms develop, move individual away from exposure and into fresh air. Flush eyes gently with water while holding eyelids apart. If symptoms persist or there is any visual difficulty, seek medical attention.

Skin

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Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse.

Inhalation If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention.

Notes to physician Hazards: No information available. Treatment: No information available.

5. FIREFIGHTING MEASURES

Suitable extinguishing media Dry chemical, Carbon dioxide (CO2), Water spray

Hazardous combustion products Aldehydes, carbon dioxide and carbon monoxide, Hydrocarbons, formaldehyde, Hydrogen, silicon oxides

NFPA Flammable and Combustible Liquids Classification not applicable

6. ACCIDENTAL RELEASE MEASURES

Personal precautions For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed.

Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system.

Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

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SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX Version: 4.1 E12089244

Other information Comply with all applicable federal, state, and local regulations.

7. HANDLING AND STORAGE

Storage Store in a cool, dry, ventilated area.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines Contains no substances with occupational exposure limit values. General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities.

Exposure controls General room ventilation should be adequate for normal conditions of use. However, if unusual operating conditions exist, provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects.

Eye protection Not required under normal conditions of use. Wear splash-proof safety goggles if material could be misted or splashed into eyes.

Skin and body protection Wear resistant gloves (consult your safety equipment supplier).

Respiratory protection Respiratory protection is not required under normal conditions of use.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state liquid Colour white Boiling point/boiling range 212 °F / 100 °C @ 1,013.33 hPa Calculated Phase Transition Liquid/Gas pH 7 - 8

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Flash point not applicable Lower explosion limit/Upper explosion limit 0.6 %(V) / 7 %(V) Calculated Explosive Limit Vapour pressure 23.333 hPa @ 68 °F / 20 °C Calculated Vapor Pressure

10. STABILITY AND REACTIVITY

Stability Stable.

Conditions to avoid None known.

Incompatible products Strong oxidizing agents, strong reducing agents

Hazardous decomposition products Aldehydes, carbon dioxide and carbon monoxide, Hydrocarbons, formaldehyde-like, Hydrogen, silicon oxides

Hazardous reactions Product will not undergo hazardous polymerization.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Inhalation exposure Skin absorption Skin contact Eye Contact Ingestion Product Acute oral toxicity : no data available

Acute inhalation toxicity : no data available

Acute dermal toxicity : no data available

Skin corrosion/irritation : no data available

Serious eye damage/eye : no data available

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irritation Respiratory or skin sensitisation : no data available

Target Organ Systemic Toxicant : Target Organs: Exposure to this material (or a component) has - Repeated exposure been found to cause kidney damage in male rats. The mechanism by which this toxicity occurs is specific to the male rat and the kidney effects are not expected to occur in humans.

Components: SOLVENT NAPHTHA (PETROLEUM), HEAVY ALIPHATIC: Acute oral toxicity : LD 50 Rat: > 5 g/kg Information given is based on data obtained from similar substances.

Acute inhalation toxicity : LC 50 Rat: > 5 mg/l Exposure time: 4 h Information given is based on data obtained from similar substances.

Acute dermal toxicity : LD 50 Rat: > 2,000 mg/kg Information given is based on data obtained from similar substances.

Aspiration toxicity : May be fatal if swallowed and enters airways.

DIMETHYL SILICONES AND SILOXANES: Acute oral toxicity : LD 50 Rat: > 5 g/kg

Acute inhalation toxicity : LC 50 Rat: > 695 mg/m3 Exposure time: 4 h Method: OECD Test Guideline 403

Acute dermal toxicity : LD 50 Rabbit: > 2,000 mg/kg

Respiratory or skin sensitisation : Classification: Did not cause sensitisation on laboratory animals.

Germ cell mutagenicity Genotoxicity in vitro : In vitro tests did not show mutagenic effects Carcinogenicity : see user defined free text

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SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX Version: 4.1 E12089244

Repeated dose toxicity : Note: No adverse effect has been observed in chronic toxicity tests.

12. ECOLOGICAL INFORMATION

Ecotoxicity Product: no data available

Components: no data available

Persistence and degradability Product: no data available

Components:

DIMETHYL SILICONES AND SILOXANES: Biodegradability : Not readily biodegradable.

Bioaccumulative potential Product: no data available

Components: no data available

Mobility in soil Product: no data available

Components:

DIMETHYL SILICONES AND SILOXANES:

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SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX Version: 4.1 E12089244

Surface tension : 20 mN/m

13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations.

14. TRANSPORT INFORMATION

REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE CLASS HAZARDS GROUP POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods

U.S. DOT - RAIL Not dangerous goods

U.S. DOT - INLAND WATERWAYS Not dangerous goods

TRANSPORT CANADA - ROAD Not dangerous goods

TRANSPORT CANADA - RAIL Not dangerous goods

TRANSPORT CANADA - INLAND WATERWAYS Not dangerous goods

INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods

INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods

INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods

MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID

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SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX Version: 4.1 E12089244

15. REGULATORY INFORMATION

California Prop. 65 WARNING! This product contains a chemical known to the State of DIETHANOLAMINE California to cause cancer. FORMALDEHYDE ACETALDEHYDE

SARA Hazard Classification SARA 311/312 Classification Acute Health Hazard

SARA 313 Component(s) SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. New Jersey RTK Label Information WATER 7732-18-5 SOLVENT NAPHTHA (PETROLEUM), HEAVY ALIPHATIC 64742-96-7 DIMETHYL SILICONES AND SILOXANES 63148-62-9

Pennsylvania RTK Label Information WATER 7732-18-5 SOLVENT NAPHTHA (PETROLEUM), HEAVY ALIPHATIC 64742-96-7 DIMETHYL SILICONES AND SILOXANES 63148-62-9

Notification status US. Toxic Substances Control Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). Domestic y (positive listing) Substances List (DSL). (Can. Gaz. Part II, Vol. 133) Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing) Japan. ENCS - Existing and New Chemical Substances Inventory n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Philippines. The Toxic Substances and Hazardous and Nuclear y (positive listing) Waste Control Act China. Inventory of Existing Chemical Substances y (positive listing)

Reportable quantity - Product US. EPA CERCLA Hazardous Substances (40 CFR 302) 666666 lbs

Reportable quantity-Components DIETHANOLAMINE 111-42-2 100 lbs

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SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX Version: 4.1 E12089244

HMIS NFPA Health 1 1 Flammability 1 1 Physical hazards 0 Instability 0 Specific Hazard -- --

16. OTHER INFORMATION

List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization” IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level

CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act

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SAFETY DATA SHEET Revision Date: 06/22/2013 Print Date: 8/19/2014 MSDS Number: 000000109636 Eagle One™ WAX-AS-U-DRY® SPRAY WAX Version: 4.1 E12089244

DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System

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Page 83 of 262 Page 84 of 262 Page 85 of 262 Page 86 of 262 Page 87 of 262 SAFETY DATA SHEET

Revision Date 15-May-2015 Version 1

1. IDENTIFICATION

Product identifier Product Name FAST ORANGE SMOOTH LOTION WITH BRUSH 15 FL.OZ

Other means of identification Product Code 23113 Synonyms None

Recommended use of the chemical and restrictions on use Recommended Use Hand Cleaner or Soap - Heavy Duty Uses advised against No information available

Details of the supplier of the safety data sheet Manufacturer Address Distributor ITW Permatex ITW Permatex Canada 10 Columbus Blvd. 35 Brownridge Road, Unit 1 Hartford, CT 06106 USA Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994

Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453

E-mail address [email protected]

2. HAZARDS IDENTIFICATION

Classification

OSHA Regulatory Status This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Label elements

Emergency Overview

Appearance White Physical state Lotion Odor Citrus

Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) Not applicable

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Other Information Harmful to aquatic life. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons.

Unknown acute toxicity 6.4155% of the mixture consists of ingredient(s) of unknown toxicity

3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s)

Chemical Name CAS No Weight-% Trade Secret WATER 7732-18-5 60 - 100 * ETHOXYLATED C11-C16 ALCOHOL 127036-24-2 1 - 5 * D-LIMONENE 5989-27-5 0.1 - 1 * *The exact percentage (concentration) of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

Description of first aid measures

General advice Get medical advice/attention if you feel unwell.

Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Skin contact None under normal use conditions.

Inhalation None under normal use conditions.

Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician.

Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.

Most important symptoms and effects, both acute and delayed

Symptoms See section 2 for more information.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam

Unsuitable extinguishing media None.

Specific hazards arising from the chemical None in particular.

Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None.

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Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with eyes.

Environmental precautions

Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological Information.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep from freezing.

Incompatible materials None known

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines . Appropriate engineering controls

Engineering Controls Eyewash stations

Individual protection measures, such as personal protective equipment

Eye/face protection Tight sealing safety goggles.

Skin and body protection None under normal use conditions.

Respiratory protection None under normal use conditions.

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

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Information on basic physical and chemical properties

Physical state Lotion Appearance White Odor Citrus Odor threshold No information available

Property Values Remarks • Method pH 6.0-8.0 Melting point / freezing point No information available Boiling point / boiling range > 100 °C / 212 °F Flash point > 95 °C / > 203 °F Evaporation rate < 1 Butyl acetate = 1 Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density >1 Air = 1 Relative density 0.96 Water solubility Soluble in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Explosive properties No information available Oxidizing properties No information available

Other Information

Softening point No information available Molecular weight No information available VOC Content (%) <1 Density No information available Bulk density No information available

10. STABILITY AND REACTIVITY

Reactivity No data available

Chemical stability Stable under recommended storage conditions.

Possibility of Hazardous Reactions None under normal processing.

Conditions to avoid Excessive heat.

Incompatible materials None known

Hazardous Decomposition Products Carbon oxides

11. TOXICOLOGICAL INFORMATION

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Information on likely routes of exposure

Inhalation None known.

Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes.

Skin contact Repeated or prolonged skin contact may cause allergic reactions with susceptible persons.

Ingestion Ingestion may cause irritation to mucous membranes.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 WATER > 90 mL/kg ( Rat ) - - 7732-18-5 D-LIMONENE = 4400 mg/kg ( Rat ) > 5 g/kg ( Rabbit ) - 5989-27-5

Information on toxicological effects

Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA D-LIMONENE - Group 2A - X 5989-27-5 IARC (International Agency for Research on Cancer) Group 2A - Probably Carcinogenic to Humans Not classifiable as a human carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present

The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 405680 mg/kg ATEmix (dermal) 461460 mg/kg

12. ECOLOGICAL INFORMATION

Ecotoxicity

6.4372% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea D-LIMONENE - 35: 96 h Oncorhynchus mykiss - 5989-27-5 mg/L LC50 0.619 - 0.796: 96 h Pimephales promelas mg/L LC50 flow-through

Persistence and degradability No information available.

Bioaccumulation No information available.

Mobility No information available.

Other adverse effects No information available

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13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated packaging Do not reuse container.

US EPA Waste Number Not applicable

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous Waste Status D-LIMONENE Toxic 5989-27-5

14. TRANSPORT INFORMATION

DOT Proper shipping name: Not regulated

IATA Proper shipping name: Not regulated

IMDG Proper shipping name: Not regulated

15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed. ENCS Not Listed. IECSC Complies KECL Not Listed. PICCS Complies AICS Complies

Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

US Federal Regulations

SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories Acute health hazard Yes ______

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Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No

CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material

US State Regulations

California Proposition 65 This product does not contain any Proposition 65 chemicals

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania LANOLIN - - X 8006-54-0 U.S. EPA Label Information EPA Pesticide Registration Number Not applicable

NFPA Health hazards 1 Flammability 1 Instability 0 - HMIS Health hazards 1 Flammability 1 Physical hazards 0 Personal protection B

NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System)

Revision Date 15-May-2015

Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

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Page 94 of 262 SAFETY DATA SHEET

1. Identification Product number 1000008356 Product identifier GERMICIDAL CLEANER Revision date 03-23-2015 Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-630-543-7600 Emergency telephone US 1-866-836-8855 Emergency telephone outside 1-952-852-4646 US Version # 04 Supersedes date 03-05-2015 Recommended use Cleaner Recommended restrictions None known.

2. Hazard(s) identification

Physical hazards Flammable aerosols Category 1 Health hazards Serious eye damage/eye irritation Category 2 Environmental hazards Not classified. OSHA defined hazards Not classified.

Label elements

Signal word Danger Hazard statement Extremely flammable aerosol. Causes serious eye irritation. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Wear eye/face protection. Response If swallowed: Rinse mouth. Do NOT induce vomiting. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Not available. Hazard(s) not otherwise None known. classified (HNOC)

Supplemental information None.

3. Composition/information on ingredients

Mixtures

Chemical name Common name and synon yms CAS number %

2-Butoxyethanol 111-76-2 2.5 - 10

Butane 106-97-8 1 - 2.5

EDTA Tertrasodium Salt 64-02-8 1 - 2.5 Other components below reportable levels 90 - 100

Product name: GERMICIDAL CLEANER SDS US Product #: 1000008356 Version #: 04 Revision date: 03-23-2015 Issue date: 07-28-2014 1 / 9 Page 95 of 262 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if symptoms occur. Most important Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred symptoms/effects, acute and vision. delayed Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation. medical attention and special Symptoms may be delayed. treatment needed General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

5. Fire-fighting measures Suitable extinguishing media Water. Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from Contents under pressure. Pressurized container may explode when exposed to heat or flame. the chemical Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with and precautions for firefighters face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting Move containers from fire area if you can do so without risk. Containers should be cooled with equipment/instructions water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol.

6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch emergency procedures damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no containment and cleaning up smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, Level 1 Aerosol. including any incompatibilities Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS).

Product name: GERMICIDAL CLEANER SDS US Product #: 1000008356 Version #: 04 Revision date: 03-23-2015 Issue date: 07-28-2014 2 / 9 Page 96 of 262

8. Exposure controls/personal protection

Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value

2-Butoxyethanol (CAS PEL 240 mg/m3 111-76-2) 50 ppm

US. ACGIH Threshold Limit Values Components Type Value

2-Butoxyethanol (CAS TWA 20 ppm 111-76-2) Butane (CAS 106-97-8) STEL 1000 ppm

US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value

2-Butoxyethanol (CAS TWA 24 mg/m3 111-76-2) 5 ppm Butane (CAS 106-97-8) TWA 1900 mg/m3 800 ppm

Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time

2-Butoxyethanol (CAS 200 mg/g Butoxyacetic Creatinine in * 111-76-2) acid (BAA), urine with hydrolysis * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles).

Hand protection Wear appropriate chemical resistant gloves. Skin protection Other Wear suitable protective clothing. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene When using do not smoke. Always observe good personal hygiene measures, such as washing considerations after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

Product name: GERMICIDAL CLEANER SDS US Product #: 1000008356 Version #: 04 Revision date: 03-23-2015 Issue date: 07-28-2014 3 / 9 Page 97 of 262 9. Physical and chemical properties Appearance Physical state Gas. Form Aerosol. Color Not available. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling 212 °F (100 °C) estimated range Flash point -156.0 °F (-104.4 °C) Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available.

(%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 55 - 75 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 0.979 estimated

10. Stability and reactivity Reactivity Reacts violently with strong acids. This product may react with oxidizing agents. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Avoid temperatures exceeding the flash point. Do not mix with other chemicals. Contact with incompatible materials. Incompatible materials Acids. Oxidizing agents. Hazardous decomposition No hazardous decomposition products are known. products

11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful.

Skin contact 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans.

Eye contact Causes serious eye irritation.

Product name: GERMICIDAL CLEANER SDS US Product #: 1000008356 Version #: 04 Revision date: 03-23-2015 Issue date: 07-28-2014 4 / 9 Page 98 of 262 Symptoms related to the Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred physical, chemical and vision. toxicological characteristics Information on toxicological effects

Acute toxicity Harmful if inhaled. Harmful if swallowed. Components Species Test Results 2-Butoxyethanol (CAS 111-76-2)

Acute Dermal LD50 Guinea pig 230 ml/kg, 24 Hours

7.3 ml/kg, 4 Days

Rabbit 450 ml/kg, 24 Hours

435 mg/kg, 24 Hours

0.63 ml/kg

Rat > 2000 mg/kg, 24 Hours

Inhalation LC50 Rabbit 400 ppm, 7 Hours

Rat 450 ppm, 4 Hours Oral LD100 Rabbit 695 mg/kg

LD50 Dog > 695 mg/kg

Guinea pig 1200 mg/kg

Rat 530 - 2800 mg/kg

Butane (CAS 106-97-8) Acute Inhalation LC50 Mouse 1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

EDTA Tertrasodium Salt (CAS 64-02-8) Acute Oral LD50 Rat 1658 mg/kg

* Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin burns. Serious eye damage/eye Causes eye burns. Risk of serious damage to eyes. irritation Respiratory or skin sensitization Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - Not classified. single exposure

Product name: GERMICIDAL CLEANER SDS US Product #: 1000008356 Version #: 04 Revision date: 03-23-2015 Issue date: 07-28-2014 5 / 9 Page 99 of 262 Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin.

2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans.

12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Test Results 2-Butoxyethanol (CAS 111-76-2) Aquatic Fish LC50 Inland silverside (Menidia beryllina) 1250 mg/l, 96 hours

EDTA Tertrasodium Salt (CAS 64-02-8) Aquatic Algae IC50 Algae 1.01 mg/L, 72 Hours

Fish LC50 Bluegill (Lepomis macrochirus) 472 - 500 mg/l, 96 hours

13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers.

14. Transport information

DOT UN number UN1950 UN proper shipping name Aerosols Transport hazard class(es) Class 2.2 Subsidiary risk - Label(s) 2.2 Packing group Not applicable. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging exceptions 306 Packaging non bulk None Packaging bulk None

Product name: GERMICIDAL CLEANER SDS US Product #: 1000008356 Version #: 04 Revision date: 03-23-2015 Issue date: 07-28-2014 6 / 9 Page 100 of 262 This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN number UN1950 UN proper shipping name Aerosols, non-flammable Transport hazard class(es) Class 2.2 Subsidiary risk - Label(s) Packing 2.2 group Environmental Not applicable. hazards ERG Code Yes 2L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Other information Passenger and cargo Allowed. aircraft Cargo aircraft only Allowed. Packaging Exceptions LTD QTY IMDG UN number UN1950 UN proper shipping name AEROSOLS Transport hazard class(es) Class 2.2 Subsidiary risk - Label(s) Packing 2.2 group Environmental Not applicable. hazards Marine pollutant Yes EmS Not available. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging Exceptions LTD QTY Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code DOT

IATA; IMDG

Product name: GERMICIDAL CLEANER SDS US Product #: 1000008356 Version #: 04 Revision date: 03-23-2015 Issue date: 07-28-2014 7 / 9 Page 101 of 262 Marine pollutant

15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Chemical name CAS number Reportable Threshold Threshold Threshold quantity planning quantity planning quantity, planning quantity, lower value upper value Anhydrous Ammonia 7664-41-7 100 500 lbs Hydrogen Peroxide 7722-84-1 1000 1000 lbs SARA 311/312 Hazardous No chemical

SARA 313 (TRI repo rting ) Not regulated.

Product name: GERMICIDAL CLEANER SDS US Product #: 1000008356 Version #: 04 Revision date: 03-23-2015 Issue date: 07-28-2014 8 / 9 Page 102 of 262 US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no )* Australia Australian Inventory of Chemical Substances (AICS) No Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical No

Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances No (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision Issue date 07-28-2014 Revision date 03-23-2015 Version # 04

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision Information Product and Company Identification: Alternate Trade Names

Product name: GERMICIDAL CLEANER SDS US Product #: 1000008356 Version #: 04 Revision date: 03-23-2015 Issue date: 07-28-2014 9 / 9 Page 103 of 262 SAFETY DATA SHEET

1. Identification Product number 1000006753 Product identifier GLEME GLASS CLEANER Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-630-543-7600 Emergency telephone US 1-866-836-8855 Emergency telephone outside 1-952-852-4646 US Version # 01 Recommended use cleaner Recommended restrictions None known. 2. Hazard(s) identification Physical hazards Gases under pressure Liquefied gas Health hazards Not classified. Environmental hazards Not classified. OSHA defined hazards Not classified. Label elements

Signal word Warning Hazard statement Contains gas under pressure; may explode if heated. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Protect from sunlight. Store in a well-ventilated place. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information None. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % 2-Butoxyethanol 111-76-2 2.5 - 10 Ethyl Alcohol 64-17-5 2.5 - 10 Butane 106-97-8 1 - 2.5 Propane 74-98-6 1 - 2.5 Other components below reportable levels 90 - 100 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Get medical attention if symptoms persist.

Product name: GLEME GLASS CLEANER SDS US Product #: 1000006753 Version #: 01 Issue date: 05-26-2015 1 / 10 Page 104 of 262 Skin contact Get medical attention if irritation develops and persists. Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Most important Direct contact with eyes may cause temporary irritation. symptoms/effects, acute and delayed Indication of immediate Provide general supportive measures and treat symptomatically. medical attention and special treatment needed General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from Contents under pressure. During fire, gases hazardous to health may be formed. the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire-fighting In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed equipment/instructions to heat. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Emergency emergency procedures personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. See Section 8 of the SDS for Personal Protective Equipment. For personal protection, see section 8 of the SDS. Methods and materials for Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no containment and cleaning up smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Ground and bond containers when transferring material. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, Level 1 Aerosol. including any incompatibilities Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Keep containers tightly closed in a dry, cool and well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS).

Product name: GLEME GLASS CLEANER SDS US Product #: 1000006753 Version #: 01 Issue date: 05-26-2015 2 / 10 Page 105 of 262 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value 2-Butoxyethanol (CAS PEL 240 mg/m3 111-76-2) 50 ppm Ethyl Alcohol (CAS 64-17-5) PEL 1900 mg/m3 1000 ppm Propane (CAS 74-98-6) PEL 1800 mg/m3 1000 ppm US. ACGIH Threshold Limit Values Components Type Value 2-Butoxyethanol (CAS TWA 20 ppm 111-76-2) Butane (CAS 106-97-8) STEL 1000 ppm Ethyl Alcohol (CAS 64-17-5) STEL 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 2-Butoxyethanol (CAS TWA 24 mg/m3 111-76-2) 5 ppm Butane (CAS 106-97-8) TWA 1900 mg/m3 800 ppm Ethyl Alcohol (CAS 64-17-5) TWA 1900 mg/m3 1000 ppm Propane (CAS 74-98-6) TWA 1800 mg/m3 1000 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time

2-Butoxyethanol (CAS 200 mg/g Butoxyacetic Creatinine in * 111-76-2) acid (BAA), urine with hydrolysis * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection If contact is likely, safety glasses with side shields are recommended. Hand protection For prolonged or repeated skin contact use suitable protective gloves. Skin protection Other Wear suitable protective clothing.

Product name: GLEME GLASS CLEANER SDS US Product #: 1000006753 Version #: 01 Issue date: 05-26-2015 3 / 10 Page 106 of 262 Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene When using do not smoke. Always observe good personal hygiene measures, such as washing considerations after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Clear. Physical state Gas. Form Aerosol. Liquefied gas. Color Light yellow. Odor Characteristic. Odor threshold Not available. pH 9.1 - 10.1 estimated Melting point/freezing point Not available. Initial boiling point and boiling 212 °F (100 °C) estimated range Flash point -156.0 °F (-104.4 °C) Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 80 - 100 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Aerosol spray enclosed space Deflagration density > 2.52 g/cm3 Tested Aerosol spray ignition < 15 cm Tested estimated distance Specific gravity 0.977 - 0.997 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous No dangerous reaction known under conditions of normal use. Hazardous polymerization does not reactions occur. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Product name: GLEME GLASS CLEANER SDS US Product #: 1000006753 Version #: 01 Issue date: 05-26-2015 4 / 10 Page 107 of 262 Incompatible materials Strong oxidizing agents. Hazardous decomposition No hazardous decomposition products are known. products 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected.

2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans.

Eye contact Direct contact with eyes may cause temporary irritation. Symptoms related to the Direct contact with eyes may cause temporary irritation. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity May be harmful if swallowed. May be harmful in contact with skin. May be harmful if inhaled. Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Components Species Test Results 2-Butoxyethanol (CAS 111-76-2) Acute Dermal LD50 Guinea pig 230 ml/kg, 24 Hours 7.3 ml/kg, 4 Days Rabbit 450 ml/kg, 24 Hours 435 mg/kg, 24 Hours 0.63 ml/kg Rat > 2000 mg/kg, 24 Hours Inhalation LC50 Rabbit 400 ppm, 7 Hours Rat 450 ppm, 4 Hours Oral LD100 Rabbit 695 mg/kg LD50 Dog > 695 mg/kg Guinea pig 1200 mg/kg Rat 530 - 2800 mg/kg Butane (CAS 106-97-8) Acute Inhalation LC50 Mouse 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l Ethyl Alcohol (CAS 64-17-5) Acute Inhalation LC50 Cat 85.41 mg/l, 4.5 Hours 43.68 mg/l, 6 Hours Mouse > 60000 ppm 79.43 mg/l, 134 Minutes Rat > 115.9 mg/l, 4 Hours

Product name: GLEME GLASS CLEANER SDS US Product #: 1000006753 Version #: 01 Issue date: 05-26-2015 5 / 10 Page 108 of 262 Components Species Test Results 51.3 mg/l, 6 Hours Oral LD50 Monkey 6000 mg/kg Mouse 10500 ml/kg Rat 1187 - 2769 mg/kg 7800 ml/kg Propane (CAS 74-98-6) Acute Inhalation LC50 Mouse 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l 658 mg/l/4h

* Estimates for product may be based on additional component data not shown. Skin corrosion/irritation May be irritating to the skin. Prolonged skin contact may cause temporary irritation. Serious eye damage/eye Direct contact with eyes may cause temporary irritation. May be irritating to eyes. irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - Not classified. single exposure Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard Not an aspiration hazard. Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin.

2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans.

