Experiences with Compressed Natural Gas in Colorado Vehicle Fleets
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Combustion and Heat Release Characteristics of Biogas Under Hydrogen- and Oxygen-Enriched Condition
energies Article Combustion and Heat Release Characteristics of Biogas under Hydrogen- and Oxygen-Enriched Condition Jun Li 1, Hongyu Huang 2,*, Huhetaoli 2, Yugo Osaka 3, Yu Bai 2, Noriyuki Kobayashi 1,* and Yong Chen 2 1 Department of Chemical Engineering, Nagoya University, Nagoya, Aichi 464-8603, Japan; [email protected] 2 Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China; [email protected] (H.); [email protected] (Y.B.); [email protected] (Y.C.) 3 Faculty of Mechanical Engineering, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192, Japan; [email protected] * Correspondence: [email protected] (H.H.); [email protected] (N.K.); Tel.: +86-20-870-48394 (H.H.); +81-52-789-5428 (N.K.) Received: 10 May 2017; Accepted: 20 July 2017; Published: 13 August 2017 Abstract: Combustion and heat release characteristics of biogas non-premixed flames under various hydrogen-enriched and oxygen-enriched conditions were investigated through chemical kinetics simulation using detailed chemical mechanisms. The heat release rates, chemical reaction rates, and molar fraction of all species of biogas at various methane contents (35.3–58.7%, mass fraction), hydrogen addition ratios (10–50%), and oxygen enrichment levels (21–35%) were calculated considering the GRI 3.0 mechanism and P1 radiation model. Results showed that the net reaction rate of biogas increases with increasing hydrogen addition ratio and oxygen levels, leading to a higher net heat release rate of biogas flame. Meanwhile, flame length was shortened with the increase in hydrogen addition ratio and oxygen levels. -
Biomass-Derived Hydrogen from a Thermally Ballasted Gasifier
Proceedings of the 2002 U.S. DOE Hydrogen Program Review NREL/CP-610-32405 Biomass-Derived Hydrogen from a Thermally Ballasted Gasifier Robert C. Brown, Glenn Norton, Andy Suby, Jerod Smeenk, Keith Cummer, and Josh Nunez Center for Sustainable Environmental Technologies Iowa State University Ames, IA 50011-3020 INTRODUCTION The goal of this project is to optimize performance of an indirectly heated gasification system that converts switchgrass into hydrogen-rich gas suitable for powering fuel cells. We have developed a thermally ballasted gasifier that uses a single reactor for both combustion and pyrolysis. Instead of spatially separating these processes, they are temporally isolated. The producer gas is neither diluted with nitrogen or the products of combustion. The heat released during combustion at 850°C is stored as latent heat in the form of molten salt sealed in tubes immersed in the fluidized bed. During the pyrolysis phase, which occurs at temperatures between 600 and 850°C, the reactor is fluidized with steam or recycled producer gas rather than air. Heat stored in the phase change material is released during this phase of the cycle to support the endothermic reactions of the pyrolysis stage. Because air is not used during the gas-producing phase of the cycle, nitrogen does not dilute the product gas, resulting in relatively high concentrations of hydrogen and carbon monoxide in the producer gas compared to conventional gasifiers. The carbon monoxide, along with steam used to fluidize the reactor, can be shifted to additional hydrogen by the water-gas shift reaction. Objectives in the first year include: • Determine whether switchgrass is a suitable fuel for the ballasted gasifier. -
Energy and the Hydrogen Economy
Energy and the Hydrogen Economy Ulf Bossel Fuel Cell Consultant Morgenacherstrasse 2F CH-5452 Oberrohrdorf / Switzerland +41-56-496-7292 and Baldur Eliasson ABB Switzerland Ltd. Corporate Research CH-5405 Baden-Dättwil / Switzerland Abstract Between production and use any commercial product is subject to the following processes: packaging, transportation, storage and transfer. The same is true for hydrogen in a “Hydrogen Economy”. Hydrogen has to be packaged by compression or liquefaction, it has to be transported by surface vehicles or pipelines, it has to be stored and transferred. Generated by electrolysis or chemistry, the fuel gas has to go through theses market procedures before it can be used by the