The Prospect and Analysis of Nanogenerator for Wearable Device
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Piezoelectricity in PVDF and PVDF Based Piezoelectric Nanogenerator: a Concept
IOSR Journal of Applied Physics (IOSR-JAP) e-ISSN: 2278-4861.Volume 9, Issue 3 Ver. I (May. – June. 2017), PP 95-99 www.iosrjournals.org Piezoelectricity in PVDF and PVDF Based Piezoelectric Nanogenerator: A Concept Binoy Bera1,*, Madhumita Das Sarkar2 1,2Department of computer science and engineering, West Bengal University of Technology, Kolkata – 700064, India Abstract: Polyvinylidene fluoride or simply PVDF is one of the most important semicrystalline polymers which generate piezoelectricity when a pressure or mechanical force applied on it. It has four crystalline phases α, β, ɣ and δ depending on the chain conformation structure. Among them α is non polar phase and β and ɣ are polar phase. Piezoelectricity in PVDF arises due to the β and ɣ phase formation. Several materials have been introduced for the preparation of nanogenerator. Among them PVDF (polyvinylidene fluoride) is most interesting material used in nanogenerator preparation due to its flexibility, bio- compatiable, nontoxic in nature. It is used in nanogenerator application due to its good ferroelectric, piezoelectric and pyroelectric properties. In this article we describe little bit concept about PVDF, its piezoelectricity and PVDF based nanogenerator. Application of piezoelectric nanogenerator is also briefly described here. Keywords: PVDF, nanogenerator, piezoelectricity, β phase, electrospinning, electroactive phase, Poling process. I. Introduction Polyvinylidene fluoride, or polyvinylidene difluoride, (PVDF) is a highly non- reactive thermoplastic fluoropolymer produced by the polymerization of vinylidene difluoride. PVDF has four crystalline phases α, β, ɣ and δ depending on the chain conformation. Among them α is thermodynamically most stable and non polar in nature. β and ɣ are polar phase. -
High Performance Triboelectric Nanogenerator and Its Applications
HIGH PERFORMANCE TRIBOELECTRIC NANOGENERATOR AND ITS APPLICATIONS A Dissertation Presented to The Academic Faculty by Changsheng Wu In Partial Fulfillment of the Requirements for the Degree DOCTOR OF PHILOSOPHY in the SCHOOL OF MATERIALS SCIENCE AND ENGINEERING Georgia Institute of Technology AUGUST 2019 COPYRIGHT © 2019 BY CHANGSHENG WU HIGH PERFORMANCE TRIBOELECTRIC NANOGENERATOR AND ITS APPLICATIONS Approved by: Dr. Zhong Lin Wang, Advisor Dr. C. P. Wong School of Materials Science and School of Materials Science and Engineering Engineering Georgia Institute of Technology Georgia Institute of Technology Dr. Meilin Liu Dr. Younan Xia School of Materials Science and Department of Biomedical Engineering Engineering Georgia Institute of Technology Georgia Institute of Technology Dr. David L. McDowell School of Materials Science and Engineering Georgia Institute of Technology Date Approved: [April 25, 2019] To my family and friends ACKNOWLEDGEMENTS Firstly, I would like to express my sincere gratidue to my advisor Prof. Zhong Lin Wang for his continuous support and invaluable guidance in my research. As an exceptional researcher, he is my role model for his thorough knowledge in physics and nanotechnology, indefatigable diligence, and overwhelming passion for scientific innovation. It is my great fortune and honor in having him as my advisor and learning from him in the past four years. I would also like to thank the rest of my committee members, Prof. Liu, Prof. McDowell, Prof. Wong, and Prof. Xia for their insightful advice on my doctoral research and dissertation. My sincere thanks also go to my fellow lab mates for their strong support and help. In particular, I would not be able to start my research so smoothly without the mentorship of Dr. -
Piezoelectric Nanogenerator Using Cds Nanowires