12. Ecological information Ecotoxicity Harmful to aquatic life. Product Species Test Results GLEME GLASS CLEANER (CAS Mixture) Aquatic Crustacea EC50 Daphnia 13838.1602 mg/l, 48 hours estimated Components Species Test Results 2-Butoxyethanol (CAS 111-76-2) Aquatic Fish LC50 Inland silverside (Menidia beryllina) 1250 mg/l, 96 hours

Product name: GLEME GLASS CLEANER SDS US Product #: 1000006753 Version #: 01 Issue date: 05-26-2015 6 / 10 Page 109 of 262 Components Species Test Results Ethyl Alcohol (CAS 64-17-5) Aquatic Crustacea EC50 Water flea (Daphnia magna) 7700 - 11200 mg/l, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) > 100.1 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Ethyl Alcohol -0.31 Propane 2.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN number UN1950 UN proper shipping name Aerosols Transport hazard class(es) Class 2.2 Subsidiary risk - Label(s) 2.2 Packing group Not applicable. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging exceptions 306 Packaging non bulk None Packaging bulk None This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN number UN1950 UN proper shipping name Aerosols, non-flammable Transport hazard class(es) Class 2.2 Subsidiary risk - Label(s) 2.2 Packing group Not applicable. Environmental hazards No. ERG Code 2L Special precautions for user Read safety instructions, SDS and emergency procedures before handling.

Product name: GLEME GLASS CLEANER SDS US Product #: 1000006753 Version #: 01 Issue date: 05-26-2015 7 / 10 Page 110 of 262 Other information Passenger and cargo Allowed. aircraft Cargo aircraft only Allowed. Packaging Exceptions LTD QTY IMDG UN number UN1950 UN proper shipping name AEROSOLS Transport hazard class(es) Class 2.2 Subsidiary risk - Label(s) 2.2 Packing group Not applicable. Environmental hazards Marine pollutant No. EmS Not available. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging Exceptions LTD QTY Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code DOT

IATA; IMDG

Product name: GLEME GLASS CLEANER SDS US Product #: 1000006753 Version #: 01 Issue date: 05-26-2015 8 / 10 Page 111 of 262 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated.

Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act Not regulated. (SDWA) US state regulations US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. Pennsylvania Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. Rhode Island RTK Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Yes Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances No (PICCS)

Product name: GLEME GLASS CLEANER SDS US Product #: 1000006753 Version #: 01 Issue date: 05-26-2015 9 / 10 Page 112 of 262 Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 05-26-2015 Version # 01 References EPA: AQUIRE database NLM: Hazardous Substances Data Base US. IARC Monographs on Occupational Exposures to Chemical Agents Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Product name: GLEME GLASS CLEANER SDS US Product #: 1000006753 Version #: 01 Issue date: 05-26-2015 10 / 10 Page 113 of 262 Safety Data Sheet Spartan Chemical Company, Inc.

Revision Date: 04-May-2015

1. PRODUCT AND COMPANY IDENTIFICATION

Product Identifier Product Name: GS RESTROOM CLEANER Product Number: 3503 , 3533 Recommended Use: Disinfectant Uses Advised Against: For Industrial and Institutional Use Only

Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA 800-537-8990 (Business hours) www.spartanchemical.com

24 Hour Emergency Phone Numbers: Medical Emergency/Information: 888-314-6171 Transportation/Spill/Leak: CHEMTREC 800-424-9300

2. HAZARDS IDENTIFICATION

GHS Classification Serious Eye Damage/Eye Irritation: Category 2A

GHS Label Elements Signal Word: Warning Symbols:

Hazard Statements: Causes serious eye irritation Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling. Wear eye / face protection Response: -Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information.

Storage: Not Applicable Disposal: Not Applicable

Hazards Not Otherwise Classified: Not Applicable

Other Information: • May be harmful if swallowed. • May cause skin irritation. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children.

0.30298% of the mixture consists of ingredient(s) of unknown toxicity.

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Page 114 of 262 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 ______3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-% water 7732-18-5 60-100 citric acid 77-92-9 5-10 alcohol ethoxylate 68439-46-3 1-5 xanthan gum 11138-66-2 0.1-1

Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

-Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or physician if you feel unwell. -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media: Product does not support combustion, Use extinguishing agent suitable for type of surrounding fire Specific Hazards Arising from the Dried product is capable of burning. Combustion products are toxic. Chemical: Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors.

Protective Equipment and Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full Precautions for Firefighters: protective gear. Cool fire-exposed containers with water spray.

6. ACCIDENTAL RELEASE MEASURES

7. HANDLING AND STORAGE

Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Storage Conditions: Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep from freezing.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits: None established.

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Page 115 of 262 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 ______Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance/Physical State: Liquid Color: Clear Odor: Bland pH: 1.5-2.5 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 100 °C / 212 °F Flash Point: > 100 °C / > 212 °F Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 1.03 Solubility(ies): Soluble in water Partition Coefficient: No information available. Autoignition Temperature: No information available. Decomposition Temperature: No information available. Viscosity: No information available.

10. STABILITY AND REACTIVITY

Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Heat, flames and sparks. Incompatible Materials: Strong oxidizing agents. Strong acids. Hazardous Decomposition May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. Products:

11. TOXICOLOGICAL INFORMATION

Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. Symptoms of Exposure: -Eye Contact: Pain, redness, swelling of the conjunctiva and blurred vision. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification.

Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 29382 mg/kg

Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

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Page 116 of 262 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 ______water > 90 mL/kg ( Rat ) Not Available Not Available 7732-18-5 citric acid = 3000 mg/kg ( Rat ) Not Available Not Available 77-92-9 alcohol ethoxylate = 1378 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) Not Available 68439-46-3

Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA.

12. ECOLOGICAL INFORMATION

Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Crustacea Microorganisms citric acid Not Available 1516: 96 h Lepomis Not Available 120: 72 h Daphnia magna 77-92-9 macrochirus mg/L LC50 mg/L EC50 static

Persistence and Degradability: No information available. Bioaccumulation: No information available.

Other Adverse Effects: No information available.

13. DISPOSAL CONSIDERATIONS

Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Dispose of in accordance with federal, state and local regulations.

14. TRANSPORT INFORMATION

DOT: Not Regulated Proper Shipping Name: Non Hazardous Product Special Provisions: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Check with a trained hazardous materials transportation expert for information specific to your situation.

15. REGULATORY INFORMATION

TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances.

SARA 313 This product does not contain listed substances above the "de minimus" level

SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No

California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 acetaldehyde - 75-07-0 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer.

EPA Pesticide Registration Number: 5741-25

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Page 117 of 262 3503 - GS RESTROOM CLEANER Revision Date: 04-May-2015 ______EPA Statement: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label: Caution. Causes moderate eye irritation. May be harmful if swallowed. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet.

16. OTHER INFORMATION

NFPA Health Hazards: 1 Flammability: 0 Instability: 0 Special: N/A HMIS Health Hazards: 1 Flammability: 0 Physical Hazards: 0

Revision Date: 04-May-2015 Reasons for Revision: No information available.

End of Safety Data Sheet

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Page 118 of 262 Page 119 of 262

HOSPECO HEALTH GARDS AIR FRESHENER VINEYARD, 7OZ.

HOSPECO HMIS NFPA Minimal 0 Insignificant Cleveland, Ohio 44143 Slight 1 Slight Moderate 2 Moderate Serious 3 High 800-321-9832 Severe 4 Extreme

March 21, 2013 NEW

HOSPECO HEALTH GARDS AIR FRESHENER VINEYARD, 7OZ.

Mixture packaged in pressurized aerosol spray can.

500 ppm 2-Propanone 67-64-1 1000 ppm 750 ppm STEL

Liquefied Petroleum Gas 68476-86-8 Unknown 1000 ppm *Section 313 Supplier Notification - Indicates hazardous ingredients which are toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372.

>100°F 0.78 – 0.81g/ml No Data

20.0% >1.00 N/A

Insoluble Water white clear liquid with a characteristic odor

Dry chemical, CO2, FLAMMABLE Alcohol-resistant N/A N/A foam Keep containers cool using water spray. Use proper equipment to protect personnel from bursting containers. Contents under pressure. Do not expose to temperatures exceeding 120° F as containers may vent, rupture or burst.

Unstable □ Heat, sparks May Occur □ ■ open flames; ■ Stable Temp. > 120°F. Will not Occur Acids, alkalis, Reducing agents, Strong oxidizing agents

CO and CO2

Page 120 of 262 SECTION 6 - HEALTH HAZARDS Routes of Entry Inhalation: Yes Eyes / Skin: Yes Ingestion: Unlikely Eye contact: Can cause eye irritation. Symptoms include stinging, tearing, redness, and swelling of eyes; Skin contact: May cause mild skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may include redness, burning, drying and cracking of skin, and skin burns. Passage of this material into the body through the skin is possible, but it is unlikely that Signs and Symptoms of this would result in harmful effects during safe handling and use. Ingestion: Swallowing small Exposure (Acute & amounts of this material during normal handling is not likely to cause harmful effects. Swallowing Chronic) large amounts may be harmful. This material can get into the lungs during swallowing or vomiting. This can result into lung inflammation and other lung injury; Inhalation: Breathing of vapor or mist is possible. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Medical Conditions Generally Aggravated Pre-existing skin and lung disorders by Exposure Chemical Listed as Carcinogen National Toxicology Yes  I.A.R.C. Yes  Yes  OSHA or Potential Carcinogen Program No  Monographs No  No  Emergency and First Aid Procedures 1. Inhalation Immediately move to fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. 2. Eyes Immediately move to fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. 3. Skin Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse. 4. Ingestion Seek medical attention. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. SECTION 7 – SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type) None required for normal use. Local Mechanical Ventilation Special Other Exhaust Maintain adequate ventilation. (General) N/A N/A N/A Protective Gloves Chemical Resistant Eye Protection Safety Glasses Other Protective Clothing or Equipment Wash hands after use. SECTION 8 – SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES WARNING: FLAMMABLE. Contents under pressure. Keep away from heat, sparks and open flames. Excessive inhalation in confined areas may cause headaches or dizziness. Intentional misuse by deliberately concentrating or inhaling the contents may Precautions to be Taken be harmful or fatal. Avoid contact with skin and eyes. Avoid contact with food and food Handling and Storage handling surfaces. Avoid contact with painted, varnished or plastic surfaces. Do not store at temperatures above 120°F. Do not puncture or incinerate containers. Keep out of reach of children. Store in accordance with NFPA 30B for Level 3 Aerosols. Other Precautions Read label cautions carefully. Follow label directions to avoid injury. Steps to be Taken in Case Absorb spill with inert material then place in a chemical waste container. Dispose of Material is Released or Spilled spill material in accordance with regulations. Waste Disposal Methods Dispose of in accordance with local, state, and federal regulations. California Safe Drinking Water and Toxic Enforcement Act of 1986: This product is not known to contain any chemicals currently listed as carcinogens or Proposition 65 reproductive toxins under California Proposition 65 at levels which would be subject to the proposition. DOT Shipping Name: Aerosols, Limited Quantity Transportation Info Hazard Class: Class 2.1(flammable gas) UN/ID Number: UN 1950 We believe all information given is accurate. It is offered in good faith, but without guarantee. Since conditions are beyond our control, user assumes all responsibility and risk. 1254354 / 9004354 / 9004117 132103

Page 121 of 262 SAFETY DATA SHEET

Spectrum Group Product Name: Hot Shot Natural Flying Insect Killer Division of United Industries Corp Phone: 1-800-971-5431 P.O. Box 142642 Items: HG-95844 St. Louis, MO 63114-0642 Formula Code: 21-1082

SDS Date: 03/11/15 Product Name: Hot Shot Natural Flying Insect Killer

SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION

CAS #: Aerosol Product Use: Flying Insect Killer Aerosol

Manufacturer: Chemsico Div. of United Industries Corp. P.O. Box 142642 St. Louis, MO 63114

SECTION 2 - HAZARDS IDENTIFICATION This product is classified according to the Globally Harmonized System (GHS).

ROUTES OF EXPOSURE

Potential short term health effects: Eyes, Skin

Eyes: Causes moderate eye irritation.

Skin: May cause skin irritation.

Inhalation: No expected reaction.

Ingestion: No expected reaction.

Target organs: Eyes, Skin

Chronic effects: Prolonged or repeated exposure can cause drying, defatting and dermatitis.

Signs and symptoms: Symptoms may include redness, edema, drying, defatting

and cracking of the skin.

SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS

Composition comments: This product is considered not hazardous under 29 CFR

1910.1200 (Hazard Communication).

NOTE: No reportable quantities of hazardous ingredients are present per OSHA 29 CFR 1910.1200. No toxic chemical(s) subject to reporting requirements of Section 313 of Title III and 40 CFR 372 are present.

ACTIVE COMPONENT CAS# PERCENTAGE Lemongrass Oil 8007-02-1 3.00% Carbon Dioxide 124-38-9 2.50%

OTHER COMPONENT CAS# PERCENTAGE Other N/A 94.50%

Note: Ingredients not identified are not hazardous.

Page 1 Page 122 of 262 SAFETY DATA SHEET

SECTION 4 - FIRST AID MEASURES

FIRST AID PROCEDURES

Eye contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses if present after the first 5 minutes then continue rinsing eye. Contact a physician for treatment advice.

Skin contact: Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum or using the toilet.

Inhalation: None required

Ingestion: None required

Note to Physician: Skin symptoms may be delayed.

General advice: If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Keep out of reach of children.

SECTION 5 - FIRE FIGHTING MEASURES

Flammable properties: Pressurized Aerosol Container.

SUITABLE EXTINGUISHING MEDIA

Extinguishing media: Water Fog, Foam, CO 2, Dry Chemical

Unsuitable extinguishing media: Not Available

SPECIFIC HAZARDS ARISING FROM THE CHEMICAL

Protection of firefighters: Not Available

Protective equipment for firefighters: Firefighters should wear full protective clothing including self-contained breathing apparatus.

Hazardous combustion products: None known

SENSITIVITY TO MECHANICAL IMPACT

Explosion data: Not Available

Sensitivity to static discharge: Not Available

Personal precautions: Keep unnecessary personnel away. Do not touch or walk through spilled material.

HMIS Ratings Health Hazard 1 Fire Hazard 0 Reactivity 0

SECTION 6 - ACCIDENTAL RELEASE MEASURES

Methods for containment: Prevent entry into waterways, sewers, basements or confined areas.

Page 2 Page 123 of 262 SAFETY DATA SHEET

Methods for cleaning up: Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with earth, sand or absorbent material swept up and placed in suitable, covered, and labeled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use.

SECTION 7 - HANDLING AND STORAGE

Handling: Use good industrial hygiene practices in handling this material.

Storage: Keep out of reach of children. Store in a closed container away from incompatible materials.

SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering controls: General ventilation normally adequate.

EYE / FACE PROTECTION

Personal protective equipment: None required

Hand protection: None required

Skin and body protection: None required

Respiratory protection: None required

General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice. When using, do not eat or drink. Wash hands before breaks and immediately after handling the product.

SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES

Appearance: Clear to hazy

Color: Yellow

Form: Aerosol

Odor: Lemongrass & Wintergreen

Odor threshold: Not Available

Physical state: Pressurized liquid

pH: 8.3

Freezing point: 32°F

Boiling point: 212°F

Flash point: 130 0F (liquid portion)

Flame Extension 0” (level 1 aerosol)

Flammability limits in air, lower, % by volume: Not Available

Page 3 Page 124 of 262 SAFETY DATA SHEET

Flammability limits in air, upper, % by volume: Not Available

Vapor pressure: Not Available

Vapor density: Not Available

Specific gravity: 0.985

Octanol/water coefficient: Not Available

Auto-ignition temperature: Not Available

SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION

Chemical stability: Stable under recommended storage conditions.

Conditions to avoid: Do not mix with other chemicals.

Incompatible materials: Avoid strong oxidizers.

Hazardous decomposition products: None known.

Possibility of hazardous reactions: Hazardous polymerization does not occur.

SECTION 11 - TOXICOLOGICAL INFORMATION

EFFECTS OF ACUTE EXPOSURE

Eye: Causes temporary eye injury.

Skin: May cause skin irritation.

Inhalation: LC 50 > 2mg/L (EPA Tox category IV)

Ingestion: LD 50 > 5000 mg/kg

Sensitization: Not a skin sensitizer.

Chronic effects/ Carcinogenicity: Not Available

Mutagenicity: Not Available

Reproductive effects: Not Available

Teratogenicity: Not Available

Ecotoxicity: Not Available

SECTION 12 - ECOLOGICAL INFORMATION

Environmental effects: Not Available

Aquatic toxicity: Not Available

Persistence / degradability: Not Available

Bioaccumulation / accumulation: Not Available

Partition coefficient: Not Available

Mobility in environmental media: Not Available

Chemical fate information: Not Available

Page 4 Page 125 of 262 SAFETY DATA SHEET

SECTION 13 - DISPOSAL CONSIDERATIONS

Waste codes: Not Available

Disposal instructions: Dispose in accordance with all applicable regulations.

Waste from residues / unused products: Not Available

Contaminated packaging: Not Available

SECTION 14 - TRANSPORTATION INFORMATION

U.S. Department of Transportation (DOT): Aerosols, Flammable, 2.1, UN-1950, Limited Quantity

U.S. Federal regulations: This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.

IATA: 1950, Aerosols, Flammable, 2.1

IMDG: 1950, Aerosols, 2.1, Limited Quantity

SECTION 15 - REGULATORY INFORMATION

29 CFR 1910.1200 hazardous chemical Occupational Safety and Health Administration (OSHA): No

CERCLA (Superfund) reportable quantity: Not Available

HAZARD CATEGORIES

Superfund Amendments and Reauthorization Act of 1986 (SARA):

Immediate Hazard No Delayed Hazard No Fire Hazard No Pressure Hazard No Reactivity Hazard No

Section 302 extremely hazardous Substance: No

Section 311 hazardous chemical: No

Clean Air Act (CAA): Not Available

Clean Water Act (CWA): Not Available

State regulations:

INVENTORY STATUS

Inventory Country(s) or region name on inventory (yes/no)*: N/A, Regulated by EPA

Page 5 Page 126 of 262 SAFETY DATA SHEET

Disclaimer: Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document.

SECTION 16 - OTHER INFORMATION

Issue date: 3/11/15

Prepared by: United Industries Corp. (800) 242-1166

Page 6 Page 127 of 262 Page 128 of 262 Page 129 of 262 Page 130 of 262 SAFETY DATA SHEET

1. Identification Product identifier Insect Repellent Other means of identification Product code 14011 Registration number EPA: 51147-13-55809 Recommended use Insect repellent Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical 800-521-3168 Assistance Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Physical hazards Flammable aerosols Category 1 Gases under pressure Liquefied gas Health hazards Acute toxicity, oral Category 4 Acute toxicity, dermal Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Sensitization, skin Category 1 Specific target organ toxicity, single exposure Category 3 narcotic effects Environmental hazards Hazardous to the aquatic environment, acute Category 2 hazard Hazardous to the aquatic environment, Category 3 long-term hazard OSHA defined hazards Not classified. Label elements

Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause drowsiness or dizziness. Toxic to aquatic life. Harmful to aquatic life with long lasting effects.

Material name: Insect Repellent SDS US 14011 Version #: 01 Issue date: 05-21-2015 1 / 10 Page 131 of 262 Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing. Wear eye/face protection. Avoid release to the environment. Response If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise Static accumulating flammable liquid can become electrostatically charged even in bonded and classified (HNOC) grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. Supplemental information 32.11% of the mixture consists of component(s) of unknown acute oral toxicity. 32.11% of the mixture consists of component(s) of unknown acute dermal toxicity. 72.39% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Isopropyl alcohol 67-63-0 30 - 40 N,N-Diethyl-m-toluamide (DEET) 134-62-3 25.1 Liquefied Petroleum Gas 68476-86-8 20 - 30 Dicarboximide 113-48-4 5 - 10 Dipropyl isocinchomeronate 136-45-8 2.5 Acetone 67-64-1 1 - 3 Propylene glycol 57-55-6 1 - 3 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical advice/attention if you feel unwell. Most important May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. symptoms/effects, acute and Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May delayed cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim medical attention and special under observation. Symptoms may be delayed. treatment needed General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse.

Material name: Insect Repellent SDS US 14011 Version #: 01 Issue date: 05-21-2015 2 / 10 Page 132 of 262 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This the chemical product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with and precautions for firefighters face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without equipment/instructions risk. Containers should be cooled with water to prevent vapor pressure build up. General fire hazards Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of protective equipment and low areas. Remove all possible sources of ignition in the surrounding area. Many vapors are emergency procedures heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep containment and cleaning up combustibles (wood, paper, oil, etc.) away from spilled material. The product is immiscible with water and will spread on the water surface. Stop the flow of material, if this is without risk. Prevent product from entering drains. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination. 7. Handling and storage Precautions for safe handling Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. When using, do not eat, drink or smoke. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. Wash contaminated clothing before reuse. For product usage instructions, please see the product label. Conditions for safe storage, Level 3 Aerosol. including any incompatibilities Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS).

Material name: Insect Repellent SDS US 14011 Version #: 01 Issue date: 05-21-2015 3 / 10 Page 133 of 262 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Acetone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Isopropyl alcohol (CAS PEL 980 mg/m3 67-63-0) 400 ppm US. ACGIH Threshold Limit Values Components Type Value Acetone (CAS 67-64-1) STEL 750 ppm TWA 500 ppm Isopropyl alcohol (CAS STEL 400 ppm 67-63-0) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Acetone (CAS 67-64-1) TWA 590 mg/m3 250 ppm Isopropyl alcohol (CAS STEL 1225 mg/m3 67-63-0) 500 ppm TWA 980 mg/m3 400 ppm US. AIHA Workplace Environmental Exposure Level (WEEL) Guides Components Type Value Form Propylene glycol (CAS TWA 10 mg/m3 Aerosol. 57-55-6) Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time

Acetone (CAS 67-64-1) 50 mg/l Acetone Urine * Isopropyl alcohol (CAS 40 mg/l Acetone Urine * 67-63-0) * - For sampling details, please see the source document. Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves such as: Nitrile. Viton®. Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene When using do not smoke. Keep away from food and drink. Always observe good personal considerations hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace.

Material name: Insect Repellent SDS US 14011 Version #: 01 Issue date: 05-21-2015 4 / 10 Page 134 of 262 9. Physical and chemical properties Appearance Physical state Liquid. Form Aerosol. Color Clear. Colorless. Odor Mild. Alcoholic. Odor threshold Not available. pH Not available. Melting point/freezing point -138.5 °F (-94.7 °C) estimated Initial boiling point and boiling 132.9 °F (56.1 °C) estimated range Flash point 75 °F (23.9 °C) Tag Closed Cup Evaporation rate Moderate. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower 2 % estimated (%) Flammability limit - upper 12.8 % estimated (%) Vapor pressure 1234.3 hPa estimated Vapor density > 1 (air = 1) Relative density 0.8 estimated Solubility (water) Immiscible. Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature 700 °F (371.1 °C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 67.3 % estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions Conditions to avoid Heat, flames and sparks. Contact with incompatible materials. Incompatible materials Acids. Strong oxidizing agents. Isocyanates. Chlorine. Hazardous decomposition Carbon oxides. Nitrogen oxides (NOx). products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Skin contact Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Eye contact Causes serious eye irritation. Ingestion Harmful if swallowed. Symptoms related to the Headache. May cause drowsiness and dizziness. Nausea, vomiting. Severe eye irritation. physical, chemical and Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May toxicological characteristics cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Information on toxicological effects Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and central nervous system effects. Harmful in contact with skin. Harmful if swallowed. Narcotic effects. May cause an allergic skin reaction.

Material name: Insect Repellent SDS US 14011 Version #: 01 Issue date: 05-21-2015 5 / 10 Page 135 of 262 Product Species Test Results Insect Repellent Acute Dermal LD50 Rabbit 1380 mg/kg estimated Inhalation LC50 Rat 40990 ppm, 4 hours estimated 12 mg/l, 4 Hours estimated Oral LD50 Rat 1737 mg/kg estimated TDL0 Human 117 g/kg estimated

* Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye Causes serious eye irritation. irritation Respiratory sensitization Not a respiratory sensitizer. Skin sensitization May cause an allergic skin reaction. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - May cause drowsiness and dizziness. single exposure Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard Not an aspiration hazard. 12. Ecological information Ecotoxicity Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Product Species Test Results Insect Repellent Aquatic Acute Crustacea EC50 Daphnia 171.4605 ppm, 48 hours estimated Fish LC50 Fish 218.1529 ppm, 96 hours estimated Components Species Test Results Acetone (CAS 67-64-1) Aquatic Crustacea EC50 Water flea (Daphnia magna) 10294 - 17704 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout 4740 - 6330 mg/l, 96 hours (Oncorhynchus mykiss) Isopropyl alcohol (CAS 67-63-0) Aquatic Acute Crustacea EC50 Water flea (Daphnia magna) 7550 - 13299 mg/l, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) 3200 mg/l, 96 hours N,N-Diethyl-m-toluamide (DEET) (CAS 134-62-3) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 106 - 114 mg/l, 96 hours

Material name: Insect Repellent SDS US 14011 Version #: 01 Issue date: 05-21-2015 6 / 10 Page 136 of 262 Components Species Test Results Propylene glycol (CAS 57-55-6) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 710 mg/l, 96 hours Acute Crustacea EC50 Water flea (Daphnia magna) 4850 - 34000 mg/l, 48 hours

* Estimates for product may be based on additional component data not shown. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Acetone -0.24 Isopropyl alcohol 0.05 N,N-Diethyl-m-toluamide (DEET) 2.02 Propylene glycol -0.92 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal of waste from If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or residues / unused products dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Hazardous waste code D001: Waste Flammable material with a flash point <140 F Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT UN number UN1950 UN proper shipping name Aerosols, flammable, Limited Quantity Transport hazard class(es) Class 2.1 Subsidiary risk - Label(s) 2.1 Packing group Not applicable. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Special provisions N82 Packaging exceptions 306 Packaging non bulk None Packaging bulk None IATA UN number UN1950 UN proper shipping name Aerosols, flammable, Limited Quantity Transport hazard class(es) Class 2.1 Subsidiary risk - Packing group Not applicable. Environmental hazards No. ERG Code 10L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Other information Passenger and cargo Allowed. aircraft Cargo aircraft only Allowed.

Material name: Insect Repellent SDS US 14011 Version #: 01 Issue date: 05-21-2015 7 / 10 Page 137 of 262 IMDG UN number UN1950 UN proper shipping name AEROSOLS, LIMITED QUANTITY Transport hazard class(es) Class 2 Subsidiary risk - Packing group Not applicable. Environmental hazards Marine pollutant No. EmS Not available. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 304 Emergency release notification Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Dipropyl isocinchomeronate (CAS 136-45-8) CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) Listed. CERCLA Hazardous Substances: Reportable quantity Acetone (CAS 67-64-1) 5000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Food and Drug Not regulated. Administration (FDA) US EPA Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) FIFRA Information This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. Signal word Warning. Hazard statement Harmful if swallowed. Causes substantial but temporary eye injury.