customer, even if it is produced locally at filling stations. As there are no environmental or energetic advantages in producing hydrogen from natural gas or other hydrocarbons, we do not consider this option, although hydrogen can be chemically synthesized at relative low cost. In the past, hydrogen production and hydrogen use have been addressed by many, assuming that hydrogen gas is just another gaseous energy carrier and that it can be handled much like natural gas in today’s energy economy. With this study we present an analysis of the energy required to operate a pure hydrogen economy. High-grade electricity from renewable or nuclear sources is needed not only to generate hydrogen, but also for all other essential steps of a hydrogen economy. But because of the molecular structure of hydrogen, a hydrogen infrastructure is much more energy-intensive than a natural gas economy. In this study, the energy consumed by each stage is related to the energy content (higher heating value HHV) of the delivered hydrogen itself. -
Reporting Manual
U.S. Department of Transportation Federal Transit Administration Reporting Manual 1995 National Transit Database Report Year Reporting Manual 1995 National Transit Database Report Year Gordon J. Linton Administrator Federal Transit Administration January 1995 Executive Summary The Federal Transit Administration's (FTA) National Transit Database (NTD) (formerly Section 15) program helps meet information needs in plarming for public transportation services and making investment decisions at the Federal, State, and local levels. The program's goal is to provide an accurate and validated National Transit Database in a timely manner. Since the information collected in this program will affect public policy for many years, your cooperation to provide accurate data is essential. FTA continues to streamline the reporting process while maintaining historical continuity for analysis, and enhancing data accuracy. Improvements to the reporting system for 1995 include: • Further enhancements to Diskette reporting, including: • "Smart" forms for data checks; • Menu options for declarations; • Options to import data from a prior year; and • Expanded error and form status reports. • Declarations retained on file at your transit agency; • Detailed reporting for purchased transportation (optional); • Security data reporting; and • Inclusion of a Glossary of Transit Terms into the Reporting Manual. Changes to the NTD for 1995 are summarized in the introduction and incorporated throughout the Reporting Manual. The enclosed reporting forms are designed to help you report as easily as possible while establishing uniformity. The forms are used to record information in several areas. The initial series of forms, the Basic Information Forms (000 's) establish a basic transit agency profile. The Capital Funding Form (103) details the origin, amount and uses of a transit agency's capital funding. -
Lng Flow Calibration Facilities
LNG FLOW CALIBRATION FACILITIES Oswin Kerkhof, VSL Mijndert van der Beek, VSL Peter Lucas, VSL Maria Mirzaei, VSL Gerard Blom, VSL Gertjan Kok, VSL Keywords: calibration, flow, flowmeter, custody transfer, measurement, uncertainty, accuracy, transport fuel, quality measurement, 1. Introduction Reliable, accurate and commonly agreed measurement methods are a first requirement for the trade of goods. For the large scale LNG distribution chain there is a commonly agreed measurement practice as described in various ISO standards and in the GIIGNL “Custody transfer handbook”. In comparison with other commodities like natural gas or gasoline the total uncertainty on measured energy is very high for LNG. The LNG industry is therefore committed to improve their measurement accuracies to reduce their financial risks and to optimize their mass and energy balances. As an extension of the traditional distribution chain for LNG a new market of professional consumers is developing with LNG as transport fuel. In this case there is no commonly agreed measurement practice and the metrological framework is not yet in place. This will be a showstopper for the roll-out of the LNG as transport fuel because laws will be enforcing protection of (professional) consumers. For small scale LNG the legal metrology framework will lay down requirements on traceability to national standards and will define maximum permissible measurement errors. This is not the case for large scale LNG where the industrial players are assumed to take care of their own business interests. For this reason the development of an LNG calibration facility is a crucial step and urgently required for the development of the small scale LNG distribution chain. -
