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Joint European Thermodynamics Conference IX JETC IX Joint European Thermodynamics Conference IX Ecole nationale supérieure des mines de Saint-Etienne, June 12-15 2007 Proceedings Wärme Heat Chaleur Calor Θερμότητα Calore Varme חום Editors : Bernard Guy and Daniel Tondeur JETC IX – 12-15 June 2007 Joint European Thermodynamics Conference IX Ecole nationale supérieure des mines de Saint-Étienne, France Contents Foreword....................................................................................................................................1 Committees................................................................................................................................2 Acknowledgements ...................................................................................................................3 Program .....................................................................................................................................4 The Ilya Prigogine prize of thermodynamics ..........................................................................13 List of papers (alphabetic order of the first authors) ...............................................................15 List and numbers of posters...................................................................................................219 Geological field trip...............................................................................................................221 Exhibition on thermodynamics..............................................................................................223 Exhibition of old and rare books on thermodynamics...........................................................225 Ceilidh ...................................................................................................................................227 Ecast ......................................................................................................................................228 List of authors........................................................................................................................229 JETC IX – 12-15 June 2007 Joint European Thermodynamics Conference IX Ecole nationale supérieure des mines de Saint-Étienne, France Foreword Why organize a conference on thermodynamics ? Are the bases of the discipline not founded solidly enough? And are the applications now so various that the dialog between the specialists from chemistry, geology, materials science, chemical engineering etc., all using thermodynamics in their own way, is becoming impossible? As a matter of fact, thermodynamics is continuously developing and new ideas and methods do appear at all levels (concepts, scale changes, mesoscopic thermodynamics and links with the nano-sciences, ab-initio methods, optimisation etc.). For this reason, it is important that all the scientists that use it and make it progress can find a place to exchange and promote new ideas. Some new methods in a domain may also appear be useful in another. So the first aim of the conference is to make a review of current research in thermodynamics and promote interdisciplinary exchanges on the progresses of thermodynamics; the focus will be given on the concepts and on the methods rather than on the applications, or in that case mostly provided a general bearing may be given. Welcome to Saint-Etienne! Pourquoi un congrès de thermodynamique? Les bases de la discipline ne sont-elles pas fondées solidement ? Et ses applications ne sont-elles pas maintenant si dispersées que le dialogue entre les spécialistes qui l’utilisent dans des domaines aussi éloignés que la chimie, la géologie, les matériaux, le génie des procédés etc. est devenu impossible ? Non, il se trouve que la thermodynamique connaît sans cesse de nouveaux développements à tous les niveaux (concepts, changements d’échelle, thermodynamique mésoscopique et liens avec les nano-sciences, méthodes ab initio, optimisation etc.). Et, pour cette raison, il est important que tous ceux qui l’utilisent et la font progresser puissent trouver un lieu pour échanger et promouvoir de nouvelles idées : de nouvelles méthodes dans un domaine peuvent- elles servir dans un autre ? Telle est l’ambition première de ce congrès : faire le point, être un lieu d’échange pluri- et inter-disciplinaire sur les progrès de la thermodynamique, en se focalisant sur les concepts et les méthodes plus que les applications. Bienvenue à Saint-Etienne ! Bernard GUY and Daniel TONDEUR, chairs of the scientific committee of JETC IX 1 JETC IX – 12-15 June 2007 Joint European Thermodynamics Conference IX Ecole nationale supérieure des mines de Saint-Étienne, France Committees Scientific committee Bernard GUY, Ecole des mines, Saint-Etienne and Daniel TONDEUR, Ensic, Nancy