This product is registered in all 50 United States and Puerto Rico. This product is not registered outside of the United States and Puerto Rico.

Material name: Insect Repellent SDS US 14011 Version #: 01 Issue date: 05-21-2015 8 / 10 Page 138 of 262 Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 Immediate Hazard - Yes Hazard categories Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely No hazardous substance US state regulations US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Acetone (CAS 67-64-1) Dipropyl isocinchomeronate (CAS 136-45-8) Isopropyl alcohol (CAS 67-63-0) Liquefied Petroleum Gas (CAS 68476-86-8) US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Propylene glycol (CAS 57-55-6) Dipropyl isocinchomeronate (CAS 136-45-8) Isopropyl alcohol (CAS 67-63-0) US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Isopropyl alcohol (CAS 67-63-0) US. Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Isopropyl alcohol (CAS 67-63-0) Propylene glycol (CAS 57-55-6) US. Rhode Island RTK Acetone (CAS 67-64-1) Dipropyl isocinchomeronate (CAS 136-45-8) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2) Listed: February 27, 1987 Cumene (CAS 98-82-8) Listed: April 6, 2010 Dipropyl isocinchomeronate (CAS 136-45-8) Listed: May 1, 1996 Ethanal (CAS 75-07-0) Listed: April 1, 1988 US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 64.9 % 51.100(s)) Consumer products Not regulated (40 CFR 59, Subpt. C) State Consumer products This product is regulated as an Insect Repellent. This product is compliant for use in all 50 states. VOC content (CA) 64.9 % VOC content (OTC) 64.9 %

Material name: Insect Repellent SDS US 14011 Version #: 01 Issue date: 05-21-2015 9 / 10 Page 139 of 262 International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical Yes Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances No (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 05-21-2015 Prepared by Allison Cho Version # 01 Further information CRC # 926 HMIS® ratings Health: 1 Flammability: 3 Physical hazard: 0 Personal protection: B NFPA ratings Health: 1 Flammability: 3 Instability: 0 NFPA ratings 3 1 0

Disclaimer The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries.

Material name: Insect Repellent SDS US 14011 Version #: 01 Issue date: 05-21-2015 10 / 10 Page 140 of 262 SAFETY DATA SHEET

Issuing Date: 18-Feb-2015 Revision Date: 18-Feb-2015 Version 1

1. IDENTIFICATION

Product Name Ivory Original Liquid Hand Soap

Product ID: 97161377_RET_NG

Product Type: Finished Product - Consumer (Retail) Use Only

Recommended Use Personal Beauty Care Product

Manufacturer The Procter & Gamble Company Sharon Woods Innovation Center 11510 Reed Hartman Highway Cincinnati OH 45241 +1 513 626-2500

E-mail Address [email protected]

Emergency Telephone Transportation (24 HR) CHEMTREC - 1-800-424-9300 (U.S./ Canada) or 1-703-527-3887 Mexico toll free in country: 800-681-9531

2. HAZARD IDENTIFICATION

"Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumer duration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is being provided as a courtesy to help assist in the safe handling and proper use of the product.

This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:.

Eye Damage / Irritation Category 2B

Signal Word WARNING

Hazard Statements Causes eye irritation

Hazard pictograms None

Precautionary Statements - Wash hands thoroughly after handling Prevention

Precautionary Statements - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if Response present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention

Precautionary Statements - None Storage

Precautionary Statements - None

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Disposal

Hazards not otherwise classified None (HNOC)

3. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation

Chemical Name Synonyms Trade Secret CAS-No Weight % Poly(oxy-1,2-ethanediyl), - No 9004-82-4 5 - 10 alpha-sulfo-omega-(dodecyloxy)-, sodium salt (1:1) Sulfuric acid monododecyl ester - No 151-21-3 1 - 5 sodium salt (1:1) 1-Propanaminium, - No 61789-40-0 1 - 5 3-amino-N-(carboxymethyl)-N,N-dimet hyl-, N-coco acyl derivs., inner salts

4. FIRST AID MEASURES

First aid measures for different exposure routes

Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Skin contact None under normal use.

Ingestion Not an expected route of exposure. If swallowed:. Clean mouth with water and afterwards drink plenty of water.

Inhalation None under normal use.

Most important symptoms/effects, May cause eye irritation. acute and delayed

Indication of immediate medical attention and special treatment needed, if necessary

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media Water. Dry chemical. Alcohol-resistant foam.

Unsuitable Extinguishing Media None.

Special hazard None known.

Special protective equipment for As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH fire-fighters (approved or equivalent) and full protective gear.

Specific hazards arising from the None. chemical

6. ACCIDENTAL RELEASE MEASURES

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Personal precautions, protective equipment and emergency procedures

Personal precautions None under normal use conditions.

Advice for emergency responders Use personal protective equipment as required.

Environmental precautions Do not discharge product into natural waters without pre-treatment or adequate dilution.

Methods and materials for containment and cleaning up

Methods for containment Prevent product from entering drains. Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Keep container closed when not in use.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible products None known.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines Exposure guidelines are not relevant when product is used as intended in a household setting.

Exposure controls

Engineering Measures No information available

Personal Protective Equipment

Eye Protection Manufacturing Sites: Safety glasses with side-shields Distribution, Workplace and Household Settings: No special protective equipment required

Hand Protection No special protective equipment required

Skin and Body Protection No special protective equipment required

Respiratory Protection No special protective equipment required

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State @20°C liquid Appearance clear blue-green Odor characteristic Odor threshold No information available

Property Values Note pH value 5.8 - 7.3 Melting/freezing point No information available

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Boiling point/boiling range No information available Flash point No information available Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air Upper flammability limit No information available Lower Flammability Limit No information available Vapor pressure No information available Vapor density No information available Relative density No information available Water solubility No information available Solubility in other solvents No information available Partition coefficient: n-octanol/waterNo information available Autoignition temperature No information available . Decomposition temperature No information available . Viscosity of Product No information available

VOC Content (%) Products comply with US state and federal regulations for VOC content in consumer products.

10. STABILITY AND REACTIVITY

Reactivity None under normal use conditions.

Stability Stable under normal conditions.

Hazardous polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

Conditions to Avoid None under normal processing.

Materials to avoid None in particular.

Hazardous Decomposition Products None under normal use.

11. TOXICOLOGICAL INFORMATION

Product Information Information on likely routes of exposure

Inhalation No known effect. Skin contact No known effect. Ingestion No known effect. Eye contact Avoid contact with eyes. Irritating to eyes.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Acute toxicity No known effect. Skin corrosion/irritation No known effect. Serious eye damage/eye irritation Irritating to eyes. Skin sensitization No known effect. Respiratory sensitization No known effect. Germ cell mutagenicity No known effect. Neurological Effects No known effect. Reproductive toxicity No known effect. Developmental toxicity No known effect. Teratogenicity No known effect. STOT - single exposure No known effect. STOT - repeated exposure No known effect. Target Organ Effects No known effect. Aspiration hazard No known effect. Carcinogenicity No known effect.

Page 4 / 6

Page 144 of 262 97161377_RET_NG - Ivory Original Liquid Hand Soap Revision Date: 18-Feb-2015

12. ECOLOGICAL INFORMATION

Ecotoxicity

The product is not expected to be hazardous to the environment.

Persistence and degradability No information available.

Bioaccumulative potential No information available.

Mobility No information available.

Other adverse effects No information available.

13. DISPOSAL CONSIDERATIONS

Waste treatment

Waste from Residues / Unused Disposal should be in accordance with applicable regional, national and local laws and Products regulations.

Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations.

California Hazardous Waste Codes 561 (non-household setting)

14. TRANSPORT INFORMATION

DOT Not regulated

IMDG Not regulated

IATA Not regulated

15. REGULATORY INFORMATION U.S. Federal Regulations

SARA 313 Not applicable for consumer use

CERCLA Not applicable for consumer use

Food and Drug Administration (FDA) The product described in this Material Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safe to use as per directions on container, box or accompanying literature (where applicable)

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Not applicable for consumer use

Clean Water Act Not applicable for consumer use

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Page 145 of 262 97161377_RET_NG - Ivory Original Liquid Hand Soap Revision Date: 18-Feb-2015

California Proposition 65 This product is not subject to warning labeling under California Proposition 65.

U.S. State Regulations (RTK) Not applicable for consumer use

International Inventories

United States Product is a personal care product and regulated under FDA.

Canada This product is in compliance with CEPA for import by P&G.

Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act

Perfumes contained with the products comply with appropriate IFRA guidance.

16. OTHER INFORMATION

Issuing Date: 18-Feb-2015 Revision Date: 18-Feb-2015 Reason for revision Initial Release.

End of SDS

Page 6 / 6

Page 146 of 262 MATERIAL SAFETY DATA SHEET SECTION 1: PRODUCT AND COMPANY IDENTIFICATION MSDS #: 0108KD Issue Date: 6/9/2003 PRODUCT NAME: Kiwi Select All Protector Rain and Stain Protector GENERAL USE: Waterproofing aerosol. APPEARANCE: Aerosol concentrate is clear to pale straw. Distributor in USA Distributor in Canada Sara Lee Household & Body Care USA Sara Lee Household & Body Care -Canada 707 Eagleview Blvd. Cambridge, Ontario N1T1B2 Canada Exton, PA 19341-1124 USA EMERGENCY TELEPHONE NUMBER EMERGENCY TELEPHONE NUMBER: (519) 622-9800 CHEM-TEL, INC. 1- (800) 255-3924, Outside U.S.A. (813) 248-0585 SECTION 2 - HAZARDOUS INGREDIENTS HAZARDOUS CAS # % OSHA PEL ACGIH SARA SARA INGREDIENTS (By weight) TWA 302 313 ACETIC ACID, BUTYL 123864 1 TO 3 TWA 150PPM 150 ppm No No ESTER STEL 200PPM HEPTANE 142825 65 TO 72 TWA 500PPM 400 ppm No No STEL None MINERAL SPIRITS 64742887 1 TO 3 TWA None None No No STEL None ISOPROPYL ALCOHOL 67630 1 TO 3 TWA 400PPM 400 ppm No Yes STEL 500PPM PROPANE 74986 9 TO 13 TWA 1000PPM 2500 ppm No No STEL None PROPANE, 2-METHYL- 75285 12 TO 16 TWA None 800 ppm No No STEL None In Canada, Not a WHMIS Controlled Product (Consumer Commodity) SECTION 3 - HAZARDS IDENTIFICATION Ingestion: May be harmful or fatal if swallowed. This product may be aspirated into the lungs during swallowing or vomiting and cause lung damage. Eye Contact: Aerosol mist may irritate eyes; always direct spray away from face. Solvent vapors may irritate eyes; always use in well ventilated area. Direct eye contact with product may cause stinging, tearing, redness or swelling. Inhalation: Intentional misuse by deliberately concentrating and inhaling vapors can be harmful or fatal. High vapor concentrations resulting from misuse may cause irritation to the respiratory tract. Overexposure symptoms may include headaches, dizziness, and irritation to the respiratory tract. Overexposure symptoms may include headaches, dizziness, anesthetic, and include redness, burning, drying, and cracking of skin. CHRONIC: Repeated or prolonged exposure may lead to drying of skin, defatting of skin and dermatitis. SECTION 4 - FIRST AID MEASURES Remove person to fresh air; contact a physician and/or transport to medical facility. If victim is not breathing, INHALATION immediately begin artificial respiration. If breathing difficulties develop, oxygen may be given by qualified personnel. SKIN / EYE CONTACT Eye: Flush eyes with water for 15 minutes. If irritation develops, seek medical attention. Skin: Wash exposed skin with soap and water. If irritation develops, seek medical attention. INGESTION: Do not induce vomiting. Contact a poison control center or physician immediately. If victim is unconscious or drowsy, place them on their left side with head down. SECTION 5 - FIRE FIGHTING MEASURES FLASH POINT Propellant: -104 C (-156 F) Concentrate: Approximately -8 C (18 F) Product determined to be extremely flammable as per U. S. Federal Hazardous Substance Act 16 CFR 1500.45 and Canadian Hazardous Products Act. Page 1 of 4

Page 147 of 262

FLAMMABLE LIMITS LEL: N.D. UEL N.D. AUTOIGNITION TEMP. N.D. NFPA AEROSOL LEVEL: 3 EXTINGUISHING MEDIA Foam, carbon dioxide, dry chemical or water fog. FIRE FIGHTING PROCEDURE : Use air supplied breathing equipment. UNUSUAL FIRE & EXPLOSION HAZARDS Water may be ineffective. Aerosol cans may explode from internal pressure build-up when exposed to extreme heat. Water may be used to cool containers and

prevent explosion. HAZ. COMBUSTION PRODUCTS Combustion will yield carbon dioxide and/or carbon monoxide. SECTION 6: ENVIRONMENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED - Wear proper personal protective equipment. Remove all possible ignition sources. Provide adequate ventilation. Keep out of water supply. Mop up, wipe up, or soak up with absorbent. Place spill cleanup material in an approved container. SECTION 7: HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE - This product is classified as a Level III aerosol in accordance with the National Fire Protection Association DANGER: Keep away from heat and flame. Do not use while smoking. Do not puncture, incinerate, or store above 49 C (120 F). SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS Local exhaust required if using large amounts of product in a confined area. PERSONAL PROTECTION: RESPIRATORY PROTECTION (SPECIFY TYPE): Use approved cartridge respirator or supplied air if exposure limits are exceeded. PROTECTIVE GLOVES Chemical resistant gloves if sensitivity exists or if repeated or prolonged contact occurs. EYE PROTECTION: Safety glasses recommended when using any aerosol. OTHER PROTECTION: DANGER: Keep away from heat and flame. Do not use while smoking. WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this as well as all chemicals in general. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES VAPOR PRESSURE (MM Hg) N.D. VAPOR DENSITY (AIR =1 ) N.D. SPECIFIC GRAVITY (WATER =1) 0.7 EVAPORATION RATE (WATER =1) N.D. SOLUBILITY IN WATER Slight. FREEZING POINT N.D. pH N.D. ODOR Characteristic. BOILING POINT N.D. VOLATILE ORGANIC COMPOUND (Total VOC’s) 99% SECTION 10 - STABILITY AND REACTIVITY STABILITY: Stable. CONDITIONS TO AVOID: DANGER: Keep away from heat and flame. Do not use while smoking. Do not puncture, incinerate, or store at temperatures above 49 C (120 F). If swallowed or if excessive inhalation occurs resulting in abnormal reactions including dizziness or nausea, contact a physician. Do not induce vomiting. If eye contact occurs, flush eyes with water for 15 minutes and contact physician. Use in a well- ventilated area. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Contains hydrocarbon propellant and petroleum distillates. Keep out of reach of children. INCOMPATIBILITY (MATERIALS TO AVOID) Strong oxidizing agents, hot surfaces, and open flames. HAZARDOUS DECOMPOSITION PRODUCTS: Combustion will yield carbon dioxide and/or carbon monoxide. Decomposition products dependent on combustion conditions. HAZARDOUS POLYMERIZATION Will not occur. Page 2 of 4

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SECTION 11 -TOXICOLOGICAL INFORMATION Hazardous Ingredients % CAS # LD50 of Ingredients LC50 of Ingredients (Specify Species and (Specify Species and Route Route) ISOPROPYL ALCOHOL 1 TO 3 67630 5045 mg/kg N.AV. Rat-oral PROPANE, 2-METHYL- 12 TO 16 75285 N.AV. 57 pph/15 min. Rat-inh PROPANE 9 TO 13 74986 N.AV. N.AV. HEPTANE 65 TO 72 142825 222 mg/kg 75 g/m3 Mus-i.v. Mus-inh ACETIC ACID, BUTYL 1 TO 3 123864 13100 mg/kg 2000 ppm/4 hr ESTER Rat-oral Rat-inh MINERAL SPIRITS 1 TO 3 64742887 N.AV. N.AV. SECTION 12 -ECOLOGICAL INFORMATION None. SECTION 13 - DISPOSAL INFORMATION Dispose of product in accordance with federal, state, and local regulations. SECTION 14 - TRANSPORTATION INFORMATION aerosols, flammable UN 1950, Hazard Division 2.1 reclassed Consumer Commodity ORM-D for ground transportation SECTION 15 - REGULATORY INFORMATION TSCA (Toxic Substance Control Act): Components of this product are listed on the TSCA Inventory. SARA TITLE III (Superfund Amendments and Reauthorization Act) ,Canadian Regulations and California Prop 65: Chemical Name CAS # SARA 313 SARA 302 CANADA IDL DSL NDSL ISOPROPYL ALCOHOL 67630 Yes No Yes Yes No PROPANE, 2-METHYL- 75285 No No No Yes No PROPANE 74986 No No No Yes No HEPTANE 142825 No No Yes Yes No ACETIC ACID, BUTYL ESTER 123864 No No Yes Yes No MINERAL SPIRITS 64742887 No No No Yes No Chemical Name CAS # Prop65 Prop65 Prop65 Prop65 Cancer Developmental Female Male Reproductive Reproductive ISOPROPYL ALCOHOL 67630 No No No No PROPANE, 2-METHYL- 75285 No No No No PROPANE 74986 No No No No HEPTANE 142825 No No No No ACETIC ACID, BUTYL ESTER 123864 No No No No MINERAL SPIRITS 64742887 No No No No Page 3 of 4

Page 149 of 262

SECTION 16 -OTHER INFORMATION US SKU 382-001 Canada SKU HMIS HAZARD HEALTH: 2 0 = INSIGNIFICANT 3 = HIGH FLAMMABILITY 4 1 = SLIGHT 4 = EXTREME REACTIVITY: 1 2 = MODERATE PERSONAL PROTECTION None EQUIPMENT: MSDS Prepared By: SCH SARA LEE Household and Body Care - USA Issue Date: 6/9/2003 707 Eagleview Blvd Exton, PA 19341 (610) 321-2171 THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. Page 4 of 4

Page 150 of 262 MATERIAL SAFETY DATA SHEET

TT3701 DATE OF PREPARATION 06 00 May 4, 2015

SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NUMBER TT3701 PRODUCT NAME KRYLON® Industrial QUIK-MARK™ Solvent-Based Inverted Marking Paint (Fluorescent), Red Orange MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY KRYLON INDUSTRIAL PRODUCTS GROUP Cleveland, OH 44115

Telephone Numbers and Websites Product Information (800) 247-3266 www.kpg-industrial.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 *for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident)

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SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS

% by Weight CAS Number Ingredient Units Vapor Pressure 14 74-98-6 Propane ACGIH TLV 1000 PPM 760 mm OSHA PEL 1000 PPM 6 106-97-8 Butane ACGIH TLV 1000 PPM 760 mm OSHA PEL 800 PPM 8 110-54-3 Hexane ACGIH TLV 50 PPM 127 mm OSHA PEL 50 PPM 4 107-83-5 2-Methylpentane ACGIH TLV Not Available 211 mm OSHA PEL Not Available 1 96-14-0 3-Methylpentane ACGIH TLV 500 PPM 211 mm OSHA PEL Not Available 1 79-29-8 2,3-Dimethylbutane ACGIH TLV Not Available 230 mm OSHA PEL Not Available 9 142-82-5 Heptane ACGIH TLV 400 PPM 50 mm ACGIH TLV 500 PPM STEL OSHA PEL 400 PPM OSHA PEL 500 PPM STEL 7 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent ACGIH TLV 300 PPM 12 mm OSHA PEL 300 PPM 0.4 100-41-4 Ethylbenzene ACGIH TLV 20 PPM 7.1 mm OSHA PEL 100 PPM OSHA PEL 125 PPM STEL 2 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm ACGIH TLV 150 PPM STEL OSHA PEL 100 PPM OSHA PEL 150 PPM STEL 0.3 14808-60-7 Quartz ACGIH TLV 0.025 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 27 1317-65-3 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction

SECTION 3 — HAZARDS IDENTIFICATION

ROUTES OF EXPOSURE HMIS Codes INHALATION of vapor or spray mist. Health 2* EYE or SKIN contact with the product, vapor or spray mist. Flammability 3 EFFECTS OF OVEREXPOSURE Reactivity 0 EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system.

May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the reproductive system SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11.

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SECTION 4 — FIRST AID MEASURES

EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately.

SECTION 5 — FIRE FIGHTING MEASURES

FLASH POINT LEL UEL Propellant < 0 °F 0.9 9.5 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat.

SECTION 6 — ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent.

SECTION 7 — HANDLING AND STORAGE

STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children.

SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION

PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.

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SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

PRODUCT WEIGHT 7.36 lb/gal 881 g/l SPECIFIC GRAVITY 0.89 BOILING POINT <0 - 325 °F <-18 - 162 °C MELTING POINT Not Available VOLATILE VOLUME 78% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER Not Available pH > 2.0, < 11.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 56.41% Less Water and Federally Exempt Solvents

SECTION 10 — STABILITY AND REACTIVITY

STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur

SECTION 11 — TOXICOLOGICAL INFORMATION

CHRONIC HEALTH HAZARDS Prolonged and repeated exposure to Hexane may cause damage to nerve tissue of the arms and legs (peripheral neuropathy), resulting in muscular weakness and loss of sensation. This effect may be increased by the presence of Methyl Ethyl Ketone. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans. Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer.

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TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 110-54-3 Hexane LC50 RAT 4HR Not Available LD50 RAT 28700 mg/kg 107-83-5 2-Methylpentane LC50 RAT 4HR Not Available LD50 RAT Not Available 96-14-0 3-Methylpentane LC50 RAT 4HR Not Available LD50 RAT Not Available 79-29-8 2,3-Dimethylbutane LC50 RAT 4HR Not Available LD50 RAT Not Available 142-82-5 Heptane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available 100-41-4 Ethylbenzene LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 1317-65-3 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available

SECTION 12 — ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION No data available.

SECTION 13 — DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution.

SECTION 14 — TRANSPORT INFORMATION

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as LTD. QTY. OR ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY

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SECTION 15 — REGULATORY INFORMATION

SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element 110-54-3 Hexane 8 100-41-4 Ethylbenzene 0.3 1330-20-7 Xylene 2 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.

SECTION 16 — OTHER INFORMATION

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.

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MATERIAL SAFETY DATA SHEET

Manufacturer: Sun & Skin Care Research, LLC 5. FIRE FIGHTING MEASURES (CONT) d/b/a Ocean Potion Address: 851 Greensboro Road, Cocoa FL 32926 Special Fire Fighting Emergency Telephone: (CHEMTREC) (800) 424-9300 Procedures: Self-contained positive pressure breathing Information Telephone: (800) 715-3485 apparatus and protective clothing should be worn in fighting fires involving chemicals. The 1. PRODUCT IDENTIFICATION liquid will not sustain combustion. Remove Product Name: No-Ad SPF 50 Sport Sunblock Lotion product containers from fire area if possible. Do Product ID: BULK-NA220-00A not scatter spilled materials with high pressure 2. COMPOSITION / INGREDIENT INFORMATION water streams. Unusual fire and Chemical/Common Name CAS Number % (w/w) Explosion hazards: None known. Not Applicable 6. ACCIDENTAL RELEASE PROCEDURES

3. HAZARDS IDENTIFICATION Wear protective clothing. Contain spills. Scoop or shovel material Emergency overview: No Hazard to the skin: for external use only. into containers. Rinse residue with water as material can cause Do not use in eyes. slippery conditions. Prevent wash water from entering drinking Eye contact: May cause eye irritation. water supplies or waterways. Skin contact: Does not irritate skin under normal conditions. Report all emergency spills/leaks by phone to 911. Ingestion: May cause irritation to the membranes of the mouth, throat and gastrointestinal tract. CHEMTREC is a national center established by the Chemical Abdominal discomfort, nausea, and diarrhea Manufacturer Association (CMA) in Washington DC, to relay may occur. pertinent information concerning specific chemicals on request. Inhalation: High vapor concentrations may cause a burning CHEMTREC has a 24-hour toll-free number (800) 424-9300 sensation in the nose and throat, and stinging and watering in the eyes. 7. HANDLING AND STORAGE

Chronic effects: Not determined. STORAGE: Avoid freezing or excessive heat/open flame. Other health hazards: Not determined. HANDLING: Avoid contact with eyes. Keep out of reach of The TLV of the mixture has not been established. children.

4. FIRST AID MEASURES 8. PERSONAL PROTECTIVE EQUIPMENT (PPE) Eye contact: Remove contact lenses, if used. Flush eyes with water for at least 15 minutes holding eyelids EYE/FACE PROTECTION: When packing or mechanically working open. Contact physician if irritation persists. with this product, wear safety glasses Skin contact: Wash off skin with water. Contact physician if or coverall goggles. irritation persists. RESPIRATORS: When packing or mechanically working Ingestion: Give two glasses of water. Contact Poison this product, wear NIOSH approved Control Center. respiratory protection if there is Inhalation: Remove to fresh air. Give artificial respiration if potential for airborne exposures in not breathing. Consult a physician if symptoms excess of applicable limits. of respiratory discomfort persist. VENTILATION: Normal area ventilation is sufficient in most cases to keep this product within 5. FIRE FIGHTING MEASURES applicable limits.

SKIN: Gloves may be required for certain Flash point: >200°F workers who have sensitive skin or Extinguishing media: Dry chemical, foam or water spray/fog contact dermatitis Incompatibility OTHER: Observe good personal hygiene. (Materials to avoid): None known.