2002-00201-01-E.Pdf (Pdf)
report no. 2/95 alternative fuels in the automotive market Prepared for the CONCAWE Automotive Emissions Management Group by its Technical Coordinator, R.C. Hutcheson Reproduction permitted with due acknowledgement Ó CONCAWE Brussels October 1995 I report no. 2/95 ABSTRACT A review of the advantages and disadvantages of alternative fuels for road transport has been conducted. Based on numerous literature sources and in-house data, CONCAWE concludes that: · Alternatives to conventional automotive transport fuels are unlikely to make a significant impact in the foreseeable future for either economic or environmental reasons. · Gaseous fuels have some advantages and some growth can be expected. More specifically, compressed natural gas (CNG) and liquefied petroleum gas (LPG) may be employed as an alternative to diesel fuel in urban fleet applications. · Bio-fuels remain marginal products and their use can only be justified if societal and/or agricultural policy outweigh market forces. · Methanol has a number of disadvantages in terms of its acute toxicity and the emissions of “air toxics”, notably formaldehyde. In addition, recent estimates suggest that methanol will remain uneconomic when compared with conventional fuels. KEYWORDS Gasoline, diesel fuel, natural gas, liquefied petroleum gas, CNG, LNG, Methanol, LPG, bio-fuels, ethanol, rape seed methyl ester, RSME, carbon dioxide, CO2, emissions. ACKNOWLEDGEMENTS This literature review is fully referenced (see Section 12). However, CONCAWE is grateful to the following for their permission to quote in detail from their publications: · SAE Paper No. 932778 ã1993 - reprinted with permission from the Society of Automotive Engineers, Inc. (15) · “Road vehicles - Efficiency and emissions” - Dr. Walter Ospelt, AVL LIST GmbH. -
Material Safety Data Sheet
SAFETY DATA SHEET EFFECTIVE JUNE 2016 SECTION 1 – PRODUCT & COMPANY IDENTIFICATION Product Name: Commercial Odorized Propane Chemical Name: Propane (C3H8) Chemical Family: Petroleum Hydrocarbon Common Names: Liquefied Petroleum Gas, LP-Gas, LPG, Bottle Gas Intended Use: Propane is a liquid fuel Distributor: Campora Propane Service, PO Box 31717 Stockton, CA 95213 Emergency Response: CHEMTREC (800) 424-9300 General Information: (209) 941-2994 SECTION 2 – CHEMICAL HAZARD CLASSIFICATION & WARNING INFORMATION Fire Hazard NFPA CLASSES: 1-Slight 2-Moderate 3-Serious Health Hazard Reactivity 4-Severe Physical hazards Flammable gases Category 1 Gases under pressure Liquefied gas Health hazards Acute toxicity, inhalation Category 4 Germ cell mutagenicity Category 1B Carcinogenicity Category 1A Reproductive toxicity Category 1A Specific target organ toxicity, repeated Category 2 exposure OSHA defined hazards Not classified. Label Elements Signal Word Danger Hazard Statement Propane (also called LPG-Liquefied Petroleum Gas or LP-Gas) is a liquid fuel stored under pressure. In most systems, propane is vaporized to a gas before it leaves the tank. Propane is highly flammable when mixed with air (oxygen) and can be ignited by many sources, including open flames, smoking materials, electrical sparks, and static electricity. Severe “freeze burn” or frostbite can result if propane liquid comes in contact with your skin. Extremely flammable gas. Harmful if inhaled. May cause genetic defects. May cause cancer. May damage fertility or the unborn child. May cause damage to Blood through prolonged or repeated exposure. May cause cryogenic burns or injury. Propane is a simple asphyxiant. Precautionary statement General Read and follow all Safety Data Sheets (SDS’S) before use. -
Producing Fuel and Electricity from Coal with Low Carbon Dioxide Emissions