APPLIED PHYSICS LETTERS 92, 022105 ͑2008͒ Piezoelectric nanogenerator using CdS nanowires ͒ ͒ Yi-Feng Lin,1,2 Jinhui Song,1 Yong Ding,1 Shih-Yuan Lu,2,b and Zhong Lin Wang1,a 1School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0245, USA 2Department of Chemical Engineering, Tsing Hua University, Hsinchu, Taiwan 30013, Republic of China ͑Received 2 November 2007; accepted 15 December 2007; published online 14 January 2008͒ Vertically grown cadmium sulfide ͑CdS͒ nanowire ͑NW͒ arrays were prepared using two different processes: hydrothermal and physical vapor deposition ͑PVD͒. The NWs obtained from the hydrothermal process were composed of alternating hexagonal wurtzite ͑WZ͒ and cubic zinc blende ͑ZB͒ phases with growth direction along WZ ͗0001͘ and ZB ͓111͔. The NWs produced by PVD process are single crystalline WZ phase with growth direction along ͗0001͘. These vertically grown CdS NW arrays have been used to converting mechanical energy into electricity following a developed procedure ͓Z. L. Wang and J. Song Science 312, 242 ͑2006͔͒. The basic principle of the CdS NW nanogenerator relies on the coupled piezoelectric and semiconducting properties of CdS, and the data fully support the mechanism previously proposed for ZnO NW nanogenerators and nanopiezotronics. © 2008 American Institute of Physics. ͓DOI: 10.1063/1.2831901͔ CdS is a piezoelectric semiconducting material1 with an The morphology of the hydrothermally grown CdS NWs energy band gap of about 2.5 eV. A wide range of applica- was characterized with scanning electron microscope ͑SEM͒. tions have been demonstrated for one-dimensional CdS As shown in Fig. -
Temperature Field Analysis for Zno Thin-Film Pyroelectric Devices with Partially Covered Electrode
Sensors and Materials, Vol. 24, No. 8 (2012) 421–441 MYU Tokyo S & M 0896 Temperature Field Analysis for ZnO Thin-Film Pyroelectric Devices with Partially Covered Electrode Chun-Ching Hsiao1,*, Sheng-Wen Huang1 and Rwei-Ching Chang2 1Department of Mechanical Design Engineering, National Formosa University, No. 64, Wunhua Rd., Huwei Township, Yunlin County 632, Taiwan 2Department of Mechanical and Computer-Aided Engineering, St. John’s University, 499, Sec. 4, Tam King Road, Tamsui, Taipei 251, Taiwan (Received July 6, 2011; accepted February 3, 2012) Key words: zinc oxide, pyroelectricity, sensor, temperature variation rate In this study, a finite element modeling is applied to simulate the temperature field of multilayer ZnO pyroelectric devices. The results show that alterations to the electrode width to improve the temperature variation rate are more successful when the ZnO film thickness is reduced. The marked improvement in the temperature variation rate in the ZnO layer of 200 nm thickness indicates a saturation rate of about 27% when the electrode width is approximately 1 μm. Furthermore, the optimal electrode width is reduced when the ZnO film thickness is decreased. Decreasing the ZnO film thickness clearly increases the temperature variation rate and reduces the response time; an electrode with the optimal width further enhances the temperature variation rate. Moreover, the temperature variation rate significantly decreases for thinner ZnO films when the electrode width is smaller than the optimal value. In addition, an experimental result is successful to verify the simulation results, and the electrode width is a critical parameter for designing a pyroelectric sensor. 1. Introduction ZnO is a unique material because it possesses such properties as semiconductivity, piezoelectricity, and pyroelectricity. -
Influence of Drying on the Characteristics of Zinc Oxide
i “21” — 2009/5/13 — 10:15 — page 248 — #1 i i i 248 C.P. Rezende et al. Influence of Drying on the Characteristics of Zinc Oxide Nanoparticles C.P. Rezende1, J.B. da Silva1;2, N.D.S. Mohallem1∗ 1Laboratorio´ de Materiais Nanoestruturados, Departamento de Qu´ımica, ICEx UFMG and 2Centro de Desenvolvimento da Tecnologia Nuclear – CDTN/CNEN 31270-901 Belo Horizonte-MG, Brazil (Received on 1 July, 2008) The recent growth in the field of porous and nanometric materials prepared by non-conventional processes has stimulated the search of new applications of ZnO nanoparticulate. Zinc oxide is an interesting semiconductor material due to its application on solar cells, gas sensors, ceramics, catalysts, cosmetics and varistors. In this work, the precipitation method was used followed by controlled and freezing drying processes. The materials obtained were thermally treated at various temperatures. The influence of temperature on structural, textural, and morphological properties of the materials was studied by powder X-ray diffraction, infrared spectroscopy, scanning electron microscopy, nitrogen adsorption, and thermal analysis. The characteristics of both materials were compared. Keywords: zinc oxide, drying process, nanoparticle I. INTRODUCTION II. EXPERIMENTAL Zinc nitrate and sodium carbonate were used as precursors Zinc oxide is a versatile material due to properties such of the ZnO particles. In a typical synthesis, Zn(NO3)2.6H2O as: pyroelectricity, semiconducting, piezoelectricity, lumi- were dissolved in deionized water in the molar ratio of 1:5, nescence, and catalytic activity [1 − 2]. Its optical band gap, and mixed for homogenization during 1 h. Na2CO3 were also chemical and thermal stabilities are also very important char- dissolved in deionized water in the molar ratio of 7:10, and acteristic. -