Date Issued: 09/15/08 MSDS Ref #: BULK-NA220-00A Date Revised: 07/09/12 Page 1 of 2

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• 15. MAJOR REFERENCES 9. PHYSICAL AND CHEMICAL PROPERTIES • OSHA: United States Occupational Safety and Health APPEARANCE: White Lotion Administration www.OSHA.gov PHYSICAL STATE: Lotion Emulsion • NIOSH: National Institute of Occupational Safety & Health BOILING POINT: 100 °C www.niosh.com SOLUBILITY IN WATER: Miscible • EPA: United States Environmental Protection Agency www.epa.gov SPECIFIC GRAVITY: 0.96 – 1.03 • PHMSA: United States Department of Transportation Pipeline pH: 6.50 – 7.50 and Hazardous Materials Safety Administration. FRAGRANCE: None www.phmsa.dot.gov

10. STABILITY AND REACTIVITY DATA • http://safety.science.tamu.edu/nfpa.h • http://www.paint.org/hmis/hmis_ratings.pdf Stability: Stable under normal conditions. Conditions to avoid: Avoid heat/open flames. Do not freeze. 16. OTHER INFORMATION Incompatibility HAZARD RATINGS (Materials to avoid): None known. HMIS Classification: Hazardous decomposition Health: 0 or products: None generated under normal storage or handling conditions. Flammability: 0 Hazardous polymerization: Will not occur. Physical Hazard: 0

11. ECOLOGICAL INFORMATION Reactivity: 0

No data available.

12. DISPOSAL CONSIDERATIONS Follow all federal, state, and local regulations regarding proper disposal.

13. TRANSPORATION INFORMATION

Proper shipping name: Not regulated. US DOT: This product is not a Hazardous Material according to the Hazardous Materials Transportation Act and DOT

regulation is 49CFR. Canadian TDG: Not regulated. Figure 1 NFPA Ratings 14. REGULATORY INFORMATION NFPA Classification: UNITED STATES FEDERAL REGULATIONS Health Hazard: 0 DOT: Registered with the U.S Department of Transportation as required by 49 CFR Part 107, Subpart G. Information Fire Hazard Flash Points: 0 available upon request. Reactivity Hazard: 0 Specific Hazards:

Manufacture Disclaimer: The information presented herein has

been compiled from reputable and current sources as of the date

provided without any warranty, expressed or implied, regarding its

correctness or accuracy. Since the use of the information and the

use of the product are not within the control of SSCR, it is the user’s

responsibility to determine safe conditions for use and to assume

liability for loss, injury, damage, or exposure resulting from the

misuse of this product.

Date Issued: 09/15/08 MSDS Ref #: BULK-NA220-00A Date Revised: 07/09/12 Page 2 of 2

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Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200

OFF!® DEEP WOODS® INSECT REPELLENT VII Version 1.1 Print Date 03/04/2015

Revision Date 02/24/2015 SDS Number 350000022042

1. PRODUCT AND COMPANY IDENTIFICATION

Product information Product name : OFF!® DEEP WOODS® INSECT REPELLENT VII

Recommended use : Insect Repellent

Manufacturer, importer, : S.C. Johnson & Son, Inc. supplier 1525 Howe Street Racine WI 53403-2236

Telephone : +18005585252 Emergency telephone : 24 Hour Medical Emergency Phone: (866)231-5406 number 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300

2. HAZARDS IDENTIFICATION Classification of the substance or mixture

Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Flammable liquids Category 3 Flammable liquid and vapour. Eye irritation Category 2A Causes serious eye irritation.

Labelling Hazard symbols Flame Exclamation mark

Signal word Warning

Hazard statements Flammable liquid and vapour. Causes serious eye irritation.

Precautionary statements If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.

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IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Store in a well-ventilated place. Keep cool. Dispose of contents/ container to an approved incineration plant. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves. Wash hands thoroughly after handling. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Other hazards : None identified

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. Weight percent Ethyl alcohol 64-17-5 30.00 - 60.00 N,N-Diethyl-m-toluamide 134-62-3 10.00 - 30.00 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES

Eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention.

Skin contact : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If you suspect a reaction to this product, discontinue use and remove contaminated clothing.

Inhalation : No special requirements.

Ingestion : No special requirements

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5. FIREFIGHTING MEASURES

Suitable extinguishing : Use water spray, alcohol-resistant foam, dry chemical or media carbon dioxide.

Specific hazards during : Flammable liquid. Vapors are heavier than air and may travel firefighting to a source of ignition and flash back. Liquid run-off to sewers may create fire/explosion hazard. Container may melt and leak in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses.

Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. For large quantities of flammable liquids, consider containment to prevent the spread of fire. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Wear personal protective equipment. Wash thoroughly after handling.

Environmental : Do not flush into surface water or sanitary sewer system. precautions Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment.

Methods and materials : Soak up with inert absorbent material. for containment and Use only non-sparking equipment. cleaning up Dike large spills. Clean residue from spill site.

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7. HANDLING AND STORAGE

Handling Precautions for safe : Avoid contact with eyes and lips. handling For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Wash thoroughly after handling.

Advice on protection : Keep away from sources of ignition - No smoking. against fire and explosion Take measures to prevent the build up of electrostatic charge. Use only non-sparking tools. Use explosion-proof equipment. Ground/bond container and receiving equipment.

Storage Requirements for storage : Keep container closed when not in use. areas and containers Keep away from food, drink and animal feedingstuffs. Keep tightly closed. Store in a well-ventilated place. Keep cool.

Other data : Stable under normal conditions.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- Basis standard units Ethyl alcohol 64-17-5 1,900 mg/m3 1,000 ppm - OSHA TWA

Ethyl alcohol 64-17-5 - 1,000 ppm - ACGIH STEL

Personal protective equipment Respiratory protection : Do not spray in enclosed areas.

Hand protection : No special requirements.

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Eye protection : Safety glasses with side-shields

Skin and body protection : No special requirements.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form : liquid

Color : clear

Odor : pleasant

Odour Threshold : No data available

pH : 6.98 at (20 °C)

Melting point/freezing point : No data available

Initial boiling point and : No data available boiling range

Flash point : 84 °F

Method: Tag Closed Cup (TCC)

Evaporation rate : No data available

Flammability (solid, gas) : Sustains combustion

Upper/lower flammability or : No data available explosive limits

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Vapour pressure : No data available

Vapour density : No data available

Relative density : 0.93 g/cm3 at 20 °C

Solubility(ies) : partly miscible

Partition coefficient: n- : No data available octanol/water

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity, dynamic : No data available

Viscosity, kinematic : Not applicable

Oxidizing properties : No data available

Volatile Organic : 34.7 % - additional exemptions may apply Compounds *as defined by US Federal and State Consumer Product Total VOC (wt. %)* Regulations

Other information : None identified : No data available

10. STABILITY AND REACTIVITY

Possibility of hazardous : If accidental mixing occurs and toxic gas is formed, exit area reactions immediately. Do not return until well ventilated.

Conditions to avoid : Heat, flames and sparks.

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Incompatible materials : Strong oxidizing agents Do not mix with bleach or any other household cleaners. Strong bases

Hazardous decomposition : Thermal decomposition can lead to release of irritating gases products and vapours.

11. TOXICOLOGICAL INFORMATION

Emergency Overview : Warning

Acute oral toxicity : LD50 4,103 mg/kg

GHS Properties Classification Routes of entry Acute toxicity No classification proposed -

Skin corrosion/irritation No classification proposed -

Eye irritation Category 2A -

Skin sensitisation No classification proposed -

Respiratory No classification proposed - sensitisation Germ cell mutagenicity No classification proposed -

Carcinogenicity No classification proposed -

Reproductive toxicity No classification proposed -

Specific target organ No classification proposed - toxicity - single exposure Specific target organ No classification proposed - toxicity - repeated exposure Aspiration hazard No classification proposed -

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Acute inhalation toxicity : GHS LC50 (dust and mist) > 2.07 mg/l

Acute dermal toxicity : LD50 > 5,000 mg/kg

Aggravated Medical : Do not apply to cuts or irritated skin. Condition

12. ECOLOGICAL INFORMATION

Product : The product itself has not been tested.

Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions.

Toxicity to fish Components End point Species Value Exposure time Ethyl alcohol flow- Pimephales promelas 14,200 96 h through (fathead minnow) mg/l test LC50

N,N-Diethyl-m-toluamide static test Oncorhynchus mykiss 71.25 mg/l 96 h LC50 (rainbow trout)

Toxicity to aquatic invertebrates Components End point Species Value Exposure time Ethyl alcohol static test Daphnia magna (Water 48 h EC50 flea)

2 mg/l

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NOEC Daphnia magna 9.6 mg/l 9 d

N,N-Diethyl-m-toluamide No data available

Toxicity to aquatic plants Components End point Species Value Exposure time Ethyl alcohol Static Chlorella vulgaris (Fresh 275 mg/l 72 h EC50 water algae)

N,N-Diethyl-m-toluamide No data available

Persistence and degradability Component Biodegradation Exposure Summary time Ethyl alcohol 97 % 28 d Readily biodegradable

N,N-Diethyl-m-toluamide No data available

Bioaccumulative potential

Component Bioconcentration Partition Coefficient n- factor (BCF) Octanol/water (log) Ethyl alcohol 3.2 estimated -0.35 Measured N,N-Diethyl-m-toluamide No data available No data available

Mobility

Component End point Value

Ethyl alcohol No data available N,N-Diethyl-m-toluamide No data available

PBT and vPvB assessment Component Results

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Ethyl alcohol Not fulfilling PBT and vPvB criteria

N,N-Diethyl-m-toluamide Not fulfilling PBT and vPvB criteria

Other adverse effects : None known.

13. DISPOSAL CONSIDERATIONS

PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label. Consumer may discard empty container in trash, or recycle where facilities exist.

14. TRANSPORT INFORMATION

Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.

Land transport Sea transport Air transport UN number 1993 1993 1993 UN proper UN 1993 Flammable UN 1993 Flammable UN 1993 Flammable shipping name liquid, N.O.S. (Ethyl liquid, N.O.S. (Ethyl liquid, N.O.S. (Ethyl alcohol) alcohol) alcohol) Transport hazard 3 3 3 class(es) Packing group III III III Environmental - - - hazards Special Limited quantities Limited quantities Limited quantities precautions for derogation may be derogation may be derogation may be user applicable to this applicable to this applicable to this product, please check product, please product, please check transport documents. check transport transport documents. documents.

15. REGULATORY INFORMATION

Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA)

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Chemical Substance Inventory.

California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65.

Registration # / Agency 4822-399/US/EPA

16. OTHER INFORMATION HMIS Ratings Health 2

Flammability 3

Reactivity 0

NFPA Ratings Health 2

Fire 3

Reactivity 0

Special -

This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.

Further information

This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

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Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)

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Page 170 of 262 There was a PDF conversion failure for - Product Name: Orange Away CAS Number: Manufacturer: Total Solutions SDS Date: 1/8/2015 To complete your binder, please link a different SDS for this product or print the SDS manually from http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=sqcvz62yEjM%3d and add to your binder. We are currently researching solutions to this issue. Thank you for your patience.

Page 171 of 262 PARTS MASTER PREMIUM POWER STEERING FLUID

Revision Date:18-Jan-2012 Material Safety Data Sheet

NFPA HMIS

1 Health Hazard 0 0 0 Fire Hazard 1 Reactivity 0

Issuing Date 19-July-2010 Revision Date 18-Jan-2012 Revision Number 2

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name PARTS MASTER PREMIUM POWER STEERING FLUID

Product Code F-79

Recommended Use

Manufactured by: Omni Specialty Packaging 10399 S. Hwy 1 Shreveport, LA 71115 Phone: 1 (318) 524-1100

Emergency Telephone Number CHEMTREC 1 (800) 424-9300

2. HAZARDS IDENTIFICATION

Emergency Overview

Appearance Clear Liquid Physical State Liquid Odor Mild petroleum odor

Potential Health Effects Principal Routes of Exposure Eye contact, Skin contact, Inhalation, Ingestion

Acute Toxicity Eyes Eye contact may result in slight irritation and redness.. Skin Minimally irritating upon direct contact. Inhalation Inhalation of oil mist or fumes can cause irritation of the nose, throat and upper respiratory tract Ingestion Do not ingest. May cause nausea, vomiting/diarrhea.

Chronic Effects Prolonged exposure may cause chronic effects.

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Revision Date:18-Jan-2012

Aggravated Medical Conditions Personnel with pre-existing skin disorders should avoid contact with this product.

Environmental Hazard See Section 12 for additional Ecological Information.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Formula Mixture

Chemical Name CAS-No Weight % Solvent-Dewaxed Heavy Paraffinic 64742-65-0 85-100 Distillates (Petroleum) Viscosity Index Improver Lubricant Mixture 5-15 Additive Package N/A 0-10

4. FIRST AID MEASURES

Eye Contact Flush with large amounts of water for 15 minutes. Get medical attention if eye irritation develops or persists. If material is hot, treat for thermal burns and take victim to the hospital immediately.

Skin Contact Wash off immediately with soap and plenty of water for at least 15 minutes while removing all contaminated clothing and shoes. Get medical attention immediately if skin discoloration occurs.

Inhalation If affected, remove individual to fresh air. If not breathing, give mouth-to-mouth resuscitation. Get medical attention if symptoms develop or persist.

Ingestion CALL PHYSICIAN IMMEDIATELY. Never give anything by mouth to an unconscious person. Don’t induce vomiting except at the instructions of the physician.

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Flammable Properties Not flammable.

Flash Point 380°F

Suitable Extinguishing Media Water Fog. Carbon dioxide (CO2). Foam. Dry chemical.

Unsuitable Extinguishing Media Water stream may spread fire.

Hazardous Combustion Products Decomposition and combustion products may include smoke, carbon dioxide, carbon monoxide, and other low molecular weight hydrocarbons.

Explosion Data Sensitivity to Mechanical Impact Not sensitive. Sensitivity to Static Discharge Not sensitive.

Protective Equipment and Precautions for Firefighters Wear positive pressure self-contained breathing apparatus (SCBA). Use water to cool containers exposed to flames. Structural firefighters’ protective clothing will only provide limited protection. Mist or sprays may be flammable below the product normal flash point.

NFPA Health Hazard 0 Flammability 1 Reactivity 0 Physical and Chemical Hazards -

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6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Use personal protective equipment. Avoid contact with skin, eyes, and clothing. Ensure adequate ventilation.

Methods for Containment Dike far ahead of liquid spill for later disposal.

Methods for Cleaning Up Pick up free liquid for recycle and/or disposal. Residual liquid and/or solid can be absorbed on inert material.

Evacuation Procedures Large Spill Consider initial downwind evacuate for at least 300 meters (1000 feet). Fire If tank, rail car or tank car is involved in a fire, isolate for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions.

Reporting Requirements Spills that enter a water body must be reported immediately to the USEPA’s National Response Center at (800)424-8802. Check with your local and state regulators regarding their reporting requirements.

7. HANDLING AND STORAGE

Handling Do not pressure, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode. See NFPA 30 and OSHA 1910.106 – flammable and combustible liquids.

Storage Store away from heat, sparks, open flame, or strong oxidizing agents in closed and properly labeled containers. Empty containers retain product residue (liquid, and/or vapor) and can be dangerous

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Solvent-Dewaxed Heavy 5 mg/m³ mist 5 mg/m³ mist None listed Paraffinic Distillates (Petroleum) 64742-65-0 Viscosity Index improver 5 mg/m³ mist 5 mg/m³ mist None listed Lubricant

Engineering Measures Additional area ventilation or local exhaust may be required to maintain air concentrations below recommended limits.

Personal Protective Equipment Eye/Face Protection Safety glasses or face shield where splashing is possible. Full face-shield to be worn during emergencies. Skin and Body Protection As needed to prevent repeated skin contact. Solvent resistant gloves should be used if needed. Respiratory Protection Not normally needed. During emergencies wear respirator.

Hygiene Measures Remove and wash contaminated clothing before re-use. Wash hands before breaks and immediately after handling the product.

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Page 174 of 262 PARTS MASTER PREMIUM POWER STEERING FLUID

Revision Date:18-Jan-2012 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Clear Liquid Odor Mild petroleum odor Physical State Liquid pH N/A Flash Point 380°F Autoignition Temperature 600°F Boiling Point/Range >500°F Freezing Point <-40°C Explosion Limits N/A Flammability Limits in Air N/A Specific Gravity 0.85 Solubility Negligible Evaporation Rate N/A Vapor Pressure N/A Vapor Density Not Determine Density N/A

10. STABILITY AND REACTIVITY

Stability Stable under recommended storage conditions.

Incompatible Products Open Flame and strong oxidizing agents.

Conditions to Avoid Heat, flames, and sparks.

Hazardous Decomposition Products Decomposition and combustion products may include hydrogen sulfide, alkyl mercaptans, sulfides, oxides or sulfur, oxides of : phosphorous, calcium and zinc; aldehydes, carbon monoxide and carbon dioxide.

Hazardous Polymerization None under normal processing.

11. TOXICOLOGICAL INFORMATION

Acute Toxicity

Product Information Test on similar materials show a low order of acute oral and dermal toxicity.

Acute Oral Test on similar materials indicates low order of acute toxicity. Effects Acute Inhalation Low acute toxicity expected on inhalation. Effects Skin Effects Practically non-toxic if absorbed. Other similar highly refined products have not shown skin tumors in mouse skin painting studies. Eye Irritation Minimal irritation on contact. Eye irritation slightly or practically non-irritating base on similar products.

Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Solvent-Dewaxed Heavy Rat >2000 mg/kg Rabbit >2000 mg/kg Rat > 2.18 mg/L Paraffinic Distillates 4 hours (Petroleum) 64742-65-0

Chronic Toxicity

Chronic Toxicity Prolonged exposure may cause chronic effects.

Carcinogenicity Not considered a potential carcinogen base on IP346 DMSO of less than 3.0 wt%

Target Organ Effects Respiratory system, Eyes, Skin,

Genotoxicity This product is considered non-mutagenic and has negative potential for tumor development based on from Modified Ames Assay, with Mutagenic Index of less than 1.0.

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Revision Date:18-Jan-2012 12. ECOLOGICAL INFORMATION

Ecotoxicity This product is not toxic to fish but may coat gill structures resulting in suffocation if spilled in shallow, running water. Product may be moderately toxic to amphibians by preventing dermal respiration. This product may cause gastrointestinal distress to birds and mammals through ingestion during pelage grooming.

13. DISPOSAL CONSIDERATIONS

Waste Disposal Method Dispose of in accordance with local regulations. Keep this product out of sewers and waterways.

Contaminated Packaging Dispose of in accordance with local regulations.

14. TRANSPORT INFORMATION

DOT Not regulated

IATA Not regulated

IMDG/IMO Not regulated

15. REGULATORY INFORMATION

International Inventories

TSCA DSL EINECS/ELINCS ENCS IECSC KECL PICCS AICS Solvent-Dewaxed Present X 265-169-7 X X X X X Heavy Paraffinic Distillates (Petroleum) 64742-65-0

U.S. Federal Regulations

SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No

Clean Water Act If spilled into navigable waters it is reportable to National Response Center, 800-424-8802. Reportable Quantity = Oil Sheen present on navigable water surface. (40 CFR 116; 401.15)

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990.

CERCLA

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Revision Date:18-Jan-2012 U.S. State Regulations

California Proposition 65 This product does not contain any Proposition 65 chemicals. Florida No listed ingredients are present Massachusetts RTK No listed ingredients are present Minnesota RTK No listed ingredients are present New Jersey RTK Lists petroleum oil, but this product does not contain hazardous ingredients. Pennsylvania RTK Lists petroleum oil, but this product does not contain hazardous ingredients greater than 3%. Illinois DOL TSL No listed ingredients are present

International Regulations

Mexico – Grade No information available.

Canada Not listed on the Canadian Controlled Product Ingredient Disclosure and is compliant with Controlled Products Regulation

CONEG Metals Since cadmium, chromium, lead and mercury are not detectable and it does not exceed 100ppm total in this product, it is compliant with CONEG Metals regulation.

EEC (Europe) This product is not known to be a dangerous good internationally. R-Phrases R45: May Cause Cancer S-Phrases S53: Avoid Exposure S45 Hazard Label None Danger Symbol None

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS Hazard Class D2B Toxic materials

16. OTHER INFORMATION

Prepared By Juan Parker

Issuing Date 28-June-2010

Revision Date 31-Jan-2012

Revision Note Not applicable

Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.

End of MSDS

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Page 177 of 262 Page 178 of 262 Page 179 of 262 Page 180 of 262 Page 181 of 262 Page 182 of 262 Initial Preparation Date: 7/19/1999 Last Revision Date: 10/23/2014 Effective Date: 10/29/2014

MATERIAL SAFETY DATA SHEET

PRODUCT IDENTITY: POLAR WINDSHIELD WASH & DEICER FLUID -30F

1. CHEMICAL PRODUCT & COMPANY INFORMATION

OLD WORLD INDUSTRIES, LLC 4065 COMMERCIAL AVENUE NORTHBROOK, ILLINOIS 60062 PHONE: 847-559-2000 EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)

2. COMPOSITION / INFORMATION ON INGREDIENTS

8-Hour Time Weighted Vapor Pressure Material CAS# % by Wt. Avg. (TWA) mm Hg @ Temp

Methanol 67-56-1 35 200 ppm (260 Mg/M3) 96.1 20 C Propylene Glycol 57-55-6 <5 Not established 0.8 20 C Additives N/A <1 N/A N/A

3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

Slight odor. May be fatal if swallowed. Vapors can cause eye irritation.

LD50 Rat (Oral): 5,628 mg/kg (Methanol) LD50 Rabbit (Skin): 20 g/kg (Methanol) Carcinogency: No National Toxicology Program: No International Agency for Research on Cancer: No OSHA Regulated: Yes

HAZARD RATING SYSTEM

HMIS: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: A

KEY: 0 - Minimal 1 - Slight 2 - Moderate 3 - Serious 4 - Severe A - Safety glasses

POTENTIAL HEALTH EFFECTS

Health Hazards (Acute and Chronic):

Acute: Acute methanol intoxication is manifested initially by signs of narcosis. This is followed by a latent period

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Page 183 of 262 in which formic acid accumulates in the body causing metabolic acidosis. Severe abdominal, leg, and back pain occur and visual degeneration can lead to blindness.

1. Humans – Ingestion of 80 to 150 mL of methanol is usually fatal to humans (HSDB 1994). One worker died from exposure to vapor ranging from 4,000 to 13,000 ppm over 12 hours (ACGIH 1991). The concentration of 4,000 ppm is roughly equivalent to a total of 1,140 mg/kg over the 12-hour period (see end note 2). Poisoning by nonlethal doses can be described in three stages: (1) narcotic stage similar to ethanol; (2) latent period of 10-15 hours; (3) visual disturbances and central nervous system lesions (Rowe and McCollister 1981). Visual disturbances can lead to blindness due to edema of the retina and atrophy of the optic nerve head (HSDB 1994). Third-stage CNS lesions include headache, dizziness, abdominal, back, and leg pain, delirium that can lead to coma, and nausea (HSDB 1994). Formic acid production causes severe metabolic acidosis (Rowe and McCollister 1981).

2. Animals – Oral LD50 values for methanol is animals are 0.4 g/kg in the mouse, 6.2 to 13 g/kg in the rat, 14.4 g/kg in the rabbit, and 2 to 7 g/kg in the monkey (Rowe and McCollister 1981). The LD50 for dermal application to rabbits is 20 mL/kg (approximately 16 g/kg) (Rowe and McCollister 1981). Dose-response data for inhalation vary with species, dose, and duration (8,800 ppm for 8 hours to 152,800 ppm for 94 minutes). Symptoms of intoxication include incoordination, salivation, lethargy, narcosis, and death (Rowe and McCollister 1981).

Sub-chronic/Chronic: Chronic exposure to methanol, either orally or by inhalation, causes headache, insomnia, gastrointestinal problems, and blindness in humans and hepatic and brain alterations in animals. EPA has derived an oral RfD (reference dose) (see end note 3) for methanol of 0.5 mg/kg/day, based on the absence of liver and brain effects in animals exposed by mouth to 500 mg/kg/day.

1. Humans – “Chronic” exposure to methanol vapors (no time or dose given) caused conjunctivitis, headache, giddiness, insomnia, gastric disturbances, and bilateral blindness (ACGIH 1991). Marked vision loss occurred in one worker exposed to 1,200 to 8,000 ppm vapor for 4 years (ACGIH 1991).

2. Animals – No effects were seen in rats given 1% (approximately 140 mg/kg/day) methanol in drinking water for 6 months (Rowe and McCollister 1981). Hepatic abnormalities (proteinic degeneration, altered RNA metabolism) occurred in rhesus monkeys given 3 to 6 g/kg for 3 to 20 weeks and in rats given 10, 100, or 500 mg/kg/day for one month (Rowe and McCollister 1981). Rabbits chronically fed methanol (no dose or time given) had increasing blood levels, brain and eye edema, and myelin thinning (HSDB 1994). Male and female rats were gavaged with 100, 500, or 2,500 mg/kg/day for 90 days (U.S. EPA 1994). Increased levels of SGPT and SAP as well as decreased brain weights were seen in both sexes at the highest dose; a no-observed-adverse effect level (NOAEL) for the study was 500 mg/kg/day. Based on these data, the U.S. EPA (1994) calculated a chronic RfD (see end note 4) for methanol of 0.5 mg/kg/day. No toxic effects were seen in dogs exposed by inhalation to either 10,000 ppm for 3 minutes, 3x/day, for 100 days or to 450 or 500 ppm, 8 hours/day for 379 days (Rowe and McCollister 1981). Ultrastructural changes were observed in the photoreceptor cells of rabbits exposed to 46.6 ppm for 6 months (Rowe and McCollister 1981). Rowe and McCollister (1981) concluded that the effects of combined oral and inhalation exposure appear to be additive. Rats exposed by inhalation to 16.8 ppm, 4 hours/day, for 6 months and administered 0.7 mg/kg/day orally had changes in blood morphology, oxidation-reduction processes, and liver function (Rowe and McCollister 1981).

Carcinogenicity: No information was found on the carcinogenicity of methanol in the secondary sources searched.

1. Humans – No information was found in the secondary sources searched concerning the carcinogenicity of methanol to humans.

2. Animals – No information was found in the secondary sources searched concerning the carcinogenicity of methanol to animals. The NTP has assigned a project leader for methanol and the design of the study is in progress (NTP 1994).

Polar Windshield Wash & Deicer Fluid -30F 2

Page 184 of 262 4. FIRST AID MEASURES Ensure physician has access to this MSDS.

Routes of Entry: Inhalation, Skin, Ingestion

Signs and Symptoms of Exposure:

Eye Contact: May cause eye irritation.

Skin Contact: Frequent or prolonged contact may cause skin irritation experienced as burning, drying, cracking and redness.