Producing Fuel and Electricity from Coal with Low Carbon Dioxide Emissions K. Blok, C.A. Hendriks, W.C. Turkenburg Depanrnent of Science,Technology and Society University of Utrecht Oudegracht320, NL-351 1 PL Utrecht, The Netherlands R.H. Williams Center for Energy and Environmental Studies Princeton University Princeton, New Jersey08544, USA June 1991 Abstract. New energy technologies are needed to limit CO2 emissions and the detrimental effects of global warming. In this article we describe a process which produces a low-carbon gaseousfuel from coal. Synthesis gas from a coal gasifier is shifted to a gas mixture consisting mainly of H2 and CO2. The CO2 is isolated by a physical absorption process, compressed,and transported by pipeline to a depleted natural gas field where it is injected. What remains is a gaseousfuel consisting mainly of hydrogen. We describe two applications of this fuel. The first involves a combined cycle power plant integrated with the coal gasifier, the shift reactor and the CO2 recovery units. CO2 recovery and storage will increase the electricity production cost by one third. The secondprovides hydrogen or a hydrogen-rich fuel gas for distributed applications, including transportation; it is shown that the fuel can be produced at a cost comparable to projected costs for gasoline. A preliminary analysis reveals that all components of the process described here are in such a phase of development that the proposed technology is ready for demonstration. ~'> --. ~'"' .,.,""~ 0\ ~ 0\0 ;.., ::::. ~ ~ -.., 01) §~ .5~ c0 ~.., ~'> '" .~ ~ ..::. ~ ~ "'~'" '" 0\00--. ~~ ""00 Q....~~ '- ~~ --. ~.., ~ ~ ""~ 0000 .00 t¥") $ ~ .9 ~~~ .- ..~ c ~ ~ ~ .~ O"Oe) """1;3 .0 .-> ...~ 0 ~ ,9 u u "0 ...~ --. -
Field Reference Manual, 2015
CALIFORNIA DEPARTMENT OF FOOD AND AGRICULTURE DIVISION OF MEASUREMENT STANDARDS FIELD REFERENCE MANUAL 2015 California Code of Regulation Title 4, Division 9 Chapter 1 Tolerances and Specifications for Commercial Weighing and Measuring Devices NIST Handbook 44 Sections 3.30. Liquid-Measuring Devices through 3.39 Hydrogen Gas-Measuring Devices DISCLAIMER This document represents the Division of Measurement Standards’ field manual for enforcing regulations pertaining to weights and measures in California. This field manual is not to be considered as the official Code of Regulations, as published by Barclays Law Publishers. NOTE: Language in Handbook 44 that is not adopted is annotated “[NOT ADOPTED]” in this document. NOTE: Requirements are different than, or in addition to, the requirements of Handbook 44 are included in the appropriate section this document. They are shaded, bordered, and numbered in the 4002 series to differentiate them from the Handbook 44 requirements. To find the latest online version of the California Code of Regulations (CCR) Title 4, Division 9, visit the California Office of Administration Law (OAL) at: http://ccr.oal.ca.gov/linkedslice/default.asp?SP=CCR-1000&Action=Welcome The CCR may also be accessed at http://oal.ca.gov/ by selecting the link Titled “California Code of Regulations” under the list of “Sponsored Links” in the left column on the OAL Home page. For information concerning the contents of this document, please contact the Division of Measurement Standards by e-mail at [email protected]. NIST Handbook 44 (2015 Edition) - Specifications, Tolerances, and Other Technical Requirements for Weighing and Measuring Devices as adopted by the 98th National Conference on Weights and Measures July 2014 is available at: www.nist.gov/pml/wmd/pubs/hb44.cfm 3.30. -
Chapter 38 Liquefied Petroleum Gases
Color profile: Generic CMYK printer profile Composite Default screen CHAPTER 38 LIQUEFIED PETROLEUM GASES SECTION 3801 3803.2.1.2 Construction and temporary heating. Por- GENERAL table containers are allowed to be used in buildings or 3801.1 Scope. Storage, handling and transportation of lique- areas of buildings undergoing construction or for tempo- fied petroleum gas (LP-gas) and the installation of LP-gas rary heating as set forth in Sections 6.17.4, 6.17.5 and equipment pertinent to systems for such uses shall comply with 6.17.8 of NFPA 58. this chapter and NFPA 58. Properties of LP-gases shall be 3803.2.1.3 Group F occupancies. In Group F occupan- determined in accordance with Appendix B of NFPA 58. cies, portable LP-gas containers are allowed to be used to 3801.2 Permits. Permits shall be required as set forth in Sec- supply quantities necessary for processing, research or tions 105.6 and 105.7. experimentation. Where manifolded, the aggregate Distributors shall not fill an LP-gas container for which a water capacity of such containers shall not exceed 735 permit is required unless a permit for installation has been pounds (334 kg) per manifold. Where multiple mani- issued for that location by the fire code official. folds of such containers are present in the same room, each manifold shall be separated from other manifolds 3801.3 Construction documents. Where a single container is by a distance of not less than 20 feet (6096 mm). more than 2,000 gallons (7570 L) in water capacity or the aggregate capacity of containers is more than 4,000 gallons (15 3803.2.1.4 Group E and I occupancies. -