Triboelectric Nanogenerator Networks Integrated with Power Management Module for Water Wave Energy Harvesting
FULL PAPER Blue Energy www.afm-journal.de Triboelectric Nanogenerator Networks Integrated with Power Management Module for Water Wave Energy Harvesting Xi Liang, Tao Jiang, Guoxu Liu, Tianxiao Xiao, Liang Xu, Wei Li, Fengben Xi, Chi Zhang,* and Zhong Lin Wang* by the consumption of fossil fuels have Ocean waves are one of the most promising renewable energy sources for attracted worldwide attention.[1,2] It is large-scope applications. Recently, triboelectric nanogenerator (TENG) network highly urgent to search for other renew- has been demonstrated to effectively harvest water wave energy possibly able and clean energy sources. Water toward large-scale blue energy. However, the absence of effective power wave energy, which has abundant reserves and little dependence on environmental management severely restricts the practicability of TENGs. In this work, a conditions, is a promising renewable energy hexagonal TENG network consisting of spherical TENG units based on spring- source with great potential for large-scale assisted multilayered structure, integrated with a power management module applications.[3–5] However, such energy has (PMM), is constructed for harvesting water wave energy. The output perfor- rarely been exploited due to lack of eco- mance of the TENG network is found to be determined by water wave frequen- nomical energy scavenging technologies in spite of the great efforts devoted.[6–8] cies and amplitudes, as well as the wave type. Moreover, with the implemented So far, most demonstrated converters for PMM, the TENG network could output a steady and continuous direct current water wave energy rely on the electromag- (DC) voltage on the load resistance, and the stored energy is dramatically netic generators, which are heavy, bulky, improved by up to 96 times for charging a capacitor. -
Graphene Oxide Papers in Nanogenerators for Self-Powered
www.nature.com/scientificreports OPEN Graphene Oxide Papers in Nanogenerators for Self-Powered Humidity Sensing by Finger Tapping Faezeh Ejehi1, Raheleh Mohammadpour1 ✉ , Elham Asadian2, Pezhman Sasanpour2,3, Somayeh Fardindoost4 & Omid Akhavan4 Triboelectric nanogenerators (TENGs) ofer an emerging market of self-sufcient power sources, converting the mechanical energy of the environment to electricity. Recently reported high power densities for the TENGs provide new applications opportunities, such as self-powered sensors. Here in this research, a fexible graphene oxide (GO) paper was fabricated through a straightforward method and utilized as the electrode of TENGs. Outstanding power density as high as 1.3 W.m−2, an open-circuit voltage up to 870 V, and a current density of 1.4 µA.cm−2 has been extracted in vertical contact-separation mode. The all-fexible TENG has been employed as a self-powered humidity sensor to investigate the efect of raising humidity on the output voltage and current by applying mechanical agitation in two forms of using a tapping device and fnger tapping. Due to the presence of superfcial functional groups on the GO paper, water molecules are inclined to be adsorbed, resulting in a considerable reduction in both generated voltage (from 144 V to 14 V) and current (from 23 µA to 3.7 µA) within the range of relative humidity of 20% to 99%. These results provide a promising applicability of the frst suggested sensitive self-powered GO TENG humidity sensor in portable/wearable electronics. Energy harvesting is an area of tremendous attention because of the huge worldwide energy demands motivating considerable research on self-powered and autonomous systems1. -
Smart Wearable Sensors Based on Triboelectric Nanogenerator for Personal Healthcare Monitoring