Inhalation: May cause nose and throat irritation. High concentrations may cause acute central nervous system depression characterized by headaches, dizziness, nausea and confusion.

Skin Absorption Health Risks and Symptoms of Exposure: Harmful quantities of Methyl Alcohol may affect eyes and central nervous system.

Ingestion Health Risks and Symptoms of Exposure: May cause nausea, abdominal pain, headache, shortness of breath, visual impairment and blindness. Severe poisoning can cause coma and death.

Medical Conditions Generally Aggravated by Exposure: Ingestion of large amounts of Methyl Alcohol has been shown to damage organs including liver, kidney, pancreas, heart, lungs and brain. Although this rarely occurs, survivors of severe intoxication may suffer permanent neurological damage. Overexposure may aggravate pre-existing disorders of the eyes.

People have died as a result of drinking large amounts of methanol. Drinking smaller, non-lethal amounts of methanol adversely affects the human nervous system. Effects range from headaches to incoordination similar to that associated with drunkenness. Delayed effects such as severe abdominal, leg, and back pain can follow the inebriation effects of methanol. Loss of vision and even blindness can also occur after exposure to amounts of methanol causing inebriation. These effects are not likely to occur at levels of methanol that are normally found in the environment.

Human health effects associated with breathing or otherwise consuming smaller amounts of methanol over long periods of time are not known. Workers repeatedly exposed to methanol have experienced several adverse effects. Effects range from headaches to sleep disorders and gastrointestinal problems to optic nerve damage. Laboratory studies show that repeat exposure to large amounts of methanol in air or in drinking water cause similar adverse effects in animals.

TREATMENT

Eyes: Flush with large quantities of water for 15 minutes and seek medical attention.

Skin: Remove contaminated clothing and wash contaminated skin with large amounts of soap and water. If irritation persists, get medical attention. Launder clothing before reuse.

Inhalation: Remove to fresh air. If breathing has stopped, apply artificial respiration. If breathing is difficult, give oxygen provided a qualified operator is available. Get medical attention.

Ingestion: If swallowed, Do Not induce vomiting. Drink a large amount of water, milk or sodium bicarbonate to dilute material in stomach. (Never give anything by mouth to an unconscious person.) Call Poison Control Center, hospital emergency room or physician immediately.

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Page 185 of 262 Notes to Physician: This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic symptoms, their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in symptomatic patients or at blood hemodialysis. Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material: skin, lung (for example, asthma-like conditions), liver, kidney, central nervous system, pancreas, heart). Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias.

5. FIRE FIGHTING MEASURES

FIRE & EXPLOSION HAZARD DATA

Flammable Properties: Flash Point: 86 F Method Used: ETA 1010 CC

Flammability Limits: Percentage of vapor concentration at which methanol can ignite in presence of spark: LEL: 6.0% UEL: 36.0%

Hazardous Combustion Products: Methanol

Extinguishing Media: Foam, dry chemical, carbon dioxide or any Class B extinguishing agent. Water may be unsuitable as an extinguishing medium but helpful in keeping adjacent containers cool

Fire Fighting Instructions: Use water spray to cool fire exposed containers. Water may be ineffective but may be used to cool exposed containers to prevent pressure buildup and possible auto-ignition or explosion when exposed to extreme heat. If water is used, fog nozzles are preferable.

Unusual Fire and Explosion Hazards: Handle as flammable liquid. Vapors are heavier than air and may travel along the ground or may be moved by ventilation. Vapors form an explosive mixture in air between the upper and lower explosive limits which can be ignited by many sources, such as pilot lights, open flames, electrical motors and switches.

Protective Equipment For Fire Fighters: Wear NIOSH approved self-contained breathing apparatus with full face piece and protective clothing to prevent contact with skin and eyes.

6. ACCIDENTAL RELEASE MEASURES

Small Spill: Absorb liquid on vermiculite, floor absorbent or other absorbent material.

Large Spill: Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks). Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source. Prevent from entering drains, sewers, streams or other bodies of water. Prevent from spreading. If runoff occurs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for disposal. Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occurred.

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Page 186 of 262 7. HANDLING AND STORAGE

Do not swallow. Store in closed containers in a cool, dry, well-ventilated area. Keep away from sparks and open flame.

Respiratory Protection: Use approved NIOSH respirator when TLV is exceeded.

Ventilation: Provide sufficient ventilation to maintain exposure below TLV.

Protective Gloves: Wear appropriate impermeable gloves.

Eye Protection: Use chemical safety glasses, goggles and face shields for eye protection.

Other Protective Clothing or Equipment: Long sleeves and apron are recommended.

Work / Hygienic Practices: Avoid prolonged or repeated skin contact.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Eye Protection: Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Consult your safety representative.

Skin Protection: Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin contact, wear impervious clothing and boots.

Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines), a NIOSH/MSHA approved air supplied respiratory is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see your industrial hygienist). Engineering or administrative controls should be implemented to reduce exposure.

Engineering Controls: Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s).

Exposure Guidelines: Component: Methyl Alcohol (67-56-1) OSHA VPEL 200.000 ppm – TWA (skin) OSHA VPEL 250.000 ppm – STEL (skin) ACGIH TLV 200.000 ppm – TWA (skin) ACGIH TLV 250.000 ppm – STEL (skin)

9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Range: 166 F - 194 F Specific Gravity (Water =1): .94 @ 20 C Vapor Density (Air=1): Heavier than air Water Solubility: Soluble Appearance: Clear purple liquid Odor: Mild alcohol odor Evaporation Rate: Greater than n-butyl acetate

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Page 187 of 262 10. STABILITY & REACTIVITY DATA

Stability: Stable

Conditions to Avoid: Ignition sources, such as heat, sparks and flames

Incompatibility (Materials to Avoid): Strong acids and strong oxidizing agents

Hazardous Decomposition Products: Burning can produce carbon monoxide and/or carbon dioxide. Carbon monoxide is highly toxic if inhaled; carbon dioxide in sufficient concentrations an act as an asphyxiant.

Hazardous Polymerization: Will not occur

11. TOXICOLOGICAL INFORMATION

Mutagenicity (The Effects On Genetic Material):

Genotoxicity: Methanol was negative for cell transformation in Syrian hamster embryo cells (clonal assay and viral enhanced), sister chromatid exchange in vitro, and for aneuploidy and chromosome aberrations in Neurospora crassa (GENETOX 1992). The micronucleus test and the assay for chromosome aberrations in mammalian polychromatic erythrocytes were inconclusive (GENETOX 1992).

Developmental/Reproductive Toxicity: No information was found on the developmental toxicity of methanol in humans. Methanol can cause adverse effects in the developing offspring in rats at doses that cause overt maternal intoxication.

1. Humans – No information was found in the secondary sources searched regarding the developmental or reproductive toxicity of methanol to humans. However, one of the breakdown products of the artificial sweetener aspartame is methanol. Increased blood methanol levels did not lead to increased formic acid levels in women receiving up to 200 mg/kg aspartame (no other details reported) and no evidence of fetal risk was detected (HSDB 1994).

2. Animals – Rats were exposed by inhalation, 7 hours/day, to 5,000 or 10,000 ppm methanol on gestation days 1-19 or to 20,000 ppm on days 7-15. Maternal intoxication (unsteadiness) occurred at the highest dose and coincided with extra or rudimentary ribs and urinary or cardiovascular defects in the fetuses (ACGIH 1991). Male rats had significantly lowered testosterone levels after inhalation exposure to 200 ppm methanol for 6 weeks; at 10,000 ppm a change in luteinizing hormone was also observed (HSDB 1994).

Neurotoxicity: Methanol causes central nervous system depression in humans and animals as well as degenerative changes in the brain and visual system.

1. Humans – Methanol causes narcosis similar to ethanol intoxication and nonlethal doses can lead to blindness. Autopsy of individuals after lethal doses revealed edema and hyperemia of the brain and degeneration of the ganglion cells of the retina (Rowe and McCollister 1981).

2. Animals – Acute methanol intoxication in animals causes CNS depression as observed by narcosis, incoordination, lethargy, drowsiness, and prostration (Rowe and McCollister 1981).

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Page 188 of 262 Significant Data With Possible Relevance To Humans:

Pharmacokinetics:

1. Absorption – Methanol is readily absorbed after oral, inhalation, or dermal exposure. Oral doses in humans of 71 to 84 mg/kg resulted in blood levels of 4.7 to 7.6 mg/100 mL of blood within 3 hours (Rowe and McCollister 1981). Inhalation of 500 to 1,000 ppm methanol for 3 to 4 hours gave urine concentrations of 1 to 3 mg methanol/100 mL of urine at the end of exposure (Rowe and McCollister 1981). Based on urinary methanol levels, the rate of absorption of the chemical appears to be proportional to the concentration of vapor inhaled (HSDB 1994). The rate of dermal absorption increased for 35 minutes then decreased over the next 25 minutes (no other details given) (HSDB 1994).

2. Distribution – Methanol distributes rapidly in dogs exposed to 4,000 to 15,000 ppm for 12 hours to 5 days; the highest concentrations of the chemical were found in blood, eye fluid, bile, and urine (HSDB 1994).

3. Metabolism – Methanol is oxidized in the human liver by the enzyme alcohol dehydrogenase (Rowe and McCollister 1981). Metabolic products include formaldehyde and formic acid (HSDB 1994). The rate of metabolism for methanol (25 mg/kg/hr) is much slower than for ethanol (175 mg/kg/hr) and is independent of concentrations in the blood (HSDB 1994). Formic acid is responsible for the toxic effects of methanol (ACGIH 1991).

4. Excretion – Methanol is excreted either as parent compound in the urine or expired air, or as the formic acid metabolite in urine (Rowe and McCollister 1981; HSDB 1994). The amount of formic acid excreted varies greatly with species from 1% in rabbits to 20% in dogs; humans are intermediate (HSDB 1994). In humans, the half-life of methanol elimination in expired air after oral or dermal exposure is 1.5 hours (HSDB 1994).

12. ECOLOGICAL INFORMATION

ENVIRONMENTAL FATE

Methanol evaporates when exposed to air. It dissolves completely when mixed with water. Most direct releases of methanol to the environment are to air. Methanol also evaporates from water and soil exposed to air. Once in air, it breaks down to other chemicals. Microorganisms that live in water and in soil can also break down methanol. Because it is a liquid that does not bind well to soil, methanol that makes it way into the ground can move through the ground and enter groundwater. Plants and animals are not likely to store methanol.

Methanol by itself is not likely to cause environmental harm at levels normally found in the environment. Methanol can contribute to the formation of photochemical smog when it reacts with other volatile organic carbon substances in air.

Movement & Partitioning: The miscibility of methanol in water and a low KOC (9) indicate that the chemical will be highly mobile in soil (HSDB 1994). Volatilization half-lives from a model river and an environmental pond were estimated at 4.8 days and 51.7 days, respectively (HSDB 1994). Methanol can be removed from the atmosphere in rain water (HSDB 1994).

Degradation & Transformation:

1. Air – Once in the atmosphere, methanol exists in the vapor phase with a half life of 17.8 days (HSDB 1994). The chemical reacts with photochemically produced hydroxyl radicals to produce formaldehyde (HSDB 1994). Methanol can also react with nitrogen dioxide in polluted air to form methyl nitrite (HSDB 1994).

2. Soil – Biodegradation is the major route of removal of methanol from soils. Several species of

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Page 189 of 262 Methylobacterium and Methylomonas isolated from soils are capable of utilizing methanol as a sole carbon source (CHEMFATE 1994).

3. Water – Most methanol is removed from water by biodegradation. The degradation products of methane and carbon dioxide were detected from aqueous cultures of mixed bacteria isolated from sewage sludge (CHEMFATE 1994). Aerobic, Gram-negative bacteria (65 strains) isolated from seawater, sand, mud, and weeks of marine origin utilized methanol as a sole carbon source (CHEMFATE 1994). Aquatic hydrolysis, oxidation, and photolysis are not significant fate processes for methanol (HSDB 1994).

4. Biota – Bioaccumulation of methanol in aquatic organisms is not expected to be significant based on an estimated bioconcentration factor of 0.2 (HSDB 1994).

Ecotoxicology:

1. Toxicity to Aquatic Organisms – Methanol has low acute toxicity to aquatic organisms; lethal concentrations are much greater than 100 mg/L. Ninety-six hour LC50 values for fish are 28,100 mg/L for Pimephales promelas (fathead minnow), 20,100 mg/L for Oncorhynchus mykiss (rainbow trout), and >28,000 mg/L for Alburnus alburnus (bleak) (AQUIRE 1994). Forty-eight hour LC50 values for Cyprinus carpio (common carp) and Carassius auratus (goldfish) are 28,000 mg/L and 1,700 mg/L, respectively (AWQUIRE 1994). Growth inhibition occurred for 4 strains of Anabaena (blue-green algae) over a range of EC50s of 2.57%-3.13% for 10-14 days (AQUIRE 1994). The LC50 for Artemia salina (brine shrimp) is >10,000 mg/L in 24 hours and that for Culex restuans (mosquito) is 20,000 mg/L in 18 hours (AQUIRE 1994).

2. Toxicity to Terrestrial Organisms – No information was found in the secondary sources searched regarding the toxicity of methanol to terrestrial organisms. However, based on the range of oral LD50s, 0.4 to 14.2 g/kg, for monkeys, rats, mice, and rabbits (Rowe and McCollister 1981), it is unlikely that methanol would be toxic to terrestrial animals at environmental levels.

3. Abiotic Effects – Methanol reacts with nitrogen dioxide in polluted atmospheres to produce methyl nitrite (HSDB 1994). According to the definition provided in the Federal Register (1992), methanol is a volatile organic compound (VOC) substance. As a VOC, methanol can contribute to the formation of photochemical smog in the presence of other VOCs.

13. DISPOSAL CONSIDERATIONS

Waste Disposal Method: Dispose in accordance with federal, state and local regulations.

14. TRANSPORT INFORMATION

U. S. Department of Transportation:

In Inner Packaging No More Than 5.0 L: Proper Shipping Name: Consumer Commodity ORM-D Per 49 CFR Part 173.10 (PG III, inner packaging no more than 5.0L)

In Packaging Over 5.0 L: Proper Shipping Name: Flammable Liquid, n.o.s. (Methanol) ID #: UN 1993 Class: 3 Hazard Label: Flammable Liquid PG: III

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Page 190 of 262 International Air Dangerous Good Regulations (IATA): Proper Shipping Name: Flammable Liquid, n.o.s. (Methanol) ID #: UN 1993 Class: 3 Hazard Label: Flammable Liquid PG: III Ltd. Qty. Packaging Instruction: Y309 (Max qty. per package 10L) Special Provision: A3

International Maritime Dangerous Goods (IMDG): Proper Shipping Name: Limited Quantities of Class 3 (This must be notated on Shipper's Declaration).

15. REGULATORY INFORMATION

THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS:

CHEMICAL NAME CAS NUMBER Methanol 67-56-1

U.S. Federal Regulations

TSCA (Toxic Substances Control Act) Status – TSCA (UNITED STATES) The intentional ingredients of this product are listed.

CERCLA RQ – 40 CFR 302.4(a) Component RQ (lbs) Methyl Alcohol 5,000

SARA 302 Components – 40 CFR 355 Appendix A None

Section 311/312 Hazard Class – 40 CFR 370.2 Immediate (X) Delayed (X) Fire (X) Reactive ( ) Sudden Release of Pressure ( )

SARA 313 Components – 40 CFR 372.65 Section 313 Component(s) CAS Number % Methanol 67-56-1 35

International Regulations

Inventory Status – DSL (CANADA) The intentional ingredients of this product are listed.

WHMIS Information: B2, D1A

ECL (SOUTH KOREA) The intentional ingredients of this product are listed.

EINECS (EUROPE) The intentional ingredients of this product are listed.

ENCS (JAPAN) The intentional ingredients of this product are listed.

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Page 191 of 262 State and Local Regulations

California Proposition 65: Methanol is on the California Proposition 65 list as a reproductive toxicant.

New Jersey RTK (Right-to-Know) Label Information: Methyl Alcohol (67-56-1)

Pennsylvania RTK (Right-to-Know) Label Information: Methanol (67-56-1)

Atmospheric Standards: The Clean Air Act Amendments of 1990 list methanol as a hazardous air pollutant.

16. OTHER INFORMATION

Contact: Tom Cholke Phone: (847) 559-2225

Old World Industries, LLC makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Old World Industries, LLC as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Old World Industries, LLC assume liability arising out of the use by others of this product referred to herein. The data in this MSDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process.

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Page 192 of 262 SAFETY DATA SHEET

PRIME SOURCE® SILKY PINK HAND SOAP

Version Revision Date: MSDS Number: Date of last issue: 03/19/2015 1.4 04/27/2015 31606-00005 Date of first issue: 11/24/2014

SECTION 1. IDENTIFICATION

Product name : PRIME SOURCE® SILKY PINK HAND SOAP

Product code : 75004224

Manufacturer or supplier's details Company name of supplier : PRIME SOURCE, LLC

Address : One City Place Drive, Suite 200 St. Louis MO 63141

Telephone : 314-997-5959

Emergency telephone : 800-424-9300

Recommended use of the chemical and restrictions on use Recommended use : Skin-care

Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification Not a hazardous substance or mixture. GHS Label element Not a hazardous substance or mixture. Other hazards None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous ingredients

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Version Revision Date: MSDS Number: Date of last issue: 03/19/2015 1.4 04/27/2015 31606-00005 Date of first issue: 11/24/2014

Chemical Name CAS-No. Concentration (%) Alcohols, C10-16, ethoxylated, sulfates, sodium 68585-34-2 >= 1 - < 5 salts Cocoamidopropyl betaine 61789-40-0 >= 1 - < 5

SECTION 4. FIRST AID MEASURES

If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur.

In case of skin contact : Wash with water and soap as a precaution. Get medical attention if symptoms occur.

In case of eye contact : Flush eyes with water as a precaution. Get medical attention if irritation develops and persists.

If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.

Most important symptoms : None known. and effects, both acute and delayed

Protection of first-aiders : No special precautions are necessary for first aid responders.

Notes to physician : Treat symptomatically and supportively.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical

Unsuitable extinguishing : None known. media

Specific hazards during fire : Exposure to combustion products may be a hazard to health. fighting

Hazardous combustion prod- : Sulfur oxides ucts Carbon oxides Metal oxides Chlorine compounds Nitrogen oxides (NOx)

Specific extinguishing : Use extinguishing measures that are appropriate to local methods circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so.

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Evacuate area.

Special protective equipment : Wear self-contained breathing apparatus for firefighting if for fire-fighters necessary. Use personal protective equipment.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Follow safe handling advice and personal protective protective equipment and equipment recommendations. emergency procedures

Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.

Methods and materials for : Soak up with inert absorbent material. containment and cleaning up For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.

SECTION 7. HANDLING AND STORAGE

Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Handle in accordance with good industrial hygiene and safety practice. Take care to prevent spills, waste and minimize release to the environment.

Conditions for safe storage : Keep in properly labeled containers. Store in accordance with the particular national regulations.

Materials to avoid : Do not store with the following product types: Strong oxidizing agents

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Version Revision Date: MSDS Number: Date of last issue: 03/19/2015 1.4 04/27/2015 31606-00005 Date of first issue: 11/24/2014

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. Hazardous components without workplace control parameters Ingredients CAS-No. Alcohols, C10-16, ethoxylated, 68585-34-2 sulfates, sodium salts Cocoamidopropyl betaine 61789-40-0 Engineering measures : Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations. Dust formation may be relevant in the processing of this product. In addition to substance-specific OELs, general limitations of concentrations of particulates in the air at workplaces have to be considered in workplace risk assessment. Relevant limits include: OSHA PEL for Particulates Not Otherwise Regulated of 15 mg/m3 - total dust, 5 mg/m3 - respirable fraction; and ACGIH TWA for Particles (insoluble or poorly soluble) Not Otherwise Specified of 3 mg/m3 - respirable particles, 10 mg/m3 - inhalable particles.

Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection.

Hand protection

Remarks : Wash hands before breaks and at the end of workday.

Eye protection : Wear the following personal protective equipment: Safety glasses

Skin and body protection : Skin should be washed after contact.

Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.

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Version Revision Date: MSDS Number: Date of last issue: 03/19/2015 1.4 04/27/2015 31606-00005 Date of first issue: 11/24/2014

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : opalescent, pink

Odor : floral

Odor Threshold : No data available

pH : 4.8 - 6.2

Melting point/freezing point : No data available

Solidification / Setting point 2.9 °C

Initial boiling point and boiling : 97.00 °C range

Flash point : > 100 °C

Evaporation rate : No data available

Flammability (solid, gas) : Not applicable

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapor pressure : No data available

Relative vapor density : No data available

Density : 1.00 g/cm3

Solubility(ies) Water solubility : soluble

Partition coefficient: n- : Not applicable octanol/water

Autoignition temperature : No data available

Decomposition temperature : The substance or mixture is not classified self-reactive.

Viscosity Viscosity, kinematic : 3,000 - 16,000 mm2/s (20 °C)

Explosive properties : Not explosive

Oxidizing properties : The substance or mixture is not classified as oxidizing.

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SECTION 10. STABILITY AND REACTIVITY

Reactivity : Not classified as a reactivity hazard.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : Can react with strong oxidizing agents. tions

Conditions to avoid : None known.

Incompatible materials : Oxidizing agents

Hazardous decomposition : No hazardous decomposition products are known. products

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method

Ingredients: Alcohols, C10-16, ethoxylated, sulfates, sodium salts: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity

Cocoamidopropyl betaine: Acute oral toxicity : LD50: > 5,000 mg/kg Method: OECD Test Guideline 401 Remarks: Based on data from similar materials

Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials

Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation

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Ingredients: Alcohols, C10-16, ethoxylated, sulfates, sodium salts: Result: Skin irritation

Serious eye damage/eye irritation Not classified based on available information. Product: Result: No eye irritation

Ingredients: Alcohols, C10-16, ethoxylated, sulfates, sodium salts: Result: Irreversible effects on the eye

Cocoamidopropyl betaine: Species: Rabbit Result: Irreversible effects on the eye Method: OECD Test Guideline 405 Remarks: Based on data from similar materials

Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization.

Ingredients: Cocoamidopropyl betaine: Test Type: Maximization Test (GPMT) Routes of exposure: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials

Germ cell mutagenicity Not classified based on available information. Ingredients: Cocoamidopropyl betaine: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Remarks: Based on data from similar materials

Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Ingestion Result: negative

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Remarks: Based on data from similar materials

Carcinogenicity Not classified based on available information. IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity Not classified based on available information. Ingredients: Cocoamidopropyl betaine: Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative Remarks: Based on data from similar materials

STOT-single exposure Not classified based on available information. STOT-repeated exposure Not classified based on available information. Repeated dose toxicity

Ingredients: Cocoamidopropyl betaine: Species: Rat NOAEL: 250 mg/kg Application Route: Ingestion Exposure time: 90 d Method: OECD Test Guideline 408 Remarks: Based on data from similar materials

Aspiration toxicity Not classified based on available information.

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SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Ingredients: Cocoamidopropyl betaine: Toxicity to fish : LC50: > 1 - 10 mg/l Exposure time: 96 h Method: ISO 7346/2 Remarks: Based on data from similar materials

Toxicity to bacteria : EC50: > 100 mg/l Method: OECD Test Guideline 209 Remarks: Based on data from similar materials

Persistence and degradability

Product: Biodegradability : Result: Biodegradable

Ingredients: Alcohols, C10-16, ethoxylated, sulfates, sodium salts: Biodegradability : Result: Readily biodegradable.

Cocoamidopropyl betaine: Biodegradability : Result: Readily biodegradable. Biodegradation: > 60 % Exposure time: 28 d Method: OECD Test Guideline 301 Remarks: Based on data from similar materials

Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods Waste from residues : Dispose of in accordance with local regulations.

Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal.

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SECTION 14. TRANSPORT INFORMATION

International Regulation

UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation

49 CFR Not regulated as a dangerous good

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : No SARA Hazards

SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

US State Regulations

Pennsylvania Right To Know Water 7732-18-5 70 - 90 % Alcohols, C10-16, ethoxylated, sulfates, 68585-34-2 1 - 5 % sodium salts Sodium chloride 7647-14-5 1 - 5 % New Jersey Right To Know Water 7732-18-5 70 - 90 % Alcohols, C10-16, ethoxylated, sulfates, 68585-34-2 1 - 5 % sodium salts Sodium chloride 7647-14-5 1 - 5 % Cocoamidopropyl betaine 61789-40-0 1 - 5 %

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California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.

The ingredients of this product are reported in the following inventories: AICS : All ingredients listed or exempt.

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)

SECTION 16. OTHER INFORMATION

Further information

NFPA: HMIS III: Flammability

HEALTH 0 1 Instability

0 0 FLAMMABILITY 1 Health

PHYSICAL HAZARD 0

0 = not significant, 1 =Slight, Special hazard. 2 = Moderate, 3 = High 4 = Extreme, * = Chronic

Sources of key data used to : Internal technical data, data from raw material SDSs, OECD compile the Material Safety eChem Portal search results and European Chemicals Agen- Data Sheet cy, http://echa.europa.eu/

Revision Date : 04/27/2015

Items where changes have been made to the previous version are highlighted in the body of this document by two vertical lines.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in-

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cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable.

US / Z8

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Material Safety Data Sheet U.S. Department of Labor May be used to comply with Occupational Safety and Health Administration OSHA's Hazard Communication Standard, (Non-Mandatory Form) 29 CFR 1910.1200. This Standard must be Form Approved consulted for specific requirements. OMB No. 1218-0072

IDENTITY (As Used on Label and List) Note: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be PROPANE marked to indicate that.

Section I Manufacturer's Name Emergency Telephone Number BernzOmatic 800-654-9011 Address (Number, Street, City, State, and ZIP Code) Telephone Number for Information 800-424-9300 1 Bernzomatic Drive Date Prepared June 11, 2011 Medina, NY 14103 Signature of Preparer (optional)

Section II - Hazard Ingredients/Identity Information Hazardous Components (Specific Chemical US OSHA PEL ACGIH TLV Other Limits % (optional) Identity; Common Name(s)) Recommended PROPANE (CAS No. 74-98-6) 1000PPM 1000PPM N/A 100

NFPA HAZARD RATINGS HMIS RATINGS Health – 1 Health – 0 Flammability – 4 Flammability – 4 Reactivity - 0 Reactivity - 0

Notes: When propane fuel is burned efficiently, the normal by-products of combustion are CO2 and H20. Inefficient burning may add CO to the by-products of combustion.

