Oxygen Isotope Variations in Lau Basin Lavas
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Chemical Geology 144Ž. 1998 177±194 Oxygen isotope variations in Lau Basin lavas Colin G. Macpherson ), David P. Mattey Department of Geology, Royal Holloway UniÕersity of London, Egham, Surrey TW20 0EX, UK Abstract New laser-fluorination oxygen isotope data are presented for volcanic glasses and phenocrysts from Lau and North Fiji Basin lavas. The low oxygen blank of the technique allows accurate analysis of these often scarce igneous phases. d 18O values of volcanic glass range from 5.53½ to 6.06½. Oxygen isotope ratios of ferromagnesian and plagioclase phenocrysts are lower and higher than their host glasses, respectively, and coexisting phases appear to represent oxygen isotope equilibrium at magmatic temperatures. Evolved lavas from the propagating and dying rift tips in the Central Lau Basin display significant 18O-enrichment with magmatic evolution due to FeTi-oxide crystallisation and require that precursor melts had relatively low d 18O values immediately prior to oxide saturation. Development of these precursor melts from basaltic parents involved assimilation of hydrothermally altered sheeted dykes or gabbros in recently accreted oceanic crust accompanied by crystallisation of a plagioclase-rich assemblage. The stable isotope geochemistry and petrology of Central Lau Basin lavas constrain magmatic evolution to depths between 2.5 and 5 km beneath the seafloor. A dacite from Valu Fa Ridge is slightly 18O-enriched relative to Valu Fa basalts, consistent with crystallisation of a mineral assemblage similar to mid-ocean ridge basalts. 18Or 16O ratios of Lau Basin basaltic glasses decrease with Mg Number; this observation could be reconciled with the assimilation and fractional crystallisation model proposed for initial differentiation of the evolved lavas. However, oxygen isotope data for Central Lau Basin basalts correlate positively with BarLa while basaltic glasses from 18 throughout the region display a negative correlation between d O and Na8.0 suggesting that recycling of subducted oxygen andror mantle fertility may also exert an influence on 18Or 16O of primary melts. Presently, the lack of quantitative control over oxygen isotope fractionation in basaltic systems prohibits resolution of these effects. Detailed investigation of less complex suites of lavas, employing the precision offered by laser fluorination, may provide new insights into the behaviour of oxygen at magmatic temperatures. q 1998 Elsevier Science B.V. Keywords: Lau Basin; Oxygen isotopes; Magmatism; Subduction; Melting; Assimilation 1. Introduction Unaltered lavas erupted at mid-ocean spreading centres display limited18 Or 16O variationŽ 5.7" 0.3½; Ito et al., 1987. This is thought to result from ) Corresponding author. Present address: Geosciences Research melting of an upper mantle reservoir that is uniform Division ± 0220, Scripps Institution of Oceanography, 9500 with respect to oxygen isotopes, followed by limited Gilman Drive, La Jolla, CA 92093-0220, USA. Tel.: q1Ž. 619 534-3260; fax: q 1Ž. 619 534-0784; e-mail: degrees of chemical evolution in sub-ridge magma [email protected] chambersŽ Muehlenbachs and Clayton, 1972; Taylor 0009-2541r98r$19.00 q 1998 Elsevier Science B.V. All rights reserved. PII S0009-2541Ž. 97 00130-7 178 C.G. Macpherson, D.P. MatteyrChemical Geology 144() 1998 177±194 and Sheppard, 1986, and references therein. Pro- oxygen from various reservoirs into primary Lau tracted fractional crystallisation can produce oxygen Basin melts. isotope variations in cogenetic lava suites but this is rare at mid-ocean spreading centres, having been recognised only at the 958W propagating rift tip of 2. Samples and technique the Galapagos Spreading CentreŽ Muehlenbachs and Byerly, 1982; Ito et al., 1987. Oxygen isotope ratios The Lau Basin is a triangular-shaped back-arc are frequently employed in petrogenetic studies of basin situated west of the Tonga RidgeŽ. Fig. 1a , subduction zone magmatism to discriminate between where the Pacific Plate is being subducted beneath source and crustal contamination of the magmatic the Australian Plate at the Tonga TrenchŽ Karig, systemŽ. James, 1981 . While the effects of both 1970. The triangular shape results from rapid, crystallisation and open system behaviour have been clockwise rotation of the Tonga Ridge relative to the observed in some tholeiitic lava series, the magni- remnant Lau Ridge, and the southward propagation tude of variations that may be produced by these of two phases of ocean spreadingŽ Parson and processes are small: F0.5½Ž e.g. Taylor, 1968; Hawkins, 1994; Bevis et al., 1995. At around 5.5 Anderson et al., 1971; Matsuhisa et al., 1973; Shep- Ma the first phase of spreading was initiated, south- pard and Harris, 1985; Woodhead et al., 1987; Ellam east of what is now Peggy Ridge, producing oceanic and Harmon, 1990. Furthermore, identification of crust at the Eastern Lau Spreading CentreŽ. ELSC original magmatic 18 Or 16 O variation in submarine and the Valu Fa RidgeŽ. Fig. 1a . These spreading lavas is often obscured by the effects of post-erup- centres propagated southwards through extended arc tive alterationŽ Muehlenbachs and Clayton, 1972; crust between the Tonga and Lau ridges. Then, Pineau et al., 1976; Taylor and Sheppard, 1986. around 1.5 Ma, the Central Lau Spreading Centre Phenocrysts or fresh volcanic glass can be analysed Ž.CLSC began to propagate through crust formed at to avoid alteration products but these phases are the ELSCŽ. Fig. 1a . commonly too scarce in seafloor dredge hauls to Parson et al.