micromachines Article Smart Wearable Sensors Based on Triboelectric Nanogenerator for Personal Healthcare Monitoring Ruonan Li 1,2, Xuelian Wei 3,4, Jiahui Xu 3,4, Junhuan Chen 3, Bin Li 1, Zhiyi Wu 3,4,5,* and Zhong Lin Wang 3,4,5,6,* 1 School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China; [email protected] (R.L.); [email protected] (B.L.) 2 Center on Nano-Energy Research, School of Physical Science & Technology, Guangxi University, Nanning 530004, China 3 Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, China; [email protected] (X.W.); [email protected] (J.X.); [email protected] (J.C.) 4 College of Nanoscience and Technology, University of Chinese Academy of Science, Beijing 100049, China 5 CUSPEA Institute of Technology, Wenzhou 325024, China 6 School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA * Correspondence: [email protected] (Z.W.); [email protected] (Z.L.W.) Abstract: Accurate monitoring of motion and sleep states is critical for human health assessment, especially for a healthy life, early diagnosis of diseases, and medical care. In this work, a smart wearable sensor (SWS) based on a dual-channel triboelectric nanogenerator was presented for a real-time health monitoring system. The SWS can be worn on wrists, ankles, shoes, or other parts of the body and cloth, converting mechanical triggers into electrical output. By analyzing these signals, the SWS can precisely and constantly monitor and distinguish various motion states, including stepping, walking, running, and jumping. -
Piezoelectric-Nanowire-Enabled Power Source for Driving Wireless Microelectronics
ARTICLE Received 4 Jun 2010 | Accepted 23 Sep 2010 | Published 19 Oct 2010 DOI: 10.1038/ncomms1098 Piezoelectric-nanowire-enabled power source for driving wireless microelectronics Sheng Xu1, Benjamin J. Hansen1 & Zhong Lin Wang1 Harvesting energy from irregular/random mechanical actions in variable and uncontrollable environments is an effective approach for powering wireless mobile electronics to meet a wide range of applications in our daily life. Piezoelectric nanowires are robust and can be stimulated by tiny physical motions/disturbances over a range of frequencies. Here, we demonstrate the first chemical epitaxial growth of PbZrxTi1 − xO3 (PZT) nanowire arrays at 230 °C and their application as high-output energy converters. The nanogenerators fabricated using a single array of PZT nanowires produce a peak output voltage of ~0.7 V, current density of 4 µA cm − 2 and an average power density of 2.8 mW cm − 3. The alternating current output of the nanogenerator is rectified, and the harvested energy is stored and later used to light up a commercial laser diode. This work demonstrates the feasibility of using nanogenerators for powering mobile and even personal microelectronics. 1 School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0245, USA. Correspondence and requests for materials should be addressed to Z.L.W. (email: [email protected]). NATURE COMMUNICATIONS | 1:93 | DOI: 10.1038/ncomms1098 | www.nature.com/naturecommunications © 2010 Macmillan Publishers Limited. All rights reserved. ARTICLE NatUre cOMMUNicatiONS | DOI: 10.1038/ncomms1098 he search for sustainable micro/nano-powering sources for driving wireless and mobile electronics is an emerging field in today’s energy research, which could offer a fundamental solu- T 1–3 001 tion to the energy needed for driving nanodevices/nanosystems . -
Multi-Frequency Band Pyroelectric Sensors
Sensors 2014, 14, 22180-22198; doi:10.3390/s141222180 OPEN ACCESS sensors ISSN 1424-8220 www.mdpi.com/journal/sensors Article Multi-Frequency Band Pyroelectric Sensors Chun-Ching Hsiao * and Sheng-Yi Liu Department of Mechanical Design Engineering, National Formosa University, No. 64, Wunhua Rd., Huwei Township, Yunlin County 632, Taiwan; E-Mail: [email protected] * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +886-5-6315-557; Fax: +886-5-6363-010. External Editor: Vittorio M.N. Passaro Received: 23 September 2014; in revised form: 6 November 2014 / Accepted: 20 November 2014 / Published: 25 November 2014 Abstract: A methodology is proposed for designing a multi-frequency band pyroelectric sensor which can detect subjects with various frequencies or velocities. A structure with dual pyroelectric layers, consisting of a thinner sputtered ZnO layer and a thicker aerosol ZnO layer, proved helpful in the development of the proposed sensor. The thinner sputtered ZnO layer with a small thermal capacity and a rapid response accomplishes a high-frequency sensing task, while the thicker aerosol ZnO layer with a large thermal capacity and a tardy response is responsible for low-frequency sensing tasks. A multi-frequency band pyroelectric sensor is successfully designed, analyzed and fabricated in the present study. The range of the multi-frequency sensing can be estimated by means of the proposed design and analysis to match the thicknesses of the sputtered and the aerosol ZnO layers. The fabricated multi-frequency band pyroelectric sensor with a 1 μm thick sputtered ZnO layer and a 20 μm thick aerosol ZnO layer can sense a frequency band from 4000 to 40,000 Hz without tardy response and low voltage responsivity. -