Section III - Physical/Chemical Characteristics

Boiling Point: -44° F Specific Gravity (H2O = 1): Liquid @ 60° F .51

Vapor Pressure (mm Hg.): @ 100° F 197psig Melting Point: Not Applicable Vapor Density (AIR = 1): @ 1 ATM @ 60° F 1.56 Evaporation Rate Not Applicable (Butyl Acetate = 1): Solubility in Water: Insoluble Appearance and Odor (At Normal Conditions): Colorless – Rotten Egg Odor.

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Section IV - Fire and Explosion Hazard Data Flash Point (Method Used): Flammable Limits: LEL UEL -156° F Closed Cup 2.1 9.5 Extinguishing Media: Stop flow of gas or oxygen. Special Fire Fighting Procedures: Use water to cool tanks. Unusual Fire and Explosion Hazards: Auto ignition temp. 842° F. Heavier than air (vapor density 1.5). May travel a considerable distance to a source of ignition and flashback.

Section V - Reactivity Data Stability: Unstable NO Conditions to Avoid:

Stable X N/A Incompatibility (Materials to Avoid): N/A Hazardous Decomposition or Byproducts At temperatures above the melting point metal oxide fumes may be evolved. Hazardous May Occur NO Conditions to Avoid: Polymerization: Will Not Occur X N/A

Section VI - Health Hazard Data Route(s) of Entry: Inhalation? Skin? Ingestion? YES YES NO Health Hazards (Acute and Chronic) Contact with liquid propane may cause frost burns. Carcinogenicity: NTP? IARC Monographs? OSHA Regulated? Not listed as a carcinogen Not listed as a carcinogen Not listed as a carcinogen Signs and Symptoms of Exposure: High concentrations may cause headaches and drowsiness. Medical Conditions Generally Aggravated by Exposure: Not Applicable Emergency and First Aid Procedures: Remove exposed person from contaminated area. Warning: This fuel and by-products of combustion of this fuel, contain chemicals known to the State of California to cause cancer, birth defects, and other reproductive harm.

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Section VII - Precautions for Safe Handling and Use Steps to Be Taken in Case Material is Released or Spilled: Remove ignition sources and ventilate area. Waste Disposal Method: Vent gas to atmosphere in flame free, spark free area outdoors. Precautions to Be taken in Handling and Storing: Store at temperatures below 120° F in well ventilated, spark free, flame free area. Other Precautions: None

Section VIII - Control Measures Respiratory Protection (Specify Type): Not required with normal use. Ventilation: Local Exhaust – N/A Mechanical (General) – N/A Special – N/A Other – N/A Protective Gloves: Eye Protection: Not Required Not Required Other Protective Clothing or Equipment: Not Required Work/Hygienic Practices: N/A

Section IX – Transportation Information WHMIS Classification: A – Compressed Gas & B1 – Flammable Gas Class: 2.1 Proper Shipping Name: Petroleum Gas, Liquefied Hazard Classification: Flammable Gas UN Number: 1075

Section X – Additional Information DISCLAIMER: Judgments as to the suitability of information herein or the purchaser’s purposes are necessarily the purchaser’s responsibility. Reasonable care has been taken in the preparation of this material, but there are NO WARRANTIES, NO REPRESENTATIONS, AND NO RESPONSIBILITY AS TO THE ACCURACY OR THE SUITABILITY OF THIS INFORMATION FOR ANY PURCHASER’S USE OR FOR ANY CONSEQUENCE TO USE.

This Material Safety Data Sheet is offered solely for your information, consideration and investigation. BernzOmatic provides no warranties; either express or implied, and assumes no responsibilities for the accuracy or completeness of the data contained in this document. The data in this Material Safety Data Sheet relates only to this product and does not relate to use in combination with any other material or in any process.

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1. PRODUCT AND COMPANY IDENTIFICATION

Product information Product name : RAID® WASP & HORNET KILLER 33

Recommended use : Insecticide

Manufacturer, importer, : S.C. Johnson & Son, Inc. supplier 1525 Howe Street Racine WI 53403-2236

2. HAZARDS IDENTIFICATION Classification of the substance or mixture

Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Aerosol Category 1 Extremely flammable aerosol. Aspiration hazard Category 1 May be fatal if swallowed and enters airways. Gases under pressure Compressed gas Contains gas under pressure; may explode if heated.

Labelling Hazard symbols Flame Gas cylinder Health hazard

Signal word Danger

Hazard statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways.

Precautionary statements If medical advice is needed, have product container or label at hand.

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Keep out of reach of children. Read label before use. IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Do NOT induce vomiting. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. Protect from sunlight. Store in a well-ventilated place. Dispose of contents/ container to an approved incineration plant. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Other hazards : None identified

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. Weight percent Distillates (petroleum), hydrotreated 64742-47-8 60.00 - 100.00 light Carbon dioxide 124-38-9 1.00 - 5.00 Isopropanol 67-63-0 1.00 - 5.00 Cypermethrin 52315-07-8 0.0001 - 0.10 Prallethrin 23031-36-9 0.0001 - 0.10 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES

Eye contact : No special requirements

Skin contact : No special requirements

Inhalation : No special requirements.

Ingestion : IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Do NOT induce vomiting.

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5. FIREFIGHTING MEASURES

Suitable extinguishing : Use water spray, alcohol-resistant foam, dry chemical or media carbon dioxide.

Specific hazards during : Do not use a solid water stream as it may scatter and spread firefighting fire. Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses.

Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.

NFPA Classification : NFPA Level 3 Aerosol

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Remove all sources of ignition. Wear personal protective equipment. Wash thoroughly after handling.

Methods and materials : If damage occurs to aerosol can: for containment and Contain spillage, soak up with non-combustible absorbent cleaning up material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site.

7. HANDLING AND STORAGE

Handling

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Precautions for safe : Avoid contact with skin, eyes and clothing. handling Do not enter places where used or stored until adequately ventilated. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Pressurized container. Do not pierce or burn, even after use.

Advice on protection : Keep away from sources of ignition - No smoking. against fire and explosion Do not spray on an open flame or other ignition source.

Storage Requirements for storage : Protect from sunlight. Do not expose to temperatures areas and containers exceeding 50 °C/ 122 °F. Keep away from food, drink and animal feedingstuffs. Keep in a dry, cool and well-ventilated place. Store locked up.

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8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- Basis standard units Distillates 64742-47-8 1,200 mg/m3 152 ppm - SUPPLIER (petroleum), hydrotreated light Carbon dioxide 124-38-9 9,000 mg/m3 5,000 ppm - OSHA TWA

Carbon dioxide 124-38-9 - 30,000 ppm - ACGIH STEL

Carbon dioxide 124-38-9 - 5,000 ppm - ACGIH TWA

Isopropanol 67-63-0 980 mg/m3 400 ppm - OSHA TWA

Isopropanol 67-63-0 - 400 ppm - ACGIH STEL

Isopropanol 67-63-0 - 200 ppm - ACGIH TWA

Personal protective equipment Respiratory protection : Do not spray in enclosed areas.

Hand protection : No special requirements.

Eye protection : No special requirements.

Skin and body protection : No special requirements.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

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Form : aerosol

Color : clear

Odor : characteristic

Odour Threshold : No data available

pH : Not applicable

Melting point/freezing point : No data available

Initial boiling point and : No data available boiling range

Flash point : 22 °C 71.6 °F

Evaporation rate : No data available

Flammability (solid, gas) : Sustains combustion

Upper/lower flammability or : No data available explosive limits

Vapour pressure : Not applicable

Vapour density : No data available

Relative density : 0.81 g/cm3 at 21 °CGLP: yes

Solubility(ies) : negligible

Partition coefficient: n- : No data available

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octanol/water

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity, dynamic : No data available

Viscosity, kinematic : No data available

Oxidizing properties : No data available

Volatile Organic : 3 % - additional exemptions may apply Compounds *as defined by US Federal and State Consumer Product Total VOC (wt. %)* Regulations

Other information : None identified : No data available

10. STABILITY AND REACTIVITY

Possibility of hazardous : Stable under recommended storage conditions. reactions

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : Thermal decomposition can lead to release of irritating gases products and vapours.

11. TOXICOLOGICAL INFORMATION

Emergency Overview : Danger

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Acute oral toxicity : NA GHS LD50 estimated > 5,000 mg/kg

Acute inhalation toxicity : NA GHS LC50 (dust and mist) estimated > 5.47 mg/l

Acute dermal toxicity : NA GHS LD50 estimated > 5,000 mg/kg

GHS Properties Classification Routes of entry Acute toxicity No classification proposed -

Acute toxicity No classification proposed -

Skin corrosion/irritation No classification proposed -

Serious eye No classification proposed - damage/eye irritation Skin sensitisation No classification proposed -

Respiratory No classification proposed - sensitisation Germ cell mutagenicity No classification proposed -

Carcinogenicity No classification proposed -

Reproductive toxicity No classification proposed -

Specific target organ No classification proposed - toxicity - single exposure Specific target organ No classification proposed - toxicity - repeated exposure Aspiration hazard Category 1 -

Aggravated Medical : None known.

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Condition

12. ECOLOGICAL INFORMATION

Product : The product itself has not been tested.

Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions.

Toxicity to fish Components End point Species Value Exposure time Distillates (petroleum), static test Lepomis macrochirus 2.2 mg/l 96 h hydrotreated light LC50

Carbon dioxide No data available

Isopropanol LC50 Pimephales promelas 9,640 mg/l 96 h (fathead minnow)

Cypermethrin LC50 Oncorhynchus mykiss 0.00283 96 h (rainbow trout) mg/l

NOEC Pimephales promelas 0.00001 28 d (fathead minnow) mg/l

Prallethrin LC50 Oncorhynchus mykiss 0.012 mg/l 96 h (rainbow trout)

Toxicity to aquatic invertebrates Components End point Species Value Exposure time Distillates (petroleum), No data hydrotreated light available

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Carbon dioxide No data available

Isopropanol EC50 Daphnia magna (Water 13,299 48 h flea) mg/l

Cypermethrin EC50 Daphnia magna (Water 0.00471 48 h flea) mg/l

NOEC Daphnia magna (Water 0.00004 21 d flea) mg/l

Prallethrin EC50 Daphnia magna (Water 0.0062 48 h flea) mg/l

Toxicity to aquatic plants Components End point Species Value Exposure time Distillates (petroleum), No data hydrotreated light available Carbon dioxide No data available Isopropanol EC50 Desmodesmus > 1,000 72 h subspicatus (green algae) mg/l

Cypermethrin ErC50 > 0.0033 72 h No data mg/l available Prallethrin Pseudokirchneriella 2 mg/l 96 h No data subcapitata (green algae) available

Persistence and degradability Component Biodegradation Exposure Summary time

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Distillates (petroleum), No data available hydrotreated light Carbon dioxide No data available Isopropanol 53 % 5 d Readily biodegradable

Cypermethrin 0.6 - 1.4 % 33 d Not readily biodegradable.

Prallethrin No data available Not readily biodegradable.

Bioaccumulative potential

Component Bioconcentration Partition Coefficient n- factor (BCF) Octanol/water (log) Distillates (petroleum), 61 - 159 No data available hydrotreated light Carbon dioxide No data available No data available

Isopropanol 0.96 estimated 0.05 Cypermethrin 373.4 Measured 5.3 - 5.6 Prallethrin No data available 4.49

Mobility

Component End point Value

Distillates (petroleum), No data available hydrotreated light Carbon dioxide No data available Isopropanol No data available Cypermethrin Koc 80653 - 574360

Prallethrin No data available

PBT and vPvB assessment Component Results Distillates (petroleum), Not fulfilling PBT and vPvB criteria hydrotreated light Isopropanol Not fulfilling PBT and vPvB criteria

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Cypermethrin Not fulfilling PBT and vPvB criteria

Prallethrin Not fulfilling PBT and vPvB criteria

Other adverse effects : None known.

13. DISPOSAL CONSIDERATIONS

PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label. Consumer may discard empty container in trash, or recycle where facilities exist.

14. TRANSPORT INFORMATION

Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.

Land transport Sea transport Air transport UN number 1950 1950 1950 UN proper AEROSOLS, AEROSOLS, AEROSOLS, shipping name Flammable, 2.1 Flammable, 2.1 Flammable, 2.1 Transport hazard 2.1 2 2.1 class(es) Packing group - - -

Environmental - - - hazards Special Limited quantities Limited quantities Limited quantities precautions for derogation may be derogation may be derogation may be user applicable to this applicable to this applicable to this product, please check product, please product, please check transport documents. check transport transport documents. documents.

15. REGULATORY INFORMATION

FIFRA Labeling

This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to

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certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:

CAUTION:

CONTENTS UNDER PRESSURE. Exposure to temperatures above 130° F may cause bursting. Extremely flammable. This product is extremely toxic to fish and aquatic invertebrates. Drift and runoff may be hazardous to fish in water adjacent to treated areas.

Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Registration # / Agency 4822-553/US/EPA

16. OTHER INFORMATION HMIS Ratings Health 2

Flammability 3

Reactivity 0

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NFPA Ratings Health 2

Fire 3

Reactivity 0

Special -

Further information

Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)

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Page 221 of 262 Page 222 of 262 Page 223 of 262 Page 224 of 262 Material Safety Data Sheet TWINKLE METAL POLISH & FIBERGLASS CLEANER National Fire Fire Hazard Hazardous Material Health 1 Protection Information System 0 Fire Hazard 0 Association (NFPA) Health 1 0 Reactivity (HMIS) Reactivity 0

Specific Hazard Protective None required. Emergency Blue. Paste. See Section 9. Clothing Overview CAUTION: May be mildly irritating to eyes. May be mildly irritating to skin. Section 1. Chemical Product and Company Identification

Product Name TWINKLE METAL POLISH & FIBERGLASS Code 90165 CLEANER Product Use Industrial/Institutional: Cleaning product. PMS# 433283 MSDS# 126154001 Validation Date 04/19/2000

U.S. Headquarters Print Date 04/20/2000 Drackett Professional Supersedes 04/13/2000. A Division of S.C. Johnson Commercial Markets, Inc. In Case of (800) 851-7145 8310 16th Street Emergency Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249

Section 2. Composition and Information on Ingredients

Ingredients CAS # % by Weight Exposure Limits LC50/LD50

Ammonium Hydroxide 1336-21-6 <1.0 Not available. ORAL (LD50): Acute: 350 mg/kg [Rat]. Emulsifier 68439-49-6 <1.0 Not available. ORAL (LD50): Acute: 1260 mg/kg [Rat]. Octadecanoic acid 26764-26-1 5-10 Not available. Not available. Petroleum distillates 64342-88-7 10-30 Not available. Not available. Polishing powder 1313-74-7 10-30 Not available. Not available. Water 7732-18-5 30-60 Not available. Not available.

Section 3. Hazards Identification

Routes of Entry Inhalation. Skin contact. Eye contact.

Potential Acute Health Effects Eyes May be mildly irritating to eyes. Skin May be mildly irritating to skin. Inhalation None known. Ingestion None known.

Medical Conditions None known. Aggravated by Overexposure: See Toxicological Information (section 11)

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Section 4. First Aid Measures

Eye Contact Flush immediately with plenty of water. Get medical attention if irritation occurs. Skin Contact Flush immediately with plenty of water. Get medical attention if irritation occurs. Inhalation No specific first aid measures are required. Ingestion No specific first aid measures are required.

Section 5. Fire Fighting Measures

Flammability of the Product None known. Flash Points Not available. Products of Combustion None known. Fire Fighting Media Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire and Instructions fighting procedure may be used. Special Remarks on Fire and None known. Explosion Hazards

Section 6. Accidental Release Measures

Personal Precautions Put on appropriate personal protective equipment (see Section 8). Environmental Precautions In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep and Clean-up Methods or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up.

Section 7. Handling and Storage

Handling Avoid contact with skin and eyes. FOR INDUSTRIAL USE ONLY. Storage Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN.

Section 8. Exposure Controls/Personal Protection

Engineering Controls No special ventilation requirements. General room ventilation is adequate. Personal Protection Eyes No special protective clothing is required. Hands No special protective clothing is required. Respiratory No special protective clothing is required. Feet No special protective clothing is required. Body No special protective clothing is required.

Section 9. Physical and Chemical Properties

Physical State and Solid. (Paste.) Appearance Odor Ammoniacal. Color Blue. pH 9.5 [Basic.] Specific Gravity 1.12 Boiling/Condensation Point 93°C (199.4°F) Solubility in water Negligible.

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Section 10. Stability and Reactivity

Stability and Reactivity The product is stable. Conditions of Instability None known. Incompatibility with Various Not available. Substances Hazardous Decomposition When exposed to fire: Produces normal products of combustion. Products Hazardous Polymerization Will not occur.

Section 11. Toxicological Information

Acute toxicity ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat). Effects of Chronic Exposure None known. Other Toxic Effects Not available.

Section 12. Ecological Information

Not available.

Section 13. Disposal Considerations

Waste Information No special precautions. Dispose of according to all federal, state and local regulations.

Section 14. Transport Information

DOT Classification Not regulated

TDG Classification Not regulated

Section 15. Regulatory Information Reporting in this section is based on ingredients disclosed in Section 2 US Regulations This product is not subject to the reporting requirements under California's Proposition 65. Registered Product Not applicable. Information Canadian Regulations WHMIS Classification Not applicable.

WHMIS Icon

Registered Product Not applicable. Information Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

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Section 16. Other Information Other Special Not available. Considerations

Version 1

Notice to Reader This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

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UNITED 166

MATERIAL SAFETY DATA SHEET

320 37t h A ve n u e, St. Ch arles, Il linois 6 0174 • 214 Dol o mi te Dr i ve, Do w n sview, Ontario M3J2N2 To Reorder Call: www.unitedlabsinc.com 800-323-2594

1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): 800-535-5053 PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 166 POWER UP Foaming, No Rinse Chiller Coil Cleaner March 5, 2008

HEALTH (0 = Maximum Safety) 1 REACTIVITY (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Susceptible to Release of Energy. AlwAalwyas yfols followlo Labw Label eDli rDeicreticonstions and and Cauti Cautions.ons.

4 Extreme 3 High 2 Moderate 1 Slight 0 Minimal 4 May detonate-vacate area if 2 Violent chemical change 4 materials are exposed to fire. possible-use hose stream See Hazards Identification Section of this MSDS 3 Strong shock of heat may from distance for more detailed information. detonate-use monitors from 1 Unstable if heated-use behind explosion resistant precaution. barriers. 0 Normally stable. FLAMMABILITY (0 = Maximum Safety) 2

Susceptibility of Material to Burning. PERSONAL PROTECTION: B

4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn.

2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) 3030 mg/kg Tetrasodium EDTA 64-02-8 1-5 NE NE NE (Rat/oral) Diethylene glycol monoethyl 1920-9050 111-90-0 1-5 NE NE NE ether mg/kg (Rat/oral) 450 ppm/4 hr 470 mg/kg (Rat/ 2-Butoxyethanol 111-76-2 1-5 20 ppm 50 ppm Skin (Rat/oral) Inhalation)

Propane/n-Butane 68476-86-8 1-5 1000 ppm 1000 ppm NE NE

3. HAZARDS IDENTIFICATION Eyes: May cause irritation. Can cause burning sensation, redness, and pain. Skin: May cause irritation on prolonged contact. Inhalation: Breathing vapors and mists may cause mucous membrane and respiratory irritation. Excessive overexposure may cause headache, dizziness, drowsiness, depressed respiration and heart rate, heat rhythm irregularities, shortness of breath, unconsciousness or death. Intentional misuse by concentrating and inhaling contents may be harmful or fatal. Ingestion: Exposure by ingestion is unlikely since an aerosol, but if occurs: may cause gastrointestinal irritation, nausea, vomiting, dizziness.

4. FIRST AID MEASURES Eyes: Flush with plenty of water for at least 15 minutes while holding eyelids open. Call a physician or poison control center immediately. Skin: Wash with soap and water. If irritation persists, call a physician or poison control center. Inhalation: Remove to fresh air. If irritation persists, call a physician or poison control center. If Swallowed: DO NOT induce vomiting. Call a physician or poison control center immediately.

5. FIRE FIGHTING MEASURES Flash Point (TCC): (of Concentrate Only) >154°F/>68°C Explosive Limits: Lower (LEL): 1.8 Upper (UEL): 9.5 Flame Projection (Aerosol): Product is not required to be labeled as flammable per 16 CFR 1500.3 and 1500.45. Hazardous Products of Combustion: When strongly heated, as in a fire, may produce oxides of carbon. Fire and Explosion Hazards: Contents under pressure. Keep away from heat and open flames. Container may rupture or explode in the heat of a fire. Prolonged exposure to temperatures above 54°C/130°F may cause cans to burst. Extinguishing Media: Water spray, Foam, Carbon dioxide, Dry chemical. Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water fog to prevent vapor pressure build up. Use equipment or shielding, as required, to protect personnel from bursting, rupturing or venting containers.

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6. ACCIDENTAL RELEASE MEASURES

Small Spills: Ventilate area. Remove all sources of ignition. Soak up spill with an inert absorbent and place into a designated disposal container. Large Spills: Wear appropriate protective clothing. Remove all sources of ignition. Soak up spill with an inert absorbent and place into a designated disposal container.

7. HANDLING AND STORAGE

Store in a cool, dry area away from heat or open flame. Do not puncture or incinerate containers. Do not store at temperatures above 120°F/ 49°C. Do not expose to direct sunlight. For Industrial and Institutional use only. NFPA Code 30 B Storage Level Number 1 Aerosol. Avoid breathing vapors or spray mist. Avoid contact with eyes. Avoid prolonged contact with skin or clothing. Wash thoroughly with soap and water after handling. KEEP OUT OF REACH OF CHILDREN.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Eyes: Safety glasses or safety goggles are recommended. Skin: Chemical resistant gloves are recommended if needed to avoid prolonged skin contact. Respiratory: None required if good ventilation is maintained. If exposure exceeds TLV levels, use a NIOSH/MSHA approved respirator to prevent overexposure. Engineering Controls: General ventilation is adequate under normal conditions; mechanical ventilation may be required for use in poorly ventilated areas or when large amounts are used.

9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point: NA Specific Gravity: 0.9697 (H2O=1) Vapor Pressure: 116@130°F/ 51@70°F Melting Point: ND Vapor Density: >1 Evaporation Rate: ND Solubility in Water: Soluble pH: 12-12.5 Appearance and Odor: Aerosol; hazy, yellow spray with floral odor.

10. STABILITY AND REACTIVITY

Hazardous Polymerization: Will not occur. Hazardous Decomposition: When ignited or strongly heated, as in a fire this product may produce oxides of carbon. Chemical Stability: Stable Incompatibility: Avoid contact with strong oxidizing agents, acids and bases.

11. TOXICOLOGICAL INFORMATION

Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? Yes

12. ECOLOGICAL INFORMATION ND

13. DISPOSAL CONSIDERATIONS

Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Disposal regulations may be different for each state and/or locality.

14. TRANSPORT INFORMATION DOT: Available upon request TDG: Available upon request UN: Availabale upon request

15. REGULATORY INFORMATION

VOC(Volatile Organic Compounds): 8% TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: ND SARA Title III Section 311/312: ND SARA Title III Section 313 Toxic Chemicals: None WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR.

16. OTHER INFORMATION Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN.

UNITED 166 POWER UP PREPARED BY: Sandy Kopacz

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UNITED 195 MATERIAL SAFETY DATA SHEET 320 37th Avenue , St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca 800-323-2594

1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): 800-535-5053 PRODUCT NAME USE/DESCRIPTION REVISION DATE UNITED 195 SMELL JEL Jellied Deodorant Spray December 22, 2012

HMIS III HEALTH (0 = Maximum Safety) 0 PHYSICAL HAZARD (0 = Maximum Safety) 0 Always follow Label Directions and Cautions. Susceptible to Release of Energy. AlwaysAlways follow follow Label Label Directions Directions and and Cautions. Cautions.

* Chronic 2 Moderate 4 May detonate-vacate area if 2 Violent chemical change 4 4 Severe 1 Slight materials are exposed to fire. possible-use hose stream 3 Serious 0 Minimal 3 Strong shock of heat may from distance See Hazards Identification Section of this MSDS detonate-use monitors from 1 Unstable if heated-use for more detailed information. behind explosion resistant precaution. barriers. 0 Normally stable.

FLAMMABILITY (0 = Maximum Safety) 1 Susceptibility of Material to Burning. PERSONAL PROTECTION: A

4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn.

2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA) (PEL-TWA) (Species/Route) (Species) 400 ppm >5045 mg/kg 16000 ppm Isopropyl alcohol 67-63-0 5-10 200 ppm 980 mg/m3 (Rat/oral) 8 hr (Rat) 22000-31000 1.2-propanediol 57-55-6 5-10 N/A N/A N/A Mg/kg(Rat/oral) 1000 ppm 1000 ppm Propane/N-Butane 68476-85-7 10-30 N/A N/A 1800 mg/m3 1800 mg/m3

3. HAZARDS IDENTIFICATION Emergency Overview: Aerosol under pressure do not expose to high temperatures 120°F/49°C or store in direct sunlight. Routes of Entry: Eyes, Skin, Ingestion, Inhalation Eyes: May cause irritation. Skin: May cause slight irritation, possible dryness with prolonged contact. Inhalation: Intentional overexposure to mist or vapors may result in dizziness and headache. Ingestion: May cause nausea or gastric discomfort. Chronic Health Hazards: None known. Medical Conditions Generally Aggravated by Exposure: None known. Carcinogenicity (NTP/IARC/OSHA): None

4. FIRST AID MEASURES Eyes: Flush with plenty of water for 15 minutes and call a physician immediately. Skin: Wash with soap and water. If irritation persists, call a physician. If Inhaled: Remove patient to fresh air immediately. Apply artificial respiration if needed and call a physician. If Swallowed: Drink several glasses of water. Call a physician immediately.

5. FIRE FIGHTING MEASURES Flash Point (TCC): 180°F/82.2°C Explosive Limits: Lower (LEL): ND Upper (UEL): ND Flame Projection (Aerosol): Nonflammable per 16 CFR 1500.45 Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Fire and Explosion Hazards: Do not expose aerosols to temperatures above 120°F/49°C or the container may burst, rupture or vent. Extinguishing Media: Water, foam, Carbon dioxide, Dry chemical, Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water to prevent vapor pressure build up. Prevent runoff from entering sewers and public waterways.