Ž. 1990 identified three active spread- allow conventional oxygen isotope analysis of entire ing segments in the Central Lau Basin, representing suites of lavas. propagating and dying rifts with an intermediate This study presents oxygen isotope data obtained `relay' sectionŽ. Fig. 1b . The crests of these ridges by laser-fluorinationŽ. LF for fresh lavas collected were dredged by Cruise 33 of the R.V. Charles from three sites of active volcanism in the Lau Darwin Ž.Pearce et al., 1994 . Eruptive products from Basin. Laser ablation of bulk samples vastly reduces the ELSC and Intermediate Lau Spreading Centre oxygen blanks compared to the classic `bomb' fluo- Ž.ILSC are dominantly basaltic with Mg No.)50, rination method and thus allows routine determina- although glasses from the northern ELSCŽ. site 20 tion of18 Or 16O ratios in igneous phasesŽ Sharp, are more evolvedŽ. Table 1 . Ferrobasalts and an- 1990; Mattey and Macpherson, 1993. Furthermore, desites erupted at the propagating rift tip of the highly refractory phases can be analysed with high CLSC display evidence of extreme chemical frac- precision. Intensive sampling of a propagating rift tip tionation and volatile degassing, compared to other and associated dying rift in the Central Lau Basin Central Lau Basin lavas and mid-ocean ridge basalt has allowed examination of oxygen isotope systemat- ŽMORB; Pearce et al., 1994; Macpherson and Mat- ics through a diverse compositional spectrum of tey, 1994; Farley and Newman, 1994. Plagioclase lavas generated in an oceanic setting. In an effort to dominated the crystallising assemblage in melts with detect subduction-related spatial controls on the 4 wt.%-MgO-7.5 wt.% subduing Sr enrichment 18 Or 16 O ratios of lavas, oxygen isotope data are and producing negative Eu anomalies during differ- also reported for lavas from the northern and south- entiation. Strong FeO, TiO2 and V depletions in ern extremities of the basin. These results are com- evolved lavas are the result of FeTi-oxide crystallisa- pared with other geochemical properties of the lavas tionŽ. Pearce et al., 1994 . Elevated concentrations of and conventionally obtained 18 Or 16 O data from incompatible alkali and alkali earth elements and nearby localities in an effort to constrain the flux of greater vesicularity in ELSC lavas, relative to MORB, C.G. Macpherson, D.P. MatteyrChemical Geology 144() 1998 177±194 179 Fig. 1.Ž. a Map of the Lau Basin and Eastern part of the North Fiji Basin modified from Parson et al.Ž. 1994 . A heavy box outlines the propagating rift system of the Central Lau Basin shown inŽ. b , and the dashed line marks the approximate extent of oceanic crust formed at the Valu Fa Ridge and East Lau Spreading CentreŽ. ELSC . KK16 was recovered approximately 300 km west of Fiji. SO indicates the location of the Valu Fa samples for which detailed localities are presented by Frenzel et al.Ž.Ž. 1990 . b Geometry of the Central Lau Basin neovolcanic zonesŽ. stippled identified by Parson et al. Ž. 1990 , and dredge sites from Cruise 33 of the R.V. Charles Darwin. CLSCsCentral Lau Spreading Centre; ILSCsIntermediate Lau Spreading Centre; ELSCsEastern Lau Spreading Centre. The CLSC is propagating south at the expense of the ELSC. The ILSC is a `relay' zoneŽ. Parson et al., 1990 . 180 C.G. Macpherson, D.P. MatteyrChemical Geology 144() 1998 177±194 may reflect a greater flux of subducted material followed by oxide saturationŽ. Frenzel et al., 1990 . being recycling close to the arcŽ. Pearce et al., 1994 . Magma chambers have been seismically imaged, at The southern end of the Valu Fa Ridge marks the 1±4 km depth, along the entire length of the spread- limit of ocean spreading in the Lau BasinŽ Parson ing segment from which these samples were col- and Hawkins, 1994. Collection sites and petrology lectedŽ. Collier and Sinha, 1992 . Radiogenic isotope of the three glasses analysed from this ridge are and trace element ratios suggest that a small but described by Frenzel et al.Ž. 1990 . Major element significant slab flux is present in Valu Fa lavas concentrations of the basaltic andesites are similar to ŽJenner et al., 1987; Sunkel, 1990; Loock et al., MORB and the daciteŽ. SO35-77KD2 was produced 1990.Ž. ; however, Hilton et al. 1993 showed that He by `normal basaltic differentiation' of basic melts isotopic variations are decoupled from Sr, Nd and Pb isotopes as a result of combined degassing and as- similation.