Self-Powered Multifunctional Motion Sensor Enabled by Magnetic
Article Cite This: ACS Nano XXXX, XXX, XXX−XXX www.acsnano.org Self-Powered Multifunctional Motion Sensor Enabled by Magnetic-Regulated Triboelectric Nanogenerator † ‡ ⊥ † ⊥ † ⊥ † † † † Zhiyi Wu, , , Wenbo Ding, , Yejing Dai, , Kai Dong, Changsheng Wu, Lei Zhang, Zhiming Lin, † † § Jia Cheng, and Zhong Lin Wang*, , † School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0245, United States ‡ Engineering Research Center for Mechanical Testing Technology and Equipment of Ministry of Education, Chongqing University of Technology, Chongqing 400054, China § Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, China *S Supporting Information ABSTRACT: With the fast development of the Internet of Things, the requirements of system miniaturization and integration have accelerated research on multifunctional sensors. Based on the triboelectric nanogenerator, a self-powered multifunctional motion sensor (MFMS) is proposed in this work, which is capable of detecting the motion parameters, including direction, speed, and acceleration of linear and rotary motions, simultaneously. The MFMS consists of a triboelectric nanogenerator (TENG) module, a magnetic regulation module, and an acrylic shell. The TENG module is formed by placing a free-standing magnetic disk (MD) on a polytetrafluorethylene (PTFE) plate with six copper electrodes. The movement of the MFMS causes the MD to slide on the PTFE plate and hence excites the electrodes to produce a voltage output. The carefully designed six copper electrodes (an inner circle electrode, an outer circle electrode, and four arc electrodes between them) can distinguish eight directions of movement with the acceleration and determine the rotational speed and direction as well. Besides, the magnetic regulation module is applied here by fixing a magnetic cylinder (MC) in the shell, right under the center of the PTFE plate. -
Time-Resolved Open-Circuit Conductive Atomic Force Microscopy for Quantitative Analysis of Nanowire Piezoelectricity and Triboelectricity
Time-Resolved Open-Circuit Conductive Atomic Force Microscopy for Quantitative Analysis of Nanowire Piezoelectricity and Triboelectricity Yonatan Calahorra,1∗ Wonjong Kim,2 Jelena Vukajlovic-Plestina,2 Anna Fontcuberta i Morral,23 Sohini Kar-Narayan1 1Department of Materials Science and Metallurgy University of Cambridge, CB3 0FS, Cambrdige, UK 2Laboratory of Semiconductor Materials, Institute of Materials, School of Engineering Ecole polytechnique fed´ erale´ de Lausanne (EPFL), 1015 Lausanne, Switzerland 3Institute of Physics, School of Basic Sciences Ecole polytechnique fed´ erale´ de Lausanne (EPFL), 1015 Lausanne, Switzerland ∗To whom correspondence should be addressed; E-mail: [email protected] Piezoelectric nanowires are promising materials for sensing, actuation and en- ergy harvesting, due to their enhanced properties at the nanoscale. However, quantitative characterization of piezoelectricity in nanomaterials is challeng- ing due to practical limitations and the onset of additional electromechani- cal phenomena, such as the triboelectric and piezotronic effects. Here, we present an open-circuit conductive atomic force microscopy (cAFM) method- arXiv:1908.05512v4 [cond-mat.mes-hall] 2 Oct 2019 ology for quantitative extraction of the direct axial piezoelectric coefficients of nanowires. We show, both theoretically and experimentally, that the stan- dard short-circuit cAFM mode is inadequate for piezoelectric characterization of nanowires, and that such measurements are governed by competing mech- 1 anisms. We introduce an alternative open-circuit configuration, and employ time-resolved electromechanical measurements, to distinguish between elec- trical generation mechanisms and extract the piezoelectric coefficients. This method was applied to nanowires of GaAs, an important semiconductor, with relatively low piezoelectric coefficients. The results obtained for GaAs piezo- electric coefficient, ∼0.4-1 pm/V, are in good agreement with existing knowl- edge and theory.