6. ACCIDENTAL RELEASE MEASURES Small Spills: Pick up small spills with rag or towel. Clean surface thoroughly to remove residual contamination. Large Spills: Remove sources of ignition and ventilate area. Soak up with an inert absorbent and place in designated disposal container. Prevent material from entering sewers or drains. Wash area thoroughly to remove residual contamination.

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7. HANDLING AND STORAGE Keep this product properly labeled and store in a cool, well-ventilated area, away from heat or other sources of ignition. Do not expose to direct sunlight or store at temperatures above 120°F/49°C. may cause bursting. Wash hands and face with soap and water after using this product. Keep out of reach of children.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses recommended if direct contact is possible. Skin: Chemical resistant gloves recommended only for prolonged or repeated exposure. Respiratory: Not normally needed. If TLV is exceeded, an organic vapor cartridge respirator or SCBA may be needed. Engineering Controls: Ventilation not normally required and local exhaust generally adequate.

9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 212°F/100°C (Initial-Concentrate) Specific Gravity: 0.99 (Concentrate@77°F) Vapor Pressure: 17.5 (@ 77°F Melting Point: ND Vapor Density: >1 Evaporation Rate: <1 Solubility in Water: Soluble pH: 7.6—7.7 VOC (Volatile Organic Compounds): 24.9% Appearance and Odor: White aerosol foam in orange or mulberry scent

10. STABILITY AND REACTIVITY Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce carbon dioxide and carbon monoxide. Chemical Stability: Stable Conditions to Avoid (Polymerization): None Incompatibility: Avoid contact with strong oxidizers, alkalies, and acids.

11. TOXICOLOGICAL INFORMATION See section 2

12. ECOLOGICAL INFORMATION N/A

13. DISPOSAL CONSIDERATIONS Consult your local, state, provincial and federal regulations for proper disposal guidelines. Do not puncture or incinerate containers. Wrap container and place in trash collection. Disposal regulations may be different for each state and/or locality. Aerosol cans when vented to atmospheric pressure through normal use pose no disposal hazard. RCRA Hazard Class: Considered non-hazardous under RCA, however product should be fully characterized prior to disposal (40 CFR 261)

14. TRANSPORT INFORMATION US DOT: Consumer Commodity, ORM-D IMDG-Water/Ocean: UN 1950, AEROSOLS IN LIMITED QUANTITIES OF CLASS 2, 2.2, PG None IATA-Air: UN 1950, AEROSOLS IN LIMITED QUANTITIES OF CLASS 2, 2.2 PG None

15. REGULATORY INFORMATION

U.S. Federal Regulations: TSCA (Toxic Substances Control Act): All Chemicals are listed or exempt CERCLA (Comprehensive Response Compensation, and Liability Act): None SARA Title III Section 302 EHS: None SARA Title III Section 311/312: None SARA Title III Section 313 Toxic Chemicals: Isopropyl Alcohol – CAS#67-63-0

State Regulations: California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No Right-to-know acts for Rhode Island, Pennsylvania, Florida, Minnesota, Massachusetts, New Jersey, Tennessee, Connecticut hazardous material survey. Illinois toxic substances disclosure to employee act.

195WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR.

California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No

UNITED 195 SMELL JEL PREPARED BY: Sandy Kopacz

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UNITED 77 MATERIAL SAFETY DATA SHEET 320 37th Avenue , St. Charles, Illinois 60174 To Reorder Call: www.unitedlabsinc.com . www.unitedlabsinc.ca 800-323-2594

1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES 24 Hour INFOTRAC (US and CANADA): 800-535-5053 PRODUCT NAME USE/DESCRIPTION REVISION DATE ® UNITED 77 BIATRON Organic Digester and Liquid Drain Cleaner February 8, 2013

HMIS III HEALTH (0 = Maximum Safety) 3 PHYSICAL HAZARD (0 = Maximum Safety) 2 Always follow Label Directions and Cautions. Susceptible to Release of Energy. AlwaysAlways follow follow Label Label Directions Directions and and Cautions. Cautions.

FLAMMABILITY (0 = Maximum Safety) 0 Susceptibility of Material to Burning. PERSONAL PROTECTION: p, n, o

4 Extremely flammable. 1 Must be preheated 3 Ignites at normal temperature. to burn. 2 Ignites when moderately heated. 0 Will not burn.

2. COMPOSITION/INFORMATION ON INGREDIENTS ACGIH OSHA LD50 LC50 Hazardous Ingredients CAS# %Range (TLV-TWA ) (PEL-TWA) (Species/Route) (Species) 2140 mg/kg 347 ppm Sulfuric acid 7664-93-9 60-100 1 mg/m3 1 mg/m3 (rat/oral) 1 hr/rat

3. HAZARDS IDENTIFICATION

Eyes: Very corrosive. Causes severe burns and blindness. Do not wear contact lenses. Skin: Very corrosive. Causes severe and painful burns. Inhalation: May cause headache, drowsiness, and central nervous system depression. Mist causes severe irritation of nose, throat and lungs. Ingestion: Very corrosive. Causes severe burns to mouth, throat, and stomach. Harmful or fatal.

4. FIRST AID MEASURES

Eyes: Flood with cool water for at least 15 minutes and get medical attention immediately. DO NOT wear contact lenses. Skin: Flood with cool water for several minutes until all the product is washed away. Then cover area with moistened sodium bicarbonate. Seek medical attention immediately. Inhalation: Remove patient to fresh air immediately. If patient is not breathing, apply artificial respiration. Seek medical attention immediately. Ingestion: DO NOT induce vomiting. If conscious, immediately drink large amounts of water to reduce the concentration. Give milk of magnesia or whites of eggs beaten into water. Avoid carbonates or sulfates. Get medical attention immediately.

5. FIRE FIGHTING MEASURES

Flash Point (TCC): None Explosive Limits: Lower (LEL): NA Upper (UEL): NA Flame Projection (Aerosol): NA Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce oxides of sulfur and carbon. Fire and Explosion Hazards: This product reacts violently with generation of great heat, when water is added. Temperatures may exceed 240F and may boil and splatter the mixture. May react with metals to release hydrogen gas. Extinguishing Media: Use media appropriate for surrounding material. Use water spray to cool containers exposed to fire. Do not get water inside containers. Fire Fighting Instructions: Avoid spraying water onto leaking containers. Water applied directly to sulfuric acid causes evolution of heat and splattering. Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus. Stay upwind if product is involved in a fire.

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6. ACCIDENTAL RELEASE MEASURES

Small Spills: Wear protective equipment and clothing before entering area. Ventilate area. Avoid contact with skin and eyes. Neutralize spill with soda ash. Flush area with water using care. Unneutralized acid will generate heat when mixed with water. Large Spills: Same as above.

7. HANDLING AND STORAGE

Store in a secure area out of reach of children and unauthorized persons. Keep containers tightly closed when not in use. Do not store near incompatible materials, such as strong alkalis or flammables. Store product in a well-ventilated area. Do not add water to concentrate. Wear appropriate personal protective equipment. Do not breathe sprays or mists. Do not get in eyes, on skin or on clothing. Do not ingest. Deactivating chemicals: Lime, limestone, sodium carbonate, sodium bicarbonate, diluted sodium hydroxide, dilute aqua ammonia.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Eyes: Safety goggles and Face Shield are recommended. Skin: Chemical resistant gloves are recommended. Respiratory: To avoid breathing fumes, use NIOSH-approved respirator. Engineering Controls: Mechanical ventilation recommended when handling in enclosed/tight spaces. Other Protective Equipment: Coveralls, boots and or other acid resistant protective clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point: 535F/279C Specific Gravity: 1.835 (H2O=1) Vapor Pressure: 1.7 mmHg Melting Point: -31F/35C Vapor Density: >1 (air=1) Evaporation Rate: <1 (BA=1) Solubility in Water: Complete pH: 1 Appearance and Odor: Slightly viscous, clear, tan colored liquid with no scent

10. STABILITY AND REACTIVITY

Hazardous Polymerization: Will not occur. Hazardous Decomposition: When strongly heated, as in a fire, this product may produce toxic gases and vapors (sulfur dioxide, sulfuric acid vapors and sulfur trioxide) may be released when sulfuric acid decomposes. Chemical Stability: Stable under normal conditions, but reacts violently with water and organic materials with evolution of heat. Under fire conditions, decomposes to form sulfur oxides. Incompatibility: Do not mix this product with other cleaning chemicals, especially bases or oxidizers such as bleach.

11. TOXICOLOGICAL INFORMATION Carcinogenicity (NTP/IARC/OSHA): None California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm? No

12. ECOLOGICAL INFORMATION ND

13. DISPOSAL CONSIDERATIONS Consult your local, state and federal regulations for proper disposal guidelines. Disposal regulations may be different for each state and/or locality.

14. TRANSPORT INFORMATION DOT- Land: UN 1830, Sulfuric Acid, 8, PG II TDG - Land: UN 1830, Sulphuric Acid, 8, PG II UN: Available upon request.

15. REGULATORY INFORMATION VOC Volatile Organic Compounds): None TSCA (Toxic Substances Control Act): Listed SARA Title III Section 302 EHS: Extremely hazardous substance. SARA Title III Section 311/312: Immediate health, delayed health and physical hazard. SARA Title III Section 313 Toxic Chemicals: Sulfuric acid CAS# 7664-93-9 WHMIS Classification: E, D1A This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the MSDS contains all the information required by the CPR.

® UNITED 77 BIATRON PREPARED BY: Sandy Kopacz

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Page 234 of 262 SAFETY DATA SHEET

1. Identification Product identifier Unleaded Gasoline - All Grades Other means of identification SDS number SER20 Product code 8950A; 8951A Recommended use Fuel. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Silver Eagle Refining Inc. Address 2355 South 1100 West Woods Cross Utah 84087 US Telephone number 801-298-3211 Contact person Quality Assurance Manager Emergency telephone CHEMTREC 800-424-9300 number

2. Hazard(s) identification Physical hazards Flammable liquids Category 1 Health hazards Skin corrosion/irritation Category 2 Germ cell mutagenicity Category 1B Carcinogenicity Category 1A Reproductive toxicity Category 2 Specific target organ toxicity, single exposure Category 3 respiratory tract irritation Specific target organ toxicity, single exposure Category 3 narcotic effects Specific target organ toxicity, repeated Category 1 (Bone Marrow, Central nervius exposure System, Blood) Aspiration hazard Category 1 Environmental hazards Hazardous to the aquatic environment, acute Category 1 hazard Hazardous to the aquatic environment, Category 1 long-term hazard OSHA defined hazards Not classified. Label elements

Signal word Danger Hazard statement Extremely flammable liquid and vapor. Causes skin irritation. May cause genetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. May cause respiratory irritation. May cause drowsiness or dizziness. Causes damage to organs (Central Nervous System, Blood, Bone Marrow) through prolonged or repeated exposure. May be fatal if swallowed and enters airways. Very toxic to aquatic life with long lasting effects.

Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 1 / 15 Page 235 of 262 Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe mist or vapor. Use only outdoors or in a well-ventilated area. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Response In case of fire: Use appropriate media to extinguish. If ingested: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin (or hair): Immediately remove all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before re-use. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If exposed or concerned: Get medical advice/attention. Specific treatment (see this label). Collect spillage. Storage Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise Static Accumulating Liquid. Static accumulating flammable liquid can become electrostatically classified (HNOC) charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. 3. Composition/information on ingredients Mixtures Chemical name CAS number % Gasoline 86290-81-5 88-100

Toluene 108-88-3 5-25

Xylene 1330-20-7 5-20

Ethanol 64-17-5 9-10

2-Methylbutane 78-78-4 0-10

2,3-Dimethylbutane 79-29-8 0-5

2-Methylheptane 592-27-8 0-5

2-Methylhexane 591-76-4 0-5

2-Methylpentane 107-83-5 0-5

3-Methylheptane 589-81-1 0-5

3-Methylhexane 589-34-4 0-5

3-Methylpentane 96-14-0 0-5

Benzene 71-43-2 0-5

Butane 106-97-8 0-5

Cyclohexane 110-82-7 0-5

Ethylbenzene 100-41-4 0-5

Ethyltoluene 25550-14-5 0-5

Heptane 142-82-5 0-5

Octane 111-65-9 0-5

Pentane 109-66-0 0-5

Trimethylbenzene 25551-13-7 0-5

n-Hexane 110-54-3 0-5

Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 2 / 15 Page 236 of 262 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Immediately remove all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important Irritation of eyes and mucous membranes. Irritation of nose and throat. Aspiration may cause symptoms/effects, acute and pulmonary edema and pneumonitis. May cause respiratory irritation. Vapors have a narcotic effect delayed and may cause headache, fatigue, dizziness and nausea. Skin irritation. May cause redness and pain. Indication of immediate Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an treatment needed ambulance. Continue flushing during transport to hospital. Keep victim under observation. Symptoms may be delayed. General information Immediately remove all contaminated clothing. If exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Water may be an ineffective extinguishing medium. Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source the chemical of ignition and flash back. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures. This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with and precautions for firefighters face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire fighting In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do equipment/instructions so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Extremely flammable liquid and vapor. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of protective equipment and low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). emergency procedures Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 3 / 15 Page 237 of 262 Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take containment and cleaning up precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is NOT miscible in water. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Clean surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust ventilation. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices.

For additional information on equipment bonding and grounding, refer to the American Petroleum Institute (API) Recommended Practice 2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or National Fire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or National Fire Protection Association (NFPA) 70, "National Electrical Code".

Use only as a motor fuel. Do not siphon by mouth. Conditions for safe storage, Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge including any incompatibilities build-up by using common bonding and grounding techniques. Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS).

Tank storage: Tank must be equipped with foam injection.

8. Exposure controls/personal protection Occupational exposure limits US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Components Type Value Benzene (CAS 71-43-2) STEL 5 ppm TWA 1 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value 2-Methylheptane (CAS PEL 2350 mg/m3 592-27-8)

Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 4 / 15 Page 238 of 262 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value 500 ppm 3-Methylheptane (CAS PEL 2350 mg/m3 589-81-1) 500 ppm 3-Methylhexane (CAS PEL 2000 mg/m3 589-34-4) 500 ppm Cyclohexane (CAS PEL 1050 mg/m3 110-82-7) 300 ppm Ethanol (CAS 64-17-5) PEL 1900 mg/m3 1000 ppm Ethylbenzene (CAS PEL 435 mg/m3 100-41-4) 100 ppm Heptane (CAS 142-82-5) PEL 2000 mg/m3 500 ppm n-Hexane (CAS 110-54-3) PEL 1800 mg/m3 500 ppm Octane (CAS 111-65-9) PEL 2350 mg/m3 500 ppm Pentane (CAS 109-66-0) PEL 2950 mg/m3 1000 ppm Xylene (CAS 1330-20-7) PEL 435 mg/m3 100 ppm US. OSHA Table Z-2 (29 CFR 1910.1000)

Components Type Value Benzene (CAS 71-43-2) Ceiling 25 ppm TWA 10 ppm Toluene (CAS 108-88-3) Ceiling 300 ppm TWA 200 ppm US. ACGIH Threshold Limit Values

Components Type Value 2,3-Dimethylbutane (CAS STEL 1000 ppm 79-29-8) TWA 500 ppm 2-Methylbutane (CAS TWA 1000 ppm 78-78-4) 2-Methylhexane (CAS STEL 500 ppm 591-76-4) TWA 400 ppm 2-Methylpentane (CAS STEL 1000 ppm 107-83-5) TWA 500 ppm 3-Methylhexane (CAS STEL 500 ppm 589-34-4) TWA 400 ppm 3-Methylpentane (CAS STEL 1000 ppm 96-14-0) TWA 500 ppm Benzene (CAS 71-43-2) STEL 2.5 ppm TWA 0.5 ppm Butane (CAS 106-97-8) STEL 1000 ppm Cyclohexane (CAS TWA 100 ppm 110-82-7) Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 5 / 15 Page 239 of 262 US. ACGIH Threshold Limit Values

Components Type Value Ethanol (CAS 64-17-5) STEL 1000 ppm Ethylbenzene (CAS TWA 20 ppm 100-41-4) Gasoline (CAS 86290-81-5) STEL 500 ppm TWA 300 ppm Heptane (CAS 142-82-5) STEL 500 ppm TWA 400 ppm n-Hexane (CAS 110-54-3) TWA 50 ppm Octane (CAS 111-65-9) TWA 300 ppm Pentane (CAS 109-66-0) TWA 1000 ppm Toluene (CAS 108-88-3) TWA 20 ppm Trimethylbenzene (CAS TWA 25 ppm 25551-13-7) Xylene (CAS 1330-20-7) STEL 150 ppm TWA 100 ppm US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value 2,3-Dimethylbutane (CAS Ceiling 1800 mg/m3 79-29-8) 510 ppm TWA 350 mg/m3 100 ppm 2-Methylheptane (CAS Ceiling 1800 mg/m3 592-27-8) 385 ppm TWA 350 mg/m3 75 ppm 2-Methylpentane (CAS Ceiling 1800 mg/m3 107-83-5) 510 ppm TWA 350 mg/m3 100 ppm 3-Methylheptane (CAS Ceiling 1800 mg/m3 589-81-1) 385 ppm TWA 350 mg/m3 75 ppm 3-Methylhexane (CAS Ceiling 1800 mg/m3 589-34-4) 440 ppm TWA 350 mg/m3 85 ppm 3-Methylpentane (CAS Ceiling 1800 mg/m3 96-14-0) 510 ppm TWA 350 mg/m3 100 ppm Benzene (CAS 71-43-2) STEL 1 ppm TWA 0.1 ppm Butane (CAS 106-97-8) TWA 1900 mg/m3 800 ppm Cyclohexane (CAS TWA 1050 mg/m3 110-82-7) 300 ppm Ethanol (CAS 64-17-5) TWA 1900 mg/m3 1000 ppm Ethylbenzene (CAS STEL 545 mg/m3 100-41-4)

Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 6 / 15 Page 240 of 262 US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value 125 ppm TWA 435 mg/m3 100 ppm Heptane (CAS 142-82-5) Ceiling 1800 mg/m3 440 ppm TWA 350 mg/m3 85 ppm n-Hexane (CAS 110-54-3) TWA 180 mg/m3 50 ppm Octane (CAS 111-65-9) Ceiling 1800 mg/m3 385 ppm TWA 350 mg/m3 75 ppm Pentane (CAS 109-66-0) Ceiling 1800 mg/m3 610 ppm TWA 350 mg/m3 120 ppm Toluene (CAS 108-88-3) STEL 560 mg/m3 150 ppm TWA 375 mg/m3 100 ppm Trimethylbenzene (CAS TWA 125 mg/m3 25551-13-7) 25 ppm Xylene (CAS 1330-20-7) STEL 655 mg/m3 150 ppm TWA 435 mg/m3 100 ppm Biological limit values ACGIH Biological Exposure Indices

Components Value Determinant Specimen Sampling Time Benzene (CAS 71-43-2) 25 µg/g S-Phenylmerca Creatinine * pturic acid in urine Ethylbenzene (CAS 0.15 g/g Sum of Creatinine * 100-41-4) mandelic acid in urine and phenylglyoxylic acid n-Hexane (CAS 110-54-3) 0.4 mg/l 2,5-Hexanedio Urine * n, without hydrolysis Toluene (CAS 108-88-3) 0.3 mg/g o-Cresol, with Creatinine * hydrolysis in urine 0.03 mg/l Toluene Urine * 0.02 mg/l Toluene Blood * Xylene (CAS 1330-20-7) 1.5 g/g Methylhippuric Creatinine * acids in urine * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Benzene (CAS 71-43-2) Can be absorbed through the skin. n-Hexane (CAS 110-54-3) Can be absorbed through the skin. Toluene (CAS 108-88-3) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Toluene (CAS 108-88-3) Skin designation applies. US ACGIH Threshold Limit Values: Skin designation Benzene (CAS 71-43-2) Can be absorbed through the skin.

Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 7 / 15 Page 241 of 262 n-Hexane (CAS 110-54-3) Can be absorbed through the skin. Appropriate engineering Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air controls changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Chemical respirator with organic vapor cartridge and full facepiece. Skin protection Hand protection Wear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Nitrile or neoprene gloves are recommended. Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such considerations as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color Clear to bronze. Odor Strong Hydrocarbon. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling 85 - 437 °F (29 - 225 °C) range Flash point -45.0 °F (-43 °C) Evaporation rate 10 - 11 (BuAc=1) Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower 1.4 (%) Flammability limit - upper 7.6 (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 200 - 450 mm Hg ( 68°F) Vapor density > 1 ( Air=1) Relative density 0.74 (H20=1) Solubility(ies) Solubility (water) Gasoline: negliglible. Ethanol: readily soluble in water Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature > 530 °F (> 277 °C) Decomposition temperature Not available. Viscosity Not available. 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions.

Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 8 / 15 Page 242 of 262 Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Strong acids. Strong oxidizing agents. Halogens. Hazardous decomposition No hazardous decomposition products are known. products 11. Toxicological information Information on likely routes of exposure Inhalation Headache. Nausea, vomiting. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Symptoms related to the May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. physical, chemical and Aspiration may cause pulmonary edema and pneumonitis. Irritation of eyes and mucous toxicological characteristics membranes. May cause respiratory irritation. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. May be harmful if inhaled. Narcotic effects. May cause respiratory irritation. Components Species Test Results 2-Methylbutane (CAS 78-78-4) Acute Inhalation LC50 Mouse 1000 mg/l, 1 Hours 450 mg/l, 2 Hours Benzene (CAS 71-43-2) Acute Oral LD50 Rat 930 mg/kg Cyclohexane (CAS 110-82-7) Acute Oral LD50 Rat 12705 mg/kg Ethanol (CAS 64-17-5) Acute Inhalation LC50 Rat 30000 mg/m3 Ethylbenzene (CAS 100-41-4) Acute Dermal LD50 Rabbit 15400 mg/kg Inhalation LC50 Rat 17.4 mg/m³, 4 Hours Oral LD50 Rat 35000 - 47000 mg/kg Heptane (CAS 142-82-5) Acute Inhalation LC50 Rat 103 mg/l, 4 Hours

Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 9 / 15 Page 243 of 262 Components Species Test Results Toluene (CAS 108-88-3) Acute Dermal LD50 Rabbit 14.1 ml/kg Inhalation LC50 Rat 49000 mg/m³, 4 Hours Oral LD50 Rat 636 mg/kg Xylene (CAS 1330-20-7) Acute Dermal LD50 Rabbit 12126 mg/kg, 24 Hours Inhalation LC50 Rat 6350 ppm, 4 Hours Oral LD50 Rat 3523 mg/kg Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Respiratory or skin sensitization Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity May cause genetic defects. Carcinogenicity May cause cancer. IARC Monographs. Overall Evaluation of Carcinogenicity Benzene (CAS 71-43-2) 1 Carcinogenic to humans. Ethylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans. Gasoline (CAS 86290-81-5) 2B Possibly carcinogenic to humans. Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans. Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans. NTP Report on Carcinogens Benzene (CAS 71-43-2) Known To Be Human Carcinogen. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Benzene (CAS 71-43-2) Cancer Reproductive toxicity Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals. Suspected of damaging fertility or the unborn child. Specific target organ toxicity - May cause respiratory irritation. May cause drowsiness and dizziness. single exposure Specific target organ toxicity - Causes damage to organs (Bone Marrow, Central nervius System, Blood) through prolonged or repeated exposure repeated exposure. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. 12. Ecological information Ecotoxicity Very toxic to aquatic life with long lasting effects. Components Species Test Results Cyclohexane (CAS 110-82-7) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 3.961 - 5.181 mg/l, 96 hours Ethylbenzene (CAS 100-41-4) Aquatic Crustacea EC50 Daphnia 1.81 mg/l, 48 hours

Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 10 / 15 Page 244 of 262 Components Species Test Results Fish LC50 Bluegill (Lepomis macrochirus) 32 - 88 mg/l, 96 hours Fathead minnow (Pimephales promelas) 12.1 mg/l, 96 hours Toluene (CAS 108-88-3) Aquatic Crustacea EC50 Water flea (Daphnia magna) 5.46 - 9.83 mg/l, 48 hours Fish LC50 Pink salmon (Oncorhynchus gorbuscha) 6.86 - 8.48 mg/l, 96 hours Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2,3-Dimethylbutane (CAS 79-29-8) 3.42 2-Methylbutane (CAS 78-78-4) 2.3 2-Methylheptane (CAS 592-27-8) 5.18 2-Methylpentane (CAS 107-83-5) 3.74 3-Methylheptane (CAS 589-81-1) 5.18 3-Methylhexane (CAS 589-34-4) 4.66 3-Methylpentane (CAS 96-14-0) 3.6 Benzene (CAS 71-43-2) 2.13 Butane (CAS 106-97-8) 2.89 Cyclohexane (CAS 110-82-7) 3.44 Ethanol (CAS 64-17-5) -0.31 Ethylbenzene (CAS 100-41-4) 3.15 Heptane (CAS 142-82-5) 4.66 Octane (CAS 111-65-9) 5.18 Pentane (CAS 109-66-0) 3.39 Toluene (CAS 108-88-3) 2.73 Xylene (CAS 1330-20-7) 3.2 n-Hexane (CAS 110-54-3) 3.9 Mobility in soil No data available. Other adverse effects The product is a volatile organic compound which has a photochemical ozone creation potential. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. D001: Waste Flammable material with a flash point <140 °F Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN number UN1203 UN proper shipping name Gasoline Transport hazard class(es) Class 3 Subsidiary risk - Label(s) 3 Packing group II Environmental hazards Marine pollutant No Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Special provisions 144, 177, B1, B33, IB2, T4

Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 11 / 15 Page 245 of 262 Packaging exceptions 150 Packaging non bulk 202 Packaging bulk 242 IATA UN number UN1203 UN proper shipping name Gasoline Transport hazard class(es) Class 3 Subsidiary risk - Label(s) 3 Packing group II Environmental hazards No ERG Code 3H Special precautions for user Read safety instructions, SDS and emergency procedures before handling. IMDG UN number UN1203 UN proper shipping name GASOLINE Transport hazard class(es) Class 3 Subsidiary risk - Label(s) 3 Packing group II Environmental hazards Marine pollutant No EmS F-E, S-E Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Transport in bulk according to Not applicable. However, this product is a liquid and if transported in bulk covered under Annex II of MARPOL 73/78 and MARPOL 73/78, Annex I. the IBC Code 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. One or more components are not listed on TSCA. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Benzene (CAS 71-43-2) Cancer Central nervous system Blood Aspiration Skin Eye respiratory tract irritation Flammability CERCLA Hazardous Substance List (40 CFR 302.4) 2,3-Dimethylbutane (CAS 79-29-8) LISTED 2-Methylbutane (CAS 78-78-4) LISTED 2-Methylheptane (CAS 592-27-8) LISTED 2-Methylhexane (CAS 591-76-4) LISTED 2-Methylpentane (CAS 107-83-5) LISTED 3-Methylheptane (CAS 589-81-1) LISTED 3-Methylhexane (CAS 589-34-4) LISTED 3-Methylpentane (CAS 96-14-0) LISTED Benzene (CAS 71-43-2) LISTED Butane (CAS 106-97-8) LISTED Cyclohexane (CAS 110-82-7) LISTED Ethanol (CAS 64-17-5) LISTED Ethylbenzene (CAS 100-41-4) LISTED Gasoline (CAS 86290-81-5) LISTED Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 12 / 15 Page 246 of 262 Heptane (CAS 142-82-5) LISTED n-Hexane (CAS 110-54-3) LISTED Octane (CAS 111-65-9) LISTED Pentane (CAS 109-66-0) LISTED Toluene (CAS 108-88-3) LISTED Xylene (CAS 1330-20-7) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. Toluene 108-88-3 5-25 Xylene 1330-20-7 5-20 Benzene 71-43-2 0-5 Cyclohexane 110-82-7 0-5 Ethylbenzene 100-41-4 0-5 Trimethylbenzene 25551-13-7 0-5 n-Hexane 110-54-3 0-5 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Benzene (CAS 71-43-2) Ethylbenzene (CAS 100-41-4) n-Hexane (CAS 110-54-3) Toluene (CAS 108-88-3) Xylene (CAS 1330-20-7) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) 2-Methylbutane (CAS 78-78-4) Butane (CAS 106-97-8) Pentane (CAS 109-66-0) Safe Drinking Water Act Not regulated. (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Toluene (CAS 108-88-3) 6594 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Toluene (CAS 108-88-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Toluene (CAS 108-88-3) 594 US state regulations US. Massachusetts RTK - Substance List 2,3-Dimethylbutane (CAS 79-29-8) 2-Methylbutane (CAS 78-78-4) 2-Methylheptane (CAS 592-27-8) 2-Methylhexane (CAS 591-76-4) 2-Methylpentane (CAS 107-83-5) 3-Methylheptane (CAS 589-81-1) 3-Methylhexane (CAS 589-34-4) 3-Methylpentane (CAS 96-14-0) Benzene (CAS 71-43-2) Butane (CAS 106-97-8) Cyclohexane (CAS 110-82-7) Ethanol (CAS 64-17-5) Ethylbenzene (CAS 100-41-4)

Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 13 / 15 Page 247 of 262 Heptane (CAS 142-82-5) n-Hexane (CAS 110-54-3) Octane (CAS 111-65-9) Pentane (CAS 109-66-0) Toluene (CAS 108-88-3) Trimethylbenzene (CAS 25551-13-7) Xylene (CAS 1330-20-7) US. New Jersey Worker and Community Right-to-Know Act 2,3-Dimethylbutane (CAS 79-29-8) 2-Methylbutane (CAS 78-78-4) 2-Methylheptane (CAS 592-27-8) 2-Methylpentane (CAS 107-83-5) 3-Methylheptane (CAS 589-81-1) 3-Methylhexane (CAS 589-34-4) Benzene (CAS 71-43-2) Butane (CAS 106-97-8) Cyclohexane (CAS 110-82-7) Ethanol (CAS 64-17-5) Ethylbenzene (CAS 100-41-4) Ethyltoluene (CAS 25550-14-5) Heptane (CAS 142-82-5) n-Hexane (CAS 110-54-3) Octane (CAS 111-65-9) Pentane (CAS 109-66-0) Toluene (CAS 108-88-3) Trimethylbenzene (CAS 25551-13-7) Xylene (CAS 1330-20-7) US. Pennsylvania Worker and Community Right-to-Know Law 2,3-Dimethylbutane (CAS 79-29-8) 2-Methylbutane (CAS 78-78-4) 2-Methylhexane (CAS 591-76-4) 2-Methylpentane (CAS 107-83-5) 3-Methylhexane (CAS 589-34-4) 3-Methylpentane (CAS 96-14-0) Benzene (CAS 71-43-2) Butane (CAS 106-97-8) Cyclohexane (CAS 110-82-7) Ethanol (CAS 64-17-5) Ethylbenzene (CAS 100-41-4) Gasoline (CAS 86290-81-5) Heptane (CAS 142-82-5) n-Hexane (CAS 110-54-3) Octane (CAS 111-65-9) Pentane (CAS 109-66-0) Toluene (CAS 108-88-3) Trimethylbenzene (CAS 25551-13-7) Xylene (CAS 1330-20-7) US. Rhode Island RTK 2-Methylbutane (CAS 78-78-4) Benzene (CAS 71-43-2) Butane (CAS 106-97-8) Cyclohexane (CAS 110-82-7) Ethylbenzene (CAS 100-41-4) n-Hexane (CAS 110-54-3) Pentane (CAS 109-66-0) Toluene (CAS 108-88-3) Xylene (CAS 1330-20-7) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Benzene (CAS 71-43-2) Ethylbenzene (CAS 100-41-4) Toluene (CAS 108-88-3) Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 14 / 15 Page 248 of 262 International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) No Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical Yes Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances No (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 18-May-2015 Revision date - Version # 01 HMIS® ratings Health: 2 Flammability: 4 Physical hazard: 0 References IARC Monographs. Overall Evaluation of Carcinogenicity (Volumes 1-106) HSDB (2005) ACGIH (2007) IUCLID Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. Silver Eagle Refining Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use.

Unleaded Gasoline - All Grades SDS US 920117 Version #: 01 Revision date: - Issue date: 18-May-2015 15 / 15 Page 249 of 262 Material Safety Data Sheet

Section 1: Product & Company Identification

Product Name: White Lithium Grease (aerosol)

Product Number (s): 14200

Product Use: lubricating grease

Manufacturer / Supplier Contact Information: In United States: In Canada: CRC Industries, Inc. CRC Canada Co. 885 Louis Drive 2-1246 Lorimar Drive Warminster, PA 18974 Mississauga, Ontario L5S 1R2 www.crcindustries.com www.crc-canada.ca 1-215-674-4300 (General) 1-905-670-2291 (800) 521-3168 (Technical) (800) 272-4620 (Customer Service)

24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887

Section 2: Hazards Identification

Emergency Overview

DANGER: Extremely Flammable. Harmful or Fatal if Swallowed. Contents Under Pressure. Appearance & Odor: Off-white, viscous grease with solvent odor

Potential Health Effects:

ACUTE EFFECTS: EYE: May cause mild irritation including stinging and redness, but does not injure eye.

SKIN: Single, brief exposures may cause mild irritation. Frequent or prolonged contact may cause more severe irritation, defatting of the skin, and dermatitis.

INHALATION: High vapor concentrations are irritating to the respiratory tract and may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects, including death. May cause peripheral nervous system disorder and/or damage. Heating the dispensed grease may generate irritating vapors.

INGESTION: Low order of toxicity by ingestion. Main hazard is aspiration into the lungs during swallowing or vomiting. Small amounts aspirated into the respiratory system may cause bronchopneumonia or pulmonary adema, possible progressing to death.

CHRONIC EFFECTS: Overexposure to n-hexane may cause progressive and potentially irreversible damage to the peripheral nervous system, particularly in the arms and legs.

TARGET ORGANS: central nervous system, peripheral nervous system, respiratory system

Medical Conditions Aggravated by Exposure: skin and respiratory conditions

See Section 11 for toxicology and carcinogenicity information on product ingredients.

Page 1 of 7 Page 250 of 262 Product Name: White Lithium Grease (aerosol) Product Number (s): 14200 Section 3: Composition/Information on Ingredients

COMPONENT CAS NUMBER % by Wt. Hexane isomers 64742-49-0 / 107-83-5 40 - 50 n-Hexane 110-54-3 3.2 Heavy naphthenic petroleum distillates 64742-52-5 10 - 20 Liquefied petroleum gas 68476-86-8 35 - 45

Section 4: First Aid Measures

Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists.

Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if irritation persists. Wash contaminated clothing prior to re-use.

Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult give oxygen. Call a physician.

Ingestion: Do NOT induce vomiting. Contact a physician immediately.

Note to Physicians: Treat symptomatically. Gastric lavage using a cuffed endotracheal tube may be performed at your discretion.

Section 5: Fire-Fighting Measures

Flammable Properties: This product is extremely flammable in accordance with aerosol flammability definitions. (See 16 CFR 1500.3(c)(6) ). Flash Point: < 20°F / -6°C (TCC) Upper Explosive Limit: 9.0 Autoignition Temperature: 489°F / 254°C Lower Explosive Limit: 1.7

Fire and Explosion Data:

Suitable Extinguishing Media: Class B fire extinguishers, dry chemical, foam or CO2

Products of Combustion: Fumes, smoke and carbon monoxide

Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Vapors may accumulate in a confined space and create a flammable atmosphere.

Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Proper eye and skin protection should be provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. Do not spray water directly on fire; product will float and could be reignited on surface of water.

Section 6: Accidental Release Measures

Personal Precautions: Use personal protection recommended in Section 8.

Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains.

Page 2 of 7 Page 251 of 262 Product Name: White Lithium Grease (aerosol) Product Number (s): 14200 Methods for Containment & Clean-up: Dike area to contain spill. Remove all sources of ignition. Ventilate the area with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate respiratory protection. Recover or absorb spilled material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers.

Section 7: Handling and Storage

Handling Procedures: Use proper grounding and bonding procedures for transferring materials. Do not use product near any source of ignition. Avoid contact with eyes and skin. Avoid breathing vapors. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. For product use instructions, please see the product label.

Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120°F / 49°C to prevent cans from rupturing.

Aerosol Storage Level: III

Section 8: Exposure Controls/Personal Protection

Exposure Guidelines:

OSHA ACGIH OTHER COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT

Hexane isomers 500(v) 1000(v) 500 1000 NE ppm n-Hexane 500 NE 50(s) NE NE ppm Heavy naphthenic petroleum distillates 5 NE NE NE NE mg/m3 Liquefied petroleum gas 1000 NE 1000 NE NE ppm N.E. – Not Established (c) – ceiling (s) – skin (v) – vacated

Controls and Protection:

Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at the source, preventing dispersion into the general work area. Use mechanical means if necessary to maintain vapor levels below the exposure guidelines. If working in a confined space, follow applicable OSHA regulations.

Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual employee exposure levels. Use a self-contained breathing apparatus in confined spaces and for emergencies.

Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles.

Skin Protection: Use protective gloves such as nitrile, PVC or Viton®. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin.

Section 9: Physical and Chemical Properties Page 3 of 7 Page 252 of 262 Product Name: White Lithium Grease (aerosol) Product Number (s): 14200

Physical State: semi-solid / grease Color: off-white Odor: solvent Odor Threshold: ND Specific Gravity: 0.6257 Initial Boiling Point: 140°F / 60°C Freezing Point: < -50°F / -45°C Vapor Pressure: ND Vapor Density: > 1 (air = 1) Evaporation Rate: fast Solubility: not soluble in water Coefficient of water/oil distribution: ND pH: NA Volatile Organic Compounds: wt %: 85 g/L: 531.8 lbs./gal: 4.43

Section 10: Stability and Reactivity

Stability: Stable

Conditions to Avoid: Sources of ignition, temperature extremes

Incompatible Materials: Strong oxidizers

Hazardous Decomposition Products: Oxides of carbon

Possibility of Hazardous Reactions: No

Section 11: Toxicological Information

Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product.

Acute Toxicity:

Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat) Hexane isomers > 5000 mg/kg > 2000 mg/kg No data n-Hexane 28,710 mg/kg > 3000 mg/kg 48,000 ppm/4H Heavy naphthenic petroleum distillates No data No data No data Liquefied petroleum gas No data No data No data

Chronic Toxicity:

OSHA IARC NTP Component Carcinogen Carcinogen Carcinogen Irritant Sensitizer Hexane isomers No No No No Unknown n-Hexane No No No Skin No Heavy naphthenic petroleum No No No Eye Unknown distillates Liquefied petroleum gas No No No No No

Reproductive Toxicity: No information available Teratogenicity: No information available Mutagenicity: No information available Synergistic Effects: No information available

Page 4 of 7 Page 253 of 262 Product Name: White Lithium Grease (aerosol) Product Number (s): 14200 Section 12: Ecological Information

Ecological studies have not been conducted for this product. The following information is available for components of this product.

Ecotoxicity: n-hexane - 48 Hr EC50 water flea: 3.87 mg/L 96 Hr LC50 Lepomis macrochirus: 4.12 mg/L Persistence / Degradability: No information available Bioaccumulation / Accumulation: No information available Mobility in Environment: No information available

Section 13: Disposal Considerations

Waste Classification: The packaged liquid product is a RCRA hazardous waste for the characteristic of ignitability with a waste code of D001. The dispensed grease is not a hazardous waste. (See 40 CFR Part 261.20 – 261.33). Empty aerosol containers may be recycled.

All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more stringent than state, provincial or national requirements.

Section 14: Transport Information

US DOT (ground): UN1950, Aerosols, flammable, 2.1, Limited Quantity**

ICAO/IATA (air): UN1950, Aerosols, flammable, 2.1, Limited Quantity

IMO/IMDG (water): UN1950, Aerosols, 2.1, Limited Quantity

Special Provisions: **This product can be classified and labeled as ‘Consumer Commodity, ORM-D’ for domestic ground shipping until December 31, 2020. If shipping as limited quantity by ground, note that shipping papers are not required.

Section 15: Regulatory Information

U.S. Federal Regulations:

Toxic Substances Control Act (TSCA): All ingredients are either listed on the TSCA inventory or are exempt.

Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Reportable Quantities (RQ’s) exist for the following ingredients: n-hexane (5000 lbs)

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee.

Superfund Amendments Reauthorization Act (SARA) Title III: Section 302 Extremely Hazardous Substances (EHS): None

Section 311/312 Hazard Categories: Fire Hazard Yes Reactive Hazard No Release of Pressure Yes Acute Health Hazard Yes Chronic Health Hazard No

Page 5 of 7 Page 254 of 262 Product Name: White Lithium Grease (aerosol) Product Number (s): 14200 Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: n-hexane (3.2%)

Clean Air Act: Section 112 Hazardous Air Pollutants (HAPs): n-hexane

Occupational Safety and Health Administration: This product is regulated by the Hazard Communications Standard.

U.S. State Regulations:

California Safe Drinking Water and Toxic Enforcement Act (Prop 65): This product may contain the following chemicals known to the state of California to cause cancer, birth defects or other reproductive harm: None

Consumer Products VOC Regulations: This product is not regulated (semi-solid lubricant).

State Right to Know: New Jersey: 75-83-2, 109-66-0, 78-78-4, 96-37-7, 110-54-3, 79-29-8, 68476-86-8 Pennsylvania: 107-83-5, 75-83-2, 110-54-3, 79-29-8, 68476-86-8 Massachusetts: 107-83-5, 75-83-2, 110-54-3, 79-29-8, 68476-86-8 Rhode Island : 75-83-2, 110-54-3, 79-29-8, 68476-86-8

Canadian Regulations:

Controlled Products Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

WHMIS Hazard Class: A, B5, D2A, D2B

Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt.

European Union Regulations:

RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003. This product does not contain any of the restricted substances as listed in Article 4(1) of the RoHS Directive.

Additional Regulatory Information: None

Section 16: Other Information

HMIS® (II) NFPA

Health: 1 Flammability 3 : 3 Reactivity: 0 1 0 PPE: B

Ratings range from 0 (no hazard) to 4 (severe hazard)

Page 6 of 7 Page 255 of 262 Product Name: White Lithium Grease (aerosol) Product Number (s): 14200

Prepared By: Michelle Rudnick CRC #: 568G Revision Date: 06/09/2015

Changes since last revision: Revision Date

The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a health & safety professional, or CRC Industries.

ACGIH: American Conference of Governmental Industrial Hygienists NA: Not Applicable CAS: Chemical Abstract Service ND: Not Determined CFR: Code of Federal Regulations NIOSH: National Institute of Occupational Safety & Health DOT: Department of Transportation NFPA: National Fire Protection Association DSL: Domestic Substance List NTP: National Toxicology Program g/L: grams per Liter OSHA: Occupational Safety and Health Administration HMIS: Hazardous Materials Identification System PMCC: Pensky-Martens Closed Cup IARC: International Agency for Research on Cancer PPE: Personal Protection Equipment IATA: International Air Transport Association ppm: Parts per Million ICAO: International Civil Aviation Organization RoHS: Restriction of Hazardous Substances IMDG: International Maritime Dangerous Goods STEL: Short Term Exposure Limit IMO: International Maritime Organization TCC: Tag Closed Cup lbs./gal: pounds per gallon TWA: Time Weighted Average LC: Lethal Concentration WHMIS: Workplace Hazardous Materials Information LD: Lethal Dose System

Page 7 of 7 Page 256 of 262 MATERIAL SAFETY DATA SHEET

. 1. Product and Company Identification

space Product number 700-006 space Product name Xtreme Gleme All Weather Surface Degreaser space Effective date 03-Oct-2012 space Company information Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States space Company phone General Assistance 1-630-543-7600 space Emergency telephone US 1-866-836-8855 space Emergency telephone outside US 1-952-852-4646 space Version # 09 space Supersedes date 04-Mar-2011 space Product use Degreaser

. 2. Hazards Identification

space Emergency overview Aerosol. CONTENTS UNDER PRESSURE. Harmful in contact with eyes. space Potential health effects Routes of exposure Eye contact. Skin contact. Ingestion. space Eyes Contact may irritate or burn eyes. space Skin Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. space Inhalation Intentional misuse by concentrating and inhaling the product can be harmful or fatal. space Ingestion Exposure by ingestion of an aerosol is unlikely. Components of the product may be absorbed into the body by ingestion. May cause delayed lung damage. Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. space Target organs Central nervous system. Lungs. space Chronic effects Unconsciousness. Conjunctiva. Cyanosis (blue tissue condition, nails, lips, and/or skin). May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion and blurred vision) and/or damage. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May cause delayed lung injury. space Signs and symptoms Discomfort in the chest. Narcosis. Cyanosis (blue tissue condition, nails, lips, and/or skin). Coughing. Jaundice. Defatting of the skin. Skin irritation.

. 3. Composition / Information on Ingredients

space Components CAS # Percent Ethyl Alcohol 64-17-5 5 - 8 Diethylene Glycol Monobutyl Ether 112-34-5 3 - 5 n-Butane 106-97-8 1 - 3 Non-hazardous and other components below reportable levels 80 - 90

. 4. First Aid Measures

space First aid procedures Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. space Skin contact Wash off with warm water and soap. Get medical attention if irritation develops and persists. space Inhalation Move to fresh air. Get medical attention if symptoms persist. space Ingestion If material is ingested, immediately contact a poison control center.

Product name: Xtreme Gleme All Weather Surface Degreaser MSDS US Product #: 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 1 / 5 Page 257 of 262 space Notes to physician Keep victim warm. Keep victim under observation. Symptoms may be delayed.

. 5. Fire Fighting Measures

space Flammable properties Vapor or gas may spread to distant ignition sources and flash back. Runoff to sewer may cause fire or explosion hazard. space Extinguishing media Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). space Protection of firefighters Protective equipment and In case of fire and/or explosion do not breathe fumes. Containers should be cooled with precautions for firefighters water to prevent vapor pressure build up.

. 6. Accidental Release Measures

space Methods for containment Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Stop the flow of material, if this is without risk. space Methods for cleaning up Should not be released into the environment. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

. 7. Handling and Storage

space Handling Pressurized container: Do not pierce or burn, even after use. Do not smoke while using or until sprayed surface is thoroughly dry. Do not use if spray button is missing or defective. Do not re-use empty containers. Do not get this material in contact with eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin. space Storage Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed containers can increase under the influence of heat. Do not handle or store near an open flame, heat or other sources of ignition. Avoid exposure to long periods of sunlight. Store in cool place. Keep container dry. Keep out of the reach of children. Keep away from food, drink and animal feedingstuffs. Level 1 Aerosol (NFPA 30B)

. 8. Exposure Controls / Personal Protection

space Exposure limits ACGIH Components CAS # TWA STEL Ceiling Ethyl Alcohol 64-17-5 1000 ppm 1000 ppm Not established Diethylene Glycol Monobutyl 112-34-5 20 ppm Not established Not established Ether n-Butane 106-97-8 1000 ppm Not established Not established space space OSHA Components CAS # TWA STEL Ceiling Ethyl Alcohol 64-17-5 1000 ppm Not established Not established Diethylene Glycol Monobutyl 112-34-5 100 ppm Not established Not established Ether space space Personal protective equipment Eye / face protection Do not get in eyes. Chemical goggles are recommended. space Skin protection Wear appropriate chemical resistant clothing. Chemical resistant gloves. space Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator.

. 9. Physical & Chemical Properties

space Appearance Cloudy. space Boiling point 215.6 °F (102.2 °C) estimated

Product name: Xtreme Gleme All Weather Surface Degreaser MSDS US Product #: 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 2 / 5 Page 258 of 262 space Color Not available space Density 0.9597 g/cm3 estimated space Flammability (HOC) 4.6332 kJ/g estimated space Flash back No space Flash point -156 °F (-104.4 °C) Propellant space Form Aerosol. space Freezing point Not available space Odor Characteristic. space pH 9.5 - 10.5 space Physical state Liquid. space Pressure 65 - 70 psig @70F space Solubility Partially space Specific gravity 0.9598 estimated

. 10. Chemical Stability & Reactivity Information

space Chemical stability Risk of ignition. space Conditions to avoid Heat, flames and sparks. space Hazardous decomposition products Irritants. Toxic gas.

. 11. Toxicological Information

space Acute effects Acute LD50: 55663 mg/kg estimated, Rat, Dermal space Component analysis - LD50 Toxicology Data - Selected LD50s and LC50s Diethylene Glycol Monobutyl Ether 112-34-5 Oral LD50 Rat 3384 mg/kg; Dermal LD50 Rabbit 2700 mg/kg Ethyl Alcohol 64-17-5 Oral LD50 Rat 7060 mg/kg; Inhalation LC50 Rat 124.7 mg/L 4 h n-Butane 106-97-8 Inhalation LC50 Rat 658 mg/L 4 h space Carcinogenicity IARC - Group 1 (Carcinogenic to Humans) Ethyl Alcohol 64-17-5 Monograph 100E [in preparation] (in alcoholic beverages); Monograph 96 [2010] (in alcoholic beverages)

. 12. Ecological Information

space Ecotoxicity LC50 23777 mg/L, Fish, 96.00 Hours, EC50 23978 mg/L, Daphnia, 48.00 Hours, IC50 5503 mg/L, Algae, 72.00 Hours, Contains a substance which causes risk of hazardous effects to the environment.

. 13. Disposal Considerations

space Waste codes D001: Waste Flammable material with a flash point <140 F space Disposal instructions Contents under pressure. Do not puncture, incinerate or crush. Dispose of this material and its container to hazardous or special waste collection point. Do not allow this material to drain into sewers/water supplies. If discarded, this product is considered a RCRA ignitable waste, D001.

. 14. Transport Information

space Department of Transportation (DOT) Requirements Basic shipping requirements: Proper shipping name Aerosols Hazard class 2.1 UN number UN1950 Additional information: Special provisions 153, N82 Packaging exceptions 306 Packaging non bulk None Packaging bulk None

Product name: Xtreme Gleme All Weather Surface Degreaser MSDS US Product #: 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 3 / 5 Page 259 of 262 space Further information This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2013, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/13 and may be used now in place of the "Consumer Commodity ORM-D" marking but not concurrently. space IMDG Basic shipping requirements: Proper shipping name AEROSOLS Hazard class 2.1 UN number 1950 Additional information: Packaging exceptions LTD QTY Item 5F Labels required None Transport Category 2

space IATA Basic shipping requirements: Proper shipping name Aerosols, flammable Hazard class 2.1 UN number 1950 Additional information: Packaging exceptions LTD QTY Labels required 2.1

. 15. Regulatory Information

space US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. U.S. - CERCLA/SARA - Section 313 - Emission Reporting Diethylene Glycol Monobutyl Ether 112-34-5 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3, R=alkyl C7 or less, or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate, Chemical Category N230) space Occupational Safety and Health Administration (OSHA) 29 CFR 1910.1200 hazardous Yes chemical space CERCLA (Superfund) reportable quantity None space Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 302 extremely No hazardous substance space Section 311 hazardous chemical Yes space Hazard categories (311/312) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No space Inventory status Country(s) or region Inventory name On inventory (yes/no)* China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of New and Existing Chemicals (EINECS) Yes Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

Product name: Xtreme Gleme All Weather Surface Degreaser MSDS US Product #: 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 4 / 5 Page 260 of 262 space State regulations U.S. - Pennsylvania - RTK (Right to Know) List Diethylene Glycol Monobutyl Ether 112-34-5 Environmental hazard Ethyl Alcohol 64-17-5 Present n-Butane 106-97-8 Present

. 16. Other Information

space Further information HMIS® is a registered trade and service mark of the NPCA. space HMIS® ratings Health: 1 Flammability: 2 Physical hazard: 0 space Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. The information in the sheet was written based on the best knowledge and experience currently available. space MSDS sections updated Product and Company Identification: Product and Company Identification Physical & Chemical Properties: Appearance Physical & Chemical Properties: Color Physical & Chemical Properties: Form Transport Information: Product Shipping Name/Packing Group Transport Information: Further information space Prepared by Regulatory Compliance

Product name: Xtreme Gleme All Weather Surface Degreaser MSDS US Product #: 700-006 Revision date: 03-OCT-2012 Print date: 03-OCT-2012 5 / 5 Page 261 of 262 Safety Data Sheets

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