Guidelines for Gas Meters & Manifolds
Guidelines for Gas Meters & Manifolds * By carefully following attached suggestions, you will help us get your meters set on the first trip and avoid costly delays related to return trips (for which you are being charged $65 per trip). CoServ Gas Engineering (940) 270-7585 For Gas Emergencies or Leaks call: (844) 330-0763 CoServ Gas Meters and Manifolds Builder & Customer Requirements 1) Gas Meter Planning Guidelines a. The size of gas metering and regulating facilities varies widely depending upon the gas-load needs of each residence, business or commercial building. Due to the parameters associated with meter and regulator selection, it is imperative that the Customer, or the Customer’s agent, contact the assigned CoServ Gas representative prior to construction to determine the exact requirements for specific installations, including location and space requirements. Consulting with us early in the process may eliminate the need for changes to the gas metering facilities or gas Main Extensions or relocation of gas risers at a later date with additional delays and expense to Builder or Customer. 2) Meter Selection Criteria a. To assure proper operation, each gas meter must be the proper size and type for the maximum gas demand and required pressure. The maximum gas demand is determined by adding the Btu input ratings of all gas burning devices that may possibly be operating simultaneously. Furnaces, space heaters, water heaters, boilers, pool heaters, fireplace logs, gas clothes dryers, gas lights, and gas generators should be included at their maximum input ratings. b. The type of meter installed can also vary depending upon the Customer’s usage factors, e.g., what type of business, hours of operation, critical operations, etc. -
Sub-Metering of Natural Gas Flexible Flow Measurement Delivers Improved Accuracy and Substantial Savings
WHITEPAPER Sub-Metering of Natural Gas Flexible Flow Measurement Delivers Improved Accuracy and Substantial Savings by: Scott Rouse, VP Product Management, Sierra Instruments, Inc fter a decade of remarkable growth, This natural gas boom highlights the importance A the United States has become the for utility companies to provide homes, world’s number one producer of natural gas, businesses, and mid-to-large size facilities and its largest consumer, with consumption in with accurate natural gas billing. Traditionally, 2019 at 31 trillion cubic feet. This high growth utility companies have used diaphragm meters rate is expected to continue. For example, to measure natural gas usage, which is then electricity generation using natural gas has charged to customers on their monthly energy increased from 17% to 35% of total electrical bill. Although diaphragm meters are a trusted consumption, and is likely to increase to 50% billing mechanism by utility companies, they by mid-century. may not provide customers with the most accurate natural gas bill. Diaphragm meters have SUB-METERING OF NATURAL GAS WHITEPAPER limitations in natural gas measurement. If the WHAT IS NATURAL GAS? diaphragm meter does not ac curately measure Natural gas is the cleanest burning fossil the natural gas, this can result in utility companies fuel, producing by-products of mostly carbon overcharging customers. dioxide and water vapor. It is used extensively To avoid this problem, many mid-to-large-size in power generation, industrial and commercial facilities use flow meters to sub-meter their applications, and for home utility and heating. natural gas usage to validate the diaphragm Natural gas is primarily a mixture of methane, meters’ readings and more efficiently allocate ethane and propane, but those components energy.