chairs of the scientific committee Bjarne ANDRESEN, Niels Bohr Institute, Copenhagen Dick BEDEAUX, Leyden José CASAS-VASQUEZ, University of Barcelona Danièle CLAUSSE, UTC, Compiègne Michel COURNIL, Ecole des mines, Saint-Etienne Alexis De VOS, University of Gent Jean-Pierre DUMAS, University of Pau Jean DUBESSY, CNRS, Nancy Daniel FARGUE, Ecole des mines, Paris Walter FURST, ENSTA, Paris Daniel GARCIA, Ecole des mines, Saint-Etienne Karl-Heinz HOFFMANN, Chemnitz Christian JALLUT, CPE, Lyon François MARECHAL, Ecole polytechnique fédérale de Lausanne Jean-Karl PLATTEN, University of Mons Dominique RICHON, Ecole des mines de Paris, Fontainebleau Jacques ROUX, CNRS, Paris Michel SOUSTELLE, Ecole des mines, Saint-Etienne Annie STEINCHEN-SANFELD Marseille Antonio VALERO, Saragosse Local organization committee Bernard GUY, Ecole des mines, Saint-Etienne Grégoire BERTHEZENE, Ecole des mines (website) Gérard THOMAS, Ecole des mines Olivier BONNEFOY, Ecole des mines Jean-Luc BOUCHARDON, Ecole des mines Emilie POURCHEZ, Ecole des mines (exhibition on thermodynamics) Joëlle VERNEY, Ecole des mines (secretary) Frédéric GALLICE, Ecole des mines Organisation of geological field trip Bernard GUY, Ecole des mines Jean-Yves COTTIN, Université Jean Monnet, Saint-Etienne Jean-Luc BOUCHARDON, Ecole des mines 2 JETC IX – 12-15 June 2007 Joint European Thermodynamics Conference IX Ecole nationale supérieure des mines de Saint-Étienne, France Acknowledgements We thank the following people : Frédrérique Arcos from Tourist Office for her help in the hotel and gala organisation, Marine Triomphe from Ecole des mines and BV Conseil for their help in the public relations of the conference, Noël Paul from Saint-Etienne Métropole for funding the conference, M. Michel Thiollière, Mayor of Saint-Etienne for welcoming us in the Town-Hall and Mrs Fontanilles and Tavernier for their help, All the members of the committees (refer to page 2), especially Joëlle Verney and Grégoire Berthezène; and also all those who helped us in so many ways and do not apprear in the previous lists: the doctorate researchers: Frédéric Bard, Franck Diedro, Morad Lakhssassi and Guillaume Battaia; Marc Doumas and Jacques Moutte (Ecole des mines) ; Marie- Christine Gerbe and Peter Bowden (university of Saint-Etiennne), and all the people in Ecole des mines who worked for the organisation tasks… Our non-thermodynamicists wifes and husbands… 3 JETC IX – 12-15 June 2007 Joint European Thermodynamics Conference IX Ecole nationale supérieure des mines de Saint-Étienne, France Program Joint European Thermodynamics Conference IX, JETC IX Ecole nationale supérieure des mines de Saint-Etienne Saint-Etienne, France 12-15 June 2007 This program may still be modified… Please tell us if there is a big discrepancy with your schedule or if there are mistakes. 65 communications: 40 oral communications and 25 poster communications. The oral communications last for 20 minutes including discussion (prepare 15 minutes talks) and the oral presentations of posters last for 3 minutes (no discussion, prepare 3 slides). Please bring your ppt file in advance, i.e. before the session, to the computer in the main amphitheatre. Those participants who have written books are invited to bring copies along with them for display during the conference Posters come first! Start your day by a look at the posters between 8h 30 and 9h 30 each day! Four main themes : A. Foundations of thermodynamics : history, philosophy, teaching of thermodynamics, I. Prigogine’s legacy, new approaches B. Non-equilibrium thermodynamics: thermodiffusion, kinetics of phase transitions, transport processes, advanced concepts C. Equilibrium thermodynamics: equations of state, phase equilibria, nanosystems, computation D. Optimization and engineering systems: exergy, energy, finite-time thermodynamics 4 JETC IX – 12-15 June 2007 Joint European Thermodynamics Conference IX Ecole nationale supérieure des mines de Saint-Étienne, France Day 1: Tuesday June 12 2007 8h 30 - 9h 30: registration, installation of posters, coffee, a first look to the exhibitions (thermodynamics, books) 9h 30 – 10h 50: Welcome and session A1 - 20 minutes, chair B. Guy: - welcome addresses: Bernard Guy, Daniel Tondeur, Jean-Charles Pinoli (Ecole des mines), Noël Paul (Saint-Etienne Métropole) - announcements: exhibition on thermodynamics: Emilie Pourchez, and Ecole des mines students; exhibition on books: Thierry Veyron; Ceilidh: Peter Bowden; publication of presentations in thermodynamics journals: Daniel Tondeur ; geological excursion: B. Guy - 60 minutes: Session A1 : 3 oral communications; chair: D. Tondeur • Gian Paolo Beretta : Axiomatic definition of entropy for non-equilibrium states • Jean-François LeMaréchal: Teaching and learning thermodynamics at school • Bernard Guy:
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